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H. E. Cubuklusu
CMS Jant ve Makina San. A.S., R&D Centre, Cigli, Izmir, Turkey
Abstract
The heat-treated AlSi7Mg0.3 alloy is the standard wheel of the latter is believed to offer better feeding character-
alloy as it offers the best compromise between fatigue istics, which in turn improves the soundness of the casting
strength and elongation. Alloys with less than 7 wt% Si and thus leads to superior structural quality and mechan-
may also be of interest for the manufacture of aluminium ical properties. An overall industrial assessment favours
wheels to limit Si poisoning that impairs grain refinement. the standard Al7Si0.3 Mg alloy in the manufacture of light
Hence, the potential of AlSi5Mg0.3 alloy was investigated alloy wheels.
as it could offer superior mechanical properties owing to a
smaller grain structure. AlSi5Mg0.3 alloy does indeed Keywords: Al–Si casting alloys, automotive, grain
exhibit smaller grains but fails to offer higher mechanical refinement, microstructure
properties. AlSi7Mg0.3 alloy with a smaller dendritic
structure but coarser grains is superior. The higher fluidity
Among the forged and cast varieties, the latter enjoy a high Non-heat-treatable, near-eutectic AlSi11 Mg alloys with
styling versatility, dimensional accuracy, adequate 11–12% Si were also used during 1980s, particularly in
mechanical properties under static and dynamic loading Germany and Italy.1 Investigations carried out with dif-
conditions.5 Cast aluminium wheels produced with the ferent Si contents clearly demonstrated that an increase in
low-pressure die casting (LPDC) process are also popular Si has an adverse effect on ductility, particularly at low
in spite of inferior mechanical properties with respect to the rates of solidification encountered in thick hubs.12,13 Yet,
forged counterparts.6,7 alloys with 9–11% Si are still employed when castability is
critical.1,2 Alloys with less than 7 wt% Si may also be of
interest for the manufacture of aluminium wheels.3 The
M. Kaba, A. Donmez, A. Cukur, and A. F. Kurban are undergraduate grain size of Al–Si-based alloys increases with increasing
students.
Table 1. Chemical Composition of the AlSiMg Alloys Investigated in the Present Work (wt%) (Chemistry Before
Master Alloy Additions)
Si Fe Mg Ti Sr Mn B Cu Al
AlSi7Mg0.3 6.83 0.10 0.28 0.107 0.023 0.004 0.0016 0.003 Bal.
AlSi5Mg0.3 4.91 0.09 0.28 0.099 0.020 0.004 0.0017 0.001 Bal.
practices. They were ground with SiC paper and polished silicon fibres thanks to an effective modification in both
with diamond paste to a 0.25-micron finish. Their alloys.13,22 Sr addition is credited for this structural
microstructures were examined after etching with a 0.5% refinement since the cooling rate during solidification of
HF solution using an Olympus GX41 model optical the hub region does not suffice to offer thermal modifica-
microscope. The grain structures were checked after etch- tion.11 It is evident from Figure 4 and SDAS measurements
ing in a solution of iron (III) chloride hexahydrate from various sections of cast samples that the dendritic
(Cl3FeH12O6). Some samples were anodized in Barker’s structure in the standard wheel alloy, AlSi7Mg0.3, is
solution, 5 ml HBF4 (48%) in 200 ml water, and were markedly smaller with respect to the potential wheel alloy,
examined under polarized light to facilitate precise grain AlSi5Mg0.3. The SDAS values were measured in the as-
size measurements. cast state to be 74.3 ± 8 lm and 55.7 ±12 lm for
AlSi5Mg0.3 and AlSi7Mg0.3 alloys, respectively
(Table 2). Increase in the Si and in the overall alloy content
Results and Discussion of aluminium melts are known to lead to a considerable
refinement of the dendritic structure.23–26 Evidently, the
The as-cast microstructures of the AlSi5Mg0.3 and volume fraction of the inter-dendritic eutectic phase is
AlSi7Mg0.3 alloys are illustrated in Figure 4. The eutectic relatively higher in the AlSi7Mg0.3 alloy as expected
silicon plates have apparently transformed into small owing to a higher Si content.
Figure 3. Spiral mould used to measure fluidity (a) and the pouring cup (b).
