Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
A Thesis
In Partial Fulfilment
by
Khen A. Gimeno
Jhunly L. Maglasang
John Gerald A. Laput
John Reeve S. Taliquig
October 2018
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Approval Sheet
______________________
Panel Member
Date: __________
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Abstract
an alternative binder. Cassava starch was the main component used un the
production of plastic mixed with water, soya bean oil and glycerol. The glycerol
was used as a plasticizer with water, jackfruit peel and PVA as a separate binders.
The mixtures were then prepared and plastic samples produced were subjected to
different tests. Three difference preparations were made from the different
mixtures. The first preparation contained 50 grams starch, 50 grams water, 2.5
grams oil and 2.5 grams glycerol. The second preparation contain 50 grams starch,
50 grams Jackfruit Pulp, 50 grams water, 2.5 grams oil, and 2.5 grams glycerol.
The third preparation contained 50 grams starch, 50 grams PVA, 50 grams water,
2.5 grams oil, and 2.5 grams glycerol. The second preparation exhibited the most
determine the difference among the samples that were subjected to different
using water, jackfruit pulp, and PVA as separate binders. Jackfruit peeling was
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Acknowledgement
The researchers would like to thank the people behind our successful
research; Ms. Shiela Tirol a Science teacher and currently the principal in Cebu
Roosevelt Memorial Colleges who gave us some advice for our research, to Engr.
Marilto V. Patunob for being our instructor and the one who guide us all throughout
our research. Lastly, the researchers would also like to thank their family for their
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Table of Contents
Page
Abstract 3
Acknowledgement 4
List of Tables 7
List of Figures 8
Chapter 1 INTRODUCTION
1.3 Objectives 11
2.1 Theories 15
5
Chapter 3 RESEARCH METHODOLOGY
3.7 Computations 24
BIBLIOGRAPHY 26
CURRICULUM VITAE 31
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List of Tables
Page
7
List of Figures
Page
8
Chapter 1
INTRODUCTION
especially since people became more environmentally aware that those non-
demand for plastic, from the highly technological fields of electronics, fiber
garbage bags have never changed. However, this high demand for plastics
have been a major contributor to the world’s present garbage problems. The
aids have always been a must. Binders have been called the most important
processing additive along with other additives. The role of the binder includes
Many of the controversies associated with plastics are associated with the
Cassava starch was mixed with water, epoxidized soya bean oil (ESBO),
glycerol and polyvinyl alcohol (PVA). The polyvinyl alcohol (PVA) was used as
a water-soluble binder. The samples would not dissolved in ethanol since the
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binder (PVA) used is water-soluble. In order to solve this problem, an
explore the possibility of finding an alternative binder that can be easily found
in our surroundings.
PVA is nontoxic but its biodegrades only slowly and only up to 5% solutions
are nontoxic (Hallensleben, 2000). PVA can be quite expensive and the
utilization of binders from local and cheaper materials is also quite a necessity
Philippines.
Researchers of the study, plan to use Jackfruit peeling as the raw material
of the target alternative binder. Almost all the parts of the jackfruit tree including
its fruit secretes latex when injured which is a good factor when it comes to
binding. The jackfruit peeling itself also contains cellulose which is the chief
the raw material for an alternative binder. Furthermore, the study will determine
The study will evaluate the potential of the Jackfruit peeling as an effective
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Sub-problems
1.) What are the characteristics of new plastic using water as plastic binder
and the characteristics of the new plastic using jackfruit pulp as plastic
b) Tensile Strength
c) Flammability
e) Biodegradability
2.) Is there a difference between the plastic using water, jackfruit pulp and
PVA as binder?
1.3 Objectives
to alternative binder.
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nowadays. The goal of the researches in this study is to produce a better
alternative material using the Jackfruit peeling as the raw material as one of
This study also aims to lessen the level of waste products in our society.
disposed jackfruit peeling into useful products, is also a major stem in solving
This study will utilize the Jackfruit peeling as the raw material to the
alternative binder; it will be compared to water and PVA as binders. The study
will also determine the characteristics of the new plastic using jackfruit pulp as
plastic binder in terms of its effect on strong acid and strong base, tensile
Jackfruit
California Rare Fruit Growers, Inc. 1996). Jackfruit peeling is used in out study as
the source of cellulose and latex that will be the main materials needing in
producing binders.
