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Mineralium Deposita (2005) 40: 598–616

DOI 10.1007/s00126-005-0026-6

A RT I C L E

R. Charlie Davies Æ Patrick J. Williams

The El Galeno and Michiquillay porphyry Cu–Au–Mo deposits: geological


descriptions and comparison of Miocene porphyry systems
in the Cajamarca district, northern Peru

Received: 29 September 2004 / Accepted: 29 August 2005 / Published online: 18 November 2005
 Springer-Verlag 2005

Abstract El Galeno and Michiquillay are early to middle the deposit, potassic alteration zones contain moderate
Miocene Cu–Au–Mo porphyry-related deposits located hypogene grades (0.14 g/t Au and 0.8% Cu) and are
in the auriferous Cajamarca district of northern Peru. characterised by chalcopyrite and pyrite mineralisation.
The El Galeno deposit (486 Mt at 0.57% Cu, 0.14 g/t The core of the deposit is defined by a lower grade
Au and 150 ppm Mo) is associated with multiple dioritic (0.08 g/t Au and 0.57% Cu) phyllic alteration that
intrusions hosted within Lower Cretaceous quartzites overprinted early potassic alteration. Michiquillay con-
and shales. Emplacement of the porphyry stocks (17.5– tains a supergene enrichment blanket of 45–80 m
16.5 Ma) in a hanging wall anticline was structurally thickness with an average Cu grade of 1.15%, which is
controlled by oblique faults superimposed on early overlain by a deep leached cap (up to 150 m). Cu–Au–
WNW-trending fold-thrust structures. Early K-feld- Mo (El Galeno-Michiquillay) and Au-rich (Minas
spar–biotite–magnetite (potassic) alteration was associ- Conga) deposits in the Cajamarca region are of similar
ated with pyrite and chalcopyrite mineralisation. A age (early–middle Miocene) and intrusive rock type
quartz–magnetite assemblage that occurs at depth has (dioritic) associations. Despite these geochronological
completely replaced potassically altered rocks. Late- and and geochemical similarities, findings from this study
post-mineralisation stocks are spatially and temporally suggest variation in metal grade between the hybrid-type
related to weak quartz–muscovite (phyllic) alteration. and Au-rich deposits result from a combination of
High Au grades are associated with early intrusive physio-chemical factors. These include variations in
phases located near the centre of the deposit. Highest Cu temperature and oxygen fugacity conditions during
grades (0.9% Cu) are mostly associated with a super- hypogene mineralisation resulting in varied sulphide
gene enrichment blanket, whilst high Mo grades are assemblages, host rock type, precipitation of ubiquitous
restricted to contacts with the metasedimentary rocks. hydrothermal magnetite, and late hydrothermal fluid
The Michiquillay Cu–Au–Mo deposit (631 Mt at 0.69% flow resulting in a well-developed phyllic alteration
Cu, 0.15 g/t Au, 100–200 ppm Mo) is associated with a zone.
Miocene (20.0–19.8 Ma) dioritic complex that was em-
placed within the hanging wall of a back thrust fault. Keywords Northern Peru Æ Copper Æ Gold Æ
The intrusive complex is hosted in quartzites and lime- Miocene Æ Porphyry
stones. The NE-trending deposit is crosscut by NNW-
trending prospect-scale faults that influenced both
alteration and metal distribution. In the SW and NE of Introduction

The Cajamarca mining region, located in northern


Editorial handling: A. Boyce Peru, has one of the largest gold inventories in South
America with the high-sulphidation giant Yanacocha
R. C. Davies (&) Au mine, plus over 30 smaller auriferous epithermal
Ivanhoe Mines Mongolia Inc, PO Box 353,
210646A Ulaanbaatar, Mongolia and porphyry deposits exposed at different erosion
E-mail: charliedavies@ivanhoemines.com depths (Gustafson et al. 2004). Gold proven reserves
Tel.: +976-9976-5248 for the Yanacocha district are 69.4 Moz (Newmont
Fax: +976-1134-5634 2004). The Minas Conga (Au–Cu), Michiquillay (Cu–
P. J. Williams Au–Mo) and El Galeno (Cu–Au–Mo) prospects are
School of Earth Science, James Cook University, located 10–15 km east of Yanacocha. These three early
4810 Townsville, QLD, Australia Miocene intrusion-related systems have a combined
599

mineral resource in excess of 1,600 Mt (Llosa and Veliz


2000; P. McInnes, unpublished data; Cordova and Regional geological setting of the miocene deposits
Hoyos 2000). Several barren intrusions of older or
similar age and composition also crop out in the re- The Cajamarca district is located in the Western Cor-
gion. To the north of the Cajamarca district are a dillera of northern Peruvian Andes. The region is char-
number of high-sulphidation Au deposits that include acterised by deformed Cretaceous marine sedimentary
Sipán, La Zanja, Tantahuatay, and the porphyry- rocks that have undergone several phases of compressive
skarn-manto polymetallic Hualgayoc district that hosts deformation since Palaeogene time and been intruded by
the Cerro Corona deposit (Fig. 1). The district is lo- multiple magmatic phases (Fig. 2). Hydrothermal and
cated in the Andes with elevations ranging between mineralisation events were temporally related to two
2,700 and 4,400 m above sea level. major magmatic episodes, i.e. early to middle Miocene
This paper presents a detailed geological description porphyry Cu–Au–Mo formation and late Miocene epi-
of the El Galeno (Cu–Mo–Au) porphyry prospect with thermal activity (R. C. Davies, unpublished data). The
emphasis on documentation of the relative timing of geological setting of northern Peru and the Cajamarca
different intrusive phases, as well as characterisation of region is outlined in Benavides (1956), Reyes (1980),
the alteration, mineralisation and vein infill paragenesis. Wilson (1985a, 1985b), Cobbing et al. (1981), S. J.
Revised intrusive, structural, alteration and mineralisa- Turner (unpublished data) and Wilson (2000).
tion data from the Michiquillay porphyry prospect are
also presented. Finally, El Galeno and Michiquillay are
compared with the relatively well-documented Au-rich Cretaceous to Oligocene rocks
Minas Conga porphyry complex.
The oldest rocks that crop out in the Cajamarca region
are a thick package of lower- to upper-Cretaceous
platform sedimentary rocks. These sedimentary units
include lower- Cretaceous sandstone and quartzite se-
quences at the base of the package that fine upward to
Upper-Cretaceous limestone, marl and shale sequences
(Benavides 1956). Intense folding and thrusting of the
marine sediments from 59 to 55 Ma resulted in emer-
gence of the Cretaceous sedimentary units and devel-
opment of open, upright folds and imbricate thrust
sheets (Mégard 1984, 1987).
The deformed sedimentary rocks are unconformably
overlain by predominantly basaltic to andesitic volcanic
sequences known as the Llama Formation (Noble et al.
1990; Atherton et al. 1985). The Lower Llama Volcanic
Sequence forms an aerially-extensive volcanic succession
that range in age from 54.8 to 42.6 Ma (Atherton et al.
1985; Noble et al. 1990; R. C. Davies, unpublished data).
Intrusions in the Minas Conga, Cerro Perol and Cruz
Conga regions indicate several stocks were emplaced
between 57 and 43 Ma (Llosa et al. 1996; R. C. Davies,
unpublished data).

