MOLE CONCEPTS

QUIZ-1
Q.1 The action of bacteria on meat and fish produces a poisonous compound called cadaverine. As its
name and origin imply, it stinks! It is observed that 510 gm of it contains 300 gm carbon, 70 gm
hydrogen & rest is nitrogen. Given that its molar mass is 102g/mol. Determine the molecular
formula of cadaverine.

Q.2 A sample of MgCO3 contains impurities which do not react with a acid. When 10 grams of the
sample were reacted with the acid, 2463 ml of carbon dioxide were obtained at 27oC and 1 atm
pressure. Calculate the % purity by mass of the sample? [R = 0.0821 atm.L/ mole /K]

Q.3 Calculate the amount of ZnO produced (in gm) when 195 gm of ZnS reacts with 89.6 l O2 at 1 atm
and 273 K.

ZnS  O2 
 ZnO  SO2
Q.4 Once Tom & Jerry entered a chemistry lab where a chemist was preparing 3 l H2SO4 solution. He
labelled the solution as 10 m (dsolution = 3.3 gm/ml). As the chemist left the lab, a mischief came in
Tom’s mind. He tried to throw the solution on Jerry but failed. In doing so some of the H2SO4
solution fell on the floor, so he added water to make it again to 3l. The chemist returned back & got
astonished when he saw the result of analysis, that were d = 1.5 gm/ml and % w/w = 98. Find out
the moles of H2SO4 which fell down on the floor.

Q.5 Two liquids ‘A’ (Molecular mass = 40) and ‘B’ (Molecular mass = 20) are partially miscible. When
1 mol of A and B are shaken together and allowed to settle, two layer ‘L1’ and ‘L2’ are formed as
shown in diagram.

Layer ‘L1’ contains 0.1 mole fraction of ‘A’ and layer ‘L2’ contains 0.4 mole fraction of A calculate
the ratio of masses of layer L1 to layer L2.
 MOLE CONCEPT
QUIZ-2
By: Dr. Rajan Khare
Q.1 Preparation of cobalt Metaborate involves the following steps of reaction:
(i) Ca2 B6O11  Na2CO3 (aq ) 
Boiled
CaCO3 (insoluble)  Na2 B4O7  2NaBO2

(ii) Na2 B4O7   NaBO2  B2O3

(iii) CoO  B2O3   Co( BO2 )2
(a) Mass of Ca2B6O11 in kg required to produce 14.5 kg of Co(BO2)2, assuming 100% yield of each
reaction.
200
(b) If the yield of reaction (i), (ii) & (iii) is 60%, % and 32.2% respectively. Calculate mass of
3
Ca2 B6O11 in kg required to produce 14.5 kg of Co(BO2)2.

Q.2 Water is added to 3.52 grams of UF6. The products are 3.08 grams of a solid [containing only U, O
and F] and 0.8 gram of a gas only. The gas [containing fluorine and hydrogen only], contains 95%
by mass fluorine.
(a) Determine the empirical formula of the gas.
(b) What fraction of fluorine of the original compound is converted into gaseous compound.
(c) What is the empirical formula of the solid product?
(d) Write a balanced equation for the reaction of UF6 and H2O.

Q.3 The mass P4O10 produced if 440 gm of P4 S3 is mixed with 384 gm of O2 is

P4 S3  O2 
 P4O10  SO2

(A) 568 gm (B) 426 gm (C) 284 gm (D) 396 gm

Q.4 Volume of water which must be added to 8M HCl to make 2 lit. of 7.3% w/v HCl solution is
(A) 1.5 lit. (B) 0.5 lit. (C) 1 lit. (D) 2 lit.

Q.5 Molarity of aqueous NaOH solution will be, if mole fraction of NaOH in the solution is 0.5.
[Given: density of pure NaOH = 4 gm/ml]
(A) 76.92 (B) 35.71 (C) 68.96 (D) 26.46
 MOLE CONCEPT
QUIZ-3
By: Dr. Rajan Khare
Q.1 The molarity of OHion in the final solution, if 200 ml of 8 M HCl solution is mixed with 800 ml of
2M Ca(OH)2 solution is
(a) 0.08 M (b) 1.6 M (c) 3.2 M (d) 0.16 M

Q.2 Calculate percentage change in Mavg of the mixture, if PCl5 undergo 50% decomposition.

