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The Mechanical Properties of Concrete Incorporating Silica Fume as Partial


Replacement of Cement

Article · September 2015

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International Journal of Emerging Technology and Advanced Engineering
Website: www.ijetae.com (ISSN 2250-2459, ISO 9001:2008 Certified Journal, Volume 5, Issue 9, September 2015)

The Mechanical Properties of Concrete Incorporating Silica


Fume as Partial Replacement of Cement
Hanumesh B M1, B K Varun2, Harish B A3
1
Post graduate student, University B D T College of Engineering, Davangere, Karnataka, India
2,3
Assistant Professor, G M Institute of Technology, Davangere, Karnataka, India
Abstract-- Concrete is the most important engineering Silica fume, also referred to as micro silica or condensed
material and the addition of some other materials may change silica fume, is used as an artificial pozzlanic admixture. It
the properties of concrete. With increase in trend towards the is the product resulting from reduction of high purity quartz
wider use of concrete for prestressed concrete and high rise with coal in an electric arc furnace in the manufacture of
buildings there is a growing demand of concrete with higher
silicon or ferrosilicon alloy. Silica fume rises as an
compressive strength. Mineral additions which are also
known as mineral admixtures have been used with cements oxidized vapour. It cools, condenses and is collected in
for many years. Silica fume particles are 100 times smaller cloth bags. It is further processed to remove impurities and
than the average cement particle. Its handling and disposal is to control particle size. Condensed silica fume is essentially
a point of concern because of the environment concerns. Silica silicon dioxide (more than 90%) in noncrystalline form.
fume is usually categorized as a supplementary cementitious Since it is airborne material like fly ash, it has spherical
material. These materials exhibit pozzolanic properties, shape. It is extremely fine with particle size less than 1
cementitious properties and a combination of both properties. micron and with an average diameter of about 0.1 micron,
Due to these properties, it can affect the concrete behavior in about 100 times smaller than average cement particles.
many ways. In the present work, an attempt has been made to
Silica fume has specific surface area of about 20000m2/kg ,
use silica fume as a supplementary material for cement and to
evaluate the limit of replacement of cement for M20 grade as against 230 to 300m2/kg.
concrete. The main aim of this work is to study the
mechanical properties of M20 grade control concrete and II. OBJECTIVES OF THE STUDY
silica fume concrete with different percentages (5, 10, 15 and The following are the main objective of the study
20%) of silica fume as a partial replacement of cement.
a) To evaluate the compressive strength of control concrete
Keywords-- Silica Fume, Pozzolanic, Mix-Design, of grade M20 and silica fume concrete produced by
Compressive strength, Split Tensile Strength. replacing cement in different percentage.
b) To evaluate the split tensile strength of control concrete
I. INTRODUCTION of grade M20 and silica fume concrete produced by
Concrete is one of the most common material used in the replacing cement in different percentage.
construction industry. In the past few years, many research
and modifications has been done to produce concrete which III. LITERATURE REVIEW
has the desired characteristics. There is always a search for Many researchers have been studied the effect of
concrete with higher strength and durability. Particularly replacement of cement by silica fume on strength and
mineral admixtures are indispensable in production of high durability aspects of concrete.
strength concrete for practical application. The use of K.C.Biswal and Suresh Chandra Sadangi their
mineral admixtures as a pozzolana has increased worldwide journal entitled “Effect of superplasticizer and silica
attention over the recent years because when properly used fume on properties of concrete” (March 2011).
it as certain percent, it can enhance various properties of Nowadays high strength and high performance concrete are
concrete both in the fresh as well as in hardened states like widely used in many civil engineering constructions. To
cohesiveness, strength, permeability and durability. The produce them it is required to reduce the water/powder
best mineral admixtures in optimum proportions mixed ratio and increase the binder content. Superplasticizers are
with OPC improves many qualities of concrete such as commonly used to achieve the workability. Silica fume is
lowers the heat of hydration, increases the watertightness, one of the popular pozzolanas used in concrete to get
reduces alkali-aggregate reaction, improves workability improved properties.
and resistance to attack by sulphate soils, sea water.

