Oxygen Analyser (PPB)

Oxygen analyser (ppb)
- 9182 -
Instruction manual
September, 1st 2000 621=191=082

Rev. C
Oxygen analyser (ppb) - 9182 -
This instrument conforms to the European Directives :
- 89/336/CEE modified by the directive 93/68/CEE

- 73/23/CEE modified by directive 93/68/CEE
Warning!
There are no user-serviceable parts in either the transmitter or sensor. Only Zellweger Analytics
personnel or their authorized representative should attempt repair of the system and only
components expressly approved by the manufacturer should be used. Any attempt to repair the
instrument in contradiction of these guidelines may result in damage to the instrument and injury to
the person making the repair. It will also void the warranty and may compromise the safe operation,
electrical integrity or CE compliance of the instrument.
Table of contents
Warnings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iii
Chapter 1 : Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1

1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1
1.2 Principle of operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1
1.3 Main characteristics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-3
1.4 Technical characteristics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-3
1.5 Dimensions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-6
Chapter 2 : Description of the analyser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1

2.1 Analytical part . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1
2.2 Hydraulic mounting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-2
2.3 Transmitter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-3
2.3.1 Presentation of the transmitter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-3
2.3.2 Application fields . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-5
2.3.3 Standard mounting possibilities (use of the red clamping bow) . . . . . . . . . . . . 2-5
Chapter 3 : Installation of the instrument . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1

3.1 Unpacking . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1
3.2 Inspection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1
3.3 Mounting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1
3.4 Location . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1
3.5 Electrical connections . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-2
3.6 Description of the different terminals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3
3.7 Mains connection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-4
3.8 Starting the transmitter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-4
3.9 Adjusting the display contrast . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-4
Chapter 4 :Using the instrument . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-1

4.1 Front panel keys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-1
4.2 Displays 1...4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-2
4.3 Description of the function keys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-3
4.4 Icons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-3
4.5 Enter ou modify a value . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-4
4.6 Warnings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-4
Chapter 5 : Programming the analyser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-1

5.1 Main menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-1
5.1.1 CALIBRATION Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-2
5.1.2 MAINTENANCE Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-3
i
5.1.3 PROGRAMMING Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-3

5.1.3.1 MEASURE Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-4
5.1.3.2 ALARMS Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-5
5.1.3.3 mA OUTPUTS Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-8
5.1.3.4 RS485 Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-10
5.1.4 SERVICE Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-11
5.1.4.1 AVERAGE Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-11
5.1.4.2 DISPLAY Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-12
5.1.4.3 CODE Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-13
5.1.4.4 SOFT VERSION Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-14
5.1.4.5 DEFAULT VAL. Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-14
5.1.4.6 mA ADJUST Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-15
5.1.4.7 CONFIGURATION Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-16
5.1.4.8 POLYMETRON Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-16
Chapter 6 : Calibrating the instrument . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-1

6.1 Calibration of the temperature sensor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-1
6.1.1 Automatic temperature compensation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-2
6.1.2 Manual temperature compensation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-3
6.2 Calibration of the measurement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-4
6.2.1 Slope calibration in the air + electric zero . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-4
6.2.2 Slope calibration in the air + chemical zero . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-5
6.2.3 Slope process calibration + electric zero . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-6
6.2.4 Slope process calibration + chemical zero . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-7
Chapter 7 : Start up, maintenance and troubleshooting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-1

7.1 Start up . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-1
7.1.1 Assembling the probe . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-1
7.1.2 Probe connection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-3
7.1.3 Main power supply connection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-3
7.1.4 Starting up the analyser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-3
7.2 Changing the membrane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-4
7.2.1 Dismounting the membrane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-5
7.2.2 Mounting the new membrane . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-6
7.3 Oxygen electrode rejuvenation procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-7
7.4 Functional troubleshooting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-7
7.5 Electric troubleshooting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-12
Chapter 8 : Error messages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-1
Appendix 1 : Pressure conversion table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A1-1

Appendix 2 : Temperature conversion table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A2-1
Appendix 3 : Default values . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A3-1
Appendix 4 : Detailled cable connections . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A4-1
Appendix 5 : Security data sheet . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A5-1
Appendix 6 : Spare parts list . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A6-1
Appendix 7 : RS485 MODBUS-JBUS addressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A7-1
i
Changing the programming language
Changing the programming language
The programming language is English when factory-programmed, when changing

the software version and when loading the default values. To change the language
follow the procedure below (example for French) :
iii
Programming the mains supply frequency

When your programming language is chosen,you may change the mains supply
frequency if necessary.
This change occurs at the first switching on and afterresetting the instrument.
Follow the procedure below :
iv
Chapter 1 : Introduction
1.1 Introduction O2 + 2H2O + 4e- 4OH-
The 9182 oxygen analyser is a one-channel A large silver counter electrode (anode)
analyser for the measurement of dissolved provides the oxidation reaction which
oxygen in the boiler feedwater, occurs on its surface :
economizers, condensers and more
generally all thermal equipment using water
4Ag+ + 4Br- 4AgBr + 4e-
as a heat transfer liquid.
The reduction of oxygen is the current
limiting reaction, thus making the cell
current linearly proportional to the dissolved
oxygen concentration.
1.2 Principle of operation
Electrochemical reactions and diffusion

The measurement of dissolved oxygen is
rates are temperature-sensitive. The
based on the well-known Clark cell
measuring cell, therefore, is equipped with
principle.
a temperature sensor which allows an
An oxygen-permeable membrane isolates
automatic temperature compensation.
the electrodes from the sample water, thus
obviating the need for sample conditioning.
Other reducible or oxidizable ions do not
interfere, because they cannot pass
through the gas-permeable membrane.
A constant voltage supply powers two
electrodes, maintaining each at a constant
potential.
A gold working electrode (cathode) reduces
the dissolved oxygen to hydroxyl ions :
1-1
Principle of oxygen cell
2
4
3
5
8
2
7
1 : Assembled electrode 6 : Membrane holder

2 : Electrolyte 7 : Membrane
3 : Probe body 8 : Cathode
4 : Filling hole 9 : Sample
5 : Anode
1-2
1.3 Main characteristics
Range 0- 2 ppm
Calibration in the air
Temperature compensation
Programmable alarm levels, outputs on relays
4-20 mA, 0-20 mA analogue outputs(standard) and RS485 (option)
Wall- , panel- and tubing mounting
1.4 Technical characteristics
SAMPLE
Number of channels 1
Temperature 0...45 %C (32...113°F)
Working pressure Atmospheric pressure
Flowrate 4...10 l/h
ELECTRICAL CHARACTERISTICS
Mains q Standard version :
100...240 VAC - 50/60 Hz
q Low voltage version :
13...30 VAC - 50/60 Hz
18...42 VDC
Power consumption 25 VA
Connections 2,5 mm² screw terminal
Fuse 5x20 mm cartridge - T2AL - 250V
ANALYSIS
Measuring range 0...2 ppm
Sensibility 0,5 ppb
Reproducibility ± 0,5 ppb or ± 2% whichever the greater
Detection limit 1 ppb
Response time (90 %) 3 min
1-3
Ambiant temperature -20...60 %C (-4...140°F)

