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TABLE OF CONTENT
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TABLE LIST
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PICTURE LIST
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CHAPTER I
INTRODUCTION
I. MODULE TITLE
DETERMINING SPECIFIC GRAVITY OF GAS AND SPECIFIC GRAVITY OF OIL
There are two gas laws that underlie this stage, namely Graham's effusion / diffusion
law and Avogadro's law. Both of these laws produce time that can be used to determine the
specific gravity of a gas sample.
Graham's diffusion / effusion law was discovered in 1830. In principle, this law states
that the flow of effusion and gas diffusion of two gases at the same temperature and pressure
will be inversely proportional to the square root of its density. Mathematically it can come out
with the equation:
V1 d2
V2 d1
V12 t2 2 M 2 d 2
V2 2 t12 M 1 d1
From the above equation it can be seen that gas specific gravity is defined as the ratio
of the molecular weight of the gas to the weight of the dry air molecule at the same pressure
and temperature.
In this experiment effusionometer was used. SG prices obtained from calculations
using experimental data data must be corrected for the following parameters:
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Dry vapor pressure, W (mmHg)
Space pressure, P (mmHg))
Average pressure, p (mmHg)
t
2
W t 2
SG 2 0.627
*
2 1
t1 P p W t1
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9. Stirring rod
10. Scales
11. Sample of crude oil
12. Water
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CHAPTER II
DATA PROCESSING
I. EXPERIMENTAL DATA
A. Specific Gravity of Gas
Measuring time
No Type of Gas Average of time (s)
t1 (s) t2 (s)
1. Dry Air 48 48 48
2. N2 50 50 50
3. CO2 44 44 44
Table 1 Experimental Data Flow Time of Each Type of Gas
W (mmHg) = 0.029
P (mmHg) = 760
p (mmHg) = 10
10
𝑣12 𝑡22 𝜌2 𝑀𝑟2
𝑆𝐺 = 2 = 2 = =
𝑣2 𝑡1 𝜌1 𝑀𝑟1
𝑘𝑔
𝜌𝑁2 = 𝑆𝐺𝑁2 × 𝜌𝑢𝑑𝑎𝑟𝑎 = 1.0851 × 1.225 = 1.32924 𝑘𝑔/𝑚3
𝑚3
2
𝜌𝐶𝑂2 𝑡𝐶𝑂 442
𝑆𝐺𝐶𝑂2 = = 2 2 = 2 = 0.84028
𝜌𝑢𝑑𝑎𝑟𝑎 𝑡𝑢𝑑𝑎𝑟𝑎 48
𝑘𝑔
𝜌𝐶𝑂2 = 𝑆𝐺𝐶𝑂2 × 𝜌𝑢𝑑𝑎𝑟𝑎 = 0.84028 × 1.225 3
= 1.029343 𝑘𝑔/𝑚3
𝑚
𝑊
𝑆𝐺𝑁∗ 2 = 𝑆𝐺𝑁2 + 0.627 × × (𝑆𝐺𝑁2 − 1)
𝑃+𝑝−𝑊
0.029
𝑆𝐺𝑁∗ 2 = 1.0851 + 0.627 × × (1.0851 − 1) = 1.08510201
760 + 10 − 0.029
∗
𝑊
𝑆𝐺𝐶𝑂 = 𝑆𝐺𝐶𝑂2 + 0.627 × × (𝑆𝐺𝐶𝑂2 − 1)
2
𝑃+𝑝−𝑊
∗
0.029
𝑆𝐺𝐶𝑂 = 0.84028 + 0.627 × × (0.84028 − 1) = 0.8402762282
2
760 + 10 − 0.029
∗
𝑆𝐺𝐶𝑂 − 𝑆𝐺𝐶𝑂2 0.8402762282 − 0.84028
𝑒𝑟𝑟𝑜𝑟 = 2
× 100% = × 100% = −4.488742 × 10−4 %
𝑆𝐺𝐶𝑂2 0.84028
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B. Specific Gravity of Oil
Determining Specific Gravity of Crude Oil by Using Hydrometer
Looking for Specific Gravity of formation water:
141.5
°𝐴𝑃𝐼 = − 131.5
𝛾
141.5 141.5
𝛾 𝑜𝑓 𝑓𝑜𝑟𝑚𝑎𝑡𝑖𝑜𝑛 𝑤𝑎𝑡𝑒𝑟 = = = 1.0064
°𝐴𝑃𝐼 + 131.5 9.1 + 131.5
Looking for Specific Gravity of crude oil (25.5°C):
141.5
°𝐴𝑃𝐼 = − 131.5
𝛾
141.5 141.5
𝛾 𝑜𝑓 𝑐𝑟𝑢𝑑𝑒 𝑜𝑖𝑙 (25.5℃) = = = 0.903576
°𝐴𝑃𝐼 + 131.5 25.1 + 131.5
Determining Specific Gravity of Crude Oil by Using Picnometer
Looking for volume of pycnometer :
𝑔𝑟
𝑎𝑠𝑠𝑢𝑚𝑒 ∶ 𝜌 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 = 1
𝑚𝑙
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟
𝜌 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 =
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑝𝑖𝑐𝑛𝑜𝑚𝑒𝑡𝑒𝑟
𝑚𝑎𝑠𝑠 26.19 𝑔𝑟
𝑣𝑜𝑙𝑢𝑚𝑒 𝑜𝑓 𝑝𝑖𝑐𝑛𝑜𝑚𝑒𝑡𝑒𝑟 = = = 26.19 𝑚𝑙
𝜌 1 𝑔𝑟/𝑚𝑙
0,9
Specific Gravity
0,895
0,89
0,885
0,88
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Temperature
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CHAPTER III
ANALYSIS
I. ASUMPTIONS
Constant Temperature is 60°F
Constant gravity is 9.8 m/s2
Density of water is 1 gr/ml
Density of gas is 1.225 kg/m3
Dry vapor pressure is 0.029 mmHg
Standard condition pressure 760 mmHg
Average pressure 10 mmHg
Molecular weight of dry air is 29 gr/mol
Gas compressor only consist of dry air
All tools in clean and good condition
