Material Safety Data Sheet

ROHM AND HAAS QUÍMICA LTDA

Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

Print Date: 21.08.2018
ROHM AND HAAS QUÍMICA LTDA encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: PRIMENE™ JM-T Amine

Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Chemical intermediate

COMPANY IDENTIFICATION
ROHM AND HAAS QUÍMICA LTDA
Subsidiária da The Dow Chemical Company
AV. DAS NACOES UNIDAS 14171
1 ANDAR - PARTE E 4 ANDAR - PARTE
DIAMOND TOWER - SANTO AMARO
04794-000 SAO PAULO - SP
BRAZIL

Customer Information Number: 0800 0474714

SDSQuestion@dow.com

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: (55) 13-3358-8226
Local Emergency Contact: 0800-763-8422

2. HAZARDS IDENTIFICATION
This product has been classified in accordance with ABNT NBR 14725-2, Chemicals - Safety, Health
and Environmental Information - Part 2: Hazard Classification System.

Hazard classification
Flammable liquids - Category 4
Acute toxicity - Category 4 - Oral
Acute toxicity - Category 2 - Inhalation
Acute toxicity - Category 3 - Dermal
Skin corrosion - Category 1A
Serious eye damage - Category 1
Skin sensitisation - Category 1
Aspiration hazard - Category 1
Short-term (acute) aquatic hazard - Category 1
Long-term (chronic) aquatic hazard - Category 1

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 12

company of Dow
Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

Signal word: DANGER!

Hazards
Combustible liquid.
Harmful if swallowed.
May be fatal if swallowed and enters airways.
Toxic in contact with skin.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Fatal if inhaled.
Very toxic to aquatic life with long lasting effects.

Precautionary statements
Prevention
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Avoid release to the environment.
Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response
IF SWALLOWED: Immediately call a POISON CENTER/doctor.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call
a POISON CENTER/doctor.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Take off immediately all contaminated clothing and wash it before reuse.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide to
extinguish.
Collect spillage.

Storage
Store in a well-ventilated place. Keep container tightly closed.

Other hazards
No data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature: Amine

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

This product is a mixture.

Component CASRN Concentration

Alkyl primary amines 68955-54-4 80,0 - 90,0 %

Octadecene, branched 182636-02-8 10,0 - 20,0 %

4. FIRST AID MEASURES

Description of first aid measures
Inhalation: Move to fresh air.

Skin contact: IMMEDIATELY get under a safety shower. Remove contaminated clothing. Wash off
with soap and water. Immediate medical attention is required. Wash contaminated clothing before re-
use. Do not take clothing home to be laundered. Discard contaminated shoes, belts, and other
articles made of leather.

Eye contact: Rinse immediately with plenty of water for at least 15 minutes. Immediate medical
attention is required.

Ingestion: Do NOT induce vomiting. Drink 1 or 2 glasses of water. IMMEDIATELY see a physician.
If vomiting occurs spontaneously, keep airway clear. Never give anything by mouth to an unconscious
person.

Most important symptoms and effects, both acute and delayed:

Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed

Notes to physician: If swallowed, careful evacuation of the stomach is advisable.

5. FIREFIGHTING MEASURES
Suitable extinguishing media: Carbon dioxide (CO2) Water spray Dry chemical

Extinguishing Media to Avoid: Not Determined

Special hazards arising from the substance or mixture

Hazardous combustion products: No data available

Unusual Fire and Explosion Hazards: Combustion generates toxic fumes of the following: Nitrogen
oxides (NOx) Carbon oxides

Advice for firefighters

Fire Fighting Procedures: No data available

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

Special protective equipment for firefighters: Wear self-contained breathing apparatus and
protective suit.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Material is corrosive. If
exposed to material as-is or mixed with run-off water during fire-fighting, IMMEDIATELY remove all
contaminated clothing and wash exposed skin areas with soap and water. See SECTION 4, First Aid
Measures, for further information. Wear a NIOSH approved (or equivalent) self-contained breathing
apparatus in the pressure demand mode or a full-facepiece airline respirator in the pressure demand
mode with emergency escape provisions. Wear full protective equipment including: acid-resistant
clothing, gloves and boots, chemical splash goggles and face shield (ANSI Z-87.1 or approved
equivalent).

