SKIMA KIMIA TINGKATAN 4

PEPERIKSAAN PERTENGAHAN TAHUN 2019

Question Answer Submark

1(a) (i) Nucleon number = total number of proton and neutron in 1 2

an atom.

Proton number = number of proton in nucleus an atom 1

(ii) Electron 1 1

(iii) 1.S and T 1 2

2.Atom of the same element with same proton number
but different nucleon number/number of neutron 1
(iv)

1 1

(v) 1 1

(b) (i) 6 1 1
(ii) Isotope 1 1
(iii) Carbon-14 1 1
(iv) Fosforus-32 = to detect the absorption rate of 1 1
phosphate
fertilizers by plants

Kobalt -60 = for cancer treatment

Uranium -235 = nuclear power

TOTAL 10

2 Question Answer Submark

(a) (i) Chlorine 1 1

(ii) Sodium 1 1
(b) Chlorine 1 1
(c) Makes diodes/ transistor/ simiconductor 1
1 2
(d) (i) 2.8.2 1 1
(ii) 2.8.7 1
1 2
(e) The number of proton imcrease/the charge of 1
nuclueus increase
The attraction force between nuclueus and 1 2
valence electron increases

TOTAL 10
Question Answer Submark

3(a) (i) 1. Lime water turns cloudy 1 2

2. Green solid turns to black 1

(ii) Carbon dioxide gas 1 1

(b)(i) CuCO3 CuO + CO2 1 2

1
(ii) 1 mole of copper(II) carbonate solid decompose 1 1
produce 1 mole of copper(II)oxide solid and 1 mole
of carbon dioxide gas
(iii) 6.4g/ 124 = 0.05 mole 1 1
3 3
Volume of gas = 0.05 mole X 24dm = 1.2 dm
(c) (i) C is carbon 1 1
(ii) Empirical formula is a chemical formula that shows the 1 1
simplest ratio of whole number of atoms of each
element in a compound.
TOTAL 10

4 Question Answer Submark

(a) Tenaga elektrik → tenaga kimia 1 1

(b) Cu2+, Cl-, OH-, H+ 1 1
(c) (i) Gas oksigen 1 1
(ii) Masukkan kayu uji berbara ke dalam tabung uji 1
yang mengandungi gas oksigen, kayu uiji 1 2
berbara menyala
(d) (i) Elektrod P menipis/terhakis 1 1
(ii) Elektrod P menyahcas, 1
ion Cu2+ terhasil 1 2
(iii) Cu→ Cu2+ + 2e- 1 1
(e) Logam Argentum, elektrolit Agentum klorida 1 1
TOTAL 10
 Question Answer Marks Total
5. a) (i) Sodium carbonate solution / kalium carbonate solution// 1
ammonium carbonate solution 2
Zinc nitrate solution // zinc sulphate solution // zinc chloride 1
solution
or any suitable solution of zinc.
(ii) Double decomposition reaction // precipitation reaction 1 1

(iii) Zn2+ + CO32- ZnCO3 1 1

(iv) Heat zinc carbonate solid strongly 1
Channel the gas produced into lime water 1
Lime water turns cloudy 1 3
b) (i) Magnesium // aluminium 1 1
(ii) White precipitate formed 1
Then dissolved in excess ammonia aqueous 1 2
Total marks 10

Question Answer Mark Total

6 (a) (i) Alkene 1
(ii) C3H8 1 2
(b) (i) Hydroxyl 1
(ii)
H H H
1
H C C C H 2

H H OH

(c) (i) Hydration 1

(ii) C3H6 + H2O → C3H7OH

 Correct formulae of reactants 1 3

 Correct formulae of products 1

(d) Propane = C3H8 Propene = C3H6

%C = x 100 %C = x 1+1
 100 3

= 81.81 % = 85.71 % 1

Propene produce more soot than propane because the

percentage of carbon by mass is higher

Total 10

QUESTION RUBRIC MARK TOTAL

NO S MARKS
7 (a) 1. No of mol in 18.25g hydrogen chloride = 18.25/ 36.5 // 0.5 1
mol
2. Volume = 0.5 mol x 24dm3 // 12dm3 1
3. no of mol in 8.5g of ammonia = 8.5g / 17 // 0.5mol 1
4. Volume = 0.5 x 24dm3 // 12dm3 1 4

(b) Able to determine the empirical formula and molecular

formula of caffeine correctly

element C H N O
1 Mass/g 0.48 0.05 0.28 0.16 1
2 number 0.48/12 // 0.05/1 0.28/14 0.16/16
of mol 0.04 // 0.05 // 0.02 //0.01 1
3 Simplest 0.04/0.01 0.05/0.01 0.02/0.01 0.01/0.01
ratio // 4 //5 // 2 //1 1

4. Empirical formula = C4H5N2O 1

5. [C4H5N2O]n = 194 1
6. [97]n = 194 1
7. n = 194/97 // 2 1
8. molecular formula = C8H10N4O2 1 8

(c) (i) Able to suggest metal P, Solution Q, Substance R and metal

S correctly

Answer:
1. Metal P - Magnesium // Aluminium // Zinc 1
2. Solution Q - Any acid [hydrochloric acid//sulphuric 1
acid]
3. Substance R - Anhydrous calcium chloride 1
4. Metal S - Copper (II) oxide // lead (II) oxide // 1 4
silver oxide // Iron(II) oxide

(ii) Able to write the chemical equation and balanced the

equation

1. Correct all chemical formula

2. Balanced the equation

Sample answer:
 CuO + H2 CuO + H2O
1+1 2
(d) 1. No 1
2. Because the reactivity of magnesium is higher than 1 2
hydrogen.

