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Article history: With the aim of specifying the type of curing compound for water-scarce areas, four types of curing com-
Received 27 May 2015 pound (acrylic-based, paraffin-based, silicate-based and composite-based) were chosen to investigate the
Received in revised form 24 September effect of curing compound on the mechanical property, durability and microstructure of cement con-
2015
cretes. The effect was assessed by measuring compressive and flexural strength, drying shrinkage, imper-
Accepted 18 October 2015
meability and crack resistance. The results indicated that curing compounds were effective in increasing
the compressive, flexural strength and the impermeability of concretes, and decreasing the drying shrink-
age and cracks. In general, the composite-based and the acrylic-based curing compound performed better
Keywords:
Curing compound
than the paraffin-based and the silicate-based curing compound. At the same time, microstructure test
Cement concrete results showed that curing compound promoted the hydration of the cement to form a compact and
Mechanical properties homogenous microstructure, and AFt crystalline particles were rod-like with a larger size.
Durability Ó 2015 Elsevier Ltd. All rights reserved.
Microstructure
http://dx.doi.org/10.1016/j.conbuildmat.2015.10.124
0950-0618/Ó 2015 Elsevier Ltd. All rights reserved.
B. Xue et al. / Construction and Building Materials 101 (2015) 410–416 411
Al-Gahtani [9] assessed the effect of different curing methods Fine aggregate (river sand)
on plain and blended cement concretes. The results showed that Apparent density (g/cm3) 2.65
the concrete specimens cured by wet burlap had higher strength Fineness modulus 2.6
Sediment percentage (%) 1.7
development than specimens cured by water-based and acrylic-
based curing compounds. Both kinds of curing compound effec- Coarse aggregate (crushed limestone)
Type of gradation Continuous grading
tively decreased the drying and plastic shrinkage of plain and Crushed stone value (%) 4.2
blended cement concrete. What’s more, acrylic-based curing com- Grain size (mm) 5–20
pound performed better than the water-based curing compound. Flat and elongated particles (%) 5.3
Choi et al. [10] explored the ways to improve the effectiveness
of curing operations. They noted that curing had substantial effects
on the performance of Portland cement concrete (PCC) pavement. (1) Cement content: 360 kg/m3.
The quality of curing materials, the time, and amount and unifor- (2) Fine/coarse aggregate ratio: 0.61.
(3) Water cement ratio: 0.5.
mity of application had great influences on the effectiveness of
membrane-forming curing compound. Alizadeh et al. [11] tested
The basic properties of curing compounds are shown in Table 3.
the values of diffusion coefficient and surface chloride content
under different curing conditions. Radlinski et al. [12] evaluated
2.2. Specimen preparation
the effect of curing compounds on scaling resistance of ternary
concrete produced with fly ash and silica fume. The concrete constituents were plunged into 60 L mixer at once and mixed for
According to Yilmaza and Turken [13], each curing materials 3 min. The temperature of materials and environment should be remained at
presented various results for concrete specimens produced with 20 ± 5 °C, and the relative humidity should be controlled at 50 ± 10%. Plastic molds
were used and the hole of mold was sealed. The specimens of microstructure test
no admixture and different chemical admixtures. For concrete
were chosen from the surface coat of concretes.
specimens produced with some particular types of chemical
admixture, curing materials increased the compressive strength
2.3. Curing condition
of specimens. However, curing materials reduced the compressive
strength of specimens produced with another types of chemical The concrete specimens were cured by water or air, or one of curing com-
admixture. It is necessary to make preliminary tests in the labora- pounds. The concrete specimens cured by water or air were treated as control spec-
tory to select the most suitable curing material for the concretes imens. The specimens cured by water were conserved in a standard curing room
(20 ± 2 °C, RH P 95%) and kept surface moist at all times. The specimens cured by
produced with different chemical admixtures.
