Atomic Structure

PREVIOUS YEAR
PROBLEM SOLVING
IIT JEE MAIN + ADVANCED
PHYSICAL CHEMISTRY
BY
JITENDRA HIRWANI
ATOMIC
STRUCTURE
ETOOSINDIA
INDIA’S NO. 1 ONLINE COACHING
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar,
Kota, Rajasthan – 324005 Mob. : 9214233303
ETOOSINDIA J.H. SIR
JEE MAINS
1. Which of the following ions has the maximum magnetic moment? [AIEEE 2002]
+2 +2 +2 +2
(A) Mn (B) Fe (C) Ti (D) Cr .
Ans. (A)
2. Energy of H-atom in the ground state is –13.6 eV, hence energy in the second excited state is [AIEEE 2002]
(A) – 6.8 eV (B) – 3.4 eV (C) – 1.51 eV (D) – 4.53 eV
Ans. (C)
Uncertainity in position of a particle of 25 g in space is 10–15 m. Hence, Uncertainity in velocity (in m.sec–1) is :
A
3.
(plank’s constant, h = 6.6  10–34 Js) [AIEEE 2002]
Ans.
4.
(A) 2.1  10–28
(A)
(B) 2.1  10–34
(planck’s constant, h = 6.63  10–34 J-s)

(C) 0.5  10–34
D
(D) 5.0  10–24
I
The de-Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 m/s is approximately.
[AIEEE 2003]
N
(A) 10–33 m (B) 10–31 m (C) 10–16 m (D) 10–25 m
I
Ans. (A)
S
5. In Bohr series of lines of hydrogen spectrum, the third line from the red end corresponds to which one of the
following inner-orbit jumps of the electron for Bohr orbits in an atom of hydrogen ? [AIEEE 2003]
(A) 3  2 (B) 5  2 (C) 4  1 (D) 2  5
O
Ans. (B)
6. The numbers of d-electrons retained in Fe2+ (atomic number Fe = 26) ion is [AIEEE 2003]
O
(A) 3 (B) 4 (C) 5 (D) 6
Ans. (D)
7.
Ans.
E T
The orbital angular momentum for an electron revolving in an orbit is given by
for an s-electron will be given by
(A) +
(B)
1 h
.
2 2
(B) Zero (C)
h
2
 (   1)
(D)
h
2 . 2
h
2
. This momentum
[AIEEE 2003]
8. The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to stationary state
1, would be (Rydberg constant = 1.097  107 m–1) [AIEEE 2004]
(A) 91 nm (B) 192 nm (C) 406 (D) 9.1  10–6 nm
Ans. (A)
9. Which of the following set a of quantum numbers is correct for an electron in 4f orbital? [AIEEE 2004]
(A) n = 4, l =3, m = +4, s = +1/2 (B) n = 4, l = 4, m = –4, s = –1/2
(C) n = 4, l = 3, m = +1, s = +1/2 (D) n = 3, l=2, m =–2, s = +1/2
Ans. (C, D)
Plot No. 38, Near Union Bank of India, Rajeev Gandhi Nagar, Page # 2
ETOOSINDIA J.H. SIR
10. Consider the ground state of Cr atom (Z = 24). The numbers of electrons with the azimuthal quantum numbers,
 = 1 and 2 are, respectively [AIEEE 2004]
(A) 12 and 4 (B) 12 and 5 (C) 16 and 4 (D) 16 and 5
Ans. (B)
11. Which of the following statements in relation to the hydrogen atom is correct ? [AIEEE 2005]
(A) 3s, 3p and 3d orbitals all have the same energy
(B) 3s and 3p orbitals are of lower energy than 3d orbital
(C) 3p orbital is lower in energy than 3d orbital
(D) 3s orbital is lower in energy than 3p orbital
Ans.
12.
(A)
I A
In a multi-electron atom, which of the following orbitals described by the three quantum numbers will have the
same energy in the absence of magnetic and electric field ? [AIEEE 2005]
D
(i) n = 1, l = 0, m = 0 (ii) n =2, l = 0, m = 0 (iii) n = 2, l = 1, m = 1 (iv) n = 3, l = 2, m =1
(v) n = 3, l = 2, m = 0
N
(A) (iv) and (v) (B) (iii) and (iv) (C) (ii) and (iii) (D) (i) and (ii)
I
Ans. (A)
13. Uncertainity in the position of an electron (mass = 9.1  10–31 Kg) moving with a velocity 300 m.sec–1, Accurate
S
upto 0.001%, will be : (h = 6.63  10–34 J-s) [AIEEE 2006]
(A) 19.2  10–2 m (B) 5.76  10–2 m (C) 1.92  10–2 m (D) 3.84  10–2 m
O
Ans. (C)
14. According to Bohr’s theory, the angular momentum to an electron in 5th orbit is : [AIEEE 2006]
O
h h h h
(A) 25 (B) 1.0 (C) 10 (D) 2.5
   