PCl5 
 PCl3  Cl2

(a) 50% (b) 66.66% (c) 33.33% (d) zero

Q.3 For which of the following solution, minimum amount of NaOH is required for complete neutralisation.
[Assume complete dissociation of acid]
(a) 50 ml H2SO4 solution [basicity = 2] (dsolution = 2 gm/ml), % w/w = 98
(b) 50 ml H3PO4 solution [basicity = 3] (dsolution = 2 gm/ml), % w/w = 98
(c) 100 ml HCl solution [basicity = 1) (dsolution =1.5 gm/ml), % w/w = 36.5
(d) 100 ml HNO3 solution [basicity = 1] (dsolution =1.5 gm/ml), % w/w = 36.5

Q.4 Statement – 1: For a very dilute solution molality & molarity are always approximately equal
Statement – 2: Mass of solution is always approximately equal to mass of solvent for a very dilute
solution.
(a) Statement –1is true, statement – 2 is true and statement – 2 is correct explanation for statement – 1.
(b) Statement – 1 is true, statement – 2 is true and statement – 2 is NOT the correct explanation for
statement – 1.
(c) Statement – 1 is false, statement – 2 is true.
(d) Statement – 1 is true, statement – 2 is false.

Q.5 Statement – 1: Molality of pure ethanol is lesser than pure water.

Statement – 2: As density of ethanol is lesser than density of water.
[Given : dethanol = 0.789 gm/ml; dwater = 1 gm/ml]
(a) Statement – 1 is true, statement – 2 is true and statement – 2 is correct explanation for statement - 1
(b) Statement – 1 is true, statement – 2 is true and statement – 2 is NOT the correct explanation for
statement – 1.
(c) Statement – 1 is false, statement – 2 is true
(d) Statement – 1 is true, statement – 2 is false.
 MOLE CONCEPT
QUIZ-4
By: Dr. Rajan Khare
Q.16 ‘2V’ ml of 1M Na2SO4 is mixed with ‘V’ ml of 2M Ba(NO3)2 solution.
(a) Molarity of Na+ ion in final solution can’t be calculated as V is not known.
(b)Molarity of BaSO4 in final solution is 2/3M.
(c) Molarity of NO3 in final solution is 4/3M.

(d) Molarity of NO3 is final solution is 2/3M.

Q.17 Select the option (s) which have equal number of ‘O’ atom.
(a) 10 ml H2O(l) (b) 0.15 mole of V2O5
(c) 12 gm O3(g) (d) 12.044  1022 molecules of CO2

Q.18 The incorrect option(s) is/are:

For the reaction,
aA( g )  bB( g ) 
 cC ( g )  dD( g )
[Given : a + b  c + d]
(a) Vapour density of mixture increases with the progress of reaction if (a + b) > (c + d).
(b) Percentage change in vapour density, with progress of reaction depends upon extent of reaction.
(c) Variation of vapour density of the mixture, with progress of reaction doesn’t depend on
stoichiometric coeefficients of the species.
(d) Vapour density of mixture decreases with the progress of reaction if (a + b) > (c + d).

Q.19 [It is known that the formation of CO or CO2 depends upon the relative amount of O2 and carbon.
When O2 is limited it gives CO, when in excess gives CO2. CO can be converted to CO2 when reacted
with O2.]
When 1 mol of CO is formed from 1 mol of carbon and ½ mol of O2, 25 K cal heat is evolved. When
1 mol of CO2 is formed from 1 mol of carbon and 1mol of O2, 75 Kcal heat is evolved.
Select the option (s) in which heat evolved is more than 100 Kcal.
(a) 10 mol of carbon and 1.5 mol of O2 (b) 36 gm of carbon and 96 gm of O2
(c) 6 mol of carbon and 3 mol of O2 (d) 72 gm of carbon and 32 gm of O2
 MOLE CONCEPT
QUIZ-5
By: Dr. Rajan Khare

Q.1 H3PO4 undergoes dissociation as

 3H   PO43
H3 PO4 
n cation + n anion
If
n H3 PO4  undissocia ted

Calculate % dissociation of H3PO4.

Q.2 A mixture is prepared by mixing 10 gm H2SO4 and 40 gm SO3 calculate,

(a) mole fraction of H2SO4 (b) % labelling of oleum

Q.3 A mixture of C5H8 and H2 gas was placed in a container at a constant temperature. Initial volume of
mixture was 40ml. Sparking the mixture caused hydrogenation reaction
C5 H8 ( g )  2H 2 ( g ) 
 C5 H12 ( g )
Causing a decrease in volume by 24 ml. Excess of O2 was then added and on sparking the volume
further decreased by 60 ml. Calculate volume of each gas in original mixture. Assuming that all
volumes are measured at same temperature and pressure.

