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Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
Each Section is further divided into two Parts: Part – A & Part – B.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
(i) PART-A (01 – 08) contains 8 Multiple Choice Questions which have Only One Correct answer. Each
question carries +4 marks for correct answer and –2 marks for wrong answer.
PART-A (09 – 16) contains 4 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer and
–1 mark for a wrong answer.
(ii) PART-B (01 – 04) contains 4 Matrix Match Type Question which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +12 marks for all correct answer however
for each correct row +3 marks will be awarded and –1 mark for each row matched incorrectly.
Name of Candidate :
Enrolment Number :
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |2
Section – I (CHEMISTRY)
PART – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
1. What volume of 0.4 M aqueous solution of HCl is required to completely dissolve 3.2 g of calcium
metal?
(A) 200 mL (B) 400 mL
(C) 800 mL (D) 100 mL
2. The atomic number of an atom is 21. What is the orbital angular momentum of it’s unpaired
electron?
h h
(A) 2 (B) 6
2 2
h
(C) 2 3 (D) Zero
2
3. Which of the following statement is correct regarding the most electronegative element of the
periodic table?
(A) It has the highest electron gain enthalpy in the periodic table.
(B) It is the smallest atom of it’s group as well as period.
(C) It forms ionic compounds in which it’s oxidation state is +1.
(D) It contains eight electrons in the outermost orbit.
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5. In which of the following reaction, the product(or the major product) has the largest molecular mass?
OH OH
(A) (B)
H2O
Heat
CH2N2 Br2
OH OH
(C) (D)
CS2 C5H5NPy
Br2 CH3COCl
6. Which of the following oxidation reaction is most favourably carried out by using MnO2?
(A) O
CH3 CH CH CH3OH CH3COOH HOOC COOH
(B) O
CH3 CH CH CH2OH CH3COOH HOOC COOH
(C) O
CH3 CH CH CH2OH CH3 CH CH CHO
(D) CHO
CH3 CH CH CHO
CH3COOH
CHO
7. Two balloons are separately filled with hydrogen and oxygen at the same temperature and
pressure. If O2 escapes at the rate of 75 mL/hour, then hydrogen will diffuse at the rate of
(A) 600 mL/hour (B) 300 mL/hour
(C) 450 mL/hour (D) 150 mL/hour
8. CH2OH CH2
PX3
X2
CH2OH CH2
In the above reaction ‘X’ is
(A) F (B) Cl
(C) Br (D) I
Space for rough work
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Paragraph
(Single Correct Choice Type)
Paragraph ( 9 – 10)
MnO2 4HCl
MnCl2 Cl2 2H2O
Above reaction is accompanied with oxidation as well as reduction. MnO2 behaves as an oxidizing agent
and HCl is used as a reducing agent. The reducing agent in HCl is chlorine. All the chlorine atoms are not
oxidized and no hydrogen atom is reduced. Out of the four moles of HCl consumed per mole of MnO 2, only
two moles are involved in the change in oxidation number. This is a convenient reaction which is used in
the preparation of chlorine in the laboratory.
Answer the following questions on the basis of above write up.
10. How many maximum number of moles of chlorine gas is evolved by complete reaction of one mole
each of MnO2 and HCl?
(A) 0.5 (B) 1
(C) 0.25 (D) 2
Paragraph ( 11 – 12)
Consider the following reactions.
Cl
CH3
Alcoholic KOH
E2
P Q R
CH 3CHO S T O U O
C2H5CCH 2CH 2CH 3 CH 3CC 2H5
11. Which of the following unknown compound form urotropine with NH3?
(A) R (B) S
(C) T (D) U
Space for rough work
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |5
Paragraph ( 13 – 14)
OH
S
Conc.NaOH
H3O
T
Answer the following questions on the basis of above write up.
Paragraph ( 15 – 16)
Compound ‘P’(C5H10O) forms compound ‘Q’(C5H12) upon wolf-kishner reduction. Reaction of ‘P’ with
NH2OH is slightly acidic medium forms oxime(R) which does not show geometrical isomerism. (S) is the
position isomer of (P). (S) forms an yellow precipitate when treated with I 2 in presence of hot NaOH.
Compound(Q) can form three monochloro products if stereoisomers are neglected.
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |6
PART – B
(Matrix Match Type)
1. Match the characteristics of atoms mentioned in Column - I with their dependent quantum numbers
mentioned in Column - II.
Column – I Column – II
(A) Energy of an atomic orbitals (P) Principal quantum number
(B) Wave function of an atomic orbital (Q) Azimuthal quantum number
2. Match the alcohols mentioned in Column - I with their chemical properties mentioned in Column - II.
Column – I Column – II
(A) CH3OH (P) Reacts with HCl through SN2 path
(B) CH3CH2OH (Q) Reacts with HCl through SN1 path
Forms alkene upon dehydration
(C) n – C3H7OH (R)
reaction at high temperature
(D) Iso – C3H7OH (S) Forms only ethers upon dehydration
3. Match the entries in column-I with entries in Column-II and then give the correct answer.
Column-I Column-II
1
vs P for ideal gas at constant T and n
(A) V2 (P)
1
(B) V vs for ideal gas at constant P and n (Q)
T
1
(D) V vs for ideal gas at constant T and n (S)
P2
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | Page |7
4. Arrange the carbonyl compounds mentioned in Column - I with their properties mentioned in
Column - II.
