Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
2. Let f : R → 0, defined by f(x) = tan–1 (x2 + x +), then the set of values of for which f is onto, is
2
1
A. [0, ) B. [-2, 1] C. , D. none of these
4
3. Let f : 0, 3 → 0,
+ loge2 defined by f ( x ) = log e x 2 + 1 + tan −1 x then f ( x ) is
3
A. one – one and onto B. one – one but not onto
C. onto but not one – one D. neither one – one nor onto
x −1 1
4. The set of values of so that f(x) =
− x2 +1
does not take any value in the interval −1, − 3 is
1 1 1
A. −, − B. [2, ) C. − , 2 D. −, − [2, )
4 4 4
5. Let f(x) = cos([x]), (where []represents the greatest integer function)
A. f(x) is periodic having no fundamental period
B. f(x) is periodic with period 1
C. f(x) is periodic with period 2
D. f(x) is non periodic
−1, x0
6. Let g ( x ) = 1 + x − x ,where [ . ] is greatest integer function and f ( x ) = 0 , x=0
1 , x0
Then for all x,f ( g ( x ) ) is equal to
A. x B. 1 C. f ( x ) D. g ( x )
9e
4
A. f ( x ) dx = In 4
3
C. f ( 2 ) + f ( 3) = 5 D. f ( 2 ) + f ( 3) = 6
Paragraph - I
The Solution of two Curves Can be obtained graphically by the point of intersection of two curves.
11. The no. of solution of | 2 − x − 1 |=| log | x ||
A. 1 B. 3 C. 4 D. 5
12. Find the no. of solution of min {| x |,| x − 1|,| x + 1|} = 1 − x2 for −1 x 1 .
A. 1 B. 2 C. 3 D. No solution exists
Paragraph – II
Let f be a real valued function with domain D, a subset of R. Then f is continuous at a point x0 D , if for
every sequence ( xn ) in ‘D’ tending to x0, we have Lt f ( xn ) = f ( x0 ) . This concept is equivalent to the
n →
concept of Lt f ( x ) = f ( x0 )
x → x0
( x 2 ) + f
x
f : R → R is a continuous function satisfying the relation f ( x ) − 2 f = x and f ( 0 ) = 0 .
2
4
Answer questions 17 to 19
13. The curve y = f ( x ) represents a conic, which is
A. Parabola B. ellipse C. hyperbola D. rectangular hyperbola
14. The length of the latus rectum is
4 8 9
A. B. C. D. 8
9 9 16
17. The number of elements in the range of the function f : (−,1) → R ,defined by
f ( x ) = 9 x − 3x + 1 , where [.] is the greatest integer function, is
4. A 150ml of solution of I 2 is divided into two unequal parts. Part – I reacts with hypo solution in acidic
medium where 15ml of 0.4M hypo was consumed. Part – 2 was added to 100ml of 0.3M hot and conc.
NaOH solution. Residual base required 10ml of 0.3M H SO solution for complete neutralization. What
2 4
was the initial concentration of I 2 .
A. 0.08 M B. 0.1 M C. 0.2M D. 0.04M
5. The density of 3M sodium thiosulphate is 1.25 g.ml-1 Identify the correct statements among the following.
A. % by wt of Na2S2O3 is 3.792
B. The mole fraction of Na2SO3 is 0.65
C. The molality of Na+ is 2.53
D. The molality of S2 O32− is 1.25
6. 7.35 g of a dibasic acid was dissolved is water and diluted to 250 ml. 25 ml of this solution was neutralised
by 15 ml of N NaOH solution. The molecular weight of the acid will be.
A. 49 B. 98 C. 35 D. 50.
Paragraph – I
In an experiment, one litre of an acidified solution of KMnO4 containing 15.8 gm of KMnO4 is decolourized
by passing sufficient amount of SO2.