270
International Journal of Emerging Technology and Advanced Engineering
Website: www.ijetae.com (ISSN 2250-2459, ISO 9001:2008 Certified Journal, Volume 5, Issue 9, September 2015)
The use of silica fume in conjuction with The mechanical properties of mortar were measured in
superplastisizers has become the backbone of high strength terms of compressive strength at 7 and 28 days and it was
and high performance concrete. An experimental program observed that the strength developments at 7, and 28 days
has been carried out to study the effect of superplasticizer and the highest development rate of compressive strength
alone and in conjuction with silica fume on some of the was observed at 15% replacement ratio for each the marble
properties of fresh and harden of concrete. powder and silica fume separately. Results showed that the
compressive strength increased by 31.4%, 48.3% at 7, and
28 days respectively at 15% replacement ratio of silica
fume with cement content and in case of replacement
marble powder with cement content the compressive
strength increased by 22.7%, 27.8% at 7, and 28 days at
15% replacement ratio of marble powder with cement
content respectively.
Due to analysis of the tests results, the maximum value
for compressive strength was obtained with the use of 15%
silica fume as a partial replacement and the percentage of
the increasing 48.3%. The compressive strength of mortar
is decreased when Silica fumes contents used as a partial
replacement with percentage higher than 15%. The
compressive strength of mortar increased when Silica
fumes contents used as an addition with percentage 5%,
Figure 1: Variation of compressive strength with varying percentage
of SF
10%, 15% and is almost comparable at percentage higher
than 15 %. Using marble powder up to 15% as an additive
The following conclusions may be made from the materials enhancement the compressive strength up to
present investigation of the replacement of cement silica 31.5%. Marble powder can be used as alternative materials
fume and use of superplasticizer on fresh and harden for silica fume in mortar.
concrete properties. Faseyemi Victor Ajileye in their papers entitled
 The water cement ratio reduces by 23% in concrete by “Investigations on Microsilica (Silica Fume) As Partial
using superplasticizer ( 1% by weight of cement) for a Cement Replacement in Concrete” (January 2012).
constant range of slump 80 to 85mm. Studies have been carried out to investigate the possibility
 The compressive strength of concrete is increased by of utilizing abroad range of materials as partial replacement
use of silica fume upto 20% replacement of cement. materials for cement in the production of concrete. This
 The flexural strength of concrete is increased by use study investigated the strength properties of Silica fume
of silica fume upto 15% replacement of cement. concrete.
The specific gravity and chemical composition of silica
Hassan A. Mohamadienin their journal entitled “The
fume and cement were replaced with micro silica from 0 to
Effect of marble powder and silica fume as partial
25% in steps of 5% by weight, mix proportioning was
replacement for cement on mortar” (2012). The possibility
based on 1:2:4 mix ratio. Cubes (150 x 150 x 150 mm)
of using marble powder and silica fume (S.F) separately as
were produced and cured in a curing tank for 3, 7, 14 and
partial replacement of cement on mortar were studied and
28 days. The cubes were subjected to compressive strength
evaluated based upon the percentage of the partial cement
tests after density determination at 3,7,14 and 28 days
replacement with both marble powder and silica fume
respectively. The chemical composition and physical
separately. Four types of mortar mixture with same
composition of micro silica and cement were determined.
workability, cement to sand ratio of 1:3 and water to
Ordinary Portland cement was replaced with silica fume.
cementitious materials ratio of 0.4 were prepared marble
The total amount of Tricalcium aluminate in the cement
powder and silica fume used in mixes separately, once as a
was 7.7% and this was above the requirement. (Specified
partial replacement of cement content and another as an
by BS12/EN196:1996),others chemical compositions for
addition to the mix proportion. Replacement and addition
silica fume such as SiO2, moisture content, loss of ignition,
ratio of both marble powder and silica fume with cement
carbon, > 45 micron, bulk density.
content separately at 0%, 5%, 10%, 15%, 20%, 30% and 50
Also % chemical composition and physical properties
% by weight were investigated.
for SiO2, Al2O3, Fe2O3,CaO, MgO, SO3, Alkalis ( Na2O
271
International Journal of Emerging Technology and Advanced Engineering
Website: www.ijetae.com (ISSN 2250-2459, ISO 9001:2008 Certified Journal, Volume 5, Issue 9, September 2015)
+ 0.658K2O), loss of ignition (Lo1), insoluble residue (IR), Table. 1:
Tricalcium, silicate, Dicalcium silicate, CaO / SiO2, Physical properties of cement
chloride, fineness (Blaine air permeability test) in Cm2/g, Experimental
soundness (mm) were in compliance with BS Standard. Particulars As per standard
result
The density of the concrete decreased with increased in Soundness
percentage of micro silica replacement up to 10%. Increase 1.00 mm 10 mm
(Le chatlier mould)
in the level of micro silica fume replacement between 15% Setting time (minutes)
to 25% led to a reduction in the compressive strength of Initial set 61min 30min (minimum)
hardened concrete. The test was carried out conforming to 600min
BS EN: 12390 – 3: 2009 to obtain compressive strength of Final set 240min
(maximum)
C30 grade of concrete. The compressive strength of high Comp.strength
strength concrete with OPC and silica fume concrete at the (MPa)
age of 3, 7, 14 and 28 days. 3 days 20.79MPa 16MPa (minimum)
7 days 36.22MPa 22MPa (minimum)
28 days 45.93MPa 43MPa (minimum)
Temperature during
27.810C 270C±20C
testing
Fine Aggregate
The sand used for this project was locally procured and
conformed to grading zone ІІІ as per IS: 383-1970. The
specific gravity of fine aggregate was found to be 2.89.
and Fineness modulus 2.3. Water absorption was found to
be 1.2%. And free moisture content was 0.36%.
Table 2:
Sieve analysis of fine aggregate
Figure 2: Relationship between compressive strength with varying
percentage of micro silica Cumulative
Sieve Weight Cumulative Cumulative
Weight
Cement replacement upto 10% with silica fume leads to size retained percentage percentage
retained,
(mm) (gm) retained passing
increase in compressive strength, for C30 grade of (gm)
concrete. From 15%, there is decrease in compressive 4.75 3 3 0.3 99.7
strength for 3,7,14 and 28 days curing period. It was 2.36 18 21 2.1 97.9
observed that the compressive strength of C30 grade of 1.18 172 193 19.3 80.7
concrete is increased from 16.15% to 29.24% and 0.60 151 344 34.4 65.6
decreased from 23.98% to 20.22%. the maximum 0.30 450 794 79.4 20.6
replacement level of silica fume is 10% for C30 grade of
concrete. 0.15 165 959 95.9 4.1
Pan 41 1000 100 0
IV. MATERIALS AND METHODOLOGY The fine aggregate belongs to zone III
Cement (as per IS: 383-1970)
In this present work Ultratech cement of 43garde F.M. = 231.4/100 = 2.314
ordinary Portland cement (OPC) was used for casting cubes Coarse Aggregate
and cylinder for all concrete mixes. The cement was of
Locally available coarse aggregates having the
uniform colour i.e. grey with a light greenish shade and
maximum size of 20mm were used in the present work.
was free from any hard lumps. The various tests conducted
The specific gravity of coarse aggregate was found to be
on cement are initial and final setting time, specific gravity,
2.82. Water absorption was found to be 0.3%. And free
fineness and compressive strength.
moisture content was 0.0%.
Testing of cement was done as per IS: 8112-1989. The
specific and composition limits of Portland cement are
reported in Table 1.
272
International Journal of Emerging Technology and Advanced Engineering
Website: www.ijetae.com (ISSN 2250-2459, ISO 9001:2008 Certified Journal, Volume 5, Issue 9, September 2015)
Silica Fume
Silica fume from Sai Dhurga Enterprises, Bangalore,
Karnataka.
Water
Potable tap water was used for the preparation of
specimens and for curing specimens.
Mix Design
The proportioning of the ingredients of concrete is an
important phase of concrete technology as it ensures
quality and economy. In pursuit of the goal of obtaining
concrete with desired performance characteristics the
selection of component materials is the first step, the next
step is a process called mix design by which one arrives at
the right combination of the ingredients. The mix design
procedure adopted in the present work to obtain M20 grade Figure 3: Testing of cubes
concrete is in accordance with IS 10262 – 2009. Table 5:
Overall results of compressive strength
Table 3:
Mix proportions
Compressive Strength (N/mm2)
Fine Coarse
W/C Water Cement
aggregate aggregate Mix
ratio ( kg/m3) (kg/m3)
(kg/m3) (kg/m3) designation
0.52 197 378.85 718.48 1224.97 7 Days 28 Days 56 Days 90 Days
Concrete mix designation:
Table 4: M0
Concrete Mix Designation 18.96 27.70 39.84 40.88
Mix designation Description
M0 Control concrete of grade M20
M1 5% Silica fume + 95% Cement M1
19.03 28.14 39.84 41.03
M2 10% Silica fume + 90% Cement
M3 15% Silica fume + 85% Cement
M4 20% Silica fume + 80% Cement
M2
19.77 29.18 42.21 43.77
V. EXPERIMENTAL RESULTS
Compressive strength test results:
M3
For each concrete mix, the compressive strength is
15.92 23.25 29.92 32.44
determined on three 150×150×150mm cubes at 7, 28, 56
and 90 days of curing.
The table below gives the overall result of compressive
strength of silica fume concrete produced with different M4
14.66 21.03 24.29 24.44
percentages of silica fume. The variation of compressive
strength in the form of graph as shown in fig 4.