Cellulose
units which comprises about 33 percent of all vegetable matter and is the basic
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structural component of plant cell wall. It is also known to be the most abundant of
all naturally occurring organic compounds (“Cellulose,” n.d.). Besides its latex
Binder
Is an ingredient which binds or holds the particles and gives dry and wet strength
that holds or draws other materials together to form a cohesive whole. Materials
labelled as binders in different proportions or uses can often have their roles
reversed with what they are binding (“Binder”, n.d.). It will be alternative binder
using the jackfruit peeling as a raw material for Cassava starch plastic.
Starch
Is the chief form of stored energy in plants, especially wheat, corn, rice and
potatoes and is a mixture of two different polysaccharides built out of glucose units,
which forms a white, tasteless powder when purified. (The American Heritage
Science Dictionary, 2005). In many parts of the plant, it occurs in the form of grains
Polyvinyl alcohol
alcohol,” n.d.) It is usually used for grease proofing paper, in adhesives, in gas-
and oil-impervious films and Coatings. This substance, although soluble in water,
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Glycerol
structure are responsible for its solubility in water and its hygroscopic nature. It is
also important to note that the glycerol backbone is central to all lipids known as
triglycerides. Its sweet-tasting and low toxicity property is very important (“What is
glycerol?,” n.d.)
Tensile Strength
force per cross-sectional area. As an example, if a metal rod one square inch in
cross section can withstand a pulling force of 1000 pounds but breaks if more force
is applied, the metal has a tensile strength of 1000 pounds per square inch
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Chapter II
THEORETICAL BACKGROUND
2.1 Theories
starch line up and bonding an ordered fashion (due to hydrogen bonding) when
making the plastic film to make a strong material. The straight chained amylase
molecules form a more ordered, and stronger, plastic film, compared to the
branched amylopectin molecules that are difficult to align. To break down the
boiling once the starch solution is acidified. The starch becomes soluble in the
water as the solution is heated then loses its semi-crystalline structure as the
starch granules swell with water. This process is known as gelatinization which
creates a paste that is highly viscous. Once the paste cools, the water is expelled
and the amylase molecules form hydrogen bond to for a semi-crystalline structure
again resulting in a brittle plastic film. Other chemicals can be added to the solution
before heating to improve the flexibility of the samples. Glycerol is a small molecule
that is hygroscopic or water attracting. So that when added to the starch mixture,
glycerol traps water in the starch chains making it less crystalline, and
consequently less brittle. Gelatinization can be delayed with the presence of sugar
by competing with starch to absorb water. Moreover, glue will increase the
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flexibility sample, while keeping a high tensile strength (“Starch to Plastics: Making
Most plastics contain other organic or inorganic compounds blended in. The
amount of additives ranges from zero percentage for polymers used to wrap foods
to more than 50% for certain electronic applications. The average content of
reduce production costs. Stabilizing additives include fire retardants to lower the
flammability of the material. Many plastics contains fillers, relatively inert and
inexpensive materials that make the product cheaper by weight. Typically fillers
are mineral in origin, e.g., chalk. Some fillers are more chemically active and are
reinforcing agents. Since many organic polymers are too rigid for particular
applications, they are blended with plasticizers (the largest group of additive, oily
Southeast Asia and is considered the national fruit of Bangladesh, locally called
forests of India. It is also well suited to tropical lowlands, and its fruit is the largest
long and 20 inches (50cm) in diameter. Outside of its countries of origin, fresh
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jackfruit can be found at Asian food markets, especially in the Philippines. Its has
a ripening season in Asia of late spring to late summer. All parts of the tree exude
sticky while latex when injured. The latex contains resins that may have use in
varnishes. The latex also has bacteriolytic value comparable to that of papaya
latex.
introduced and the chemical basis of the process is explored in depth. The
polymer chains from one another; restraining them from becoming rows of chains
undesired because it is a brittle and fragile structure which makes the plastic brittle
and fragile as well. Instead of the crystalline structure, the formation of film (not
thermoplastic synthetic resin was the one used as a binder in the experiment.