Total 20

QUESTION RUBRIC MARK TOTAL

NO S MARKS
8 (a) 1.A Acid is Hyrochloric acid // Nitric acid 1
2. B Acid is Ethanoic acid
3. A acid is a strong acid 1
4. B acid is a weak acid
1
5. Strong acid ionises completely in water produce higher
concentration of hydrogen ion while weak acid ionizes 1
partially in water produce lower ions concentration of
hydrogen 1
6. The higher the concentration of hydrogen ions, the lower 1
the pH value.

1 7

(b) 1.Vinegar 1
2. Vinegar is acidic properties which able neutralize the stung
of jelly fish 1

3. Vinegar is weak acid which is mild to skin// any reasonable

answer. 1 3

(c) 1. Water is present in test tube X but in test tube Y there is no 1

water.
2. Water helps ammonia to ionise // ammonia ionise in water 1

3. OH-ion present 1

4. OH- ion causes ammonia to show its alkaline properties

5. Without water ammonia exist as molecule // without water 1

OH- ion does not present

6. When OH- ion does not present, ammonia cannot show its 1 6
alkaline properties
 (d) Diprotic acid : sulphuric Acid 1

Monoprotic acid: Hydrochloric acid// Nitric acid 1

Diprotic acid: 1 mole of acid ionizes in water produce 2 mole 1

of hydrogen ion

Monoprotic acid: 1 mole of acid ionizes inwater produce 1 1 4

mole of hydrogen ion.
Total 20

9 (a) Sebagai mangkin 1 1

(b) Zn + 2HCl → ZnCl2 + H2 2 2
(c) Dengan kehadiran mangkin;
T/b melalui satu laluan alternative di mana tenaga 1
pengaktifannya lebih rendah
Lebih banyak perlanggaran yang boleh mencapai tenaga 1
pengaktifan yang rendah
Frekuensi perlanggaran meningkat, frekuensi perlanggaran 1 3
berkesan meningkat
(d) Set I = 0.1667 cm3s-1 1
Set II= 0.50 cm3s-1 1 2
(e) * ada perbezaan tenaga pengaktifan pada set I dan II (mangkin) 1
*label bahan dan hasil pada rajah profil tenaga 1 2
(f) Materials;
0.2 mol dm-3 sodium thiosulphate, Na2S2O3 solution, 1.0 mol dm- 1
3
sulphuric acid, water, a piece of white paper marked ‘X’ at the
centre
Apparatus; 1 2
150 cm3 conical flask, stopwatch, 50cm3 measuring cylinder,
thermometer, Bunsen burner, wire gauze
Procedure; 1
1. Using a measuring cylinder, 50cm3 of 0.2 mol dm-3
sodium thiosulphate solution is measured and poured 1
into a conical flask
2. The conical flask is place on top of a piece of white 1
paper marked at the centre.
3. 5 cm3 of 1.0 mol dm-3 sulphuric acid is measured using 1
another measuring cylinder.
4. The sulphuric acid is poured immediately and carefully 1
into the conical flask. At the same time the stopwatch is 1
started. 1
5. The mixture in the conical flask is swirled 1
6. The ‘X’ marked is observed vertically from the top of the
conical flask through the solution. 1
7. The stopwatch is stopped once the ‘X’ marked Max:7 7
disappears from view
8. Step 1-7 are repeated by adding 5cm3, 10cm3, 15cm3, 1 1
20 cm3 and 40 cm3 of distilled water
Conclusion;
The increase of concentration, increase the rate of reaction.
 TOTAL 20

Question Answer Marks Total

10 a) (i) Molar mass of CnH2n+2 = 86

n(12) + (2n +2)(1) = 86

14n = 84
n =6 1

(ii) Molecular formula of Q is C6H14 1

P is an unsaturated hydrocarbon // contains double bond 1

between carbon atoms (C=C)
P undergoes reaction. 1

Q is a saturated hydrocarbon // contains single bond 1

between carbon atoms (C-C)
No reaction. 1 6

b)

2+2

Any Two correct

c) (i) Name of alcohol 1

Name of alkene 1 2

(ii) 1. Place glass wool in a boiling tube 1

2. Add a few drops of alcohol to the glass wool 1
3. Clamp the boiling tube horizontally 1
4. Place a porcelain in the middle of the boiling tube 1
5. Heat the alcohol / glass wool. 1
6. Collect the gas produced in a test tube 1
1
7. Functional diagram 1
8. Label : Glass wool damped with alcohol, porcelain chips,
water, heat 1 Max
9. Balanced Equation 8

Total marks 20