Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
This package was designed to save time, in order to allow for more
exam preparation time, if any, at the end of the course.
You can purchase a booklet for $2.00, and use it as your main source
out notes. (There may be cases when additional notes and problems are
needed)
You can also sign the booklet out, like a textbook. However, all notes
and problems would need to be done in you regular notes binder. It is
your choice!
Acids and bases introduction:
B) Solvated ion
C) Hydronium ion
D) Neutral solution
E) Acidic solution
F) Basic solution
As you can see, the negative ion determines the name given to the acid. It
tells you the rule to use.
Examples:
*For acids, we must know how to (A) write chemical formulas and also (B)
name acids.
If time allows and the need is present, I may request that this review
sheet, one we did in chem..11, be completed to provide more practice
with acid naming and formulas.
HBr HClO2
HBr (aq) HClO2(aq)
HClO3 H2S2O3
HClO3(aq) H2S2O3(aq)
H2S HClO
H2S(aq) HClO(aq)
H2CrO4 Write the acid formula
H2CrO4(aq) Sulfuric acid
H2SO3 Hrdriodic acid
H2SO3(aq) Sulfurous acid
H3PO4 Hydrosulfuric acid
H3PO4(aq) Nitrous scid
H2C2O4 Hydrobromic acid
H2C2O4(aq) Oxalic acid
H2CO3 Ethanoic acid
H2CO3(aq) Phosphorous acid
HCl Phosphoric acid
HCl(aq)
HNO2
HNO2(aq)
H2Se
H2Se (aq)
PROPERTIES OF ACIDS
Acids release a hydrogen ion into water (aqueous) solution.
Acids neutralize bases in a neutralization reaction. An acid and a base combine to make a salt
and water. A salt is any ionic compound that could be made with the anion of an acid and the
cation of a base. The hydrogen ion of the acid and the hydroxide ion of the base unite to form
water.
Acids corrode active metals. Even gold, the least active metal, is attacked by an acid, a mixture
of acids called 'aqua regia,' or 'royal liquid.' When an acid reacts with a metal, it produces a
compound with the cation of the metal and the anion of the acid and hydrogen gas.
Acids turn blue litmus to red. Litmus is one of a large number of organic compounds that change
colors when a solution changes acidity at a particular point. Litmus is the oldest known pH
indicator. It is red in acid and blue in base. The phrase, 'litmus test,' indicates that litmus has
been around a long time in the English language. Litmus does not change color exactly at the
neutral point between acid and base, but very close to it. Litmus is often impregnated onto paper
to make 'litmus paper.'
Acids taste sour. TASTING LAB ACIDS IS NOT PERMITTED BY ANY SCHOOL. The word
'sauer' in German means acid and is pronounced almost exactly the same way as 'sour' in
English. Stomach acid is hydrochloric acid. Although tasting stomach acid is not pleasant, it has
the sour taste of acid. Acetic acid is the acid ingredient in vinegar. Citrus fruits such as lemons,
grapefruit, oranges, and limes have citric acid in the juice. Sour milk, sour cream, yogurt, and
cottage cheese have lactic acid from the fermentation of the sugar lactose.
PROPERTIES OF BASES
Bases release a hydroxide ion into water solution. (Or, in the Lowry- Brønsted model, cause a
hydroxide ion to be released into water solution by accepting a hydrogen ion in water.)
Bases denature protein. This accounts for the "slippery" feeling on hands when exposed to base.
Strong bases that dissolve in water well, such as sodium or potassium lye are very dangerous
because a great amount of the structural material of human beings is made of protein. Serious
damage to flesh can be avoided by careful used of strong bases.
Bases turn red litmus to blue. This is not to say that litmus is the only acid- base indicator, but
that it is likely the oldest one.
Bases taste bitter. There are very few food materials that are alkaline, but those that are taste
bitter. It is even more important that care be taken in tasting bases. Again, NO SCHOOL
PERMITS TASTING OF LAB CHEMICALS. Tasting of bases is more dangerous than tasting
acids due to the property of stronger bases to denature protein.