KMnO4 + H+ + SO2 ⎯⎯
→Mn2+ + SO24− ...(i)
It is given that SO2 is produced by roasting of iron pyrites (FeS2)
FeS2 + O2 ⎯⎯
→Fe2O3 + SO2 ... (ii)
11. Amount of FeS2 required to produce the necessary SO2 is
A. 15 g B. 30 g C. 9.5 g D. 14 g
12. Equivalent weight of FeS2 is equal to its
A. molecular weight B. molecular weight/6
C. molecular weight/11 D. molecular weight/10
Paragraph – II
Oleum is considered as a solution of SO3 in H2SO4, which is obtained by passing SO3 in solution of H2SO4.
When 100 g sample of oleum is diluted with desired weight of H2O then the total mass of H2SO4 obtained
after dilution is known as % labeling in oleum. For example, a oleum bottle labeled as ‘109% H 2SO4’
means the 109 g total mass of pure H2SO4 will be formed when 100 g of oleum is diluted by 9 g of H2O
which combines with all the free SO3 present in oleum to form H2SO4 as SO3 + H2O ⎯⎯→H2SO4 .
(Moderate)
13. If excess water is added into a bottle sample labelled as “112% H2SO4” and is reacted with 5.3 g Na2CO3,
then find the volume of CO2 evolved at 1 atm pressure and 300 K temperature after the completion of the
reaction:
A. 1.46 L B. 24.6 L C. 1.23 L D. 12.3 L
14. 1 g of oleum sample is diluted with water. The solution required 54 mL of 0.4 N NaOH for complete
neutralization. The % of free SO3 in the sample is:
A. 74 B. 26 C. 20 D. None of these
(A) A (P) 5
(B) B (Q) 10
(C) C (R) 7
(D) D (S) 3
A. A-R, B-S, C-P, D-Q B. A-S, B-R, C-Q, D-P
C. A-P, B-Q, C-S, D-R D. A-Q, B-P, C-R, D-S
16. If one third mole of aluminium permanganate oxidizes 1.67 moles of M x+ as per the given reaction then
1
the value of x in the metal ion is MnO−4 + M x+ ⎯⎯
→ Mn 2+ + MO3− + O 2
2
17. A 25 ml portion of a phosphate mixture (NaH2PO4 & H3 PO4) requires 10.87 ml of 0.1 N NaOH for methyl
orange end point, another 25 ml portion requires 46.43 ml of 0.1 N NaOH for titration to the
phenolpthalein end point. Then ten times of molar concentration of NaH2 PO4 will approximately be
18. 4.35 g of a mixture of NaCl and Na2CO3 was dissolved in 100 ml of water, 20 ml of which was exactly
neutralized by 75.5 ml of N/10 solution of H2SO4. Hence the weight of Na2CO3 in the mixture is …………
gram
1
19. x M 100ml KMnO4 is first titrated with(acidic medium) M , 1L FeSO4 solution then It is treated with oxalic
2
acid, then it releases 224L of gas(which turns lime water milky) at 245.7 0C, later before losing its oxidizing
property completely. Find x
20. 26.8 g of Na2SO4.nH2O contains 12.6 g of water. The value of n is ………………….
m
M
M
mMg 2mMg 2mMg 2m 2 g
A. B. C. D.
2M + m 2M + m M +m 2M + m
2. A man is sitting in a cabin swinging from a frictionless pulley P as shown in figure. The rope attached with
cabin passes over the pulley and is held by the man. Total mass of the man and the cabin is 95 kg. The
man wants to pull the rope and rise upwards with an acceleration of 1.2 m/s 2. The correction option are:
(g =9.8 m/s2)
T
T
m1 m2
2kg 4kg
10
A. 10 m/s2 B. 5 m/s2 C. m/s2 D. zero
3
5. A block of mass m is resting on a wedge of mass M and inclination . Wedge is accelerated with a = g tan
as shown in figure. The acceleration of block with respect to wedge is (assume all surfaces to be smooth)
a m
M
A. zero B. 2g sin C. g sin (1 – tan) D. g sin (1 + tan)
6. A cylinder and a wedge each of mass m are touching each other. Both are free to move on smooth
inclined surfaces of two fixed inclined planes. The normal exerted by the wedge on the cylinder will be
fixed fixed
F
m2
m1
P5
P6
m A
m B
m C
A. the acceleration of block A is 2g upward
B. the acceleration of block B is 2g downward
C. the acceleration block C is zero
D. the acceleration of block C is g downward
10. A car has total mass 50 kg (including fuel). Gases are ejected backwards with a velocity 20 m/s with
respect to car. The rate of ejection of gas is 2 kg/s. If the mass of fuel is 20 kg and the car starts from rest.
