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Environ Earth Sci (2012) 65:1841–1846

DOI 10.1007/s12665-011-1166-x

ORIGINAL ARTICLE

Drying sewage sludge using flue gas from power plants in China
Xue-wen Ma • Huan-xin Weng • Min-hua Su •

Lehua Pan

Received: 5 May 2010 / Accepted: 24 June 2011 / Published online: 8 July 2011
Ó Springer-Verlag 2011

Abstract A lot of energy is required for drying the about 16,440 tons of CO2 emission could also be reduced
sewage sludge produced during the wastewater treatment every year.
process in China; however, on the other hand, the thermal
energy in flue gas from power plants is usually wasted as it Keywords Sewage sludge  Sludge drying  Waste heat
discharges into the atmosphere. In this study, a new tech- reuse  CO2 emission reduction
nique for sludge drying is introduced. The key component
of the new technique is equipment of a two-stage drying
and granulation that utilizes thermal energy contained in Introduction
the flue gas from power plants and extends sludge contact
time with flue gas during the constant-rate evaporation Sludge is by far the largest in volume among the byproducts
stage. The primary results of the implementation in the of wastewater treatments (Werther and Ogada 1999). Sew-
Kangshun sludge treatment plant (daily treatment capacity age sludge, also known as biosolids, is a material formed
of 100 tons of wet sludge) show that the new drying during wastewater treatment. Sludge is rich in organic
technique is very effective economically and environ- matter, which can be transformed to energy (Otero et al.
mentally. The water content in the sludge was reduced 2008; Folgueras et al. 2003; Abbas et al. 1996). However,
from 78% to less than 30%. The resulted sludge could be the dewatered sludge with approximately 75–80% water
used either to co-incinerate with coal in a circulating flu- content is considered too wet to be incinerated due to its low
idized bed or to mix with clay to make better bricks. calorific value (Taib et al. 2001) and high water content
Besides the saving in the direct heating cost in the sludge (Stasta et al. 2006). Further drying is, therefore, required and
drying processes by 80%, the saving in fossil fuel con- many drying methods have been proposed (Vaxelaire et al.
sumption due to reuse of the dried sludge is also significant. 2001). Among them, thermal drying is one of several
As a result of the implementation of the new technique in a methods that are widely used to reduce the volume and
sludge treatment plant at the scale of the Kangshun plant, pathogen and improve the quality of sludge (Wang 2007).
However, thermal drying is not a cheap solution mainly
because of its high energy demand. Heat drying systems
X. Ma  H. Weng (&)
Institute of Environment and Biogeochemistry, require 1,400-1,700 British Thermal Units per pound of
Zhejiang University, Hangzhou 310027, water evaporated (US Environmental Protection Agency
People’s Republic of China 2006a). Most thermal sludge drying systems rely on a fuel-
e-mail: gswenghx@zju.edu.cn
burning furnace as their heat source, which burns natural gas,
M. Su digester gas, fuel oil, or even coal. In China, coal is widely
Hangzhou Xinyuan Environmental Engineering Co. Ltd, used because it is relatively cheap. However, burning coal is
Hangzhou 310012, People’s Republic of China dirty, and will produce more pollutants and also increase
CO2 emission. Even though the coal price is relatively low, it
L. Pan
Lawrence Berkeley National Laboratory, One Cyclotron Road, is still a significant burden in this energy-tight age. Many
MS: 90-1116, Berkeley 94720, USA alternative heat sources such as biogas, landfill gas, gas