Bases Introduction
NaOH –
Ca(OH)2 –
Mg(OH)2 –
NH4OH –
Al(OH)3 -
Exercise A:
Complete the following equations:
Label and name the acid, base and salt.
Exercise B:
For each of the equation above, I left space for you to write the complete
ionic equation and net ionic equation.
(Note: this is a review from the solutions unit)
Special case of the equilibrium constant (Keq)
The ionization constant for water (Kw)
Water ionizes to a tiny extent (reacts with itself)
H2O(l) Í==Î H+(aq) + OH-(aq)
Since we do not use pure liquids in the expression, the bottom is eliminated. This is
why. Since water ionizes only slightly, it concentration (the amount of ionized H2O
molecules dispersed among its ions) is essentially constant.
1 molecule in a million ionizes.
If the above expression, the [H+ ]and [OH- ]are inversely proportional and
can be used in the following expression to find the concentration of H+ or
OH-. If we know one concentration we can compute the other using Kw.
Example:
H+ = .125M =
Using [H+ ] x [OH- ] = 1.00 x 10-14
OH - = 1.00 x 10-14
H+
= 1.00 x 10-14 = 8.00 x 10 -14M
.125M
Note: Do not forget to keep a section of your binder for the class
problems will be do on the board to review the previous lesson
Activity
Each of the following compounds was dissolved in water.
Complete the table, assuming 100% ionization. (straight arrow)
Compound Name Type Ionic Equation [ ] of each ion, if
compound [ ] in
water is .050 mol/l
HClO4 (aq)
MgCl2 (aq)
Ba(OH)2 (aq)
NaOH (aq)
HBr (aq)
H3PO4 (aq)
An acid is a molecule or an ion* that can contribute a hydronium ion (H+) to a solution.
An acid has the power to neutralize alkalis.
An alkali (which is often called a "base") is a molecule or an ion that combines with
hydronium ions to remove them from a solution.
pH = - log 10 [H+]
____________________________________________________________
Sample Problem
What is the pH of 0.0066 M H2SO4 (aq) solution assuming complete
ionization?
_____________________________________________________________
Find the pH of a 0.0084 M KOH?
____________________________________________________________
POH Scale
pH + pOH = 14.00
pH = 14.00 – pOH
Sample Problem!
Find the pOH of a 0.0084 M KOH solution?
Problems:
1) The pH of a urine sample was measured to be 5.53 . What is the [H3O+], [OH-] and
pOH of the urine. Is the sample acidic, basic or neutral.
2) A sample of household ammonia is 11.9 . What is the pOH and the [OH-] of the
solution.
3) Phenol is used as a disinfectant. An aqueous solution of phenol was found to have a
pH of 4.72. Calculate the [H3O+], [OH-] and pOH of the solution.
4) A sample of baking soda was dissolved in water and the pOH of the solution was
found to be 5.81.
5) The pH of an aspirin solution is 2.37. What is the [H3O+], and [OH-] of the solution.
6) If the [H3O+] of a 0.53 mol/l solution of a weak acid is 4.5 * 10 -5 mol/l what is the
pH of the solution?
Calculating pH
pH = -log [H+]
Calculating pOH
POH = -log [OH-]
[H+] = 10 –pH
Calculating the [OH-] from the pOH value. (Must know [OH-])
[OH-] = 10 –pOH
pH + pOH = 14
Classify each as acidic or basic. Give the [H+] for the acid
solutions and give the [OH-] for the basic solutions.
a. pH = 9.0
b. pH = 11.4
c. pH = 4.0
d. pH = 1.5
Kw, pH, pOH review Assignment
(Turn sideways to View properly)
Arrhenius Acids and Bases
The Arrhenius definition of acids and bases is one of the oldest. An
Arrhenius acid is a substance that when added to water increases the
concentration of H1+ ions present. The chemical formulas of Arrhenius acids
are written with the acidic hydrogens first. An Arrhenius base is a substance
that when added to water increases the concentration of OH1- ions present.