If the coefficient of friction between car and road is = 0.1. Which of the following statements is/are
correct
4
( g = 10 m/s 2 and ln = 0.28 )
3
Paragraph - I
The forces acting on 1kg block in two different situations A and B are as shown in figure. All the coefficient of
friction values are given.
11. In figure A. the friction between blocks is
= 0.5
1 kg F= 10 N
2 kg (A)
=0
2 kg (B)
= 0.2
Paragraph – II
A train starts from rest at t = 0 along a straight track with a constant acceleration of 5 m/s2. A passenger
at rest in train observes a particle of mass 1 kg on the floor with which it has a co-efficient of friction s =
k = 0.6. At t = 4 s, a horizontal force F = 13 N is applied on the particle for 2 s duration. The passenger
observes that the particle is now moving in direction perpendicular to the motion of the train. (g = 10
m/s2)
13. The direction in which force (F = 13 N) is applied is at
A. 90° with the direction of motion of the train
5
B. cos −1 with the direction of motion of the train
13
5
C. cos −1 with the direction of motion of the train
12
12
D. cos −1 with the direction of motion of the train
13
14. The magnitude of acceleration of the particle with respect to the ground at t = 5 sec is
A. 61 m/s2 B. 72 m/s2 C. 8 m/s2 D. 6 m/s2
Column-I Column-II
w
B. Acceleration is non-zero
II.
A. (I) − (A), (B), (D); (II) − (C); (III) − (A), (B); (IV) − (A), (B)
B. (I) − (C); (II) − (B); (III) − (C), (D); (IV) − (D), (C)
C. (I) − (D), (C); (II) − (A), (B); (III) − (C); (IV) − (D)
D. (I) − (B), (C); (II) − (A); (III) − (C); (IV) − (C)
B
A
C
17. A ball of mass 1 kg is at rest in position P by means of two light strings OP and RP. The string RP is now cut
and the ball swings to position Q. If = 45°. Find the ratio of tensions in the strings in positions OP (when
RP was not cut) and OQ (when RP was cut). Take g = 10 m/s2.
O
P
R Q
18. A block of mass 1 kg start moving at t = 0 with speed 2 m/s on rough horizontal surface with coefficient of
friction 0.2. A horizontal force F is applied in the same direction of velocity which varies with time shown
in figure (b). Find the speed of particle at t = 3s (g = 10 m/s2).
F
1 kg 2 m/s 2N
=0.2 t
1s 2s 3s
Figure (a) Figure (b)
19. Two blocks A and B of equal mass 3 kg each are connected over a massless pulley as shown in figure. The
block A is placed on a rough inclined plane of angle 30°. The coefficient of friction between block A and
inclined plane is 0.6. The friction force acting on the block A is
3kg
B A
= 0.6
30°
20. A block B is kept on an inclined plane. Another block A is inserted in a slot in the block B through a light
string. One end of the string is fixed to a support and other end of the string is attached to A. All the
surfaces are smooth. Masses of A and B are same. The acceleration of block B is found to be 4/n. Find
value of n. (sin37° = 3/5)
S
B
37°
1
Put y = –t t ,1
3
1
Hence we get, (–, – ]
4
5. C.
1, x [2n, 2n + 1)
Sol. f(x) = cos([x]) = . SO it is periodic with period 2.
