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9/25/2016 BEC Reviewer (BEC Chem) Flashcards | Quizlet

BEC Reviewer (BEC Chem) 101 terms by elainne_catalan

protons and electrons Uranium-235 and uranium-238 have


--- the same number of which of the
isotopes have the same number of following?
protons & electrons

4 What is the valence (oxidation state) of


--- CARBON in sodium carbonate (Na₂CO₃)?
Na₂CO₃
Na = 1, O = 2-
1(2)+x-2(3)=0
x=6-2 = 4
C=4

3.3g Water and SO₃ combine to sulfuric acid


--- (H₂SO₄) according to the following
SO₃ + H₂O → H₂SO₄ reaction. How many grams of water
S=32.06g; O=16g; H=1.01g must be added to 100g of 20% oleum
1mol SO₃ = 32.06g + 3(16) = 80.06 (20% SO₃ and 80% H₂SO₄ by weight) to
1mol H₂O = 2(1.01) + 16 = 18.02 produce a 95% solution (by weight) of
1mol H₂SO₄ = 2(1.01) + 32.06 + 4(16) sulfuric acid?
= 98.08

H₂O = 18.02 x 20% = 3.604g ≈ 3.3g

5.17 L During a laboratory experiment at 1.0


atm and 25°C, a student observed that
oxygen gas was produced by
decomposition of 15g of sodium
chlorate. What was the volume of
oxygen?

the activation energy of a reaction Which of the following does a catalyst


change?

different arrangement of the same What is an isomer?


atoms

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the amount of I₂ will have increased The reaction shown occurs in a gaseous
phase. Once equilibrium has been
achieved in a particular reaction vessel,
additional HI gas is injected directly into
the reaction vessel. Compared to the
initial conditions, which of the following
statements is correct after the new
equilibrium has been achieved?

KCI Which of the following compounds


would be ionic, considering the
electronegativities of the elements?

HCI An unknown gas with a temperature of


25°C and a pressure of 740 mm Hg is
collected in a sampling bag. The volume
and mass of the gas are 24.0L and
34.9g, respectively. Which chemical
formula could represent the gas?

0.067 What is the percentage (by mass) of


hydrogen in glucose (C₆H₁₂O₆)?

63 2.00g of a substance dissolved in 250g


--- water produces a boiling point elevation
0.065 = 0.512(2g/M) / (250)(1/1000)kg of 0.065°C. What is the molecular weight
M = 63.02g/mol of the substance?

0.050g A current of 0.075A passes through a


solution of silver nitrate for 10 munites.
How much silver is deposited?

3.6g How many grams of copper will be


deposited at an electrode if a current of
1.5A is supplied for 2 hours to a CuSO₄?

second order with respect to E; second What is the order of reaction with
order overall respect to the reactant E and the overall
order of the reaction described by the
following rate law?

a mole What is the term for a quantity of a


substance to which a chemical formula
can be assigned and whose mass is
equal to its formula weight?

3 The pH of a 0.001 M HCI solution is:


---
pH = -10g [0.001]
=3

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14,500 atoms The half-life of radioactive carbon is


approximately 5700 years. If a sample is
found to have 7000 atoms after 6000
years, how many atoms were present
initially?

more ammonia (NH₃) would be Given the following reversible chemical


generated reaction, assume all reactants and
products are ideal gases.

concentration have NO effect on the Which of the following statements


direction of the reaction concerning reversible reactions is FALSE?

I and III Which of the following reactions are not


balanced?

63 2.00g of a substance dissolved in 250g


water produces a boiling point elevation
of 0.065°C. What is the molecular weight
of the substance?

0.5 mol Oxygen reacts stoichimetrically with


methane to form 14g of carbon
monoxide. How many moles of methane
are consumed?

CaCI Which of the following chemical


formulas is INCORRECT?
(--> CaCI₂)

AI(NO₃)₃ , Mg(OH)₂ , CaO , CuCO₃ What are the chemical formulas for the
following compounds: aluminum nitrate,
magnesium hydroxide, calcium oxide,
and cupric carbonate?

