Sec: Sr.

IIT_IZ GTA-15 Date: 19-05-19

Time: 09:00AM to 12:00 NOON 2011_P1 Max.Marks: 240
KEY SHEET

CHEMISTRY
1 A 2 C 3 C 4 C 5 A

6 D 7 B 8 ABC 9 AB 10 ABC

11 ACD 12 B 13 C 14 B 15 A

16 C 17 2 18 1 19 3 20 5

21 1 22 3 23 6

PHYSICS
24 B 25 C 26 A 27 A 28 A

29 A 30 D 31 AD 32 ABC 33 ABD

34 AD 35 A 36 B 37 A 38 B

39 C 40 3 41 3 42 1 43 6

44 2 45 2 46 6

MATHS
47 C 48 A 49 A 50 B 51 C

52 B 53 A 54 BCD 55 AC 56 ABC

57 ABCD 58 B 59 C 60 B 61 D

62 C 63 6 64 7 65 5 66 8

67 1 68 5 69 3
Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s
SOLUTIONS
CHEMISTRY
A 
 C
1.
a  2x x
A 
 D
a  2x x
a  2x  x
a
x
3
 2K1  t  n 3
n 3
t
2K1
2. NaBH 4 reduces aldehyde and ketone to alcohol, not esters. Where is LiAlH 4 reduces
both.
3. PbO 2 +HCl = PbCl 2  Cl 2 + H 2O
5. Lead chamber process: NO
Contact process: V2O5
2 CuCl2  SO2  H 2O  Cu2Cl2  H 2 SO4  2 HCl

HCl(aq) is fully ionized; solutions of NH3 contain dissolved NH3

9. Al/NaOH as well as Zn/NaOH reduce nitrate to ammonia and CuO as well as NaOCl
will oxidise NH3 to N 2
10. A) In cis-1-bromo-4-tertbutylcyclohexane Bromine is on axial position so sterically
easy to replace or attacked by Nucleophile
B) 1 alkyl halide are faster to react with NaCN than 2
C) 1 alkyl halide are faster to react with NaCN than 2
D) % Racemisation indicates SN1
12. Donation of electrons from the filled d-orbitals of metal, electrons enter into the anti-
bonding molecular orbitals of CO. Therefore, bond order decreases.
13.  Ni(CO)4  -sp3 ,diamagnetic ;  Fe(CO)6  -d 2sp3 ,diamagnetic
 V(CO)6  -d2sp3 ,paramagnetic ;  Cr(CO)6  -d 2sp3 ,diamagnetic
18. Pb 2 , Bi3 and Cu 2 all give black ppt with Na 2S but its only Cu 2 which gives green
ppt with Na 2CO3 . (Cu  OH 2 .CuCO3 is green remaining carbonates are almost white)
ZnS is grey ppt and MnS is buff/pale pink ppt
19.

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Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s
Cl Cl Cl

Cl
Noneis optically active

Cl Cl
21. H 2O

a) b) c) d) e) f)
22. are isomers of C 4 H 8 .
Out of these a and b will give racemic mix on reaction with Br2 in CCl4
PHYSIS
24. FH  Pavg  Vertical projected area of gate
PA  PB  gR   g 3R  2
  2 R  3R     6 R  12  gR
3

2  2 
N f
W

mg sin 

 mg cos 
25.
Which block is static
mg sin   f
f
 sin 
w
Impending state of motion
mg sin  0   s mg cos  0
tan  0   s
When block slips
f  k mg cos 
f
  k cos 
w
 V  V0 
26. f  f0  
 V 
Here, V0  u  at
Vs  0  f varies linearly with ‘t’
27. Lr  L1 , (about linge)
  4m 2  
2

m v  m  
2  12  2  

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Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s
mv 7 6v
 m 2  
2 12 7
28. PV 2/3  C
T 2/3 T
V C  C
V V 1/3
T  CV 1/3
29. In equilibrium, the level of liquid in both the vessels will be equal,
X1  X 2
i.e., h 
2
Work done = Change in PE
X1 X h
m1 g  m2 g 2   m1  m2  g
2 2 2
 X  X 2   1 gdS X  X 2
2
X2 X2
 gdS 1  gdS 2  gdS 1  2 1
2 2 4 4
YA K1 Y1 m
30. K ;  ; T  2
L K 2 Y2 K
T1 K2 Y T1 3
  2 ; 
T2 K1 Y1 T2 2
T F

2g
31.
1 2
mv  16
2
v  4m / s
v  u  at
a  2m / s 2
If a is upward F  24 N
If a is downward F  16
32. Conceptual
Fy
F

x B
A 30N
P Fx

33. 10N 40N

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Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s
Let P be point of application of force.
TA  Fy x  40  5  0
Fy x  200 ... 1
Fy  10  40 ...  2 
Fy  50 N , Fx  30 N , x  4m
34. Speed of sound depends on the frame of reference observer.
hc
35.  7.56 eV

36. K.E max = Incident photon energy – Work function
42.35 h
37. p  2mE  2  9.1 1031  19
; 
1.6 10 p
1
38. K .E  I axis 2
2
1
 m 2 sin 2   m sin 2    2  m 2 2 sin 2 
2
Alternate Solution :
1
K .E  2   m l sin  
2

2
39. Torque about C is:
F  m 2 r

 m

l

C

m 
r
F  m 2 r
  lF sin   lF sin 
 2lF sin  90   
 2l  m 2 r  sin  90   

 2l  m 2l sin   sin  90   

 2m 2l 2 sin  cos 

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Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s