Miocene rocks

Early to middle Miocene magmatic units (23.2–15.6 Ma)


are composed of intermediate, calc-alkaline porphyritic
intrusive and volcanic rocks that contain plagioclase,
mafic±quartz phenocrysts. Geochronological studies of
mineralised porphyry systems indicate emplacement,
main stage alteration and mineralisation at these centres
occurred during this magmatic interval (Llosa et al.
1996; R. C. Davies, unpublished data; Gustafson et al.
2004; Noble et al. 2004). Coeval barren porphyritic
stocks of similar composition display weak propylitic
Fig. 1 Map of Peru showing the major mineralised centres near the alteration (R. C. Davies, unpublished data). The youn-
township of Cajamarca gest intrusive age for this second magmatic interval is
600

Fig. 2 Simplified geological map of the Cajamarca region showing et al. 2004; (3) Turner, unpublished data; (4) R.C. Davies
the distribution of the major mineralised Miocene centres (modified (unpublished data); (5) Noble et al. 2004
from Reyes 1980). Age dates: (1) Llosa et al. 1996; (2) Gustafson

defined by an 40Ar/39Ar date of 16.5 Ma from a post- (1999) and Longo (2000) provided detailed discussions
mineralisation intrusion at El Galeno (R. C. Davies, on gold deposits and trends within the Yanacocha dis-
unpublished data), whilst the Upper Llama Volcanic trict, whilst Llosa and Veliz (2000) documented alter-
Sequence has been dated at 15.8 Ma also using ation and mineralisation styles at the Au–Cu Minas
40
Ar/39Ar (S. J. Turner, unpublished data). An interval Conga prospect. Unpublished reports (R. Hammond; J.
from ca. 16 to 12 Ma is defined by an apparent decrease B. Garcia; R. H. Sillitoe; R. C. Davies) and published
in magmatic and deformation activity in the Cajamarca work by Cordova and Hoyos (2000) and Davies (2000)
region. However, the period between 14 and 10 Ma describe the geology of El Galeno. Turner (unpublished
corresponded with major magmatic and hydrothermal data, 1999) discussed the volcanic setting and styles of
activity in the polymetallic Hualgayoc district to the mineralisation of the late Miocene Yanacocha district as
north (Macfarlane et al. 1994). well as other high-sulphidation systems such as Sipán,
Deposition of andesitic lava flows of the Regalado La Zanja and Tantahuatay. More recently, Gustafson
Formation (12.3–11.6 Ma; S. J. Turner, unpublished et al. (2004) discussed porphyry-epithermal transitional
data) represented the initiation of middle to late Mio- features observed in a variety of deposits within the
cene magmatic activity. Economically, the most pro- Cajamarca region.
ductive interval for the Cajamarca region occurred
between 12 and 10 Ma with formation of the high-sul-
phidation Yanacocha Au deposit. Main stage minerali- Regional structure
sation at Yanacocha took place between 11.5 and
10.9 Ma (S. J. Turner, unpublished data). Magmatic and The Cajamarca area is located within the southern part
hydrothermal activity in the region ceased in the late of the Huancabamba Deflection zone where Andean
Miocene (8 Ma) with the onset of a shallowing sub- structural fabric rotates from NNW to near E–W
duction zone (Gutscher et al. 1999). (Mégard 1984). Structural features observed in the de-
Previous work at mineralised centres in the Caja- formed Cretaceous sedimentary rocks include large
marca region includes several studies at the Michiquillay wavelength (>5 km) open folds that gently plunge
deposit by Laughlin et al. (1968), Hollister and Sirvas WNW or ESE. In the northeastern part of the study
(1974), and reports by the Metal Mining Agency, Japan area, a thrust fault known as the Puntre Fault is spatially
International Cooperation Agency (MMA, unpublished associated with numerous magmatic units of both
data) and P. McInnes (unpublished data). Harvey et al. Palaeogene and Miocene age (Fig. 2). The thrust fault
601

displays a major deflection in trend from near E–W to P1 porphyry


near N–S (see below). To the east and west of the
deflection, the Puntre fault has a NW trend consistent The oldest intrusive phase is a crowded medium-grained
with local regional structures. Faults and fractures in the porphyritic diorite composed of euhedral to subhedral
Cretaceous sedimentary rocks are generally subvertical plagioclase, with minor euhedral biotite, hornblende and
with dominant normal slip ranging from a few to tens of rounded quartz phenocrysts (Fig. 5a). Plagioclase phe-
metres. In the study area, subvertical fault planes plot in nocrysts (An44-46; 35–45 vol%) range between 0.3 and
three general domains, which include N–S, E–W and 5.0 mm in length and show multiple twinning plus
ESE-trending. N-striking faults are the most abundant oscillatory zoning. Magmatic biotite and hornblende
orientation recognised from aerial-photo interpretation phenocrysts (1 vol%) of 0.5–2.0 mm length are mostly
(R. C. Davies, unpublished data). replaced by secondary biotite. The P1 porphyry is the
largest body of the four recognised phases and later
intrusive units were emplaced toward the core of this
El Galeno deposit stock.

