2.4.1.

- Ecuación de Peng - Robinson

𝑅𝑇 𝑎𝛼
𝑃= − 𝑬𝒄. 𝟐. 𝟔𝟑
𝑉 − 𝑏 𝑉(𝑉 + 𝑏) + 𝑏(𝑉 − 𝑏)

𝑅 2 𝑇𝑐𝑖 2
𝑎𝑖 = 0.45724 𝑬𝒄. 𝟐. 𝟔𝟒
𝑃𝑐𝑖

𝑅𝑇𝑐𝑖
𝑏𝑖 = 0.0778 𝑬𝒄. 𝟐. 𝟔𝟓
𝑃𝑐𝑖

2
𝑇
𝛼𝑖 = [1 + 𝑆𝑖 (1 − √ )] 𝑬𝒄. 𝟐. 𝟔𝟔
𝑇𝑐𝑖

𝑆𝑖 = 0.37464 + 1.54226𝜔 − 0.26992𝜔2 𝑬𝒄. 𝟐. 𝟔𝟕

𝑛 𝑛

𝑎𝛼 = ∑ ∑ 𝑦𝑖 𝑦𝑗 (𝑎𝛼)𝑖𝑗 𝑬𝒄. 𝟐. 𝟔𝟖
𝑖=1 𝑗=1

(𝑎𝛼)𝑖𝑗 = √𝑎𝑖 𝑎𝑗 𝛼𝑖 𝛼𝑗 𝑬𝒄. 𝟐. 𝟔𝟗

𝑏 = ∑ 𝑥𝑖 𝑏𝑖 𝑬𝒄. 𝟐. 𝟕𝟎

𝑎 𝑖 𝛼𝑖 𝑃
𝐴𝑖 = 𝑬𝒄. 𝟐. 𝟕𝟏
𝑅2𝑇 2

𝑏𝑖 𝑃
𝐵𝑖 = 𝑬𝒄. 𝟐. 𝟕𝟐
𝑅𝑇

𝑛 𝑛

𝐴 = ∑ ∑ 𝑦𝑖 𝑦𝑗 𝐴𝑖𝑗 𝑬𝒄. 𝟐. 𝟕𝟑
𝑖=1 𝑗=1
 𝐴𝑖𝑗 = √𝐴𝑖 𝐴𝑗 𝑬𝒄. 𝟐. 𝟕𝟒

𝐵 = ∑ 𝑥𝑖 𝐵𝑖 𝑬𝒄. 𝟐. 𝟕𝟓

𝐿𝑛𝜑𝑖𝑠 = 𝑧𝑖 − 1 − 𝐿𝑛(𝑧𝑖 − 𝐵𝑖 )
𝐴𝑖 𝑧𝑖 + 2.414𝐵𝑖
− 𝐿𝑛 ( ) 𝑬𝒄. 𝟐. 𝟕𝟔
2√2𝐵 𝑖 𝑧𝑖 − 0.414𝐵𝑖

𝐵𝑖
𝐿𝑛𝜑̂𝑖𝑉 = (𝑧 − 1) − 𝐿𝑛(𝑧 − 𝐵)
𝐵
𝑛
𝐴 𝐵𝑖 2 𝑧𝑖 + 2.414𝐵
+ [ − ∑ 𝑦𝑗 (𝑎𝛼)𝑖𝑗 ] 𝐿𝑛 ( ) 𝑬𝒄. 𝟐. 𝟕𝟕
2828𝐵 𝐵 𝑎𝛼 𝑧𝑖 − 0.414𝐵
𝑗=1