HCl is an example of an Arrhenius acid and NaOH is an example of an
Arrhenius base.
b. diprotic acid
c. triprotic acid
The acids on this short list are called strong acids, because the amount of acid
quality of a solution depends upon the concentration of ionized hydrogens. You
are not likely to see much HBr or HI in the lab because they are expensive. You
are not likely to see perchloric acid because it can explode if not treated carefully.
Other acids are incompletely ionized, existing mostly as the unionized form.
Incompletely ionized acids are called weak acids, because there is a smaller
concentration of ionized hydrogens available in the solution. Do not confuse this
terminology with the concentration of acids. The differences in concentration of
the entire acid will be termed dilute or concentrated.
Strong Bases:
Likewise, there is a short list of strong bases, ones that completely ionize into
hydroxide ions and a conjugate acid. All of the bases of Group I and Group II
metals except for beryllium are strong bases. Lithium, rubidium and cesium
hydroxides are not often used in the lab because they are expensive. The bases
of Group II metals, magnesium, calcium, barium, and strontium are strong, but
all of these bases have somewhat limited solubility. Magnesium hydroxide
has a particularly small solubility. Potassium and sodium hydroxides both
have the common name of lye. Soda lye (NaOH) and potash lye (KOH) are
common names to distinguish the two compounds.
The strong acids will give more H+ ions in solution. Since it has a single
arrow in its equation, it shows that reactants are transformed into products.
With weak acids, the double arrow indicates an equilibrium system.
Therefore, there is an appreciable amount of both reactants and products.
There is not a complete transformation to products.
The above are the only strong acids. However, in every acid-base reaction,
there is a stronger and weaker acid. For example, when the reaction
contains 2 weak acids, one of the acids is a stronger acid and one is the
weaker acid.
To this point, we have mostly been using strong acids and bases in
our kw, pH, pOH calculations. Why?
Writing Ka expressions
WEAK ACIDS AND WEAK BASES
We can write the chemical equation for the dissociation of a weak acid, using 'A-' to
represent the conjugate base, as;
HA Í==Î A- + H+
And, similarly, we can write the chemical equation for the dissociation of a weak base,
using 'X+' to represent the conjugate acid, as;
The equilibrium expression for the dissociation of a weak acid is; Note, weak acids and
bases are equilibriums, like we dealt with in our other unit. The Ka is very similar to the
Keq
Write balanced ionization equations (1 ionization) and Ka expressions for these acids in
water.
a) H3PO4 b) C6H5COOH
c) HSO4- d) HCOOH
equation Ka expression
a) a)
b) b)
c) c)
d) d)
Calculating Ka (for weak acids)
1) A student prepared a 0.10 M solution of formic acid, HCHO2 (aq). Its pH
was determined to be 2.38 at 25 oC. Calculate the Ka for this acid at this
temperature.
Notice that we have written explicitly in these reactions. The reason is that
acid/base dissociation occurs by a proton transfer reaction from an acid species to a
specific water molecule. The transfer occurs through a hydrogen bond between the acid
molecule and a solvating water molecule. (remember chem..11)
Here, CH3COOH is a BL acid because it can donate a proton, and CH3COO its
conjugate base because it can accept a proton. Note that H2O and H3O+ also form such a
conjugate pair.
Note that the rather than has been used to denote the nature of ions in
water in the above reaction.
Here, NH3 is the BL base and its conjugate acid is NH4+ . Similarly, H2O acts as a BL
acid and OH- acts as a BL base.
An interesting ambiguity comes up within the BL definition, namely, that some species
can act either as a BL acid or a BL base. Such beasts are called amphoteric. An
example is the hydrogen carbonate ion, HCO . When dissolved in water, two posible
reaction can occur:
or
In the first of these, HCO3- acts as a BL acid with CO32- as its conjugate base, while in
the second it acts as a BL base with H2CO3 as its conjugate acid.
Bronsted Lowry definition of acids and bases:
PartA: Definition
Examples:
HCl + H2O -----Æ H3O+ + Cl-
Write down the identity of the acid and base for the forward reaction?
