ARIF RAZA GROUP COACHING

0334 36 53 937
𝑵𝑨𝑴𝑬: −
Date:- 02nd April, 2019,
GRAND TEST 𝑻𝒊𝒎𝒆: − 𝟎𝟒: 𝟎𝟎 𝑷𝑴 − 𝟕: 𝟎𝟎 𝑷𝑴
Tuesday
𝑴𝒂𝒙. 𝑴𝒂𝒓𝒌𝒔: − 𝟖𝟓 Chemistry XI 𝑴𝒂𝒓𝒌𝒔 𝑶𝒃𝒕𝒂𝒊𝒏𝒆𝒅: −

𝐴𝑅𝐼𝐹 𝑅𝐴𝑍𝐴 𝐺𝑅𝑂𝑈𝑃 𝐶𝑂𝐴𝐶𝐻𝐼𝑁𝐺, 0334 − 36 53 937 𝑷𝒓𝒆𝒑𝒂𝒓𝒆𝒅 𝑩𝒚: −𝑺𝒚𝒆𝒅 𝑴𝒖𝒉𝒂𝒎𝒎𝒂𝒅 𝑯𝒂𝒊𝒅𝒆𝒓 𝒁𝒂𝒊𝒅𝒊
SECTION “A”
(MULTIPLE CHOICE QUESTIONS)
1. Choose the correct answer for each from the given options:- (𝟏𝟕)
(i) Which of the following number has zero as significant number?
* 0.000321 * 321000 * 321.000 * 3.21 × 10−4
(ii) 𝟒. 𝟎 𝒈 of 𝑵𝒂𝑶𝑯 have ___ number of 𝑵𝒂𝑶𝑯 molecules.
* 6.02 × 1022 * 6.02 × 1023 * 6.02 × 1021 * 6.02 × 1024
(iii) ___ has the highest rate of diffusion.
* 𝐶𝑙2 * 𝐶𝐻4 * 𝐶𝑂2 * 𝐻2 𝑆
(iv) 𝑶𝒏𝒆 𝒄𝒎𝟑 is equal to ___.
* 10−3 𝑑𝑚3 * 100 𝑑𝑚3 * 1000 𝑑𝑚3 * 10 𝑑𝑚3
(v) If 𝒂 = 𝒃 = 𝒄 and 𝜶 = 𝜷 = 𝜸 = 𝟗𝟎°, the crystal structure is ___.
* Cubic * Tetragonal * Orthorhombic * Triclinic
(vi) When an electron moves from an inner orbit to higher orbit, energy is ___.
* Emitted * Absorbed * Zero * Not changed
(vii) The quantum numbers 𝒏 = 𝟐 and 𝒍 = 𝟏 represents orbital ___.
* 2𝑠 * 2𝑝 * 2𝑑 * 1𝑠
(viii) Radius of an anion compared with the radius of its neutral atom is ___.
* Same * Smaller * Greater * Two times
(ix) The angular momentum of the electron in an orbit is equal to ___.
𝑛ℎ 𝑛ℎ 𝑛ℎ 𝑛ℎ
∗ ∗ ∗ ∗
𝜋 2𝜋 3𝜋 4𝜋
(x) The structure of water is ___.
* Linear * Angular * Tetrahedral * Pyramidal
(xi) In ethene (𝑪𝟐 𝑯𝟒 ) molecule, there are ___ bonds.
* 5𝜎, 1𝜋 * 6𝜎 * 4𝜎, 2𝜋 * 6𝜋
(xii) ___ is a/an intensive property.
* Enthalpy * Pressure * Entropy * Internal energy
(xiii) 𝜟𝑯 is always – 𝒗𝒆 in ___.
* Formation * Combustion * Decomposition * Evaporation
(xiv) When 𝑵𝒂𝑪𝒍 is added to a solution of 𝑨𝒈𝑪𝒍, the solubility of 𝑨𝒈𝑪𝒍 is ___.
* Increased * Decreased * No change * Reversed
(xv) In the reaction 𝟐𝑺𝑶𝟐 + 𝑶𝟐 → 𝟐𝑺𝑶𝟑 , ___.
* 𝐾𝑝 > 𝐾𝑐 * 𝐾𝑝 < 𝐾𝑐 * 𝐾𝑝 = 𝐾𝑐 * 𝐾𝑝 = 𝐾𝑠𝑝
(xvi) What is the 𝒑𝑶𝑯 of a solution whose 𝒑𝑯 is 8?
* 6 * 10 * 4 * 2
(xvii) ___ reactions have high value of activation energy.
* Fast * Slow * Ionic * Very fast
 ARIF RAZA GROUP COACHING
0334 36 53 937
SECTION “B” (Short−Answer Questions)
Note:- Attempt any TEN questions from this section. All questions carry equal marks.
𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔𝒆𝒔: = − 𝑯 = 𝟏, 𝑪 = 𝟏𝟐, 𝑵 = 𝟏𝟒, 𝑶 = 𝟏𝟔, 𝑪𝒍 = 𝟑𝟓. 𝟓, 𝒁𝒏 = 𝟔𝟓, 𝑨𝒈 = 𝟏𝟎𝟕. 𝟖 (𝟒𝟎)

