Eh (Volts) S - Cu - Fe - H2O - System at 25.

00 C
2.0

1.5
HS2O8(-a)

1.0

0.5
HS2O7(-a)
SO4(-2a)
0.0
Cu2S S4O3(-2a)
Cu5FeS4
S3O3(-2a)
-0.5
Fe0.877S

-1.0
H2S(a)
-1.5 HS(-a) S(-2a)

-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\CuFeS298.iep pH

ELEMENTS Molality Pressure

Cu 1.000E+00 1.000E+00
Fe 1.000E+00 1.000E+00
S 1.000E+00 1.000E+00
Eh (Volts) Fe - Cu - S - H2O - System at 25.00 C
2.0

1.5 FeO*OH
Fe(+3a)

1.0

0.5

CuFeO2
0.0 Fe(+2a) FeO*OH
Cu5FeS4
Fe(+2a)
-0.5 Fe3O4
Fe0.877S
Fe0.877S
-1.0

-1.5 Fe

-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\CuFeS298.iep pH

ELEMENTS Molality Pressure

Cu 1.000E+00 1.000E+00
Fe 1.000E+00 1.000E+00
S 1.000E+00 1.000E+00
Eh (Volts) Cu - Fe - S - H2O - System at 25.00 C
2.0

1.5 Cu(+2a)
Cu(OH)2
1.0

0.5

Cu2S CuFeO2
0.0
Cu5FeS4
-0.5

-1.0

-1.5 Cu

-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\CuFeS298.iep pH

ELEMENTS Molality Pressure

Cu 1.000E+00 1.000E+00
Fe 1.000E+00 1.000E+00
S 1.000E+00 1.000E+00
Eh (Volts) Cu - H2O - System at 25.00 C
2.0

1.5
Cu(+2a)
CuO
1.0

0.5

0.0

-0.5

-1.0 Cu2O

-1.5

-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\Cu298.iep pH

ELEMENTS Molality Pressure

Cu 1.000E+00 1.000E+00
Eh (Volts) Zn - S - H2O - System at 25.00 C
2.0

1.5
Zn(+2a)
1.0
ZnO(a)
ZnO2(-2a)
0.5

0.0

-0.5
ZnS

-1.0

-1.5
Zn

-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\ZnS298.iep pH

ELEMENTS Molality Pressure

Zn 1.000E+00 1.000E+00
S 1.000E+00 1.000E+00
Eh (Volts) S - Zn - H2O - System at 25.00 C
2.0

1.5
SO4(-2a)
HSO4(-a)
1.0

0.5
S

0.0

-0.5
ZnS

-1.0

-1.5 H2S(a) HS(-a) S(-2a)

-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\ZnS298.iep pH

ELEMENTS Molality Pressure

Zn 1.000E+00 1.000E+00
S 1.000E+00 1.000E+00