El Galeno is a Cu–Au–Mo porphyry deposit with an


P2 porphyry
estimated geological resource of 486 Mt at 0.57% Cu,
0.14 g/t Au and 150 ppm Mo (Cordova and Hoyos
The second intrusive phase is also a porphyritic diorite
2000). It is exposed at an altitude between 3,850 and
but texturally heterogeneous. It is dominantly charac-
4,100 m. Multiple intrusive stocks were emplaced be-
terised by a crowded porphyritic texture (Fig. 5b) with
tween ca. 17.50 and 16.53 Ma (R. C. Davies, unpub-
fine-grained plagioclase (0.5–1.0 mm; An42-60) and less
lished data). The intrusions are hosted by folded Lower
abundant rounded quartz grains, but varies to a med-
Cretaceous sedimentary rocks and were emplaced in a
ium-grained (1.5–3.0 mm) weakly porphyritic rock.
hanging wall anticline (Fig. 2). Mineralisation is char-
Phenocrysts show similar characteristics to magmatic
acterised by a hypogene zone overlain by a supergene
grains in the P1 porphyry. Hydrothermal biotite from
enrichment blanket up to 120 m thick. Several unmi-
this intrusion yielded an age of 17.5±0.3 Ma using
neralised gabbroic dykes crop out to the southwest and 40
Ar/39Ar (R. C. Davies, unpublished data).
northwest of the mineralised centre, and display weak to
moderate chlorite alteration. The dykes intruded both
subvertical N- to NW-trending fault planes and steeply P3 porphyry
dipping bedding planes. 40Ar/39Ar age dating of horn-
blende phenocrysts from a gabbroic dyke yielded an P3 porphyry stocks are coarse-grained crowded por-
approximate age of 29.4±1.4 Ma (R. C. Davies, phyritic quartz-diorite with euhedral plagioclase, quartz,
unpublished data), indicating the dykes are Oligocene in biotite and hornblende phenocrysts (Fig. 5c). Plagio-
age and intruded prior to emplacement of the El Galeno clase phenocrysts (An42-51; 30–35 vol%) display oscilla-
porphyry complex. tory zoning and range in length from 1.0 up to 8.0 mm.
Rounded quartz phenocrysts are 2.0–10.0 mm in length
and may have minor embayments. Euhedral biotite
Lithology books (6 vol%) range from 1.0 to 10.0 mm in length and
hornblende (3 vol%) phenocrysts are between 1.0 and
Field evidence indicates that the El Galeno porphyry 5.0 mm. This porphyry contains rare xenoliths of
complex is mainly hosted within quartzite and siltstone quartz–magnetite altered fragments. In drill core, the
sedimentary units (Fig. 3). Observed contacts between occurrence of these intrusions was sporadic, varying in
intrusions and sedimentary host rocks are subvertical. thickness from a few metres to tens of metres and was
Furthermore, drilling indicates the intrusive complex mainly intersected toward the centre of the P1 porphyry
does not extend laterally beyond the outcrop limit (Fig. 4). In outcrop (Fig. 3), contacts of a P3 porphyry
(Sillitoe, unpublished data; R. C. Davies, unpublished body are near vertical from which it is inferred that this
data). The intrusive complex is elliptical in shape, intrusive phase occurs as a number of small sized vertical
1,250 m in length by 600 m wide, and its long axis is dykes.
oriented NW–SE. This orientation is roughly parallel to
the WNW trend of the hanging wall anticline (El Galeno
Anticline) that hosts the mineralised centre. The com- P3 porphyritic breccia
plex comprises at least four intrusive phases (Fig. 4),
three of which are identifiable in outcrop and the other Hydrothermal breccias (P3 porphyritic breccia) are
in drill core. Timing for emplacement of the four located along the contacts of some of the P3 porphyry
intrusions has been established from crosscutting, bodies (Fig. 4). Fragments observed within the hydro-
overprinting, alteration and vein relationships observed thermal breccia include angular to subrounded quartz
in both drill core and outcrop. and quartz–magnetite veins that range in size from
602

Fig. 3 Geological map of El


Galeno with the major
lithological units and prospect-
scale structures. Also, shown
are the outer limits of Cu grade
zones and the locations of drill
core logged

millimeters up to several centimetres. The matrix is (0.6–2.5 mm) and minor mafic phenocrysts set within a
dominantly composed of quartz, muscovite and pyrite. light grey feldspathic groundmass. The dykes were not
Thin (0.3–2.0 m wide) dioritic dykes are characterised observed in outcrop and rarely intersected in drill core.
by crowded porphyritic texture with abundant feldspar The dykes are considered to have formed late in the
603

Fig. 4 Near E–W section through the El Galeno porphyry complex Sillitoe (unpublished data) and R.C. Davies (unpublished data)].
showing the distribution of the major lithological units and outer The lower limits of the leached cap, chalcocite–covellite zone and
limits of alteration assemblages [based on drill core logging R.H. sulphide enrichment blanket are also shown

Fig. 5 Photographs of the


different intrusive phases within
the Galeno complex. a P1
porphyry composed dominantly
of plagioclase (Pl), hornblende
(Hbl), biotite (Bt) and quartz
(Qtz) phenocrysts. Plagioclases
have been partially replaced by
muscovite and illite. b P2
porphyry with a medium to fine-
grained crowded porphyritic
texture consisting of plagioclase,
biotite phenocrysts and fine-
grained hornblende. Crosscutting
quartz-K-feldspar veins and
minor sulphides are related to
dark K-feldspar–biotite
alteration that is overprinted by
weak propylitic alteration. c P3
porphyry with coarse-grained
plagioclase, biotite and
hornblende and quartz
phenocrysts. d Biotite altered
MBx porphyry with Pl and Bt
phenocrysts. MBx contains
fragments of altered and
mineralised P3 porphyry. Dark,
fine-grained selvages composed
of hydrothermal biotite rim some
fragments
604

evolution of the intrusive complex, probably following east and northwest of El Galeno, to a high-angle oblique
emplacement of the third intrusive phase. However, ramp within the zone of deflection.
their exact timing is unclear. Southwest of the intrusive complex, exposures on
Senal Guaguayo mountain contain subvertical normal
faults that range from NW- to near E-trending. Dis-
MBx porphyry placement along the fault planes varies from roughly 2
to 5 m. Fault breccias and altered Oligocene gabbroic
The youngest intrusive phase is a magmatic breccia dykes (1–3 m wide) occur along some of these fault
that is weakly porphyritic, with phenocrysts and planes. Normal faults measured at Cerro Listo have a
xenoliths set in a feldspar-rich matrix (Fig. 5d). Euhe- uniform orientation with a general NE trend and offsets
dral plagioclase phenocrysts (An40–56; 10 vol%; 0.5– up to 10 m. These subvertical faults are characterised by
9.0 mm) show multiple twinning textures and generally minor brecciation along fault planes, although gabbroic
contain sieve-textured rims that suggest plagioclase dykes are noticeably absent at Cerro Listo. Aerial photo
instability (refer to insert of Fig. 11b). Biotite books interpretation suggests a NE-trending tear fault bisects
(2 vol%) are euhedral and vary from 0.3 to 3.0 mm the valley between topographic peaks of Senal Gua-
in size. Rounded quartz phenocrysts (1 vol%) are guayo and Cerro Listo (R. C. Davies, unpublished
3.0 mm in length and acicular hornblende grains data). This tear fault is interpreted to crosscut the El
(0.3–2.0 mm) are partially replaced by secondary bio- Galeno Anticline.
tite. This unit was intersected at depth in the northern To the west of Laguna Rinconada (Fig. 3), a series of
central part of the P1 porphyry. Xenoliths are generally small-scale normal faults was observed within the Farrat
rounded and range in size from a few to tens of cen- Formation. These subvertical faults have an approxi-
timetres. Altered and mineralised xenoliths of the pre- mate E–W strike and display 0.5–2.0 m displacement.
vious three intrusive phases are the dominant clasts. Drill cores along strike of these faults are strongly
Many clasts have thin (1 mm) fine-grained dark sel- fractured and characterised by intense clay alteration to
vages composed of hydrothermal biotite. Magmatic depths in excess of 300 m (R. C. Davies, unpublished
biotite books from this intrusion yielded a 40Ar/39Ar data). It is inferred that the fault set west of Laguna
plateau age of 16.53±0.18 Ma (R. C. Davies, unpub- Rinconada extends into the intrusive centre. The nature
lished data). and history of this fault with respect to pluton
emplacement, controls on mineralisation plus possible
post-mineralisation offset is uncertain.
Structural geology

