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Submitted by
PRAKASH S T (822114103031)
PRAGATHEESWARAN M (822114103303)
SAKTHIVEL A (822114103039)
CIVIL ENGINEERING
RAJAMADAM
APRIL 2018
1
ANNA UNIVERSITY: CHENNAI 600 025
BONAFIDE CERTIFICATE
SIGNATURE SIGNATURE
Dr G ELANGOVAN ME., PhD., Dr G ELANGOVAN ME., PhD.,
Pattukkottai, Pattukkottai,
2
CHAPTER NO. TITLE PAGE NO
ACKNOWLEDGEMENT
ABSTRACT
LIST OF SYMBOLS
1 INTRODUCTION 9
2 LITERATURE REVIEW 10
3 METHODOLOGY 13
6 CONCLUSION 48
3
ACKNOWLEDGEMENT
First of all we thank the almighty for giving us all that we need to complete our
project. We express our sincere thanks to our beloved dean Dr.G.ELANGOVAN
M.E., Ph.D., for allowing me to do this project
We are greatly thankful to the HOD’s, Staffs and Lab technicians Civil
Engineering Department, for their valuable guidance without whom this project
would not have been a successful one.
4
ABSTRACT
The project is about the desalination technique .We know that world
contains 97 % of sea water But we are using the remaining 3% of fresh and
ground water . So in order to meet the demand in the time of scarcity we need to go
on to the next step which becomes the process of desalination by using Reverse
Osmosis . We are proposing the desalination plant for the University college of
Engineering , Pattukkottai .
We proposed the plant for better drinking for students , and all the staff
members , the various treatment process are involved in this project , this method
is very fine and quit simple than other methods .
5
LIST OF SYMBOLS
Ca Calcium
Mg Magnesium
Na Sodium
PO43- Phosphate
TDS Total dissolved solids
N2 Nitrogen
NH3 Ammonium
SO4 Sulphate
CO3 Carbonate
HCO3 Bi carbonate
CO2 Carbon dioxide
Cl2 Chloride
NO3- Nitrate
F- Fluoride
Si Silica
Fe Iron
Mn Manganese
6
Al Aluminium
O2 Oxygen
Zn Zinc
ppm parts per milligram
psi pound force per square inch
RO Reverse Osmosis
NTU Nephelometric Turbidity Units
HPP High Pressure Pump
CA Cellulose acetate
CTA Cellulose triacetate
ENM Ectro-spun nanofiber membranes
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CHAPTER 1
INTRODUCTION
Desalination can be defined as any process that removes salts from
water. Desalination processes may be used in municipal, industrial, or commercial
applications. With improvements in technology, desalination processes are
becoming cost-competitive with other methods of producing usable water for our
growing need .
The two major types of technologies that are used around the world
for desalination can be broadly classified as either thermal or membrane. Both
technologies need energy to operate and produce fresh water. Within those two
broad types, there are sub-categories (processes) using different techniques
OBJECTIVE
8
To analyse the proper method for sea water treatment
Improving the quality of the water designated for personal use: treatment
of drinking water
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CHAPTER 2
LITERATURE REVIEW
A brief review of literature on existing methods of textile effluent
treatment, namely wastewater treatment by Reverse Osmosis (RO), RO separation
of organic pollutions from wastewater, membrane filtration, RO membrane
preparation, structure and properties, RO membrane modules and module
configurations, RO membrane characterization techniques are considered and
discussed. EXISTING METHODS OF TEXTILE EFFLUENT TREATMENT In
an early study, Anderson et al (1989) reported some of the factors influencing the
separation of several different organics (including acetone, urea, phenol, 2, 4 -
dichlorophenol, nitrobenzene) by cellulose acetate membranes. Rejections varied
considerably for the different solutes, and rejections of ionizable organics were
greatly dependent on the degree of dissociation. Nonionized and hydrophobic
solutes were found to be strongly sorbed by the membranes and exhibited poor
rejection. Duvel and Helfgott (2015) also found organic separations that varied
with molecular size and branching. They postulated that organic separation was
also a function of the solute's potential to form hydrogen bonds with the
membrane. 19 Edwards and Schubert (2017) reviewed some of the early separation
10
results of herbicides and pesticides with RO membranes. They also conducted
studies with the herbicide 2, 4 - D and found that the separations were < 51%. It
was noted that solute adsorption could occur on the cellulose acetate membranes.
