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1 1
− = A × aging period × e −E /(RT ),
DPaging period DPstart
(2)
Figure 1. Cellulose chain.
where A is a constant depending on the chemical environment, E
The products of cellulose degradation include carbon is the activation energy of the aging reaction (in J/mol), R is the
monoxide (CO), carbon dioxide (CO2), organic acids, water, gas constant (8.314 J/mol per kelvin), T is the temperature of the
and free glucose molecules. The glucose rings can decompose paper (in kelvin), and DPstart and DPaging period are the DP values at
further into other compounds called furans [4], as shown in the beginning and end of the aging period, respectively.
Figure 3. In a real transformer, the temperature of the paper changes
It is not feasible to measure the DP of the insulating paper with the load and the environmental conditions. The Arrhenius
directly on an operating transformer. However, an estimation relationship does not take such changes into account. The
can be obtained using markers in the oil, e.g., the concentration environmental conditions will also determine whether hydrolysis
of furans. The DP of nonthermally upgraded paper can be or oxidation dominates the aging reaction. Nevertheless,
estimated from the concentration, c, of the compound 2-furfural, Equation (2) can be used to estimate the aging of the paper due
expressed in parts per billion (ppb), using the following modified to each process, assuming steady-state conditions.
Chendong equation [5]:
In this article DP values measured directly on the failed phase A (see Figure 7), causing the copper winding in discs 5
transformer mentioned earlier are compared with estimates and 6 to melt.
obtained from furan analysis. Separate estimates were obtained
for hydrolysis and oxidation, using A and E values taken from Results
the literature. The criticality of the temperature, and the A and E Paper samples were taken from the top, middle, and
values, is discussed. bottom of each phase and from the tapping, HV, LV, and
tertiary windings. The DP value of the samples was measured
The Failed Transformer in accordance with ASTM D4243 [1]. In this test method the
The failed transformer was 47 years old, rated at 20/27 MVA, sample of paper is degreased, cut finely, and then dissolved
and filled with mineral oil. It was free breathing, i.e., it did not in the solvent cupriethylene-diamine. The DP is then deduced
have a rubber bag in the conservator or a silica gel breather from a measurement of the specific viscosity of the solution. The
installed to prevent oxygen and moisture ingress. Consequently results are plotted in Figure 8.
a high concentration of oxygen had accumulated, and the It can be seen that the DP values vary across the transformer.
moisture content of the insulation paper was high. Lower values at the top of the transformer windings are expected
Figure 4 shows the three phases of the transformer. Each because of the higher temperatures there (see Figure 9).
phase has four winding layers. The outermost is the tapping The DP values at the top and bottom of the transformer vary
winding, followed by the HV and low-voltage (LV) windings, little between the same windings in the different phases (except
and then the tertiary winding. A top view of the HV, LV, and the bottom HV tapping winding). However, there is considerable
tertiary windings is shown in Figure 5. variation between the different windings in the same phase. The
A cross section of the tapping, HV, and LV windings is shown approximate range is 230 to 420 at the top and 380 to 500 at the
in Figure 6. The tertiary winding is not shown in Figure 6. The bottom. The values for the HV tapping winding, at the bottom of
number of turns in each winding section and the number of the transformer, increase a great deal from phase A to phase C
paper layers on the conductors are given in Table 1. The fault (400 to 700). Because the HV tapping winding is the outermost
leading to failure occurred on the LV winding at the bottom of winding, we believe this increase (more precisely, decreased
aging) is due to lower temperatures associated with oil flow
and greater cooling. The radiator cooling ducts on one side of
Figure 6. Tapping, HV, and low-voltage (LV) windings of the The DP of the outer layer of Crepe paper (from the cable end
transformer. of phase B, LV winding) was 275, and that of the innermost layer
was 300. These values are slightly higher than 231, the value for
the Kraft paper at the top of the LV winding. This observation
the transformer tank are shown in Figure 10. There are more
suggests that the DP values of the Crepe paper could possibly be
ducts around phase C than around phase A, and therefore the
used as approximations of the DP values of the Kraft paper on
temperature in phase C would be expected to be lower.
the windings.