2. (i) Define the following terms:-

* Significant figure * Avogadro’s Number
* Unit cell * Latent heat of fusion
(ii) An organic compound contains 𝑪 = 𝟓𝟏. 𝟖𝟎 %, 𝑯 = 𝟏𝟑. 𝟏𝟐 % and 𝑶 = 𝟑𝟓. 𝟎𝟖 %.
Determine the empirical formula of the compound.
(iii) 𝟑𝟖𝟎. 𝟎 𝒄𝒎𝟑 of Hydrogen gas was collected over water at 𝟐𝟑 °𝑪 and 𝟔𝟏𝟑 𝒕𝒐𝒓𝒓. Find the
volume of dry Hydrogen at 𝑺. 𝑻. 𝑷.(Vapour pressure of 𝑯𝟐 𝑶 at 𝟐𝟑 °𝑪 = 𝟐𝟏 𝒕𝒐𝒓𝒓)
(iv) What is the density of methane gas at 𝟏𝟐𝟕 °𝑪 and 𝟑. 𝟓 𝒂𝒕𝒎𝒐𝒔𝒑𝒉𝒆𝒓𝒆?
(v) Give scientific reasons for the following:-
* Explain why a drop of ink spread on blotting paper?
* Boiling point of liquid remains constant although heat is continuously supplied
to liquid. Why?
* Water spilled on a floor evaporate more rapidly than same amount of water in a
glass. Why?
* 𝒔 − 𝒔 sigma bond is weaker than 𝒔 − 𝒑 sigma bond. Why?
(vi) (a) Explain Heisenberg Uncertainty principle.
(b) Write the electronic configuration of the following:-
* 𝑪𝒓 (𝒁 = 𝟐𝟒) * 𝑪𝒖 (𝒁 = 𝟐𝟗)
(vii) (a) State Hess’s law of heat summation, explain it with an example.
(b) A system absorb 𝟐𝟎𝟎 𝑱 of heat from the surrounding and does 𝟏𝟐𝟎 𝑱 of work on
the surrounding by expansion. Find the internal energy change of the system?
(viii) Write the postulates of kinetic molecular theory of gases.
(ix) The solubility product of 𝑨𝒈𝑪𝒍 is 𝟗. 𝟔 × 𝟏𝟎−𝟏𝟏 𝒎𝒐𝒍𝟐 . 𝒅𝒎−𝟔 at 𝟐𝟓 °𝑪, Calculate the
solubility of 𝑨𝒈𝑪𝒍 in 𝒈/𝒅𝒎𝟑 .
(x) State Le−Chatelier principle. Give its application in the manufacture of 𝑵𝑯𝟑 .
(xi) Define electrode potential? How electrode potential of 𝒁𝒏 can be determined?
(xii) Differentiate the following:- (Any TWO)
* Endothermic and exothermic reactions * Hydration and hydrolysis
* Intensive and extensive properties * Molarity and molality
* Isomorphism and Polymorphism
* Crystalline and Amorphous solids
(xiii) Find the oxidation no. of the following.
(a) 𝑺 in 𝑵𝒂𝟐 𝑺𝟐 𝑶𝟑 (b) 𝑪𝒍 in 𝑴𝒈(𝑪𝒍𝑶𝟒 )𝟐 (c) 𝑪𝒓 in 𝑪𝒓𝟐 𝑶−𝟐
𝟕 (d) 𝑵 in 𝑵𝑯+
𝟒

(xiv) Calculate heat of formation of 𝑵𝟐 𝑶𝟒 from the given data.