T
Ans. (D)
E
15. The ‘spin-only’ magnetic moment [in units of Bohr magneton ()] of Ni2+ in aqueous solution would be (Atomic
number : Ni = 28) [AIEEE 2006]
(A) 2.84 (B) 4.90 (C) 0 (D) 1.73
Ans. (A)
16. The ionisation enthalpy of hydrogen atom is 1.312  106 J mol–1. The energy required to excite the electron in the
atom from n1 = 1 to n2 = 2 is [AIEEE 2008]
(A) 8.51  105 J mol–1 (B) 6.56  105 J mol–1
(C) 7.56  105 J mol–1 (D) 9.84  105 J mol–1
Ans. (D)
ETOOSINDIA J.H. SIR
17. Which of the following set of quantum numbers represents the highest energy of an atom ?
1 1
(A) n = 3, l = 0, m = 0, s = + (B) n = 3, l = 1, m =1, s = + [AIEEE 2008]
2 2
1 1
(C) n = 3, l = 2, m = 1, s = + (D) n = 4, l = 0, m = 0, s = +
2 2
Ans. (C)
18. In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005 percent. Certainly with
which the position of the electron can be located is (h = 6.6 × 10 –34 kg m 2s –1, mass of electron,
A
e m = 9.1 × 10 –31 kg) [AIEEE 2009]
I
(A) 1.52 × 10–4 m (B) 5.10 × 10–3 m (C) 1.92 × 10–3 m (D) 3.84 × 10–3 m
Ans. (C)
19.
1.67 × 10–27 kg and h = 6.63 × 10–34 Js) :
(A) 0.032 nm (B) 0.40 nm (C) 2.5 nm
N D
Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 × 103 ms–1 (Mass of proton =
[AIEEE 2009]
(D) 14.0 nm
I
Ans. (B)
S
20. The energy required to break one mole of Cl – Cl bonds in Cl2 is 242 kJ mol–1 . The longest wavelength of light
capable of breaking a single Cl – Cl bond is [AIEEE 2010]
(c = 3 × 108 m s–1 and NA = 6.02 × 1023 mol–1)
O
(A) 594 nm (B) 640 nm (C) 700 nm (D) 494 nm
Ans. (D)
O
21. Ionisation energy of He+ is 19.6 × 10–18 J atom–1 . The energy of the first stationary state (n = 1) of Li2+ is :
[AIEEE 2010]
T
(A) 4.41 × 10–16 J atom–1 (B) – 4.41 × 10–17 J atom–1
(C) – 2.2 × 10–15 J atom–1 (D) 8.82 × 10–17 J atom–1
E
Ans. (B)
22. A gas absorbs a photon of 355 nm and emits at two wavelengths. If one of the emission is at 680 nm, the other is at
[AIEEE 2011]
(A) 1035 nm (B) 325 nm (C) 743 nm (D) 518 nm
Ans. (C)
23. The frequency of light emitted for the transition n = 4 to n = 2 of He+ is equal to the transition in H atom corresponding
to which of the following? [AIEEE 2011]
(A) n = 2 to n = 1 (B) n = 3 to n = 2 (C) n = 4 to n = 3 (D) n = 3 to n = 1
Ans. (A)
ETOOSINDIA J.H. SIR
24. The electrons identified by quantum numbers n and  : [AIEEE 2012]

