Exercise - IV: JEE Problems

CHEMICAL BONDING Page # 44
Exercise - IV JEE Problems

Only One Correct Answer
4. The geometry of H2S and its dipole moment are :
1. The geometry & the type of hybrid orbitals present [JEE '99]
about the central atom in BF3 is : [JEE '98]
(A) angular & non zero (B) angular & zero
(A) linear, sp (B) trigonal planar, sp2
(C) linear & non zero (D) linear & zero
(C) tetrahedra sp3 (D) pyramidal, sp3
Sol.
Sol.
5. In compounds type E Cl3, where E = B, P, As or Bi,

the angles Cl - E - Cl for different E are in the order
[JEE '99]
(A) B > P = As = Bi (B) B > P > As > Bi
(C) B < P = As = Bi (D) B < P < As < Bi
2. The correct order of increasing C – O bond length Sol.
of, CO, CO32–, CO2 is [JEE '99]
2– 2–
(A) CO3 < CO2 < CO (B) CO2 < CO3 < CO
(C) CO < CO32– < CO2 (D) CO < CO2 < CO32–
Sol.
6. The most likely representation of resonance

structure of p-nitrophenoxide is : [JEE '99]
–O O –O + O
N+ N
(A) (B)
3. In the dichromate anion [JEE'99]
(A) 4 Cr-O bonds are equivalent O– O
(B) 6 Cr-O bonds are equivalent –O
O O + O
(C) all Cr-O bonds are equivalent
N+ N
(D) all Cr-O bonds are non equivalent
Sol.
(C) (D)
O– O–
Sol.
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7. Amongst H2O, H2S, H2Se and H2 Te, the one with 11. Specify hybridization of N and B atoms in a 1 : 1
the highest boiling point is [JEE 2000] complex of BF3 and NH3 [JEE 2002]
(A) H2O because of hydrogen bonding (A) N : tetrahedral, sp ; B : tetrahedral, sp3
3
(B) H2 Te because of higher molecular weight (B) N : pyramidal, sp3; B: pyramidal, sp3
(C) H2S because of hydrogen bonding (C) N : pyramidal, sp3; B : planar sp2
(D) H2 Se because of lower molecular weight (D) N : pyramidal, sp3 ; B : tetrahedral, sp3
Sol. Sol.
8. The hybridization of atomic orbitals of nitrogen in

NO 2 , NO 3– and NH4 are [JEE 2000] 12. The nodal plane in the -bond of ethene is located
(A) sp2, sp3 and sp2 respectively in [JEE 2002]
(B) sp, sp2 and sp3 respectively (A) the molecular plane
(C) sp2, sp and sp3 respectively (B) a plane parallel to the molecular plane
(C) sp2, sp3 and sp respectively (C) a plane perpendicular to the molecular plane which
Sol. bisects, the carbon-carbon  bond at right angle.
(D) a plane perpendicular to the molecular plane which
contains, the carbon-carbon bond.
Sol.
9. The correct order of hybridization of the central

atom in the following species NH3, PtCl4–2, PCl5 and
BCl3 is [JEE 2001]
(A) dsp2, sp3d, sp2 and sp3 13. Identify the least stable ion amongst the following
(B) sp3, dsp2, sp3d, sp2 [JEE 2002]
(C) dsp2, sp2, sp3, sp3d (A) Li–
(B) Be–
(C) B–
(D) C–
(D) dsp2, sp3, sp2, sp3d Sol.
Sol.
14. Which of the following molecular species has

10. The common features among the species CN–, CO unpaired electron (s) ? [JEE 2002]
and NO+ are [JEE 2001] –
(A) N2 (B) F2 (C) O2 (D) O22–
(A) Bond order three and isoelectronic
Sol.
(B) Bond other three and weak field ligands
(C) Bond order two and -acceptors
(D) isoelectronic and weak field ligands
Sol.
15. Which of the following are isoelectronic and

isostructural ? NO3–, CO32–, ClO3–, SO3 [JEE 2003]
(A) NO 3– , CO 23 – (B) SO 3 ,NO 3–
(C) ClO 3– , CO 23– (D) CO 23– , SO 3
Sol.
16. According to molecular orbital theory which of the 20. The species having bond order different from that
following statement about the magnetic character and in CO is [JEE 2007]
– + –
bond order is correct regarding O2+ [JEE 2004] (A) NO (B) NO (C) CN (D) N2
(A) Paramagnetic and Bond order < O2 Sol.
(B) Paramagnetic and Bond order > O2
(C) Diamagnetic and Bond order < O2
(D) Diamagnetic and Bond order > O2
Sol.
21. The structure of XeO3 is [JEE 2007]