Relative humidity 10...90%
TRANSMITTER
Display Display in concentration units
Display of the direct, concentration dependent cell
current in µA
Display of the sample temperature in %C/°F
Programming via menus
Units nA, µA, ppb-µg/l ppm-mg/l, %C, °F
Calibration Electrical zero, chemical zero, slope calibration in
the air, slope process calibration by comparison
with a laboratory measurement
Interferences Any gas liable to reduce to a potential > -850 mV
Analogue outputs 2 x 0/4... 20 mA isolated from input signal, 800
Ohms load maximum
- for the measure or for the temperature
- mode : linear, bi-linear
- accuracy : 0,1 mA
Alarms - Number : 4
- Functions : alarm - system alarm - timer
- Hysteresis : 0...10%
- Delay : 0...999s
- Breaking power : 250 VAC, 3A maximum
30 VDC, 0,5A maximum
Temperature compensation Automatic in the range of 0...45 %C (32...113 °F)
RS485 (option) Speed : 300...9600 bauds
Insulation : galvanic
Station number : 32 maximum
transmitter protection IP 65 (NEMA 4X in option)
Error reports Cell current > 999 µA
Sample temperature > 45 %C(113°F) or < 0%C
(32°F)
Ambiant temperature > 45%C or < 0%C (32...113°F)
during air calibration
Slope calibration error
Zero calibration error (offset)
ELECTROMAGNETIC COMPATIBILY
Immunity against electromagnetic EN 50082-2 and EN 50082-1
interferences
Electromagnetic emission EN 50081-1 and EN 50081-2
Low voltage standard IEC61010-1
1-4
MATERIALS
Working electrode Cathode : gold
Counter-electrode Anode : silver
Membrane holder Noryl
Membrane PFA
Transmitter Aluminium + polyester painting
Probe body Noryl
Probe with optional immersion stainless steel 316L
MAINTENANCE
Approximative membrane lifetime ~ 6 months depending on the sample

Cleaning Clean the instrument with a soft tissue and
without any agressive agent.
1-5
1.5 Dimensions
(Dimensions are in mm and [in inches])
1-6
Oxygen Analyser (ppb) - 9182 -
Chapiter 2 : Description of the analyser
2.1 Analytical part
6 5
Figure 2-1 : Electrode cross-section Figure 2-2 : Complete probe
1 : Connector 1 : Adjusting nut

2 : Anode holder 2 : Electrode
3 : Anode 3 : Probe body
4 : Cathode holder 4 : Membrane
5 : Cathode 5 : Filling screw
6 : Temperature sensor 6 : Gasket
2-1
2.2 Hydraulic mounting
(Dimensions are in mm [inches])

1 : cable 5 : cell
2 : shrink ring 6 : 1/4" NPT connector (not provided)
3 : assembled probe 7 : M4 screws (not provided)
4 : probe gasket 8 :1/4" NPT connector (not provided)
2-2
2.3 Transmitter
2.3.1 Presentation of the transmitter
The electronic unit amplifies the signal of the amperometric measuring cell and converts it into
a direct digital readout in ppm, mg/l, ppb, µg/l, %C and °F. The transmitter comprises the
following items :
Potentiostat which maintains the working electrode potential constant

Amperometric measuring module
Analog multiplexer
Microprocessor unit
The analog multiplexer allows measurements to be acquired from the measuring cell,
temperature sensor and internal checkpoints. Further, the microprocessor operates the relays,
the RS485 interface (optional) and the analog outputs.
The unit has a built-in concentration-autoranging feature and a microprocessor-operated

calibration routine.
The output of the potentiostat is monitored for possible overdriving of the potentiostat-output
stage. This condition can occur with the connections to the measuring cell open, inoperable
electrodes or a defective reference electrode.
2-3
Transmitter synoptic below is :
1 : Programmable potentiostat 6 : Auxiliary input

2 : Polarization voltage amplifier 7 : Multiplexer
3 : Reversing switch for a 2 or 3 electrode 8 : A/D converter
operation . In the 9181 the configuration is
2 electrodes
4 : Temperature measurement circuit 9 : Microprocessor
5 : Measurement circuit current amplifier
2-4
2.3.2 Application fields
Easy-to-use (installation, programming), this instrument is suitable for the following applications
- boiler feedwater
- ultrapure water
2.3.3 Standard mounting possibilities (use of the red clamping bow)
The transmitter housing conforms to norm DIN 43700.
Panel mounting
Panel cutting : 138 x 138 mm
Front panel dimensions : 144 x 144 mm
5 -
2 screws 4 mm lg 16 flat head (provided) for panel thickness 0 to 4 mm
5 -
2 screws 4 mm lg 20 flat head (provided) for panel thickness 4 to 8 mm
Wall mounting
5 2 screws - 4 mm lg 60 flat head (not provided)/ 80 mm center distance
2-5
Vertical pipe mounting

5- 2" maximum - 2 screws - 4 mm lg
60 (provided)
Horizontal pipe mounting

53 2" maximum - 2 screws 3 4 mm lg
60 (provided)
2-6
Chapter 3 : Installation of the instrument
3.1 Unpacking 3.3 Mounting
The analyser should be unpacked with CAUTION !

great care.. Make sure not to loose any
accessory when unpacking. Mounting should be done by
qualified service personnel only. No
power should be applied until the
3.2 Inspection installation is complete.
The analyser has been factory-checked and 3.4 Location

tested prior to shipment, it is however
advisable to inspect all parts immediately The analyser should be located in an
upon receipt for any damage which may accessible site.
have occured during shipment. A damaged
shipping container may indicate internal The site should permit the access for any
damage which may not be immediately checking or maintenance operation.
obvious. If there is any evidence of
damage, keep the shipping container and The sample flowrate has to be maintained
refer to your local agent or to : within the specifications (See § 1-4).
Zellweger Analytics S.A.
Z.I. des Richardets
33, rue du Ballon
93160 NOISY-LE-GRAND
3-1
3.5 Electrical connections
3 MONEC
Do not switch on the instrument until completion of the installation.
An aluminium armour plate inside the MONEC gives a detailled description of the different
terminals and their connections :
P1 contrast adjustment Relay board
Microprocessor board
RS485 board (option)
Amperometric board Power supply board
L The different terminals represented on the right side are accessible by removing the armour
plate.
3-2
3.6 Description of the different terminals
0/4... 20 mA outputs Description Connection

galvanicly insulated
0...20 mA or 4...20 mA (n°1) [+] user
0...20 mA or 4...20 mA (n°1) [-] user
0...20 mA or 4...20 mA (n°2) [-] user
0...20 mA or 4...20 mA (n°2) [+] user
option RS485 user
user
amperometric module Description Colour Connection
temperature sensor [+] black temp +

temperature sensor [-] blue temp -
reference if use of 3 not used on the 9182
electrodes oxygen analyser
Counter electrode (anode) red counter
Working electrode (cathode) white work
entrée auxiliaire aux.
External shield braid armour plate
Internal shield brown GND
Not used for the oxygen measurement n.c.
Mains, 100...240 VAC 50/60 Hz

or 24 V AC/DC (special version)
Descriptiion connection
alarm 1, simple contact user
alarm 2, simple contact user
alarm 3 or alarm system, simple contact user

alarm 4 or timer, simple contact user
3-3
L Electrical connections should remain dry to ensure a proper operation of the

instrument.
Check the creeping of the cables when opening the transmitter.
L It is required to use shielded cables. This shielding should be connected to the
earth central shielding.
3.7 Mains connection
Electrical connection should be performed only by qualified personnel. The power supply
accepts 100-240 VAC ± 10 %, (50/60 Hz) without changes in configuration. The terminal block
for power connections can be lifted from its header for easier installation. For safety reasons,
it is required to observe the precautions below :
! Use a three core mains supply cord (2 core + PE) rated for the maximum equipment
current
! The instrument should be connected to the power supply by means of a breaker located
close to the instrument and be identified. The supply shall be fitted with an overcurrent
protection device rated at 20 Amp maximum
! This breaker should switch off phase and neutral in case of electrical problems or when
the user wish to service the instrument. However the power supply earth must always
be connected.
Before servicing the instrument, ensure that the power supply is switched
off.
3.8 Starting the transmitter
Before switching on the transmitter, make sure the site voltage corresponds to the instrument
voltage indicated on the identification plate.
3. Adjusting the display contrast
If your display contrast is not sufficient, you can adjust it with the potentiometer P1 (blue colour,
see figure page 3-2) which is located on the top left of the CPU board (after opening the
enclosure).
3-4
Chapter 4 : Using the instrument
4.1 Front panel keys
The display may be programmed to indicate :
Sample concentration
Sample temperature
Diffusion current
Programming codes
Programming arguments
Figure 4-1 : Front panel
4-1
4.2 Displays 1 to 4 (live displays)
6.59 ppb : concentration measurement

(ppm unit)
23.2°C : temperature measurement

O2 : application
S1...S4 : alarm status (invisible if alarm
inactive).
Display of the parameters measured :

Concentration
Temperature
Cell current
S1...S4 : alarm status

In this case relays S1 and S3 are
activated.
Analogue output allocation and level
4-2
4.3 Description of the function keys
The function keys below have their signification highlighted at the bottom of the screen :
Modify a parameter
Scrolling in a list of menus
Go back to the main display
Display the main menu
Display screen 2
Display screen 3
Display screen 4
Validate the measure during the calibration
Confirm a command
Decrease a value
Increase a value
4.4 Icons
Symbol of waiting or instrument reset
Alarm system for relay S3
Timer symbol : countdown for relay S4
4-3
4.5 Enter or modify a value
The highlighted digit can be modified with the key .

