Reagent Reaction

SET-I
1. HBr
→ Find major product
CCl4

(a) (b) (c) (d)

2. Total number of Isomeric product in question 1

(a) 1 (b) 2 (c) 3 (d) 4
HBr
3. CH3  CH == CH 2  → product is
Peroxide

Br
|
(a) CH3  CH  CH3 (b) CH3—CH2—CH2Br
Br
|
(b) CH 2  CH == CH 2 (d) CH3  C == CH 2
|
Br HCl
4. CH3—CH==CH2 → Intermediate is
Peroxide

+ °
(a) CH3  C H  CH3 (b) CH3  CH  CH3
Cl
°
| °
(b) CH3  CH  CH 2Cl (d) CH3  CH  CH 2

5. Which is wrong according to given

Cl
HCl
|
(a) CH3  CH == CH 2 → CH3  CH  CH3

Br Br
Br2 | |
(b) CH3  CH == CH 2 → CH3  CH  CH 2

1
 Reagent Reaction

I I
I2 | |
(c) CH3  CH == CH 2 → CH3  CH  CH 2

(d)

CH3
| HOCl
6. CH3  CH  CH == CH 2 → which is correct

(A) First attack is of Cl+   (B) No rearrangement only

CH3
|
CH3  CH  CH  CH 2Cl is the product
|
      OH
-
(C) First attack is only HO (D) Transition state is formed

CH3
|
CH3  C H  CH  CH 2
 
       Cl+
(a) A, B, C (b) A, B, D (c) A, B, C, D (d) B, C

2 Br
7. → Product

(a) (b) (c) Both (d) None

8. Which is Correct
(A) HBr attack according to Markonikov with rearrangement
(B) HCl attack according to Anti markanikov in presence of peroxide
(C) Br2 gives Cyclic addition without rearrangment
(D) I2 easily attack on alkene to give diiodo product
(a) A,B,C,D (b) A, B (c) A, C (d) A, C, D

2
Reagent Reaction

H 2SO 4 (D il) Fractional

9. → A →
B
 
Distillation
A contains ‘X’ number of Isomeric Products
B contains ‘Y’ number of Isomeric Products
Then X and Y are
X      Y          X    Y       X    Y         X    Y
(a) 2  1 (b) 3  1 (c) 3  2 (d) 4  2
10. Which is correct
CH3 CH3
| Br2
|
(A) H  C → H  C  Br
|| |
HC H  C  Br
| |
CH3 CH3
CH3 CH3 CH3
| Br
| |
(B) H  C 2 → H  C  Br + Br  C  Η
|| | |
HC Br  C  H H  C  Br
| | |
CH3 CH3 CH3
CH3 CH3
| Zn |
(C) H  C  Br → H C
| CH3OH ||
H  C  Br CΗ
| |
CH3 CH3
CH3 CH3
| Zn
|
(D) H  C  Br → H C
| CH3OH ||
H  C  Br HC
| |
CH3 CH3

(a) A, B (b) B, C (c) C, D (d) B, D

3
 Reagent Reaction
11. Correct on is
(a) In the attack of HOBr on alkene first attack is of Br+
(b) In Br2 attack on alkene first attack is of Br+
(c) In addition of H2SO4 (Dil) first attack is of H+
(d) All correct
H 2 /Pd
12. → A, A is
BaSO 4

(a) (b) (c) (d)

NaNH Li in NH3 HCOOOH

13. CH3  C ≡≡ CH 2→ A → B → C, C is
CH3Cl

(a) (b)

(c) (d)

14. Which can show this reaction

(a) H2/Pd (b) Raney Nickel

(c) LiAlH4 (d) NaBH4
15. CH3  CN → CH3  CH 2 NH 2
This reaction can be carried out is presence of
(a) LiAlH4 (b) H2/Pd-C
(c) NaBH4 (d) a and b

4
Reagent Reaction

16. Then find out which reaction is correct

(a)

(b)

(c)

(d)

17. Which is correct

(a)

(b)

(c)

(d) a and b

5
 Reagent Reaction
18. Which will react with NBS to give substitution reaction
O
||
(A) CH2==CH—CH3 (B) CH3  C  CH3
(C) CH3 — CH3 (D) CH2==CH2
(a) A, B (b) A,B,C,D (c) C, D (d) B, C
NBS
19. CH2==CH—CH2—CH==CH2 → Major Product
Br
|
(a) CH 2 == CH  CH  CH == CH 2
(b) CH 2 == CH  CH == CH  CH 2 Br
Br Br
| |
(c) CH 2 == CH  CH 2  CH  CH 2
Br
|
(d) CH 2 == CH  CH  CH 2  CH3

NBS
20. CH3  CH == CH  CH 2OH → Product is

(a) CH 2  CH == CH  CHO (b) CH 2  CH == CH  CH 2OH

| |
Br Br

(c) CH3—CH==CH—CHO (d) Br  CH  CH == CH  CH 2OH

|
Br
21. Which is correct
Cl2
(a) CH3  CH == CH 2 → CH 2  CH == CH  Cl

Cl2
(b) CH3  CH == CH 2 → CH 2  CH == CH 2
600°C |
Cl
Cl Cl
Cl2 | |
(c) CH3  CH == CH 2 → CH3  CH  CH 2

(d) b and c
6
Reagent Reaction

  Darken the Correct Option

1.       8.       15.      

2.       9.       16.      

3.       10.       17.      

4.       11.       18.      

5.       12.       19.      

6.       13.       20.      

7.       14.       21.      

  Performance Analyser
All 21 16-21 Questions 12-21 Questions Less than 10
Question Correct Correct Correct Correct

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