Q.4 500 ml of a H2O2 solution on complete decomposition produces 2 moles of H2O. Volume strength of
H2O2 solution is [Given : Volume of O2 is measured at 1 atm and 273 K]
(a) 11.2 V (b) 22.4 V (c) 5.6 V (d) 44.8 V

Q.5 A gaseous reaction,

3 A 
 2B
Is carried out in a 0.0821 litre closed container initially containing 1 mole of gas A. After sufficient
time a curve of P (atm) vs T (K) is plotted and the angle with x-axis was found to be 42.95o. The degree
of association of gas A is
(a) 0.4 (b) 0.6 (c) 0.5 (d) 0.8
 MOLE CONCEPT
QUIZ-6
By: Dr. Rajan Khare
Q.1 Statement – 1 : Mass of a solution of 1 litre of 2M H2SO4 [dsolution = 1.5 gm/ml] is greater than the
mass of solution containing 400 gm MgO which is labelled as 40%(w/w)MgO.
Statement – 2: Mass of H2SO4 in 1 litre 2M H2SO4 [dsolution = 1.5 gm/ml] is greater than the mass of
MgO in 1 litre 40% (w/w)MgO [dsolution = 2gm /ml] solution.
(a) Statement -1 is true, statement -2 is true and statement – 2 is correct explanation for statement -1.
(b) Statement – 1 is true, statement – 2 is true and statement – 2 is NOT the correct explanation for
statement – 1.
(c) Statement – 1 is false, statement – 2 true.
(d) Statement – 1 is true, statement – 2 is false

Q.2 For the compound

Select the correct option(s)

(a) If the above 22.8 gm compound is subjected to Liebig’s method the mass of CO2 and H2O produced
are 22 gm and 9 gm respectively.
(b) If the 114 gm of the above compound is subjected to Kjeldahl’s method the moles of H2SO4
required to neutralized evolved ammonia is 0.25 moles.
(c) The mass of Ammonium phosphor molybdate [(NH4)3 PO4. 12MoO3] obtained when the 45.6
gm of above compound is subjected to first HNO3 and then with (NH4)2MoO4 is 206.9 gm.
(d) The mass of precipitate formed in Carius method is 18.8 gm when 22.8 gm of above compound is
used.

Q.3 Concentration of 2 M NaOH solution [dsolution = 1.2 gm/ml] can also be written as
(a) 80% w/v NaOH (b) 6.66% w/w NaOH
(c) 1.3 m NaOH solution (d) 6.66  107 ppb NaOH

Q.4 100 ml of 0.1 M solution of AB (d = 1.5 gm/ml) is mixed with 100 ml of 0.2 M solution of CB2 (d =
2.5 gm/ml). Calculate the molarity of B in final solution if the density of final solution is 4 gm/ml.
Assuming AB and CB2 are non reacting & dissociates completely into A+, B, C+2.

Comprehension: (1 Question)
2 litre of 9.8% w/w H2SO4 (d = 1.5 gm/ml) solution is mixed with 3 litre of 1 M KOH solution.
Q.5 The number of moles H2SO4 added are
(a) 1 (b) 2 (c) 3 (d) 0.5
 MOLE CONCEPT
QUIZ-7
By: Dr. Rajan Khare
Comprehension (2 Questions)
For the given series of reaction
NH3 ( g )  O2 ( g ) 
 NO( g )  H 2O(l )

NO( g )  O2 ( g ) 
 NO2 ( g )
Q.1 If 20 ml of NH3 is mixed with 100 ml of O2, volume contraction at the completion of above reactions
is
(A) 20 (B) 85 ml (C) 35 ml (D) 100 ml

Q.2 To obtain maximum mass of NO2 from a given mass of a mixture of NH3 and O2, the ratio of mass of
NH3 to O2 should be
4 17 17
(A) (B) (C) (D) None of these
7 56 40

Q.3 An aqueous solution contain 10% by mass CH3COOH. Which is/are correct for this solution. (Assume
density of solution is 2 gm/ml)
1
(A) mole fraction of CH3COOH = (B) molarity = 3.33 M
31
1
(C) molality = m (D) ppm of CH3COOH = 185
1.85