(a) n = 4,  = 1 (b) n = 4,  = 0 (c) n = 3,  = 2 (d) n = 3,  = 1
can be placed in order of increasing energy as :
(A) (d) < (b) < (c) < (a) (B) (c) < (d) < (b) < (a)
(C) (d) < (b) < (a) < (c) (D) (b) < (d) < (c) < (a)
Ans. (A)
25. The correct set of four quantum numbers for the valence electrons of rubidium atom (Z = 37) is : [JEE Main 2013]
1 1 1 1
A
(A) 5, 1, 1, + (B) 5, 0, 1, + (C) 5, 0, 0, + (D) 5, 1, 0, +
2 2 2 2
Ans.
26.
(C)
quantum number (n–1). If n >> 1, the frequency of radiation emitted is proportional to
1 1 1
D [JEE MAIN 2013]
1
I
In a hydrogen-like atom electrons make transition from an energy level with quantum number n to another with
N
(A) 3/2 (B) (C) (D)
n n3 n n2
I
Ans. (B)
S
27. The energy of an electron in first Bohr orbit of H-atom is – 13.6 eV. The energy value of electron in the excited state
of Li2+ is : [JEE Main (Online) 2014]
(A) –30.6 eV (B) – 27.2 eV (C) 27.2 eV (D) 30.6 eV
O
Ans. (A)
28. Based on the equation [JEE Main (Online) 2014]
O
 1 1 
E  2.0 1018 J  2  2 
 n2 n1 
Ans.
29. E
(B)
T
the wavelength of the light that must be absorbed to excite hydrogen electron from level n = 1 to n = 2 will be
(h = 6.625 × 10–34 Js, C = 3 × 108 ms–1)
(A) 2.650 × 10–7 m (B) 1.325 × 10–7 m (C) 1.325 × 10–10 m (D) 5.300 × 10–10 m
If 0 and  be the threshold wavelength and wavelength of incident light, the velocity of photoelectron ejected from
the metal surface is [JEE Main (Online) 2014]
2hc  0    2h  1 1  2h 2hc
(A)   (B)    (C) (0   ) (D) (0   )
m  0  m  0   m m
Ans. (A)
30. Excited hydrogen atom emits light in ultraviolet region at 2.47 × 1015 Hz. With this frequency, the energy of a single
photon is :- (h = 6.63 × 10–34 Js) [JEE Main (Online) 2014]
–19 –17 –18
(A) 2.680 × 10 J (B) 6.111 × 10 J (C) 1.640 × 10 J (D) 8.041 × 10–40 J
Ans. (C)
ETOOSINDIA J.H. SIR
31. The de-Brogile wavelengths of a particle of mass 6.63 g moving with a velocity 100 ms–1 is :-
[JEE Main (Online) 2014]
(A) 10–35 m (B) 10–33 m (C) 10–25 m (D) 10–31 m
Ans. (B)
32. If m and e are the mass and charge of the revolving electron in the orbit of radius r for hydrogen atom, the total
energy of the revolving electron will be [JEE Main (Online) 2014]
me2 e2 1 e2 1 e2
(A) (B)  (C) (D) 
r r 2 r 2 r
A
Ans. (D)
33.
Ans.
sodium atom is (h =- 6.626 × 10–34 Js, NA = 6.022 × 1023 mol–1)
(A) 3.15 × 1015 s–1
(C)
(B) 4.76 × 1014 s–1 (C) 1.24 × 1015 s–1
D I
Ionization energy of gaseous Na atoms is 495.5 kJ mol–1. The lowest possible frequency of light that ionizes a
(D) 7.50 × 104 s–1
N
34. Which of the following is the energy of a possible excited state of hydrogen? [JEE Main 2015]
I
(A) –3.4 eV (B) +6.8 eV (C) +13.6 eV (D) –6.8 eV
Ans. (A)
S
3
35. At temperature T, the average kinetic energy of any particle is kT. The de Broglie wavelength follows the order
2
O
(A) Thermal proton > Visible photon > Thermal electron
(B) Thermal proton > Thermal electron > Visible photon
(C) Visible photon > Thermal electron > Thermal neutron
O
(D) Visible photon > Thermal neutron > Thermal electron
Ans. (C)
T
36. A stream of electrons from a heated filament was passed between two charged plates kept at potential difference V
esu. If e and m are change and mass of an electron respectively, then the value of h/ (where  is wavelength
E
associated with electron wave) is given by : [JEE Main 2016]
(A) 2meV (B) meV (C) 2meV (D) me V
Ans. (C)
37. The radius of the second Bohr orbit for hydrogen atom is :
(Planck’s Const. h = 6.6262 × 10–34 Js ; mass of electron = 9.1091 × 10–31 kg; charge of electron e = 1.60210 × 10–19 C
permittivity of vacuum 0 = 8.854185 × 10–12 kg–1 m–3A2) [JEE Main 2017]
(A) 0.529 Å (B) 2.12 Å (C) 1.65 Å (D) 4.76Å
Ans. (B)
38. The electron in the hydrogen atom undergoes transition from higher orbitals to orbital of radius 211.6 pm. This
transition is associated with : [JEE Main (Online) 2017]
(A) Lyman series (B) Balmer series (C) Brackett series (D) Paschen series
Ans. (B)
ETOOSINDIA J.H. SIR
JEE ADVANCED
Subjective Type Questions
1. The energy of the electron in the second and third Bohr’s orbits of the hydrogen atom is –5.42 × 10–12 erg and
–2.41 ×10–12 erg respectively. Calculate the wavelength of the emitted light when the electron drops from the third to
the second orbit. [JEE 1981]
Ans.  = 660 nm
2. Calculate the wavelength in Angstroms of the photon that is emitted when an electron in the Bohr’s orbit, n = 2
returns to the orbit, n = 1 in the hydrogen atom.The ionisation potential of the ground state hydrogen atom is
2.17 × 10–11 erg per atom. [JEE 1982]
A
Ans.  = 1220 Å
3. The electron energy in hydrogen atom is given by E n 

