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EXERCISE-01 CHECK YOUR GRASP
SELECT THE CORRECT ALTERNATIVE (ONLY ONE CORRECT ANSWER)
1. In a reaction PCl5 PCl3 + Cl2 degree of dissociation is 30%. If initial moles of PCl5 is one then total
moles at equilibrium is
(A) 1.3 (B) 0.7 (C) 1.6 (D) 1.0
2. For reaction HI ½ H2 + ½ I2 value of Kc is 1/8 then value of Kc for H2 + I2 2HI.
1 1
(A) (B) 64 (C) (D) 8
64 8
3. In a equilibrium reaction H2(g) + I2(g) 2HI(g)
H = – 3000 calories,
which factor favours dissociation of HI :-
(A) Low temp. (B) High Pressure (C) High temp. (D) Low pressure.
4. N2 + 3H2 2NH3
If temp. of following equilibrium reaction increase then -
(A) Shift Right side (B) Shift left side (C) Unchanged (D) Nothing say.
5. C(s) + H2O (g) H2(g) + CO(g)
by increasing pressure following equilibrium
(A) Unaffected (B) Proceed in backward direction
(C) Proceed in forward direction (D) Unfixed
6. Unit of equilibrium constant Kc for following homogenous reaction :-
4NH3 + 5O2 4NO + 6H2O is
n -1
(A) (Conc ) (B) (Conc n) +1 (C) (Conc n) +10 (D) Have no unit
7. Which of the following factor shifted the reaction PCl3 + Cl2 PCl5 at left side.
(A) Adding PCl5 (B) Increase pressure (C) Constant temp. (D) Catalyst.
8. In which of the following process reaction is fastest complete.
(A) K = 10 (B) K = 1 (C) K = 103 (D) K = 10–2
9. At 298 K equilibrium constant K1 and K2 of
following reaction SO2 (g) + ½ O2(g) SO3(g) ----- (1)
2SO3(g) 2SO2(g) + O2(g) -------- (2)
K
CO + H2O CO2 + H2
K1
2CO + O2 2CO2
K2
2H 2+ O 2 2H 2O
then find out the relation between equilibrium constants :-
(A) K = K1K2 (B) K = (K1K2)2 (C) K = (K1K2)–½ (D) K = (K1/K2)½
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21. The reaction A + B C + D is studied in a one litre vessel at 250°C. The initial concentration of
A was 3n and that of B was n. When equilibrium was attained, equilibrium concentration of C was found
to the equal to the equilibrium concentration of B. What is the concentration of D at equilibrium :
(A) n/2 (B) (3n – 1/2) (C) (n – n/3) (D) n
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the equilibrium concentration are (a – x) and (b + x) respectively ; express x in terms of k1, k 2, a and b :
k1a k 2 b k1a k 2 b k1a k 2 b k1a k 2 b
(A) k1 k 2 (B) k1 k 2 (C) k1k 2 (D) k1 k 2
23. The value of K p for the reaction
2H 2 O (g) + 2Cl 2O (g) 4HCl (g) + O 2 (g)
is 0.03 atm at 427°C, when the partial pressure are expressed in atmosphere then the value of K C for
the same reaction is :
(A) 5.23 × 10 –4 (B) 7.34 × 10 –4 (C) 3.2 × 10 –3 (D) 5.43 × 10 –5
1
24. The equilibrium constant of the reaction SO2 (g) + O (g) SO3 (g) is 4 × 10–3 atm–1/2. The equilibrium
2 2
constant of the reaction 2 SO 3 (g) 2 SO 2 (g) + O 2 (g) would be :
(A) 250 atm (B) 4 × 10 3 atm (C) 0.25 × 10 4 atm (D) 6.25 × 10 4 atm
25. When alcohol (C 2H5OH) and acetic acid are mixed together in equimolar ratio at 27°C, 33% is converted
into ester. Then the K C for the equilibrium :
C 2 H 5 OH () + CH 3 COOH () CH 3COOC 2H 2 () + H 2 O ()
(A) 4 (B) 1/4 (C) 9 (D) 1/9
26. 2 moles each of SO3, CO, SO2 and CO2 is taken in a one lit. vessel. If KC for SO3 + CO SO2 + CO2
is 1/9 then :
(A) total no. of moles at equilibrium are less than 8
(B) n (SO 3 ) + n(CO 2 ) = 4
(C) [n(SO 2 )/n (CO)] < 1
(D) both (B) and (C)