Removal of ignition sources: Keep away from sources of ignition.

Dust Control: Not applicable

Environmental precautions: WARNING: KEEP SPILLS AND CLEANING RUNOFFS OUT OF

MUNICIPAL SEWERS AND OPEN BODIES OF WATER.

Methods and materials for containment and cleaning up: Evacuate personnel to safe areas. Floor
may be slippery; use care to avoid falling. Contain spills immediately with inert materials (e.g., sand,
earth). Transfer liquids and solid diking material to separate suitable containers for recovery or
disposal. Flush cleaned area with water to a sewage treatment facility.

7. HANDLING AND STORAGE

Precautions for safe handling: This material is corrosive. See SECTION 8, Exposure
Controls/Personal Protection, prior to handling. NOTE: During storage, harmful vapors can
accumulate in the container head when containers are opened. Harmful vapors can be evolved when
this material is heated during processing. Every effort must be made to protect workers from airborne
concentrations exceeding the exposure limits shown in SECTION 8, Exposure Controls/Personal
Protection.

Conditions for safe storage: Avoid temperature extremes during storage; ambient temperature
preferred. Store away from excessive heat (e.g. steampipes,radiators), from sources of ignition and
from reactive materials. An atmosphere of dry Nitrogen may be used to preserve the chemical purity.
Do not store this material in containers made of the following: copper Copper alloys Although
stainless steel or cast iron equipment is satisfactory, mild steel is preferred. Keep container tightly
closed.
CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied containers retain product
residue follow all (M)SDS and label warnings even after container is emptied. Improper disposal or re-
use of this container may be dangerous and illegal. Refer to applicable local, state and federal
regulations.

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value/Notation
Alkyl primary amines Dow IHG TWA 1 ppm
Dow IHG TWA SKIN
Dow IHG STEL 2,5 ppm
Dow IHG STEL SKIN

Exposure controls
Engineering controls: Use local exhaust ventilation with a minimum capture velocity of 100 ft/min.
(0.5 m/sec.) at the point of vapor evolution. Refer tothe current edition of Industrial Ventilation: A
Manual of Recommended Practice published by the American Conference of Governmental Industrial
Hygienists for information on the design, installation, use, and maintenance of exhaust systems.

Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.

Individual protection measures

Eye/face protection: Use chemical splash goggles and face shield (ANSI Z87.1 or approved
equivalent).
Skin protection
Hand protection: Chemical-resistant gloves should be worn whenever this material is
handled. The glove(s) listed below may provide protection against permeation.
(Gloves of other chemically resistant materials may not provide adequate protection):
butyl-rubber Neoprene gloves Nitrile rubber Gloves should be removed and
replaced immediately if there is any indication of degradation or chemical
breakthrough. Rinse and remove gloves immediately after use. Wash hands with
soap and water.
Other protection: Wear as appropriate: Chemical resistant apron protective suit
Boots
Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI
Z88.2 requirements or equivalent must be followed whenever workplace conditions warrant a
respirator's use. None required if airborne concentrations are maintained below the exposure
limit listed in Exposure Limit Information. Up to 10 times the exposure limit: Wear a properly
fitted NIOSH approved (or equivalent) half-mask, air-purifying respirator. Up to 50 times the
exposure limit: Wear a properly fitted NIOSH approved (or equivalent) full-facepiece, air-
purifying respirator, OR full-facepiece, airline respirator in the pressure demand mode. Above
50 times the exposure limit or Unknown: Wear a properly fitted NIOSH approved (or
equivalent) self-contained breathing apparatus in the pressure demand mode, OR full-
facepiece, airline respirator in the pressure demand mode with emergency escape provision.
Air-purifying respirators should be equipped with NIOSH approved (or equivalent)
ammonia/methylamine cartridges and N95 filters. If oil mist is present, use R95 or P95 filters.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state liquid