 21.7  10 12
n2
D I
erg. Calculate the energy required to remove
an electron completely from the n= 2 orbit. What is the longest wavelength (in cm) of light that can be used to cause
this transition ? [JEE 1984]
N
Ans.  = 3.66 × 10–5 cm
4.
Ans.
number 3 and azimuthal quantum number 2 ?
Ten
S I
What is the maximum number of electrons that may be present in all the atomic orbitals with principal quantum
[JEE 1985]
O
5. Give reason why the ground state outermost electronic configuration of silicon is [JEE 1985]
3s 3p 3s 3p






O
and not
T
Ans. The 2nd configuration is against Hund’s rule of maximum multiplicity which states that the singly occupied
degenerate atomic orbitals must have electrons of like spins.
6.
Ans.
E
According to Bohr’s theory, the electronic energy of hydrogen atom in the nth Bohr’s orbit is given by :
471 nm
En 
21.7  10 19
n2
J
Calculate the longest wavelength of electron from the third Bohr’ orbit of the He+ ion. [JEE 1990]
7. Electromagnetic radiations of wavelength 242 nm is just sufficient to ionise sodium atom. Calculate the ionisation
energy of sodium in kJ mol–1. [Roorkee 1992]
Ans. 494.5 kJ mol–1
ETOOSINDIA J.H. SIR
8. Estimate the difference in energy between 1st and 2nd Bohr’s orbit for a hydrogen atom. At what minimum atomic
number, a transition from n = 2 to n = 1 energy level would result in the emission X-rays with l = 3.0 × 10–8 m? Which
hydrogen atom like species does this atomic number correspond to? [JEE 1993]
Ans. E = 1.635 × 10–18, Z = 2(He+)
9. Calculate the energy emitted when electrons of 1.0 g atom of hydrogen undergo transition giving the spectral lines
of lowest energy in the visible region of its atomic spectra. [Roorkee 1993]
RH = 1.1 × 107 m–1, c = 3 × 108 m sec–1 and h = 6.62 × 10–34 J sec.
Ans. 182.5 kJ
A
10. Find out the number of waves made by a Bohr’s electron in one complete revolution in its 3rd orbit. [JEE 1994]
I
Ans. Three
11. Iodine molecule dissociates into atoms after absorbing light to 4500Å. If one quantum of radiation is absorbed by
D
each molecule, calculate the kinetic energy of iodine atoms. [JEE 1995]
(Bond energy of I2 = 240 kJ mol–1)
Ans. Ek = 2.16 × 1020 J/atom
12.
photons are emitted by the bulb per second ?
I N
A bulb emits light of  4500Å. The bulb is rated as 150 watt and 8% of the energy is emitted as light. How many
[JEE 1995]
S
Ans. n = 27.2 × 108
13. Calculate the wave number for the shortest wavelength transition in the Balmer series of atomic hydrogen.
O
[JEE 1996]
6 –1
Ans. 2.725 × 10 m
O
14. An electron beam can undergo diffraction by crystals. Through what potential should a beam of electrons be
accelerated so that its wavelength becomes equal to 1.54Å. [JEE 1997]
T
Ans. V = 63.56 V
E
15. With what velocity should an  - particle travel towards the nucleus of a copper atom so as to arrive at a distance
10–13 m from the nucleus of the copper atom ? [JEE 1997]
Ans. 6.3 × 108 m/s
16. A compound of vanadium has a magnetic moment of 1.73 BM. Work out the electronic configuration of the
vanadium ion in the compound. [JEE 1997]
Ans. 23
V4+ : 1s2, 2s2 2p6 , 3s2 3p6 3d1
17. Calculate the energy required to excite one litre Hydrogen gas at 1 atm and 298 K to first excited state of atomic
hydrogen. The energy for the dissociation of H-H bond is 436 kJ mol-1. [JEE 2000]
Ans. 98.44 kJ
ETOOSINDIA J.H. SIR
18. The wavelength corresponding to maximum energy for hydrogen is 91.2 nm. Find the corresponding wavelength for
He+ ion. [JEE 2003]
Ans. 22.8 nm
19. (A) The Schrodinger wave function of an electron in 2s orbital in hydrogen atom is given below :
3/2
1  1   r   r/ 2a 0
2s =   2 e [JEE 2004]
(2 32 )  a 0   a 0 
where a 0 is the Bohr radius. This wave function has a radial node at r = r 0. Express r 0 in terms of a 0.
(B)
Ans.
A base ball having mass 100 g moves with velocity 100 m/s. Find out the value of wavelength of base
ball.
(A) r 0 = 2a0
I A
D
(B) 6.625 × 10 –25 Å (negligibly small)
N
20. Find out the following
I
(A) The velocity of electron in first Bohr’s orbit of H atom (r = a0)
(B) de Broglie wavelength of the electron in first Bohr’s orbit of H atom.
S
h
(C) The orbital angular momentum of 2p orbital in terms of units.
2
O
 4 
Ans. (A) 2.19 × 108 cm s–1 , (B) 3.32 Å (C) 2  
 2 
21. The maximum number of electrons that can have principal quantum number, n = 3, and spin quantum number,
O
ms = –1/2, is [JEE 2011]
Ans. 9
22.
E T
The work function () of some metals is listed below. The number of metals which will show photoelectric effect
when light of 300 nm wavelength falls on the metal is
Metal
 (eV)
Li
2.4
Na
2.3
K
2.2
Mg
3.7
Cu
4.8 4.3
Ag Fe
4.7
[JEE 2011]
Pt
6.3
W
4.75
Ans. 4
23. The atomic masses of He and Ne are 4 and 20 amu, respectively. The value of the de-Broglie wavelength of He gas
at –73°C is ‘M’ times that of the de-Broglie wavelength of Ne at 727°C. M is [JEE 2013]
Ans. 5
24. In an atom, the total number of electrons having quantum numbers n = 4, | m | = 1 and ms = – 1/2 is [JEE 2014]
Ans. 6
ETOOSINDIA J.H. SIR
Objective Type Questions