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turbine exhausts, and wood-fired gasifiers have been pro- The Kangshun sludge treatment plant and the sludge
posed to be used in sludge drying, especially in Europe and drying system
America (Finnveden et al. 2005; U.S. Environmental Pro-
tection Agency 2006b). However, the usage of these waste The drying technique was implemented in the Kangshun
heat sources in sludge drying is rare in China, partly because sludge treatment plant (KSTP) in Jiangyin, China. KSTP is
these alternative heat sources are not common in China. one of the three centralized sludge treatment stations in
There are many thermal power plants (TPPs) in China. Jiangyin. KSTP was built within the Kangshun thermal
The temperature of flue gas in many thermal power plants power plant, which provided flue gas. About 100 tons of
(TPPs) is at about 160–200°C, and is often discharged sludge with 78% water from local wastewater treatment
uselessly. In this paper, the drying characteristics of sew- plants was processed in KSTP. In wastewater treatment,
age sludge were analyzed, and a technique for sludge about 70% was domestic sewage while the rest came from
drying using waste heat of thermal energy of flue gas, printing and dyeing factories. Figure 1 shows the flow
which is usually wasted, was introduced. The new tech- chart of the processes used in the sludge processing system
nique has been successfully implemented in the Kangshun in KSTP.
sludge treatment plant (KSTP) (daily treatment capacity of The sludge drying system consists of three parts: the wet
100 tons wet sludge). sludge storage, the thermal drying system, and the product
storage. Every day, about 100 tons of mechanically
dewatered sludge with 78% water content is transported to
Materials and methods KSTP and stored in wet sludge storage about 500 m2 where
the sludge undergoes natural evaporation for several days.
Drying experiments Usually, as a result of the natural evaporation, water con-
tent of sludge decreases to about 75%. The sludge is then
Sewage sludge produced in China is complex because of fed into thermal drying and granulation systems. Thermal
the mixed treatment of domestic and industrial wastewa- drying is an energy consumption process, and energy cost
ters. To understand the drying characteristics of sludge in in conventional thermal drying system usually takes about
KSTP, a number of experiments to dry sewage sludge at 80% of the total cost in sludge drying (Wang et al. 2007).
constant temperature were carried out at different temper- The advantage of the thermal drying system implemented
atures, 100, 120, 140, 160, 180 and 200°C. The sludge in KSTP is that flue gas used for sludge drying is from
samples were granules with a diameter of 1 cm. The circulating fluidized bed (CFB) at the site as a free heating
samples were weighted at various drying time and the source. Flow rate of the flue gas is about 15 9 104 m3/h
drying rates were calculated. and its temperature is at 170°C. A two-dryer drying system
was designed to extend contact time of sludge with flue gas
Thermal stability analysis (Weng and Su 2005) and to complete the thermal drying
process at critical moisture content (about 40%). The gas is
Thermogravimetric analysis methodology was used to injected into the first dryer and the second dryer at a rate of
study thermal stability of sludge using a TA SDTQ600 10 9 104 and 5 9 104 m3/h, respectively. The first drying
analyzer. Air-dried samples were heated in air stream at a equipment is a rotary dryer with spiral flights, lifting
heating rate of 10°C/min. flights, and chain hammers. The first dryer is 2.2 m in

Fig. 1 Flow chart of the


processes used in the sludge
processing system in KSTP

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Environ Earth Sci (2012) 65:1841–1846 1843

diameter and 24 m in length and its inclination angle is curves of the drying rate to either water content or heating
1.5°. Residence time of the sludge in the first dryer is about time are very sensitive to the heating temperature, the entire
50 min. Sludge will become granules in the first dryer. drying process is divided into three stages: warm-up phase
Therefore, chain hammers are not needed in the second (I), constant-rate drying phase (II), and falling-rate drying
dryer. The second dryer is 2.0 m in diameter and 20 m in phase (III). This is because thermal drying sludge is actually
length. Its inclination angle is 1.5°. Because the granules an evaporation process driven by the heat input. In stage I,
are easier to move than the original mud-like sludge in the most of the input thermal energy is used to warm up the
first dryer, the residence time of the sludge in the second sludge and thus the evaporation process is relatively weak
dryer is about 30 min, less than that of the first dryer. but it quickly reaches its maximum strength as the tem-
Sludge granules from the second dryer with 40% water perature of the sludge increases. During stage II, the drying
content are transported into the product storage to cool rate reaches the maximum and is almost a constant for each
down for 1–2 days during which the water content further heating temperature because the energy consumed in
decreases to below 30% before the sludge is used for brick- evaporation process reaches a balance with the input ther-
making or co-incinerated with coal. mal energy in this stage. In stage III, the drying rate drops
continuously; more energy is needed to evaporate the same
amount of water than in stage II, because the capillary force
Results and discussion in sludge becomes significant and holds water more and
more tightly as water content decreases. Results show that
Drying rate of sludge the critical point is about 40% for the sludge in KSTP.
This is an important factor to consider for design an
The drying rate of sludge varies with heating time (Fig. 2b) optimal sludge drying system because stage II is the most
and sludge water content (Fig. 2a). Although the response important and efficient stage. Stages I?II take only about
57% of the total drying time but takes away 77.8% of the
total water evaporated. Therefore, ending the thermal dry-
ing process at the water content of 40% is the right choice.

