31.

In the reaction : 2Al(s) + 6HCl(aq) ¾¾ 3+

® 2Al(aq) + 6C l (aq)+ 3H2(g)
(A) 6L HCL(aq) is consumed for every 3L H2 produced.
(B) 33.6 mL H2(g) is produced regardless of temperature and pressure for every mole Al that
reacts.
(C) 67.2 L H2(g) at STP is produced for every mole Al that reacts.
(D) 11.2 L H2(g) at STP is produced for every mole HCl(aq) consumed.

32. The density of a solution prepared by dissolving 120g of urea (mol×mass = 60 u) in 1000g of
water is 1.15 g/mL the molality of the solution is :
(A) 0.50 M (B) 1.78 M (C) 1.02 M (D) 2.05 M
33. Equal masses of H2, O2 and methane have been taken in a container of volume V at
temperature 27°C in identical conditions. The ratio of the volumes of gases H2 : O2 : methane
would be -
(A) 8 : 16 : 1 (B) 16 : 8 : 1 (C) 16 : 1 : 2 (D) 8 : 1 : 2
34. The most abundant elements by mass in the body of a healthy human adult are : Oxygen
(61.4 %); Carbon (22.9 %); Hydrogen (10.0 %) and Nitrogen (2.6 %). The weight which a 75 kg
person would gain if all 1H atoms are replaced by 2H atoms is ......
(A) 15 kg (B) 37.5 kg (C) 7.5 kg (D) 10 kg
35. If uncertainty in position and momentum are equal, then uncertainty in velocity is
1 h 1 h h h
(A) (B) (C) (D)
2m p m p 2p p
æ Z2 ö
36. Energy of an electron is given by E = –2.178 × 10–18J çè 2 ÷ø Wavelength of light required to
n
excite an electron in a hydrogen atom from level n = 1 to n = 2 will be...
(h = 6.62 ´ 10–34 Js, c = 3.0 ´ 108 ms–1)
(A) 1.214 × 10–7m (B) 2.816 × 10–7m (C) 6.500 × 10–7m (D) 8.500 × 10–7m
æ Z2 ö
37. Based on equation E = –2.178 ´ 10 –15 J ç 2 ÷ certain conclusion are written. Which of
èn ø
them is not correct ? n = 3, l = 1 and m = 0
(A) Larger the value of n, the larger is the orbit radius.
(B) Equation can be used to calculate the change in energy when the electron changes orbit.
(C) For n = 1, the electron has a more negative energy than it does for n = 6 which means that
the electron is more loosely bound in the smallest allowed orbit.
(D) The negative sign in equation simply means that the energy of electron bound to the nucleus
is lower than it would be if the electrons were at the infinite distance from the nucleus.
38. The group having isoelectronic species is ......
(A) O2–, F–, Na+, Mg2+ (B) O–, F–, Na, Mg+ (C) O2–, F–, Na, Mg2+ (D) O–, F–, Na+, Mg2+

39. If Z is a compressibility factor, Van der Waals equation at low pressure can be written as :
Pb Pb RT a
(A) Z = 1 – (B) Z = 1 + (C) Z = 1 + (D) Z = 1 –
RT RT Pb VRT
40. Two closed bulbs of equal volume(V) containing an ideal gas initially at pressure pi and
temperature T1 are connected through a narrow tube of negligible volume as shown in the
figure below. The temperature of one of the bulbs is then raised to T2. The final pressure pf
is :

æ TT ö
(B) pi ç 1 2 ÷
 i
temperature T1 are connected through a narrow tube of negligible volume as shown in the
figure below. The temperature of one of the bulbs is then raised to T2. The final pressure pf
is :
T1T2
(A) pi ç T1 T1 T1 T2
è T1 + T2 ÷ø
pi, V pi, V pf, V pf, V

æ TT ö
(B) pi ç 1 2 ÷
è T1 + T2 ø

æ T1 ö
(C) 2pi ç
è T1 + T2 ÷ø
æ T2 ö
(D) 2pi ç
è T1 + T2 ÷ø
41. What will be the change in enthalpy (DH) for endothermic reaction ?
(A) Zero (B) –ve (C) +ve (D) (B) and (C) both
42. Combustion enthalpy of carbon, Hydrogen and Methane at 25°C temperature are –395.5 KJ mol–
1, –284.8 KJ mol–1 and –890.4 KJ mol–1 respectively. Calculate the standard enthalpy of formation

of methane for the same temperature.