25. Rutherford’s experiment on scattering of -particles showed for the first time that the atom has [JEE 1981]
(A) Electrons (B) Protons (C) Nucleus (D) Neutrons
Ans. (C)
26. Rutherford’s scattering experiment is related to the size of the [JEE 1983]
(A) Nucleus (B) Atom (C) Electron (D) Neutron
Ans. (A)
A
27. Any p-orbital can accommodate upto [JEE 1983]
I
(A) four electrons
(B) six electrons
(C) two electrons with parallel spins
D
(D) two electrons with opposite spins
Ans. (D)
N
28. The principal quantum number of an atom is related to the [JEE 1983]
I
(A) size of the orbital
(B) spin angular momentum
S
(C) orientation of the orbital in space
(D) orbital angular momentum
Ans. (A)
O
29. Correct set of four quantum numbers for the valence (outermost) electron of rubidium (Z = 37) is [JEE 1984]
1 1 1 1
(A) 5, 0, 0,  (B) 5, 1, 0,  (C) 5, 1, 1,  (D) 6, 0, 0, 
O
2 2 2 2
Ans. (A)
30.
Ans.
31.
E
(D)
T
Which electronic level would allow the hydrogen atom to adsorb a photon but not to emit a photon ? [JEE 1984]
(A) 3s (B) 2p (C) 2s (D) 1s
The increasing order (lowest first) for the values of e/m (charge/mass) for electron (e), proton (p), neutron (n) and
alpha particle () is [JEE 1984]
(A) e, p, n,  (B) n, p, e,  (C) n, p, , e (D) n, , p, e
Ans. (D)
32. Bohr’s model can explain [JEE 1985]
(A) the spectrum of hydrogen atom only
(B) spectrum of an atom or ion containing one electron only
(C) the spectrum of hydrogen molecule
(D) the solar spectrum
Ans. (B)
ETOOSINDIA J.H. SIR
33. The radius of an atomic nucleus is of the order of [JEE 1985]

(A) 10–10 cm (B) 10–13 cm (C) 10–15 cm (D) 10–8 cm
Ans. (B)
34. Electromagnetic radiation with maximum wavelength is [JEE 1985]

(A) ultraviolet (B) radio wave (C) X-ray (D) infrared
Ans. (B)
35. Which one of the following sets of quantum numbers represents an impossible arrangement ? [JEE 1986]
A
n l m s
I
(A) 3 2 –2 1/2
(B) 4 0 0 1/2
D
1
(C) 3 2 –3
2
N
1
(D) 5 3 0 
2
Ans.
36.
(C)
(A)
1
4
(B) 4 I
The ratio of the energy of a photon of 2000 Å wavelength radiation to that of 4000 Å radiation is
S (C)
1
2
(D) 2
[JEE 1986]
O
Ans. (D)
37. Rutherford’s alpha particle scattering experiment eventually led to the conclusion that [JEE 1986]
O
(A) mass and energy are related
(B) electrons occupy space around the nucleus
T
(C) neutrons are burried deep in the nucleus
(D) the point of impact with matter can be precisely determined
Ans. (B)
E
38. The wavelength of a spectral line for an electronic transition is inversely related to [JEE 1988]
(A) the number of electrons undergoing the transition
(B) the nuclear charge of the atom
(C) the difference in the energy of the energy levels involved in the transition
(D) the velocity of the electron undergoing the transition
Ans. (C)
ETOOSINDIA J.H. SIR
39. The orbital diagram is which the Aufbau principle is violated [JEE 1988]
 
  
(A)
  

(B)
 

(C)


