• PROBLEMAS PROPUESTOS PRIMER PARCIAL to compute the activity coefficients over the entire range of compositions and compare

the entire range of compositions and compare them in a

plot like Fig. 5.1 with the experimental points of Problem 5.6.
Entregar 3 problemas libres como parte de la nota de trabajo en clase
Libro Smith Van Ness 5.14. From Hála et al., the van Laar constants for the system n-hexane(1)-benzene(2) at
11.13 a), b), y calcule el volumen final al mezclar 70 ml de 1 con 30 ml de 2. approximately 70°C are determined to be A12=0.6226 and A21=0.2970.
11.14 Cuál es el calor transferido al mezclar 4 moles de 1 con 6 moles de 2. Asuma que la (a) Predict the van Laar constants at 25°C.
temperatura es igual a T=298K antes y después de mezclar, y que H (J/mol). (b) Predict the excess enthalpy at 25°C over the entire composition range and compare your values
11.20, 11.43, 11.44. with the following experimental values of Jones and Lu [J. Chem. Eng. Data, 11, 488 (1966)].
16.5, 16.10, 16.11, 16.13, HE,
Problemas del libro de Henley-Seader, Equilibrium Stage separation operations in Chem Eng. x2 cal/gmole
5.7. Hermsen and Prausnitz [Chem. Eng. Sci., 18, 485 (1963)] show that the mixture benzene- 0.1519 102.9
cyclopentane does not form a regular solution. Confirm this by computing liquid phase activity 0.2136 129.8
coefficients for this system at 35°C, over the entire composition range, from regular solution theory, 0.3575 185.5
with and without the Flory-Huggins correction, and prepare a plot of your results similar to Fig. 5.1, 0.4678 209.7
0.5242 213.5
compared to the following experimental values of Hermsen and Prausnitz.
0.6427 207.5
0.6497 205.2
xbenzene gbenzene gciclopentane 0.6957 196.1
0.0 1.5541 1.0000 0.7211 189.3
0.1 1.4218 1.0047 0.8075 155.3
0.2 1.3150 1.0186 0.9157 82.8
0.3 1.2294 1.0416
0.4 1.1611 1.0742
5.19 For the system ethanol (1) – benzene (2), the Wilson constants at 45°C are: L12=0.124 and
0.5 1.1075 1.1165
0.6 1.0664 1.1693 L21=0.523.
0.7 1.0362 1.2333 (a) Predict Wilson Constants at 25°C.
0.8 1.0157 1.3096 (b) Predict the excess enthalpy at 25°C over the entire composition range and compare your values
0.9 1.0038 1.3993 in a plot of HE versus x1 with the following experimental values. [J. Chem. Eng. Data, 11, 480 (1966)].
1.0 1.0000 1.5044
HE,
x1 cal/gmole
5.10. Use (5-23) with regular solution theory to predict K-values for the n-octane-ethylbenzene 0.0250 75.2
system at 270.3 °F and 1 atm with experimental compositions of xC8 = 0.201 and yC8 = 0.275 [Ind. 0.0586 112.0
0.1615 190.0
Eng. Chem., 47, 293 (1955)]. Compare your results with the experiemental values computed from
0.2673 216.5
the experimental compositions.
0.4668 197.0
0.5602 168.4
5.12. From the experimental infinite-dilution activity coefficients given in Problem 5.7 for the 0.7074 114.8
benzene-cyclopentane system, calculate the constants in the Van Laar equation. With these 0.9058 37.8
constants, use the Van Laar equation to compute the activity coefficients over the entire range of
compositions and compare them in a plot like Fig. 5.1 with the experimental points of Problem 5.7.

5.13. From the azeotropic composition for the benzene-cyclopentane system in Problem 5.7,
calculate the constants in the Van Laar equation. With these constants, use the Van Laar equation