Fang and Chian conducted studies on the separation of several polar organic
compounds with various functional groups using cellulose acetate and several
other types of membranes. That study found that the organic rejection varied
considerably not only with solute but also with membrane type. Chian et al
reported high rejections (> 99%) for several pesticides with cellulose acetate and a
composite membrane. However, a significant adsorption of the pesticides on the
membranes was noted. Light studied dilute solutions of polynuclear aromatic
hydrocarbons (PAHs), aromatic amines, and nitrosamines and found rejections of
these compounds to be over 99% for polyamide membranes. Williams et al (1999)
developed two models namely a modified steady-state solution diffusion model
and an unsteady-state diffusion adsorption model which are able to predict flux and
permeate concentrations from a single RO experiment. Further, the development of
these models allows for the understanding of the mechanisms of organic membrane
interactions. For instance, it has been proposed that increased adsorption inherently
leads to an increase in flux drop. However, we have found, on one hand, that due
to specific interactions with membrane water transport groups, chloro and
nitrosubstituted phenols cause significant flux drops. On the other hand, benzene
had a high physical adsorption but caused negligible flux drop. The results were
further extended to nanofiltration experiments with an aromatic pollutant
containing two types of charge groups.
11
12
CHAPTER 3
METHODOLOGY
DESALINATION
Desalination is the process of removal of salts and minerals from the sea
water and making it suitable for the drinking purpose . normal water contains only
few amount of salt content in it. While the sea water contains about 10 ppm of
impurities .To remove these things desalination process is achieved
Methods of desalination;
In Desalination Process There are Ten Methods. They are the methods
Vaccum distillation
Freeze thawl
Solar evoporation
Electrodialysis reversal
Membrane desalination
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Table 1
Electric
Energy 4-6 1.5-2.5 7-12 2.3-5.5
(kwh/cu.m)
Thermal
Energy 50-110 60-110 No No
(kwh/cu.m)
Electrical
Equivalent of 9.5-19.5 5-8.5 No No
Thermal energy
(kwh/cu.m)
Total equivalent
electrical energy 13.5-25.5 6.5-11 No No
(kwh/cu.m)
As in the table we can say that power and thermal requirement of other
process is high when compared to reverse osmosis. So in such this case the
desalination plant is of reverse osmosis
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DESALINATION PLANT SET UP
The desalination plant is usually set up in the region where as the salt water is very
high , the proper set up reduces the salinity and make it suitable for drinking
purpose. The plants which forms with filter cylinder, spun, measuring systems,
chemical dosing, pressure pump, RO membrane, storage tank. The completed set
as,
1 = filter membrane
2= spun filter
3=RO membrane
4=chemical dosing
5=measuring system
6=booster pump
Fig 3.1
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WATER IMPURITIES
Table 2
16
expressed as CaCO3 steel; bicarbonate and zeolite softening;
carbonate produce demineralization
CO2 in steam, a source dealkalization by anion
of corrosion in exchange
condensate lines
Free
H2SO4 , HCI. etc., neutralization with
Mineral Corrosion
expressed as CaCO3 alkalies
Acid
hydrogen ion
pH varies according to
concentration
acidic or alkaline solids pH can be increased by
defined as:
PH in water; most natural alkalies and decreased
1 waters have a pH of 6.0- by acids
pH = log
8.0
[H+]
demineralization,
Chloride Cl - adds to solids content
reverse osmosis,
and increases corrosive
electrodialysis,
17
character of water evaporation
18
conjunction with
demineralization,
reverse osmosis,
evaporation
aeration; coagulation
discolors water on
and filtration; lime
precipitation; source of
softening; cation
Fe2+ (ferrous) deposits in water lines,
Iron exchange; contact
Fe3+ (ferric) boilers. etc.; interferes
filtration; surface active
with dyeing, tanning,
agents for iron
papermaking, etc.
retention
usually present as a
result of floc carryover
from clarifier; can cause improved clarifier and
Aluminum AI3+
deposits in cooling filter operation
systems and contribute
to complex boiler scales
19
exchange
20
Numerous chemical tests must be conducted to ensure effective control of a
water treatment program. Because of their significance in many systems, three
tests, pH, alkalinity, and silica
21
parameter BIS guideline value(maximum limited
value)
pH 6.5 – 8.5
Calcium 200 mg / L
Magnesium 100 mg / L
22
Aluminium 0.2 mg/L
Zinc 5 – 15 mg mg/L
Nitrite nil
Fluoride 1-1.5 mg /L
23
Phosphate nil
24
POPULATION FORCASTING
The population forcasting is one in which the amount is to be distributed for the
students and staffs for hostel and the college .