(D)
A
Ans. (B)
40.
Ans.
The outermost electronic configuration of the most electronegative element is
(A) ns np
(C)
2 3 2
(B) ns np 4 2
(C) ns np 5
D
2
(D) ns np 6
I [JEE 1988,90]
N
41. The correct ground state electronic configuration of chromium atom is [JEE 1989]
I
5 1 4 2 6 0 5 1
(A) [Ar] 3d 4s (B) [Ar] 3d 4s (C) [Ar] 3d 4s (D) [Ar] 4d 4s
Ans. (A)
42.
(A)
(C)
O
n
2
3
l
1
1
m
0
1
S
The correct set of quantum numbers for the unpaired electron of chlorine atom is
(B)
(D)
n
2
3
l
1
0
m
1
0
[JEE 1989]
O
Ans. (C)
T
43. Which of the following does not characterise X-rays ? [JEE 1992]
(A) The radiation can ionise gases
(B) It causes ZnS to fluorescence
Ans.
44.
E
(C) Deflected by electric and magnetic fields
(D) Have wavelengths shorter than ultraviolet rays
(C)
Which of the following relates to photons both as wave motion and as a stream of particles ?
(A) Interference (B) E = mc 2
(C) Diffraction (D) E = hv
[JEE 1992]
Ans. (D)
45. The orbital angular momentum of an electron in 2s- orbital is [JEE 1996]
1 h h h
(A)  . (B) zero (C) (D) 2.
2 2 2 2
Ans. (B)
ETOOSINDIA J.H. SIR
46. Which of the following has the maximum number of unpaired electrons ? [JEE 1996]
2+ 3+ 3+ 2+
(A) Mg (B) Ti (C) V (D) Fe
Ans. (D)
47. The first use of quantum theory to explain the structure of atom was made by [JEE 1997]
(A) Heisenberg (B) Bohr (C) Planck (D) Einstein
Ans. (B)
48. For a d-electron, the orbital angular momentum is [JEE 1997]
 h   h   h   h 
6  2  (D) 2  
A
(A) (B) (C)  
 2   2   2   2 
I
Ans. (A)
D
49. The energy of an electron in the first Bohr orbit of H-atom is –13.6 eV. The possible energy value(s) of the excited
state(s) for electrons in Bohr orbits of hydrogen is (are) [JEE 1998]
(A) –3.4 eV (B) –4.2 eV (C) –6.8 eV (D) + 6.8 eV
N
Ans. (A)
50.
Ans.
(A) (iv) < (ii) < (iii) < (i)
(A)
(B) (ii) < (iv) < (i) < (iii)
S I
The electrons, identified by quantum numbers n and l, (i) n = 4, l= 1, (ii) n = 4, l = 0, (iii) n = 3, l = 2, (iv) n = 3, l = 1 can
be placed in order of increasing energy, from the lowest to highest,as
(C) (i) < (iii) < (ii) < (iv)
[JEE 1999]
(D) (iii) < (i) < (iv) < (ii)
51.
Ans.
O O
The electronic configuration of an element is 1s2, 2s2 2p6, 3s2 3p6 3d5, 4s1. This represents its
(A) excited state
(B)
(B) ground state (C) cationic form (D) anionic form
[JEE 2000]
52.
Ans.
53.
T
If I is the intensity of absorbed light and C is the concentration of AB for the photochemical process AB+h  AB*.
The rate of formation of AB* is directly proportional to :
E
(A) C
(B)
(B) I
The number of nodal planes in a px orbital is