El Galeno is situated at the intersection of a hanging Alteration, mineralisation and vein paragenesis
wall anticline and a NE-striking tear fault (Fig. 2). The
hanging wall anticline, called El Galeno Anticline, has a Four separate alteration events are identifiable at the El
gentle plunge to the NW (25 fi 303) and is located Galeno prospect based on drill core logging and petro-
immediately above the Puntre Thrust fault. The lower graphic studies. The first of these is temporally and
Cretaceous rocks in the hanging wall of the fault are spatially related to the earliest two intrusive phases. P3
juxtaposed against middle-upper Cretaceous rocks in the porphyry stocks truncate mineralised P1 and P2 por-
footwall, indicating over 2,000 m of reverse offset based phyries indicating that hydrothermal events occurred
on unit thicknesses measured by Benavides (1956). To prior to its emplacement. Altered P3 porphyry is in turn
the east and northwest of the intrusive system, the re- crosscut by P3 hydrothermal breccias, with MBx por-
verse fault strikes approximately WNW and dips at a phyry containing mineralized fragments of all earlier
low angle (30) to the SSW, suggesting that the fault intrusive phases. Alteration assemblages associated with
forms a low-angle thrust ramp. However, to the north- each of the intrusive phases display zoned distributions.
east of the complex, the reverse fault deflects in a Mineralisation is divided into hypogene mineralisa-
clockwise direction to near NNW. Within this NNW tion, which includes up to three separate stages, and
trending zone of the fault, argillic-altered sedimentary supergene mineralisation (Fig. 6). Hypogene minerali-
rocks have a subvertical dip and display polyphase sation occurs in all four generations of porphyry intru-
deformation. These features include early WNW shal- sions as well as extending ten to a few hundreds of
lowly plunging folds and subhorizontal calcite veins that metres into the host sedimentary rocks.
are both crosscut by later extensional structures
including subvertical calcite veins and small-scale nor-
mal faults (R. C. Davies, unpublished data). Other fea- Stage 1
tures observed in near proximity to the thrust zone
include a bend in the hanging wall anticline axis towards Alteration The oldest and most widespread alteration
the deflection zone and abundant fractures in quartzites identified in drill core is observed within the P1 and P2
on the northern limb of the anticline. These features porphyries. The dominant assemblage consists of
suggest a change from a low-angle frontal ramp, to the K-feldspar and biotite (potassic alteration). This is
605

Fig. 6 Intrusion, alteration and vein infill paragenesis at El Galeno

characterised by replacement of plagioclase pheno- to 50 vol%) is related to this alteration stage and
crysts by K-feldspar (Fig. 7a), while primary horn- generally extends about 200 m below the current sur-
blende and biotite phenocrysts are replaced by face (R. C. Davies, unpublished data). Stockwork
hydrothermal biotite, and fine-grained secondary bio- density generally decreases with depth and toward the
tite formed within the matrix. Minor amounts of fine- periphery of the intrusive system, although quartz
grained magnetite occur along the rims of altered stockwork locally extends up to 100 m into the host
mafic minerals and disseminated within the matrix. rocks. Minor silicification and a weak propylitic
The earliest vein types include biotite-quartz fracture alteration are also evident along the contact margins
infillings (Fig. 7b), followed by quartz veins 0.5 mm up with sedimentary host rocks and in localised zones of
to 10 cm width. High density of quartz stockwork (up the P1 porphyry.
606

Pervasive magnetite-quartz alteration (Fig. 7c) occurs hydrothermal biotite alteration zones and localised
at depth and toward the central zone of the P1 porphyry contacts between the host units and P1 porphyry
(Fig. 3). Quartz–magnetite-altered fragments occur as (Fig. 8b–c).
xenoliths in the P3 porphyry, although a weak magnetite
alteration is evident along its contacts. These relation-
ships indicate this quartz-magnetite alteration domi- Stage 2
nantly occurred at depth and prior to emplacement of
the third intrusive phase. Alteration The second alteration stage was temporally
Hypogene sulphides Hypogene mineralisation identi- and spatially related to emplacement of the P3 por-
fied at El Galeno is both fracture infill and disseminated phyry P3 hydrothermal breccias and diorite dykes
in character. The earliest mineralisation was molybde- (Fig. 6). The earliest alteration identified with this stage
nite (Fig. 7d) deposited in re-opened early quartz veins involved intense K-feldspar replacement of the
within both the P1 porphyry and host sedimentary groundmass and primary plagioclase grains, and
rocks. These quartz veins range in thickness from a few hydrothermal biotite replacement of primary mafic
millimetres to centimetres. The highest molybdenite minerals. This potassic alteration has a smoky, light
abundances occur along the contacts between the host grey appearance that is a unique characteristic within
sedimentary rocks and P1 porphyry (Fig. 8a). This P3 porphyries (Fig. 5c). The diorite dykes have a sim-
oldest mineralisation phase was followed by the depo- ilar alteration assemblage but a slightly darker
sition of magnetite and pyrite (Fig. 7d) with varying appearance. Development of new quartz veins and
proportions of arsenopyrite and pyrrhotite. Later chal- reopening of older veins was also related to this alter-
copyrite (Fig. 7d) and minor amounts of bornite cross- ation phase. This alteration has a substantially lower
cut these earlier phases. These later mineralisation vein density than the Stage 1 alteration.
phases are evident in both the P1 and P2 intrusions.
Hypogene pyrite, chalcopyrite and molybdenite also A quartz–muscovite/illite ± pyrite (phyllic) alter-
extend into the sedimentary host rocks. Based on log- ation assemblage overprints the potassic-silicate alter-
ging and assay data (R. C. Davies, unpublished data), ation and early quartz ±molybdenite veins. The quartz–
high-grade hypogene zones are associated with intense muscovite/illite alteration is defined by muscovite

Fig. 7 Photographs of alteration and mineralisation features at El Photomicrograph of Stage 1 mineralisation with early molybdenite,
Galeno. a Photomicrograph of a zoned plagioclase phenocryst followed by pyrite and finally chalcopyrite. e Photomicrograph
crosscut and partially replaced by early Stage 1 potassic alteration. showing Stage 2 K-feldspar (bottom left to top centre) has partially
b Stage 1 early Bt vein in the P1 porphyry crosscut by a Qtz vein replaced a plagioclase phenocryst. Fine-grained hydrothermal
(middle left of image). Thin magnetite (Mag) veins post-date both biotite (top right) also precipitated during this alteration stage.
the biotite and quartz veins. c Stage 1 quartz–magnetite alteration Both these minerals are partially replaced by muscovite/illite. f
crosscut by quartz and quartz–magnetite veins. Magnetite infill of Stage 2 pyrite vein with a quartz–muscovite selvedge in a P3 dioritic
reopened veins and late pyrite (Pyr) veinlets are also evident. d dyke
607

