Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
concrete
Presented by:
• To follow
Introduction: Concrete aggregates
• Aggregate definition: ‘mineral constituents of concrete in granular or
particulate form, usually comprising fine and coarse fractions’
- a ‘natural conglomerate’
• Volumetrically, aggregates occupy 70-80% of concrete, and so MUST
have a profound influence on concrete properties.
− Paste is not an engineering material – concrete is!
• Approx. 0.75 ton of concrete aggregate consumed per capita per annum
globally
• How do we view aggregates?
− Outdated view: simply an inert filler, used mainly for bulk
− Reality: each constituent of concrete is important, with their
interactions giving the composite engineering material response
• Focus in this presentation on natural aggregates – increasingly in short
supply
Introduction
• What happens in the plastic state, and the first few hours or days of
the hardened state, negatively or positively affect concrete for the
rest of its life!
AGGREGATE PASTE
Overview of aggregates and their role in concrete
Plastic state
• Concrete properties affected by aggregates
− Workability & Consistence
Hence: water requirement
− Cohesiveness, flowability
− Settlement & bleeding
− Plastic shrinkage potential
C-S-H + FH3
Porosity
CH + C3AH6 +Aft + AFm
Anhydrous cement
ITZ PERCOLATION
• Chemical bonding
It is probable that no aggregate is truly ‘inert’, i.e. all
aggregates interact chemically with cement paste to
some degree
• Physical bonding
This is mainly a function of micro- and macro-texture,
with micro-texture often being more important
Cement paste – aggregate bond
Cement paste – aggregate bond
E.g. effect of Gauteng andesite aggregates on concrete strength
Andesite surface
Quartzite surface
x2000
x2000
Strength premiums of andesite concrete over quartzite concrete (Alexander & Ballim, 1987)
Age Percentage increase in strength
(d) for w/c ratio
0.83 0.56 0.42
Cube Compressive 28 28% 23% 17%
Strength
Indirect Tensile 28 19% 24% 18%
Strength
Modulus of Rupture 35 16% 27% 9%
Cement paste
– aggregate
bond
Effect of
ITZ - interfacial
transition zone
EFFECT OF ITZ
• Strongly influences bond between paste and aggregate
– weaker more porous ITZs represent surfaces of
weakness and low bond strength
Parallel model
Series model
Counto model
E paste Hashin & Hobbs model
Introduction
Elastic modulus – cube strength relationship for
dolomite concrete for ages from 3 - 28 days
Static Elastic Modulus (GPa)
Relationship between
static elastic modulus
and cube strength of
concrete for different
aggregate types
Cube Strength (MPa)
Increase in elastic modulus of dolomite concrete from
28 days to 6 months – effect of ITZ alteration with time?
Predictive relationship for elastic modulus as function
of concrete compressive strength, allowing for
aggregate type:
Ec = K0 + βfcu
Where
K0 = Aggregate stiffness factor
β = Aggregate interaction factor
Values for estimating elastic modulus of concrete for ages (a)
from 3 - 28 days, and (b) six months or older (SA aggregates)
(From Fulton’s Concrete Technology, 2001)
1200
Total Strain (10-6)
1000
800
600
400
30 35 40 45 50 55
Concrete E (GPa)
Aggregate Coefficient of thermal
expansion of concrete
(x10-6/ oC)
Basalt 9.3
Blastfurnace slag 10.6
Chert 13.2
Dolerite 9.5
Dolerite (SA) 7.5 – 8.0
Dolomite (SA) 8.5 – 9.0
Felsite (SA) 9.0
Granite (SA) 8.0 – 9.5
Granite and rhyolite 6.8 – 9.5 Effect of
Limestone 6.1 – 9.9 aggregate type on
Malmesbury hornfels (SA) 10.0 – 11.0 coefficient of
Marble 4.1 thermal
Quartz 10.4 expansion of
Quartzite 12.8 concrete
Quartzite (SA) 9.5 – 12.0
Sandstone 11.7
Thermal expansion of concrete having different
aggregate types and contents
AGGREGATES AND CONCRETE DURABILITY
Aggregates
• make a substantial contribution to concrete durability by
normally being durable, hard, and longwearing
• reduce the cementitious paste component, which is
susceptible to deterioration being more thermodynamically
unstable.
• are more resistant to external aggressive attack and are
usually less permeable than the matrix
• may, however, in certain cases exhibit properties that
render them susceptible to deterioration and thus
compromise concrete durability.