(A) linear (B) planar (C) pyramidal (D)T-shaped
Sol.
17. Which species has the maximum number of lone
pair of electrons on the central atom ? [JEE 2005]
(A) ClO 3– (B) XeF4 (C) SF4 (D) I3–

Sol.
22. Statement-1 : p-Hydroxybenzoic acid has a lower

boiling point than o-hydroxybenzoic acid.
Stat ement-2 : o- Hy dro xy be nzo ic ac id h as
intramolecular hydrogen bonding. [JEE 2007]
18. The percentage of p-character is the orbitals (A) Statement-1 is True, Statement-2 is True ;
forming P–P bonds in P4 is [JEE 2007] Statement-2 is a correct explanation for Statement-1
(A) 25 (B) 33 (C) 50 (D) 75 (B) Statement-1 is True, Statement-2 is True ;
Sol. Statement-2 is NOT a correct explanation for
Statement-1
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
Sol.
19. Among the following, the paramagnetic compound

is [JEE 2007]
(A) Na2O2 (B) O3 (C) N2O (D) KO2
Sol.
23. Statement-1 : In water, orthoboric acid behaves 26. The nitrogen oxide(s) that contain(s) N–N bond(s)
as a weak monobasic acid. is (are). [JEE 2009]
Statement-2 : In water, orthoboric acid acts as a (A) N2O (B) N2O3 (C) N2O4 (D) N2O5
proton donor. [JEE 2007] Sol.
(A) Statement-1 is True, Statement-2 is True ; Statement-
2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True ;
Statement-2 is NOT a correct explanation for
Statement-1
Sol.
27. In the reaction [JEE 2009]
+ –
2X + B2H6  [BH2(X)2] [BH4]
the amine(s) X is (are) :
(A) NH3 (B) CH3NH2 (C) (CH3)2NH (D) (CH3)3N
Sol.
24. Statement-1 : Pb4+ compounds are stronger

oxidizing agents than Sn4+ compounds. [JEE 2008]
Statement-2 : The higher oxidation states of group
14 elements are more stable for the heavier members
of the group due to 'inert pair effect'.
(A) Statement-1 is True, Statement-2 is True ; Statement-
2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True ;
28. The species having pyramidal shape is
Statement-2 is NOT a correct explanation for
[JEE 2010]
Statement-1
(A) SO3 (B) BrF3 (C) SiO32– (D) OSF2
Sol.
Sol.
25. Match each of the diatomic molecules in Column -

I with its property/ properties in Column-II. 29. Assuming that Hund's rule is violated, the bond
order and magnetic nature of the diatomic molecule
Column-I Column-II [JEE 2009]
B2 is [JEE 2010]
(A) B2 (P) Paramagnetic
(A) 1 and diamagnetic (B) 0 and diamagnetic
(B) N2 (Q) Undergoes oxidation
(C) 1 and paramagnetic (D) 0 and paramagnetic
(C) O2— (R) Undergoes reduction
Sol.
(D) O2 (S) Bond order 2
(T) Mixing of 's' and 'p' orbitals
Sol.
30. All the compounds listed in Column I react with 4. Explain why the dipolemoment of NH3 is more than
water. Match the result of the respective reactions that of NF3. [JEE' 95]
with the appropriate options listed in Column II. Sol.
Column-I Column-II [JEE 2010]
(A) (CH3)2SiCl2 (P) Hydrogen halide formation
(B) XeF4 (Q) Redox reaction
(C) Cl2 (R) Reacts with glass
(D) VCl5 (S) Polymerization
(T) O2 formation
Sol. 5. The experimentally determined N-F bond length in
NF3 is greater than the sum of single bond covalent
radii of N & F. Explain. [JEE'95]
Sol.
Explain the following

1. Give reason carbon oxygen bond lengths in formic 6. Explain the difference in the nature of bonding in
acid are 1.23 Å & 1.36Å and both the carbon oxygen LiF & LiI. [JEE'96]
bonds in sodium formate have the same value i.e. Sol.
1.27 Å [JEE' 88]
Sol.
7. Explain PCl5 is formed but NCl5 cannot.