Fig. 8 Section A–A1 showing


metal grade distributions. High
Au and Cu grades are located in
the upper eastern section of the
porphyry complex. Moderate Cu
grades also occur on the western
flank of the complex. High Mo
grades are mostly located on the
edges of the complex. The
quartz–magnetite alteration and
late porphyries (P3 and MBx) are
poorly mineralised

replacement of feldspar grains (Fig. 7e), quartz Hypogene sulphides Late quartz–muscovite–pyrite
replacement of the groundmass and quartz infill in new veins and thin pyrite veinlets overprint earlier stock-
or reopened fractures. Weak quartz–muscovite alter- work. The quartz–pyrite veins with muscovite halos
ation is evident within the first three intrusive phases and (Fig. 7f) are related to the weak phyllic alteration and
dominantly restricted to the upper 15 m of the intrusive veins mostly comprise pyrite infill. Minor chalcopyrite,
centre. bornite and molybdenite also precipitated along fracture
608

planes. These veins are dominantly found within, or in magmatic breccia. This phyllic alteration is character-
close proximity, to the third intrusive phase. The P3 ised by a high abundance (up to 15 vol%) of dissemi-
hydrothermal breccias have a quartz muscovite–pyrite nated fine-grained pyrite and intense muscovite
matrix with xenoliths of quartz–magnetite (Fig. 9a). replacement of feldspar (Fig. 9c).
This mineralisation event is distinguishable from stage
1 by a substantial decrease in Au, Cu and to a lesser Hypogene sulphides Several late veining events are
extent Mo, but produced zones with anomalously high temporally related with this alteration phase and contain
Zn and Pb content. Anomalously high Ag, Pb, and Zn similar mineralogy of the previous stages. The fragments
grades are also associated with the hydrothermal display barren and mineralised veins that terminate at
breccia. It is inferred that main stage deposition of Au, the fragment boundaries, which suggest that this min-
Cu and Mo occurred prior to emplacement of this eralisation phase represents a new hypogene mineral
phase. deposition phase.

Stage 3 Sulphide minerals are commonly associated with


zones of intense biotite and K-feldspar alteration. Early
Alteration The youngest alteration event identified magnetite precipitation was followed by development
was temporally and spatially related to the emplace- of thin (3 mm), wavy quartz veins. Quartz veins were
ment of the final intrusive phase. Alteration is dark later reopened and molybdenite, followed by pyrite,
grey in appearance (Fig. 9b) and dominantly charac- then chalcopyrite and bornite were deposited (Fig. 9b–
terised by intense fine-grained hydrothermal biotite e). These assemblages are crosscut by hairline pyrite
replacement of magmatic mafic phenocrysts and veinlets (Fig. 9c). This late stage alteration also in-
groundmass. Weak K-feldspar replacement of plagio- volved partial to complete hematite replacement of
clase and the groundmass was also associated with this chalcopyrite and bornite (Fig. 9d–e). This was possibly
event. Quartz muscovite–pyrite (phyllic) alteration is associated with late fluorite–epidote–carbonate–quartz
evident near contacts between xenoliths and the infill.

Fig. 9 Photographs of alteration and mineralisation features at El between the P1 fragment and MBX porphyry. Fine-grained
Galeno. a Xenolith fragments of P1, P2, P3 and quartz–magnetite plagioclase grains have been near completely replaced by musco-
veins in the P3 hydrothermal breccia. The matrix of the breccia vite/illite. d Photomicrograph of stage 3 molybdenite that has been
dominantly comprises quartz, muscovite and pyrite. b Biotised partially replaced by hematite (Hem). e Photomicrograph of stage 3
MBx porphyry that contains thin quartz veins related to Stage 3 molybdenite, chalcopyrite and bornite (Bn). The chalcopyrite–
alteration. These veins have been reopened and filled in with bornite grain is rimmed by late overprinting hematite. f Chalco-
molybdenite (Mo) and chalcopyrite (Ccp). Insert, plagioclase pyrite grain rimmed by late chalcocite (Cc) during secondary
phenocryst with sieved-texture rim. c Phyllic altered MBx porphyry enrichment
with P1 porphyry fragment. Late pyrite veinlets crosscuts contact
609

Secondary enrichment and weathering Lithology

Weak clay (argillic) alteration mostly occurs within the The Michiquillay intrusive centre is hosted within
upper 10 m of the intrusive complex or zones with quartzite units to the north and limestone units to the
abundant fractures. In these zones, relict feldspar and south (Fig. 10). At least two major intrusive phases were
mafic minerals have been replaced by kaolinite. recognised during drill core logging based on textural
Secondary mineralisation is restricted to a super- evidence. The most common lithology is a medium-
gene blanket that extends 120 m below the current grained crowded porphyritic diorite (termed D1) with
surface (Fig. 4; Sillitoe, unpublished data). Sulphide plagioclase, biotite and hornblende phenocrysts set in a
minerals present within the supergene blanket include feldspathic groundmass (Fig. 11a). Quartz phenocrysts
chalcocite and minor covellite. Chalcocite replacement are rounded, have a low abundance (between 0.5 and 4.0
is mostly observed along the rims of both hypogene vol%) and occur in localised zones. Euhedral plagioclase
chalcopyrite and bornite (Fig. 9f). Metal grades within phenocrysts (An42-52) range from 0.3 to 5.0 mm and are
the supergene blanket range, from 0.7 up to 1.2% Cu. the most abundant minerals (35–45 vol%). Book-
These grades are considerably higher than those re- shaped euhedral biotite phenocrysts (3 vol%) vary
lated to hypogene mineralisation, which generally from 0.5 to 8.0 mm and generally contain minor feldspar
range between 0.2 and 0.3% Cu. El Galeno also inclusions. Hornblende phenocrysts (1–3 vol%) are
contains a leached cap that extends 10 m below the acicular and mostly 0.3–1.0 mm in length. Slight varia-
surface. tions in grain-size and mineral abundance occur
throughout the intrusive body, although no clear trun-
cations or crosscutting relationships were observed
Michiquillay deposit making it difficult to distinguish discrete intrusive pha-
ses. Hollister and Sirvas (1974) referred to this unit as a
Michiquillay is a Cu–Au–Mo intrusive porphyry system quartz–biotite monzonite. However, petrographic evi-
with an indicated resource of 631 Mt at 0.69% Cu, dence indicates primary feldspar phenocrysts are pla-
0.15 g/t Au and between 100 and 200 ppm Mo with a gioclase and primary hornblende grains have been
supergene enrichment zone containing an estimated re- replaced by secondary biotite. Therefore, it is suggested
source of 46.2 Mt at 1.15% Cu (P. McInnes, unpub- that this intrusive unit be classified as a biotite–horn-
lished data). The Michiquillay porphyry contains a blende diorite.
leached cap (varying from a few metres up to 150 m The second intrusive phase is weakly porphyritic and
thick) that overlies a secondary enrichment blanket characterised by low vein abundances and intense biotite
(1.15% Cu) extending up to a further 80 m in thickness. alteration (Fig. 11b–c). This medium- to fine-grained
Exposures of the mineralised complex occur at altitudes intrusive phase dominantly contains euhedral plagio-
from 3,500 to 3,750 m (Fig. 10). clase phenocrysts (15 vol%), plus biotite altered
Extensive mapping and drilling in the mid 1970s by hornblende phenocrysts and euhedral biotite books
the Metal Mining Agency (MMA) of Japan defined the (Fig. 11b). This second intrusive phase forms dykes that
dimensions of the intrusive complex as being 5 km in range in thickness from 1 to 6 m (Fig. 12a). The dykes
length and 1.5 km wide (Fig. 10). The main intrusive crosscut and truncate the potassic-altered main intrusion
body is roughly parallel to the local NW structural and contain xenoliths of the altered biotite–hornblende
trend. Laughlin et al. (1968) dated two intrusions in the diorite (Fig. 11b). The dykes generally lack well-devel-
Michiquillay region using the K–Ar technique. These oped quartz stockwork veins. No quenched margins
include a quartz–biotite monzonite from the Michi- were observed along the rims of xenoliths. The dykes
quillay prospect that yielded an age of 20.6±0.6 Ma were only observed in the northeastern and southwest-
(biotite) and a quartz–hornblende monzonite from the ern zones of the complex. This phase is inferred to be a
Michiquillay suite to the north that produced an age of series of syn- to late-mineralisation vertical diorite
46.4±1.8 Ma (hornblende). Llosa et al. (1996) ob- dykes.
tained an age date of 18.8±1.6 Ma (magmatic biotite)
from an intrusion at the Michiquillay prospect also
using the K–Ar technique. 40Ar/39Ar data by R. C. Structural geology
Davies (unpublished data) indicate emplacement of a
synmineralisation stock at the Michiquillay prospect The Michiquillay intrusive complex is located in the
occurred 19.77±0.05 Ma. More recently, Noble et al. hanging wall of a NW-trending back thrust (Fig. 10)
(2004) dated a biotite phenocryst from a biotite altered that was interpreted by Hollister and Sirvas (1974) to
porphyry dyke at 20.02±0.15 Ma. To the north of the be crosscut by the NE-trending Encañada Fault. The
prospect, a barren intrusion was emplaced latter fault was not recognised during aerial photo
20.6±0.14 Ma (R. C. Davies, unpublished data). This analysis or fieldwork by the author and its existence is
indicates synmineralisation stocks at the deposit are suspect. The thrust dips at 60 towards the NE and is
slightly younger than unmineralised intrusions to the referred to as the Michiquillay Fault (Hollister and
north. Sirvas 1974; MMA, unpublished data). It is charac-
610