27. An equilibrium mixture in a vessel of capacity 100 litre contain 1 mol N 2, 2 mol O 2 and 3 mol NO. No.
of moles of O 2 to be added so that at new equilibrium the conc. of NO is found to be 0.04 mol/lit :
(A) (101/18) (B) (101/9) (C) (202/9) (D) None of these
28. Ammonia gas at 15 atm is introduced in a rigid vessel at 300 K. At equilibrium the total pressure of the
46
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6. One mole of N 2O 4 (g) at 300 K is left in a closed container under one atm. It is heated to 600 K when
20% by mass of N 2O 4 (g) decomposes to NO 2 (g). The resultant pressure is :
1 2 Kp 1 2K p 2K p 2 Kp
(A) (B) (C) (D)
2 2 1 2K P 1 2 Kp
8. The vapour density of N 2O 4 at a certain temperature is 30. What is the % dissociation of N 2 O 4 at this
temperature :
(A) 53.3% (B) 106.6% (C) 26.7% (D) None
9. For the reaction PCl5 (g) PCl3 (g) + Cl2 (g), the forward reaction at constant temperature is favoured
by :
(A) introducing an inert gas at constant volume
(B) introducing chlorine gas at constant volume
(C) introducing an inert gas at constant pressure
(D) introducing PCl 5 at constant volume
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1 1
20. N2 + O 2 2NO, K 1 ; N 2 + O 2 NO, K 2
2 2
1 1
2NO N 2 + O 2 , K 3 ; NO 2 N 2 + O2, K 4
2
Correct relation between K 1, K 2, K 3 and K 4 is :
(A) K 1 × K 3 = 1 (B) K1 K 4 = 1 (C) K3 K2 = 1 (D) None
D d
21. The equation, a = is correctly matched for :
(n 1)d
(A) A nB/2 + nC/3 (B) A nB/3 + (2n/3)C
(C) A (n/2)B + (n/4)C (D) A (n/2)B + C
22. Variation of equilibrium constant K for the reaction ; 2A (s) + B (g) C(g) + 2D(g) is plotted againstt
absolute temperature T in figure as - nK Vs (1/T) :
nK
1/T
(nK vs 1/T diagram)
(A) the forward reaction is exothermic (B) the forward reaction is endothermic
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% NH 3 at equilibriu m
40 400°C 500°C
40
(A) 20 (B) 20
500°C 400°C
0 10 20 0 10 20
Pressure/103 kPa Pressure/103 kPa
% NH 3 at equilibriu m
% NH 3 at equilibriu m
40 40
400°C 400°C
(C) 20 (D) 20
500°C 500°C
0 10 20 0 10 20
Pressure/103 kPa Pressure/103 kPa
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TRUE / FALSE
1. Van't Hoff's equation gives the quantitative relation between change in value of K with change in tempera-
ture.
2. The larger value of K indicates that the product is more stable relative to reactants.
3. The value of equilibrium constant changes with change in the initial concentration of the reactants.
4. Extent of a reaction can always be increased by increasing the temperature.
n
5. K P is related to K C as K P = K C (RT) .
6. Introduction of inert gas in a gaseous reaction (ng 0) at equilibrium keeping pressure constant has no
effect on equilibrium state.
7. For the reaction, N 2O 4 (g) 2NO 2 (g), K P = K C (RT).
8. For a reaction the value of Q greater than K indicates that the net reaction is proceeding in backward
direction.
9. Solubilities of all solids in water increase with increase in temperature.
10. Dissolution of all gases in water is accompained by evolution of heat.
[NH 3 ]2
11. For the reaction, N 2 + 3H 2 2NH 3, the equilibrium expression may be written as K = .
[N 2 ][H 2 ]3
12. For the reaction, CaCO 3 (s) CaO (s) + CO 2 (g), K P = p CO .
2
13. A catalyst increases the value of the equilibrium constant for a reaction.
14. If concentration quotient of reaction is less than K, the net reaction is proceeding in the backward direction.
15. In case of endothermic reaction, the equilibrium shifts in backward direction on increasing the temperature.
16. The value of K increases with increase in pressure.
17. For the reaction, H 2 + I 2 2HI, the equilibrium constant, K is dimensionalless.
18. The reaction 2SO 2 (g) + O 2 (g) 2SO 3 (g), H = –X kJ, is favoured by high pressure and high
temperature.
