Calcular KG (Coeficiente de TDM) y ZF (Espesor efectivo)

Fluidos dentro de tubos circulares

Propiedades a 25 °C
Amoniaco Aire
Densidad kg/m3 0,7037 1,1839
Viscosidad Kg/m.s 1,0245e-5 1,849e-5
Concentración promedio del amoniaco en el aire

𝑃𝐴 30.8 𝑚𝑚𝐻𝑔
𝑦𝐴 = = = 0.040 𝑀𝑢𝑦 𝑝𝑜𝑐𝑜 𝑐𝑜𝑛𝑐𝑒𝑛𝑡𝑟𝑎𝑑𝑜 ∴ 𝑠𝑜𝑙𝑢𝑐𝑖ó𝑛 𝑑𝑖𝑙𝑢𝑖𝑑𝑎
𝑃𝑡 760 𝑚𝑚𝐻𝑔
41.4 𝑔 1 𝑚𝑜𝑙 𝑎𝑖𝑟𝑒 1 𝑚𝑖𝑛
𝑛̇ 𝑎𝑖𝑟𝑒 = ∙ ∙ = 0.02379 𝑚𝑜𝑙𝑎𝑖𝑟𝑒 ⁄𝑠
𝑚𝑖𝑛 29 𝑔 60 𝑠
𝑛̇ 𝑎𝑖𝑟𝑒
𝑛̇ 𝑁𝐻3 = 𝑦 = 0.02379(0.040) = 9.52𝑥10−4 𝑚𝑜𝑙𝑁𝐻3 ⁄𝑠
𝑦𝑎𝑖𝑟𝑒 𝑁𝐻3
𝑚𝑜𝑙 𝑁𝐻3 17 𝑔 𝑔
𝑚̇𝑁𝐻3 = 9.52𝑥10−4 ∙ = 0.016
𝑠 1 𝑚𝑜𝑙 𝑁𝐻3 𝑠
𝑔 41.4 𝑔 1 𝑚𝑖𝑛 𝑔
𝑚̇𝑡𝑜𝑡𝑎𝑙 = 0.016 + ( ∙ ) = 0.706
𝑠 𝑚𝑖𝑛 60 𝑠 𝑠
Se obtiene la velocidad, se consideran las propiedades del aire para el sistema, ya que el amoniaco
está en muy diluido.

𝑚̇ 0.706𝑥10−3 𝐾𝑔⁄𝑠 𝑚
𝑉= = 𝜋 = 3.57
𝜌𝐴 1.1839 𝐾𝑔⁄𝑚3 ∗ ∗ (0.0146𝑚)2 𝑠
4
𝜌𝑉𝐷 1.1839 𝑘𝑔⁄𝑚3 (3.57 𝑚⁄𝑠)(0.0146 𝑚)
𝑅𝑒 = = = 3337.33
𝜇 1.849𝑥10−3 𝑘𝑔⁄𝑚. 𝑠
Se calcula DAB

A= NH3
B= Aire

rA=0.29
rB=0.3711

EA/k=558.3
EB/k=78.6

0.29 + 0.3711 𝜀𝐴𝐵

𝑟𝐴𝐵 = = 0.3306 = √558.3 ∗ 78.6 = 209.48
2 𝑘

𝑘𝑇 298 𝑘𝑇
= = 1.42 → 𝑉𝑒𝑟 𝑒𝑛 𝐹𝑖𝑔 2.5 𝑓 ( ) = 0.62
𝜀𝐴𝐵 209.48 𝜀𝐴𝐵

1 1
√ + = 0.305
𝑀𝐴 𝑀𝐵

3
10−4 (1.084 − 0.249(0.305))2982 (0.305)
𝐷𝐴𝐵 = = 2.3𝑥10−5 𝑚⁄𝑠
101325(0.3306)2 0.62

2000 < 𝑅𝑒 < 35000

𝜇 1.849𝑥10−5
𝑆𝑐 = = = 0.67 0.6 < 𝑆𝑐 < 2.5
𝜌𝐷𝐴𝐵 1.1839(2.3𝑥10−5 )
∴

𝑆ℎ = 0.023 𝑅𝑒 0.83 𝑆𝑐 0.44 → 𝑃𝑎𝑟𝑎 𝑔𝑎𝑠𝑒𝑠

𝑆ℎ = 0.023 3337.330.83 0.670.44 = 16.20
𝐾𝐺 𝑃̅𝐵,𝑀 𝑅𝑇𝐷 𝑃𝑡 𝐷𝐴𝐵 𝑆ℎ
𝑆ℎ = → 𝑇𝑎𝑏𝑙𝑎 3.2 𝑠𝑒𝑐𝑐𝑖ó𝑛 4 𝐾𝐺 = → 𝐶𝑎𝑙𝑐𝑢𝑙𝑎𝑟 𝑃̅𝐵,𝑀
𝑃𝑡 𝐷𝐴𝐵 𝑃̅𝐵,𝑀 𝑅𝑇𝐷

𝑃𝐴1 = 30.8 𝑚𝑚𝐻𝑔 𝑃𝐵1 = 760 − 30.8 = 729.2 𝑚𝑚𝐻𝑔

𝑃𝐴2 = 0 (𝐶𝑜𝑛𝑑𝑖𝑐𝑖ó𝑛 𝑑𝑒𝑙 𝑝𝑟𝑜𝑏𝑙𝑒𝑚𝑎) 𝑃𝐵2 = 760 𝑚𝑚𝐻𝑔
760 − 729.2
𝑃̅𝐵,𝑀 = = 744.5 𝑚𝑚𝐻𝑔
𝐿𝑛(760⁄729.2)
 760 𝑚𝑚𝐻𝑔(2.3𝑥10−5 𝑚⁄𝑠)(16.20) 𝑚𝑜𝑙
𝐾𝐺 = 3 = 1.4020𝑥10−3
𝑚𝑚𝐻𝑔 𝑚 𝑚𝑚𝐻𝑔 𝑚2 . 𝑠
744.5 𝑚𝑚𝐻𝑔 (0.06236 ) 298𝐾(0.0146𝑚)
𝑚𝑜𝑙 𝐾
𝑁𝐴 = 𝐾𝐺 (𝑃1 − 𝑃2 ) → 𝑃2 = 0
𝑚𝑜𝑙 𝑚𝑜𝑙
𝑁𝐴 = 1.4020𝑥10−3 2
(30.8 𝑚𝑚𝐻𝑔) = 0.043 2
𝑚𝑚𝐻𝑔 𝑚 . 𝑠 𝑚 .𝑠
Para la teoría de la película se trata de encontrar el espesor efectivo

𝐷𝐴𝐵 𝐶
𝐹= (1)
𝑍𝐹
𝑇𝑎𝑏𝑙𝑎 3.2 𝑠𝑒𝑐𝑐𝑖ó𝑛 4
𝐹𝐷
𝑆ℎ = (2)
𝐶𝐷𝐴𝐵
1 𝑒𝑛 2
𝐷𝐴𝐵 𝐶
𝐷 𝐷
𝑍
𝑆ℎ = 𝐹 =
𝐶𝐷𝐴𝐵 𝑍𝐹
0.0146𝑚
𝑍𝐹 = = 9.012𝑥10−4
16.20