There are no contamination in sample
The measurement of stopwatch stopped exactly when the air is touching the limit
II. ANALYSIS
A. Specific Gravity of Gas
1. Tools
All tools that has been used in this experiment is in a good condition. The
functions and working principle of the main tools in this experiment of measuring
specific gravity are :
Effusiometer
Effusiometer is a tool to measure specific gravity of gas by using effusion and
diffusion principle by Graham and Avogadro’s Law. This tools consist of
tubes and valves. Effusion and diffusion occur when there are two different
physical conditions and both are related. We can determine specific gravity
of gas in this experiment by comparing gas flow time of sample with dry air.
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Figure 4 Effusiometer
2. Practical Work
At the first of specific gravity of gas experiment, we all measure the dry air
flow time limit. We measure it as the reference data of specific gravity of dry air.
We measure twice to make sure that the flow time is correct. After that we do
bleed of effusiometer to make sure all of dry gas out from the pipe and ready to
use with another gas. My group are doing next experiment to measure the flow
time of N2 gas and CO2 gas. The gas enter the pipeline and the next enter the small
tube inside effusiometer until the tube full of gas sample. Then we stop supply gas
from gas source and close the valve above effusiometer. The last we open valve
above effusiometer and measure the flow time when water enter the small tube
again between two boundaries.
3. Result
According to the data analysis, I get the specific gravity of each gas those are
SG of N2 gas = 1.0851 and SG of CO2 gas = 0.84028. Beside that I get the density
each gas those are density of N2 gas = 1.32924 kg/m3 and density of CO2 gas =
1.029343 kg/m3. According Graham’s Law and Avogadro’s Law the specific
gravity and density of gas has correlation with their molecular weight, so when
the molecular weight is big so does the specific gravity because the molecular
weight is proportional to the density. Molecular weight of dry air that assume is
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29 gr/mol, molecular weight of N2 is 28 gr/mol, and molecular weight of CO2 is
44 gr/mol. But in this experiment data, the value is CO2 gas has small density and
specific gravity than N2 gas. This can be done because of many factors such as :
gas compressibility factor, bleed of process not clean the gas fully, the observation
less accuracy and many more. From this effusiometer experiment we can calculate
specific gravity not only with flow time value but also molecular weight to
compare the result.
B. Specific Gravity of Oil
1. Tools
All tools that has been used in this experiment is in a good condition. The
functions and working principle of the main tools in this experiment of measuring
specific gravity are :
Hydrometer
Hydrometer is a tool to measure specific gravity by using Archimedes
Principle and immersed itself into the sample to be measured. Hydrometer
shows °API scales and directly read parallel with the surface of the sample.
When we use hydrometer, we can count specific gravity faster than using
pycnometer because we just directly read scale and count it. Error in this
hydrometer is still acceptable.
Figure 6 Hydrometer
Pycnometer
Pycnometer is a tool to measure specific gravity by calculating mass of
sample and divided by the volume of sample itself. Then after we get the
density of the sample, we compare it with density of water as standard fluid.
We need more time to measure specific gravity of sample if we use
pycnometer because there are more steps to count it. We need to measure
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empty pycnometer, then fill it with sample, and after that we count its mass.