Q.4 What volume of 0.2 M NaOH (in ml) solution should be mixed to 500 ml of 0.5 M NaOH solution so
that 300 ml of final solution is completely neutralized by 20 ml of 2 M H3PO4 solution.
[Assuming 100% dissociation]

Q.5 100 ml of 0.1 M Na2SO4 is mixed with 100 ml of 0.2 M NaCl solution. Molarity of Na+ ion in final
solution. If final solution has density 1.2 gm/ml.
(A) 0.1 (B) 0.2 (C) 0.8 (D) 0.15
 MOLE CONCEPT
QUIZ-8
By: Dr. Rajan Khare
Q. Number of moles of NH3 produced if 140 gm of N2 reacts with 40 gm of hydrogen.
[Given % yield of reaction is 50%]
(A) 12 (B) 10 (C) 5 (D) 6

Q. Match the column:

(A) 50 gm of “109% oleum” (P) wt. of H 2 SO4 finally 3
 or 4
wt. of SO3 Finally 2

(B) 100 gm of “109% oleum” + 4.5 gm H2O (Q) 20 gm SO3 in the final solution
(C) 25 gm of “118% oleum” (R) Final % labelling 104.5%
(D) 200 gm of “104.5 % oleum” (S) 80 gm H2SO4 per 100 gm oleum solution
finally

Q. Molarity of aqueous solution of NaOH having mole fraction 0.2 and density 1 gm/ ml.
(A) 13.8 (B) 8.9 (C) 12.2 (D) 10.1

Q. The density of a pure liquid (mol wt. 70) is 1.2 gm/ml. If 2 ml of liquid contain 35 drops, the no. of
molecules in 2 ml of liquid are
1.2 1 1.2
(A)  NA (B)  NA (C)  NA (D) 1.2 N A
(35) 2 35 35

Q. A sample of acetone undergoes 40% dimerization. Then mole fraction of the dimer in the final mixture
is
(A) 0.16 (B) 0.75 (C) 0.4 (D) 0.25
 MOLE CONCEPT
QUIZ-9
By: Dr. Rajan Khare

Q.1 Calculate the mass (in gm) of copper nitrate Cu(NO3)2 obtained by treating 254 gm of copper with
excess of concentrated nitric acid (HNO3) from above reaction.
Cu(s)  HNO3 (aq) 
 Cu( NO3 )2 (aq)  H 2O(l )  NO2 ( g )

Q.2 A compound containing Mg, S, O and H. It is observed that 492 gm of it contains 48 gm of Mg, 64 gm
sulphur, 352 gm of oxygen and remaining is hydrogen. Given that its molar mass is 246 gm/mol. All
the hydrogen present in it is in the form of water of crystallization. Write its molecular formula showing
water of crystallization.

Q.3 Calculate the percentage loss in mass, when 2.02  102 gm KNO3 is completely decomposed by heating
into KNO2(s) & O2(g).
KNO3 (s) 
 KNO2 (s)  O2 ( g )

Q.4 A mixture of sodium chloride (NaCl) and anhydrous sodium carbonate (Na2CO3) has a mole ratio 2 :
1. It is dissolved in water and treated with BaCl2 solution. The mass of BaCO3 precipitated is 98.5 gm
. Calculate the mass (in gm) of NaCl in the mixture.

Q.5 34 gm of a mixture containing N2 and H2 in 1 : 3 by mole is partially converted into NH3. Calculate the
vapour density of the mixture (containing remaining N2, H2 and NH3 formed) after reaction if it has
been found that the NH3 formed required 0.5 moles of H3PO4 for complete neutralization.
 MOLE CONCEPT
QUIZ-9
By: Dr. Rajan Khare

Q.1 The mass of Mg3N2 produced if 48 gm of Mg metal is reacted with 34 gm NH3 gas is
Mg  NH3 
 Mg3 N2  H 2
200 100 400 150
(A) (B) (C) (D)
3 3 3 3

Q.2 The number of carbon atoms present in a signature, if a signature written by carbon pencil weights 1.2
 103 g is
(A) 12.04  1020 (B) 6.02  1019
(C) 3.01  1019 (D) 6.02  1020

24
Q.3 The average atomic mass of a mixture containing 79 mole % of Mg and remaining 21 mole % of
25
Mg and 26Mg, is 24.31. % mole of 26Mg is
(A) 5 (B) 20 (C) 10 (D) 15

Q.4 Rearrange the following (I to IV) in the order of increasing masses.