Each digit can be validated by pressing ENTER. Repeat both operations for each digit.
Example :
4.6 Warnings
Note 1 : If you do not use the keyboard for at least 10 minutes, the instrument returns to the
measuring mode.
Note 2 : An access code may be required for the calibration, programming and service
menu (see § CODE menu).
Possibility to display a negative first digit “-”

Possibility to display a “.” for the other digits.
4-4
Chapter 5 : Programming the transmitter
5.1 Main menu
5-1
5.1.1 CALIBRATION menu
L Any calibration should follow the procedure below :

ì Configuration of the calibration characterics in the “PROGRAMMING” menu.
í Realization of the calibration via the “EXECUTION” menu.
An access code may be required if it has been programmed (See §5.1.4.3

CODE Menu)
See chapter 6 for a detailled programming of the calibrations.
Some menus may appear or not according to how some parameters have
been programmed.
CONC. CALIB.
TEMP. CALIB.
PARAMETERS
ZERO
EXECUTION
SLOPE
DATE: 01/01/98
P: 1.000µA/ppm
)T: 0.0 °C
PARAMETERS
DATE xx/xx/xx Date of the last calibration. The date programmed is
not updated automatically.
P x.xxx µA/ppm Slope value
)T x.x°C Drift between the theorical temperature (sensor
curve) Th and the temperature measured Tm :
)T = Th - Tm
5-2
5.1.2 MAINTENANCE menu
Used for any maintenance operation in the instrument;

The transmitter continues to display the variables
measured.
The relay status is not modified.

The analogue output value depends on the
configuration in the mA OUTPUTS/SPECIAL PROG.
/MAINTENANCE menu.
5.1.3 PROGRAMMING menu
An access code may be required.(See § 5.1.4.3 CODE menu)
5-3
51.3.1 MEASURE menu
TEMPERATURE COMPENSATION
TYPE - Auto Choice of a temperature measurement with automatic
- Manual compensation or with a manual compensation
If you have chosen a manual temperature compensation,
the TEMP. CALIB. Menu is not accessible anymore.
TEMP. - xx.x°C Possibility to enter the sample temperature in a

manual compensation mode
SENSOR NTC/AD590 Type of temperature sensor used on the 9182 Oxygen
analyser. You have to program the NTC.
5-4
5.1.3.2 ALARMS menu
Relays S1...S4 may be allocated to the limit, alarm system or timer functions.
5LIMIT FUNCTION :
The alarm relays are activated if the comparison of the measured value with the limit
programmed meets the alarm function condition (up or down). The limits are programmed
according to the following programming variables :
ALARMS 1 .... 4 (LIMIT)

AFFECT -Conc. Choice to use a limit on the measure,
- no on the temperature or not to use a limit.
-EC/EF
LIM xxxx Enter a limit value
DIR. -Up Choice of the direction

-Down
DELAY xxxs Temporisation time before the relay is
commutated (in seconds).
HYST. XX% Definition of the hysteresis limit in %
(10% max.)
The hysteresis operates only on one
side of the limit. The hysteresis is below
the limit for the high alarm (up) and
above the limit for the low alarm
(down).
RELAY -NO Relay normally open or normally closed
-NC
5-5
5 SYSTEM ALARM FUNCTION :
The relay S3 may be used to indicate a faulty functionning of the analyser.

It is required to connect the relay S3 to an external alarm system to control the faults traced by
the analyser.
The relay S3 is activated as soon as a default appears.
In case of a manual acknowledgment, the relay remains activated even if the default
disappears. It is required to press ENTER to desactivate the relay and the error message.
In case of an automatic acknowledgment, the relay and the error message are desactivated
when the default disappears.
ALARM 3 (ALARM SYSTEM)

MODE -No The alarm S3 may be programmed as a
-Limit limit function (See paragraph above) or as
-Syst. an alarm system function
ACCEPT -Auto In the case of an alarm system, choice
-Manu between a manual (key ENTER) or an
automatic acknowledgment
RELAY -NO Choice of S3 normally open or normally
-NC closed.
5-6
5 TIMER FUNCTION :
Relay S4 may be affected to a timer function.
ALARM 4 (TIMER)
MODE -No Choice between a limit (see parameters
-Limit above) or a timer function for alarm 4.
-Timer
INTERV XXXXmn Interval between 2 active cycles (in
minutes).
IMPUL. X Number of pulses during an active
cycle.
Ton XXXs Adjustment of the relay active time (in
seconds) for each pulse.
Toff XXXs Adjustment of the relay inactive time (in
seconds) for each pulse.
TmA XXmn Hold time for the analogue outputs after
each cycle.
L The analogue output status depends on
the configuration of the menu mA
OUTPUTS/SPECIAL PROG./TIMER
Example of a timer operating cycle :
Relay S4
pulse number
Closed
Open
Time
TmA
Ton Toff
Interval
5-7
5.1.3.3 mA OUTPUTS menu
The analogue output signals allow the transmission of the measurements from the analyser to
any external control system.
It is highly recommended to use shielded cables for the output signals. This shielding should
be connected to the earth terminal on the armour plate.
OUTPUT 1
OUTPUT 2
SPECIAL PROG.
TEST
MAINTENANCE AFFECT.: µA
CALIBRATION TYPE : 4-20
SYST. ALARM. MODE : Lin
TIMER LOW : 00001 nA
UP: 100.0 µA
MODE : Preset
VALUE : 00mA VALUE : 00 mA
5-8
OUTPUT 1/2
AFFECT - Conc. Choice of the analogue output allocation to the cell current
- µA to the concentration or to the temperature measurement.
- EC/EF
TYPE 0/20 Choice of the analogue output type
4/20
MODE - Lin Choice between a linear or dual range (see drawing below).
- Dual
LOWER XXXX Bottom of the scale value
MIDD. XXXX Mid-scale value (only in dual mode)
UPPER XXXX Top of the scale value
SPECIAL PROG.
MODE - last Characterictics of the analogue output during calibration,
- preset alarm system, maintenance or timer active cycles : frozen to
- live the latest stored before any operation listed above, forced to
a preset value, live measurement.
VALUE XX Preset value ( 0 to 21 mA)
TEST Test the analogue outputs by steps of 1 mA (0...21 mA)
5-9
5.1.3.4 RS485 Menu
If the RS485 optional board is installed in your transmitter, program the parameters of the menu
below.
The RS485 optional board enables the connexion between your analyser and a digital
communication system. The Communication protocol is JBUS/MODBUS. Refer to the
instruction manual “JBUS/MODBUS communication” (part number : 621=991=000) for further
details and to the Appendix D for the address list.
RS485
NE XX MONEC number (0...32)
BAUD - 300 Transmission speed in baud
- 600
- 1200
- 2400
- 4800
- 9600
PARITY - No Without parity bit
- Odd With odd parity bit
- Even With even parity bit
BIT STOP -1 1 bit stop
-2 2 bit stop
5-10
5.1.4 SERVICE Menu
An access code may be required if it has been programmed (see §5.2.4.3

