Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
1xxx 99%+ Al O
2xxx Cu 2: ¼ hard
annealed
3xxx Mn 4: ½ hard
(wrought only)
4xxx Si 6: ¾ hard
5xxx Mg 8: Hard
6xxx Mg+Si 9: Extra hard
7xxx Zn F
8xxx Li (etc.) as fabricated
1: Partial solution & natural ageing
2: Annealed cast products
3: Solution & cold-work
T
4: Solution & natural ageing
Changes denote heat-treated
5: Artificial ageing only
distinct alloys
6: Solution & artificial ageing
Changes denote minor variants 7: Solution & stabilising
8: Solution & cold-work & artificial ageing
[except 1xxx: xxx denotes purity level] 9: Solution & artificial ageing & cold-work
700
1 - Hold at ~550ºC till all Mg is in solution
Liquid
600
α+L 2 – Quench to room temperature.
500 α
Mg is now in supersaturated solution
Temperature (ºC)
120
200
80
100 40
2 0
0 0 1 2 3 4 5 6
0 10 20 30 40 wt% Mg
Al Weight% Mg β (Mg5Al8) 3 – (possibly) Work-harden
1.8%
Portsmouth – Cherbourg fast ferry (5005 is now “old tech” for this – similar low
Launched 1998, 91m length, Mg, Fe, Cu alloys with higher conductivity
5900 tonnes gross wt., 41 knots now used)
Engineering “C” – High Perfomance Alloys: HT 2000 S.G. Roberts 3: 5
Al – Cu alloys – “2000” series
700
Liquid
600 α+L
α
500
Temperature (ºC)
400
α+θ
300
200
100 θ (CuAl2)
0
0 10 20 30 40 50 60
Al Weight% Cu
700
Liquid 1 - Hold at ~550ºC till all Cu is in solution
600 α+L
α 1 2 – Quench to room temperature.
200 3
Results:
σY UTS εF
MPa) (MPa) (%)
“Duralumin” 3.5 Cu 275 425 22 The original age hardening alloy. Now
0.5 Mg, 0.5 Mn used for rivets, etc (2017).
2014 4.4 Cu 320 425 13 The “standard” Al-Cu alloy.
0.5 Mg, 0.5 Mn Aircraft structures, automotive, etc.
0.9 Si
2219 6.3 Cu 290 - 415 - 10 Good creep strength: high temperature
0.3 Mn, 0.2 Si 390 475 applications.
0.1 Ti,Zn,V,Zr Good cryogenic strength (liquid gas tanks
for spacecraft)
This is alleviated by
• Zn:Mg ratio of 3:1
• addition of Mg and Cu (etc.),
• control of Si, Fe and other impurities
• complex, multi-stage heat treatments
100 µm
σY UTS εF
MPa) (MPa) (%)
7075 Zn 5.6 500 570 11 High strength alloy: aerospace structural parts.
Mg 2.5 Various choices of heat treatments to “emphasise”
Cu 1.6 weldability, SCC resistance, machinability.
Cr 0.2 Typical (“T73 temper”): quench, age at:
120ºC (form G.P. zones), then
170ºC (form η` - MgZn2 ppts.)
(7475 is high purity variant – better SCC)
(4 in each aircraft!)
Engineering “C” – High Perfomance Alloys: HT 2000 S.G. Roberts 3: 12
Al – Li alloys – “8000” series
Rationale: T(ºC) Liq.
• Li is light – density 540 kg m-3 600
• Reduces alloy density by 1% for each 1% Li α δ
• Li dissolves up to 14% in Al at high T 400
• Solubility drops at lower temps α+δ
Al3Li
• Can harden via the metastable δ` phase Al3Li –
though this only has low strains around it. 200
• Li has big size difference: good solid soln. α + δ`
strengthener
• Li raises E of alloy: 10%Li gives 20% boost in E 0
0 10(w) 20(w)
30(at) 50(at)
Problems ?
• Li oxidises rapidly – needs careful handling
• Severe gravity segregation during casting
• Na, K, present as impurities form low m.p. phases
• grain boundary failures
• Simple Al-Li binary alloys have poor properties
• cutting of δ` ppts ⇒ planar slip ⇒ low ductility
• Overaging gives precipitation of δ phase at grain
boundaries
• High cost – about 2-3x conventional alloys Al-Li-Zr
Typical alloy:
“8090”: 2.5%Li, 1.3%Cu, 1.0%Mg, 0.1%Zr.
(number in brackets are for “competitor” alloy 7475) 7475 26 220 3.1 9.0 1.5 3.1
1989 Prediction:
“The purchase price of the lithium-containing alloys is expected
to be two to three times that of the existing high-strength
aluminium alloys.