(I) 0.5 mole of O3 (II) 0.5 gm molecule of Nitrogen
(III) 3.011  1023 molecules of O2 (IV) 11.35 L of CO2 at STP.
(A) IV < III < II < I (B) II < III < IV < I
(C) III < II < I < IV (D) I < II < III < IV

Q.5 0.078 gms of hydrocarbon occupy 22.4 ml of volume at 1 atm and 0oC. The empirical formula of the
hydrocarbon is CH. The molecular formula is
(A) C2H2 (B) C4H4 (C) C6H6 (D) C8H8
 MOLE CONCEPT
QUIZ-11
By: Dr. Rajan Khare
Q.1 1.5 gm mixture of SiO2 and Fe2O3 on very strong heating leave a residue weighing 1.46 gm. The
reaction responsible for loss of weight is
Fe2O3 (s) 
 Fe3O4 (s)  O2 ( g )
What is the percentage by mass of Fe2O3 in original sample.
(A) 80% (B) 20% (C) 40% (D) 60%
Q.2 P4 can react with O2 to form P4O6 and P4O10 according to following reactions
P4  3O2 
 P4O6
P4  5O2 
 P4O10
If each option is written in an order like (x, y, z, p) where x represents moles of P4 taken, y represents
moles of O2 taken z represents moles of P4O6 formed and p represents moles of P4O10 formed which
options are correct.
(A) 1, 4, 0.5, 0.5 (B) 1, 3, 1, 0 (C) 0.5, 2.5, 0.5, 0 (D) 2, 5, 2, 3
Q.3 The sample (s) containing same no. of ‘Na’ atom as there are ‘Na’ atoms in 5.3 gm of Na2CO3, is/are
(A) 4 gm of NaOH (B) 5.85 gm of NaCl
(C) 0.25 mole of Na2SO4 (D) 5.6 gm of Na3PO4
Q.4 For the following reactions
( NH 4 )2 SO4  2 NaOH 
40%
 Na2 SO4  2H 2O  2 NH3

NH3  HCl 
80%
 NH 4Cl
If 4 gm of NaOH is taken then
Choose correct options.
(A) Produced moles of NH4Cl (in IInd reaction) are 1.6 times of produced moles of Na2SO4 (in Ist
reaction.)
(B) Reacting moles of HCl (in IInd reaction) is 20% lesser than original (NH4)2SO4 moles
(C) Reacting moles of HCl (in IInd reaction) is lesser than reacting moles NaOH (in Ist reaction.)
(D) Produced mass of NH4Cl is 2.71 gm.
Q.5 2.525 gm of a sample of Na2CO3. NaHCO3 and Na2SO4 is gently heated till the evolution of gases
stops. If the VCO2 =123.15 ml at 300 K and 760 mm. Another same amount of same sample requires for

complete neutralization of 150 cm3 of M/10 HCl.

[Assume Na2SO4 does not decompose under given conditions.]
(a) Calculate composition of each components in terms of moles.
(b) Calculate average molecular mass original mixture.
 MOLE CONCEPT
QUIZ-12
By: Dr. Rajan Khare
Q.1 60 ml of a “x” % w/w alcohol by weight (d = 0.6 g/cm3) must be used to prepare 200 cm3 of 12%
alcohol by weight (d = 0.90 g/cm3). Then the value of “x” will be
(A) 0.9 (B) 60 (C) 80 (D) None of these
Q.2 To 500 ml of 2 M impure H2SO4 sample, NaOH solution 1 M was slowly added & the following plot
was obtained. The percentage purity of H2SO4 sample and slope of the curve respectively are:

(A) 50%,  1/2 (B) 75%,  1/2 (C) 75%, 1 (D) None of these
Q.3 A bottle of an aqueous H2O2 solution is labelled as ’28 V’ H2O2 and the density of the solution in gm
per ml is 1.25. Choose the correct option
(A) Molality of H2O2 solution is 2 ‘m’
(B) Molarity of H2O2 solution is 5M
(C) Molality of H2O2 solution is 2.15 ‘m’
(D) Molarity of H2O2 solution is 1.25 M
Q.4 A mixture of CH4 & O2 having total volume 80 ml is sparked in an eudiometry tube & contraction of
40 ml is observed after cooling. What can be composition of reacting mixture?
(A) 35 ml, 45ml
(B) 20ml, 60ml
(C) 10ml, 70ml
(D) 40ml, 40ml
Q.5 The incorrect Statement (s) regarding 2M CaCl2 aqueous solution is/are (dSolution = 1.222 gm/ml)
(A) Molality of Cl is 4m
(B) Mole fraction of CaCl2 is 0.034
(C) % w/v of CaCl2 solution is 44.4
(D) % w/w of CaCl2 solution is 18.166
 MOLE CONCEPT
QUIZ-13
By: Dr. Rajan Khare
Q.1 50 L of 0.02 M H2SO4 solution is mixed with 200 L of 600 ppm CaCO3 dilute aq. Solution. If H2CO3
obtained according to following reaction. Calculate pH of H2CO3 solution if H2CO3 dissociates
completely. [Given : log 4 = 0.5]
CaCO3 + H2SO4  CaSO4 + H2CO3
Q.2 300 ml sample of H2O2 has 5.6 volume strength. If this sample liberate 5.6 litre of O2 at 1 atm & 273
K then calculate Molarity of resultant H2O2 solution?
(Assuming no change in volume of H2O2 solution).
(A) 1/3 M (B) 2 M (C) 3 M (D) 5 M
Q.3 A solid element which show tetravalency react with just sufficient O2 and reaction show no change in
volume at constant pressure. If vapour density of gaseous product is 32 the atomic weight of solid
element will be
(A) 16 (B) 32 (C) 64 (D) 8
Q.4 Methyl benzoate is prepared by the reaction between benzoic acid and methanol, according to the
equation C6H5COOH + CH3OH  C6H5COOCH3 + H2O
Benzoic acid Methanol Methyl benzoate
In an experiment 24.4 gm of benzoic acid were reacted with 70.0 mL of CH3OH. The density of CH3OH
is 0.79 g mL1. The methyl benzoate produced had a mass of 6.8 g. What was the percentage yield of
product?
(A) 50% (B) 23% (C) 20% (D) 25%
Q.5 Ethanol can undergo decomposition to form two sets of products:

If the mole ratio of C2H4 to CH3CHO is 9 : 1 in product gases, then the energy involved in the
decomposition of 1 mole of ethanol is
(A) 57.5 unit (B) 47.5 unit (C) 70.5 unit (D) 85.5 unit
 MOLE CONCEPT
QUIZ-14
By: Dr. Rajan Khare

Q.1 If 0.5 M methanol undergo self dissociation like CH3OH  CH3O +H+ & if concentration of H+ is 2.5

 104 M then calculate % dissociation of methanol.

(A) 2.5 (B) 0.05 (C) 0.005 (D) 5

Q.2 Calculate the minimum molarity of a H2O2 solution, which can produce at least 1 gm each of I2 & KOH,

when 6 litre of H2O2 solution is added to excess KI solution.

H2O2 + 2KI  I2KOH

(A) 1/672 (B) 1/762 (C) 1/1524 (D) 1/3048

Q.3 A 500 ml solution was prepared by dissolving 28.5 gm of MgCl2 in water. If the density of MgCl2

solution is 1.2 gm/ml, calculate

Column I Column II

(A) Molarity of Cl ion (P) 9.18  103

(B) Mole fraction of Mg2+ ion (Q) 1.2

(C) Concentration in ppm of Mg2+ ion (R) 1.2  104

(D) Molality of Mg2+ ion (S) 0.52

Q.4 Which of the following contains highest mass of H-atom

(A) 10 mole CH3COOH (B) 8 mole (COOH) 3

(C) 2.0 mol C6H16O4 (D) 4 mole C2H4O2

Q.5 Mass of 1 mole of electron in amu will be (Mass of 1 electron = 9.1  1031 kg), NA = 6  1023

(A) 54.6  108 (B) 54.6  105

(C) 3.27  1020 (D) 3.27  1017

 MOLE CONCEPT
QUIZ-15
By: Dr. Rajan Khare

Q.1 Suppose two elements A & B combine to form two compounds A2B3 & AB when 12.04  1023
molecules of A2B2 weighs 300 gm and 0.01 mole of AB weigh 0.6 gm. The atomic weight of A & B
respectively.
(A) 60, 30 (B) 60, 60 (C) 90, 60 (D) 30, 30

Q.2 Match the column.