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

Color Yellow to brown

Odor Amine odor
Odor Threshold No data available
pH No data available
Melting point/range < -40,00 °C
Freezing point No data available
Boiling point (760 mmHg) 265,00 - 305,00 °C
Flash point 76,7 °C PENSKY MARTENS CLOSED CUP
Evaporation Rate (Butyl Acetate <0,75
= 1)
Flammability (solid, gas) Not Applicable
Lower explosion limit No data available
Upper explosion limit No data available
Vapor Pressure 4,4000000 mmHg at 100,00 °C
Relative Vapor Density (air = 1) >1,0000
Relative Density (water = 1) 0,8200
Water solubility practically insoluble
Partition coefficient: n- log Pow: 2,9 OECD Test Guideline 107 or Equivalent
octanol/water
Auto-ignition temperature No data available
Decomposition temperature No data available
Kinematic Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available
Molecular weight No data available

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY

Reactivity: No data available

Chemical stability: No data available

Possibility of hazardous reactions: Stable under recommended storage conditions.

Product will not undergo hazardous polymerization.

Conditions to avoid: No data available

Incompatible materials: Acids Oxidizing agents

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

Hazardous decomposition products: There are no known hazardous decomposition products for
this material.

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Acute toxicity
Acute oral toxicity
LD50, Rat, 450 mg/kg

Acute dermal toxicity

Signs of central nervous system effects were seen by the oral, dermal, and inhalation routes
of administration.
LD50, Rabbit, 251 mg/kg

Acute inhalation toxicity

Toxicity data for a compositionally similar material.
LC50, Rat, female, vapour, 1,19 mg/l157 ppm
Toxicity data for a compositionally similar material. The saturated vapor concentration
measured during the study was 150 ppm at 19C/66.2F (room temperature) and 200 ppm at
24C/75.2F (similar to the temperature of the test chamber atmospheres).
LC50, Rat, male, vapour, 1,75 mg/l>231 ppm

Skin corrosion/irritation
Corrosive under DOT test method.

Serious eye damage/eye irritation

Severe eye irritation

Sensitization
Absolute ethanol and acetone used as vehicles in this test.

For respiratory sensitization:

No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)

Product test data not available. Refer to component data.

Specific Target Organ Systemic Toxicity (Repeated Exposure)

A 28 day inhalation study in rats showed no effects at 2 mg/m3 (0.002 mg/l) and 19 mg/m3 (0.019
mg/l), serious irritation of the respiratory tract at 129 mg/m3 (0.129 mg/l), and death at 537 mg/m3
(0.537 mg/l). No signs of systemic toxicity or neurotoxicuty were seen at concentrations of 2, 19, or
129 mg/m3 when evaluated by a functional observational battery (FOB) of tests designed to identify
these effects. All animals from the 537 mg/m3 died prior to the FOB. These analytical concentrations
are equivalent to 0.3, 2.0, 15, and 66 ppm of tertiary-alkyl amines. Maintaining airborne concentrations
below the recommended exposure limit should prevent irritation and is not expected to produce
adverse effects. Dermal exposure of rats to 5, 20, and 60 mg/kg for 28 days caused severe skin
irritation at the higher dose. No signs of systemic toxicity or neurotoxicity were observed in this test.
Toxicity data for a compositionally similar material.

Carcinogenicity

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

Product test data not available. Refer to component data.

Teratogenicity
Product test data not available. Refer to component data.

Reproductive toxicity
Toxicity data for a compositionally similar material.

In a Dietary One Generation Reproduction Study with rats, no parental or reproductive effects were
observed at doses up to and including 250 ppm (approximately 21.0 mg/kg (female) and 19.1 mg/kg
(male)). At higher doses, both parental and reproductive effects were seen. These effects occurred at
dose levels which were significantly higher than the recommended workplace exposure limit. This
material does not present a reproductive risk.

Mutagenicity
Ames mutagenicity:

Non-mutagenic
Genetic Toxicity in vivo
In vivo micronucleus assay (mouse): Negative Toxicity data for a compositionally similar
material.

Aspiration Hazard
Product test data not available. Refer to component data.

Additional information
No toxicity data are available for this material.

COMPONENTS INFLUENCING TOXICOLOGY:

Alkyl primary amines

Specific Target Organ Systemic Toxicity (Single Exposure)
Material is corrosive. Material is not classified as a respiratory irritant; however, upper
respiratory tract irritation or corrosivity may be expected.

Carcinogenicity
No relevant data found.

Teratogenicity
For similar material(s): Did not cause birth defects or any other fetal effects in laboratory
animals.

