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Submitted By
Adnan A. Mullaji
Year 2018-2019
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CERTIFICATE
This is to certify that the seminar report entitled
Submitted By:
Adnan A. Mullaji
Year 2018-2019
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ACKNOWLEDGEMENT
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CONTENTS
Sr.No Title Page
No.
1 Abstract 1
2 Introduction 2-4
3 Characteristic of fly ash 4-5
4 Fly ash utilization 6-8
5 Fly ash utilization in brick manufacturing 8-9
6 Suitability of mixing fly ash 9-11
7 Change of Properties with Fly Ash 11-13
8 Experimental Work 14-17
9 Results and Discussion 17-18
10 Characteristic of bricks before treatment 19-20
11 Characteristic of bricks after treatment 21-22
12 Financial aspect 23
13 Conclusion 24
14 Reference 25
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Abstract
Mixing various properties of fly ash in clay material (5-50% by weight, in ratio of dry
fly ash to wet clay, at a step of 5% each) this will from 16 bricks of each proportion
have been manufactured. The manufacturing process uses techniques and equipment
similar to those used in clay brick factories. The bricks produced were up to 10.60%
lighter than clay bricks. The bricks manufactured from fly ash possessed compressive
strength more than 5 N/mm2 which is more than normal clay bricks. This exceeds
some of the best of load carrying clay bricks and is several times better than
characteristics of the fly ash bricks have been evaluated. These included water
absorption capacity, compressive strength and Efflorescence test. Fly ash bricks
absorb less quantity of water which is under I.S. requirement. Fly ash-clay bricks give
nil efflorescence. The values of these characteristics for fly ash bricks are excellent
and have exceeded those pertaining to clay bricks. Moreover, fly ash bricks have been
produced with a naturally occurring reddish colour similar to that of normal clay
bricks. The new bricks and process have been given the name Fly ash Bricks. This
work presents the results of testing and the advantages gained by this type of bricks
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1.INTRODUCTION
1.1 Background
Fly ash is one of the numerous substances that cause air, water and soil pollution. It
disrupts ecological cycles and set off environmental hazards. It also contains trace
amounts of toxic metals which may have negative effect on human health, plants and
the land where the fly ash decomposed and not reused. The disposal of this waste
material is a matter of great concern from the environmental and ecological point of
view. So, it is very necessary to utilize the huge quantity of fly ash. The ever-
increasing volume of fly ash quantities in the world has not even remotely matched by
its utilization. The most important and popular use of fly ash in India has been the
India shares most of the Western countries in similar methods and traditions as far as
residential buildings are concerned. These include bricks as the main constituent.
one of the solutions to the ever-increasing fly ash disposal problem in the country. It is
therefore natural that the brick industry presents an opportunity for the efficient
utilization of the vast quantities of fly ash. In this dissertation we made the bricks with
use of fly ash and clay. Fly Ash bricks can be extensively used in all building
constructional activities similar to that of common burnt clay bricks. The fly ash
bricks are comparatively lighter in weight and stronger than common clay bricks. Fly
ash is being accumulated as waste material in large quantity near thermal power plants
and creating serious environmental pollution problems, its utilization as main raw
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material in the manufacture of bricks will not only create ample opportunities for its
proper and useful disposal but also help in environmental pollution control to a greater
In view of superior quality and eco-friendly nature, and government support the
demand for Fly Ash Bricks has picked up. Also 180 billion tones of common burnt
clay bricks are consumed annually approximately 340 billion tones of clay- about
5000 acres of top layer of soil dug out for bricks manufacture, soil erosion, emission
from coal burning or fire woods which causes deforestation are the serious problems
posed by brick industry. The all above problems can be reduced some extent by using
This has now been proven so it is taken for the manufacture of bricks from fly ash.
The response if the ash to firing temperature at 10000C and beyond can be accurately
controlled even in small factories. The potential savings with this approach are many.
transportation costs and producing bricks of superior qualities to those of standard clay
bricks are in addition to the environmental solution that such venture may bring about.
This may lead to save money which is needed to dispose the fly ash.The objective of
present work is to develop bricks with good strength as replacement of clay by fly ash
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in 5% to 50% to increase utilization of fly ash and to save environment. The objectives
• The main objective of this project is to study the effect of addition of fly ash in
bricks.
• To make the bricks without compromising its strength.
• To protect the environment by disposal of fly ash.