Distribution ;
25
CHAPTER 4
TESTING AND TREATMENT PROCESS
26
4.2 Testing the quality of the water ;
pH
Alkalinity
Total solids dissolved
Hardness
Turbidity
Chloride
Ammonium nitrogen
pH
27
industrial wastewater, and chemicals used in the water treatment process, and the
nature of the piping or hardware used to convey the water. The total dissolved
solids in the water that we have tested is found to be 1000 mg/l .
Alkanity
The alkalinity of water may be defined as its capacity to neutralize acid. For
treatment of the water we have taken the test . The alkanity of the tested water is
found to be 300 mg /l .
Hardness;
28
Turbidity;
- Phytoplankton
- Waste discharge
- Algae growth
Chloride ;
Chlorides are the inorganic compound resulting from the combination of the
chlorine gas with metal. Some common chlorides include sodium chloride (NaCl)
and magnesium chloride (MgCl2). Chlorine alone as (Cl2) highly toxic, and it is
often used a disinfectant. In combination with a metal such as sodium, it becomes
essential for life. Small amounts of chlorides are required for normal cell functions
in plant and animal life.
29
reached . but the tested water sample in which the chloride content is found to be
400mg/l .
Ammonium nitrogen ;
These are the compound rarely present in drinking water . In the sample
that we have collected there is no ammonium nitrogen present .
Iron;
Iron is the second most abundant metal in the earth's crust, of which it
accounts for about 5%. Elemental iron is rarely found in nature, as the iron ions
Fe2+ and Fe3+ readily combine with oxygen- and sulfur-containing compounds to
form oxides, hydroxides, carbonates, and sulfides. Iron is most commonly found in
nature in the form of its oxides. In the water that we have tested the iron content
found is to be 7 mg/l
Calcium;
Calcium occurs in water naturally. Seawater contains approximately 400 ppm calcium.
One of the main reasons for the abundance of calcium in water is its natural occurrence in the
earth's crust. The calcium content the water sample is found to be 218 mg/l
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Parameter Value
pH 7.6
Alkalinity 80 mg/l
Iron 7 mg/l
Turbidity 30NTU
31
4.3 Intake of water ;
Intake facilities for seawater desalination project are basically classified into the
three types, including beach well intake, subsurface water intake and open sea
water intake. Good-quality raw water can be delivered by beach well intake,
thereby it reduces investment and the operating cost of the pre-treatment
equipment, nevertheless it should be taken marine geological structure, hydrology
water quality and water quality unstable factors when operating into consideration,
and confirmed after looking into in-depth investigation. Subsurface water intake is
capable of delivering quite good water, but this kind of intake is probably less
adopted because of its large investment and complicated construction. Open sea
water intake-a kind of more popular intake method, can be used for different
seawater desalination project. In our project the intake of water for the desalination
is from the bore well. In which the dissolved solids will be low and the cost for the
investments will low on this.
32
4.4 Pretreatment process;
Pretreatment process is one in which these are characterized as the initial stage
of the treatment process , in which here the carbon filters , and various filter
process are occurred in this.
Carbon filters
Micro filters
33
Ultra filters
Nano filters.
Carbon filters ;
In this the dissolved solids removed is found to be 1000mg/l .In this dissolved
solids is filtered in the carbon filter by activated carbon . which catches the 65%
of the TDS . the outcome of the water from the carbon filters is found to be
650mg/l. The particle size of 20μ is removed. The turbidity removal of nearly
90% is occurred. The bacteria then get arrested in the filter.
Micro filters;
34
Ultra filters;
Nano filters;
The total amount of solids removed through all these four process is found
to be 91%. Nearly 910mg/l of solids are removed.