Fig. 10 Simplified geological map of the


Michiquillay prospect [modified from
previous mapping by MMA
(unpublished data)]

terised by a matrix-supported breccia that contains increase in fracture density toward the central part of
both quartzite and limestone fragments, though no the fault zone. The faults are subvertical and domi-
intrusive fragments were observed. The Michiquillay nantly strike either to the NNW or NNE.
Fault was not intersected in drill core. However, in the The NNW-striking prospect-scale faults separate
southern zone of the deposit, the reoccurrence of potassic alteration zones in the NE and SW of the
stockwork and change from potassic to phyllic alter- complex, and define the outer limit of a strong phyllic
ation toward the bottom of some drill holes is inter- alteration zone. An increase in stockwork density was
preted to indicate the Michiquillay Fault is nearby noted along these fault planes. Some NNW fault planes
(R. C. Davies, unpublished data). In outcrop, oblique contain localised zones of vuggy quartz that are
prospect-scale faults crosscut the porphyry deposit and spatially-associated with strong gossan-like oxidation
were previously mapped by MMA (unpublished data). features. The NNW-striking faults are the dominant
These dominantly occur toward the centre of the fault set at the deposit and are inferred to have strongly
deposit (Fig. 10) and are recognisable in outcrop by an influenced both alteration and mineralisation. Steeply
611

Fig. 11 Photographs of intrusive units, alteration and mineralisa- in a groundmass that has been intensely replaced by hydrothermal
tion features at Michiquillay. a The D1 porphyry consists of biotite. Late pyrite and hematite veins crosscut the dyke. d
plagioclase, biotite and hornblende phenocrysts with a feldspathic Chalcopyrite and molybdenite mineralisation in a quartz vein. e
groundmass. The groundmass has been partially to strongly Late pyrite veins with quartz–sericite halos crosscut the potassic
overprinted by hydrothermal biotite (dark grey bottom left). Minor altered D1 porphyry. f Quartz–sericite alteration has destructively
chalcopyrite (middle top) and pyrite (top right) is also present. b replaced most primary igneous textures, although some grain
Medium-grained crowded D1 porphyry (left) truncated by a fine- boundaries are evident. Late thick pyrite veins are associated with
grained dyke (right). Both intrusions contain minor quartz the quartz–sericite alteration
stockwork. c A dyke with plagioclase and biotite phenocrysts set

plunging slicken lines on some fault planes indicate late sphalerite also precipitated during this stage. Based on
subvertical displacement. logging results and corresponding assay data, average
hypogene grades for these zones are 0.14 g/t Au and
0.8% Cu (R. C. Davies, unpublished data).
Alteration and mineralisation Intense quartz–muscovite–pyrite (phyllic) and late
kaolinite (argillic) alteration zones occupy the core of
Both intrusive phases contain a well-developed K-feld- the complex (Fig. 12b). Quartz–pyrite veins with
spar–biotite–quartz–magnetite alteration assemblage. muscovite/illite selvedges are observed throughout the
The potassic alteration is strongest in the northeastern intrusive complex and crosscut all veins (Fig. 11e). In-
and southwestern parts of the prospect (Fig. 12b), but tense phyllic alteration has destructively overprinted
extends only a few metres in the host rock. Surface older textures (Fig. 11f). Intensity of the quartz–
expressions of the potassic alteration zones have a NE muscovite–pyrite alteration however weakens toward
trend (Fig. 10). This alteration is characterised by the the edges of the core where it has partially replaced
replacement of plagioclase by K-feldspar and the pre- potassic-altered rocks. As mentioned above, NNW-
cipitation of fine-grained hydrothermal biotite that is striking faults are inferred to have controlled the dis-
strongly developed in the southwestern zone. The tribution of these alteration assemblages. Sulphides
northeastern zone contains only moderate hydrothermal precipitated during this alteration include large
biotite but stronger K-feldspar–quartz alteration. De- amounts of pyrite (Fig. 11f), plus minor molybdenite
spite these slight variations, both the southwestern and and chalcopyrite (P. McInnes, unpublished data).
northeastern zones display very similar alteration styles. MMA (unpublished data) also identified luzonite and
Veins associated with the potassic alteration include tetrahedrite–tennantite within the central upper parts of
early 1–2 mm wavy magnetite and biotite veins that are the phyllic alteration zone. Au and Cu grades in this
crosscut by quartz veins. Hypogene sulphides associated zone (0.08 g/t Au and 0.57% Cu; R. C. Davies,
with the potassic alteration include chalcopyrite, unpublished data) are lower than in the potassic
molybdenite (Fig. 11d), pyrite and minor bornite. These alteration zones.
minerals occur as infill in veins and fractures, as well as Michiquillay contains a supergene enrichment zone
disseminated in the groundmass. Microscopic studies by characterised by covellite and chalcocite replacement of
MMA (unpublished data) reported that pyrrhotite and hypogene chalcopyrite (Fig. 12c). Grades associated
612