(A) 890.4 KJ mol–1 (B) –298.8 KJ mol–1 (C) –74.7 KJ mol–1 (D) –107.7 KJ mol–1
43. For the spontaneous reaction at each temperature .......... .
(A) DG –ve; DH +ve and DS +ve (B) DG +ve; DH –ve and DS +ve
(C) DG –ve; DH –ve and DS –ve (D) DG –ve; DH –ve and DS +ve
44. For complete combustion of ethanol, C2H5OH(l) + 3O2(g) ® 2CO2(g) + 3H2O(l), the amount of
heat produced as measured in bomb calorimeter is 1364.47 kJ mol–1 at 25ºC. Assuming
ideality the Enthalpy of combustion, DcH, for the reaction will be : (R = 8.314 kJ mol–1)
(A) –1460.50 kJ mol–1 (B) –1350.50 kJ mol–1 (C) –1366.95 kJ mol–1 (D) –1361.95 kJ mol–1
45. The following reaction is performed at 298 K. 2NO(g) + O2(g) ƒ 2NO2(g)
The standard free energy of formation of NO(g) is 86.6 kJ / mol at 298 K. What is the
standard free energy of formation of NO2(g) at 298 K ? (Kp = 1.6 ´ 1012)
(A) R (298) ln (1.6 ´ 1012) – 86600 (B) 86600 + R (298) ln (1.6 ´ 1012)
ln (1.6 ´ 1012 )
(C) 86600 – (D) 0.5 [2 ´ 86600 – R (298) ln (1.6 ´ 1012)]
R (298)
46. For a sample of perfect gas when its pressure is changed isothermally from Pi to Pf the entropy
change is given by
æ Pf ö æ Pi ö æ Pf ö æ Pi ö
(A) DS = nRT ln ç ÷ (B) DS = RT ln ç P ÷ (C) DS = nR ln ç ÷ (D) DS = nR ln ç ÷
è Pi ø è fø è Pi ø è Pf ø
47. For the following three reactions (i), (ii) and (iii) equilibrium constants are given
ˆˆ†
(i) CO(g) + H2O(g) ‡ˆˆ CO ˆˆ†
O2(g) + H2(g); K1(ii) CO4(g) + H2O(g) ‡ˆˆ CO
O(g) + 3H2(g); K2
ˆˆ†
(iii) CO4(g) + 2H2O(g) ‡ˆˆ CO2(g) + 4H2(g); K3 Which of the following relation is correct ?
(A) K3 · K 32 = K12
(B) K1 K 2 = K3
(C) K2K3 = K1
(D) K3 = K1K2 From equations (1), (2) and (3) ; K3 = K1 ´ K2
1
48. For the reaction SO2(g) + O ƒ SO3(g), if KP = KC (RT))x, where the symbols have usual
2 2(g)
meaning then the value of x is : (assuming ideality)
1 1
(A) (B) 1 (C) –1 (D) –
2 2
49. Aqueous solution of which of the following compounds is the best conductor of electric
current ?
(A) Ammonia, NH3 (B) Fructose, C6H12O6
(C) Acetic acid, C2H4O2 (D) Hydrochloric acid, HCl
 Aqueous solution of which of the following compounds is the best conductor of electric
current ?
(A) Ammonia, NH3 (B) Fructose, C6H12O6
(C) Acetic acid, C2H4O2 (D) Hydrochloric acid, HCl
50. Consider the following liquid - vapour equilibrium. Liquid ƒ Vapour Which of the following
relations is correct ?
dlnP DH V dlnP DH V dlnP D H V d lnG DH V
(A) =– (B) 2
=- 2 (C) = (D) 2
=
dT RT dT T dT RT 2 dT RT 2
51. For the reaction N2(g) + 3H2(g) ƒ 2NH3(g), the standard equilibrium constant Kp is 5.8 × 105 at
298 K temperature. If the concentration of gases indicate by mol L–1 then find the value of
standard equilibrium constant from the following. (R = 0.08314 L bar K–1 mol–1)
(A) 3.5 × 106 (B) 3.8 × 107 (C) 3.56 × 10+8 (D) 3.99 × 109
Kp
52. The is equal to which of the following in given reaction ? Reaction
Kc
CO(g) + Cl2(g) ƒ COCl2(g)
1
(A) (B) RT (C) RT (D) (RT)2
RT
53. The pKa and pKb of one weak acid (HA) and weak base (BOH) are 3.2 and 3.4 respectively.
Find pH of its salt AB.
(A) 7.2 (B) 6.9 (C) 7.9 (D) 1.0
54. The more positive the value of E d– , the greater is the tendency of the species to get reduced.
Using the standard electrode potential of redox couples given below find out which of the
following is the strongest oxidising agent ?
d
– d
–
E = +0.77 volt ; E = +0.54 volt
Fe+3 /Fe+2 I2 /I–
d
– d–
E = +0.34 volt ; E + = +0.80 volt
Cu+2 /Cu Ag / Ag
(A) Fe+3 (B) I2(s) (C) Cu+2 (D) Ag+