19. A very high value of K indicates that at equilibrium most of the reactants are converted into products.
20. The value of K for the reaction, N 2 + 3H 2 2NH 3, can be increased by applying high pressure or
1 1
3. K for the reaction X2 + Y2 2XY is 100 K for this reaction XY X + Y would be ..................... .
2 2 2 2
+ – + –
4. Compared to K for the dissociation, 2H 2S 2H + 2HS , then K' for the H + HS H2S
would have ...................... .
5. The equilibrium constant for a reaction decreases with increase in temperature, the reaction must
be ...................... .
6. For the reaction, PCl 5 (g) PCl 3 (g) + Cl 2 (g), K P and K C are related as ...................... .
7. For the reaction, N 2O 4 (g) 2NO 2 (g), at equilibrium, increase in pressure shifts the equilibrium in
...................... direction.
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11. Dimensions of equilibrium constant, K c for the reaction 2NH 3 N 2 + 3H 2 , are ..................... .
1. Column-I Column-II
(Reactions) (Favourable conditions)
+ 905.6 kJ
(D) Formation of NO 2 (g) (s) Increase in temperature
NO(g) + O 3 (g) NO 2(g) + O 2(g)
+ 200 kJ
2. Column-I Column-II
(Reaction) (If is negligiab le w.r.t. 1)
1/3
(C) 3X(g) Y(g) + Z(g) (r) = (2K c )
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2. Statement-I : The equilibrium of A(g) B(g) + C(g) is not affected by changing the volume.
Because
Statement-II : K c for the reaction does not depend on volume of the container.
3. Statement-I : For the reaction A(g) B(g) + C(g), K p = 1 atm. If we start with equal moles of
all gases at 9 atm of initial pressure, then at equilibrium partial pressure of A increases.
Because
Statement-II : Reaction quotient Q p > K p hence equilibrium shifts in backward direction.
4. Statement-I : For a reaction at equilibrium, the Gibb's free energy of reaction is minimum at constant
temp. and pressure.
Because
Statement-II : The Gibb's free energy of both reactants and products increases and become equal at
equilibrium.
5. Statement-I : Equilibrium constant for the reverse reaction is the inverse of the equilibrium constant
for the reaction in the forward direction.
Because
Statement-II : Equilibrium constant depends upon the way in which the reaction is written.
6. Statement-I : For the reaction H 2(g) + I 2 (g) 2HI(g) if the volume of vessel is reduced to half
of its original volume, equilibrium concentration of all gases will be doubled.
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1 1
CaSO 4 . 2H 2 O(s) CaSO 4 . H O(s) + 1 H 2 O(g)
2 2 2
The following thermodynamic data apply at 25°C, standard pressure : 1.00 bar :
1
CaSO 4 . H O(s) –1575.0 130.5
2 2
H 2 O(g) –241.8 188.6
1
1. H° for the transformation of 1.00 kg of CaSO 4.2H 2O(s) to CaSO 4. H O(s) is :
2 2
(A) +446 kJ (B) +484 kJ (C) –446 kJ (D) –484 kJ
2. Equilibrium pressure (in bar) of water vapour in a closed vessel containing CaSO 4 . 2H 2 O(s),
2
(A) 7.35 × 10 –4 bar (B) 2.15 × 10 –4 bar (C) 8.10 × 10 –3 bar (D) 7.00 × 10 –4 bar