The lowest measured DP was 231, in the LV winding at the
top of phase B. Surprisingly, the DP of the paper at the location
of the fault (LV winding, bottom) was 380. The DP was also DP Estimation From Furans
measured at two points along disc 5, in which the fault occurred. The total furan concentration dissolved in the oil of this
A value of 380 was found at a distance of 12 to 31 cm away transformer was measured on several occasions between 2001
from the fault (phase A, LV winding, bottom, disc 5, turn 20 and 2009 (Figure 12). The fall in concentration in 2005 was due
of 26), and 375 at a distance of 74 to 94 cm (or approximately to replacement of the oil. A period of 3 to 4 years elapsed before
180°) away from the fault. Thus the paper aging across this disc the concentration in the new oil reached the same level as that in
appears to be uniform. We therefore expect that the temperatures the replaced oil. The expected total furan concentration, had the
and thus the aging rates of the paper are uniform around this disc oil not been replaced, was obtained by adding the increase in the
(360°), and similarly for the other discs. concentration in the replaced oil to the values for the old oil as
If a transformer is opened at the top for maintenance, Crepe shown by the red squares in Figure 12. In 2009 the transformer
paper from the top leads is usually more accessible than the owner decided to dry the oil, using a molecular sieve, to extend
Kraft paper used to insulate the windings (without affecting the the remaining service lifetime of the transformer. This process
operation of the transformer). Crepe paper is used to tie together appears to have reduced the furan concentration. Figure 13 shows
the windings before they are connected to the bushings (see
Figure 11). To check whether the DP values of more readily
accessible Crepe paper samples could be reliably correlated
with the DP values of the windings, the two were compared.
The mechanical strength of Crepe paper is normally greater than
that of Kraft paper, so it would be expected to age more slowly.
Tapping HV 8 5
HV 26 5
Figure 10. Radiator ducts on one side of the transformer. Figure 12. Total furan concentration in the transformer oil.
Parameter Description
Cooling ONAN-ONAF
where H is the hot-spot factor, Δgr is the rated average winding Average water content of paper 2.5%
to average oil gradient, Ki is the averaged load factor for the ith
segment, and y is the winding exponent [6]. It is assumed in the
derivation of (5) that the hot-spot to top-oil gradient reaches a DP values of the paper calculated using a weighted hot-spot
steady-state value between two recordings [8], in order to avoid temperature are given in Table 3.
underestimation of the temperature rise. The DP of the paper was estimated separately for two aging
The weighted hot-spot temperature estimated for the period processes, hydrolysis and oxidation, using A and E values taken
9 December 2009 to 17 April 2010 was 59.5°C, where the from the literature (Table 3). The A values were selected based on
corresponding load profile was calculated for ONAF (oil natural, the moisture content of the paper and the oxygen concentration
air forced) cooling mode (see Figure 14). The transformer rating of the oil. The average moisture content of the paper, 2.5%, was
data given in Table 2 were used in these calculations. The calculated from the average calculated hot-spot temperature and
the oil water activity value provided by the Vaisala Probe, and
then using the water equilibrium curves published by Du [9].
The oxygen content of the oil at various dates, plotted in Figure
15, was measured using dissolved-gas analysis [10], [11]. The
oxygen content was high and varied significantly because the
transformer was fitted with a free-breathing conservator system.
Using A and E values provided by Emsley [12], the DP was
predicted to be 400, assuming a hot-spot temperature of 59.5°C
(weighted). However, the A values given in Table 3 do not take
oxidation and hydrolysis into account. Because hydrolysis
involves acids, the A value will depend on the type of acid, its
concentration, and the concentration of water absorbed by the
paper. Clearly there is a requirement to develop an equation for
Figure 14. Transformer load profile. A that takes acidity into account.
1.00E+09
59.5 111000 (Emsley) 2.5 N/A 1.00E+03 400
(Emsley)
Hydrolysis only
2.92E+11
59.5 128000 (SINTEF) 2.5 N/A 1.00E+03 517
(SINTEF)
4.60E+05
Oxidation only 59.5 89000 (SINTEF) Dry High 1.00E+03 337
(SINTEF)
Using A and E values provided by SINTEF [7], the DP estimate therefore take into account the furan concentration reduction
for hydrolysis is 517 using a weighted hot-spot temperature of during processing to obtain more accurate results.
