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Construction and Building Materials 98 (2015) 649–655

Contents lists available at ScienceDirect

Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

Comparison of the properties between high-volume fly ash concrete and


high-volume steel slag concrete under temperature matching curing
condition
Shi Mengxiao, Wang Qiang ⇑, Zhou Zhikai
Department of Civil Engineering, Tsinghua University, Beijing 100084, China

h i g h l i g h t s

 Steel slag reduces more hydration temperature rise than fly ash.
 Temperature match curing does not promote the early strength of HVSS concrete so much.
 The effect of temperature match curing on the permeability of HVSS concrete is small.

a r t i c l e i n f o a b s t r a c t

Article history: Massive concrete structures tend to have high cracking risk due to early temperature rise. High-volume
Received 10 April 2015 mineral admixture concrete, which has low hydration heat, is suitable for massive concrete structures. In
Received in revised form 15 August 2015 this paper, the properties of high-volume fly ash (HVFA) concrete and high-volume steel slag (HVSS) con-
Accepted 26 August 2015
crete were compared under two different curing conditions (standard curing condition and temperature
match curing condition). The results show that the promoting effect of temperature match curing on the
early strength of HVFA concrete is more obvious than that on HVSS concrete. Temperature match curing
Keywords:
has negative effect on the late strength and elastic modulus of HVSS concrete. The promotion of temper-
Massive concrete
Fly ash
ature match curing to the elastic modulus development is not so obvious as that to the strength devel-
Steel slag opment. Temperature match curing can significantly decrease the chloride permeability of HVFA
Strength concrete, but its influence on the chloride permeability of HVSS concrete is inconspicuous. Though the
Permeability adiabatic temperature rise of HVSS concrete is lower than that of HVFA concrete, which is beneficial to
Temperature its application to the massive concrete structures, its strength especially the splitting tensile strength
and resistance to chloride ion penetration need to be improved.
Ó 2015 Elsevier Ltd. All rights reserved.

1. Introduction Massive concrete structures tend to have high internal temperature


rise due to cement hydration and slow heat dissipation at early
With the rapid development of economy and urbanization, ages [2–4]. In the cooling process, large tensile stresses might be
more and more high-rise buildings have been built or are under generated in massive concrete structures, which may lead to the
construction in China, such as China World Trade Center Tower cracking of concrete. The cracks have obvious negative effects on
(330 m), Tianjin World Financial Center (336.9 m) and PingAn the durability and even the safety of concrete structure.
International Financial Center (660 m). The foundation slabs In order to decrease the temperature rise and avoid the cracking
of these high-rise buildings, usually having large volume and of concrete, some approaches are adopted in the construction of
thickness, are typical massive concrete structures. massive concrete structures, such as embedding internal pipes in
The ACI Committee 116 [1] defines massive concrete as ‘any concrete with cooling fluids (usually air [4–7] or water [8–10]),
volume of concrete with dimensions large enough to require the precooling the materials before mixing operations [11,12] and so
measures be taken to cope with generation of heat of hydration from on. But these construction technologies are complex and usually
the cement and attendant volume change to minimize cracking’. extend the construction time. An efficient method to control the
temperature rise of massive concrete structures is replacing a large
⇑ Corresponding author. part of cement by mineral admixtures whose hydration heat is
E-mail address: w-qiang@tsinghua.edu.cn (W. Qiang).
much smaller than that of cement [13,14].

http://dx.doi.org/10.1016/j.conbuildmat.2015.08.134
0950-0618/Ó 2015 Elsevier Ltd. All rights reserved.
650 S. Mengxiao et al. / Construction and Building Materials 98 (2015) 649–655