−1, x [2n + 1, 2n + 2), n I
6. B.
Sol. g ( x ) = 1 + x − x = 1 + x 1
f (g ( x )) = 1 x R
7. ABCD
f(x) − 5
Sol. f(x + 1) = …(1)
f(x) − 3
Replacing x by (x − 1) we have
3f(x) − 5
f(x − 1) = …(2)
f(x) − 1
Using(2), we get
3f(x) − 5
3 −5
3f(x − 1) − 5 f(x) − 1 2f(x) − 5
f(x − 2) = = = …(4)
f(x − 1) − 1 3f(x) − 5 f(x) − 2
−1
f(x) − 1
- x- 1
y= 2
(-1,0)
12. B.
Sol.
y=x
y = −x +1
-1 1 y = x −1
(-1/2,1/2) (+1/2,1/2)
-1 1 y = 1 − x2
x 2 = −1( y − 1)
13. A.
x x x
Sol. f ( x ) − f = x2 + f − f 2
2 2 2
x x x x x x x 4
Replace x with , 2 , 3 ,....... n and add f ( x ) − f n +1 = f − f n+2 + x 2
2 2 2 2 2 2 2 3
Take limit as n →
x
2
4x
f ( x ) − f ( 0) = f − f ( 0) +
2 3
x 4x
2
f ( x) − f =
2 3
Repeating the same process as above
16 x 2
f ( x ) − f ( 0) =
9
16 x 2
f ( x) =
9
16 x 2
The curve is y = which is a parabola
9
14. C.
x x x
Sol. f ( x ) − f = x2 + f − f 2
2 2 2
x x x x x x x 4
Replace x with , 2 , 3 ,....... n and add f ( x ) − f n +1 = f − f n+2 + x 2
2 2 2 2 2 2 2 3
Take limit as n →
x
2
4x
f ( x ) − f ( 0) = f − f ( 0) +
2 3
x 4x
2
f ( x) − f =
2 3
Repeating the same process as above
16 x 2
f ( x ) − f ( 0) =
9
16 x 2
f ( x) =
9
16 x 2
The curve is y = which is a parabola
9
15. A
Sol. P. x 2 − 1 + sin x = x 2 − 1 + sin x
( a + b = a + b ) only if (ab 0)
( x − 1)( x + 1) sin x 0.
x − 7x + 13 1 and x 2 − 7x + 13 0
2
2
7 3
x 2 − 7x + 13 0 x − + 0
2 4
which is true for all x R
again x 2 − 7x + 13 1 x 2 − 7x + 12 0
( x − 3)( x − 4 ) 0
3 x 4
thus Df is (3,4)
R. since 10x + 10y = 10
10y = 10 −10x y = log10 (10 − 10 x )
S. Here x 0, 0 sin x 1
2
again log a x b x a b , if 0 a 1 and x a b if a >1
1
Thus f ( x ) = exists
− logsin x tan x
if − logsin x tan x 0
logsin x tan x 0
tan x ( sin x ) = 1
0
tan x 1
x , x 0,
4 2 2
reqd. sol. is x ,
4 2
16. 18.
SOL. THE MAXIMUM POSSIBLE VALUES IS 2
sin ( x / 3 ) TAKES THE VALUES 1 WHEN
x / 3 = 2n + / 2
I.E x / 3 = 90 + 360 m
sin ( x /11) TAKES THE VALUE 1
WHEN x /11 = 2n + / 2
I.E x /11 = 90 + 360n
WE ARE LOOKING FOR A COMMON SOLUTION
WE HAVE 3m − 11n = 2. THEN SMALLEST POSITIVE SOLUTION TO THIS IS m = 8, n = 2, THUS x0 = 89100 ,
GIVING = 8910 .
17. 7
Sol. Put 3x = t . Then 3x → 0 as x → − and 3x → 3 as x → 1
x ( −,1) → t ( 0,3)
2
1 3
g (t ) = t − t + 1 = t − +
2
2 4
3
0 t 3 g (t ) 7
4
No of elements in the range of g ( t ) is 7
18. 5
Sol. If i is odd, then only fi(x) is bijective.
