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Greenhouse films
Agenda
Introduction
The opportunity
Exploring film solutions
Working together
2
World population in 2017 World population in 2040
7 billion 9 billion
3
Source: ExxonMobil 2018 Outlook for Energy
Creating differentiated Enabling progress and
solutions. Together. prosperity to make life better.
4
EM agriculture film
solutions
• Greenhouse
• Silo Bag
• Silage stretch
• Mulch
5
Performance greenhouse films
help increase yield of crops and expand
growing season with efficient use of
resources that are more sustainable
6
Haze potentially less than 5%
Refer solution: Exceed™ XP performance polymer 160 micron film
- high thermicity slide 44
7
Upto
LDPE replacement
30%
8
Refer Exceed™ XP performance polymer 80 micron film solution,
slide 38
- $3m
$3m
Potential cost savings per year
$15m $12m
Reference ExxonMobil
solution solution
Reference business size for calculation purpose is 10KT, refer more details in ViU calculator slide 60 9
Opportunity
10
Agriculture film market overview
7.3%
% Global demand in China
>60 %
North Latin Europe Middle East, China Rest of Asia India
America America & Africa
Mexico
Greenhouse Mulch Silage
11
Source: AMI & EM estimates
Agriculture film market segmentation
12
Source: EM estimates
Greenhouse film segmentation
Market size
14%
0.3 mT 86% 2 mT
Sub-segment Coated functional film EVA-based functional film PE-based functional Other PE GH film
13
*LTR – Light transmission rate
Source: EM estimates
Greenhouse film trends Performance polymers deliver:
Downgauging opportunity
Monolayer Multilayer
Longer lasting films
Tougher greenhouse films
14
Value chain considerations in the greenhouse market
OEM Distributors Associations/governments
15
Key attributes in the greenhouse market
16
*Light transmission rate
Exploring film solutions
17
Performance polyethylene product portfolio
Mechanical properties
When eXtreme Performance For superior mechanical Exceed™
matters, for step-out mechanical performance with outstanding
performance and excellent mechanical and sealing properties LLDPE Enable™
processability combined with best-in-class optics
LLDPE
blends LDPE
Enable™ performance Escorene™ Ultra EVA blends
LDPE
polymer
For optimum balance for For high thermicity in extreme
processing and bubble stability cold and easier film processing Processability
with HAO properties Escorene Ultra EVA in greenhouse
18
ExceedTM XP, ExceedTM and EnableTM performance polymer
Aging performance of EM performance polymer
Total Cl exposure
Total S exposure
UV aging test within a WOM according to ISO 4892-2 2000 100
(ppm)
(ppm)
• WOM chamber temperature: 38 °C & Humidity: 50%
• Irradiance: 0.5 W/m2 @ 340 nm 1000 50
• S based pesticide simulant: Sulphurous acid solution (H2SO3)
• Cl based pesticide simulant : Permethrin solution
• Tests were performed at NORNER (Norway) 0 0
0 1000 2000 3000 4000
WOM exposure (h) 19
DRY aging- Exceed™ XP and Enable™ performance polymers WET aging: Enable™ performance polymer vs LDPE , C4- View solution ›
View solution ›
160 µm vs. LDPE reference 200 µm (impact of downgauging) LLDPE /LDPE blend, C8-LLDPE /LDPE blend 180 µm
DRY aging - Exceed™ XP and Enable™ performance polymer vs. WET aging- Exceed™ XP and Enable™ performance polymers View solution ›
View solution ›
C8LLDPE 160 µm 160 µm vs. LDPE reference 200 µm (impact of downgauging)
20
ExceedTM XP and EnableTM performance polymer
Aging performance of Enable™ performance polymer AP Global Aging data
Tensile @ break-MD
60
50
• Excellent weatherability proved by lab aging tests (WET aging) 40
(MPa)
- Better toughness and aging performance than C8-mLLDPE 30
and higher gauge LL/LD blends 20
- Better and stable optical performance 10
0
• Field cladding aging tests, certified by CAFA, further validated 0 1000 2000 3000 4000
the superior optical, mechanical and aging performance of WOM exposure (h) 300 KLY
ExceedTM XP performance polymer in greenhouse films.