Utilization of fly ash can result not only in reducing the magnitude of the
environmental problems, but it is also to exploit fly ash as raw material for value
added products (and conserve traditional materials), and for extraction of valuable
materials. Use of fly ash in clay bricks saves the huge quantity of soil which is
required for making clay bricks and also saves agricultural land.
coal quality, type of coal pulverization and combustion process followed nature of ash
depending upon the characteristics of the coal) and refractory in nature. Its specific
surface area varies between 4,000 and 10,000 cm2/g, which is more than cement,
which has a specific surface area of about 3,000 to 3,500 cm2/g. Morphologically, fly
ash consists of 3 types of particles – irregularly shaped particles, solid spheres and
cenospheres. The fly ash particles range in size from about 115 microns to about 5
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microns. It has unburnt carbon, cinders, minerals etc. and has pozzolanic
characteristics.
Composition Indian fly ash British fly ash American fly ash German fly ash
Silica as SiO2 45 – 65.25 41.5 – 47.8 35 – 52 42.0 - 56.0
Alumina as Al2O3 14 – 31.10 26.4 – 29 15 – 32 24.0 - 33.0
Iron Oxide as Fe2O3 3 – 15.0 9.1 – 13.9 8 – 25 5.4 - 13.0
Calcium Oxide as 0.1 – 6.5 4.2 – 5.3 0.7 – 8.0 0.6 - 8.3
CaO
Magnesium Oxide 0.2 – 3.9 1.5 – 1.9 0.3 – 1.5 0.6 - 4.3
as MgO
Sulphur as SO3 0.4 – 1.8 0.7 – 1.7 0.1 – 2.8 0.1 - 1.9
Loss on Ignition 1 – 11.3 1.7 – 7.3 1.3 – 13.0 0.8 - 5.8
(LOI)
Neyveli flyash, which is high in CaO (5.0 - 16.0 %) and MgO contents (1.5 –
5.0 %) and low in SiO2 content (45.0 – 59.0 %), the range of chemical
composition of Indian fly ashes is given in Table 2.2 along with corresponding
substantial increase in amount of ash dispatched. The utilization increased six fold
from 9.2 Mt in 1998- 99 to 66.64 Mt in 2008 -09. The actual ash generated during
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2008 -09 was 116.69 MT and ash utilized was 66.64 MT and the overall utilisation
Figure 3.0 Total Ash utilization (1998-99 to 2008-09) (Mt) Source CEA(2009-10)
Figure 3.1 shows the share of different user sectors in total ash utilization.
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BOX 1: Fact Sheet of the Indian brick industry
consuming 24 million tonnes Brick production : > 1400 billion/year
of coal along with huge Annual turnover: > Rs 100 billion
quantity of biomass fuels. No of units: > 0.1 million
The total CO2 emissions Employment: 80 to 100 million people
Energy and Environment
are estimated to be 41.6
million tonnes and it accounts for o Coal : 24 million tonnes
o CO2 generation – 42 million tones
about 4.5% of total GHG o Top Soil: 350 million tones
emissions from India. Box 1
Source: TERI (2001)
represents the fact sheet of
Indian
brick industry. In the
manufacture of bricks, fly ash
can be an alternative material to
clay. Fly ash can be used
either with clay as part replacement or in combination with other materials like sand,
From the soil to be used for brick manufacturing, India can be divided into three broad
Mountainous soil is coarse and contains parts of partially wathered rocks. The
soil is ‘alluvial’ in nature formed by deposition of river Ganges and its tributaries. The
soil is considered good for brick manufacturing and has faint yellow colour and is
generally a mixture of fine sand,silt, clay and organic matter. The Peninsular soils are
generally black cotton, red or lateritic in nature. They are generally considered
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5.0 MATERIALS AND METHODS
The fly ash was collected from the Thermal Power Plant, Parli Vaijnath Dist. Beed .
Bricks are prepared from various mix of fly ash, clay and sand. Its properties such
water absorption, weight per unit volume, compressive strength were measured.
Secondly for fly ash bricks were prepared by using cement and stone powder in
varying proportions. Also, the bricks were prepared from flyash, lime, sand and
gypsum. The bricks were prepared by using different proportions of fly ash, lime,
Initially the lime was slaked with water and made it soft. The flyash was thoroughly
mixed with fly ash shows cementious property. The sand was used as an adulterant
and gave the strength to the bricks. The gypsum was used in the mixture to increase
the speed of hardening. The admixture was tempered by adding required quantity of
water.