air were conserved in the same environmental conditions (20 ± 2 °C,
So far in the literature, ample researches have been conducted RH = 50 ± 10%) with the specimens cured by curing compounds, and only difference
to evaluate the effect of curing conditions on the properties of con- between these two curing methods is the use of curing compound.
cretes. However, little research results have been reported at this The curing compounds were sprayed evenly onto the top surface of concrete
point concerning the effect of curing compounds on the durability specimens until the surface water of concretes disappeared. The dosage of curing
compound was controlled at 200 g/cm2. The vertical surface and the bottom surface
of the concrete, especially drying shrinkage, impermeability, crack-
of specimens were sprayed by curing compounds after the removal of molds.
ing resistance. In addition, the effects of curing compound on
micro-properties of concretes remain unclear. This study was con-
2.4. Test techniques
ducted to evaluate the effect of four types of curing compound on
the strength, drying shrinkage, impermeability, crack resistance 3 d, 7 d and 28 d compressive and flexural strengths of concrete specimens
and microstructure of cement concretes with the aim of specifying cured by four curing compounds were tested. Besides, third point load was used
the type of curing compound for water-scarce areas. for flexural strength test. 1 d, 2 d, 3 d, 7 d, 14 d, 21 d, 28 d, 56 d and 90 d drying
shrinkage of concrete specimens were tested by Horizontal shrinkage tester (see
Fig. 1(a)). Data was recorded in real time by dial indicator.
Impermeability of concrete specimens after curing for 3 d, 7 d and 28 d was
2. Methodology tested. During the test, water pressure of permeability instrument was kept at
1.2 ± 0.05 MPa for 24 h. The test was end until the top surface of specimens had
2.1. Materials seepage or the test time had reached 24 h. Then the truncated cone-shaped speci-
mens were taken out from the instrument, and split up under the press machine
GB 175-2007 PO42.5 type cement was used to prepare the concrete mixture. (see Fig. 1(b)), and permeation height of each specimen was recorded.
Table 1 shows the chemical compositions of PO42.5 type cement. Fine and coarse Crack resistance of concrete specimen was tested according to standard CCES
aggregates complying with standard JTG E42-2005 were used. The properties of 01-2004. At first, the concrete specimen with a size of 600 mm 600 mm 63 mm
these aggregates are shown in Table 2. was poured into a cuboid mold, which has several bolts welded around it as to
The concrete mixtures were proportioned on a weight basis. The slump of con- induce the development of cracks (see Fig. 1(c)). After curing for 8 h by each curing
crete mixtures should be controlled within 30–50 mm. In order to control the test method, specimens were put in a dry and windy condition (20 ± 2 °C, RH = 35 ± 5%
variables, no else cementing material and chemical admixture was used. And the and wind velocity = 0.6 m/s), and then test began. Lastly, the numbers and areas of
following parameters were kept constant in the study. crack at the first 3 testing days were observe and recorded by crack observation
instrument timely.
Table 1
The chemical compositions of PO42.5 cement. Table 3
Constituent (wt.%) PO42.5 cement The basic properties of curing compounds (according to standard JC 901-2002).
(a) Horizontal shrinkage tester (b) Permeation height test (c) Crack mold
Fig. 1. The instrument or specimen of the test.
The microstructure of concrete specimen was test by XRD and SEM. For XRD better than paraffin-based and silicate-based curing compound in
test, specimens with 3–5 mm diameter size were removed from the surface layer
increasing compressive strength. Comparing this result with
of concrete cured for 3, 7 and 28 days, and then the hydration of specimens was ter-
minated by acetone, and then tested by X-ray diffractometer. For SEM test, concrete
previous test result of the effective water retention of each curing
particles with a smooth surface were selected. S-4800 type field emission scanning compound (see Table 3), we can draw a conclusion that a curing
electron microscopy was used to observe the microstructure of cement hydration compound with higher water retention ability may perform better
products. In this paper, only the SEM results of 28 days were chosen to highlight in promoting the compressive strength of the concrete. This is
the difference between curing methods.