1,3,1,1,3,1 Nitroglycerin is made by combining


glycerol, nitric acid, and sulfuric acid.
What are the minimum coefficients
needed to balance the equation of these
reactions?

the water momentarily stops boiling Which of the following occurs when table
salt (NaCI) is added to continuously
heated boiling water?

320 kPa The final temperature of the hydrogen


and chlorine described in Prob. 8 is
30°C. What is the final pressure in the
reaction vessel?

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3.1 x 10⁻⁵ atm A wastewater treatment plant uses


chlorine gas as a reactant. A tank is
filled with 800 m³ of 20°C water,and
chlorine is added at a dosage of 125 g
per cubic meter of water. (Assume all of
the chlorine dissolves and none initially
reacts chemically.) If the atmospheric
pressure is 1.0 atm, what is the
theoretical partial pressure of the
chlorine gas at the tank surface
immediately after the gas is added?

ester What family of compounds is produced


from the reaction between an alcohol
and a carboxylic acid?

bases have a sour taste Which of the following statements


pertaining to acids and bases is
INCORRECT?

always increases As the pressure of a gas increases, the


solubility of that gas in a liquid..

they readily accept an electron from What is a distinguishing characteristic of


another atom to form compounds the halogens?

energy absorbed during creation of 1 Enthalpy of formation is most closely


grammole of a compound from pure defined as the..
elements

0.89 kW% Assuming all the energy goes into the


reaction, what electrical power is
required to produce oxygen gas at a rate
of 50 mg/s?

6 What is the oxidation number for


--- chromium (Cr) in the compound BaCro?
2 + x - 2(4) = 0
x=8-2
x=6

14 L A transportation company specializes in


the shipment of pressurized gaseous
materials. An order is received for 100 L
of a particular gas at STP (0°C and 1
atm). What minimum volume tank is
necessary to transport the gas at 25°C
and a maximum pressure of 8 atm?

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B₂O₃ In an experiment, a compound was


determined to contain 68.94% oxygen
and 31.06% of an unknown element by
weight. The molecular weight of this
compound is 69.7 g/mol. What is this
compound?

70 g / mol 6 g of a substance are dissolved in 1000


g of water. The solution freezes at
-0.16°C. What is the molecular weight of
the substance?

0.24 A gaseous mixture consists of 2 kg of


oxygen, 5 kg of nitrogen, and 3 kg of
xenon. What is the mole fraction of the
oxygen gas?

67 days The diameter of a spherical mothball is


observed to halve in 200 days.
Approximately how long will it take for
its remaining volume to become half of
its volume at 200 days?

45 For a given isotope of an element, the


atomic number plus the atomic weight is
148, and their difference is 58. How
many protons does an atom of the
isotope contain?

0.350 kPa 10 g of solid PCI₅ is heated in a 0.5 m₃


container to 150°C, producing gaseous
PCI₃ and CI₂ gas according to the
following decomposition reaction: The
molecule weights of the compound are
What is the increase in pressure in the
container when 50% (by weight) of PCI₅
is decomposed?

the remaining portion of an alkane after An alkyl radical is best defined as..
it loses a hydrogen atom

210 kPa It is known that ozone (O₃) will


decompose into oxygen (O₂) at a
temperature of 100°. One mole of ozone
is sealed in a container at STP (0°C and 1
atm). What will be pressure of the
container once it is heated to 100°C?

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1.78 L How much water must be added to 100


mL of a 0.75 molar solution of KCI to
make a 0.04 molar solution?

uniformly increase While moving from left to right across


the second row of the periodic table (i.e.
from Li to Ne), the atomic radii tend to..

110 A solution is adjusted from pH 8 to pH


--- 9. The relative concentration of the
8 = -log [H⁺] = 1x10⁻⁸ hydrogen [H⁺] ion has changed by a
9 = -log [H⁺] = 1x10⁻⁹ factor of what?
1x10⁻⁹ / 1x10⁻⁸ = 1/10

0.1 g The solubility constant of stronyium


sulfate, SrSO₄ is 2.8x10⁻⁷. How many
grams of SrSO₄ must be dissolved in
water to produce 1 L saturated solution?

