Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
1
Nanotechnology of Foam: Water Filtration • July 2015
2
Nanotechnology of Foam: Water Filtration • July 2015
3
Nanotechnology of Foam: Water Filtration • July 2015
4
Nanotechnology of Foam: Water Filtration • July 2015
fine sand, 150 g of coarse sand, 135 g of ceramic still be separated without a chemical process.16
beads, and 150 g of gravel. Filter Setups 1 and 2 filtered 100 mL each of
tea, while Filter Setup 3 filtered 200 mL of tea.
Another setup, Filter Setup 4, was constructed
at this point.
Both Filter Setups 3 and 5 were first sat-
urated with 200 mL of water. Then, 200 mL
of a Coca-ColaTM and PepsiTM mixture were
dripped into each setup. The effectiveness of the
filters was determined by observing the color of
the filtrates and the pH of the filtrates. These
observations were made to see if the filters re-
moved phosphoric acid or Caramel E 150D, the
main color of Coca-ColaTM and PepsiTM .17 The
pH of the soda mixture and the total time for
filtration were recorded, as well as the pH and
color of the filtrate after passing through each
setup.
Afterwards, alum, a coagulant, was added to
the other filtrates to see the difference in filtrate.
1 g, 1.5 g, 2 g, and 2.5 g of alum each was added
to four different quantities of 8 mL of filtrate
Fig 5: Filter Setup 5 (from bottom to top):
from Filter Setup 3 in the test involving the
ceramic beads, coarse sand, fine sand, charcoal
Coca-ColaTM -PepsiTM mixture.
In order to test the filtration properties of
I.4 Testing Mixed-Media Filters
the filters made, solutions containing different
In the first filter setup, the materials were contaminants commonly found in unfiltered wa-
arranged so that the filter component with the ter were mixed together, and 200 mL were added
smallest pore diameters was on the top, and to each filter. The contaminants used were the
the filter component with the largest pore di- same as the ones used in the testing of common
ameters was on the bottom. The other filter filtering materials. All water used was distilled
setup was arranged so that the filter component water. Food dye was added as a separate con-
with the largest pore diameters was on the top, taminant, as were the Coca-ColaTM /PepsiTM
and the filter component with the smallest pore mix and tea.
diameters was on the bottom. The reason for
testing two different orders was to ascertain the
most accurate and efficient organization of filter- II. Surfactant Hydrophilicity
ing components. The charcoal was considered
to have very fine pore diameters, as the round One of the superhydrophobic aerogels was
nuggets that compose charcoal have both mi- treated with a solution of polyethylene glycol
cropores of 1-3 nm and macropores of 3-10,000 and titanium dioxide. First, a brush was used to
nm.15 spread a fine layer of the solution on the top of
A burette then dripped tea into each filter the aerogel. In the end the foam was set upright
to test the filters’ abilities to separate the chem- and drops of the TiO2 -PEG solution were added
ical components of tea, particularly tannic acid, onto the surface to be absorbed over a 24 hour
from the water that the tea was made with. period. Titanium dioxide is hydrophilic, so it
Tannic acid (C76 H52 O46 ) is a relatively large was placed on top of the gel to see if it would
polymer that mixes well with water but can aid in water absorption.
5
Nanotechnology of Foam: Water Filtration • July 2015
6
Nanotechnology of Foam: Water Filtration • July 2015
VI. Discussion/Analysis
I. Filtering Properties
From the results, it appears that the con-
taminated water took longer to flow through
substances with small pore diameters and flowed
faster through substances with large pores.
Moreover, the contaminants were still present in
most of the filtrate. In the case of protein, the
tests were inconclusive. This suggests that the
filter components by themselves did not remove
different contaminants. In addition, the protein
indicator did not show presence of protein in
any sample, including in a test of 50% water
and 50% protein, so the indicator was suspected
Fig 7: Filtrate after alum added to be expired or defective.
7
Nanotechnology of Foam: Water Filtration • July 2015
II. Reorganization of Different Filters particles in tea and soda, and the groups were
large enough to be removed by coffee filters.