35
4.5 Spun filtering process;
36
Fig 4.1
4.5 Chemical dosing
A dosing pump is a small, positive displacement pump. It is designed
to pump a very precise flow rate of a chemical or substance into either a water,
steam or gas flow. A dosing pump will deliver this precise flow rate of chemical or
other product by a number of different methods but it generally involves drawing a
measured amount into a chamber and then injecting this volume of chemical into
the pipe or tank being dosed. Dosing pumps are used in a variety of applications
from agriculture, industry, manufacturing to medicine.
A dosing pump is generally quite small and is powered by either a
small electric motor or air actuator. They are controlled either by an external
control system or more commonly an internal pump controller that can alter the
flow rate, the on/off function
37
Fig 4.2
RO units run well on typical city water pressure of 60 psi, but they run
even better with a small pump to boost the pressure to 80 psi or higher. But how in
choosing the RO pressure pump the total dissolved solids in the water is taken in
38
account. It is found to be 1000 ppm , And the pressure of water is estimated to be
70 psi.
Fig 4.3
Principle;
In the normal osmosis process, the solvent naturally moves from an area of
low solute concentration (high water potential), through a membrane, to an area of
high solute concentration (low water potential). The driving force for the
movement of the solvent is the reduction in the free energy of the system when the
difference in solvent concentration on either side of a membrane is reduced,
generating osmotic pressure due to the solvent moving into the more concentrated
solution. Applying an external pressure to reverse the natural flow of pure solvent.
Fig 4.4
40
Reverse osmosis membrane
Hollow fibre membranes have a greater surface area and hence capacity but are
more easily blocked than spiral wound membranes.
RO membranes are rated for their ability to reject compounds from contaminated
water. A rejection rate (% rejection) is calculated for each specific ion or
contaminant as well as for reduction of total dissolved solids (TDS).
TFC membranes have superior strength and durability as well as higher rejection
rates than CA/CTA membranes. They also are more resistant to microbial attack,
high pH and high TDS.
The membrane sizes are of various sizes they are various sizes , they are of
Fig 4.5
41
Reverse osmosis process;
42
Fig 4.6
This is made to disinfect the raw water from any infections.By the pressure
Sand filters to remove Turbidity and Suspended solids .To remove the remaining
Chlorine after the pressure sand filter .It is very important to prevent Calcium
Sulfate from scaling It is very important to prevent calcium carbonate from scaling
by Sulfuric acid 98% . TDS rejection rates (>95%) .
After the Reverse osmosis process the various percentage of minerals
and salts are tabulated.
43
4.8 Storage of treated water;
Fig 4.7
44
4.9 Distribution of water;
45
CHAPTER 5
ESTIMATION AND RESULT
ESTIMATION
Pretreatment process cost with two filter cylinder 26865 ×2 =Rs 53730
Total Rs 126900
46
RESULT
Parameter Value
pH 7
alkalinity 80 mg/l
Hardness 59 mg/l
Calcium 50 mg/l
Chloride 60 mg/l
Turbidity 10 NTU
47
CHAPTER 6
CONCLUSION
48
REFERENCES
1. T. Pankratz, The 19th IDA Worldwide Desalting Plant Inventory, Global Water
Intelligence, Houston, TX, 2006.
49
8 . C. Gabelich, M. Williams, A. Rahardianto, J. Franklin, Y. Cohen, High-
recovery reverse osmosis using intermediate chemical demineralization, J. Membr.
Sci. 301 (2007) 131-141.
15. T.A. Cath, V.D. Adams, A.E. Childress, Experimental study of desalination
using direct contact membrane distillation: a new approach to flux enhancement, J.
Member.
17. T.Y. Cath, V.D. Adams, A.E. Childress, Membrane contactor processes for
wastewater reclamation in space: II. Combined direct osmosis, osmotic distillation,
and memebrane distillation for treatment of metabolic wastewater, J. Membr. Sci.
257 (2005) 111-119.
50
18. T.Y. Cath, S. Gormly, E.G. Beaudry, M.T. Flynn, V.D. Adams, A.E. Childress,
Membrane contactor processes for wastewater reclamation in space: part I. Direct
osmotic concentration as pretreatment for reverse osmosis, J. Membr. Sci. 257
(2005) 85-98.
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