(C) I2 (D) C.I.
[JEE 2001]
[JEE 2001]
(A) one (B) two (C) three (D) zero
Ans. (A)
54. The wavelength associated with a golf ball weighting 200 g and moving at a speed of 5 m/h is of the order
[JEE 2001]
(A) 10–10 m (B) 10–20 m (C) 10–30 m (D) 10–40 m
Ans. (C)
ETOOSINDIA J.H. SIR
1 1
55. The quantum number  and  for the electron spin represent [JEE 2001]
2 2
(A) rotation of the electron in clockwise and anti-clockwise direction respectively
(B) rotation of the electron in anti-clockwise and clockwise direction respectively
(C) magnetic moment of the electron pointing up and down respectively
(D) two quantum mechanical spin states which have no classical analogue
Ans. (D)
56. If the nitrogen atom had electronic configuration 1s7, it would have energy lower than that of the normal ground
A
state configuration 1s2 2s2 2p3, because the electrons would be closer to the nucleus, yet 1s7 is not observed
I
because it violates [JEE 2002]
(A) Heisenberg uncertainty principle
(B) Hund’s rule
D
(C) Pauli exclusion principle
(D) Bohr postulate of stationary orbits
N
Ans. (C)
57.
S I
Rutherford’s experiment, which established the nuclear model of the atom, used a beam of
(A) -particles, which impinged on a metal foil and got absorbed
(B) -particles, which impinged on a metal foil and got scattered
(C) helium atoms, which impinged on a metal foil and got scattered
[JEE 2002]
O
(D) helium nuclei, which impinged on a metal foil and got scattered
Ans. (D)
58.
Ans. (D)
TO
Which hydrogen like species will have same radius as that of Bohr orbit of hydrogen atom
(A) n = 2 of He+ (B) n = 2 of Li+2 (C) n = 3 of Li+2 (D) n = 2 of Be+3
[JEE 2004]
E
59. The number of radial nodes in 3s and 2p respectively are [JEE 2005]
(A) 2 and 0 (B) 0 and 2 (C) 1 and 2 (D) 2 and 1
Ans. (A)
60. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a0 is Bohr radius] : [JEE 2012]
h2 h2 h2 h2
(A) 4 2ma 2 (B) 16 2ma2 (C) 322ma2 (D) 64 2ma2
0 0 0 0
Ans. (C)
ETOOSINDIA J.H. SIR
 Z2 
61. Energy of an electron is given by E = –2.178 × 10–18 J  2  .
n 
Wavelength of light required to excite an electron in an hydrogen atom from level n = 1 to n = 2 will be
[JEE 2013]
( h = 6.62 × 10–34 Js and c = 3.0 × 108 ms–1)
(A) 8.500 × 10–7 m (B) 1.214 × 10–7 m (C) 1.816 × 10–7 m (D) 6.500 × 10–7 m
Ans. (B)
62. P is the probability of finding the 1s electron of hydrogen atom in a spherical shell of infinitesimal thickness, dr, at
a distance r from the nucleus. The volume of this shell is 4r2dr. The qualitative sketch of the dependence of P on
A
r is [JEE 2016]
(A)
P
0 r
(B)
P
0 r
(C)
P
D r
(D)
P
0
I r
Ans. (B)
I N
S
Multiple Objective Type Questions
63. Many elements have non-integral atomic masses, because [JEE 1984]
(A) they have isotopes
O
(B) their isotopes have non-integral masses
(C) their isotopes have different masses
O
(D) the constituents, neutrons, protons and electrons, combine to give fractional masses
Ans. (A,C)
T
64. When alpha particles are sent through a thin metal foil, most of them go straight through the foil, because
(A) alpha particles are much heavier than electrons [JEE 1984]
(B) alpha particles are positively charged
Ans.
65.
Ans.
E
(C) most part of the atom is empty space
(D) alpha particles move with high velocity
(A,C)
The sum of the number of neutrons and proton in the isotope of hydrogen is
(A) 6
(D)
(B) 5 (C) 4 (D) 3
[JEE 1986]
66. The atomic nucleus contains [JEE 1988]

(A) protons (B) neutrons (C) electrons (D) photons
Ans. (A,B)
ETOOSINDIA J.H. SIR
67. The energy of an electron in the first Bohr orbit of H-atom is –13.6 eV. The possible energy value(s) of the excited
state(s) for electrons in Bohr orbits of hydrogen is (are) [JEE 1988]
(A) –3.4 eV (B) –4.2 eV (C) –6.8 eV (D) +6.8 eV
Ans. (A)
68. Which of the following statement (s) is (are) correct ? [JEE 1998]
5 1
(A) The electronic configuration of Cr is [Ar] 3d 4s (atomic number of Cr = 24)
(B) The magnetic quantum number may have a negative value.
(C) In silver atom, 23 electrons have a spin of one type and 24 of the opposite type. (atomic number of Ag = 47)
(D) The oxidation state of nitrogen in N3H is –3
A
Ans. (A,B, C)
69. The ground state electronic configuration of nitrogen atom can be represented by
D I [JEE 1999]

N
(A)
(B)
S I

(C)
O
(D)
Ans. (A, D)
70.
TO
The radius of the orbit of an electron in a hydrogen like atom is 4.5 a0, where a0 is the Bohr’s radius. Its orbital angular
momentum is
3h
2
. It is given that h is Planck’s constant and R is Rydberg constant. The possible wavelength(s)
when the atom de-excites is / are [JEE 2013]
Ans.
E
(A)
(A, C)
Assertion & Reason
71.
9
32R
(B)
Statement I : Zn2+ is diamagnetic.

9
16R
Statement II : The electrons are lost from 4 s orbital to form Zn .