The bricks are prepared by moulding it in 10 x 10 cm size mould. The clay in the
mould was compacted by using compaction machine. The blocks were kept in shade
6.0 Suitability of mixing fly ash with clay for producing fired bricks
Two cases are being presented here related to production of clay-fly ash fired clay
bricks:
Case 1: TIFAC in their report on Fly ash bricks has mentioned that with regard to
requirements of fly ash for brick manufacture, it is desirable that the oxide
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composition should be similar to ordinary brick clays – the silica content should be
over 40%, aluminium oxide not less than 15%, iron oxide not less than 5% and
sulphide and soluble sulphite content should be insignificant. The report further
mentions that the range of chemical compositions of Indian fly ashes indicates that
they are suitable for brick making. However, not all the clays and fly ashes are
suitable for brick making. Fly ash addition as a smaller constituent (8% - 20%) to the
alluvial soil or as a larger constituent (25% - 40%) with sticky plastic alluvial red and
black soils has been found advantageous to improve workability, green and fired
cracking and fuel value of residual carbon. The characteristics of clay-fly ash bricks
manufactured using alluvial, black and red soil region/ sites is provided in the
following table:
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Ramagundam 30 - 35 65 - 82 13.5 – 18.5 1.62 – 1.7
Following advantages of clay fly ash bricks are mentioned in the report:
Fuel saving in the range of 15% - 35% (coal consumption) or coal saving up to 3 –
Drying losses are checked in the case of plastic black and red soils. Excessive
Brick strength in the case of black and red soils is increased by almost one and a
Waste material is utilized. 30 – 40 tonne per lakh bricks in case of alluvial soils
and 100 – 125 tonnes per lakh bricks in case of red and black soils
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Case 2: Aligarh Muslim university (AMU) carried out a feasibility study for mixing
fly ash into the manufacture of fired clay bricks. AMU took samples of soil from the
three brick kiln sites of Aligarh and Hathras districts of Uttar Pradesh. The fly ash
sample was collected from the Kasimpur TPS that was within the designated distance
of brick kilns as per the 1999 notification of MoEF. During the study the fluash was
mixed with sol in different proportions 5%, 10% and 20% by weight and the bricks
were moulded under usual working conditions (same workmen , drying and firing
Fly ash and soil mix requires more water and labour in comparison to soil without
Bricks moulded from soil and fly ash mix requires three times the longer duration
Breakage in handling of green bricks was more in case of soil containing 20% fly
ash
A distinct change in colour was noticed in bricks containing 20% fly ash as
compared to bricks without fly ash. The reddishness in colour was less in bricks with
For the three soil samples collected from Uttar Pradesh, the following change in
properties were found while comparing with properties of the bricks without fly ash :
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20% Fly ash 10 % Fly ash 5 % Fly ash
Efflorescence Nil (All samples) Nil (All samples) Nil (All samples)
During the study, the black cotton soil using fly ash from the Virudhu Nagar district of
Tamil Nadu was also included and fly ash was mixed in the proportion of 40 – 70 %
by weight. It was found that up to 50 % mixing of fly ash the compressive strength
increased and water absorption decreased and with increased proportions of flay ash
The percentage of fly ash by weight that can be mixed in soil for manufacturing
fired clay bricks depends upon the physical properties of soil and it should not be
mixed arbitrarily
On the basis of tests carried out in three sites in Aligarh and Hathras districts, the
maximum percentage of fly ash by weight that can be mixed in soils is not more than 5
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Determination of physical properties of soil is essential before mixing fly ash with
The use of fly ash in brick making has many advantages and TIFAC has undertaken
many initiatives to promote the use of fly ash in brick making. However, most of the
brick kilns in the Indo-Gangetic belt have not used fly ash for manufacturing bricks
The hand-moulding process is generally used for green brick making in this region
and mixing of fly ash with clay is difficult by hand moulding. Further, brick kiln
owners felt that no appropriate technology is available for mixing of clay and fly ash
procurement of less quantity from Thermal Power plant and transportation of fly ash
Increase in the cost of the product due to increase in transportation and mixing cost
with no additional premium being fetched by fly ash product in the market.
Market perception of requirement of red coloured bricks also discouraged the brick
kiln owners to start producing fly ash bricks that generally have grey colour of final
product.
