TARGET CH EMISTRY

DAILY PRACTICE PROBLEMS

JEE (ADVANCED) : 2015 DPP

COURSE NAME : UDAY (UB) DATE : 14.10.2013 to 19.10.2013 DPP NO. 39 & 40

* Marked Questions are having more than one correct option.

DPP No. # 39
1. Which of the following are isostructural?
NO3–, CO32–, ClO3– , SO3, XeO3
(I) (II) (III) (IV) (V)
(A) (I) and (IV) (B) (II) and (V) (C) (III) and (IV) (D) (IV) and (V)

2. In which of following vacant orbitals take part in hybridisation :

(A) BF3 (B) CH4 (C) B2H6 (D) N
 H
3

3. Which of the following should have pyramidal shape :

(A) [ClOF2]+ (B) ICl3 (C) [BrCl]– (D) All of these

4. The hybridisation of P in phosphate ion (PO43–) is the same as :

(A)  in C4– (B) S in SO3 (C) N in NO3¯ (D) S in SO32–


5. Specify the hybridisations of central atom in the following species respectively { N3 , NOCl, N2O}
(A) sp , sp2 , sp (B) sp , sp , sp3 (C) sp2 , sp , sp (D) sp2 , sp2 , sp.

6. In which of the following species bond angle is expected to be more than 120º :
(A) PCl4+ (B) NO2– (C) NO2+ (D) XeF2

7.* Identify the correct option(s) :

(A) NH4+ > NH3 > NH2– order of bond angle
(B) (CH3)3 B is a trigonal planar molecule (not considering the H-atoms on ‘C’)
(C) In NH4Cl ‘N’ atom is in sp3d hybridisation
(D) In S8 molecule a total of 16 electrons are left on all the ‘S’ atoms after bonding .

8. (a) Answer the following questions considering the structure of I2Cl6 molecule.
(i) Total number of lone pairs of electrons on iodine atoms.
(ii) Total number of three centre-four electron bonds, i.e. 3c–4e bonds.
(iii) Molecule is planar or non-planar.
(iv) Total number of identical I-Cl bonds (i.e. having same bond length).

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9. Arrange the following properties as indicated.
(a) Increasing order of mobility of ions in water.
Li+, Na+, K+, Rb+, Cs+

1
Degree of hydration  ionic size : Bigger hydrated ion moves slowly..

(b) Increasing order of basic character.

CO2, CaO, K2O, MgO, SiO2, CuO
(c) Increasing order of electron gain enthalpy (with negative sign).
Cl , F, Te, O, N
(d) Increasing order of number of double bonds in the molecules.
Cyclic (SO3)3 , Cyclic (HPO3)3, P4O10
(e) Increasing order of number of unpaired electrons
Mn2+, Cu2+, Fe2+, Ni2+ (Atomic Number : Mn - 25, Fe - 26, Ni - 28, Cu -29)
(h) Increasing order of bond angles (O – X–O) in the ions. Where X represents the central halogen
atoms. ClO3– , BrO3– , O3–

10. Match the following

Column () Column ()
(A) Br –2 (p) sp3d2, 2 lone pairs
(B) –5 (q) sp3d, 1 lone pair
(C) ICl–4 (r) sp3d3, 1 lone pair
(D) IF–6 (s) sp3d3, no lone pair
(t) sp3d, 3 lone pairs

DPP No. # 40
1. The hybridization of central atom and shape of (SiH3)NCO :
(A) sp2, planner (B) sp3, tetrahedral (C) sp3, pyramidal (D) sp, linear

2. Gaseous SO3 molecule

(A) is plannar triangular in shape with three  bonds from sp2 – p overlap and three -bonds formed
by two p – p overlap and one p – d overlap.
(B) is plannar triangular in shape with three -bonds from sp2 – p overlap and three -bonds formed
by one p – p overlap and two p – d overlap.
(C) is a pyramidal molecule with one double bond and two single bonds
(D) plannar triangular in shape with two double bonds between S and O and one single bond

3. The correct order of C–N bond lengths is :

P : CH3CN Q : HNCO R : CH3CONH2
(A) P > Q > R (B) P = Q = R (C) R > Q > P (D) R > P > Q

4. Resonating structures have different :

(A) Atomic arrangements (B) Electronic arrangements
(C) Functional groups (D) Alkyl groups.

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5. Resonance hybrid of nitrate ion is :

(A) (B) (C) (D)

6. Hydrogen forms a bridge in the chemical structure of :

(A) Hydrogen peroxide (B) Lithium hydride (C) Diborane (D) Sodium peroxide

7. In B2H6 :
(A) There is a direct boron-boron bond
(B) The structure is similar to that of C2H6
(C) The boron atoms are linked through hydrogen bridges
(D) All the atoms are in one plane

8. The molecules of aluminium chloride in vapour state:

(A) Have no shape (B) Are shaped like a plane triangle
(C) Are round (D) Are like randomly broken bricks

9. STATEMENT - 1 : Calculated bond length of B—F bond in BF3 is 152 pm whereas observed bond length
is 130 pm.
STATEMENT - 2 : B - F bond in boron trifluoride possesses or double bond character due to p-p back
bonding.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

ANSWER KEY
DPP No. # 39
1. (A) 2. (C) 3. (A) 4. (D) 5. (A) 6. (C) 7.* (AB)

8. (i) 4 (ii) 2 (iii) Planer (iv) 4.

(a) = 2.70 Å and (b) = 2.39Å ; (c) = 94º and (d) = 84º ; Planar molecule
9. (a) Li+ < Na+ < K+ < Rb+ < Cs+
1
Degree of hydration  ionic size : Bigger hydrated ion moves slowly..

(b) CO2 < SiO2 < CuO < CaO < K2O (c) N < O < Te < F < Cl
(d) (HPO3)3 < P4O10 < (SO3)3
3 4 6
(e) Cu2+ < Ni2+ < Fe2+ < Mn2+
n= 1 2 4 5
(h) O3– < BrO3– < ClO3–
10. (A) t ; (B) p ; (C) p ; (D) r.
DPP No. # 40
1. (D) 2. (B) 3. (C) 4. (B) 5. (B) 6. (C) 7. (C)
8. (B) 9. (A)

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