Removing carbon from a filtration system
hinders its filtration properties. When compar-
ing Filter Setup 3 to Filter Setup 4, the filtrate III. Cost Analysis of Filters
from Filter 4 was much murkier than the filtrate The cost of each filtering component affects
from Filter 3. Often in the form of charcoal, car- the overall price of the filter. Sand of vari-
bon is useful in filtering organic material, such ous sizes can cost about $4.15 for forty-eight
as protists and many microorganisms. In addi- pounds.26 250 coffee filter papers cost $7.49.25
tion, it has a high functional surface area (large Gravel costs $4.77 for sixty pounds.30 Carbon
area of filtering substance exposed to substance), powder costs $10 for 6 oz.29 Four hundred and
which is useful as contaminants are more likely fifty grams of ceramic beads cost $9.95.21 Com-
to become trapped. One of the negatives of pared to filters such as the Lifestraw
, R the
carbon is that the carbon is a likely breeding filters made during the experiment were much
ground for bacteria, as its moist and dark nature cheaper. While the Lifestraw
R costs $31.95,
is ideal for bacteria growth. Therefore, carbon Filter Setups 1 and 2 cost $1.34, Filter Setups
filters need to be disinfected after multiple uses, 3 and 5 cost $3.98, Filter Setup 4 cost $3.09 to
which is one negative concerning their overall make.23 Also, the alum adds $.04 to the filters’
usefulness.18 costs. One pound of alum costs is $9.47. More-
When comparing Filter Setup 1 and Filter over, the silica foams cost $.96 to make. 18 L
Setup 2, it appears that Filter 1 was able to colloidal silica cost $346.28 The silica aerogels
remove more particles than Filter 2 because cost about $1.50 to make since the Titanium
Filter 1 had less filtrate than Filter 2. This Dioxide costs $27 for one pound.24
suggests that more particles and contaminated
water were trapped within the filter itself. More- Filters 1 and 2 (Thin material layers)
over, when comparing Filter Setup 3 and Filter
Setup 5, Filter Setup 5 appeared to remove (45g ∗ $9.95/450g) + (50g ∗ $4.15/21772.4g)
more particles than Filter Setup 3 because there + (50g ∗ $4.15/21772.4g) + (5g ∗ $10/170.097g)
was less dye in the filtrate of Filter 5 and since + (1count ∗ $7.49/250count) = $1.334 (1)
Filter 5 seemed to have less filtrate; however,
the results may have been skewed due to the Filters 3 and 5 (Thick material layers)
presence of runoff water already present in the
filter. Therefore, the most efficient arrangement (15g∗$10/170.097g)+(150g∗$4.15/21772.4g)
of filter components is from fine to coarse.
+ (150g ∗ $4.15/21772.4g) + (135g ∗ $9.95/450g)
Because of faulty burette adjustment equip-
+ (1count ∗ $7.49/250count) = $3.98026 (2)
ment, it was difficult to maintain a steady flow
of droplets from the contaminant solution in
Filter 4 (No charcoal)
the burette to the top of the filter, so this may
have changed the results, as the rate of adding
contaminant varied per test. (150g∗$4.15/21772.4g)+(150g∗$4.15/21772.4g)
Using alum as a coagulant for fine particles + (135g ∗ $9.95/450g) + (135g ∗ $4.77/27215.5g)
left over in the filtered solutions proved to be + (1count ∗ $7.49/250count) = $3.098 (3)
very effective at filtering even more contami-
nants from the original simulated contaminant
IV. Surfactant Hydrophilicity
mixture. Alum works by attracting fine particles
and grouping them together, eventually getting Without added chemicals or pressure, the
the groups to a size that can be trapped by surfactant coating was not absorbed by the foam
filters.22 In this case, the alum coagulated fine and had no impact on the hydrophobic nature
8
Nanotechnology of Foam: Water Filtration • July 2015
of the foam. This coating is not a viable so- port water across the filter at a faster rate. This
lution without added chemicals that would en- may improve the filtration properties of sol-gels.