Thermal stability of sludge

Figure 3 shows the differential scanning calorimetry–


thermal gravimetric analyzer (DSC–TGA) curve of sewage
sludge. The first endothermic peak, at 20–150°C, was
caused by evaporation of water from sludge companioning
with a weight loss of 10.31%. From 150°C to about 560°C,
there was an obvious exothermic peak resulting from
organic matter decomposition and combustion. The results
imply that it is important to keep the sludge temperature
during drying processes below 150°C in order to conserve
the organic matter in the sludge. Previous studies indicate
that the sludge temperature during constant-rate drying
stage equals to the wet-bulb temperature (Vaxelaire et al.
2001; Kudra and Mujumdar 2009). Therefore, the system
was specifically designed in KSTP to keep the wet-bulb
temperature between 90°C (inlet) and 65°C (outlet). Thus,
most of the organic matter remained in sludge.

Efficiency of thermal drying

Figure 4 shows the percentage of water removed during


different sludge processing stages in KSTP. Most of the
water was removed during thermal drying stage. Mass and
energy balances of the two dryers are shown in Fig. 5.
Fig. 2 Change of drying speed with water content and drying time.
There were three stages during sludge thermal drying, i.e. warm-up Drying efficiency is defined as the ratio of the latent heat
stage (I), constant-rate stage (II), and falling-rate stage (III) loss (i.e., the energy used for evaporation) over the total

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Fig. 3 DSC–TGA curve of sewage sludge. Thermogravimetric


analysis of the air-dried sludge granules was performed using a
SDTQ600 instrument (heating rate of 10°C/min, air stream) to study
the thermal stability of sewage sludge

Fig. 4 Water evaporated in each stage in KSTP

heat input from flue gas. Drying efficiency of the first dryer Fig. 5 Material and energy balance of the two dryers in KSTP.
was 81.2% and the second dryer was 85.4%. The higher M weight of sludge, t temperature of sludge, V flow of flue gas,
efficiency of the second dryer is due to the higher sludge T temperature of flue gas, QInput energy released from flue gas
temperature at its inlet (65°C) than that of the first dryer
(20°C). In the first dryer, sludge was heated from 20 to Properties of coal and dried sludge are shown in
65°C whereas in the second dryer, the sludge was heated Table 1. The dried sludge has more ash and volatile con-
from 65 to 80°C. As a result, about 6.4% of the input tent and lower calorific value than the coal, which is a
energy was consumed in increasing sludge temperature in disadvantage for the combustion purpose (Jayanti et al.
the first dryer whereas only 2.2% was consumed for the 2007; Yao et al. 2008). To minimize the effect on CFB
same purpose because of less temperature increase and operation, 11.4 tons of sludge, equivalent to 5% of daily
smaller heat capacity of the sludge due to water loss in the consumption of coal in CFB, was mixed with coal to
second dryer. incinerate.
The dry sludge granules were mixed with clay
Reuse of the dried sludge granules (10:90–15:85) to make bricks (Weng and Cai 1998). The
sludge-added bricks are lighter (8.51–10.14%) and stronger
The dried sludge granules were either co-incinerated in than the conventional bricks (Table 2) because organic
CFB with coal or transported to a local brick plant as raw matter in sludge burnt and round cavities formed in bricks
material for brick making. during production.