! CODE Menu)
5.1.4.1 AVERAGE Menu
The measurement cycle lasts 4 seconds.
AVERAGE : 9 Average
TEST 3.46 ppb
Real
3.49 ppb
AVERAGENNE Program a moving average on the concentration measurement
AVERAGE X Define the number of measurements to calculate the average.
TEST Display the difference between a measurement obtained with and

without average.
5-11
5.1.4.2 DISPLAY Menu
DISPLAY
CONC - ppb/ppm Choice of the concentration unit
- µg-mg/l
TEMP. - EC Choice of the temperature unit
- EF
PRESSURE - mmHg Choice of the atmospheric pressure unit
- mbar
- InHg
LANGUAGE Choice of the language :
-F - French
- GB - English
-D - German
- SP - Spanish
-I - Italian
5-12
5.1.4.3 CODE Menu
Protection codes may be programmed to access to the PROGRAMMING, CALIBRATION,

SERVICE menus.
This code may be desactivated by programming 0000.
CODE
CALIB. XXXX Access code to the calibrations
PROG. XXXX Access code to the “PROGRAMMING” menu
SERVICE XXXX Access code to the “SERVICE” menu
If you forget your access code, press simultaneously ESC and ENTER to enter into
the menu selected.
5-13
5.1.4.4 SOFT VERSION Menu
This menu displays the software version installed in the instrument.
5.1.4.5 DEFAULT VAL. Menu
If you press YES, you load the default

values and you loose the current
programmed values and calibration
parameters.
5-14
5.1.4.6 mA ADJUST menu
The analogue output signals are factory-adjusted (upper limit : 20mA). However if a drift of
the 20 mA appears on one of the outputs, the mA ADJUST menu enables you to correct the
span value Connect an amperemeter in serial to the analogue output terminals and adjust
the value till you read 20.0 mA on the amperemeter.
L The value displayed does not correspond to an actual mA value.
5-15
5.1.4.7 CONFIGURATION menu
You have to program the operating frequency so it matches with the mains supply
characteristics. When the frequency is changed, the instrument is automatically resetted.
FREQ : 60Hz FREQ : 50Hz
@
Please
wait... Start up ...
5.1.4.8 POLYMETRON menu
This menu is reserved to POLYMETRON qualified

personnel.
5-16
Chapter 6 : Calibrating the instrument
NOTE
See chapter 5 for programming the commands.
REMARK
Any result (calibration or measurement) is always brought back to the reference
temperature(25E EC, 77EEF). If the sample temperature is different from the reference
temperature, it is required to execute a temperature compensation which can be either
manual or automatic.
6.1. Calibration of the temperature sensor
The temperature sensor is located in the dissolved oxygen measurement probe. It is factory-
preadjusted but needs to be calibrated in the sample on site. This calibration must be realised
before the oxygen measurement calibration (slope + zero).
6-1
6.1.1.Automatic temperature compensation
The sensor measures continuously the sample temperature. The concentration values are
automatically calculated according to the reference temperature (25 EC) by a preprogrammed
compensation law in the transmitter.
Follow the procedure below :
ì PROGRAMMING
Choice of an automatic temperature

compensation.
í EXECUTION
The execution is realised with the CALIBRATION
EXECUTION menu.
Enter the sample temperature value in °C.

Press OK to adjust the temperature displayed to
the actual value of the sample temperature
21.2 21.2 measured with a precise thermometer.
°C °C The gap between the calibration and the theorical
6.87ppm 21.2 °C response curve of the sensor is given for
information.
)T: 0.0 °C
ENTER : ok
ESC : cancel
6-2
6.1.2. Manual temperature compensation
This type of temperature compensation should be used only if your sample temperature is
constant.
ì PROGRAMMING
Choice of a manual temperature compensation.

TEMP. COMP.
TYPE : Manual
SENSOR : NTC
Enter your sample temperature.
TYPE : Manual
TEMP.:25.0°C
SENSOR : NTC
í EXECUTION
Not applicable when a manual temperature
compensation is chosen.
6-3
6.2. Calibration of the measurement
The slope calibration can be done in the air or in water, with electrical zero or chemical zero.
6.2.1. Slope calibration in the air + electrical zero
ì PROGRAMMING
ZERO :
Choice of an electrical zero. The electrical zero
is carried out automatically by the transmitter at
a regular frequency.
Choice of the slope in the air.
SLOPE :
Enter the atmospheric pressure in mmHg
Enter the ambiant temperature in °C
í EXECUTION
SLOPE :
PROGRAMMATION
PROGRAMMING Humidify the wadding of the calibration cap and
EXECUTION take off the probe from the sample. Position the
cap on the electrode and press ENTER.
The probe should be positionned with the
membrane downwards (see figure in §7.1.5).
21.2 DATE:01/01/98
°ppm P: 1nA/ppm The flashing "cal" message indicates that the
25.0°C
5.693µA
instrument is in calibration mode. Wait for the
current stabilisation ( approximatively 10 min.)
and press OK to validate the calibration. The
oxygen concentration value flashes during 3
seconds..
The analyser displays the date of the last

calibration and the new slope calculated. Modify
the date if you wish. Put back the electrode in
water.
6-4
6.2.2. Slope calibration in the air + chemical zero
ì PROGRAMMING
ZERO :
Choice of the chemical zero
Choice of the slope in the air
SLOPE :
Enter the atmospheric pressure in mmHg
Enter the value of the ambiant temperature
í EXECUTION
ZERO :
PROGRAMMING Make sure the water used for the chemical zero is
EXECUTION
really oxygen-free (< 1 ppb).
21.2 Press ENTER, the “CAL” message flashes and

°ppm indicates the instrument is in calibrating mode.
25.0°C
5.693µA Wait for the current stabilisation (
approximatively 10 min.) and press OK to validate
the calibration. The oxygen concentration value
0 flashes during 3 seconds..
°ppm
25.0°C
5.693µA
The instrument displays zero.
SLOPE :
PROGRAMMING
PROGRAMMATION
Humidify the wadding of the calibration cap and
EXECUTION take off the probe from the sample. Position the
cap on the electrode and press ENTER.
The probe should be positionned with the
membrane downwards (see figure in §7.1.5).
21.2 DATE:01/01/98 The flashing "cal" message indicates that the
°ppm P: 1nA/ppm instrument is in calibration mode. Wait for the
25.0°C
5.693µA current stabilisation ( approximatively 10 min.)
seconds..
the date if you wish. Put back the electrode in
water.
6-5
6.2.3. Slope process calibration + electric zero
ì PROGRAMMING
ZERO :
Choice of the electrical zero : The electrical zero
is carried out automatically by the transmitter at
a regular frequency.
Choice of a process slope
í EXÉCUTION
SLOPE :
The “CAL” message flashes and indicates the
PROGRAMMATION
PROGRAMMING
instrument is in calibrating mode. Wait for the
EXECUTION
current stabilisation and press OK.
You have the possibility to adjust the concentration
value digit by digit with the function key to the
21.2 DATE:01/01/98 value obtained with your reference analysis
°ppm P: 1nA/ppbm
25.0°C
5.693µA
method.

the date if you wish.
6-6
6.2.4. Slope process calibration + chemical zero
ì PROGRAMMING
ZERO :
Choice of the chemical zero
Choice of the slope process
í EXECUTION
ZERO :
PROGRAMMATION
PROGRAMMING
Make sure the water used for the chemical zero
EXECUTION is really oxygen-free (< 1 ppb).
Press ENTER, the “CAL” message flashes and

21.2
°ppm indicates the instrument is in calibrating mode.
25.0°C
5.693µA Wait for the current stabilisation (
approximatively 10 min.) and press OK to
validate the calibration. The oxygen
0 concentration value flashes during 3 seconds..
°ppm
25.0°C The instrument displays zero.
5.693µA
SLOPE :
PROGRAMMING The flashing "cal" message indicates that the
EXECUTION instrument is in calibration mode. Wait for the
current stabilisation ( approximatively 10 min.)
21.2 DATE:01/01/98
seconds..
°ppm P: 1nA/ppm
25.0°C calibration and the new slope calculated. Modify
5.693µA
the date if you wish.
6-7
Chapter 7 : Start up, maintenance and

troubleshooting
7.1 Start up
7.1.1 Assembling the probe
The probe is composed of the following items :
1 : Nut
2 : measuring electrode
3 : Probe body
4 : Membrane
5 : Filling screw
6 : Gasket
7-1
Proceed as follows for the assembling :
A. Screw the membrane Ô on the body till the dead stop Ñ:
B. Fill in the probe body with 5 ml of electrolyte by means of the syringe.
Check there is no impurity or bubble in the electrolyte.

