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h i g h l i g h t s g r a p h i c a l a b s t r a c t
a r t i c l e i n f o a b s t r a c t
Article history: Highly efficient adsorbents for drinking water purification are demanded since the contaminants are
Received 7 July 2018 generally in a low concentration which makes it difficult for conventional adsorbents. Herein, we present
Received in revised form a novel biomimetic SiO2@chitosan composite as adsorbent with a high adsorption capability towards
19 September 2018
heavy metal ions including As(V) and Hg(II). The hollow leaf-like SiO2 scaffold within the adsorbent has a
Accepted 29 September 2018
Available online 2 October 2018
stable chemical property; while on the surface SiO2, the chitosan nanoparticle provide a large amount of
active sites such as amino and hydroxyl groups for adsorbing heavy metal ions. The special SiO2 structure
Handling Editor: T.S. Galloway also prevents the agglomeration and loss of chitosan, which enables the efficient contact between the
functional groups of chitosan and heavy metal ions. The SiO2@chitosan composite exhibits maximum
Keywords: adsorption capacities of 204.1 and 198.6 mg g1 towards Hg(II) and As(V), respectively. In addition, the
Adsorbents removal efficiency reaches over 60% within 2 min. The adsorption performance enables the presented
Composite biomimetic adsorbent suitable for adsorbing low-concentration heavy metal ions, especially possessing a
Adsorption promising potential for drinking water purification.
Heavy metal ion
© 2018 Elsevier Ltd. All rights reserved.
Drinking water
1. Introduction
https://doi.org/10.1016/j.chemosphere.2018.09.172
0045-6535/© 2018 Elsevier Ltd. All rights reserved.
J. Liu et al. / Chemosphere 214 (2019) 738e742 739
ðC0 Ce Þ V
qe ¼ (5-1)
m
Fig. 2. (a) Low- and (b) high-magnification FESEM images of the leaf-like CdS. Fig. 5. XPS spectrum of the leaf-like CdS and the hollow SiO2.
J. Liu et al. / Chemosphere 214 (2019) 738e742 741
time was 30 min, the removal efficiency becomes stable. The rapid
increase of the adsorption efficiency at the initial stage is ascribed
to the fact that the surface of SiO2@CS composite contains a large
amount of functional groups (i.e., amine groups and hydroxyl
groups) which interact with heavy metal ions. When the adsorp-
tion time is extended, the heavy metal ions adsorbed on the
adsorbent surface would hinder the contact between the heavy
metal ions and SiO2@CS composite. In this condition, the adsorp-
tion amount of As(V) and Hg(II) gradually reaches an equilibrium.
In order to further explore the adsorption kinetics, a pseudo-
second-order model was used to fit the kinetics. The second-
order kinetics equation is expressed as follows:
t 1 t
¼ þ
qt k2 q2e qe
Ce 1 Ce
¼ þ
qe qm KL qm
Fig. 9. (a) Adsorption isotherms of SiO2@CS composites towards As(V) and Hg(II); (b)
Fig. 8. (a) Adsorption kinetic curves of SiO2@CS towards As(V) and Hg(II), and (b) the Fitted Freundlich adsorption model towards As(V); (c) Fitted Langmuir adsorption
corresponding pseudo-second-order kinetics models. model towards Hg(II).
742 J. Liu et al. / Chemosphere 214 (2019) 738e742
Table 1
Comparison of maximum adsorption capacity of some adsorbents.
Heavy metal ions Adsorbents Maximum adsorption capacity (mg g1) Ref.
ions in the remained solution with the units of mg L1, qe repre- modifications, some high-performance adsorbents will be devel-
sents the equilibrium adsorption capacity with the unit of mg g1, oped for removing both inorganic and organic pollutants in water.
qm represents the maximum adsorption capacity with the unit of
mg g1, and KL represents the Langmuir adsorption constant related Acknowledgements
to the adsorption energy and the unit is L mg1. A straight line can
be plotted from Ce by Ce/qe. The values of qm and KL can be calcu- This work was supported by the National Natural Science
lated by the slope and intercept of the straight line. Foundation of China (51672176, 21471005, 61203212, and
The Freundlich adsorption model is used to describe the het- 661573334), the Major Project of the Department of Education of
erogeneous adsorption process. The equation is expressed as Anhui Province (KJ2018ZD034), and the Intergovernmental Inter-
follows: national Scientific and Technological Cooperation of Shanghai
(17520710200).
1
In qe ¼ In Ce þ In KF
n
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