0
5
10
Haze (%)
15
20
25
0 1000 2000 3000 4000
WOM exposure (h) 300 KLY
Exceed XP 6026 + 2%UV@80µm
Exceed XP 6056 + 2%UV@80µm
Greenhouse of Exceed XP 6056 at aging cladding test field Enable 2005 + 2%UV@80µm
C8-mLLDPE + 2%UV@80µm
ExceedTM XP and EnableTM performance polymer Data from tests performed by or on behalf of ExxonMobil 74% C4-LLDPE + 24%LDPE + 2%UV @100µm
Aging performance of EM performance polymer (new study) AP Global Aging data
20 160 µm
0 0
0 1000 2000 3000 4000 5000 0 1000 2000 3000 4000 5000
KLY: 0 85 170 255 340 425 KLY: 0 85 170 255 340 425
vs C8-LLDPE ref
UV-aging of film in a pesticide environment (DRY aging*)
Elongation @ break - MD (retension %)-DRY aging Carbonyl index - DRY aging
0.2
100
160 µm 160 µm
80 0.15 160 µm
60 160 µm 0.1
40 Film failure zone + 160 µm
160 µm
0.05
20
0 0
0 1000 2000 3000 4000 5000 0 1000 2000 3000 4000 5000
KLY: 0 85 170 255 340 425 KLY: 0 85 170 255 340 425
• Superior aging performance with thinner films using EM performance polymer (no failure yet)
200 µm
160 µm
0.05
160 µm
0.025
0
0 1000 2000 3000 4000 5000 6000 7000
KLY: 0 85 170 255 340 425 510 600
WOM exposure (h) *only rain cycle exposure / no pesticide exposure
• Superior aging performance with thinner films using EM performance polymer (no failure yet)
Reference polymer (100% LDPE (0.922d,0.33MI)) – 200 µm mono film
Reference polymer (100% C8-LLDPE (0.920d,1MI)) – 160 µm mono film
Exceed™ XP 6026 performance polymer– 160 µm mono film
Enable™ 2005 performance polymer– 160 µm mono film
+All films contains 1.2% of HALS & 0.1% UV abs (same ppm level) ExceedTM XP and EnableTM performance polymer Data from tests performed by or on behalf of ExxonMobil
Asia Pacific
5-layer functional film concept Reference: C4-LLDPE + LDPE, 100pm, Layer ratio 1/1/1
Prolonged functional performance via
View solution ›
controlled-release of anti-drip
28
ExceedTM XP and EnableTM performance polymer
Winter greenhouse
Asia Pacific
29
Winter greenhouse Asia Pacific
0N 5N 10N 15N 20N 25N 30N 35N 40N 45N 50N 55N
Up to 1.3x
Tensile at break MD
Elmendorf tear TD
0g 200g 400g 600g 800g 1000g 1200g
Up to 1.4x
Tear resistance TD
50% 45% 40% 35%
Thermicity
Dart impact
0g 150g 300g 450g 600g 750g 900g 1050g
Up to 2x
Dart impact
0N 5N 10N 15N 20N 25N 30N 35N 40N 45N 50N 55N
Tensile at break MD
XX%
Up to 25%
Stronger
0N 10N 20N 30N 40N 50N
Tensile strength MD with Exceed XP
Tensile at break TD
Up to 5%
Thermicity
Dart impact
0g 250g 500g 750g 1000g 1250g 1500g
Up to 2.7X
Dart impact
34
Spring greenhouse Asia Pacific
Tensile at break MD
[0-70N]
Enable™ 2010 performance polymer based
excellent mechanical strength solution:
• Higher tensile strength
• Higher tear resistance
• Higher dart impact
Dart impact Tensile at break TD
[0-700g] [0-70N] Enable™ 2010 performance polymer based
down-gauging solution:
• >20% down-gauging
• Improved dart impact
• Excellent optics
Tensile strength MD
Up to 1.8-2.6x
Haze
micron film
Exceed™ XP performance polymer offers:
Tensile at break MD • Exceptional melt strength with minimized LDPE
[0-70N]
(upto 30% LDPE replacement)
• Exceptional strength with D/G
• Excellent aging performance
micron film
+Strength
0g 100g 200g 300g 400g 500g 600g
Elmendorf tear MD
XX%
More resistant
Up to 1.4x tensile strength MD
0g 250g 500g 750g 1000g 1250g 1500g Up to 2.9x tear resistance MD
Elmendorf tear TD
Up to 4.1x dart impact
Reference: C8-LLDPE + LDPE/HEVA/C8-LLDPE + LDPE, 200µm, layer ratio 1/2/1 Reference: C8-LLDPE + LDPE, 200µm, layer ratio 1/2/1