Column – I Column – II
O
O
O
Forms monohydric alcohol when
(C) (R)
treated with NaBH4
CHO
Forms an unsaturated ketone when
(D) (S)
heated on copper metal at 300oC
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Section – II (MATHEMATICS)
PART – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
1. ABC is a right angled isosceles triangle, right angled at A (2, 1). If the equation of side BC is
2x y 3, then the combined equation of lines AB and AC is
(A) 3x2 3y2 8xy 20x 10y 25 0 (B) 3x2 3y2 8xy 20x 10y 25 0
(C) 3x2 3y2 8xy 10x 15y 20 0 (D) none of these
2. PA and PB are tangents drawn to y2 4ax from arbitrary point P. If the angle between tangents is
, then locus of point P is
4
(A) y2 x2 a2 6ax (B) y2 x2 a2 6ax
(C) y2 x2 a2 6ax (D) y2 x2 a2 6ax
log 2 x x 2n sin x
4. Let f x lim , then f x is discontinuous at:
n 1 x 2n
(A) x 1 only (B) x 1 only
(C) x 1, 1only (D) no point
1 1
6. lim 2 is equal to:
x 0 x sin2 x
1 1
(A) (B)
3 6
1 1
(C) (D)
3 6
Space for rough work
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7.
The value of parameter a so that the line 3 a x ay a2 1 0 is normal to the curve xy 1,
may lie in the interval.
(A) ,0 3, (B) (1, 3)
(C) (–3, 3) (D) none of these
4 1
8. The least value of ‘a’ for which a, has at least one solution in the interval 0, is:
sin x 1 sin x 2
(A) 9 (B) 8
(C) 4 (D) 1
Paragraph
(Single Correct Choice Type)
Paragraph ( 9 – 10)
Each side of a square has length 4 units and its centre is at (3, 4). If one of the diagonals is parallel
to the line y x, then answer the following questions.
10. The radius of the circle inscribed in the triangle formed by any three vertices is:
(A) 2 2 2 1 (B) 2 2 2 1
(C) 2 2 1 (D) none of these
Paragraph ( 11 – 12)
A coplanar beam of light emerging from a point source has the equation x y 2 1 0, R ,
the rays of the beam strike an elliptical surface and get reflected. The reflected rays form another
convergent beam having equation x y 2 1 0, R Further it is found that the foot of the
perpendicular from the point (2, 2) upon any tangent to the ellipse lies on the circle
x2 y2 4y 5 0 .
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 10
12. The area of the largest triangle that an incident ray and the corresponding reflected ray can enclose
with axis of the ellipse is equal to:
(A) 4 5 (B) 2 5
(C) 5 (D) none of these
14. If 8, then the value of c, where [ ] represents the greatest integer function, are:
(A) (–20, –16) (B) (–20, –18)
(C) (–18, –16) (D) none of these
Paragraph ( 15 – 16)
a 1 x sin x b cos x 5
, x0
x2
Let f x 3 , x 0 where P x is a cubic function and f is continuous at
1
P x x
1 2 , x0
x
x = 0.
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PART – B
(Matrix Match Type)
1. Match the following
Column-I Column-II
(A) 1 (P) 2
for x 1
If f x x is differentiable every where and
ax 2 b for x 1
k a b , then the value of k is
(B)
If f x sgn x2 ax 1 has exactly one point of (Q) –2
discontinuity, then the value of a can be
(C) f x 2 3 n sin x , n N,x 0, has exactly 11 points of (R) 1
discontinuity, then the value of n is
(D) f x x 2 a has exactly three points of non – (S) –1
differentiability, then the value of a is
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 12
4. Let the function defined in column I have domain 0, then:
2
Column-I Column-II
(A) (P) local maximum at
x2 2cos x 2 on 0, has
2 2
cos1
3
(B) (Q)
maximum at x
1
9x 4 tan x on 0, has
2 2
(C) 1 x2 x (R) no local extremum
2 x cos sin x 4 on 0, 2 has
(D) 1 1 (S) minimum at x = 1
2 x cos x 3 sin x 3 on 0, 2 has
Space for rough work
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 13
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V
6. A galvanometer of coil resistance 1 is converted
into voltmeter by using a resistance of 5 in series
and same galvanometer is converted into ammeter 15 15 6
by using a shunt of 1. Now ammeter and 4.5
voltmeter connected in circuit as shown, find the 12
30 V
reading of voltmeter and ammeter.