Based on the results, the biodegradable plastic made dissolve in water because
the binder (PVA) used is water-soluble. In order to solve this problem, an alternate
this problem.
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To find another alternative binder that can be used as binder to plastic, the
biodegradable plastic.
fruit seed starch had comparable binding properties (Narkhede Sachin, et. Al.,
2011). This study suggest that jackfruit seed powder has a lot of potential in food,
Another study was made on latex content of jackfruit. Based on the results
obtained from the study, it was found out that crude latex of jackfruit tree contains
material of binding agent and its good source of latex will be used as a reference
by the researchers of the present study. The related literature and the related
studies gathered supports the idea of jackfruit as an effective binder since it was
said that is has latex content. Also considering the sticky nature of latex, using it in
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Previous studies have used commercial materials like PVA (Polyvinyl
Some studies have already used jackfruit as a binder to different materials which
binder (which is the goal of this present study) is a new study in providing an
alternative binder that is also comparable and similar to the commercial binders or
2013). In this project, the researcher developed a method for making plastic by
using banana peels and found new areas for the use of the plastic manufactured:
cables.
alternative binder for biodegradable plastic from Cassava starch as inspired by the
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Chapter 3
RESEARCH METHODOLOGY
treatments of the study. The preparations of the binder (jackfruit pulp) will be
made at the researchers’ house and the experimentation of that binder will be
Materials:
Cassava Starch
Oil
Spatula
PVA
Tap Water
Strainer
Graduated Cylinder
Measuring Cups
Containers/petri dishes
Beakers
Glycerol
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Equipment’s:
Blender
Weighing Scale
Alcohol Lamp
Hot Plate
Fresh and new Jackfruit peelings including the spines and ragging were
utilized. The peelings were grounded using the blender and sooner or later, an
amount of water were added gradually to form a paste from the jackfruit
peeling. To obtain the size of the small particles, the paste was strained and
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preserved in a plastic bottle. Then stored in the refrigerator, ready to be used
Preparation of Plastic
water; 50 grams starch; 2.5 grams Oil; and 2.5 grams glycerol. Batch 2 is made
without Jackfruit pulp; 50 grams water; 50 grams starch; 2.5 grams Oil; and 2.5
starch; 2.5 grams Oil; and 2.5 grams glycerol. Measured amounts of water and
starch components were mixed and boiled, using a hot plate (at 50 degrees
centigrade), until a sticky paste was formed. After removing the starch-water
mixture form the hot plate, the rest of the materials were added. The mixture
was poured into a petri dish and put in the over 130 degrees centigrade. It was
Tensile Test
Strips were hooked to a spring balance and were pulled until they tore apart.
The readings on the balance when the strips broke were recorded.
Flammability Test
Strips with the same dimensions were burned using alcohol lamp. Burning
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Solubility Test
ethanol for 48 hours. Changes in length, width and appearance were also
noted.
Biodegradable of plastic
The samples also underwent biodegradability test. The strips were stapled
to a piece of cardboard and buried in a can of soil. The strips were unearthed
The data gathered during the study will be presented through a table to
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Flammability Test
Plastic Samples were burned
3.7 Computations
Prices:
Oil – P100/1.5 L
Glycerol – P54.22/kg
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1000𝑔 1000𝑔
1 kg * = 𝑃54.22 so, P0.054 per gram. Then, P0.054 * 250g =
1𝑘𝑔
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BIBLIOGRAPHY
http://en.wikipedia.org/wiki/Binder_(material).