Fly ash is a by-product of coal-fired power plants, belonging to but also make a contribution to the sustainable development of
pozzolanic materials. Different from cement, the main chemical environment.
components of fly ash are Al2O3, SiO2 and Fe2O3. The mineral In this paper, two different temperature curing conditions
constituents of fly ash include a major vitreous phase and some (standard curing condition and temperature match curing condi-
minor crystalline phases (quartz, mullite, hematite and magnetite) tion) were set. The aim is to compare the properties between HVFA
[15,16]. During the hydration of cement-fly ash composite binder, concrete and high-volume steel slag (HVSS) concrete under differ-
fly ash can react with Ca(OH)2 and produce calcium silicate hydrate ent temperature curing conditions and investigate the feasibility of
(C-S-H) gel [17,18], namely pozzolanic reaction. But the pozzolanic using HVSS concrete in massive concrete structures.
reaction of fly ash is quite slow at early ages, so it mainly behaves
as a microaggregate to fill the pore structure of concrete, making a
2. Experimental
physical effect [19]. At late ages, fly ash begins to make greater
chemical effects and improve the properties of concrete. Hanehara 2.1. Materials
et al. [20] reported that the pozzolanic reaction rate of fly ash is
much lower than cement hydration rate and it mainly depends The materials used in this study were Ordinary Portland cement with the
strength grade of 42.5 complying with the Chinese National Standard GB 175-
on the curing temperature. Wang et al. [21] also found that elevat-
2007, low-calcium fly ash complying with the Chinese National Standard GB/T
ing the curing temperature can effectively promote the pozzolanic 1596-2005, ground basic oxygen furnace steel slag complying with the Chinese
reaction of fly ash at early ages. National Standard GB/T 20491-2006, crushed limestone of 5 to 25 mm and natural
Nowadays fly ash is widely used in the concrete industry as a river sand smaller than 5 mm. The specific surface areas of cement, fly ash and steel
slag are 376 m2/kg, 358 m2/kg and 461 m2/kg, respectively. Besides, polycarboxylic
mineral admixture. A lot of studies are focused on the properties
superplasticizer was used to adjust the fluidity of concrete. The chemical composi-
and development of concretes containing high-volume fly ash tions of the cement, fly ash, and steel slag were shown in Table 1.
[22–25]. Considering that using fly ash to replace part of cement
can substantially decrease the hydration temperature rise of con-
2.2. Mix proportions
crete and reduce the cracking risk of concrete [2,13], high-
volume fly ash (HVFA) concrete is increasingly adopted in massive As shown in Table 2, two mix proportions were prepared with the same amount
concrete structures. Through a laboratory investigation Atisß [26] of binder (400 kg/m3), water-to-binder ratio (0.42) and mineral admixture substitu-
found that HVFA concrete could be used for road pavements and tion rate (45% by mass). One mix proportion was for the HVFA concrete (denoted by
large industrial floors due to its high late strength and low shrink- ‘F’), and the other was for the HVSS concrete (denoted by ‘S’).