A
(A) 3 Volt, 3 amp (B) 2 volt, 2 amp
(C) 4 Volt, 3 amp (D) 3 volt, 4 amp
y
7. A solid hemispherical uniform charged body having
charge Q is kept symmetrically along the y-axis as
shown in figure. The electric potential at a distance
d from the origin along the x-axis at point P will be P
x
(0,0,0) (d,0,0)
1 Q
(A)
40 d
1 Q
(B) less than
40 d
1 Q 2 Q
(C) more than and less than
40 d 40 d
2 Q
(D) more than
40 d
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Paragraph
(Single Correct Choice Type)
Paragraph ( 9 – 10)
100V 1
E1 R2
A capacitor of capacitance C 0.1F is
0.1F 99 1
charged by a battery of e.m.f. E1 = 100 V and
internal resistance r1 = 1 by putting switch S in R3
2
position 1 as shown in figure. 50V 1
E2 R1
9. Find out heat generated in R3 = 99 till steady state
(A) 500 J (B) 495 J
(C) 1000 J (D) 485 J
10. Now switch is thrown to position 2. Find the work done on the battery till steady state
(A) 250 J (B) 300 J
(C) 275 J (D) 325 J
Paragraph ( 11 – 12)
A cutting tool under microprocessor control has several forces acting on it. One force is F xy2 ˆj ,
a force in the negative y-direction whose magnitude depend on the position of the tool. The constant
is 2.50 N. Consider the displacement of the tool from the origin to the point x = 3.00 m, y = 3.00
m.
11. Calculate the magnitude of work done on the tool by F . If this displacement is along the straight line
y = x that connects these two points.
(A) 2.50 J (B) 500 J
(C) 50.6 J (D) 2 J
12. Calculate the work done on the tool by F of the tool is first moved out along the x-axis to the point
x = 3.00m, y = 0 and then moved parallel to the y-axis to x = 3.00 m, y = 3.00 m
(A) 67.5 J (B) 85 J
(C) 102 J (D) 7.5 J
Space for rough work
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Paragraph ( 13 – 14)
C
A river of width d is flowing with uniform velocity u. A boat
starts moving from point A (one bank of river) with speed u
relative to the river. The direction of resultant velocity is B
always perpendicular to line joining boat and fixed point C
(see figure). Point B is on the opposite side of the river and
A, B, C are in straight line. If AB = BC = d A
14. The distance from B where the boat will reach the other bank of river is
(A) d (B) d 2
d
(C) (D) d 3
2
Paragraph ( 15 – 16)
A potentiometer is a device used for measuring emf and S 30V
internal resistance of a cell. It consists of two circuits one is
main circuit in which there is a cell of given emf and given
resistance R which is connected across a wire of length r =1
100 cm and having resistance r and another circuit having A B
Jockey
unknown emf and galvano-meter. For a given G
potentiometer if = 30V, r = 1 and resistance R varies
with time t given by R = 2t. The jockey can move on wire
with constant velocity 10 cm/sec and switch S is closed at t
=0
15. If Jockey starts moving from A at t = 0 and balancing point found at t = 1 sec, then the value of is
(A) 1 V (B) 2 V
(C) 3 C (D) 4 V
16. If Jockey starts moving from A at t = 1 sec, then the balancing point will be obtained at
(A) t = 3 sec (B) t = 5 sec
(C) t = 4 sec (D) t = 9 sec
Space for rough work
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Ai TS – 1 ( XII ) | SET – A | APT – 4 | P a g e | 17
PART – B
(Matrix Match Type)
A B
K
m1 m2 F
+ +
Column-I Column-II
(A) The minimum value of F (in N) in order to shift (P) 5.12
the block of mass m1 is
(B) Negative of work done by friction (in J) on (Q) 40
block B till this moment is
(C) Work done by F till this moment (R) zero
(D) The minimum value of F in order to shift the (S) 32
block of mass m2 if it is applied on A.
(T) 6.4
C
B
2. Three conducting concentric spherical shells A, B A
and C having radii a, 2a and 3a respectively are S4 a S1 S2 S3
shown in the figure. Initial charge on shell B is Q,
then 3a 2a
Column-I Column-II
(A) charge on shell A if only S1 is closed. (P) zero
(B) charge on shell B if only S2 is closed. (Q) Q
(C) charge on shell C if only S3 is closed. (R) –Q/2
(D) charge on shell B if only S4 is closed. (S) –Q
(T) Q/2
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Column-I Column-II
(A) If = 0.6, then acm till 1 s (P) along +ve x-axis
(B) If = 0.4, then acm till 1 s (Q) along –ve x-axis
(C) If = 0.5, then acm till 1 s (R) zero
(D) If = 0.6, then friction force till 1 s (S) non-zero
Column-I Column-II
(A) Final charge on capacitor A in C is (P) 1
(B) Final charge on capacitor B in C is (Q) 0.5
(C) Work done by the battery in J is (R) 3
(D) Heat generated in the circuit in J (neglect (S) –1
work done by external agent)
(T) 4
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