Column I Column II
(A) In 36 gm C6 gm C6H12O6 (P) Number of atoms = 4.8 NA
(B) In 78.4 gm H2SO4 (Q) Number of electron = 19.2 NA
(C) In 126.4 gm KMnO4 (R) Number of moles = 0.8
(D) In 38.4 gm O3 (S) Number of gm molecule of oxygen = 1.6

Q.3 22 gm of ideal gas occupies 11.2 L volume at 1 atm & 273 K. The gas (es) may be
(A) SO2 (B) N2O (C) NO2 (D) CO2

Q.4 Total number of ions present in aqueous solution of 1476 amu of K2SO4.(NH4)2SO4.24H2O.
(Assume complete dissociation and no further reaction)

Q.5 ‘X’ is molecular substance containing 21 atoms of carbon per molecule. The weight % of C in ‘X’ is
50.4%. What is molecular weight of X.
 MOLE CONCEPT
QUIZ-16
By: Dr. Rajan Khare

Q.1 The density of a pure liquid (X2) having molecular mass 70 is 3.5 gm/ml. If 2 ml of liquid contain 35
drops, then the number of mole atoms in 2 litre of liquid will be

Q.2 Calculate the mass % of N in ammonium phosphate (NH4)3PO4.

(A) 28.2 (B) 9.39 (C) 56.4 (D) 14.1

Q.3 Adipic acid HOOC(CH2)4COOH is used in making nylon. What is the total number of atoms present
in 1.0 gm of adipic acid?
(A) 6.6  1022 (B) 16 (C) 20 (D) 8.2  1022

Q.4 The ratio of oxygen to hydrogen atom in (NH4)3PO4.

(A) 3 : 1 (B) 1 : 1 (C) 3 : 4 (D) 1 : 3

Q.5 KClOx found to contain 33.33% of Cl. What is the value of x.

 MOLE CONCEPT
QUIZ-17
By: Dr. Rajan Khare

Q.1 What mass (in gm) of NaCl would contain the same number of total ions as present in 380 gm of MgCl2.
[Assume 100% dissociation of both the compounds]

Q.2 The Kohinoor diamond was the largest diamond ever found. How many moles of carbon atom were
present in it, if it is weigh is 3300 carat. [Given : 1 carat = 200 mg].

Q.3 24 gm pure sample of magnesium is burned in air to form magnesium oxide and magnesium nitride.
When products are treated with excess of H2O, 3.4 gm of gaseous NH3 is generated according to given
reactions. The amount of magnesium oxide (in gm) in products is
Mg + O2  MgO
Mg + N2  Mg3N2
Mg3N2 + 6H2O  3Mg (OH)2 + 2NH3

Q.4 If 200 ml of 0.1 M Na2SO4 is mixed with 100 ml of 0.2 M Na3PO4 solution. Molarity of Na+ in the final
solution, if final solution has density 1.2 gm/ml.
(A) 0.196 M (B) 0.33 M (C) 0.5 M (D) None of these

Q.5 Calculate the mass of H2O (in gm) in vapour form in a 821 litre container containing liquid water at
300 K. (Assuming volume of liquid to be negligible.)
[Given vapour pressure of water at 300 K = 22.8 mm of Hg]
 MOLE CONCEPT
QUIZ-18
By: Dr. Rajan Khare

 (x  y 
Q.1 For 109% labelled oleum sample, find  110 , where x and y are number of moles of H2SO4
 ( x  y) 
and free SO3 in original sample respectively.

Q.2 Volume occupied by one molecule of propanol [C3H7OH] is

[Given : Density of propanol is 0.1 gm/ml & NA = 6  1023]
(A) 1022 ml (B) 0.160 ml (C) 1.66 ml (D)1021 ml

Q.3 Number of oxygen atoms present in 8.21 litre container, containing O2 gas at 4 atm & 400 K are
(A) 2 (B) 1.5 NA
(C) 6.023  1023 (D) 12.04  1023

Q.4 In which of the following compound ratio of mass of hydrogen to total mass of compound is minimum.
(A) CH3COCH3 (B) C3H6O2
(C) CH3CH2CHO (D) CH3CHCHOH

Q.5 A term ‘Q’ is defined as Q = 14  mass of N2 gas produced from complete dissociation of NH3. A
container of volume 11.35 lit. contains NH3 at 1 bar & 273 K. This NH3 gas is completely dissociated
into N2 gas and H2 gas. Then calculate ‘Q’.
 MOLE CONCEPT
QUIZ-19
By: Dr. Rajan Khare

Q.1 Calculate pressure (in atm) exerted by gas at 27oC, which is produced by the complete decomposition
of 162.5 gm of FeCl3 in 0.0821 l container according to the following reaction. (Assume volume
occupied by the solid substances is negligible.)
FeCl3(s)  FeCl2 (s) + Cl2 (g)

Q.2 A term ‘P’ is defined as

P = 294  (rato of masses of Al2 (SO4)3 and H2SO4 in gm each containing 96 gm of sulphur). Calculate
P.