age properties. Wang et al. [27] designed a HVFA concrete for a


foundation slab of a 597-meter building, and the results of mock- 2.3. Curing conditions and test methods
up experiment and finite-element calculation showed that the
The concrete specimens were cast with appropriate compaction and demoulded
cracking risk of concrete was very low and the strength of concrete
after about 36 h of initial curing. In order to study the properties of concrete in
could meet the design requirement. actual structures, two different curing conditions were set:
Steel slag is a by-product from the industrial production of
steel. The chemical components of steel slag, usually varying with (i) Standard curing condition (SC): Specimens were cured in a room at
20 ± 1 °C and more than 95% relative humidity.
the raw materials and producing process, mainly include CaO, SiO2,
(ii) Temperature match curing condition (TMC): Specimens were cured in a
Al2O3, Fe2O3, FeO, MgO, and P2O5 [28,29]. And the common mineral curing box whose temperature was adjusted according to the adiabatic
constituents in steel slag are olivine, merwinite, C3S, C2S, C4AF, C2F, temperature rise curve of concrete.
RO phase and free-CaO [29–31], which are similar to those in
cement. The existence of C3S, C2S, C4AF and C2F endows steel slag Thus, there are four groups of concrete. Group F-SC represents HVFA concrete
certain cementitious properties, making it a potential mineral under standard curing condition. Group S-SC represents HVSS concrete under stan-
dard curing condition. Group F-TMC represents HVFA concrete under temperature
admixture for concrete. However, due to the low cooling rate of
match curing condition. Group S-TMC represents HVSS concrete under temperature
steel slag, the activity of its cementitious minerals is much lower match curing condition.
than that in Portland cement [30,32]. Wang and Yan [32] carried A specific adiabatic temperature measuring instrument with accuracy of ±0.1 °C
out a research on the hydration of cement and steel slag and was used to measure the adiabatic temperature rise curves of concrete. The slumps
of the steel slag concrete and fly ash concrete were 17.6 and 16.8 cm, respectively.
revealed that the hydration rate of steel slag was much lower than
Specimens of 100  100  100 mm were prepared for the compressive strength and
that of cement, although their hydration processes were quite splitting tensile strength tests. Specimens of 100  100  300 mm were prepared
similar with each other. for the elastic modulus test. And specimens of 100  100  50 mm were cut for
Kourounis et al. [29] found that adding steel slag would slow chloride ion penetration test. The compressive strength, splitting tensile strength
down the hydration of the blended cements and decrease the and elastic modulus of concrete were tested at the ages of 2, 3, 5, 7, 14, 28, 56
and 90 days according to the Chinese National Standard GB/T 50081-2011. And
strength, though the blended cements containing steel slag exhib-
the permeability of concrete was measured at the ages of 28, 56 and 90 days
ited satisfactory properties. Wang et al. [33] indicated that using according to ASTM C1202 ‘‘Standard Test Method for Electrical Indication of Con-
steel slag as a mineral admixture in concrete had negative effects crete’s Ability to Resist Chloride Ion Penetration”.
on both the strength and durability of concrete, and increasing Steel slag paste was prepared by mixing sodium hydroxide solution (initial
the steel slag replacement rate would make the negative effects pH = 13.5) and steel slag at the solution/steel slag ratio of 0.42 (mass ratio). One
group was cured under the temperature of 65 °C for the initial 7 days and 20 °C
stronger. Therefore, the utilization rate of steel slag in the cement for the remaining ages (denoted by ‘S-65 °C’), and the other was cured under the
and concrete industries is quite low in China at present. Most part temperature of 20 °C throughout the ages (denoted by ‘S-20 °C’). Non-evaporable
of the steel slag is discharged as waste, which leads to a serious water (wn) content of the steel slag paste was tested at the ages of 3 and 90 days
environment problem. to evaluate its degree of hydration.
But on the other hand, it has been proved that steel slag
could prolong the dormant period of cement-steel slag composite
Table 1
binder [34]. What’s more, steel slag has an excellent effect on Chemical compositions of the cement, fly ash, and steel slag: %.
decreasing the early hydration heat of the binder [31], which is
CaO SiO2 Al2O3 Fe2O3 MgO SO3 MnO
even better than that of fly ash. These properties of steel slag highly
match the temperature requirements of massive concrete Cement 54.86 21.10 6.33 4.22 2.60 2.66 0
Fly ash 2.86 53.33 27.65 6.04 1.35 0.45 0
structures. If steel slag can be applied to massive concrete as a
Steel slag 45.38 14.38 7.19 20.34 3.46 0.34 5.13
mineral admixture, it will not only make great economy benefit
S. Mengxiao et al. / Construction and Building Materials 98 (2015) 649–655 651

Table 2
Mix proportion of concretes: kg/m3.

Cement Fly ash Steel slag Fine aggregate Coarse aggregate Water Superplasticizer
F 220 180 0 852.5 1027 168 8.4
S 220 0 180 852.5 1027 168 8.4

3. Results and discussion

3.1. Adiabatic temperature rise

Fig. 1 shows the adiabatic temperature rise curves of HVFA


concrete and HVSS concrete. It is obvious that the two curves are
similar and the growth trends of temperature are nearly the same.
However, the adiabatic temperature rise of HVSS concrete is
relatively low compared with that of HVFA concrete, which means
the effect of steel slag on reducing the hydration temperature rise
is a bit greater than that of fly ash. According to the test data, the
adiabatic temperature rise values of HVFA concrete and HVSS
concrete within 9 days are 41.85 °C and 39.46 °C, respectively.