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Table 1 Industrial analysis of coal and sludge


Wc (%) Ash (%) C (%) H (%) O (%) N (%) S (%) Volatile (%) Low calorific
value (kJ kg-1)

Coal 6.9 22.80 62.84 4.32 8.18 1.14 0.71 38.52 22,588
Sludge 30 51.75 24.35 3.59 20.11 3.05 1.14 44.05 9,062

Table 2 Capacity testing results of sludge brick


Sludge addition Number of samples Average anti-press Single least anti-press Weight Average Lighten
proportion (piece) strength (MPa) strength (MPa) range (g) weight (g) rate (%)

Common 10 14.72 9.81 2,060–2,350 2,269 –


10% 10 16.4 12.05 2,030–2,090 2,076 10.14
15% 10 15.6 11.4 2,010–2,085 2,039 8.51

Odor and exhaust gas treatment the demonstration project in KSTP, about 1.63 9 108 kJ
energy (sum of QInput of two dryers in Fig. 5), was recovered
In the sludge processing system implemented in KSTP, from flue gas each day, equivalent to save 7.22 tons of coal
both the wet sludge storage and the product storage were burnt (low calorific value of coal is 22,588 kJ kg-1). In
sealed. Air with odor was drawn to CFB as a part of the addition, heat generated by these sludge granules (low cal-
combustion air so that the odor was eliminated at high orific value of coal is 9,062 kJ kg-1) was equal to 12.62 tons
temperature. of coal. Therefore, the new technique could reduce 19.82
Exhaust gas from dryers was returned to mix with the tons of coal combustion every day, equal to a reduction of
original flue gas and treated in flue gas cleaning facility in 16,440 tons CO2 emission per year (the carbon content of
power plant, where the odor and other emission components coal is 62.84%), for a plant like KSTP.
were removed. The flue gas volume was huge enough to
dilute the moisture and odor released from sludge drying.
There was only 14.24 g moisture in a cubic meter of flue gas. Conclusion

Economic analysis During thermal sludge drying, constant-rate drying phase is


the most important and efficient stage. Therefore, sludge
The capital cost of KSTP was about $1,500,000, including should be thermally dried at the constant-rate drying phase
building and equipment. In other words, the capital cost of to maximize energy utilization efficiency. For the sludge
KSTP was about $69,000 per dry ton/day. Historical cost found in KSTP, the critical moisture content is 40% below
data in elsewhere are $220,000 to $300,000 per dry ton/day which the drying rate dropped rapidly.
(Sapienza et al. 2004). The operating and maintenance Low temperature drying (below 150°C) is necessary to
(O&M) costs of KSTP, including costs for power, opera- conserve the organic matter in dried sludge based on
tions, maintenance materials and labor, were about $75/dry studies on the thermal stability of sludge. Such dried sludge
ton of sludge, while in elsewhere are from $180 to $300/ could either be co-incinerated with coal or used as raw
dry ton (Sapienza et al. 2004). That is because O&M costs material in brick making.
are highly dependent on the cost of energy source, which A new technique for thermal drying sludge using flue
can account for 25–55% of the total O&M cost (Sapienza gas from TPPs (a free heat source) has been developed and
et al. 2004). In KSTP, energy source was free, so total successfully implemented at KSTP. The case of KSTP
O&M cost was very low. demonstrated that the new sludge processing system was
effective both environmentally and economically. It
Reduction of CO2 emission reduced the direct drying cost by 80% and generated
reusable sludge granules which could be used either to co-
The new technique implemented at KSTP used energy from incinerate with coal as new fuel or to mix with clay to
flue gas, which would otherwise be wasted, to dry the sludge. make better bricks. For a plant with similar scale of KSTP,
The technique not only saved fuel in drying, but also pro- the new sludge processing system could result in annual
duced dried sludge that can be reused as energy resource. In CO2 emission reduction of 16,440 tons.

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Acknowledgments This research was supported by Major High Stasta P, Boran J, Bebar L, Stehlik P, Oral J (2006) Thermal
Technology & Development Program of Zhejiang Province (No. processing of sewage sludge. Appl Therm Eng 26:1420–1426
2005C13005) and Key Science & Research Program of Zhejiang Taib MR, Ali KW, Tan KG, Tan CH, Kumoro AC (2001)
Province (No. 2005C23051). Comparison of sludge drying performance between microwave
and convective drying. In: 15th symposium of Malaysian
Chemical Engineer, Johor Bahru, Malaysia
U.S. Environmental Protection Agency (2006) Emerging technologies
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