sure the absorption of the coating by the foam. The hydrophilic coating could also be made
With the addition of ethanol or another alcohol, slightly basic in order to increase the pH of
which foam is attracted to, the foam may have the water being filtered. This would render the
absorbed the solution, but without any other filter helpful in regions of the world that are
chemicals added, the foam’s hydrophobic na- infamous for pollution, as contamination tends
ture would simply prevent the titanium dioxide to make water slightly more acidic.20 Adding a
solution from being absorbed. hydrophilic and basic coating to aerogel filters
would neutralize the water acidity of polluted
VII. Conclusion water to a degree safe for consumption. This
modification would also be useful in hydroponics
I. The Sol-Gel Method and irrigation systems to channel clean water to
fresh produce, as plants are very susceptible to
Although the sol-gel method is useful in changes in water pH as well.20
quickly producing foams with nanoscale pores,
Future experiments could also attempt heat-
the foams used were ineffective as water filters
ing up the aerogels to a maximum temperature
due to their superhydrophobicity. The foams
of 450 Centigrade, which would increase the
did not absorb any water, even when the wa-
pore diameter of the aerogel. This could lead
ter pressure was increased to 1 L. In addition,
to potential water absorption despite the foam’s
since the aerogels were very brittle, passing wa-
superhydrophobicity.31
ter through them at high pressures could cause
them to crumble and recontaminate the filtrate. In addition, one could experiment to see the
Without significant modifications to the foams, best placement of foams within a conglomera-
they are unable to be used as water filters. tion of filter components. Sol-gel foams could
potentially become the final processing unit in a
collection of other cheap filters with large pore
II. Future Research diameter. The foams are very brittle; exposing
With limited time and resources, the sol-gel them to large contaminants could damage them.
products could not be chemically transformed Thus, if the foams were to be used in commer-
into more viable filters. However, many possible cial water filters, they would need to be used in
directions can be taken in the future concerning conjunction with other filtering components.
hydrophobic aerogels and water filtration. Finally, in an effort to create filters that
Coating the hydrophobic aerogel could be can aid many people in developing nations at
coated with a more hydrophilic substance. A a time, perhaps one could design a quick, large
hydrophilic solution of TiO2 , PEG, and other scale water filtration system containing silica
alcohols could be applied to both ends of the aerogels. This could be attained by engineering
aerogel.18 This would mimic the phospholipid cheap, commercial processes for aerogel produc-
bilayer in biological cells and could increase the tion. Moreover, this can be achieved by altering
efficiency and flow rate of the aerogels used. The the chemical makeup of the foams and sol-gel
hydrophilic coating would draw water into the production techniques. For example, although
filter, while the hydrophobic part would filter we added a solution of titanium dioxide and
the water to a large degree due to its small pore PEG to our solution, we could have added an
diameter. Finally, the water would be able to alcohol such as ethanol to allow the solution to
exit the aerogel via the hydrophilic coating on absorb into the foam. However, since adding an
the other side of the foam. Through this method, ethanol coating to the foam could contaminate
the pore diameters would be efficiently utilized, future filtrates, alternatives to alcohol would
and the hydrophilic additions could help trans- have to be researched.
9
Nanotechnology of Foam: Water Filtration • July 2015
[3] HydrateLife,. ‘Lifesaver Bottle’. N.p., 2012. [17] Water Treatment Implementation For Develop-
Web. 18 July 2015. ing Countries. Center for Affordable Water
and Sanitation Technology, 2015. Web. 18
[4] People.uwec.edu,. ‘Common Water Pollution July 2015.
Sources’. Web. 18 July 2015.
[18] Aegerter, Michel, and Martin Mennig. ‘Coating
[5] Filtration Facts. Environmental Protection And Material Properties’. Sol-Gel Technolo-
Agency, 2005. Web. 18 July 2015. gies For Glass Producers And Users. 1st ed.
Kluwer Academic Publishers, 2004. Print.
[6] GE Power & Water: Water & Process Tech-
nologies. 1st ed. General Electric Company, [19] Epa.gov,. ‘Effects Of Acid Rain - Human
2013. Web. 18 July 2015. Health’. N.p., 2012. Web. 18 July 2015.
10
Nanotechnology of Foam: Water Filtration • July 2015
11