C. Insert the electrode Ð in the probe body until you meet a resistance. Do not force.
D. Complete the mounting by tightening the nut Ï.
E. Mount the filling screw and its gasket. Tight it sufficiently to avoid any leaking of
electrolyte or external pollution from sample..
7-2
7.1.2 Probe connection
See figure 3-2 page 3-3 for the electrical connection. The standard length of the cable is 10
m.
7.1.3 Main power supply connection
Install the ferrite on the mains supply cable as close as possible to the transmitter. Proceed
to the connections according to the drawing 3-7 page 3-2.
7.1.4 Starting up the analyser
When switched on, the analyser operates an automatic test of its electronicsand displays a
first value. Wait till stabilization of the measurement (max. 30 mn). You should not calibrate
the analyser before the temperature and the concentration are stable. (See chapter 6).
Note 1 : There is electrolyte in the probe, keep it head down when you remove it from the
water.
Note 2 : Never shake the probe during a calibration, it may provoke an introduction of
oxygen in the electrolyte and a temporary cell current increase.
7-3
7.2 Changing the membrane
/ Never take off the electrode before removing the electrolyte filling plug
/ Never touch the membrane with the hands
/ Never use a worn membrane
Ï Turn off the water supply. Remove the Ð Unscrew the cell cap and remove the
probe.
connector from the probe.
7-4
7.2.1 Dismounting the membrane
A. Unscrew cap and gasket.
B. Unscrew nut.
C. Remove elctrode without scratching the cathode.
D. Empty the electrolyte left in the probe.
E. Unscrew the worn membrane.
7-5
7.2.2 Mounting the new membrane
F. Screw the new membrane on the body till the dead stop.
G. Replenish the probe body with 5 ml of electrolyte.

Check there is no impurity or bubble in the electrolyte.
H. Preposition the electrode without forcing. It should take its place by simple gravity.
I. Screw the probe nut till the electrode meets a resistance.
J. Put back the cap and gasket, screw the cap to ensure watertightness.
7-6
7.3 Oxygen electrode rejuvenation procedure
After some months of operation (3 to 12 depending on sample oxygen concentration, plant

shut-down frequency, ...), a dark AgBr coating may cover part of the silver anode.
This coating does not affect the measurement until more than 90% of the surface is
contaminated.
When changing the electrolyte and membrane, visually check the silver anode.
If more than 2/3 of the surface is covered then an electrode rejuvenation according the
following procedure is needed :
- soak the anode in 10% ammonia for about 1 hour then rinse it with demineralised water
and wipe it with a soft cloth,
- if the ammonia cleaning is not sufficient, rejuvenation of the silver electrode has to be done
by re-polishing softly (coating is a only few microns thick) the areas covered with silver
bromide with soft abrasive (N°400 to 600). After polishing, rinse the anode with
demineralised water and wipe it with a soft cloth.
The cleaned electrode performs immediately as well as a new electrode.

Obviously, as per any operation concerning a sensing element, recalibration is required.
7.4 Functional troubleshooting
Problem : Excessive time for stabilization or no stabilization during calibration in the

air
Causes and solutions :
a) The sample temperature is further to the ambiant temperature : 6°C(43°F) in water and
35°C(95°F) in the air so that the temperature drift provokes a reading drift :
Do not wait till the probe temperature meets the external temperature (use the
temperature compensation).
b) There is an electrolyte leak (through the membrane). The current is too high because of
an excessive penetration of oxygen.
Change the membrane.
C) There is an important pollution of the electrolyte due to an uncorrect adjustment of the
7-7
filling screw.
Change the electrolyte. Check there is a gasket and the screwing. Check the Teflon
band is correctly positionned.
D) The electrode is not correctly mounted in the probe body : there is an important
looseness between the membrane and the golden cathode.
Tighten the electrode screw (rep 3 page 7-1).
E) The membrane holder is uncorrectly screwed. Risk of electrolyte pollution.

Change the electrolyte and tighten correctly the membrane holder.
F) Lack of humidity because of an excessive temperature

Use a calibration cap (see spare parts list)
g) There is humidity or water in the probe connector

You notice a high unstability. Dry the connector and check it is correctly screwed.
H) The golden cathod surface is damaged (scratch or holes due to important shocks)
Do not polish the surface. Change the electrode.
I) Mud or particles on the golden cathod

Clean the cathod with an absorbant soft tissue and rinse the membrane.
j) The electrolyse potential does not equal - 0.85 V

Enter the correct value
k) Cable or connections damaged when the probe has been replaced

Check the connexion to the transmitter. If the connexion is correct check the
connections of the probe connector.
L) The probe is uncorrectly positionned (see §7.1.5 page 7-4 - note 1). The electrolyte leaks
and air bubbles input the cathod
Put the probe in the correct position, head down.
Problem : No significant current increase when the probe is in the air for the
calibration
7-8
a) There is an important pollution of the electrolyte due to an uncorrect adjustment of the

filling screw.
Change the electrolyte. Check there is a gasket and the screwing. Check the Teflon
band is correctly positionned or that the probe is not damaged.
B) The membrane holder is uncorrectly screwed. Risk of electrolyte pollution.

Change the electrolyte and tighten correctly the membrane holder.
C) the membrane has been torn

Change the memrane
D) The electrode is not correctly mounted in the probe body : there is an important
looseness between the membrane and the golden cathode.
Tighten the electrode screw (rep 3 page 7-1).
E) Cable or connections damaged when the probe has been replaced

Check the connection to the transmitter. If the connection is correct check the
connections of the probe connector.(See appendix 4 for the connector connections)
f) The membrane is worn

Change the membrane
g) There is a AgBr (dark green) deposit on the silver

Polish the silver tube with soft abrasive (N°400 to 600)
Problem : Important instability in measuring mode
a) There is humidity or water in the probe connector

Dry the connector and check it is correctly screwed.
B) Uncorrect connexion
Check the connections of the tranmitter to the probe
7-9
c) There are bubbles close to the cathod

Replenish the electrolyte holder and check there is no bubble between the cathod
and the membrane.
D) The probe is violently shaked

Check the fixation and the stability
e) Important electromagnetic interferences close to the probe or transmitter cable

Find a better place for the cable and check the EMC level.
F) Temporary interference with other gas

mainly with H2S
g) Flowrate too weak (50 ml/h minimum)

Change the probe location
h) Mud from an heterogen sample damages the membrane

Install a deflector or change the probe location
Problem : Lack of accuracy
a) The membrane permeability has changed (dirt deposit)

Calibrate the analyser and check if the concentration is back to normal;
b) Pollution of the electrolyte

Check the parts t to screw (membrane, filling screw) and change the electrolyte.
c) leak of electrolyte
Check the parts t to screw (membrane, filling screw) and change the electrolyte.
d) Interferences, mainly with H2S

If the level of H2S (or other pollutant) is stable, take into account its concentration
to determine the O2 concentation.
e) Error during calibration or uncorrect calibration

calibrate again to check the paameters. If the error is confirmed, check the
7-10
calibration current (too high, too low or unstable) and the concentration in the air.
Refer to the problems described above.
f) The temperature calibration has not been done