(C)
2+
9
5R
(D)
4
3R
[JEE 1998]
(A) Statement - 1 is True, Statement - 2 is True and Statement - 2 is correct explanation for statement - 1
(B) Statement - 1 is True, Statement - 2 is True and Statement - 2 is NOT a correct explanation for statement - 1.
(C) Statement - 1 is True, Statement - 2 is False
(D) Statement - 1 is False, Statement - 2 is True.
Ans. (B)
ETOOSINDIA J.H. SIR
72. Statement I : The first ionisation energy of Be is greater than that of B. [JEE 2000]
Statement II : 2p – orbital is lower in energy than 2s.
(A) Statement - 1 is True, Statement - 2 is True and Statement - 2 is correct explanation for statement - 1
(B) Statement - 1 is True, Statement - 2 is True and Statement - 2 is NOT a correct explanation for statement - 1.
(C) Statement - 1 is True, Statement - 2 is False
(D) Statement - 1 is False, Statement - 2 is True.
Ans. (C)
Comprehension - 1
The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node. Upon absorbing light the
A
ion undergoes transition to a state S2. The state S2 has one radial node and its energy is equal to the ground state
I
energy of the hydrogen atom. [JEE 2010]
73. The state S1 is :
(A) 1s (B) 2s (C) 2p (D) 3s
Ans.
74.
(B)
Energy of the state S1 in units of the hydrogen atom ground state energy is :
(A) 0.75 (B) 1.50 (C) 2.25
N D (D) 4.50
I
Ans. (C)
75. The orbital angular momentum quantum number of the state S2 is :
S
(A) 0 (B) 1 (C) 2 (D) 3
Ans. (B)
Comprehension - 2
O
The wave function,  n,l ,m1 is a mathematical function whose value depends upon spherical polar coordinates
(r, ) of the electron and characterized by the quantum numbers n, l and m1. Here r is distance from nucleus,  is
O
colatitude and  is azimuth. In the mathematical functions given in the Table, Z is atomic number a0 is Bohr radius.
Column I Column 2 Colum 3
E T 3
 Zr 
n,l,m1(r)
 Z  2  a 
(I) 1s orbital (ii)  n,l,m1   e  0 (P)
 a0 
0
r/a0
1
(II) 2s orbital (ii) One radical node (Q) Probability density at nucleus 
a 30
5
 Zr 
 Z  2  2a 
(III) 2pz orbital (iii)  n,l,m1    re  0  cos  (R) Probability density is maximum at nucleus
 a0 
(IV) 3dz2 orbital (iv) xy-plane is a nodal plane (S) Energy needed to excite electron from n = 2
27
state to n = 4 state is times the energy needed
32
to excite electron from n = 2 state to n = 6 state
ETOOSINDIA J.H. SIR
76. For the given orbital in Column I, the only CORRECT combination for any hydrogen - like species is
(A) (I) (ii) (S) (B) (IV) (iv) (R) (C) (II) (ii) (P) (D) (III) (iii) (P)
Ans. (C)
77. For hydrogen atom, the only CORRECT combination is
(A) (I) (i) (S) (B) (II) (i) (Q) (C) (I) (i) (P) (D) (I) (iv) (R)
Ans. (A)
78. For He+ ion, the only INCORRECT combination is
(A) (I) (i) (R) (B) (II) (ii) (Q) (C) (I) (iii) (R) (D) (I) (i) (S)
Ans. (C)
Match the column
A
79. According to Bohr’s theory,
En = Total energy ,
Vn = Potential energy,
Match the following:

Column I
Kn = Kinetic energy
rn = Radius of nth orbit
Column II
D I [JEE 2006]
N
(A) Vn / Kn = ? (p) 0
I
(B) If radius of nth orbit  Enx , x = ? (q) – 1
(C) Angular momentum in lowest orbital (r) – 2
S
1
(D)  Zy , y  ? (s) 1
rn
O
Ans. A r ; Bq ; C  p, q, r ; D  s
80. Match the entries in Column I with the correctly related quantum number(s) in Column II. [JEE 2008]
Column – I Column – II
O
(A) Orbital angular momentum of (p) Principal
the electron in a hydrogen-like quantum
T
atomic orbital. number
(B) A hydrogen – like one-electron (q) Azimuthal
E
wave function obeying Pauli’s quantum
principle. number
(C) Shape, size and orientation of (r) Magnetic
hydrogen - like atomic orbitals. quantum
number
(D) Probability density of electron at (s) Electron spin
at the nucleus in hydrogen- like atom quantum
number
Ans. A p, q ; Bp,q,r,s ; C  p, q, r ; D  p, q, r

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Atomic Structure

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PREVIOUS YEAR

(planck’s constant, h = 6.63  10–34 J-s)

for an s-electron will be given by

24. The electrons identified by quantum numbers n and  : [AIEEE 2012]

quantum number (n–1). If n >> 1, the frequency of radiation emitted is proportional to

D [JEE MAIN 2013]

28. Based on the equation [JEE Main (Online) 2014]

(D) 7.50 × 104 s–1

3. The electron energy in hydrogen atom is given by E n 

Objective Type Questions

33. The radius of an atomic nucleus is of the order of [JEE 1985]

34. Electromagnetic radiation with maximum wavelength is [JEE 1985]

48. For a d-electron, the orbital angular momentum is [JEE 1997]

The number of nodal planes in a px orbital is

66. The atomic nucleus contains [JEE 1988]

when the atom de-excites is / are [JEE 2013]

Statement I : Zn2+ is diamagnetic.

Statement II : The electrons are lost from 4 s orbital to form Zn .

Match the following:

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