But before that we need to calibrate it with water.
Figure 7 Pycnometer
2. Practical Work
At the second experiment, my group calculate specific gravity by using
hydrometer. First of all we measure the formation specific gravity by filling the
measure cup and immersed the hydrometer until it stable vertically. After that we
read the °API scale and note it. After that we measure the crude oil specific gravity
at 25.5°C with the same procedure as before but we change the hydrometer
according to the sample that we want to measure (suitable scale).
At the third experiment, my group calculate specific gravity by using
pycnometer. First of all we calibrate the pycnometer volume by calculating the
mass of water and knowing that the density of water is 1 gr/ml. After we calibrate
the volume of pycnometer we note it to calculate the specific gravity of sample
that we want to measure. Then we measure crude oil density with the same
procedure and doing it twice with different temperature so we can compare the
effect of temperature to the specific gravity of crude oil.
3. Result
According to the data analysis, I get specific gravity of formation water =
1.0064 and specific gravity of crude oil at 25.5°C = 0.903576 by using
hydrometer. The bigger value of °API then smaller value of Specific Gravity
because it inversed proportional value. When we calculate the specific gravity of
sample we can get fast calculation by using hydrometer because we directly get
the °API.
According to the data analysis, I get specific gravity of crude oil with different
temperature, SG crude oil (26°C) = 0.90378 and SG crude oil (56°C) = 0.8896.
From the value that I get, when the temperature increase, the density will be
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decrease so does the specific gravity. This condition is affected by the fluid
expand but the mass still the same so the density is decrease. This condition can
be observed to by looking the graph at data analysis.
Different value of measuring specific gravity by using hydrometer and
pycnometer is normal because each tools has different accuracy but the error still
can be accepted.
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CHAPTER IV
CONCLUSIONS
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CHAPTER V
I. FOR ASISTANT
My first impression to both of assistant, Kak Susantry and Bang Irfan are all kind,
always smile, and little bit make me nervous because module one is my last module of
fluids reservoir class and I don’t want to be kicked in this module by assistant. Any other
my problem is my last module is using English when we have an experiment. I’m scared
that I can’t answer to the question that gave by Kak Susantry or Bang Irfan.
Before I start preliminary test, Kak Susantry feel disappointed to my group because
there are 4 student that didn’t come. I think Kak Susantry got angry to us and will make
our tool test become harder to pass. Besides Kak Susantry noted every student carefully
and said that if we answer three times and wrong, we will be kicked. I really mad at that
time because it English week, the language is different with my daily conversation so I
need to listen carefully every question that given by assistant. When Kak Susantry
question session comes to me fortunately I can answer it without any difficulties but I need
to think longer because the question is in English. After many question has given to my
group, Kak Susantry become relax so I’m not nervous again. After tools test, Kak Susantry
really helpful to us and explain the experiment with detail so we don’t confused at this
experiment. Suggestion to Kak Susantry are I hope that you will be always smile and be
person that easy to help each other. I hope in your last grade in this campus will be happy
and all your problem will be easy to pass. Wish you full of success.
My first impression to Bang Irfan is less talk and I meet Bang Irfan for the first time
is when the experiment started, before that I never see Bang Irfan. I’m sorry maybe I less
active to meet my senior. At first I feel nervous to Bang Irfan because Bang Irfan less talk,
so I think that Bang Irfan keep his image to us. But as long as the tool test, Bang Irfan
really relax people. Bang Irfan never talk in high frequency so I can feel relax too and
think clearly to answer the question by Bang Irfan. In several moment I need more time
to remember the answer for some question, for the example I almost forget the materials
of this module but in the end I remember it. I remember the funny moment at tool test
when one of my friend get question from Bang Irfan, maybe one of my friend feel nervous
so there are misunderstood between Bang Irfan’s question and one of my friend’s answer.
I want to laugh at the moment but I hold it because the situation still serious. Suggestion
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to Bang Irfan are I hope Bang Irfan still less talk and still help us when experiment is on
going. I hope there are more smiles from Bang Irfan so the situation in the laboratory will
be still relax. I hope in your last year in this campus, Bang Irfan will get more happiness
and success so every problem will be passed easily.
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REFERENCES
Laboratorium Analisa Fluida Reservoir. 2018. Modul Praktikum Analisis Fluida Reservoir.
Bandung : TM ITB.
McCain, William D. 1989. “The Properties of Petroleum Fluids, Second Edition”.
Oklahoma: PannWell Publishing Co.
Siagian, Ucok. 2002. “Diktat Kuliah Fluida Reservoir.” Bandung: TM ITB.
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