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The first is endothermic and the last two are exothermic processes.
U1 M3 Group VII elements page 2 of 4
-1
The total energy change (kJ mol ) from these three processes are:-
fluorine -775 chlorine -607 bromine -580 iodine -541
Since the fluoride ion shows the most negative enthalpy, it is the most
stable i.e. the most readily formed which translates to the most reactive
halogen, while iodine shows the least negative enthalpy change and this
means it is the least reactive halogen.
Table #1: Showing reaction of halides with aqueous ammonia and conc.
sulphuric acid
In reaction one, chlorine forms the chloride ion and the chlorate(I) ion.
While in reaction 2, chlorine forms the chloride ion and the chlorate (V)
ion. It is an example of disproportionation.
Worksheet
U1 M3 Group VII elements page 4 of 4