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SUBJECT ANNEXURE(S) PAGES TIME

3
CHEMISTRY I 2 HOURS

09h00
CODE DATE MARKS to
12:00
CMY150S /CMY150X 29 October 2018

FACULTY OF APPLIED SCIENCES

SEMESTER 2 TEST

COURSES: ND: FOOD SCIENCES AND TECHNOLOGY

(Mainstream and extended)

EXAMINER : Dr N Darangwa
Mrs. S Adonis
MODERATOR (INTERNAL) : Mr L Anthony
MODERATOR (EXTERNAL) :

SPECIAL INSTRUCTIONS

 Answer ALL questions.

 Calculators are allowed.

REQUIREMENTS

 Calculators

 Periodic Table

DO NOT TURN THE PAGE BEFORE THE STARTING TIME

Question 1
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1.1 Match the following gas laws with the equation representing them.
Column A Column B

1.1.1) Boyle’s law (A) V∝n at constant T and P

(B) pTotal= P1 +P2 + P3+.... at constant

1.1.2) Charles’s law T, V

1.1.3) Dalton’s law (C) = Constant

(D) V ∝ T at constant n and P

(E) P ∝ at constant n and T

(3)

1.2 A toy balloon filled with air has an internal pressure of 1.25 atm and a volume of

2.50 L. If I take the balloon to the bottom of the ocean where the pressure is

95 atmospheres,

1.2.1) what will the new volume of the balloon be? (3)

1.2.2) how many moles of gas does the balloon hold? (Assume T = 285 K) (3)

1.3 Classify each of the following materials as ionic, metallic, molecular or covalent.
State the forces of attraction between particles?
1.3.1 graphite
1.3.2 H2O
1.3.3 CaCl2 (6)
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Question 2

2.1 A 0.258 g piece of potassium solid is placed into water inside of a coffee cup
calorimeter resulting in a vigourous reaction. Assume a total volume of 100 mL
for the resulting solution. The temperature of the solution changes from 22 °C to
25.1 °C due to the reaction. How much heat is generated per gram of potassium
for this reaction? Assume the density of the solution after the reaction is the
density of water and that the heat capacity of the solution and reaction vessel is
only due to the water that has a specific heat of 4.184 J/g-°C. (6)

2.2 Ammonia burns in the presence of a platinum catalyst to produce nitric oxide, NO.

4 NH3 (g) + 5 O2 (g)  4 NO (g) + 6 H2O (g)

What is the heat of reaction at constant pressure? Use the following

thermochemical equations:

(1) N2 (g) + O2 (g)  2 NO (g) H = +180.6 kJ

(2) N2 (g) 3 H2 (g)  2 NH3 (g) H = -191.8 kJ

(3) 2 H2 (g) O2 (g)  2 H2O (g) H = -483.7 kJ (5)

2.3 The following rate data were obtained at 25°C for the following reaction.
What is the rate law expression? What is the overall order of the reaction?

2A + B → 3C

Experiment [A]0(mol/L) [B]0(mol/L) Initial Rate(mol/L•s)

1 0.10 0.10 2.0 × 10 -4
2 0.30 0.30 6.0 × 10-4
3 0.10 0.30 2.0 × 10-4
4 0.20 0.40 6.0 × 10-4
(8)

2.4 At a certain temperature, 3.0 mol of F2 and 2.0 mol of I2 are placed into a 10.0 L
container. At equilibrium, the concentration of IF5 is 0.020 mol/L. Calculate K c for
the reaction. (6)
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Question 3

3.1 4.60 g of potassium hydroxide is dissolved in enough water to give 400 mL of

solution. Assuming that the salt dissolves completely, calculate the pH of the
solution. (9)

3.2 Calculate the pH of a 0.75 M ethylamine (C2H 5NH2) solution.

Ka (C2H5NH3+) = 1.56 x 10-11 and Kw = 1.00 x 10-14. (4)

3.3 Titration of 0.2121 g of pure Na 2C2O4 (Mr = 134 g/mol) required 43.31 mL of
KMnO4. What is the molarity of the KMnO4 solution? The chemical equation is:

2 MnO4- + 5 C2O42- + 16 H+  2 Mn2+ + 10 CO2 + 8 H2O

(4)
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Question 4
4.1 Balance the following redox reaction in acidic medium.

Cr(OH)3 + IO3-  I- + CrO42- (6)

4.2 The cell notation for a standard chromium-iron electrochemical cell is:

Zn(s)/Zn 2+(aq)// Ag+(aq)/Ag(s)

4.2.1 Write oxidation and reduction half – equations and the overall cell equation
for this redox reaction. (3)
4.2.2 Calculate Ecell. Is the reaction spontaneous or non- spontaneous?
(2)

4.3 Calculate the oxidation number of each of the underlined elements in the
following compounds.
4.3.1 H4P2O7 (2)
4.3.2 C2O7 (2)
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Question 5

Question 5

5.1 Draw structures (line format or otherwise) for the following compounds:

5.1.1 5-bromo-4-oxopentanal
5.1.2 4-nitro-2-methyl-octa-2-ene-5-yne
5.1.3 deca-2-ene-7-yne
5.1.4 hept-3-one
(4x2=8)

5.2 Name the following compounds according to IUPAC rules:

5.2.1
Cl
H3 C CH CH (CH2)2 C C CH3
Cl

5.2.2
Cl
HO
CH3
CH3
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5.2.3

Br

5.2.4
Br NO2
Br
Cl
Cl
(4x2=8)

5.3 Write down the reaction and products for the following:

5.3.1 OH
KMnO4

(2)

5.3.2 O + H2
(2)

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Total Marks = 110