Aspiration Hazard
Based on available information, aspiration hazard could not be determined.

Octadecene, branched
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Carcinogenicity
No relevant data found.

Teratogenicity

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

For similar material(s): Contains component(s) which did not cause birth defects or any other
fetal effects in lab animals.

Aspiration Hazard
May be fatal if swallowed and enters airways.

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

General Information
The Environmental Toxicity data are for a compositionally similar material.

Ecotoxicity
Acute toxicity to fish
LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, 1,3 mg/l, Method Not Specified.

Acute toxicity to aquatic invertebrates

EC50, Daphnia magna, 48 Hour, 4,1 mg/l

Acute toxicity to algae/aquatic plants

EC50, Algae (Selenastrum capricornutum), 72 Hour, 0,20 mg/l

Persistence and degradability

Biodegradability: Closed Bottle Ready Biodegradation Test (OECD 301D): not readily
biodegradable-observed amount of degradation was 21.8% after 28 days. 10-day Window:
Fail
Biodegradation: 21,8 %
Exposure time: 28 d
Method: OECD Test Guideline 301D or Equivalent

Bioaccumulative potential
Partition coefficient: n-octanol/water(log Pow): 2,9 OECD Test Guideline 107 or
Equivalent

Mobility in Soil

Octadecene, branched
For similar material(s):
Expected to be relatively immobile in soil (Koc > 5000).
Partition coefficient (Koc): > 5000 Estimated.

Results of PBT and vPvB assessment

Alkyl primary amines

This mixture has not been assessed for persistence, bioaccumulation and toxicity (PBT).

Octadecene, branched
This substance has not been assessed for persistence, bioaccumulation and toxicity (PBT).

Other adverse effects

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

Alkyl primary amines

This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

Octadecene, branched
This substance is not on the Montreal Protocol list of substances that deplete the ozone layer.

13. DISPOSAL CONSIDERATIONS

Disposal methods: Incinerate liquid and contaminated solids in accordance with local, state, and
federal regulations.

Contaminated packaging: Empty containers retain product residues. Follow label warnings even
after container is emptied. Improper disposal or reuse of this container may be dangerous and illegal.
Refer to applicable federal, state and local regulations.

14. TRANSPORT INFORMATION

ANTT
Proper shipping name CORROSIVE LIQUID, TOXIC, N.O.S.(t-Alkyl amines)
UN number UN 2922
Class 8 (6.1)
Packing group III
Hazard Identification 86
Number
Environmental hazards t-Alkyl amines

Classification for SEA transport (IMO-IMDG):

Proper shipping name CORROSIVE LIQUID, TOXIC, N.O.S.(t-Alkyl amines)
UN number UN 2922
Class 8 (6.1)
Packing group III
Marine pollutant t-Alkyl amines
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):

Proper shipping name Corrosive liquid, toxic, n.o.s.(t-Alkyl amines)
UN number UN 2922
Class 8 (6.1)
Packing group III

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

It is recommended the customer to check in the location of use of this product whether it is specifically
regulated for human perusal or veterinary applications, as food and pharmaceuticals additives or
packaging, domissanitary, and cosmetics, or even as controlled agent recognized as precursor to
drug, chemical weapons, and ammunition manufacture.
The communication of the hazards of this product is in accordance with local and international
legislations, observing always the most restrictive requirement.

16. OTHER INFORMATION

Hazard Rating System

HMIS
Physical
Health Flammability
Hazard
3 2 0

Revision
Identification Number: 10039390 / 1751 / Issue Date: 20.08.2018 / Version: 1.1
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Legend
Dow IHG Dow Industrial Hygiene Guideline
SKIN Absorbed via skin
STEL Short Term Exposure Limit (STEL):
TWA Time Weighted Average (TWA):

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by Land
of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen,
Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN - Standard of the
German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration
associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency
Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated
with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and Equipment
of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO -
International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China;
IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL -
Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI -
Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 -
Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for

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Product name: PRIMENE™ JM-T Amine Issue Date: 20.08.2018

the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm;
NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect
Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH
- Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating
Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory;
TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN
- United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous
Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials
Information System

ROHM AND HAAS QUÍMICA LTDA urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
BR

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