The grain structures of the Al5Si0.3 Mg and Al7Si0.3 Mg the solution heat treatment (Table 3). The favourable effect
alloys cast under exactly the same conditions with and of grain refinement is reflected also by the improvement in
without the benefit of grain refinement are shown in Fig- mechanical properties of the grain-refined alloys with
ure 5. The grain sizes before grain refinement were mea- respect to the unrefined counterparts (Table 4; Figure 6).
sured to be 983.6 ± 96 and 1432.8 ± 134 lm, for The tensile strength and the elongation values, in particu-
AlSi5Mg0.3 and AlSi7Mg0.3 alloys, respectively, while lar, have enjoyed a considerable increase upon grain
they were 481.5 ± 51 and 731.1 ± 96 lm after grain refinement. However, the underlying issue regarding grain
refinement (Table 3). The grain size is apparently halved size measurements is that the Al5Si0.3Mg alloy, whether
upon grain refinement in both alloys implying a modest grain refined or not, enjoys a relatively smaller grain
refinement effect of the AlTi5B1 master alloy in the wheel structure with respect to the Al7Si0.3Mg alloy, confirming
alloys. The grain size measurements in the heat-treated the impact of Si content of the alloy on grain refinement via
state suggest that there has been no grain coarsening during poisoning effect (Figure 5).17
Table 2. SDAS Measurements (lm) however, are too small to be directly resolved at optical
As-cast Heat-treated (T6 ? PB) microscope magnifications and is evidenced only by the
increasing contrast across the matrix grains. The Fe-based
AlSi5Mg0.3 74.3 ± 8 76.7 ± 11 inter-metallic particles with plate-like morphologies that
AlSi7Mg0.3 55.7 ± 12 52.5 ± 8 are typical of aluminium foundry alloys and held partially
responsible for their poor mechanical properties are hardly
encountered in the two alloys investigated in the present
work (Figures 8e, f). This is attributed to the precise con-
The grain structures of the grain-refined alloys are illus- trol of Fe content (\ 0.1 wt% Fe) in both AlSi7Mg0.3 and
trated also with the Barker micrographs in Figure 7. It is AlSi5Mg0.3 alloys (Table 1).
striking to note the relatively coarser grains in spite of
relatively smaller dendrites in the AlSi7Mg0.3 alloy. The fluidity test was employed using the spiral flow casting
AlSi5Mg0.3 alloy, on the other hand, exhibits smaller mould with a precise control of the mould temperature, the
grains yet coarser dendrites. Since the two samples were melt temperature and the flow rate. The average fluidity
cast under exactly the same conditions with the same lengths for the AlSi5Mg0.3 and AlSi7Mg0.3 alloys were
cooling rates, this structural characteristic is attributed to estimated to be 194.0 ± 14.7 and 205.0 ± 10.5 cm,
the Si content of the two alloys and thus to the constitu- respectively (Figure 9). Typical section micrographs
tional undercooling effect. showing the distribution of shrinkage porosity in the
investigated alloys are given in Figure 10. The higher
The Si fibres in the as-cast samples have transformed into fluidity of the AlSi7Mg0.3 alloy is credited for the much
small, discrete eutectic silicon particles and have under- less shrinkage porosity of this alloy.
gone some coarsening after the solution heat treatment in
both alloys.2 (Figure 8). Heat treatment results in the for- Typical stress–strain curves obtained from tensile tests of
mation of a uniform distribution of fine Mg2Si precipitates AlSi5Mg0.3 and AlSi7Mg0.3 alloys in the as-cast and heat-
across the solid solution matrix dendrites as suggested by treated states are illustrated in Figure 11. Yield (YS),
the hardness measurements (Table 4). These precipitates, ultimate tensile strength (UTS) and tensile elongation (EL)
Table 4. Tensile Test Results, Hardness and Impact Energy Measurements of Samples Cast with and Without Grain
Refinement. Tensile Properties and Hardness Values that Exceed in the Required Range are Shown Bold
Alloy Process YS (MPa) UTS (MPa) A5 (%) Hardness (HB) Impact energy (J)
values as well as hardness and impact energy measure- data for a low Si (4.1%) material poured using those same
ments for these alloys are listed in Table 4 and are plotted ASTM permanent moulds. While this may imply some
in Figures 12 and 13. The tensile properties of AlSi5Mg0.3 methodological problems in the experiments, a fair com-
alloy are lower than those listed in the American Foundry parison of the tensile test results shows that the
Society (AFS) Casting Alloy Data Search (CADS) data- Al7Si0.3 Mg alloy offers relatively higher yield and ulti-
base that involved Static and Cyclic (Strain Life fatigue) mate tensile strength as well as elongation values with
120
100
80
60
40
20
0
200
180
b AlSi5Mg0.3 AlSi7Mg0.3
160
140
UTS (MPa)
120
100
80
60
40
20
0
9
8
c AlSi5Mg0.3 AlSi7Mg0.3
7
6
EL (%)
5
4
3
Figure 7. Barker micrographs illustrating grain struc-
2 tures of grain-refined (a) AlSi5Mg0.3 and (b) AlSi7Mg0.3
1 alloys.