Fig. 12 Section A–A1 looking


NW, showing the major
lithological units, alteration and
logged drill cores and Cu grade
map from assay data

with this enrichment zone range from 2.2 to 0.5% Cu, at and extends to depths of 100 m below the surface. The
an average of 1.09% Cu (P. McInnes, unpublished composition of the clay was determined as kaolinite
data). In parts, late clay (argillic) alteration partially to from X-ray diffraction analysis (R. C. Davies, unpub-
moderately overprints the quartz–muscovite alteration. lished data). Late development of malachite is evident in
Clay alteration is spatially associated with fault zones both outcrop and on drill core.
613

alteration zone located toward the centre of the deposit


Discussion defines a pyritic-rich, low-grade zone. It is inferred that
these late fluids remobilised some Cu and Au associated
Interpretation of the El Galeno and michiquillay with early potassic alteration. The deposit contains a
deposits supergene enrichment zone located beneath a leached
cap of varying thickness.
Previous interpretations of El Galeno geology include a
complex series of stratigraphically controlled sills and
laccoliths that intruded along bedding planes or zones of Comparison of Miocene porphyry deposits
weakness (R. Hammond, unpublished data). Sillitoe
(unpublished data) suggested that several small, vertical, The Cajamarca district hosts a number of mineralised
annular dykes intruded an early porphyry body that porphyry and high-sulphidation systems that display
contains the majority of hypogene mineralisation. Based varying mineralisation and alteration styles. Turner
on observations from this study, a revised version of the (1999) suggested one of the principal differences between
Sillitoe (unpublished data) model is presented for El the various late Miocene high-sulphidation systems in
Galeno. Emplacement of the principal and earliest por- the Cajamarca region relates to level of erosion. He
phyry occurred at the intersection of a regional structure argued that Yanacocha represents a high level epither-
crosscut by an oblique secondary structure. The P1 mal system characterised by phreatic breccias and has a
porphyry is elliptical in plan view with a northwest poorly understood structural control, whereas Sipán and
trend, similar to the localised structural fabric. These La Zanja are relatively deeply eroded systems where
features indicate that emplacement of the principal El magmatic plus hydrothermal breccias predominate and
Galeno porphyry (P1) was dominantly structurally structural controls are more clearly recognised. Age
controlled. dates from three early to middle Miocene mineralised
Early Mo precipitation occurred along the contacts porphyry deposits, El Galeno (Cu–Au–Mo), Michi-
of the P1 porphyry and host rocks. Candela and Piccoli quillay (Cu–Au–Mo) and Chailhuagon-Perol (Au–Cu)
(1995) showed that at low initial water content and a low at Minas Conga, indicate the intrusive complexes were
Cl/water ratio, Mo is preferentially partitioned from the emplaced over a period of 6 my but have significantly
melt into exsolved fluid compared to Cu. This suggests different metal grades (Table 1). The following para-
early Mo mineralisation is temporally associated with graphs compare and contrast these porphyry deposits in
emplacement of the oldest and driest porphyry. Main the Cajamarca region.
stage Cu and Au deposition occurred during, or shortly El Galeno is dominantly hosted in quartzites, Mich-
after emplacement of the P2 porphyry, towards the core iquillay in both quartzites and limestones, whereas the
of the complex where temperatures would have been Minas Conga deposits (Chailhuagon and Perol) are
elevated. A pervasive quartz–magnetite alteration at mostly hosted in limestones and marls (Table 1). Host
depth and towards the core of the P1 porphyry possibly rocks with low permeability, such as marbleised lime-
developed contemporaneously with emplacement of the stone, minimise lateral flow of hydrothermal fluids,
P2 porphyry. Both the P1 and P2 porphyries have well- thereby focusing metalliferous fluids to the host intru-
developed potassic alteration hosting modest hypogene sion and possibly increasing metal concentrations
mineralisation. The younger intrusions (P3 and MBx (Sillitoe 2000). El Galeno, Michiquillay and Chailhuagon
porphyries) have potassic and phyllic alteration phases, deposits consist of early to middle Miocene hornblende–
are poorly mineralised and have a lower abundance of biotite diorites that are geochemically very similar (R. C.
quartz stockwork than the earlier P1 and P2 porphyries. Davies, unpublished data). Chailhuagon is the oldest
These intrusions are inferred to be late- to post-miner- and possibly longest lived complex with the main por-
alisation. A substantial proportion of the higher Cu phyritic stock emplaced 23.2 Ma (Llosa et al. 1996)
grades are associated with a supergene enrichment zone and a potassic altered porphyry dated at 15.6 Ma
that extends up to 150 m beneath a thin leached cap. (Gustafson et al. 2004). Drilling at both Chailhuagon
Emplacement of the Michiquillay porphyry during and Perol has defined post-mineralisation stocks at
early to middle Miocene times (20.0–19.8 Ma) was depths that significantly reduce the Au–Cu grade of both
structurally controlled by the Michiquillay Fault. The deposits (Llosa and Veliz 2000). Michiquillay contains
existence or significance of the Encañada Fault proposed two recognisable synmineralisation intrusions that were
by Hollister and Sirvas (1974) is unclear. Early potassic emplaced between 20.0 and 19.8 Ma (R. C. Davies,
alteration developed along a NE trend and was associ- unpublished data; Noble et al. 2004). El Galeno is the
ated with chalcopyrite, pyrite, magnetite, bornite and youngest system (17.5–16.5 Ma) and has the most
minor molybdenite mineralisation. Significant hypogene complex intrusive history, with at least four intrusive
Cu and Au grades are preserved in the northeastern and phases present. The earliest two intrusions at El Galeno
southwestern potassic alteration zones. Late hydrother- are synmineralisation, whilst the final two represent late-
mal fluids related to phyllic and argillic alteration were to post-mineralisation porphyries. Post-mineralisation
transported along the NNW fault planes and over- low-grade or barren stocks are, however, common fea-
printed earlier potassic alteration. An intense phyllic tures of both Au-rich and Cu–Au–Mo porphyry
614