Write down the identity of the acid and base for the reverse reaction?
Note:
The acid on the left, after donating the H+ to the acceptor, becomes the base
on the right.
In summary:
Activity:
Label the acid, base, con. Acid, con. Base and list the acid base pairs
Review:
HCl + H2O ---Æ H3O+ + Cl- Label acid, base, con. acid, con. base
Note to memorize:
Why?
Note:
Example
H3O+ + HS- -----Æ H2S + H2O
Sa sb wa wb
Part E:
The extent of a bronsted acid-base reaction (position are equilibrium)
depends upon the relative strengths of the acids involved.
Note:
____________________________________________________________
The Summary: The five Key points to remember:
Examine the following reactant molecules and ions in aqueous Example;
Complete the reactions, label the acid, base, conjugate acid, conjugate base
and the acid / pairs
B. NH4 + + Cl - +
C. HSO3 - + PO43- +
D. H2S + NO3 - +
E. H3O + + CN- +
a)
b)
c)
d)
Bronsted / Lowry Theory:
1. A. HIO3 (aq) + HCO3-(aq) <===Î H2CO3(aq) + IO3-(aq)
Using this acid-base theory, determine
a. the acid
b. the base
c. the conjugate acid
d. the conjugate base
While the Arrenhius theory of acids and bases does not apply to the autoionization of
ammonia, the bronsted Lowry theory of acids and bases applies quite well.
A. Explain why the arrhenius theory of acids and bases does not apply to
the autoionization of ammonia.
B. Explain how the bronsted/lowry theory of acids and bases does apply
to the autoionization of ammonia. Include in you answer, both
conjugate acid and base pairs.
B. Using the structure below, explain why PFOA has a low solubility in
water.
F F F F F F F O
F -C - C - C - C – C- C - C -C - OH
F F F F F F F F
C. Does the low solubility of PFOA in water give you any information
about the strength of the acid? Explain?
Calculating the Keq for general Bronsted acid – base reaction
To find the Keq for this reaction: That is to find the Keq equilibrium constant for any
acid / base reaction. Remember this formula for the exam
Keq = Ka HF =
Ka HCN
This keq can obtained by using Ka’s, given to you or found in tables on acids
Ka HX = 5.0 x 10 -5
Ka HCN = 4.8 x 10 -10
HF (Ka = 6.6 x 10-4) and HCN (Ka = 6.2 x 10- 10)are two weak
acids that appear in this equilibrium.
A) We started 1st with the operational definition of acids and bases. This was the
original concept of acids and bases, only based upon what you can see; the operational
definition.
D) Lewis Acids –
A Lewis acid accepts an electron pair forming a covalent bond.
Lewis acids and bases
The most general definition of acids and bases, which encompasses the
Arrhenius and Bronsted-Lowry definitions is due to our old friend, Lewis
and his dot structures. A Lewis acid is defined to be any species that accepts
lone pair electrons. A Lewis base is any species that donates lone pair
electrons. Thus, is a Lewis acid, since it can accept a lone pair, while
and NH are Lewis bases, both of which donate a lone pair:
In fact octet deficient molecules are often strong Lewis acids because they
can achieve an octet configuration by accepting a lone pair from a Lewis
base. Compounds involving elements in periods lower then the second
period can act as Lewis acids as well by expanding their valence shells.
Thus, SnCl acts as a Lewis acid according to the reaction:
Amphiprotic Substances:
Some metallic hydroxides can neutralize both acids and bases, and in doing
so are acting as both an acid and a base.
Examples:
Note:
A neutral solution results from a neutralization reaction if the acid and base
are combined in the mole ratios as specified by the balanced equation and
provided that there are no other ions present that would reaction with the
water itself to from H+ or OH-. This would throw off the balance of H+ =
OH- equality of a neutral solution.
Sample
Summary:
We use the balanced chemical equation to find the chemical amount of the
other species in the equation.
Neutralization problems:
1. How many moles of HNO3 is needed to neutralize 0.20 moles of NaOH?
2. How many moles of sulfuric acid, H2SO4, are required to neutralize 0.87
moles of sodium hydroxide?