Check the temperature given by the transmitter and calibrate it (see page 6-2). If
you have chosen the manual compensation check the value is correct.
g) There are bubbles close to the cathod

Replenish the electrolyte holder and check there is no bubble at the bottom.
h) Flowrate too low (4 l/h minimum)

Increase the flowrate
i) The sample temperature or pressure is out of the specifications

Change the probe location or modify the sample so that it meets the specifications.
j) Mud or particles on the golden cathod

Clean the golden cathod with an absorbant tissue and rinse the membrane.
k) The electrolyse potential is not equal to -0.85 V

Enter the correct value.
Other problems
a) The probe current is null

There is no electrolyte in the probe (leak)
b) The probe current is negative

Connexion problem to the anode circuit (loose contact)
AgBr deposit on the anode
c) The sample temperature corresponds to the specifications but there is an error on the
temperature
There may be a short-circuit on the temperature connection
7-11
7.5 Electric troubleshooting
WARNING !
Never attempt servicing before disconnecting the instrument from the
main power line.
MALFUNCTION POSSIBLE CAUSE REMEDIES
No indication No power ; instrument is not Check for power, then check if connected
connected correctly properly
Defective fuse Check fuse
Instrument's power supply set for Check jumpers on power-supply board for
wrong line voltage correct voltage settings
Ribbon cable connecting power with Check that the ribbon plugs are properly
CPU board not properly plugged in plugged in.
Connection between CPU board and Check plug connections

measurement module loose
Short circuit in power-supply board Visually check power-supply board for

shorts
Hardware is defective Call the Service Technician
LCD displays undefined Malfunctionning CPU board or Using the Instruction manual, program the
characters processor instrument to load the default values
CPU hardware RESET the instrument by temporarily

interrupting the power (5-10 secs.)
Call the Service Technician
Keyboard does not operate ; all CPU malfunctioinning, external If there is no response, RESET the
keys are inactive interferences instrument by temporarily interrupting the
power (5-10 seconds.). Check each key
again. If there is no change, call the
Service Technician.
Measurement is not correct Instrument was programmed recheck programmed parameters. Do they
incorrectly agree with the probe's characteristics ?
System, including probe, not Calibrate the whole system (probe

calibrated correctly. connected).
Probe connected wrong. Recheck all probe connections
Probe malfunctionning, possibly Visually check the condition of the probe. Is

incompatible with the application. the application within the probe's
specifications (data sheet) ?
CPU board is defective. If error persists, call the Service

Technician.
Measurement is not stable Faulty probe Check the condition of the probe. Is it
contaminated ?
Probe connected wrong Is the probe connected correctly ?
7-12
Interferences Are there any sources of potential

interference, chemical, external,
temperature, pressure, etc...?
Cable shield is not connected Check and connect
Defective CPU board If problem persists, call the Service

Technician.
Temperature measurement is not Probe connected wrong Is the probe properly connected ? Check.
correct
Temperature was not calibrated Calibrate for temperature. Also check the
Pt100 for correct resistance (ohmmeter).
CPU board is defective If problem persists, call the Service

Technician.
Display reading static ; cannot be Malfunctionning CPU board and/or Check to make sure that probe is
changed in any way some other transmitter hardware is connected correctly.
defective.
Initiate a software RESET.
If steps 1-3 do not remedy the problem,

make a cold start (RESET) : interrupt the
power for 5-10 secs.
Reprogram the instrument again.
If problem persists, call the Service

Technician.
Relays not energised Instrument was programmed Check whether the correct relay
incorrectly parameters and setpoints have been
programmed.
Hardware is defective Check that the programmed setpoints are

compatible with the programmed
measuring range.
Check the relay characteristics for proper

functionning using an ohmmeter.
If problem persists, contact the Service

Technician.
Wrong output current, output Instrument was incorrectly Check the proggrammed output-current
current remains locked at 0 or 20 programmed parameters
mA
Connection of the Monec with Check the cables
peripherals (recorder, etc.) are faulty,
loose or defective.
Hardware is defective Compare the measured value with the

output-current range
If problem persists, call the Service

Technician
Polarization voltage uncorrect Wrong configuration (3 electrode Check the swiches under the amperometric
mode) board are correctly positionned ( “on”).
Wrong programming
7-13
Chapter 8 : Error messages
/ In case of errors, the measurements are replaced by dashes “- - -”.

Error messages Description
Error messages during a measurement

The concentration value is out of the limits. Check
the current value and the calibration parameters.
Electrode protection
In case of measuring range exceeding
“concentration too hugh” over 2 minutes, the error
message “STAND-BY” appears. From this moment
on, the electrode polarization voltage is switched off
during 10 minutes. After these 10 minutes, the
voltage is switched on.
/ In STAND-BY the user may switch on the
voltage at any time by pressing ENTER.
The concentration value is out of the limits. Check

the current value and the calibration parameters.
The sample temperature is out of the limits. Check

the cable polarity. Check if there is any short-circuit
or open circuit.
8-1
The current value is out of the limits. Check the

electrode (electrolyte and membrane).
The current value is out of the limits. Check there is

no short-circuit on the measuring line. Check the
polarization voltage.
Error messages during a calibration

The temperature difference between the calibration
and the sensor theorical response is superior to the
limit programmed.
Limits : ± 20°C
8-2
Appendix 1 : Pressure conversion table
hPa or mbars mm Hg mm H2O psi inches Hg inches H2O
920.00 690 9503.60 13.34 27.16 374.16
925.00 693.8 9555.25 13.42 27.31 376.19
930.00 697.5 9606.90 13.49 27.46 378.22
935.00 701.3 9658.55 13.56 27.61 380.26
940.00 705 9710.20 13.63 27.76 382.29
945.00 708.8 9761.85 13.71 27.90 384.32
950.00 712.5 9813.50 13.78 28.05 386.36
955.00 716.3 9865.15 13.85 28.20 388.39
960.00 720 9916.80 13.92 28.35 390.43
965.00 723.8 9968.45 14.00 28.50 392.46
970.00 727.5 10020.10 14.07 28.64 394.49
975.00 731.3 10071.75 11.14 28.79 396.53
980.00 735 10123.40 14.21 28.93 398.56
985.00 738.8 10175.05 14.29 29.08 400.59
990.00 742.5 10226.70 14.36 29.23 402.63
995.00 746.3 10278.35 14.43 29.38 404.66
1000.00 750 10330.00 14.50 29.53 406.69
1005.00 753.8 10381.65 14.58 29.68 408.73
1010.00 757.5 10433.30 14.65 29.82 410.76
1015.00 761.3 10484.95 14.72 29.97 412.79
1020.00 765 10536.60 14.79 30.12 414.83
1025.00 768.8 10588.25 14.87 30.27 416.86
1030.00 772.5 10639.90 14.94 30.42 418.89
A1-1
Appendix 2 : Temperature conversion table
Conversion from %
C into %F : %
F = 1,8 x %C + 32
Conversion from %
C into %K : %
K = %C + 273,15
% % % % % %
C F K C F K
0 32 273,15 24 75.2 297.15
1 33,8 274,15 25 77 298.15
2 35,6 275,15 26 78.8 299.15
3 37,4 276,15 27 80.6 300.15
4 39,2 277,15 28 82.4 301.15
5 41 278.15 29 84.2 302.15
6 42.8 279.15 30 86 303.15
7 44.6 280.15 31 87.8 304.15
8 46.4 281.15 32 89.6 305.15
9 48.2 282.15 33 91.4 306.15
10 50 283.15 34 93.2 307.15
11 51.8 284.15 35 95 308.15
12 53.6 285.15 36 96.8 309.15
13 55.4 286.15 37 98.6 310.15
14 57.2 287.15 38 100.4 311.15
15 59 288.15 39 102.2 312.15
16 60.8 289.15 40 104 313.15
17 62.6 290.15 41 105.8 314.15
18 64.4 291.15 42 107.6 315.15
19 66.2 292.15 43 109.4 316.15
20 68 293.15 44 111.2 317.15
21 69.8 294.15 45 113 318.15
22 71.6 295.15
23 73.4 296.15
A2-1
Appendix 3 : Default values
CALIBRATION
CONC. CALIB. PARAMETERS