H (hydrogen) Which of the following elements has the


largest first ionization energy?

100mL How many milliters of 1 M NaOH


solution will 25 mL of 2 H₂SO₄
neutralize?

0.107 What is the molarity of a solution


obtained by dissolving 25 g of NaCI in
enough water to produce 4 L of
solution?

3 days What is the half-life of a substance that


decays to 25% of its original amount in
six days?

2 moles of sodium hydroxide and 1 Two moles of sodium react with 2 moles
mole of hydrogen of water to produce which of the
following?

becomes moist When a deliquescent substance is


exposed to air, it..

sulfur Which of the following elements does


not exist as a diatomic molecule under
normal (ambient) conditions?

0.11 A given sample of radioactive material


has 80% of the original substance
remaining after 10 years. How much will
remain after 90 additional years?

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3.3x10⁹ yr The decay of U-238 to Pb-206 can be


used to estimate the age of inorganic
matter. The half-life of U-238 is
4.5x10⁹ years. In a particular rock
sample, the ratio of the numbers Pb-206
to U-238 atoms is 0.66. Assumer all of
the Pb-206 present is due to the decay
of U-238. What is the age of the rock?

0 kcal/mol How much energy is needed to convert


ozone to oxygen?

alkali metals The group of metals that includes


lithium, sodium, potassium, rubidium,
and cesium forms a closely related
family known as the..

160 kg Hydrogen and chlorine gas combine in a


25 m³ reaction vessel to produce
hydrogen chloride. The masses of
hydrogen and chlorine are 4.5 kg and
160 kg, respectively. How much
hydrogen chloride gas is produced?

2.0 L How many liters of 2M solution (i.e., a


molarity of 2) can be produced from 184
g of ethyl alcohol (CH₃CH₂OH)?

8.29 mg/s If the current, I, is 100A, at what rate is


oxygen produced?

32 mg What mass of lead nitrate, Pb(NO₃)₂,


must be dissolved in 1 L of water to
produce a solution that contains 20 mg
of lead ions? Assume 100% ionization.

C₃H₈ A compound in gas form has a mass of


0.377 g and occupies 191.6 mL at
standard conditions (0°C and 760 mm
Hg). What is the formula of the
compound?

0.510 atm A gas mixture of N₂ (g) and CO₂ (g)


contained in a volume of 10.0 L has a
total pressure of 0.750 atm at a
temperature of 273K. The mixture is
known to contain 3.00 g N₂ (g). What us
the partial pressure of CO₂ (g) in the
mixture?

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CO²2<² Rank the following gas according to


increasing effusion rates relative to O₂
(reference).

22.8 torr What is the vapor pressure of 1000.0 g


of a water solution at 25°C that contains
124.0 g of the nonvolatile solute
ethylene glycol, C₂H₆O₂? The vapor
pressure of pure water at this
temperature is 23.76 torr. Assume an
ideal solution.

raise the temperature and add more Consider a solution of water and a
water nonvolatile solute at some temperature.
What combination of conditions would
be sure to increase the vapor pressure of
the solution?

1.42 g What is the mass of 0.01 gram-moles of


Na₂SO₄?

N² An ideal gas occupies a volume of 4 L


and has a pressure of 283.71 kPa (1 atm
= 101.325 kPa). under 22.50C, what
most likely is the identity of the gas if
0.01293 kg of gas is used?

1.7x10⁻² mol/L The reaction shown proceeds in a


gaseous state. At equilibrium, the
concentration of the components X, Y,
and Z are measured to be 5.73x10⁻²
mol/L, 2.67x10⁻² mol/L, and 4.59x10⁻²
mol/L, respectively. What is the
equilibrium constant for this reaction?