Exam Prep:
A) How many more times more acidic than normal rain (5.6) if
the pH of the acid rain is 4.2.
Background Notes:
An acid base indicator is a complex organic substance that is a weak acid.
It is represented by the acid-base pair Hln, ln-.
The molecular species Hln and the anion ln- have different colors.
The relative concentrations of Hln and ln- determines the color.
To illustrate: consider that Hln is red and ln- is blue; also suppose Ka for the
indicator is 1.0 x 10 –8.
If H+ ions are added to the system, the system will shift to relieve the stress
by producing more HIn, by making H+ react with In- thus changing the color
of the solution to red
If OH- is added, the equilibrium shifts to from more ln- and eventually [Hln] and
[ln-] approach equality, giving a transition color which usually spans about 2 pH
units.
(The OH- reacts with the H+ producing H2O. This reduces the [H+], causing it to
shift to the product side of the equation.)
If more OH- is added, [ln-] increases until the color of ln- dominates. When this
product is favored, the color is blue, indicating a base.
Note:
Please keep this in mind when we start to discuss titrations, an application
of neutralization stoichiometry.
Key: Choose an indicator that has a transition color which has the same pH
as the endpoint of the titration. You want the indicator to change color
when there is stoichiometric equivalence!
For example:
If a titration has an endpoint at a pH of 6.1, which indicator would you use?
3)
Is enough info given to find out how much of the other reactant was
neutralized?
It is not necessary to start the titration with the known liquid level in the buret at
the zero mark, but the level must be within the portion of the buret that is marked.
The buret on the left shows about 1.8 ml of the yellow liquid in it. Most
laboratory burets can be read to an accuracy of one hundredth of a milliliter. (The
drawing on the left is a bit crude. Most burets show the ten divisions of a
milliliter and you can interpolate between the marks.) One reads the buret by
getting at eye level to the bottom of the meniscus (curve in the liquid) and
comparing the bottom of the meniscus to the marks on the glass. A reading of the
buret is taken before and at the end of the titration. The amount of know-
concentration liquid used is the difference of the beginning and ending buret
reading.
However, if you used Methyl orange, you would see an experimental endpoint at pH=3.
Note: Make sure the indicator matches the pH endpoint.
Indicator:
Weak Acid
Weak base
Indicator
The Hydrolysis of Salts
A salt solution may be basic, acidic or neutral based on three different
situations. When dealing with a solution, people will often forget about the
H2O present is the solution.
Situation 1:
A salt solution is basic if it contains an anion that is sufficiently strong base
to remove a proton (H+) from water, giving OH-
Example:
Situation 2:
A salt solution is acidic if it contains a cation that donates a proton to water,
giving H3O+.
Ex. Hydrated cations such as
Note: The principle from before that a Bronsted acid will donate a proton
to any base whose conjugate acid is weaker than the donar acid.
Hydrolysis Generalizations:
A) Salt containing an anion that does hydrolyse and a cation that does
not, gives a solution that is basic.
B) Salt containing an anion that does not hydrolyse and a cation that
does, gives a solution that is acidic.
C) Salt containing neither an anion nor cation that hydrolyses, gives a
solution that is neutral
D) Salt containing an anion and cation which both hydolyse gives a
solution which is an acid or a base depending on which hydrolyses to
the greater extent. The solution is neutral if both ions hydrolyse to
the same extent.
Activity:
A “salt solution” may be acidic, basic or neutral
NaCO3 (aq)
CuSO4 (aq)
1) 20.0 ml of NaOH is needed to reach the endpoint with 15.0 ml of 0.10M
H2SO4. Find the concentration of the NaOH solution
2)
It requires 75.0 ml 0.0500 mol/L NaOH (aq) to neutralize 200.0 ml of gastric
juice. We can assume that HCl (aq) is the only acid in gastric juice.
c. Ideally the [HOCl] = [OCl-] in the pool. To what pH should the pool be
adjusted so that this will be true?