OFFSET DATE :01/01/98
Type : AutoElec. S : 1.000 µA/ppm
SLOPE )T : 0.0 °C
Type : Air
P : 760 mmHg
Tamb. : 20.0°C
PROGRAMMING
MEASURE
TEMP. COMP.
TYPE : Auto
SENSOR : NTC
ALARMS
ALARMS S1/S2/S4 ALARM S3

AFFECT. : Conc. AFFECT. : System
LIM. : 0.00 ppb ACQUIT : Auto
DIR. : Low RELAY : NC
DELAY : 000 s
HYST. : 00%
RELAY : NO
mA OUTPUTS
OUTPUT 1 OUTPUT 2
AFFECT. : Conc. AFFECT. : Conc.
TYPE : 4-20 TYPE : 4-20
MODE : Lin. MODE : Lin.
LOW : 0.000 ppm LOW : 0.000 ppm
UP : 1.000 ppm UP : 1.000 ppm
A3-1
SPECIAL PROG.
MAINTENANCE CALIBRATION
MODE : Last MODE : Last
TIMER ALARM SYSTEM

MODE : Last MODE : last
RS485
No : 0
BAUD : 9600
PARITY : No
STOP BIT : 1
SERVICE
AVERAGE
AVERAGE : 1
DISPLAY
DISPLAY
CONC. : ppb/ppm
TEMP. : °C
PRESSURE : mmHg
LANGUAGE : GB
CODE
CODE
CALIB. : 0000
PROG. : 0000
SERVICE : 0000
CONFIGURATION
CONFIGURATION
FREQ. : 50 Hz
A3-2
Appendix 4 : Detailled cable connections
Rep Colour Function Rep. Connector

1 Black T+ 1
2 Blue T- 2
3 White Work 3
4 Red Counter 4
5 White GND
6 White Earth
A4-1
A4-2
Appendix 5 : Security data sheet
Potassium hydroxide pellets
PHYSICAL AND CHEMICAL PROPERTIES
Solid
Melting point 361 %C
Vapor pressure IMM 719 C
Specific gravity 2.044
LABEL PRECAUTIONARY STATEMENTS
Corrosive. Causes burns. Harmful by inhalation, in contact with skin and if swallowed. Reacts violently
with water. In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. take off immediately all contaminated clothing. Wear suitable protective clothing, gloves and
eye/face protection.
STABILITY AND REACTIVITY
Stability stable
Incompatibilites acids, aluminum, halogens, nitro compounds,

organic materials, acid chlorides, acid
anhydrides, magnesium, copper, tin, zinc. Do
not heat above melting point. Protect from
moisture. Absorbs CO2 from air. Reacts
violently with : water, generates flammable
and/or explosive hydrogen gas in contact with :
metals.
Hazardous combustion or decomposition
products : hydrogen gas.
A5-1
In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes
while removing contaminated clothing and shoes. Assure adequate flushing of the eyes by separating
the eyelids with fingers. If inhaled, remove to fresh air. If not breathing give artificial respiration. If
breathing is difficult give oxygen. If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately. Discard contaminated clothing and shoes.
FIRE FIGHTING MEASURES
Non combustible. Use extinguishing media appropriate to surrounding fire conditions. Do not use
water. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin
and eyes. Reacts violently with water. Emits toxic fumes under fire conditions.
ACCIDENTAL RELEASE MEASURES
Evacuate area. Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves.
Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash
spill site after material pickup is complete.
HANDLING AND STORAGE
Danger : under fire conditions material will melt and flow. Molten material reacts violently with water and
can react with aluminum, tin, zinc and their alloys to generate flammable and explosive hydrogen gas.
Potassium hydroxide reacts with trichloroethylene to form spontaneously flammable dichloroacetylene.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear appropriate NIOSH/MSHA-approved respirator, chemical-resistant gloves, safety goggles,

other protective clothing. Safety shower and eye bath. Use only in a chemical fume hood.
Faceshield (8-inch minimum). Do not breathe dust. Do not get in eyesz, on skin, on clothing. Avoid
prolonged or repeated exposure. Wash thoroughly after handling. Corrosive. Toxic. Keep tightly
closed. Do not allow contact with water. Store in a cool dry place.
TOXICOLOGICAL INFORMATION
Acute effects : harmful if swallowed, inhaled or absorbed through skin.Material is extremely

destructive to tissue of the mucous membranes and upper respiratory tract, eyes and skin.
Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema. Symptoms of exposure may include burning
sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.
DISPOSAL CONSIDERATIONS
Contact a licensed professional waste disposal service to dispose of this material.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide.
A5-2
Potassium bromide
PHYSICAL AND CHEMICAL PROPERTIES
White crystals
Melting point 770 %C
Specific gravity 1.984
LABEL PRECAUTIONARY STATEMENTS
Harmful. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory
system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Wear suitable protective clothing.
STABILITY AND REACTIVITY
Incompatibilites Strong oxidizing agents

Strong acids
Hazardous combustion or decomposition
products : hydrogen chloride gas
FIRST AID MEASURES
In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. In
case of contact, immediately wash skin with soap and copious amounts of water. If inhaled, remove
to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. If swallowed,
wash out mouth with water provided pereson is conscious. Call a physician. Wash contaminated
clothing before reuse.
FIRE FIGHTING MEASURES
Extinguishing media Water spray
Special firefighting procedures Wear self-contained breathing apparatus and

protective clothing to unusual fire and
explosions hazards
Unusual fire and explosions hazards Emits toxic fumes under fire conditions
ACCIDENTAL RELEASE MEASURES
Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Sweep up, place in
a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material
pickup is complete.
PROCEDURE DE CONTROLE DE L’EXPOSITION DES TRAVAILLEURS
A5-3
Lunettes de sécurité chimique, gants de caoutchouc, masque respiratoire approuvé par la

NIOSH/MSHA, douches de sécurité et fontaines oculaires, échappement mécanique requis. Eviter
tout contact et l’inhalation. Eviter tout contact avec les yeux, la peau et les vetements. Bien se laver
après manipulation. Solide nocif, irritant. Conserver le récipient bien fermé. Hygroscopique.
Conserver dans un endroit frais et sec.
TOXICOLOGICAL INFORMATION
Acute effects : harmful if swallowed, inhaled or absorbed through skin. Causes eye and skin
irritation. Material is irritating to mucous membranes and upper respiratory tract. To the best of our
knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated. Ingestion of large quantities can cause weahness, gastrointestinal irritation and
circulatory disturbances.
DISPOSAL CONSIDERATIONS
For small quantities : cautiously add to a large stirred excess of water. Adjust the pH to neutral,
separate any insoluble solids or liquids and package them for hazardous-waste disposal. Flush the
aqueous solution down the drain with plenty of water. The hydrolysis and neutralization reactions
may generate heat and fumes which can be controlled by the rate of addition. Observe all federal,
state and local environmental regulations.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide.
A5-4
Appendix 6 : Spare parts list
Any other spare parts except those below in the table should be replaced in the
instrument.
Description Part number
RS485 board + manual 09125=A=1100