3. Temperature at which the equilibrium water vapour pressure is 1.00 bar.
(A) 107°C (B) 380°C (C) 215°C (D) 240°C
Comp rehensi on # 2
Que st ions are based on t he ma nufacture of Na 2 CO 3 by Solvay proce ss :
In the manufacture of Na 2CO 3(s) by Solvay process, NaHCO 3 (s) is decomposed by heating :
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of :
(A) CO 2(g) and H 2 O(g) will be greater than their initial pressure
(B) CO 2(g) and H 2O(g) will be less than their initial pressure
(C) CO 2(g) will be larger and that of H 2O(g) will be less than their initial pressure
(D) H 2O(g) will be larger and that of CO 2(g) will be less than their initial pressure
Tr u e / Fals e
1. T 2. T 3. F 4. F
5. T 6. F 7. T 8. T
9. F 10. T 11. T 12. T
13. F 14. F 15. F 16. F
17. T 18. F 19. T 20. F
F i ll i n t h e B lank s
1 1
K2 H T2 T1
9. log 10. zero 11. mol 2 L –2
K 1 2.303R T2 T1
12. temperature 13. Guldberg and Waage 14. decreases 15. backward
16. high 17. KP = KC (RT)n 18. decreases 19. same amount of
20. large value of
Matc h th e C o lu m n
1. A - (s), B - (p,q,s), C - (p,q,r), D - (r) 2. A - (p), B - (s), C - (q), D - (r)
A s s er ti o n - R eas o n Q u es ti o ns
1. A 2. D 3. A 4. C
5. A 6. B 7. A 8. A
C o mp rehe ns i o n B as ed Q u e st i o ns
C o mp re he n s i o n # 1 : 1. B 2. C 3. A
C o mp re he n s i o n # 2 : 1. A 2. B
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4 2
(b) 2NH 3 (g) N 2 (g) + 3H 2 (g) K p = 6.8 × 10 atm
–56
5. The value of K c for the reaction 3 O 2 (g) 2O 3 (g) is 1.7 × 10 at 25°C. Do you expect pure air
at 25°C to contain much O 3 (ozone) when O 2 and O 3 are in equilibrium ? If the equilibrium concentration
–3
of O 2 in air at 25°C is 8 × 10 M, what is the equilibrium concentration of O 3 .
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Homogeneous equi libr ia degree of dissociat ion, vapour densit y a nd equi libr ium consta nt
11. The degree of dissociation of N2O4 into NO2 at 1.5 atmosphere and 40°C is 0.25. Calculate its Kp at 40°C.
Also report degree of dissociation at 10 atmospheric pressure at same temperature.
12. At 46°C, K p for the reaction N 2O 4 (g) 2NO 2 (g) is 0.667 atm. Compute the percent dissociation
of N 2 O 4 at 46°C at a total pressure of 380 Torr.
13. When 36.8 g N 2O 4 (g) is introduced into a 1.0 - litre flask at 27°C. The following equilibrium reaction
occurs :
N 2 O 4 (g) 2NO 2 (g) ; K p = 0.1642 atm.
(a) Calculate K c of the equilibrium reaction.
(b) What are the number of moles of N 2 O 4 and NO 2 at equilibrium?
(c) What is the total gas pressure in the flask at equilibrium?
(d) What is the percent dissociation of N 2O 4 ?
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23. Suggest four ways in which the concentration of hydrazine, N 2H 4, could be increased in an equilibrium
described by the equation
N 2 (g) + 2H 2 (g) N 2 H 4 (g) H = 95 kJ
24. How will an increase in temperature and increase in pressure affect each of the following equilibria?
(a) 2NH 3 (g) N 2 (g) + 3H 2 (g) H = 92 kJ
(b) N 2 (g) + O 2 (g) 2NO (g) H = 181 kJ
(c) 2O 3 (g) 3 O 2 (g) H = –285 kJ
(d) CaO (s) + CO 2 (g) CaCO 3 (s) H = –176 kJ
25. (a) Water gas, a mixture of H2 and CO, is an important industrial fuel produced by the reaction of steam
with red-hot coke,essentially pure carbon. Write the expression for the equilibrium constant for the
reversible reaction.
NODE6 (E)\Data\2014\Kota\JEE-Advanced\SMP\Che\UNIT-07\CHEMICAL EQUILIBRIUM\Eng.\Exercise
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1 3 5 7
Time/Hour
Temp erature dep endence of equi libr ium consta nt
31. Listed in the table are forward and reverse rate constants for the reaction 2NO (g) N2 (g) + O2 (g)
–1 – 1 –1 – 1
Temp erature (K) k f (M s ) k r (M s )
–6
1400 0.29 1.1 × 10
–5
1500 1.3 1.4 × 10
Is the reaction endothermic or exothermic?