55. E values of some redox couples are given below, On the basis of these values choose the
correct option.
d
– d
–
E – = +1.90 volt ; E + = +0.80 volt
Br2 /Br Ag /Ag(s)
d
– d–
E +2 = +0.34 volt ; E = +0.54 volt
Cu /Cu(s) I2(s)/I –
(A) Cu will reduced Br– (B) Cu will reduced Ag
(C) Cu will reduced I– (D) Cu will reduced Br2
56. Thiosulphate reacts differently with iodine and bromine in the reactions given below
2S2O3–2 + I2 ¾® S4O6–2 + 2I–
2S2O3–2 + 2Br2 + 5H2O ¾® 2SO4–2 + 2Br– + 10H+
Which of the following statements justifies the above dual behaviour of thiosulphate ?
(A) Bromine is stronger oxidants than iodine.
(B) Bromine is weaker oxidant than iodine.
(C) Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions.
(D) Bromine undergoes oxidation and iodine undergoes reduction in these reactions.
57. The oxidation number of an element in a compound is evaluated on the basis of certain rules.
Which of the following is incorrect in this respect ?
(A) The oxidation number of hydrogen is always +1.
(B) The algebraic sum of the all the oxidation numbers in a compound is zero.
(C) An element in the free or the uncombined state bears oxidation number zero.
(D) In all its compounds, the oxidation number of fluorine is –1.
58. Identify disproportionation reaction.
(A) CH4 + 2O2 ¾® CO2 + 2H2O (B) CH4 + 4Cl2 ¾® CCl4 + 4HCl
(C) 2F2 + 2OH– ¾® 2F– + OF2 + H2O (D) 2NO2 + 2OH– ¾® NO2– + NO3– + H2O

59. Which one of the following statements about water is FALSE ?

(A) Ice formed by heavy water sinks in normal water.
(B) Water is oxidized to oxygen during photosynthesis.
(C) Water can act both as an acid and as a base.
(D) There is extensive intramolecular hydrogen bonding in the condensed phase.

60. Hydrogen peroxide oxidises [Fe(CN)6]4– to [Fe(CN)6]3– in acidic medium but reduces
[Fe(CN)6]3– to [Fe(CN)6]4– in alkaline medium. The other products formed are, respectively.
(A) (H2O + O2) and H2O (B) (H2O + O2) and (H2O + OH–)
(C) H2O and (H2O + O2) (D) H2O and (H2O + OH–)