Box of 4 premounted membranes ppb 09182=A=3500
Reference electrolyte 100ml 363144,00100
Oxygen electrode without probe body ppb 09078=A=1000
Calibration cap 09078=A=1200
Eprom for 9180 Oxygen 09180=A=6201
Connection cable 10m 09078=A=3010
Probe body oxygen ppb 09078=C=1010
Electrolyte filling screw 09078=C=1020
Electrolyte filling washer 09078=C=1030
Stainless steel flow cell 09078=A=2000
Syringe 560150,21951
CPU board 09125=A=1000
Power supply 09125=A=2000
Analog PC board for 9180 09180=A=1500
Display board 09125=A=1010
Monec D 9180 (standard) with software 09180=A=0000
Monec D 9180 (RS485) with software 09180=A=0011
Monec D 9180 (NEMA4X) with software 09180=A=3000
Monec D 9180 (NEMA4X+RS485) with software 09180=A=3011
A6-1
9182 Instruction manual in English 621=191=082

9182 Instruction manual in French 621=091=082
9182 Instruction manual in German 621=291=082
9182 Instruction manual in Italian 621=491=082
9182 Instruction manual in Spanish 621=591=082
A6-2
Appendix 7 : RS485 MODBUS-JBUS addressing
CALIBRATION menu
/CONC. CALIB.
/ZERO
/PROGRAMMING
/Type (0:ElecAuto, 1:Chemical) 0121
/EXECUTION
/SLOPE
/PROGRAMMING
/Type (0:Process, 1:Air) 0221
/P 0222
/Tamb 0223
/EXECUTION
/TEMP. CALIB..
/EXECUTION
/PARAMETERS
MEASURE menu
/MEASURE
/ TEMP. COMP.
/Type (0:Manual,1:Auto) 1220
/Temp. 1230
ALARMS menu
/ALARM1
/Affect (0:conc, 1:°C/°F, 2:No) 2120
/Lim. 2130
/Dir. (0:Low, 1:Up) 2140
/Delay 2150
/Hyst. 2160
/Relay (0:N.O., 1:N.C.) 2170
/ALARM2
/Affect (0:conc, 1:°C/°F, 2:No) 2220
/Lim. 2230
/Dir. (0:Low, 1:Up) 2240
/Delay 2250
/Hyst. 2260
/Relay (0:N.O., 1:N.C.) 2270
/ALARM3
/Mode (0:Limit, 1:Syst, 2:No) 2310
/Affect (0:conc, 1:°C/°F, 2:No) 2320
/Lim. 2330
/Dir. (0:Bas, 1:Haut) 2340
/Delay 2350
/Hyst. 2360
/Relay (0:N.O., 1:N.C.) 2370
/Accept 2380
A7-1
/ALARM4
/Mode (0:Manu, 1:Auto) 2410
/Affect 2420
/Lim. (0:Limit, 1:Timer, 2:No) 2430
/Dir. (0:conc, 1:°C/°F, 2:No) 2440
/Delay 2450
/Hyst. (0:Low, 1:Up) 2460
/Relay 2470
/Interv 2401
/Impul. (0;N.O., 1:N.C.) 2402
/Ton 2403
/Toff 2404
/TmA 2405
mA OUTPUTS menu
/OUTPUT1
/Affect (0:µA, 1:°C/°F, 2.conc) 4110
/Type (0:0/20mA, 1:4/20mA) 4120
/ Mode (0:lin, 1:dual) 4150
/Low 4130
/ Mid. 4160
/Upp. 4140
/OUTPUT2
/Affect (0:µA, 1:°C/°F, 2:conc) 4210
/Type (0:0/20mA, 1:4/20mA) 4220
/Mode (0:lin, 1:dual) 4250
/Low 4230
/Mid. 4260
/Upp. 4240
/SPECIALPROG.
/MAINTENANCE
/Mode (0:Live, 1:Last, Preset) 4311
/Value 4312
/CALIBRATION
/Mode (0:Live, 1:Last, 2:Preset) 4321
/Value 4322
/SYST. ALARM
/Mode (0:Live, 1:Last, 2:Preset) 4331
/Value 4332
/TIMER
/Mode (0:Live, 1:last, 2:Preset) 4341
/Value 4342
/TEST
RS485 menu
/N° 5100
/Baud (0:300, 1:600, 2:1200, 3:2400, 5200
/Parity 4:4800, 5:9600) 5300
/Stop bit (0:No, 1:Odd, 2:Even) 5400
(0:1bit, 2:2bits)
SERVICE menu
/AVERAGE
/Average (0:0,...10:10) 7210
/TEST
/DISPLAY
/Conc. (0:ppb-ppm, 1:µg-mg/l) 7360
/Temp (0:°C, 1:°F) 7320
/Pressure (0:mmHg, 1:mbar, 2:inHg) 7370
/Language (0;F, 1:GB, 2:D, 3:Sp, 4:I) 7330
A7-2
/CODE
/Calib. 7410
/Program 7420
/Service 7430
/SOFT ISSUE
/DEFAULT VAL.
/ADJUST mA
/OUTPUT1
/OUTPUT2
/CONFIGURATION
/Freq (0:60HZ, 1:50Hz) 7810
Values measured :
Adr 0000 : concentration value
Adr 0002 : temperature value
Adr 0004 :current value
Adr 0006 : auxiliary value measured
A7-3

Oxygen Analyser (PPB) - 9182 - : Instruction Manual

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Oxygen Analyser (PPB) - 9182 - : Instruction Manual

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September, 1st 2000 621=191=082

This instrument conforms to the European Directives :

- 89/336/CEE modified by the directive 93/68/CEE

Chapter 1 : Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1

Chapter 2 : Description of the analyser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1

Chapter 3 : Installation of the instrument . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1

Chapter 4 :Using the instrument . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-1

Chapter 5 : Programming the analyser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-1

5.1.3 PROGRAMMING Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-3

Chapter 6 : Calibrating the instrument . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-1

Chapter 7 : Start up, maintenance and troubleshooting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7-1

Chapter 8 : Error messages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-1

Appendix 1 : Pressure conversion table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A1-1

Changing the programming language

Changing the programming language

The programming language is English when factory-programmed, when changing

Programming the mains supply frequency

1.1 Introduction O2 + 2H2O + 4e-  4OH-

Electrochemical reactions and diffusion

Principle of oxygen cell

1 : Assembled electrode 6 : Membrane holder

1.3 Main characteristics

 Wall- , panel- and tubing mounting

1.4 Technical characteristics

Ambiant temperature -20...60 %C (-4...140°F)

Approximative membrane lifetime ~ 6 months depending on the sample

(Dimensions are in mm and [in inches])

Chapiter 2 : Description of the analyser

2.1 Analytical part

Figure 2-1 : Electrode cross-section Figure 2-2 : Complete probe

1 : Connector 1 : Adjusting nut

2.2 Hydraulic mounting

(Dimensions are in mm [inches])

3 : assembled probe 7 : M4 screws (not provided)

4 : probe gasket 8 :1/4" NPT connector (not provided)

2.3.1 Presentation of the transmitter

 Potentiostat which maintains the working electrode potential constant

The unit has a built-in concentration-autoranging feature and a microprocessor-operated

Transmitter synoptic below is :

1 : Programmable potentiostat 6 : Auxiliary input

5 : Measurement circuit current amplifier

2.3.2 Application fields

2.3.3 Standard mounting possibilities (use of the red clamping bow)

The transmitter housing conforms to norm DIN 43700.

Vertical pipe mounting

Horizontal pipe mounting

Chapter 3 : Installation of the instrument

3.1 Unpacking 3.3 Mounting

The analyser should be unpacked with CAUTION !

The analyser has been factory-checked and 3.4 Location

3.5 Electrical connections

Do not switch on the instrument until completion of the installation.

P1 contrast adjustment Relay board

RS485 board (option)

Amperometric board Power supply board

3.6 Description of the different terminals

0/4... 20 mA outputs Description Connection

0...20 mA or 4...20 mA (n°1) [-] user

0...20 mA or 4...20 mA (n°2) [-] user

0...20 mA or 4...20 mA (n°2) [+] user

option RS485 user

amperometric module Description Colour Connection

1.1 Introduction O2 + 2H2O + 4e- 4OH-

Wall- , panel- and tubing mounting

Potentiostat which maintains the working electrode potential constant