19. 4
Sol. log2x + logx2 = 5/2 = log2y + logy2
1 5 1 5
t+ = , s + = where t = log2x,, s = log2y
t 2 s 2
t = 2, 1/2 & s = 2, 1/2 (as t s, x y)
t = 2 and s = 1/2 or t = 1/2 and s = 3
log2x = 2 and log2y = 1/2
x = 4 and y = 2
x+y- 2 =4+ 2 - 2 = 4.
20. 5
Sol. f(−2) < 0, f(−1) > 0, f(0) > 0, f(1) < 0, f(2) > 0.
Thus −2 < < −1, 0 < < 1, 1 < < 2 [] = −2, [] = 0, [] = 1
Hence the required quantity is 5.
Stoichiometry
1. A.
Sol. No. of moles of H2SO4 left = 0.004 – 0.002 = 0.002 = 2.0 10–3
Let the number of moles of C2H4 and C3H8 be x and y respectively. Using the formula
pV = nRT,
1 atm 0.820 L = (x + y) mol 0.082 L –atm K–1 mol–1 300 K
1
or x + y = . … (i)
30
Again 28x + 44y = 0.613 … (ii)
y
Solving, we get = 1.54
x
2. C.
32.0g
Sol. Molecular weight of X2Y3 = = 160g mol−1
0.2mol
92.8g
Molecular weight of X3Y4 = = 232g mol−1
0.4mol
Let atomic weight of X be a and that of Y be b. then 2a + 3b = 160 and 3a + 4b = 232.
Solving, we get
a = 56 and b = 16.
3. B.
112.0mL 46.0gmol−1
Sol. WNO2 = = 0.23g
22400mL mol−1
0.23 g
VNO2 , l = = 0.20 mL
1.15g mL−1
0.23
N = mN A = 6.02 1023 = 3.011021
46
4. B
Sol. I + 2Na S O → 2NaI + Na S O
2 2 2 3 2 4 6
Millimoles of Na 2S2O3 consumed = 6
Millimoles of I consumed = 3
2
3I + 6NaOH → 5NaI + NaIO + 3H O
2 3 2
30 − 6
Millimole of I reacts with NaOH = = 12
2 2
Total millimole of I 2 consumed in the reaction = 15
15
Initial concentration of I = = 0.1M
2 150
5 A.
%by.wt 10 d
Sol. M=
M.W
%bywt 10 1.25
3=
474
% by wt = 37.92
6. B.
Sol. Let the Eq. weight of the acid be E.
Eq. weight of acid = 7.35/E.
7.35 1000
m.e. of the acid = = 7350/E
E
7350
Now, 250 ml of the acid contains m.e
E
735
25 ml of the acid contains m.e
E
m.e of 25 ml of the acid = m.e. of NaOH
735
= 115, Eq.weight = 49
E
molecular weight = 2 49 = 98 .
7. ABCD
Sol. The balanced equation is
K 2Cr2O7 + 14HCl ⎯⎯
→ 2KCl + 2CrCl3 + 7H2O+ 3Cl2
294 g 1436.5 g 371g
96
Mass of K2Cr2O7 = 61.3 = 58.848g
100
30
Mass of HCl = 320 1.15 = 110.4g
100
Hence, K2Cr2O7 is limiting reagent.
Mass of Cl2 produced = 42.63 g
M
Also equivalent of K2Cr2O7 =
6
7M
Equivalent of HCl =
3
8. ABD
2 Fe3 + ( CN)6 + H 2O2 −1 + 2OH ⎯⎯
→ 2 Fe2 + ( CN)6 + 2H2O + O02
3− 4−
Sol.
H2O2 is oxidized to O2, hence it is a reducing agent.
The ion Fe ( CN)6
3−
gains one electron and changes into [Fe(CN)6]4−.
CN− ions undergoes neither oxidaition nor reduciton O.N. of hydrogen on both side is +1.