Non-availability of reliable and low-cost technology for clay-fly ash brick making
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The use of fly ash for brick making is quite popular in few States like Maharashtra
where the soil quality is such that the addition of fly ash improves the properties of
The benefits from the manufacture and use of fly ash bricks result in reduced energy
use, conservation of top soil and qualifying under clean development mechanism etc.
fly ash bricks making machinery, mindset of users, lack of awareness etc. pose
significant barriers in tapping the potential of brick making as a gainful use of fly ash.
The density of bricks decreased with the increase in flyash, lime, sand and gypsum
proportion. It is related with the volumetric shrinkage and was found in the range of
1.10 to 1.24 gm/cm3. The water absorption of the blocks were found in the range of
11-14%. As per IS - code percent water absorption in 24 hours should be less than 20
per cent. Compressive strength is the main property which determines the ultimate
Universal Testing Machine. Mix A, B,C,D,E, were found to be 174, 168, 124, 78 & 64
kg/cm2 respectively. Thus, the maximum compressive strength was observed in the
Other tests for bricks revels that no scratch was observed by using nails on the surface
of the brick. There was no efflorescence seen on the surface of the brick. Clear ringing
sound was heard after striking two bricks with each other.The structure after breaking
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7.0 Change Of Properties With Fly Ash
Water Compressive
FA:CL:
0:80:20
10:70:20
20:60:20
30:40:30
40:30:30
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8.0 EXPERIMENTAL WORK
So, far production of Flash Bricks has been performed in the laboratory. This has been
repeated successfully many times and the testing has produced consistent results. But
we tried to make bricks in the field where we can get water and clay easily. There are
several techniques for manufacturing construction bricks from fly ash, producing a
wide variety of products. One type of fly ash brick is manufactured by mixing fly ash
with an equal amount of clay, then firing in a kiln at about 1000 degrees C. We had
In this dissertation, the bricks made with four different processes. These processes are
as follows:
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Sample Bricks by weight Fly Ash (Kg) by weight Sand (Kg)
A 16 0 0 100 40
B1 16 5 2 95 38
B2 16 10 4 90 36
B3 16 15 6 85 34
B4 16 20 8 80 32
B5 16 25 10 75 30
B6 16 30 12 70 28
B7 16 35 14 65 26
B8 16 40 16 60 24
B9 16 45 18 55 22
B10 16 50 20 50 20
A series of test were performed on Flash Bricks in order to compare their qualities as
load bearing bricks with those made from clay. The Bureau of Indian Standards
12894 & 13757 – 1993 were applied in all the tests reported here. Commercially
available bricks were tested and compared to the results from Fly ash Bricks.
i. Compressive Strength
• Dry Compressive Strength of Bricks.
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9.0 Results And Discussion
9.1 Compressive strength
Dry Compressive Strength of Fly Ash-Clay Bricks
Bricks Average Compressive
Sample Strength (N/mm2)
A 4.348
B1 4.150
B2 4.427
B3 5.020
B4 3.874
B5 3.083
B6 2.213
B7 1.858
B8 1.304
B9 0.949
B10 0.830
C1 3.123
C2 3.202
C3 3.241
C4 2.253
C5 1.700
C6 1.423
C7 1.265
C8 0.870
C9 0.632
C10 0.395
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9.2 Water Absorption Test
Clay fly ash Brick
Bricks Percentage of Class of
A 21.67 IInd
B1 21.02 IInd
B2 20.11 IInd
B3 19.53 Ist
B4 22.10 IIIrd
B5 24.75 IIIrd
B6 25.73
B7 26.22
B8 28.21
B9 27.47
B10 26.51
Clay Brick
Bricks Percentage of water Class of
A 23.43 IIIrd
B1 22.92 IIIrd
B2 23.33 IIIrd
B3 21.21 IInd
B4 23.52 IIIrd
B5 25.87
B6 27.61
B7 28.34
B8 29.33
B9 28.05
B10 29.22
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10. Characterisation of bricks before treatment
The properties of the brick before treatment are shown in Table
1. Bulk density of conventional bricks varied from 1.85 - 1.90 g/cm3 and clay fly ash
bricks 1.80-1.85 g/cm3. The compressive strength of the conventional ghol brick was
in the range of 50- 55 kg/cm2 and in case of fly ash bricks 50-75 kg/cm2. Fly ash
also supported by several researchers (Pandey & Agarwal, 2002; Karade et al., (1995).