• in other cases, may be susceptible to attack from external
agents
Matrix of deterioration mechanisms relating to
aggregates in concrete
Physical Mechanisms Chemical Mechanisms
In presence of moisture:
swelling
(b)
Surface cracking of (a) haunch of portal
structure and (b) column of bridge structure
due to AAR (latter photo courtesy of Y Ballim)
(a)
Alkali Aggregate Reaction
(a) (b)
Three main types of AAR – depending on nature of aggregates
Alkali-Silicate Reaction
• Differentiates ASR from reactions involving aggregates such as
greywacke and argillite found in Nova Scotia, Canada
• Reaction surmised to involve expansion and exfoliation of certain
clay minerals (phyllosilicates)
Alkali-Carbonate-Rock Reaction (ACR)
• Does not produce a gel
• Coarse aggregate particles expand due to alkali hydroxides
reacting with small dolomite crystals in a clay matrix, resulting in
dedolomitization
• Limited to carbonate aggregate containing clay, such as certain
argillaceous dolomitic limestones or argillaceous calcitic dolostones
• ACR not widespread, encountered mainly in Canada
Mechanism of ASR
Source – P.K. Mehta and P.J.M. Monteiro, Concrete: Microstructure, Properties and Materials
Necessary conditions for ASR
Alkalis
• Primary source is cement or binder - metal alkalis of NaOH and
KOH, plus Ca(OH)2
– Recall: alkalis characterised by equivalent sodium oxide (as % by mass
of cement)
%Na20 eq = %Na20 + 0,658 x %K20
• Cements with Na20eq > 0.6 % - ‘high alkali’ cements
• But: total alkali content in concrete is more important than alkali
level of cement itself
• Total alkali content = [alkali content of cement] x [cement content]
(strictly proportion of alkalis released during hydration and available for
reaction (termed ‘active alkalis’) – typically 85%)
Effect of cement alkalinity on ASR. Malmesbury coarse aggregate
(greywacke) in combination with different cements. Cement content of
concrete = 350 kg/m3.
600
Deleterious
> 3.8 kg alkalis/m3
400
Potentially
deleterious
Innocuous
200
< 1.8 kg alkalis/m3
Potential alkali reactivity Siliceous ASTM C289 Not recommended for greywacke, hornfels,
of aggregates (chemical aggregates, quartzite, granite, etc. Test shows some
method). crushed and aggregates to be innocuous when they are
Determination of sieved (150- known to have a poor service record.
potential reactivity of 300 m)
siliceous aggregates
Accelerated mortar bar Mortar prism ASTM C1260 Based on work at SA NBRI; used in USA
(mortar prism) test. with BS DD 249 and Canada, recommended by RILEM.
Determination of susceptible CSA: A23.2-25A Rapid test; generally reliable and
potential for deleterious aggregates; RILEM TC 191- reproducible, but there are exceptions Aggregate Assessment
alkali-silica reaction of specified ARP (AAR- 2)
aggregate in mortar bars grading (4.75 SANS 6245 for AAR (Excluding
mm - 150 μm) Carbonate Rock
Concrete Prism Method Concrete ASTM C1293 Actual mixes can be tested in proportions
Determination of the aggregates for BS 812: Part 123 specified; evaluate effect of SCMs; long
Assessment)
potential ASR expansion actual CSA A23.2-14A test duration required for meaningful The shaded section
of cement-aggregate construction. RILEM TC 191-ARP results.
combinations (AAR-3) represents most
Modified Concrete Prism Concrete CSA A23.2-14A Alternative rapid test to CSA A 23.2- commonly used tests
Method aggregates for (ASTM C1293) 14A.
Determining the potential actual Good correlation with standard test for worldwide at present
ASR expansion of construction. sedimentary and carbonate rocks.
cement-aggregate
combinations
Ultra-accelerated Concrete RILEM TC 191-ARP Used to assess reactivity performance of
concrete prism test prisms with (AAR-4) particular concrete mixes
aggregates for
construction
Long-term structural Actual Inst. of Struc. Sometimes, structural monitoring is the
RILEM TC 106/TC 191 Integrated AAR Assessment Scheme
(Adapted from Sims and Nixon, 2003). Shaded boxes represent
those sections that have been published (2004)
AAR-0: Outline Guide
AAR-1: Petrographical
examination done?
Yes No
Petrography
Class I Class II (or Class III)
Silica IIS (IIIS) Silica & Carbonate IISC (IIISC) Carbonate IIC (IIIC)
AAR-3 Long-term
Concrete prism test Reference
Testing
Reduction In:
Strength Strength
0,1 - 0,2 % 0 – 25 % 20 – 25 %
0,3 - 1,0 % 20 – 65 % 20 – 30 %
>1,5 % >60 % -
Lower bound residual mechanical properties of
concrete affected by ASR as percentage of values
for unaffected concrete at 28 days
(From Oberholster, 2001, based on data in ISE, 1992)
Percentage of property as compared with unaffected
Property concrete,
for free expansion, percent
Uniaxial compressive 95 80 60 60 -
strength**
Splitting tensile strength 85 75 55 50 -
20 2.0
500
1000
(A)
1500
2000
(B)
2500
3000 (C)
3500
0.1 1 10 50 100 300 500
0.0.
Elapsed Time in Days
1
Thank You!