Al Mn Zn Zr Th RE$
State σy UTS εF Notes
(%) (%) (%) (%) (%) (%) (MPa) (MPa) (%)
*Typical heat treatment: Soln. treat: 380 - 410ºC / 16hr. Quench, pptn harden 180 – 200 ºC / 10hr.
$Ce, La, Nd, Pr – “Misch metal”
Extrusion alloys have similar compositions but with slightly lower alloy additions (esp. Zn)
Engineering “C” – High Perfomance Alloys: HT 2000 S.G. Roberts 3: 18
Microstructures and Macrostructures
µm
20µ
Optical micrograph:
Mg-Zn-Zr-(RE) alloy,
cast and aged (no
soln treatment).
Mg-Zr-Zn-(RE) helicopter
gearbox casing
Electron micrograph:
Mg-Nd-Zr alloy, cast,
soln treated and
aged to peak
hardness.
http://www.timet.com/index.html http://www.titanium.org/background.htm
Engineering “C” – High Perfomance Alloys: HT 2000 S.G. Roberts 3: 20
Ti alloys – phase stability
α+β
β
β
β
Temperature
α+ β+γ
β
α α2 α
α
+ α+β
α2 α α+γ
dashed lines for Ti – Al dashed line is Cu, Mn, Fe, Ni, Co, H
“martensite start”
dashed line is “martensite start”
dotted lines may be relevant to
normal cooling rates as eutectoid
reaction can be very sluggish.
Other α - Ti alloys:
100µm 100µm
Ti – 5%Al – 2.5%Sn:
“CP”: effectively Ti – O Can also slow-cool from β (IMI 317)
alloys. phase: produces plates of used in low interstitial
α growing into original form (“ELI”) for cryogenic
Hot – work in α phase field,
(large) β grains. tanks – space vehicles.
anneal at 675ºC, produce
fine equiaxed grain structure.
Not as strong or ductile as Ti – 2.5%Cu:
Strength from oxygen equiaxed alloys, but (IMI 230)
interstitials and Hall-Petch: tougher and with high Age hardening.
(e.g.) fatigue resistance
(complex crack paths) CP + 0.5%Pd:
σy = 230 + 10.5/√d MPa IMI260
High corrosion resistance
“CP” Ti is about 20% of current usage: applications as
aerospace sheet and panels, chemical plant components.
Guggenheim museum,
Bilbao
http://www.timet.com/architecture/index.html
“basket-weave” structure of
plates of β with α between.
8-1-1 8%Al, 1%Mo, 1%V 980 1060 15 α+β heat-treated (780ºC). Can
embrittle due to α2 formation.
IMI 679 2.25%Al, 11%Sn, 990 1100 15 Substituting Sn for Al to cut down on
5%Zr, 1%Mo, α2 embrittlement. Extra solute
0.25%Si strengtheners added.
IMI 685 6%Al, 5%Zr, 900 1020 12 β heat-treated. (1050ºC). Quenched
0.5%Mo, 0.25%Si to RT and aged at 550ºC to give
“basket weave” of α with some ppts.
IMI 834 5.8%Al, 4.5%Sn, 910 1030 15 20ºC Like 685, but Nb for extra
4%Zr, 0.7%Nb, corrosion resistance, and can
0.5%Mo, 0.4%Si,
600ºC
tailor µ-structure more easily
480 585 20
0.06%C for good compromise on
creep and fatigue strengths
General principles:
α+β
Work alloy in either α + β or β field:
α
then either
MF MS
slow cool (“anneal”) to produce plates of α
in the β grains. Can produce “basket
Quenched weave” structure.
from β
Yield Strength
and aged or
quench to produce a martensitic form of α
Annealed from the β. This can then be “aged” to give
fine microstructure of α and β.
% Solute
Engineering “C” – High Perfomance Alloys: HT 2000 S.G. Roberts 3: 26
α − β alloys: microstructures
Slow-cooled from β field Slow-cooled from α+β field Quenched from β field
(IMI 318) (IMI 318) (Ti – 12V)
2µm
Convoluted fatigue
crack growth in
“basket-weave”
IMI 318
IMI 318, Ti 6%Al 4%V IMI 318 – typical properties Air – cooled Air – cooled
is the “classic” Ti alloy. from α + β from β
forge, solution treat at 750-800ºC, quench and then age at 450-500ºC (24hr) to
precipitate fine α phase particles.
Typical properties: yield stress 1250 MPa, UTS 1350 MPa, εF 8%.
Expensive alloys, and need very careful process control to get best properties.
Difficult to weld.