32. Rate of disappearance of the reactant A at two different temperature is given by A B
d[A ] –2 –1 –3 –1
= (2 × 10 S ) [A] –4 × 10 S [B] ; 300 K
dt
d[A ] –2 –1 –4 –1
= (4 × 10 S ) [A] –16 × 10 S [B] ; 400 K
33. The KP for reaction A + B C + D is 1.34 at 60°C and 6.64 at 100°C. Determine the free energy
change of this reaction at each temperature and H° for the reaction over this range of temperature?
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PV (n 1)K c A n
that the gas obeys the approx equation = 1 where K = n & V is the volume of the
RT V n 1 c
A
container. Assume that initially one mole of A was taken in the container.
47. When 1 mole of A (g) is introduced in a closed rigid 1 litre vessel maintained at constant temperature the
following equilibria are established.
K C2 [C]eq 1
The pressure at equilibrium is twice the initial pressure. Calculate the value of if
K C1 [B]eq 5
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1. (a) 25, shifts left, (b) 0.22, shifts right, (c) , shifts left, (d) 1, shifts right, (e) 0, shifts right
2. (a) K = [Ag+] [Cl–] is less than 1. AgCl is insoluble thus the concentration of ions are much less than 1 M
(b) K = 1/[Pb 2+] [Cl–]2 is greater than one because PbCl2 is insoluble and formation of the solid will reduce the
concentration of ions to a low level.
6. The reaction is not in equilibrium because Qc > Kc . The reaction will proceed from right to left to reach equilibrium.
9. [PCl3] = [Cl2] = 0.071 M, [PCl5] = 0.089 M 10. PCIF = PF = 0.389 atm, PClF = 1.08 atm
2 3
13. (a) 6.667 × 10–3mol L–1 ; (b) n (N2O4) = 0.374 mol ; n (NO2) = 0.052 mol ; (c) 10.49 atm (d) 6.44%
23. add N2, add H2, increase the pressure, heat the reaction
24. (a) shift right, shift left, (b) shift right, no effect, (c) shift left, shift left, (d) shift left, shift right
(b) in each of the following cases the mass of carbon will change, but its concentration (activity) will not
change.
1. [H2O] no change, [CO] no change, [H2] no change ; 2. [H2O] decrease, [CO] decrease, [H2] decrease ;
3. [H2O] increase, [CO] increase, [H2] decrease ; 4. [H2O] increase, [CO] decrease, [H2] decrease ;
26.b 27. Add NaCl or some other salt that produces Cl– in the solution. Cool the solution
NODE6 (E)\Data\2014\Kota\JEE-Advanced\SMP\Che\UNIT-07\CHEMICAL EQUILIBRIUM\Eng.\Exercise
kf [C]
28. kf [A][B] = kr [C] ; kc 29. 6 × 10 –22 30. (i) 2 ; (ii) 1.2 mol/L ; (iii) 0.1 moles/hr
k r [A ][B]
31. The reaction is exothermic 32. 16.06 kJ
33. –810 J/mol ; –5872 J/mol and 41.3 kJ/mol 34. 1.3 × 10 8
37. (a) Kc =
[CO 2 ]3
, Kp =
PCO2 , (b) Kc =
1
, Kp =
1
; (c) Kc = [SO3], Kp = PSO (d) Kc = [Ba2+] [SO42–]
[CO] 3
PCO 3 [O 2 ]3
(PO 2 ) 3 3
40. (a) Kc = 0.573 and Kp = 23.5 ; (b) to the right, [PCl5] = 0.365 M ; [PCl3] = 0.285 M ; [Cl2] = 0.735 M
43. H° = 9.04 kJ/mol ; S° = – 8.64 J / mol–1 K–1 44. 2.71 g/L
45. PNa = 0.843 M Pa, PNa = 0.170 M Pa, kP = 0.293 46. To be proved 47. 4
2
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8. For the reaction N 2 O 4 2NO 2 , equilibrium mixture contains NO 2 at P = 1.1 atm & N 2 O 4 at
P = 0.28 atm at 350 K. The volume of the container is doubled. Calculate the equilibrium pressures of the
two gases when the system reaches new equilibrium.