Fig. 2. Compressive strength of concrete under temperature match curing


3.2. Compressive strength condition.

Fig. 2 presents the compressive strengths of different concretes


under temperature match curing condition. It can be easily
observed that the early compressive strength development of
HVFA concrete is faster than that of HVSS concrete under temper-
ature match curing condition. For example, the compressive
strength of HVFA concrete at 7 days is already higher than that of
HVSS concrete at 56 days. At late ages, although the compressive
strength of HVSS concrete is much lower than that of HVFA
concrete, the compressive strength increasing rates of the two
groups are very close to each other.
Figs. 3 and 4 show the compressive strength under different
curing conditions for HVFA concrete and HVSS concrete, respec-
tively. Two significant results can be got from Figs. 3 and 4. Firstly,
the promoting effect of high temperature curing on the early com-
pressive strength development of HVFA concrete is more obvious
Fig. 3. Compressive strength of HVFA concrete under different temperature curing
than that on HVSS concrete. As the test data shows, the compres- conditions.
sive strength of Group F-TMC at 7 days is 87.41% higher than that
of Group F-SC, while the compressive strength of Group S-TMC at
7 days is only 32.64% higher than that of Group S-SC. On the other
hand, at late ages the compressive strength of Group F-TMC is
superior to that of Group F-SC, while the late compressive strength
of Group S-TMC is lower than that of Group S-SC, indicating that
the effects of high temperature curing on the late strengths of
HVFA concrete and HVSS concrete are different.

Fig. 4. Compressive strength of HVSS concrete under different temperature curing


conditions.

3.3. Splitting tensile strength

The splitting tensile strengths of different concretes under tem-


perature match curing condition are shown in Fig. 5. And the split-
ting tensile strength comparison of HVFA concrete and HVSS
Fig. 1. Adiabatic temperature rise curves of concrete. concrete under different curing conditions is presented in Fig. 6
652 S. Mengxiao et al. / Construction and Building Materials 98 (2015) 649–655

Fig. 5. Splitting tensile strength of concrete under temperature match curing Fig. 7. Splitting tensile strength of HVSS concrete under different temperature
condition. curing conditions.

and Fig. 7, respectively. It can be seen that the trends of splitting


tensile strengths are quite similar to those of compressive
strengths. At early ages, HVFA concrete gains splitting tensile
strength more quickly than HVSS concrete under temperature
match curing condition, while the late splitting tensile strength
increasing rates of the two groups are very close to each other.
The splitting tensile strength of Group S-TMC is lower than that
of Group F-TMC at any age. It is also an indication that the promot-
ing effect of high temperature curing on the early splitting tensile
strength development of HVFA concrete is more obvious than that
on HVSS concrete. It can be seen that the splitting tensile strength
of Group F-TMC at 7 days is 61.18% higher than that of Group F-SC
(Fig. 6), while the splitting tensile strength of Group S-TMC at
7 days is only 24.13% higher than that of Group S-SC (Fig. 7). Fur- Fig. 8. Elastic modulus of concrete under temperature match curing condition.
thermore, the late splitting tensile strength of Group F-TMC is
superior to that of Group F-SC. For Group S-TMC, however, its late
splitting tensile strength is lower than that of Group S-SC.

3.4. Elastic modulus

Figs. 8–10 present the results of elastic modulus. On the whole,


the elastic modulus development trends of concrete are basically
consistent with the development trends of strength. It is notable
that the differences of elastic modulus values among the four
groups are not so significant as those of strength values. Especially
at late ages, the elastic modulus values of these four groups are
quite close.
It is widely known that concrete structure usually has three
phases: hardened paste, aggregates and the ITZ between them.
Among these, the properties of hardened paste and ITZ usually vary
Fig. 9. Elastic modulus of HVFA concrete under different temperature curing
conditions.

Fig. 6. Splitting tensile strength of HVFA concrete under different temperature Fig. 10. Elastic modulus of HVSS concrete under different temperature curing
curing conditions. conditions.
S. Mengxiao et al. / Construction and Building Materials 98 (2015) 649–655 653

with the change of age, temperature and humidity, while those of


the aggregates nearly don’t. As for the strength of normal strength
concrete, the strengths of hardened paste and ITZ are primary,
while the strength of aggregates is secondary. So curing tempera-
ture has obvious effect on the strength of concrete by significantly
influencing the properties of hardened paste and ITZ. However,
aggregates phase plays a more important role in the elastic modu-
lus than the strength, but the hardened paste and ITZ have less
effect on the elastic modulus than the strength. So the elastic
modulus of concrete is not so sensitive to the curing condition as
the strength of concrete.