The wear and tear performance of conventional bricks was 5.86 mm, which was
slightly greater than that of fly ash bricks (5.14 mm.). Fly ash bricks showed better
The X-ray diffraction analysis of conventional and fly ash bricks showed almost
similar phase constituent. The mineral phases in fly ash improve the strength of bricks
due to the reinforcing effect of high temperature silicates such as mullite present in ash
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9 Shrinkage (%) 17.0 13.5
The results revealed that for the clay bricks exposed under accelerated environmental
conditions, the bulk density increased by ~5% with SOx, NOx and alkaline
treatment. Also CO2 , humidity, temperature and moisture and acidic treatment, the
increase in the density was 9% as compared to the bricks of before treatment. Almost
a similar trend was recorded in the case of clay fly ash brick. The effect of 500 days
of treatment, on the performance of clay bricks and clay fly ash bricks are shown in
Table 2 & 3 respectively. The compressive strength of fly ash bricks was decreased by
~6.3 kg/cm2 (8.7%) zwith CO2 treatment ; 9.6 kg/cm2 with UV radiation; 10.92
kg/cm2 (15%) with humidity; ~16 kg/cm2 (22%) with chlorine and SOx treatment.
carbon dioxide with some constituents of solidified matrix which affects the physical
and chemical properties and which is based on the presence of chemical constituents,
The penetration of water, chloride and other ions in the materials is the most important
factor for the deterioration that affect the durability. It depends on the size distribution
of raw materials, aggregate past volume ratio and micro structure of the solidified
phenomena (Byung et al., 2002). As in the case of clay bricks, the decrease in
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compressive strength was by ~ 4.5% with NOx and alkaline treatment; 8.5% with
saline treatment and 14.7%with UV radiation. The compressive strength might have
decreased under this treatment due to chemical changes, carbonation, precipitation and
The result revealed that the water absorption capacity of bricks under different
treatment and durations, the treatment effect did not increase the water absorption
capacity except there was ~ 1.5 % decrease under saline treatment. The wear rate of
both types of bricks after 300, 400 & 500 days of treatments was found negligible.
permeability of bricks, and a decrease in permeability was recorded almost in all the
treatments.
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3 Belt Conveyor with necessary fittings 1 50,000 50,000
and 2 HP Motor
TOTAL 15,00,000
60,000
VAT 4 %
GRANT TOTAL 15,60,000
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13.0 CONCLUSIONS
i. The results are indicative of the satisfactory performance of Fly ash Bricks as
load bearing elements. This type of bricks uses 15% fly ash mixing with 85%
clay. It therefore provides a large venue for the disposal of fly ash in a very
efficient, useful and profitable way. This result is better compared to lime bricks
and clay bricks.
ii. The mechanical property of Fly ash Bricks has exceeded those of the standard
load bearing clay bricks. Notable among these properties are the compressive
strength. The wet compressive strength was 40% better than
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14.0 REFERENCES
[1] Building Materials & Technology Promotion Council, Ministry of Housing &
Poverty Alleviation, Government of India, New Delhi.
[2] Bureau of Indian Standards 12894 – 1990.
[3] Bureau of Indian Standards 13757 – 1993.
[4] Bureau of Indian Standards 2117 – 1991.
[5] Bureau of Indian Standards 3495 – 1976.
[6] ENVIS Newsletter Volume 2, No. 6.
[7] Illinois Department of Commerce and Community Affairs, Manufacturing
Commercial Bricks with Fly Ash from Illinois Coals, www.commerce.state.il.us.
[8] International Journal of Innovative Research in Science, Engineering and
Technology Vol. 2, Issue 3, March 2013
[9] International journal on civil and structural engineering volume 1, No 4, 2011
[10] Kumar, V., Mathur, M., and Kharia, P. S. (2003). Fly ash management: Vision
for the New Millenium, Technology Information Forecasting and Assessment
Council, News and Views, 25, March, www.tifac.org.in/news/flymgm.htm.
[11] Lingling, X., et al., study on fired bricks with replacing clay by fly ash in high
volume ratio. Construction and Building Materials. In Press, Corrected Proof.
[12] Ministry of Environment and Forests, Notification, Extraordinary, Part II, Section
3.
[13] Pimraksa, K., Wilhelm, M., Kochherger, M. and Wruss, W., (2001).A new
Approach to the Production of Bricks Made of Fly Ash, International Ash
Utilization Symposium, Centre for Applied Energy Research, University of
Kentucky, Paper # 84, http://www.flyash.info.
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