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because of the equilibrium : I2 (aq) + I – (aq) I3– (aq). A 0.10 M KI solution (0.10 MI–) actually dissolves
12.5 g of iodine/L, most of which is converted to I3–. Assuming that the concentration of I2 in all saturated
solutions is the same, calculate the equilibrium constant for the above reaction. What is the effect of adding
water to a clear saturated of I2 in the KI solution ?
18. A mixture of N2 & H2 are in equilibrium at 600 K at a total pressure of 80 atm. If the initial ratio of N2 and
H2 are 3 : 1 and at equilibrium NH3 is 10% by volume, calculate KP of reaction at given temperature.
K1
19. G° (298 K) for the reaction 1/2N2 + 3H2 NH3 is –16.5 kJ mol–1. Find the equilibrium constant
(K1) at 25°C. What will be the equilibrium constants K2 and K3 for the following reactions :
K2
N2 + 3H2 2NH3
K3
NH3 1/2 N2 + 3/2 H2
20. When NO & NO2 are mixed, the following equilibria are readily obtained ;
2NO2 N 2O 4 Kp = 6.8 atm–1
NO + NO2 N2O 3 Kp = ?
In an experiment when NO & NO2 are mixed in the ratio of 1 : 2, the total final pressure was 5.05 atm &
the partial pressure of N2O4 was 1.7 atm. Calculate :
(a) the equilibrium partial pressure of NO. (b) Kp for NO + NO2 N2O3
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of N2 (inert) is passed over a dehydrogenation catalyst at 900 K, what is the equilibrium percentage composi-
tion of the effluent gas mixture? The total pressure is kept at 0.5 bar. Given : rS° = 135.143 J K–1 mol–1 at
300 K. Calculate rG° at 300 K. (Assume rCp = 0).
1 3
2. K P1 2
, K P2
20P0 20P0
3. (a) 2.31 × 10–4 (b) (i) decrease (ii) no change (iii) increase (iv) increase (v) no change (vi) increase
23. (a) G° = –28.62 kJ/mole (b) PCO 2 = 202.44 kPa, PH 2 O = 3.16 kPa, PCO = 0.2 kPa, KP = 1.039 × 105
24. 103.47 kJ/mol
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1 KP
1. Reaction CO(g) + O CO2(g). The value of K is - [AIEEE-2002]
2 2(g) c
1 1
(A) (B) RT (C) (D) RT
RT RT
2. One of the following equilibrium is not affected by change in volume of the flask - [AIEEE-2002]
(A) PCl5(g) PCl3(g) + Cl2(g) (B) N2(g) + 3H2(g) 2NH3(g)
(C) N2(g) + O2 2NO(g) (D) SO2Cl2(g) SO2(g) + Cl2(g)
5. What is the equilibrium expression for the reaction P4(s) + 5O2(g) P4O10(s) ? [AIEEE-2004]
(A) KC = [P4O10] / [P4] [O2]5 (B) KC = [P4O10] / 5 [P4] [O2]
(C) KC = [O2]5 (D) KC = 1 / [O2]5
KP
6. For the reaction CO(g) + Cl2(g) COCl2(g) the K is equal to - [AIEEE-2004]
C
1
(A) (B) RT (C) RT (D) 1.0
RT
NODE6 (E)\Data\2014\Kota\JEE-Advanced\SMP\Che\UNIT-07\CHEMICAL EQUILIBRIUM\Eng.\Exercise
7. The equilibrium constant for the reaction N2(g) + O2(g) 2NO(g) at temperature T is 4 × 10– 4. The value of
1 1
KC for the reaction NO(g) N + O [AIEEE-2004]
2 2(g) 2 2(g)
(A) 2.5 × 102 (B) 50 (C) 4 × 10– 4 (D) 0.02
8. For the reaction 2NO2(g) 2NO(g) + O2(g), (Kc = 1.8 × 10– 6 at 184° C) (R = 0.831 kJ(mol.K)) When Kp and
kc are compared at 184°C it is found that [AIEEE-2005]
(A) Kp is less than Kc
(B) Kp is greater than Kc
(C) Whether Kp is greater than, less than or equal to Kc depends upon the total gas pressure
(D) Kp = Kc
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n Keq
(B) exothermic
(C) highly spontaneous at ordinary temperature 2.0
1.5 × 10–3 1/T (K–1) 2.0 × 10–3
(D) one with negligible enthalpy change
2x x x x
(A) P (B) P (C) P (D) P