because higher water retention would make the concrete maintain
higher humidity inside as to promote the hydration which would
3. Results and discussion result in a strong micro-structure.
55 6.5
Water
Acrylic-based
50 6.0
Compressive stength, MPa
Composite-based
Flexural stength, MPa
Silicate-based
45 Paraffin-based 5.5
Air
5.0
40 Water
Acrylic-based
4.5
Composite-based
35 Silicate-based
4.0
Paraffin-based
30 Air
3.5
25 3.0
0 5 10 15 20 25 30 0 5 10 15 20 25 30
Age, days Age, days
Fig. 2. Compressive strengths of concrete specimens cured by curing compounds. Fig. 3. Flexural strengths of concrete specimens cured by curing compounds.
B. Xue et al. / Construction and Building Materials 101 (2015) 410–416 413
Permeation height, mm
Fig. 4 shows the drying shrinkage of concrete specimens cured
by curing compounds. These values increased rapidly during the
early curing age and then tended to be stable. The concrete speci- 120
mens cured by all types of curing compound exhibited lower dry-
ing shrinkage than those cured by air. Maximum drying shrinkage 110
in the concrete specimens cured by air for 3 days was
227 10 6 mm/mm, by contrast, the drying shrinkages in speci-
100
mens cured by composite-based, acrylic-based, paraffin-based
and silicate-based were 117, 143, 156 and 162 10 6 mm/mm.
What’s more, drying shrinkage in concrete specimens cured by 90
0 5 10 15 20 25 30
curing compounds reached the stable state earlier than those in
Age, days
concrete specimens cured by air. For the age of 90 days, specimens
cured by curing compounds show less drying shrinkages than Fig. 5. Permeation heights of concrete specimens cured by curing compounds.
those cured by air. About 40.4%, 35.5%, 33.8% and 31.6% reduction
in drying shrinkage of specimens cured by composite-based,
acrylic-based, paraffin-based and silicate-based curing compounds 80 Air Paraffin-based
600
size of cracks of concrete specimens was increasing trend. The
500 average size of cracks of concrete specimens cured by air was lar-
ger than that of cracks of concrete specimens cured by each curing
400 compound. A slight decrease of the average size of cracks was
observed in concrete specimens cured by paraffin-based curing
300 Air compound, which could be the results of generation of smaller
Acrylic-based
200 Composite-based
crack as to reduce the average size of cracks.
Silicate-based Fig. 8 shows the total area of cracks of concrete specimens cured
100 stable state Paraffin-based by curing compounds. The concrete specimens cured by air had a
larger total area of cracks than those cured by curing compound.
0
0 10 20 30 40 50 60 70 80 90 100 The decrease in total area of cracks reached a percentage of
Time, days 98.7%, 82.1%, 94.3% and 50.2% for the specimens cured by
composite-based, acrylic-based, paraffin-based and silicate-based
Fig. 4. Drying shrinkages of concrete specimens cured by curing compounds. curing compounds respectively.
414 B. Xue et al. / Construction and Building Materials 101 (2015) 410–416
1.2
Air Paraffin-based :CH •:Alite ∗:Belite
1.0 Silicate-based Composite-based :AFt :C4AF
The average size of cracks,
Acrylic-based
0.8
• ∗
∗
mm2/optical
Intensity, a.u.
∗ • •∗ •
0.4
0.2
0.0 Water
-0.2
1 2 3
Time, days
Air
Acrylic-based
50 :CH •:Alite ∗:Belite
:AFt :C4AF
40
mm2 /m2
30 • ∗
∗
Intensity, a.u.
