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1. (3 pts) Indicate whether the following statements are TRUE or FALSE. Points
TRUE FALSE Propane has fewer carbon atoms than both heptane and butane.
TRUE FALSE Constitutional (structural) isomers of hydrocarbons have the same number of carbon atoms
and different number of hydrogen atoms.
2. (2 pts) Draw the bond-line representation (also called line structure) for CH2=CHCH=C(CH3)2
DRAW YOUR ANSWER IN THE “ANSWER” BOX.
ANSWER:
Points
# Correct /2
+½ point for using rules for bond-line structures correctly. This is a hydrocarbon - should consist only of lines!
+½ point for correct number of carbons drawn.
+½ point for correct connectivity between carbon atoms (sigma bond framework; placement of methyl group).
+½ point for double bonds being in the correct places (between C1 and C2, and between C3 and C4).
3. (4 pts) Which of the following molecules are constitutional isomers of the molecule at right?
CLEARLY CIRCLE THE MOLECULE(S) BELOW TO INDICATE YOUR ANSWER(S).
CH2=CHCH=CHCH2CH3
4. (2 pts) Open Response: What is the molecular formula of the following structure? Note: Give your answer in the form
of CxHyOz, where x, y, and z are integers.
WRITE YOUR ANSWER IN THE “ANSWER” BOX.
ANSWER: Points
ANSWER: Points
Cl
# Correct /2
C
Cl
Cl
Cl
+½ point for correct number of carbons and chlorines (and no other atoms) drawn.
+½ point for using rules for dash-wedge structures correctly. All atoms and bonds are shown.
+1 point for correct 3D representation – including bond angles! For example, the structures below would NOT
earn this point:
Cl Cl
Cl
Cl
Cl
C C C
Cl Cl Cl
Cl Cl Cl Cl
4. (7 pts) Open Response: A synthetic steroid is shown below; use this structure to answer the following questions.
WRITE EACH ANSWER IN THE BLANK PROVIDED.
O
d
e a
f
b
g. What orbitals are involved in forming the C-C bond at label f? What types of bond(s) are formed?
A s bond is formed between the sp2 orbitals of each carbon atom. A p bond is formed between the
unhybridized 2p orbitals of each carbon atom.
Points
+1 point for each correct answer.
No partial credit given for the individual parts of this problem. (Each provided answer is graded # Correct /7
as either right or wrong.) All of the highlighted phrases in the answer to 4.g are required in
student answers to be considered correct.