1 x x 1 1 x x 1
1
12. The equilibrium constant for the reaction SO3(g) SO2(g) + O (g) is KC= 4.9×10– 2. The value of KC for
2 2
the reaction [AIEEE-2006]
2SO2(g) + O2(g) 2SO3(g) will be
(A) 2.40 × 10– 3 (B) 9.8 × 10– 2 (C) 4.9 × 10– 2 (D) 416
13. The equlibrium constants K p1 and K p2 for the reaction X 2Y and Z P + Q, respectively are in
the ratio of 1 : 9. If the degree of dissociation of X and Z be equal then the ratio of total pressure at these
equilibria is [AIEEE-2008]
(A) 1 : 36 (B) 1 : 1 (C) 1 : 3 (D) 1 : 9
14. A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the
addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is :-
[AIEEE-2011]
(A) 0.3 atm (B) 0.18 atm (C) 1.8 atm (D) 3 atm
15. The equilibrium constant (K C ) for the reaction N 2 (g) + O 2 (g) 2NO(g) at temperature T is
Q u e. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans C C A A D A B B C B D D A C A
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1. For the reaction CO (g) + H2O CO2 (g) + H 2 (g) at a given temperature the equilibrium amount of
2. For the reaction, N2O5 (g) = 2 NO 2 (g) + 0.5 O2 (g), calculate the mole fraction of N2O5 (g) decomposed at
a constant volume & temperature, if the initial pressure is 600 mm Hg & the pressure at anytime is 960
mm Hg. Assume ideal gas behaviour. [JEE 1998]
3. The degree of dissociation is 0.4 at 400 K & 1.0 atm for the gaseous reaction PCl5 PCl3 + Cl2 (g).
Assuming ideal behaviour of all gases. Calculate the density of equilibrium mixture at 400 K & 1.0 atm pressure.
[JEE 1999]
4. When 3.06 g of solid NH4HS is introduced into a two litre evacuated flask at 27°C, 30% of the solid decomposes
into gaseous ammonia and hydrogen sulphide. [JEE 2000]
(ii) What would happen to the equilibrium when more solid NH 4HS is introduced into the flask?
5. When 1-pentyne (A) is treated with 4N alcoholic KOH at 175°C, it is converted slowly into an equilibrium
mixture of 1.3% 1-pentyne (A), 95.2% 2-pentyne (B) & 3.5 % of 1,2-pentadiene (C). The equilibrium was
maintained at 175°C. Calculate G° for the following equilibria.
B = A G 1 ° = ?
NODE6 (E)\Data\2014\Kota\JEE-Advanced\SMP\Che\UNIT-07\CHEMICAL EQUILIBRIUM\Eng.\Exercise
B = C G 2 ° = ?
From the calculated value of G1° & G 2° indicate the order of stability of A, B & C. Write a reasonable
reaction mechanism sharing all intermediate leading to A, B & C. [JEE 2001]
This reaction is carried out at 298 K and 20 bar. 5 mol each of N 2O 4 and NO 2 are taken initially :
(ii) Find the direction in which the reaction proceeds to achieve equilibrium. [JEE 2004]
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(A) The equilibrium will shift to forward direction because according to II law of thermodynamics the entropy
must increases in the direction of spontaneous reaction.
(B) The condition for equilibrium is G N + 3G H 2 G NH where G is Gibbs free energy per mole of
2 2 3
the gaseous species measured at that partial pressure. The condition of equilibrium is unaffected by the
use of catalyst, which increases the rate of both the forward and backward reactions to the same extent.
(C) The catalyst will increase the rate of forward reaction by and that of backward reaction by .
(D) Catalyst will not alter the rate of either of the reaction. [JEE 2006]
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