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CORROSION: GALVANIC CORROSION
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When two different metals are immersed in a corrosive solution, each will develop a
Stainless Steel Directory corrosion potential. If the corrosion potential of the two metals is significantly
different, and they are in direct contact and immersed in an electrolyte, the more
Stainless Steel Overview noble metal will become the cathode and the more active metal will become the
anode. A measurable current may flow between the anode and the cathode. The
Composition/Properties corrosion rate of the anode will be increased and the cathode decreased. The
increased corrosion of the anode is called "galvanic corrosion".
Information Handbooks
Finishes Requirements for Galvanic Corrosion:
Corrosion
In order for galvanic corrosion to occur, three elements are required.
Fabrication
Structural Design 1) Dissimilar metals
2) Metal-to-metal contact
Fasteners 3) Metals in the same conduction solution (usually called an electrolyte)
Cathodic
The greater the separation between the two metals listed, the greater the corrosion
potential. For example, if zinc (think galvanized steel) which is an active material
and near the top of the list and stainless steel, a noble metal and near the bottom of
the list were in direct contact and in the presence of an electrolyte (water), galvanic
corrosion will probably occur.
In addition to the three elements sighted above, the relative area of each of the
exposed metal surfaces is also a consideration (see Figure below). If the area of the
cathode (noble metal) is very large, and the anode (active metal) is very small, the
current produced is likely to be very high and the anode will corrode quickly. For
http://www.ssina.com/corrosion/galvanic.html 11/29/2011
SSINA: Stainless Steel: Corrosion Page 2 of 2
current produced is likely to be very high and the anode will corrode quickly. For
example, if there is a window frame made of stainless steel and it is attached with
carbon steel screws, the screws will probably corrode. If the area of the cathode
(noble metal) is very small, and the anode (active metal) is very large, the current
produced will be very low and the anode will corrode very slowly, if at all. If the
window frame is made of carbon steel and it is attached with stainless steel screws
there will be very little, if any, corrosion.
For technical help, go to the SSINA KnowledgeBase and the Nickel Development
Institute at www.nidi.org Stainless Steels in Architecture, Building and
Construction "Guidelines for Corrosion Prevention."
http://www.ssina.com/corrosion/galvanic.html 11/29/2011