LUCKNOW PUBLIC SCHOOL

ANNUAL EXAMINATION 2018-19

CLASS – XI
SUBJECT – CHEMISTRY
SAMPLE PAPER - II
TIME ALLOWED : 3hrs. M.M. 70

General Instructions:
(a) All questions are compulsory.
(b) Section A: Q.no. 1 to 5 are very short answer questions and carry 1 mark each.
(c) Section B: Q.no. 6 to 12 are short answer questions and carry 2 marks each.
(d) Section C: Q.no. 13 to 24 are also short answer questions and carry 3 marks each.
(e) Section D: Q.no. 25 to 27 are long answer questions and carry 5 marks each.
(f) There is no overall choice. However an internal choice has been provided in two
questions of
one mark, two questions of two marks, four questions of three marks and all the three
questions
of five marks weightage. You have to attempt only one of the choices in such questions.
(g) Use of log tables if necessary, use of calculators is not allowed.

Section – A
1. Write the electronic configuration of Cu(Z=29).
Or
Compute all the four quantum numbers for unpaired electron of chlorine.
2. Suggest reason why the B-F Bond in BF3 and BF4 differ?
Or
Explain why CO2 is linear and SO2 is angular.
3. Determine oxidation number of sulphur in Na2SO5 and Na2S4O6.
4. Define disproportionation reaction with example.
5. Give a chemical test to differentiate between ethene and ethyne.
Section B
6. Calculate the wavelength associated with a moving electron having a kinetic energy of
3.0x10-25 J.
7. Account for the following
a) Chlorine has more negative electron gain enthalpy than fluorine.
b) Atomic radius of Ga is smaller than Al.
8. Draw the structure of SF4 and ICl3 on the basis of VSEPR theory.
Or
Explain hydrogen bonding. Give reason why H2O is a liquid and H2S is a gas.
9. (a) Write the structural formula of 2-Chloro-3-methylbutanal.
(b) Write IUPAC name of CH3.C(CH3)2.CH(OH).CHO
10. Derive relation between KP and KC.
 Or
Describe the application of common ion effect in the second group of qualitative analysis of
basic radicals.
11. Complete the following reactions
a) B2H6 +6 HNO3 

b) H3BO3 

12. a) Arrange Al, Ga, In and Tl in increasing order of giving +1 oxidationion state.
b) Draw the structure of diborane.
Section - C
13.(a) Define law of multiple proportion
(b) 3 gram of H2 reacts with 29 grams of O2 to yield H2O. Which substance is the limiting
reagent and calculate the amount of water formed.
14. Explain Heisenberg’s uncertainty principle.
A golf ball has a mass of 40 gram and a speed of 45 m/sec. If the speed can be measured
with an accuracy of 2%, calculate the uncertainty in the position.
Or
A photon of of wavelength 4 x 10-7 m strikes on a metal surface , the work function of metal
being 2.13 electron volt. Calculate:
i. The energy of photon
ii. Kinetic energy of the emission
iii. Velocity of the photoelectron
15. a) Arrange following in increasing size
O- -, N- - -, Na+, Al3+, Mg++, F-
b) account for the following
(i) elements in the same group have similar properties.
(ii) noble gases tend to be less reactive.
16. write the molecular orbital diagram of N2+ and N2 and calculate their bond order.
17. (i) Balance following reaction by ion electron method:
Cr2O7- - + SO2 + H+ 
 Cr3+ + SO4- -
ii) Show AuCl3 and KMnO4 in stock notation.
18. (i)Write conjugate acid-base of the of the following
HS- OH- H2CO3 NH4+
(ii) calculate the pH of 0.001M NaOH solution
iii) Classify BF3 and NH3 as Lewis acid or base
Or
Nitric oxide reacts with Br2 and gives nitrosyl bromide as the reaction given below
Br2(g) + 2NO(g) 2NOBr(g)
When 0.087 mole of NO and 0.0437 mole of Br2 are mixed in a closed container at constant
temperature 0.0518 mole of NOBr is obtained at equilibrium. Calculate equilibrium amount of
NO and Br2.
19. a) What causes the temporary and permanent hardness of water?
b) How many hydrogen bonded water molecules are present in CuSO4.5H2O.
(c) What is water-gas shift reaction ?
20. Give reason
a) Boric acid is aprotic.
b) Lead tetra chloride is highly unstable towards heat
c) Concentrated HNO3 can be transported in aluminium container.
Or
a) What is Aqua regia?
b) Why Phosphorus show greater tendency for catenation than nitrogen?
c) Write the reaction of oxidation of phosphorus by concentrated acid HNO3.
21. 0.45 gram of an organic compound gave 0.792 to gram of CO2 and 0.324 gram of H2O
on combustion. 0.24 gram of same substance was analysed by Kjeldahl method and the
ammonia formed was absorbed in 50 cm3 of M/8 H2SO4 . The excess acid require 77 cm3 of
M/10 NaOH for complete neutralization. Calculate the percent of carbon, nitrogen and
hydrogen in the compound.
22. Explain
i) Friedel craft reaction
ii) Wurtz reaction
iii) Conditions for aromaticity
24.(i) Draw Newman projection of conformation of ethane.
(ii) Why boiling point of of n-hexane is higher than 2-methylpentane?
(iii) Out of benzene. metadinitrobenzene and toluene which will undergo nitration most easily
and why?
25.(i) Give reason
a) It is not advisable to use sulphuric acid in place of acetic acid for acidification while testing
sulphur by lead acetate test.
b) Carbon tetrachloride does not give white ppt when heated with silver nitrate solution.
Explain.
ii) Explain the principle of paper chromatography.
iii) Show resonance in phenol.
Or
i) Describe the chemistry of Lassaigne's test for the detection of nitrogen.
ii) What type of isomerism is shown between n-propyl bromide and isopropyl bromide?
iii) Chloroacetic acid has lower pka value than acetic acid.
iv) Arrange following in increasing order of stability
CH3CH2-, (CH3)3C-, (CH3)2CH-
v) A liquid compound starts decomposing well before its boiling point under normal pressure.
Name the method used to purify such organic liquids.
26. Define the following term with appropriate example
i) Pyrolysis (cracking) ii) Ozonolysis of an alkene iii) Isomerization iv) Aromatization
v) Markownikoff rule
Or
(a)How will you convert:
(i) Benzene to acetophenone
(ii)Sodium Acetate to ethane
(iii) Ethyne to ethanal
(b) An alkene on ozonolysis gives propanone and 2 methylbutanal. Write the structural
formula and IUPAC name of alkene.
27. a) What do you mean by buffer solution? Write the mechanism of acidic buffer.

(b) Equilibrium constant Kc for the reaction N2(g) + 3H2(g) 2 NH3(g) at 500 K is 0.061.
At particular time the analysis shows that the composition of the reaction mixture is 3.0
moles/L N2, 2.0 moles/L H2 and 0.50 moles/L NH3. Is the reaction at equilibrium? If not, in
which direction the reaction tend to proceed to reach the equilibrium.
Or
The ionization constant of phenol is 1.0 x 10-10. What is the concentration of phente ion in
0.05M solution of phenol and pH of solution? What will be the degree of dissociation of
phenol if the solution is also 0.01M in sodium phenate?
(b) what is the effect of :
(i) addition of H2 (ii) addition of CH3OH (iii) removal of CO (iv) increasing

pressure on the equilibrium of CO+2H2 CH3OH