𝟐𝑵𝑶𝟐 (𝒈) → 𝑵𝟐 𝑶𝟒 (𝒈) 𝜟𝑯𝒇 =?
𝟏
𝑵 + 𝑶𝟐 (𝒈) → 𝑵𝑶𝟐 (𝒈) 𝜟𝑯𝒇 = 𝟔𝟕. 𝟗 𝒌𝑱/𝒎𝒐𝒍
𝟐 𝟐 (𝒈)
 ARIF RAZA GROUP COACHING
0334 36 53 937
𝑵𝟐 (𝒈) + 𝟐𝑶𝟐 (𝒈) → 𝑵𝟐 𝑶𝟒 (𝒈) 𝜟𝑯𝒇 = 𝟗. 𝟑 𝒌𝑱/𝒎𝒐𝒍

(xv) Find the order of reaction from the following data:-

𝑲 = [𝑵𝑶] [𝑶𝟐 ]

# [𝑵𝑶](𝑴) [𝑶𝟐 ](𝑴) Rate(𝒎𝒐𝒍/. 𝒔𝒆𝒄)

1 0.1 0.1 2 × 10−3
2 0.2 0.1 8 × 10−3
3 0.1 0.2 4 × 10−3

SECTION “C” (Detailed−Answer Questions)

Note:- Attempt any TWO questions from this section. All questions carry equal marks.
(𝟐𝟖)
3. (a) Give the experimental evidence for the presence of very small positively charged
nucleus containing most of the mass of the atom. Also discuss the weakness of this
atomic model. (𝟎𝟔)
(b) Balance any one of the following equations by ion−electron method. (𝟎𝟒)
* 𝑴𝒏𝑶−
𝟒 + 𝑰𝟐 → 𝑴𝒏
+𝟐
+ 𝑰𝑶−
𝟑 (Acidic)
−𝟐
* 𝑪𝒓(𝑶𝑯)𝟑 + 𝑺𝑶−𝟐 −𝟐
𝟒 → 𝑪𝒓𝑶𝟒 + 𝑺𝑶𝟑 (Basic)
(c) 𝟏𝟗. 𝟔 𝒈 of 𝑯𝑪𝒍 is dissolved in 𝟐𝟓𝟎 𝒄𝒎𝟑 water to make a solution. What mass of 𝑵𝒂𝑯𝑪𝑶𝟑
should be dissolved in 𝟓𝟎𝟎 𝒄𝒎𝟑 of water to prepare the solution of the same molarity
as that of 𝑯𝑪𝒍. (𝟎𝟒)
4. (a) Write the postulates of electron pair repulsion theory. Discuss the structure of 𝑵𝑯𝟑 and
𝑩𝑭𝟑 molecules on the basis of EPRT. (𝟎𝟔)
(b) Explain Dipole moment and mention its unit. Explain why 𝑪𝑶𝟐 does not have dipole
moment? Whereas 𝑯𝟐 𝑶 has some dipole moment. (𝟎𝟒)
(c) How were X−ray originated? How did Mosley relate the wavelength of X−rays with
atomic number? (𝟎𝟒)
5. (a) Define Solubility and Solubility Product. Write solubility product 𝑲𝒔𝒑 expressions of the
following sparingly soluble salts along with their units:- (𝟎𝟒)
* 𝑪𝒂𝑪𝑶𝟑 * 𝑴𝒈(𝑶𝑯)𝟐
(b) Explain Arrhenius theory of ionization and also define degree of ionization. (𝟎𝟔)
73 × 352 × 7.0
(𝒄) 𝑈𝑠𝑖𝑛𝑔 𝒔𝒊𝒈𝒏𝒊𝒇𝒊𝒄𝒂𝒏𝒕 𝒇𝒊𝒈𝒖𝒓𝒆 𝒓𝒖𝒍𝒆𝒔, 𝑠𝑖𝑚𝑝𝑙𝑖𝑓𝑦: − (𝟎𝟒)
543 × 385

GOOD LUCK
NEW SESSION CLASSES IX, X, XI, XII
COMMENCING FROM
15TH JULY, 2019. INSHALLAH