273
International Journal of Emerging Technology and Advanced Engineering
Website: www.ijetae.com (ISSN 2250-2459, ISO 9001:2008 Certified Journal, Volume 5, Issue 9, September 2015)
Table 6:
Overall results of split tensile strength

50 Split tensile Strength (N/mm2)


compressive strength in N/mm2

45 Mix
designation
40
7 Days 28 Days 56 Days 90 Days
35 7 days
30 28 days
25 M0
1.29 2.54 2.75 2.96
56 days
20
90 days
15
M1
10 1.41 2.68 2.82 3.10

5
0 M2
1.69 3.25 3.32 3.55
0 5 10 15 20
SF in percentage
Figure 4: Overall results of compressive strength M3
1.27 2.47 2.44 2.80
Split Tensile Strength Test Result
Test has been conducted after 7, 28, 56 and 90 days of
curing. Split tensile is conducted on 150mm diameter and M4
1.10 2.26 2.28 2.49
300mm length cylinders as per IS 5816 – 1999.
The table 6 gives the overall result of split tensile
strength of silica fume concrete produced with different
percentages of silica fume. 4
Split tensile strength in N/mm2

3.5
3
2.5
2 7 days

1.5 28 days
56 days
1
90 days
0.5
0
0 5 10 15 20
SF in percentage

Figure 6: Overall results of split tensile strength


Figure 5: Testing of cylinders

274
International Journal of Emerging Technology and Advanced Engineering
Website: www.ijetae.com (ISSN 2250-2459, ISO 9001:2008 Certified Journal, Volume 5, Issue 9, September 2015)
VI. OBSERVATIONS AND DISCUSSIOS 2. The split tensile strength of concrete is increased by
In the present work the effect of silica fume as partial use of silica fume up to 10% replacement of cement.
replacement of cement on the compressive strength and From 10% there is a decrease in split tensile strength.
split tensile strength of concrete is investigated and the 3. The compressive strength mainly depends on the
following observations were made from the experiment percentage of silica fume because of its high
conducted. pozzolanic nature to form more densely packed C-S-
At 7, 28, 56 and 90days control concrete achieved a H gel.
compressive strength of 18.96, 27.70, 39.84 and 4. The split tensile strength increases mainly due to
40.88N/mm2, where as mix M2 achieved a compressive improvement in packing, i.e., action of it as a filler
strength of 19.77, 29.18, 42.21 and 43.77N/mm2. There is a material.
significant improvement in the strength of concrete because 5. The optimum percentage of replacement of cement by
of the high pozzolanic nature of silica fume to form more silica fume is 10% for M20 grade of concrete.
densely packed C-S-H gel and the void filling ability. It can
be observed that compressive strength of silica fume REFERENCES
replacement from control concrete M2 mix (10% [1] Aditya Dhagat, Manav Mittal (august 2013) “Effect of Microsilica
replacement level of silica fume) increases by 4.27%, and Fly ash on the Strength of Concrete”.
5.34%, 5.94% and 7.06% for 7, 28, 56 and 90days [2] B. Damodhara Reddy, S. Aruna Jyothy, I.V.Ramana Reddy
compared to control concrete. Beyond 10% replacement (February 2013) “Infuence of Microsilica on the Properties of