Q.3 If 123 gm of a triatomic gas having only one type of atoms occupies 22.4 l at 1 atm & 273 K, then
calculate the atomic weight of gas.

Q.4 44.8 l CO2 gas at 1 atm & 273 K was liquefied, the density of the liquid is 2.2 gm/ml. Calculate the
volume (in ml) of CO2 after liquefaction.

Q.5 If the mass of proton is halved & mass of neutron is doubled, then calculate the % increase in the
molecular weight of H2O, consisting only O18 and H1 atoms.
 MOLE CONCEPT
QUIZ-20
By: Dr. Rajan Khare

Q.1 For representing amount of solute in solution, various terms like molarity, molality etc. are defined.
Most commonly used term Molarity (M) of solution is defined by moles of solute present in 1 L
solution. E.g. 2M HCl solution means, 2 mol HCl is present in 1 L solution.
Using the above information calculate the mass (gm) of NaOH present in 100 ml iif 0.5 M NaOH
solution is taken?

Q.2 Calculate the amount of H2SO4 produced (in gm) when 40 ml H2O (d = 0.9 gm/ml) reacts with 50 

SO3 at 1 atm. And 300 K, according to the following reaction?

H2O + SO3  H2SO4

Q.3 Calculate volume of Cl2 gas (in ml) liberated at 1 atm and 273 K, when 2.61 gm MnO2 reacts with 2.92
gm HCl, according to the following reaction?
MnO2 + HCl  MnCl2 + Cl2 + 2H2O

Q.4 Calculate the amount of SO2 (in gm) produced when 120 gm of FeS2 reacts with excess of oxygen
according to the following reaction?
FeS2 + O2  Fe2O3 + 4SO2

Q.5 When C2H4 is burnt in air, Carbon dioxide and water are formed. If on combustion of C2H4, 2 mole of
CO2 is produced then calculate the number of drops of water produced along with this quantity of CO2,
if each drop contains 6.022  1021 water molecules.
 MOLE CONCEPT
QUIZ-21
By: Dr. Rajan Khare

Q.1 For a gaseous reaction of the type

aA + bB  cC + dD, [Given : a  b  c  d]
Select the incorrect statement(s)?
(A) ‘a’ mole of A combines with ‘b’ moles of B to produce ‘c’ moles of C and ‘d’ moles of D.
(B) ‘a’ gm of A combines with ‘b’ gm of B to produce ‘c’ gm of C and ‘d’ gm of D.
(C) If ‘x’ moles of A (where x > a) added with ‘b’ moles of B then number of moles of D is greater
than ‘d’
(D) If ‘a’ moles of A added with ‘a’ moles of B then number of moles of each C and D will be equal
to ‘a’

Q.2 The ratio of weight of oxygen in Fe2O3 and FeO for the same amount of iron is
(A) 3 : 2 (B) 1 : 2 (C) 2 : 1 (D) 3 : 1

Q.3 The sample containing same number of ‘H’ atoms as there are ‘H’ atoms in 3 moles of H2
(A) 74.5 gm of (NH4)3PO4
(B) 10 ml of CH3COOH (d = 3 gm/ml)
(C) 22.4 of NH3 at 1 atm and 273 K

(D) 3.01  1023 molecules of C6H5OH

Q.4 When 280 gm of ethylene polymerises to polyethylene according to the equation.

n (CH2 = CH2)  (CH2 – CH2)n.
The weight and mole of polyethylene formed will be
(A) 280, 10 n (B) 280/n, n (C) 28/n, 280 (D) 280, 10/n

Q.5 Titanium oxide (TiO2) is heated in stream of hydrogen to give water and new oxide TixOy. If 1.6 gm
TiO2 produces 1.44 gm TixOy . ‘x’ & ‘y’ are
(A) 2, 1 (B) 1, 2 (C) 2, 3 (D) 3, 2