N1

40. a

N1  a1
M1 g
Let M 1 be the mass of the rod.
For rod  M1 g  N1 cos   M1a1 ...  i 
For wedge  N1 sin    M  M  a ...  ii  a1  a tan 
relation between A1 and A
a1  a tan 
So by solving these equation M 1  3M  3kg

C
a P
x
R
mg


41.
Restoring torque
 mgx
x  CP cos   CP [a is very small]
x  R
mL2
 mgR  I  
12
gR L2 L L
 12 2
    T  2  
L 12 gR 3 gR 3R
42.   2  3m
Equation of standing wave
y  2 A sin kx cos t
y  A as amplitude is 2 A
A  2 A sin kx
2  1
x  x1  m
 6 4
2 5
and x  x2  1.25m  x2  x1  1m
 6
43. Strain developed:
    T  12  106   50   6 10 4

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Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s
2
d
T
44. As; d    dT  a  TdT

 0

 n 4  n 4
2 1/2
T
n 2  a T   2
2  a  a

N

Mg sin 

Mg cos 
Mg
45.
KE1  PE1  KE f  PE f

1  M  2a   2
2 2
a a
0  M      Mg sin 
2  12 3  3
3 g sin 
2 
2a
Differentiate
d 3g
   cos 
d 4 a
Equation along tangential & radial direction
3
M   Mg cos   N
a
3Mg
N cos 
4
a
M  2   N  Mg sin 
3
  2 tan 
x  2
FB

46. T Vd  g  a

Buoyancy force on block

2 3 
FB   V  2  V 1   g  a 
 5 5 
From the frame of the vessel under equilibrium condition
FB  T  Vd  g  a 
T  FB  Vd  g  a 
2 3 
T   g  a  V    1  d 
5 5 

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Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s
2 3 
T  15  103  1500  1000  800  T  6 N
5 5 
MATHS
47. Using applonius theorem shift origin to (1,0)

z1 z2
z  x, y 

 2  3 
2

1  2  2 x  y    
2 2 2

  2 
5 9
  x2  y 2 
2 4
1 1 1 1
 x2  y2    Z    z  1   z z  z  z   0
4 2 2 2

48.    
1  8 3  3 ,  2  2 3  3  1   2  30  6 3
 
 2
1  1 2 1 1 
49. II
2 
0
2  sin 2 x  sin 2 x
2
 I      dx
4 3 0 sin 2 x  1 2  sin 2 x 
 2 
 1
2  3 3 


 1 2  1   2 3  4
50. 1   2    
4  3 2 3 6
  2  3 2 9  4
 2   1 2       
 2 3 2 3 6
51. GE  f ' 0  9
53. 3 x  1  4  y  2  5  z  3  15 ……(1)
K  GE   x  1   y  2   z  3  4
2 2 2
…..(2)
Use cauchy scwarz
225
15  32  42  52 k  4   K 4
50
17 17
K   K min 
2 2
K  8
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Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s
1.n1 Cr 1  2.n 2 Cr 1  ....   n  r  1 .n1 Cr 1
54. f  n, r   n 1
Cr 1  n2 Cr 1  ....  r 1 Cr 1
n 1
Cr 1 n  1
 
n
Cr r 1
ghf ' fhg ' fgh '  6  fgh  6
2
55.
 
 f  x  g  x h  x  tan  6 x  
 4
56. a  b  c  0 …..(1) etc…
a2
b  7
c5
f  x  2 x 2  7 x  5
No.of solutions = 4
58-60:
x 1

 f  x dt  x f  x  x  f ' x dx .......1
2

0 0
1

f  x  x f ' x   f  x   2 x  f ' x dx
0
1

 f ' x   2 f '  x dx  0
0

 f ' x   2 A  0º  f  x   2 Ax  C

 f  C   3 3  C  f  x   2 Ax  3

6

 sin  3x  cos  3x dx

6 4

0
 
1 2 6 1 2 4
  sin x   cos x
30 30
1 5 3 1   1 3 1  
  , , ,   . . 
3 6 4 2 2 3 4 2 2
1  3 1    5   11 11
  . .    1   
3  4 2 2   6  16 6 96
1

Let  f ' x dx  A
0

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Narayana IIT Academy 19-05-19_Sr. IIT_IZ_JEE-Adv_2011-P1_GTA-15_Key & Sol’s
1

   2A dx  A
0

 2 A  A  A  0
 f  x  3
61&62:
g  g' f  f
f ' f   f ' f   f  f '  g  g '  0 (or)
g2 f 2 .g 2
f 2 g 2  1  0(not possible)
 
 f  x   f ' x   f  x   1  2 e x


g  x  1  2 e x 
   
f 1  g  1  1  2 e  1  2 e  2e   2e   5
200!
64. 2  p  99 GE 
100!100!
In the denominator it appears twice. Therefore it must appear thrice in
number for Such number is 61  sum = 7
3
65 K   GE  5
2
66. Let A=A gets exactly 3
B=B gets exactly 3
C=C gets exactly3
D=D gets exactly 3
 n  A  B  C  D  ?
Required value  4  11C2  6  7C1  4 1  1
=181
Maximum digit =8
67. Let A = A gets exactly 3
B = B gets exactly 3
C=C gets exactly 3
D= D gets exactly 3
 n  A  B  C  D  ?
Required value  4 11 C2  6 7 C1  4  1  1
 220  42  4  1  181
Maximum digit = 8
2
 b
68. Area of APD     area of BPC
 a

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2
 8
    49  64
 7
1
GE  64   sum of digits   5
2
1
 x 5x2  7 x
69. Lt 2x
x 0

 ax  bxdx
2

P(x,y)

(0,0) Q(x,0)

(using L.H. Rule)

3
4 3
4

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