technical data sheet

personal care specialties

ashland.com

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bulletin VC-934

gantrez™ ester polymer series

gantrez ester polymers are multifunctional fixative and styling polymers designed for spray styling,
specifically hairsprays. gantrez ester polymers are monoalkyl esters of poly (methyl vinyl ether/maleic
anhydride). The polymethyl vinyl ether is a flexible film former while the maleic anhydride is a polar hard
monomer that contributes to bonding strength. gantrez enables the stylist or consumer to create artistic hair
styles, special effects with curling/flat irons, lift and spray volume, and sculpted styled hair.

formulator benefits formulation benefits

tough, clear glossy films, low tack, with moldable styling for waves and updos
excellent substantivity, hair holding spray and heat style; does not stick to curling/flat irons
properties and moisture resistance for hair styles with special effects
soft, natural feel in hair
film properties and solubility can be easily brushable, no/ low residue
modified by type and degree of controls frizz and fly-aways
neutralization provides shine for gloss finish
all day hold
compatible with HFC 152a, dimethyl
ether and hydrocarbon (25%), and
blends.

applications
hair styling
product forms hairspray, mist, gel, mousse,
available formulations from Ashland hairsprays, styling sprays, styling spray mousses

The information contained in this document and the various products described are intended for use only by persons having technical skill and at their own
discretion and risk after they have performed necessary technical investigations, tests and evaluations of the products and their uses. While the information
herein is believed to be reliable, we do not guarantee its accuracy and a purchaser must make its own determination of a product’s suitability for purchaser’s
use, for the protection of the environment, and for the health and safety of its employees and the purchasers of its products. Neither Ashland nor its affiliates shall
be responsible for the use of this information, or of any product, method, or apparatus described in this document. Nothing herein waives any of Ashland’s or its
affiliates’ conditions of sale, and WE MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS OF ANY PRODUCT FOR A PARTICULAR USE OR
PURPOSE. We also make no warranty against infringement of any patents by reason of purchaser’s use of any product described in this document. All
statements, information and data presented herein are believed to be accurate and reliable, but are not to be taken as a guarantee, an express warranty, or
an implied warranty of merchantability or fitness for a particular purpose, or representation, express or implied, for which Ashland Inc. and its subsidiaries assume
legal responsibility. ® Registered trademark, Ashland or its subsidiaries, registered in various countries. ™Trademark, Ashland or its subsidiaries, registered in various
countries. *Trademark owned by a third party. © 2018, Ashland.
04-2018
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chemistry

chemistry description
INCI name:
gantrez™ es-425 POLYMER-
gantrez™ es-435 POLYMER-
gantrez™ a-425 POLYMER-
gantrez™ sp-215 POLYMER-
gantrez™ es-225 POLYMER-
omnirez™ 2000 POLYMER-
gantrez™ es-335 POLYMER-
INCI: butyl ester of PVM/MA copolymer
INCI: butyl ester of PVM/MA copolymer
INCI: butyl ester of PVM/MA copolymer
INCI: ethyl ester of PVM/MA copolymer
INCI: ethyl ester of PVM/MA copolymer
INCI: ethyl ester of PVM/MA copolymer
INCI: isopropyl ester of PVM/MA copolymer

typical properties
appearance solid version available
solubility alcohol
color clear
solids 50%
shelf life 24 months

formulation guidelines

recommended use levels 0,5 – 7% solid level

temperature/mixing anionic polymer neutralization required

conditions % of Neutralizer =
(Formula % Polymer)(%Conc.) X (Eq.Wt.Neut.) X (Desired %Neut.)
(Eq.Wt. Polymer) (100)
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when to add 10 – 15% anhydrous aerosol hairsprays

15 – 20% 80% VOC aerosol hairsprays
30 – 40% hydroalcoholic formulations (gels, mousses etc) and products for
application to wet hair

tips from our technical tough, clear glossy films, low tack, with excellent substantivity, hair holding
solvers properties and moisture resistance

film properties and solubility can be modified by type and degree of

neutralization
compatible with aerosol propellants, nonionic thickeners, and cationic
polymers (neutralize gantrez™ prior to combining)

safety, handling, and storage

It is recommended to store in a tightly closed container.

Additional information concerning safety, handling and storage is supplied in the safety data sheet, which
can be made available upon request. Such information includes:
o classification and labelling information
o protective measures for storage and handling
A toxicology summary can also be made available, on a confidential basis, by contacting Ashland’s
toxicology department.

regulatory

CAS No.

gantrez™ es-425 POLYMER- 25119-68-0 25087-06-3

gantrez™ es-435 POLYMER- 25119-68-0 31307-95-6
gantrez™ es-215 POLYMER- 25087-06-3
gantrez™ es-225 POLYMER- 25087-06-3
gantrez™ es-335 POLYMER- 31307-95-6

Other regulatory information can be made available on request.