Table 1 Summary of the El Galeno, Michiquillay and Minas Conga porphyry centres

E1 Galenoa Michiquillaya,b Chailhuagon Perol


(Minas Conga)c,d (Minas Conga)c,d

Metal association Cu–Au–Mo Cu–Au–Mo Au-Cu Au-Cu


Resource 486Mt @ 0.57% 631 Mt @ 0.69% 190Mt @ 0.77g/t 428 Mt @ 0.78g/t
Cu+ 0.14g/t Au Cu+ 0.15g/t Au Au+ 0.28%Cu Au + 0.31% Cu
Age (Ma) 17.5–16.5 20.6–19.8 23.2–15.6 23.2–15.8
Intrusion type Hornblende–biotite Hornblende–biotite Hornblende–biotite Hornblende–biotite
diorite diorite diorite diorite
No. intrusions recognised 4 2 2 3
Dimensions of principal 1,250·600 m 5,000·1,500 m 2,000·500 m 1,600·650 m
intrusive (NW oriented) (NW oriented) (N–S oriented) (NW oriented)
Host rock type Qtzte, Sst and Sh Lst and Qtzte Lst and Marl Lst, Marl and MGD
Elevation (m.a.s.l) 3,850–4,000 3,500–3,750 3,840–3,900 3,870–3,960
Structural control of Located at the Emplaced within the Located at the intersection NW-trending perol
porphyry emplacement intersection of hanging wall of N- and NW-trending thrust fault
several structures of reverse fault faults
Brecciation Minor hydrothermal Minor magmatic breccia, Absent Absent
breccia, generally absent
post-mineralisation
magmatic breccia
Principal Alteration K, QM, QS, CbEF K, M, QS, E, Cl K(+M), QS, Skn, Q, CbE K(+M), QS, Skn, AA
Phases
Quartz stockwork Moderate–strong Moderate–strong Strong Strong–moderate
Controls Dominantly intrusion NNW faults and Intrusion and Intrusion and
on mineralisation related NE alteration trend vein related vein related
Main Hypogene sulphides Pyr, Ccp, Mo Ccp, Pyr, Mo Ccp, Bn, Pyr Ccp, Bn, Pyr
Supergene blanket Present (0–12 m) Present (0–40 m) Absent Poorly developed
(<50 m)
Supergene sulphides Cc, Cv Cc, Cv Cc, Cv Cc, Cv
Leached cap Thin (<10 m) Moderate–thick Absent Absent
(up to 80 m)

Rock types: Qtzte quartzite; Sst sandstone; Sh shale; Lst limestone; MGD microgranodiorite
Alteration phases: K potassic; Q quartz/silicic; M magnetite; S sericite; Skn skarn; AA advanced argillic; Cb carbonate; E epidote;
F fluorite; Cl clay
Sulphides: Pyr pyrite; Ccp chalcopyrite; Mo molybdenite; Bn bornite; Cc chalcocite; Cv Covellite
a
This study
b
MMA (unpublished data), McInnes (unpublished data)
c
Llosa and Veliz (2000)
d
Gustafson et al. (2004)

deposits (e.g. Maricunga belt, Vila and Sillitoe 1991; (Clark and Arancibia 1995; Sillitoe 2000). All three
Bajo de la Alumbrera, Ulrich and Heinrich 2001; Sillitoe mineralized porphyry centres in the Cajamarca district
2000). contain weak quartz, propylitic and late carbonate
Multiple alteration stages at El Galeno were tempo- alteration assemblages.
rally related to the emplacement of different intrusions. Significant differences between the three porphyry
The earliest two porphyries are characterised by centres relate to the hypogene sulphide assemblage and
K-feldspar-biotite alteration and intense quartz–mag- the presence or absence of a well-developed phyllic
netite alteration at depth. Quartz–muscovite–pyrite alteration. At El Galeno, elevated hypogene Cu and Au
alteration overprints the potassic alteration and is mineralisation were temporally and spatially associated
associated with emplacement of later intrusions. At with potassic alteration and high-density quartz stock-
Michiquillay, the distribution of the potassic and phyllic work veining in early intrusions. Pyrite, molybdenite
alteration assemblages was controlled by prospect-scale and to a slightly lesser extent chalcopyrite largely form
faults. Intense potassic alteration consisting of K-feld- the hypogene sulphide assemblage. At Michiquillay,
spar–biotite and widespread magnetite defines the Cha- high hypogene grades occupy zones of intense potassic
ilhuagon main porphyritic stock. Both Galeno and alteration and are associated with chalcopyrite, pyrite,
Michiquillay lack widespread hydrothermal magnetite molybdenite and minor bornite. Late stage fluids
throughout the deposit. Au-rich porphyry deposits, such transported along faults resulted in development of
as Grasberg (Meinert et al. 1997; Pollard and Taylor a low-grade, pyrite-rich phyllic core. Gammons and
2002), Far South East (Hedenquist et al. 1998) and Bajo Williams-Jones (1997) suggest late-stage fluids associ-
de la Alumbrera (Ulrich and Heinrich 2001), are ated with phyllic overprinting have the potential to
commonly characterised by abundant hydrothermal remobilise significant quantities of Au and Cu. Such a
magnetite associated with an early potassic alteration scenario is proposed for Michiquillay with late-stage
615

fluids remobilising potassic alteration related Cu–Au that influenced metal grades between the deposits may
mineralisation away from the centre of the deposit. In include host rock type, presence of widespread hydro-
contrast to Michiquillay and El Galeno, hypogene thermal magnetite, and the occurrence of late-stage flu-
mineralisation at Chailhuagon was deficient in molyb- ids resulting in remobilisation of early potassic
denum. High hypogene Au and Cu grades are charac- alteration-related metals.
terised by abundant bornite, magnetite and chalcopyrite.
A strong association between elevated gold and bornite Acknowledgements This paper has been largely taken from a
has been documented at other Au-rich porphyry chapter of the first author’s doctorate. The study was originally
sponsored by North Ltd. and later by Rio Tinto (Peru). Both
deposits such as Bingham (Ballantyne et al. 1997) and companies provide field support and funded the analytical research.
Grasberg (Rubin and Kyle 1997). However, where Bob Beeson, Jose Machare, Jesus Cordova and Tim Moody sig-
bornite is absent or chalcopyrite is more abundant than nificantly contributed to the set up and design of the project.
bornite, gold distribution is generally closely associated Additional analytical funds were provided through a James Cook
University–Industry collaborative grant. Newmont and Buen-
with chalcopyrite (Ballantyne et al. 1997, Ulrich and aventura are thanked for allowing access and samples to be col-
Heinrich 2001; Kesler et al. 2002). Experimental studies lected from Yanacocha and Minas Conga, respectively. Special
of Au distribution for high temperature (400–700C) thanks are extended to Cesar Vidal for coordinating various visits.
porphyry copper deposits indicate that bornite is the Reviews by Tim Baker, Dick Tosdal, David Cooke, Jeremy Rich-
ards, Lluis Fontbote, Massimo Chiaradia and Eric Marcoux sig-
dominant host of Au at temperatures of 700C or nificantly improved the manuscript.
greater (Simon et al. 2000). Additionally, chalcopyrite
preferentially precipitates over bornite and magnetite at
lower temperatures and oxygen fugacity. These authors References
also showed that when experimentally equilibrated with
Au, chalcopyrite was found to contain Au which was Atherton MP, Sanderson LM, Warden V, McCourt WJ (1985) The
less by one order of magnitude than bornite. volcanic cover: chemical composition and the origin of the
The highest Cu grades at El Galeno are spatially- magmas of the Calipuy Group. In: Pitcher WS, Atherton MP,
restricted to a secondary enrichment blanket that may Cobbing EJ, Beckingsale RA (eds) Magmatism at a plate edge:
the Peruvian Andes. Blackie, Glasgow and London, pp 973–984
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quillay also contains supergene enrichment zone of mineralogy of gold and silver in the Bingham Canyon porphyry
45 m thickness that is located beneath a moderately copper deposit, Utah. Soc Econ Geol Guidebook 29:147–153
thick (up to 80 m) leached cap. In contrast, supergene Benavides V (1956) Cretaceous system in northern Peru. Am Mus
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