882°F If 1.5 L of an ideal gas at 25°C is heated,


the new volume increases 2.5 times the
original volume. The pressure and
amount of substance are held constant.
What is the new temperature of gas in
°F?

excited, ground, impossible Following are three states for fluorine:


1s22s12p6 1s22s22p5 1s22s22p42d1
they are, respectively: _________

381°C At what temperature in °C will O₂ has


under a pressure of 2.4 atm?(p of O₂ =
1.43 g/L)

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98.51 Kpa Macro Vee collected hydrogen gas using


water displacement method. He
measured the temperature of water
using a thermometer and found out that
it is 23°C with the corresponding
pressure of 21.1 mmHg. Calculate the
pressure of hydrogen gas under
standard atmospheric pressure.

C₃H₇NO A sample of an unknown compound is


found to be 49.3% carbons, 9.6%
hydrogen, 19.2% nitrogen, and 21.9%
oxygen by weight. What is its molecular
formula?

HBrO₃ + 5HBr 3H₂O + 3Br₂ Balance the following reaction.

[Xe]6s25d104f146p2 Which of the following is the correct


electron configuration of Pb?

12.00 grams of ¹²C The mole (mol) is the amount of a


substance that contains as many
elementary entities as there are atoms in
exactly

different by about 11.2 L At STP the volume of 1.5 mole N₂ as


compared to 1.0 mole O₂ is..

64.9 g How many grams of glucose, C₆H₁₂O₆,


are necessary to prepare 656 mL of a
solution with a concentration that is
0.550 molar?

Mg is the reducing agent, O₂ is the n the following reaction, which elements


oxidizing agent are the reducing oxidizing agents?

increase three times the original By decreasing the pressure of an ideal


gas at constant temperature and amount
of substance 1/3 times the original
pressure, the volume of gas will..

0.33 What is the gravimetric (i.e., mass)


percentage of oxygen in K₂CrO₄?

320 g There are 500 g of zinc sulfide (ZnS) in a


load of zinc ore. The ZnS is roasted in
excess air to form zinc oxide (ZnO) and
sulfur dioxide (S)₂). How many grams of
zinc can be subsequently recovered if 5%
of the zinc is lost in the roasting
process?

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-340 kcal/mol (exothermic) What is the enthalpy of reaction at 25°C


for the combustion of ethane (C₂H₆)?

1 In period 3 of the periodic table, the


atom with the largest atomic radius is
located in group:

energy has a mass and takes up space Which statement is incorrect regarding
energy?

3s23p5 An atom in the ground state has seven


valence electrons. Which electron
configuration could represent the
valence electron configuration of this
atom in the ground state?

2.9 L When active metals such as magnesium


are immersed in acid solution, hydrogen
gas is evolved. Calculate the volume of
H2(g) at 30.1°C and 0.85 atm that can be
formed when 275 mL of 0.725 M HCI
solution reacts with excess Mg to give
hydrogen gas and aqueous magnesium
chloride.

MnO The mineral manganosite is a compound


of manganese-55 and oxygen-16/ If
77% of the mass of manganosite is due
to manganese, what is the empirical
formula of manganosite?

its vapor pressure is equal to the A liquid will boil when..


surrounding pressure

ammonia Which substance can be decomposed


chemically?

100°C At which temperature does a water


sample have the highest average kinetic
energy?

1.8 g/L Air contains 78% N₂, 21% O₂, and 1% Ar,
by volume. What is the density of air
1,000. torr and 10°C?

gained potential energy A book is lifted off of the floor and


placed on a table that is one meter
above the floor. The book has..

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0.856 g Chlorine gas can be prepared in the


laboratory by the reaction of solid
manganese dioxide with hydrochloric
acid. (The other reaction products are
aqueous manganese chloride and water.)
How much MnO₂ should be added to
excess HCI to obtain 275 mL of chlorine
gas at 5.0°C and 650 mmHg?

valence electrons Assuming the ground state, all of the


elements located in the group of 12 of
the periodic table will have the same
number of..

57.15 g/mole The time required for a given volume of


N₂ to diffuse through an orifice is 35
sec. Calculate the molecular weight of a
gas which requires 50 sec to diffuse
through the same orifice under identical
conditions.

1s22s23s1 Which electron configuration


demonstrates an atom in the excited
state?

CO2(g) Which sample demonstrate particles


arranged in regular geometric pattern?

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