20
∗ Curing compound
∗ • •∗ •
10
0
-10
1 2 3 Water
Time, days
Fig. 8. The total area of cracks of concrete specimens cured by curing compounds. Air
20 30 40 50 60 70 80
3.3. Microstructure 2θ, degree
3.3.1. XRD b 7d
Fig. 9 shows the XRD test results of hydration products of con-
crete specimens cured by different curing methods. As can be seen
from Fig. 9, different curing methods had significant effect on the :CH •:Alite ∗:Belite
content of Ca(OH)2. At 2h = 18.1°, 34.2° and 47.1°, the XRD diffrac- :AFt :C4AF
tion intensity of Ca(OH)2 varied greatly. According to the studies of
Mounanga et al. [17] and Wang et al. [18], Ca(OH)2 content is usu- • ∗
ally considered as a good indicator of the evolution of hydration ∗
Intensity, a.u.
∗ Curing compound
reactions. For pure cement hydration system, the hydration degree ∗ • •∗ •
of cement can be describe as the ratio between the Ca(OH)2 con-
tent at specific time and the final Ca(OH)2 content at the time of
complete hydration. In order to further understand the effect of Water
curing method on the hydration of the cement, we highlighted
the Ca(OH)2 separately. Moreover, we induced an new evaluation
parameter to evaluate the efficacy of a curing compound, namely
Curing Degree Index (CDI), which was the ratio of the highest Air
diffraction intensity of Ca(OH)2 of the specimen cured by specific
method to that of specimens cured by water. Although researchers
had proposed some similar evaluation parameters, such as Curing
20 30 40 50 60 70 80
Effectiveness (CE) and Evaluation Index (EI) [6], Curing Efficiency 2θ, degree
Index (CEI) [9] and Kcuring [19], all these parameters were based
c 28d
on the macro-properties of concrete, while the micro-properties
had not received much attention. The test result of CDI which is Fig. 9. XRD test results of concrete specimens cured by curing compound.
based on the relative strength of Ca(OH)2 diffraction peak is shown
B. Xue et al. / Construction and Building Materials 101 (2015) 410–416 415
140 Air
in Fig. 10. As can be seen from Fig. 10, the CDI with regard to the
131 content of Ca(OH)2 varied from 97.7% to 131% in the concrete spec-
Water 121.2
120 Curing compound imens cured by curing compound, while the CDI varied from 58.8%
100 97.7 100 100 to 85.1% in the concrete specimens cured by air, indicating that the
100
application of curing compound can promote the hydration of the
85.1
CDI, %
80 cement.
Besides, the diffraction peaks of Alite and Belite appeared near
60 58.8 59.0
2h = 29.5°, which mean there were still some unhydrated cement
clinkers in specimens. Comparing with Fig. 9(a), (b) and (c), we
40
found that the intensity of diffraction peak of Alite and Belite
20 decreased with the increase in the age. However, the specimen
cured by air still had the greatest intensity of diffraction peak of
0 Alite and Belite, that is to say the specimen cured by air had lower
3 7 28
degree of hydration than those cured by water or curing
Age, days
compound.
Fig. 10. CDI with regard to the content of Ca(OH)2 in concrete specimens.
a cured by air
b cured by water
3.3.2. SEM difficult. However, the effect of curing compound on the surface
Fig. 11 shows the SEM test results of concrete specimens cured property of the concrete remains to be further studied.
by curing compound. As indicated in Fig. 11, specimens cured by
curing compound or water formed more compact and homogenous Acknowledgements
microstructure than those cured by air. More C–S–H was produced
in the specimens curing by water or curing compound than those Funding for this study was provided by ‘‘The Fundamental
cured by air. Such C–S–H contacted with CH to fill the micropore Research Funds for the Central Universities” (Grant No.
of the hydration of the cement. C–S–H is the main hydration pro- 2014G2310020) and ‘‘National Natural Science Funds of China”
duct and binding phase in all Portland cement-based systems, (Grant No. 51408043, No. 51408047, No. 51408048 and No.
which determine the strength and durability of concrete [20]. 51378073).
Due to lack of C–S–H, the microstructure of specimens cured by
air was porous and loose arrangement. These findings indicate that References
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