[JEE' 97]
Sol.
2. Give reason that valency of oxygen is generally

two whereas sulphur shows of 2, 4 & 6. [JEE' 88]
Sol.
8. Give reasons for the following in one or two

sentences only. [JEE'99]
(a) BeCl2 can be easily hydrolyed
3. Explain the first I.E. of carbon atom is greater (b) CrO3 is an acid anhydride.
than that of boron atom whereas the reverse is true Sol.
for the second I.E. [JEE'89]
Sol.
9. Explain why o-hydroxybenzaldehyde is a liquid at 5. Increasing order of basic character : MgO, SrO,
room temperature, while p-hydroxybenzaldehyde is a K2O, NiO, Cs2O
high melting solid. [JEE' 99] Sol.
Sol.
Arrange as directed 6. Increasing strength of H-bonding. (X.........H–X)

1. N 2 , O 2, F 2 , Cl 2 in increasing order of bond O, S, F, Cl, N.
dissociation energy. [JEE' 88] Sol.
Sol.
7. Increasing order of extent of hydrolysis CCl4, MgCl2,

AlCl3, PCl5, SiCl4
2. CO2, N2O5, SiO2, SO3 is the increasing order of Sol.
acidic character. [JEE' 88]
Sol.
3. HOCl, HOClO2, HOClO3, HOClO in increasing order

of thermal stability. [JEE'88]
Sol. 8. Arrange in increasing order of dipole moment.
[JEE'96]
(I) Toluene, (II) m-dichcorobenzene
(III) O-dichlorobenzene (IV) P-dichlorobenzene.
Sol.
4. Increasing order of ionic size : N3–, Na+, F–, O2–,

Mg2+
Sol.
9. The decreasing order of acid strength of ClOH,

BrOH, IOH. [JEE'97]
Page # 50 CHEMICAL BONDING
Sol.
2. Based on VSEPR theory, the number of 90 degree

F – Br – F angles in BrF5 is [JEE 2010]
Sol.
10. Arrange in order of increasing radii, Li+, Mg2+, K+,

Al3+ [JEE'97]
Sol.
3. The value of n in the molecular formula BenAl2Si6O18

is [JEE 2010]
Sol.
11. Arrange BeSO4, MgSO4, CaSO4, SrSO4 in order of
decreasing thermal stability. [JEE'97]
Sol.
4. The total number of diprotic acids among the

following is [JEE 2010]
H3PO4 H2SO4 H3PO3 H2CO3 H2S2O7
H3BO3 H3PO2 H2CrO4 H2SO3
12. Decreasing order of the O–O bond length present Sol.
in them O2, KO2 and O2 [AsF4] [JEE 2004]
Sol.
5. Among the following, the number of elements

showing only one non-zero oxidation state is :
Subjective O, Cl, F, N, P, Sn, Tl, Na, Ti [JEE 2010]
1. The number of water molecule(s) directly bonded Sol.
to the metal centre in CuSO4.5H2O. is [JEE 2009]
Sol.
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Exercise - IV: JEE Problems

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CHEMICAL BONDING Page # 44

Exercise - IV JEE Problems

5. In compounds type E Cl3, where E = B, P, As or Bi,

6. The most likely representation of resonance

8. The hybridization of atomic orbitals of nitrogen in

9. The correct order of hybridization of the central

14. Which of the following molecular species has

15. Which of the following are isoelectronic and

(A) NO 3– , CO 23 – (B) SO 3 ,NO 3–

(C) ClO 3– , CO 23– (D) CO 23– , SO 3

21. The structure of XeO3 is [JEE 2007]

(A) ClO 3– (B) XeF4 (C) SF4 (D) I3–

22. Statement-1 : p-Hydroxybenzoic acid has a lower

19. Among the following, the paramagnetic compound

24. Statement-1 : Pb4+ compounds are stronger

25. Match each of the diatomic molecules in Column -

Explain the following

7. Explain PCl5 is formed but NCl5 cannot.

2. Give reason that valency of oxygen is generally

8. Give reasons for the following in one or two

Arrange as directed 6. Increasing strength of H-bonding. (X.........H–X)

7. Increasing order of extent of hydrolysis CCl4, MgCl2,

3. HOCl, HOClO2, HOClO3, HOClO in increasing order

4. Increasing order of ionic size : N3–, Na+, F–, O2–,

9. The decreasing order of acid strength of ClOH,

2. Based on VSEPR theory, the number of 90 degree

10. Arrange in order of increasing radii, Li+, Mg2+, K+,

3. The value of n in the molecular formula BenAl2Si6O18

4. The total number of diprotic acids among the

5. Among the following, the number of elements

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