3.5. Chloride permeability

Figs. 11 and 12 show the charge passed and permeability grade


of concrete under standard curing condition and under tempera- Fig. 12. Chloride permeability of concrete under temperature match curing
ture match curing condition, respectively. It is evident that, no condition.
matter under which kind of curing condition, the chloride perme-
ability of HVSS concrete is far higher than that of HVFA concrete at
any age. It can also be observed that the chloride permeability slag in Group S-65 °C is 61.68% higher than that in Group S-
grade of HVFA concrete at 90 d is ‘low’ under standard curing con- 20 °C. At the age of 7 days, the wn content of Group S-65 °C is
dition and ‘very low’ under temperature match curing condition. 60.51% higher than that of Group S-20 °C. From the results it can
For HVSS concrete, although the charge passed decreases with be concluded that elevating the curing temperature at early ages
the increase of age, the chloride permeability grade at 90 d is still can promote the early reaction of both fly ash and steel slag, how-
‘high’ under standard curing condition and ‘moderate’ under ever, its promoting effect on the early reaction of fly ash is more
temperature match curing condition. significant than that of steel slag. This is a reason why HVFA con-
crete gains early strength much more rapidly than HVSS concrete
3.6. Discussion under temperature match condition.
It is well known that the pozzolanic reaction of fly ash con-
3.6.1. Effect of temperature match curing on the properties of different sumes Ca(OH)2, which improves the microstructure of interfacial
cementitious systems transition zone (ITZ) of concrete. The reaction degree of fly ash
According to the results of compressive strength and splitting increases significantly by elevating the curing temperature, so it
tensile strength, temperature match curing can effectively promote can be deduced that fly ash makes considerable contribution to
the early strength development of both HVFA concrete and HVSS the improvement of ITZ of concrete at early ages under tempera-
concrete. However, it is also evident that at early ages HVFA ture match curing condition. So the early strength of HVFA con-
concrete gains strength more quickly than HVSS concrete under crete can be highly promoted under temperature match curing
temperature match curing condition. The study of Wang et al. condition. As for steel slag, its mineral constituents and hydration
[21] showed that the reaction degrees of fly ash in the composite process are similar to those of cement [32], merely the activity of
binder containing 45% fly ash at the age of 3 days were 0.91% its mineral constituents is much lower. Therefore, steel slag can
and 8.62% under the curing temperature of 20 °C and 65 °C, respec- be seen as a kind of ‘inferior cement’. The reaction of steel slag
tively, indicating that elevated temperature curing at early ages doesn’t consume Ca(OH)2, on the contrary, it produces some Ca
can effectively motivate the activity of fly ash. Besides, Li et al (OH)2. Thus the reaction of steel slag can’t improve the ITZ of
[35] found that the reaction degree of fly ash in the composite bin- concrete. This is another reason why the promoting effect of tem-
der containing 35% fly ash at the age of 7 days were 4.83% and perature match curing on the early strength of HVFA concrete is
14.78% under the curing temperature of 20 °C and 65 °C, respec- more obvious than that on HVSS concrete.
tively. Fig. 13 shows the non-evaporable water (wn) content of The results of strength also shows an interesting phenomenon:
steel slag paste under different curing temperatures. At the age temperature match curing has negative effect on the late strength
of 3 days, the wn content of Group S-65 °C is 61.68% higher than of HVSS concrete but it has positive effect on the late strength of
that of Group S-20 °C, indicating that the reaction degree of steel HVFA concrete. Some researches [36–38] showed that early high

Fig. 13. Non-evaporable water content of steel slag paste under different curing
Fig. 11. Chloride permeability of concrete under standard curing condition. temperatures.
654 S. Mengxiao et al. / Construction and Building Materials 98 (2015) 649–655