9. ABC
+7 +1 +2 0
Sol. A. As evident from the reaction, Zn is reducing both KMnO 4 and H 2 SO 4 to MnSO 4 and H 2
respectively.
Equivalents of Zn = Equivalent of KMnO4 + Equivalents of H2SO4.
B. 2CrI3 + 64KOH + 27Cl2 ⎯→ 2K2CrO4 + 54KCl + 6KIO4 + 32H2O
+3 +2–3 +4 +5
C. [Fe(CN)6]3– ⎯→ Fe3+ + CO2 + NO3−
O.N. increases by 2
+2 +4
[Fe(CN)6]3– ⎯→ Fe3+ + CO2 + 12e–
O.N. increases by 8
–3 +5
[Fe(CN)6]3– ⎯→ NO 3− + 48e–
No change in O.S.
+3
[Fe(CN)6]3– ⎯→ Fe3+
m
M
M
Considering free body diagram of block m only
mg − N = ma
mg
N = m( g − a) = m g −
2M + m
2mMg
N=
2M + m
2. A.
Sol. 2T − Mg = Ma
M ( g + a)
T= = 522.5 N
2
3. C.
Sol. At the top
mv 2
T + mg =
L
T 10mg
v 11gL
3 gL u 13 gL
4. B.
Sol. Pulley is ideal
F = 80N
T T
a1 a2
m1 m2
m1g m2g
=20N =40N
2T = 80 T = 40 N
40 − 20
a1 = = 10 m/s2 (upwards)
2
40 − 40
a2 = =0
4
If acceleration of m1 and m2 w.r.t. pulley is a0 and acceleration of pulley is a then,
a1 = a + a0 a + a0 = 10
a2 = a – a0 a = a0
a0 = 5 m/s2
5. B.
Sol. Drawing FBD of block m from the frame of wedge,
N
ma sin
a0
a=g tan m
ma
macos + mgsin
mg cos mg
9. ABC
Sol. Before cutting the spring, the FBD of each block is
3mg T= 2mg T = mg
A B C
mg T= 2mg mg T = mg mg
After cutting the spring, the FBD becomes
3mg T = mg
A B C
T = mg
mg mg mg
10. ABC
dm
Sol. The thrust force is Vrel
dt
Fth = 20 2 = 40 N car will start moving when
40 = (0.1)(50 – 2t) × 10
t = 5 sec
dv
When car starts moving (50 − 2t ) = −(0.1)(50 − 2t ) 10 + 40
dt
Velocities of car will be maximum when whole fuel is burnt i.e. at after time t = 10 sec
vmax 10 10
dt
dv = − dt + 40 50 − 2t
0 5 5
x v
v mg
mgR(1 − cos ) =
1 1
mv 2 − mv 2
2 2
2gR − 2gR cos = Rg cos − v 2
2gR + v 2
cos =
3gR
If = 0 cos = 1
3gR – 2gR = v2 v = gR
(I) − (A), (B), (D) ; (II) − (C) ; (III) − (A), (B) ; (IV) − (A), (B).
16. 13N
40 − 20 0
Sol. a= =
6 3
Also, 20 − T = 2a
40
T= = 13.33 13N
3
17. 2
mg
Sol. T1 = , T2 = mg cos
cos
T1
= sec 2 = 2
T2
18. 0
Sol. Friction force = 0.2 × 1 × 10 = 2 N
at t= 2s block comes to rest and then F < friction so speed at t = 3s is zero.
19. 15N
Sol. mBg = 30 N
N
3kg mB mA 3kg
T T
aB N
N
A
aB
Mgsin37° Mgcos37° Mgsin37° Mgcos37°
37° 37°
The equation of motion of A and B along the incline perpendicular to if are given by
Mg sin 37 − N = MaB …(i)
T − Mg cos 37 = MaA …(ii)
Mg sin 37 + N − T = MaB …(iii)
By constraint relation, aB = aA
From (i), (ii) and (iii),
4
aB = m/s 2
3
n=3