39
ExceedTM XP and EnableTM performance polymer
Winter greenhouse
Global
40
Winter greenhouse
Up to 40%
Tensile at break MD
Up to 50%
Elmendorf tear MD
Haze
27% 22% 17% 12% 7%
Up to 60%
Improvement in dart impact
0g 250g 500g 750g 1000g 1250g 1500g
Dart impact
Thermicity Elmendorf tear TD Outer35% C8-LLDPE (MI 1.0, 0.920d) 100% Exceed XP 6026
[50-20%] [0-2000g] 65% LDPE (MI 0.33, 0.922d)
Core 100% HEVA (VA% 13%, MI 0.3) 100% FL00018
Inner 35% C8-LLDPE (MI 1.0, 0.920d) 100% LEVA (VA% 4.5%, MI 0.9)
65% LDPE (MI 0.33, 0.922d)
43
For Exceed XP processability data, please click on processability link on dashboard or refer to slides 58 and 59
Data from tests performed by or on behalf of ExxonMobil
Winter greenhouse EMEAF
Up to 4%
Elmendorf tear TD
Dart impact
0g 250g 500g 750g 1000g 1250g 1500g
Up to 60%
Improvement in dart impact strength
Reference Exceed™ XP 6026 44
200µm performance polymer, 160µm
Data from tests performed by or on behalf of ExxonMobil
Winter greenhouse
Inner skin layer 75% EVA 1 (VA 9.5%) + 25% EVA 2 (VA 6.5%) 45
46
Spring greenhouse
0N 10N 20N 30N 40N 50N 60N 70N 80N 90N 100N 110N
Tensile at break MD
Up to 20%
0N 10N 20N 30N 40N 50N 60N 70N 80N 90N 100N 110N
Downgauging opportunity
Tensile at break TD
Up to 2X improvement
0g 600g 1200g 1800g 2400g 3000g 3600g tear resistance MD
Elmendorf tear TD
Dart impact
0g 300g 600g 900g 1200g 1500g
Up to 75%
Improvement in dart impact
Delivered attributes
≥20% downgauging opportunity
Derived benefits
• Unit cost reduction
• Raw material savings
Less than 5% haze
30%
• Reduce or eliminate LDPE
Enhanced film optical properties • Faster temperature rise in greenhouse Up to
• Increase land productivity
Oustanding melt strength • Excellent bubble stability with minimized use of LDPE
LD replacement
• Support bigger size of bubble
$3M
Excellent processability • Excellent extrudability
• Easy transition with reduced time Up to
• Possible energy saving
Excellent aging property • Better weatherability Savings in use
• Maintained optical property and strength during service period
49
Working together
50
Defining our next steps
51
Collaborating with the value chain
Catalyst Process
research technology
Value creation
Application
expertise
52
Creating differentiated
solutions. Together.
53
Test Test method based on
MI (Melt Index) ASTM D-1238
Melt Strength ExxonMobil method
Melt Viscosity (SAOS) ExxonMobil method
Density ASTM D-4703 / D-1505
Haze ASTM D-1003
Light Transmission Rate ASTM D-1003
Thermicity (IR Transmittance) ExxonMobil method
Tensile at Break ASTM D-882
Elongation at Break ASTM D-882
Elmendorf Tear ASTM D-1922
Dart Impact ASTM D-1709
Creep Resistance ExxonMobil method
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Portfolio
Escorene™ Ultra EVA in greenhouse films
EVA in winter greenhouse film Escorene Ultra EVA copolymer grades
• Thermal insulation Grade VA% MI
• Excellent processability
• Exceed XP 6026 provides high melt strength
and great bubble stability
• Exceed XP 6056 allows high extrusion rate
• Extreme toughness
Melt strength at 190 °C
• Exceptional optics
Tensile at break
MD (0 - 60N)
• Minimize usage of LDPE with excellent
bubble stability Dart impact (0 - Tensile at break
650g) TD (0 - 65N)
• Exhibit superior mechanical strength
• Enhanced tensile strength
• Higher tear and puncture resistance Puncture Energy Elmendorf Tear
• Greater dart impact (0- 8J) MD (0 - 1050g)
Reference EM solution
Processing
BUR 2.6, throughput 600 kg/h
parameters