there is a decrease in compressive for 7, 28, 56 and 90days. Ordinary Portland Cement and Portland Slag Cement with and
without Super plasticizers”.
The maximum replacement level of silica fume is 10% for
M20 grade concrete. [3] Debabrata D.Dutta (October 2013) “Influence of Silica Fume on
Normal Concrete”.
The split tensile strength of the control concrete
[4] Dilip Kumar Singha Roy, AmitavaSil (August 2012) “Effect of
increases with the increase in percentage of silica fume at Partial Replacement of Cement by Silica Fume on Hardened
7, 28, 56 and 90days. Control concrete achieved split Concrete’’.
tensile strength 1.29, 2.54, 2.75 and 2.96N/mm2, where as [5] Faseyemi Victor Ajileye (January 2012) “Investigations on
M2 mix achieved a split tensile strength of 1.69, 3.25, 3.32 Microsilica (Silica Fume) As Partial Cement Replacement in
and 3.55N/mm2. As the percentage of silica fume is Concrete”.
increased, there is an improvement in packing, i.e., action [6] Gambhir M L, Reprint 2010, “Concrete Technology”, TataMcGraw
Hill publishing company Ltd., NewDelhi.
of it as a filler material resulting in improvement of the
[7] Hassan A. Mohamadienin (2012) “The Effect of marble powder and
interfacial bond between the aggregate-cement matrix. As a silica fume as partial replacement for cement on mortar”.
result sharp increase in tensile strength is observed. It can [8] IS 10262: 2009 (Specifications for concrete mix design).
be observed that the split tensile strength of M2 mix [9] IS 456: 2000 (Plain and reinforced concrete - code of practice).
increases by 31.00%, 27.95%, 20.72% and 19.93% for 7, [10] IS 2386 (part 3): 1963 (Methods of test for aggregates for concrete).
28, 56 and 90days. Beyond 10% replacement there is a [11] IS 383: 1970 (Specification for coarse and fine aggregate).
decrease in split tensile strength for 7, 28, 56 and 90days [12] IS 516: 1959 (Specifications for compressive strength).
compared to control concrete. [13] IS 5816: 1999 (Specifications for split tensile strength).
[14] IS 8112: 1989 (Specifications for 43 grade ordinary Portland
VII. CONCLUSIONS cement).
Based on the limited experimental investigation [15] K.C.Biswal and Suresh Chandra Sadangi (March 2011) “Effect of
concerning compressive strength and split tensile strength superplasticizer and silica fume on properties of concrete”.
of concrete with silica fume as a partial replacement of [16] M.S Shetty,Reprint 2009, “Concrete Technology”, S.Chand &
company Ltd., New Delhi.
cement, the following conclusion can be drawn.
[17] Sai Dhurga Enterprises, Imports & Exporters, Bangalore.
1. The compressive strength of concrete is increased by [18] T.Jeevetha, Dr.S Krishnamurthy and G.S.Rampradheep (April 2014)
the use of silica fume up to 10% replacement of “Study on Strength Properties of Self-Compacting Concrete with
cement. From 10% there is a decrease in compressive Micro Silica”.
strength.

275

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