59.5°C. The A and E values for Kraft paper with 2.5% water Degree of polymerization values calculated using a weighted
content, given in Table 3, were extrapolated from [12]. hot-spot temperature were in better agreement with the
Again using A and E values provided by SINTEF [7], the DP measured DP values than those calculated using an average hot-
estimate for oxidation is 337 for a weighted hot-spot temperature spot temperature. However, the available A and E values are not
of 59.5°C. These A and E values for oxidation are for dry paper sufficiently accurate to estimate DP using Arrhenius models,
with high oxygen content; the oxygen level in the transformer because they do not include the combined effects of moisture,
oil was high (average 19,000 ppm), but the paper was not dry, its acidity, and oxygen. The A and E values for the combined effects
water content at the top of the transformer being approximately of oxidation and hydrolysis have not been determined. More
2.5%. laboratory experiments are needed to determine these values
These calculated DP values are higher than those measured over a wide range of conditions.
directly; the lowest measured DP was 231. The calculated
DP values would probably be lower if A and E values for the Acknowledgments
combined aging effects of oxygen and water, not available at The authors wish to thank Col Feely (Powercor Australia
present, were used. Clearly the hot-spot temperature is a critical Ltd.), Meng Lee (Wilson Transformer Co., Glen Waverly,
factor in estimating the lowest DP of the paper. Victoria, Australia), and David Fernandez (Dynamic Ratings,
Glen Waverly, Victoria, Australia) for their valuable contribution
Conclusion and Future Work and Valery Davydov for his support during his time at Monash
This study has shown that the aging of the paper insulation in University.
the failed transformer was not uniform and therefore cannot be
characterized by a single DP value. The DP of Crepe paper from References
the cable end of the LV winding was similar to that of the Kraft [1] Measurement of Average Viscometric Degree of Polymerization of New
paper at the top of the windings. and Aged Electrical Papers and Boards. ASTM D4243-99.
[2] “Ageing of Cellulose in Mineral-Oil Insulated Transformers,” Cigre
Degree of polymerization values estimated from furan Brochure 323, 2007.
concentration will be too high if the transformer oil is dried [3] R. Sanghi, “Chemistry behind the life of a transformer,” Resonance, vol.
or replaced during transformer operation. Laboratories should 8, no. 6, pp. 17–23, 2003.
[4] C. Homagk, K. Mossner, and T. Leibfried, “Investigation on degradation
of power transformer solid insulation material,” in 2008 Annual Report
Conference on Electrical Insulation Dielectric Phenomena, 2008, pp.
75–78.
[5] R. D. Stebbins, D. S. Myers, and A. B. Shkolnik, “Furanic compounds in
dielectric liquid samples: Review and update of diagnostic interpretation
and estimation of insulation ageing,” in Proceedings of the 7th Interna-
tional Conference on Properties and Applications of Dielectric Materials,
2003, pp. 921–926.
[6] Loading Guide for Oil-immersed Power Transformers, 1st ed. IEC
60076-7, Dec. 2005.
[7] D. Susa, K. B. Liland, L. Lundgaard, and G. Vårdal, “Generator step-up
transformer post mortem assessment,” Eur. Trans. Electr. Power, vol. 21,
no. 5, pp. 1802–1822, Jul. 2011. doi:10.1002/etep.544.
[8] H. Nordman, N. Rafsback, and D. Susa, “Temperature responses to step
changes in the load current of power transformers,” IEEE Trans. Power
Del., vol. 18, no. 4, pp.1110–1117, Oct. 2003.
[9] Y. Du, M. Zahn, B. C. Lesieutre, A. V. Mamishev, and S. R. Lindgren,
“Moisture equilibrium in transformer paper-oil systems,” IEEE Electr.
Insul. Mag., vol. 15, pp. 11–20, Jan./Feb. 1999.
[10] Analysis of Gases Dissolved in Electrical Insulating Oil by Gas
Figure 15. Oxygen concentration in the transformer oil.