temperature curing tended to decrease the late strength of cement Fig. 12 shows that the chloride permeability of HVFA concrete
concrete due to two reasons: (1) early high temperature curing at 90 d reaches ‘very low’ grade, which can meet the design
increased the early hydration rate of cement, producing much den- requirement easily. However, the chloride permeability of HVFA
ser C-S-H gel layers, which would prevent the late hydration of concrete at 90 d only reaches ‘moderate’ grade, which can’t meet
cement; (2) early high temperature curing led to the uneven distri- the design requirement in some cases.
bution of hydration products, and large holes formed easily in the In general, there are some problems when HVSS concrete is
hardened cement paste, affecting the late strength development of used to replace HVFA concrete in the massive concrete structure.
concrete. However, it should be noted that the comparison of the properties
Fig. 13 shows that at the age of 90 days, the wn content of Group between HVFA concrete and HVSS concrete is made under the con-
S-65 °C is very close to that of Group S-20 °C, indicating that the dition of the same W/B. The research of Wang et al. [33] showed
late reaction degrees of steel slag under the two different curing that the negative influence of steel slag on the properties of
conditions are very close to each other. It should be noted that concrete would get weaker in the case of lower W/B. In theory,
the test of Fig. 13 was carried out using pure steel slag paste. Dur- HVSS concrete with satisfactory late strength and durability can
ing the hydration of cement-steel slag composite binder under be obtained by lowering the W/B, and in the meanwhile, the
temperature match curing condition, the steel slag particles would hydration heat becomes a little smaller. Therefore, it may be feasi-
be rapidly wrapped by the hydration products of steel slag as well ble to use HVSS concrete in massive concrete structures if proper
as cement. So the late reaction degree of steel slag under temper- W/B is adopted.
ature match curing condition might be lower than that under stan-
dard curing condition. Li et al [35] found that the reaction degree of 4. Conclusions
fly ash in the composite binder containing 35% fly ash at the age of
90 days were 11.26% and 19.27% under the curing temperature of (1) Temperature match curing can effectively promote the early
20 °C and 65 °C, respectively. Wang et al. [21] also found that strength development of both HVFA concrete and HVSS con-
although high temperature curing affected the late hydration of crete. But the promoting effect of temperature match curing
cement, it wouldn’t obstruct the late reaction of fly ash. At late ages on the early strength of HVFA concrete is more obvious than
fly ash can react sustainably, not only producing C-S-H gel to fill that on HVSS concrete.
the holes, but also consuming Ca(OH)2 and improving the ITZ of (2) At late ages, the strength of HVFA concrete under tempera-
concrete. Therefore, the effects of elevating temperature curing at ture match curing condition is superior to that under stan-
early ages on the late strengths of HVFA concrete and HVSS dard curing condition, while the late strength of HVSS
concrete are different. concrete under temperature match curing condition is lower
Many researches showed that fly ash tended to decrease the than that under standard curing condition.
chloride permeability of concrete at late ages mainly due to two (3) No matter for HVFA concrete or HVSS concrete, the elastic
reasons: the C-S-H gel produced by fly ash blocked the channels modulus development trends under different temperature
among pores; the pozzolanic reaction of fly ash improved the curing conditions are basically consistent with the develop-
microstructure of ITZ of concrete [39–41]. The reaction degree of ment trends of strength. But the promotion of temperature
fly ash is very crucial to the chloride permeability of concrete. match curing to the elastic modulus development is not so
The permeability grade of HVFA at the age of 28 days under obvious as that to the strength development.
standard curing condition is ‘moderate’ (Fig. 11), but that under (4) Temperature match curing can significantly decrease the
temperature match curing condition is ‘very low’ due to the high chloride permeability of HVFA concrete. However, the influ-
reaction degree of fly ash (Fig. 12). So temperature match curing ence of temperature match curing on the chloride perme-
tends to decrease the permeability of HVFA concrete obviously ability of HVSS concrete is inconspicuous.
by promoting the reaction of fly ash. Figs. 11 and 12 indicate that (5) The low adiabatic temperature rise of HVSS concrete is ben-
temperature match curing also tends to decrease the permeability eficial to its application to the massive concrete structures,
of HVSS concrete, but its influence degree is very small. It is however, its strength especially the splitting tensile strength
believed that the contribution of steel slag to the improvement and resistance to chloride ion penetration need to be
of pore structure and ITZ of concrete is much less than that of fly improved. In the region which has much steel slag but little
ash. fly ash, the HVSS concrete with proper mix proportion has
the better potential to be used in massive concrete
3.6.2. Feasibility of using HVSS concrete in massive concrete structures structures.
Low hydration heat is an important reason why HVFA concrete
is widely used in massive concrete structures. Fig. 1 shows that the
adiabatic temperature rise of HVSS concrete is even lower than Acknowledgements
that of HVFA concrete. This property of HVSS concrete is beneficial
to its application to the massive concrete structures. Authors would like to acknowledge the National Natural
In the case of the same constraint condition and shrinkage Science Foundation of China (No. 51278277) and Tsinghua
value, the tensile stress is directly proportional to the elastic University Initiative Scientific Research Program (20131089239).
modulus. Fig. 8 shows that the elastic modulus of HVSS concrete
is smaller than that of HVFA concrete under temperature match
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