http://global.britannica.com/EBchecked/topic/101633/cellulose
http://global.britannica.com/EBchecked/topic/469236/polyvinyl-alcohol-PVA
Starch to Plastics: Making Bioplastic Lab. (n.d) Retrieved July 20, 2013 from
http://www.chem.umn.edu/csp/Starch%20to%20Plastics%20Lab%20%20teacher
s%20notes.pdf
http://science.howstuffworks.com/tensilestrength-info.htm
California Rare Fruit Growers, Inc. (1996). Jackfruit. Retrieved July 20,
http://www.crfg.org/pubs/ff/jackfruit.html
Weinheim.doi:10.1002/14356007/a21_743
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Hans-Georg Elias “Plastics, General Survey: in Ullmann’s Encyclopedia of
Weinheim.doi:10.1002/14356007.a20_543
http://www.thefreedictionary.com/starch
Teuten EL, Saquing JM, Knappe DR, et al. (July 2009). “Transport and
StudyMode.com.RetrievedJuly20,2013fromhttp://www.studymode,com/essays/Bi
odegradable-Plastic-From-CassavaManihot-Esculenta-1389402.html
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September23,2013fromhttp://googlesciencefair.com/en/projects/ahJzfnNjaWVuY
2VmYWlyLTIwMTJyRAsSC1Byb@plY3RTaXR1IjNhaEp6Zm5OaMFXVnVZM1Zt
WVdseUxUSXdNVEp5RUFzU0IxQnliMnBsWTNRWW9ZR0tBUXcM
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CURRICULUM VITAE
Khen A. Gimeno
Personal Information
________________________________________________________________
Age: 20 Religion: Roman Catholic
Gender: Male Date of Birth: February 10, 1998
Civil Status: single Place of Birth: Tinaan, City of Naga, Cebu
Nationality: Filipino
Education
________________________________________________________________
2015-Present Bachelor of Science in Mechanical Engineering - Mechatronics
Cebu Institute of Technology- University Cebu City
2011- 2015 Secondary School Diploma
Mary Help of Christians School Cebu Inc.
2005- 2011 Elementary School Diploma
Cepoc Central School
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CURRICULUM VITAE
Jhunly L. Maglasang
Personal Information
________________________________________________________________
Age: 20 Religion: Roman catholic
Gender: Male Date of Birth: July 13, 1998
Civil Status: single Place of Birth: Cebu City, Cebu
Nationality: Filipino
Education
________________________________________________________________
2015-Present Bachelor of Science in Mechanical Engineering
Cebu Institute of Technology- University Cebu City
2011- 2015 Batch Valedictorian
Secondary School Diploma
Cebu Roosevelt Memorial Colleges, San Vicente St., Bogo Cebu
2005- 2011 Batch Valedictorian
Elementary School Diploma
Dakit Elementary School, Dakit, Bogo City
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CURRICULUM VITAE
Personal Information
________________________________________________________________
Age: 20 Religion: Roman Catholic
Gender: Male Date of Birth: October 21, 1997
Civil Status: single Place of Birth: City of Naga, Cebu
Nationality: Filipino
Education
________________________________________________________________
2017-Present Bachelor of Science in Mechanical Engineering
Cebu Institute of Technology- University Cebu City
2014-2017 Bachelor of Science in Mechanical Engineering
University of San Carlos Talamban Campus
2010- 2010 Secondary School Diploma
Played for DLS ASMC Men’s Football Varsity Team
De La Salle Andres Soriano Memorial College, Das Lutopan
Toledo City
2004- 2010 Elementary School Diploma
De La Salle Andres Soriano Memorial College, Das Lutopan
Toledo City
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CURRICULUM VITAE
Personal Information
________________________________________________________________
Age: 19 Religion: Iglesia Filipina Independiente
Gender: Male Date of Birth: January 9, 1999
Civil Status: single Place of Birth: Oroquieta City, Misamis Occidental
Nationality: Filipino
Education
________________________________________________________________
2015-Present Bachelor of Science in Mechanical Engineering - Mechatronics
Cebu Institute of Technology- University Cebu City
2011- 2015 Secondary School Diploma
Misamis Occidental National Science High School
2005- 2011 Elementary School Diploma
Oroquieta City Central Elementary School
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