0
unrefined grain-refined unrefined grain-refined in Table 4. The yield and ultimate tensile strength values of
the standard AlSi7Mg0.3 wheel alloy exceed the minimum
Figure 6. (a) Yield (YS), (b) ultimate tensile strength
(UTS) and (c) elongation (EL) values of AlSi5Mg0.3 and requirements of all car manufacturers. It is thus fair to
AlSi7Mg0.3 alloys before and after grain refinement. conclude that the AlSi7Mg0.3 alloy stands out in terms of
mechanical properties.
respect to the Al5Si0.3Mg alloy in both as-cast and heat-
treated states. Silicon, which contributes little to the strength of alu-
minium casting alloys alone, offers an effective level of
Marked increases in the tensile strength values were strengthening when combined with magnesium to form
accompanied by reductions in the elongation values in the Mg2Si. While the Si content of the two alloys is different,
heat-treated state, as typically encountered in age-hardened this is not expected to cause any change in the strength-
aluminium alloys. The Charpy impact energy values are ening potential as the strength/hardness properties are
quite similar in the as-cast and heat-treated states and fall in dictated by the Mg, rather than the Si, content. After all, the
the range of values reported in the literature for modified and Si level in both alloys is far more than that required to
permanent mould cast A 356 alloy.27–29 The comparable convert the entire Mg into the hardening phase, Mg2Si.
impact energies before and after the heat treatment suggest
that the structural improvement via the thermal modification Silicon particle colonies and their relatively low resistance
of Si particles overrides the effect of age hardening. The to fracture are often blamed for the failure of the heavily
comparable elongation and similar impact energy values of loaded sections of Al–Si-based castings. However,
the Al7Si0.3 Mg alloy in the heat-treated state imply higher AlSi7Mg0.3 alloy does not appear to suffer lower elonga-
ductility, a very favourable feature under dynamic loading tions in spite of a higher volume fraction of eutectic Si
conditions. The range of tensile properties and hardness particles which inevitably leads to a smaller inter-particle
values required by different car manufacturers are also listed spacing. Sr modification in addition to an adequate solution
treatment is believed to have played a key role in was found to offer higher yield and ultimate tensile
improving both the crack initiation and the crack propa- strength as well as tensile elongation values. It is thus
gation resistance.11 claimed that the scale of the dendritic structure, SDAS, is
a far more critical structural length parameter of the cast
The superior mechanical properties of the Al7Si0.3Mg alloys in dictating the mechanical properties. Contrasting
alloy can be explained by its higher Si content and the wrought aluminium alloys, the scale of the dendritic
decrease in the SDAS values.29 The favourable impact of structure is often of greater interest to the foundry people
decreasing SDAS values on the mechanical properties of owing to its impact on the mechanical properties of the
aluminium foundry alloys is also well established.22,30–44 castings.33,45 SDAS is in perfect correlation with the
cooling rate which, however, fails to predict the grain size
Al7Si0.3 Mg alloy which exhibits relatively coarser on its own. The former invariably decreases with cooling
grains yet smaller SDAS across the section of the castings rate. The impact of the alloy composition on grain size
275
250
225 AlSi7Mg0.3; T6
AlSi5Mg0.3; T6
200
stress (MPa)
75
50
25
0
0,0 0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,0 4,5
strain (%)
200
UTS (MPa)
200
YS (MPa)
150 150
100 100
50 50
0 0
as-cast T6 as-cast T6 as-cast T6 as-cast T6
8 100
7
c AlSi5Mg0.3 d AlSi5Mg0.3 AlSi7Mg0.3
AlSi7Mg0.3
80
6
hardness (HB)
5
A5 (%)
60
4
EL
3 40
2
20
1
0 0
as-cast T6 as-cast T6 as-cast T6 as-cast T6
Figure 12. (a) Yield (YS) and (b) ultimate tensile strength (UTS), (c) elongation (EL) and (d) hardness
values of AlSi5Mg0.3 and AlSi7Mg0.3 alloys in the as-cast and heat-treated states. The minimum
required for the T6 properties are marked on these graphs.