JP XII Physical&Inorganic Chemistry (29) - Prev Chaps + Inorg. Chem PDF

PHY./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2016
Course : VIJETA (JP) NO. 46 & 47
This DPP is to be discussed in the week (12.10.2015 to 17.10.2015)

DPP No. # 46 (JEE-MAIN)
Total Marks : 63 Max. Time : 42 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.11 (3 marks, 2 min.) [33, 22]
Single Integer type Questions ('–1' negative marking) Q.12 to Q.17 (3 marks 2 min.) [18, 12]
ChemINFO : 4 Questions ('–1' negative marking) Q.18 to Q.21 (3 marks, 2 min.) [12, 08]
ANSWER KEY
DPP No. # 46 (JEE-MAIN)
1. (D) 2. (C) 3. (C) 4. (C) 5. (A) 6. (B) 7. (D)
8. (A) 9. (B) 10. (A) 11. (B) 12. 1 13. 6 14. 4M
15. 6g 16. 2 17. 1 18. (C) 19. (A) 20. (D) 21*. (ABD)
DPP No. # 47 (JEE-ADVANCED)
1. (D) 2. (A) 3. (C) 4. (B) 5. (D)
6.* (ABC) 7.* (ABCD) 8.* (ABCD) 9.* (ABCD) 10.* (ACD)
11.* (ABC) 12.* (AD) 13.* (AC) 14.* (ABD) 15.* (ACD)
16. (B) 17. (C) 18. (D)
1. When CaC2 is heated in atmospheric nitrogen in an electric furnace the compound formed is :
tc CaC2 dks fo|qr HkV~Vh esa ok;qe.Myh; ukbVªkstu dh mifLFkfr esa xeZ fd;k tkrk gS] rks fuEu esa ls dkSulk ;kSfxd curk
gSA
(A) Ca(CN)2 (B) Ca3N2 (C) CaNC2 (D*) CaNCN
2. The colour of sky is due to :

(A) absorption of light by atmospheric gases (B) transmission of light
(C*) wavelength of scattered light (D) all of these
vkdk'k ds jax dk dkj.k gS :
(A) okrkoj.kh; xSlksa }kjk izdk'k ds vo'kks"k.k ds dkj.k (B) izdk'k ds ikjxeu ds dkj.k
(C*) izdhf.kZr izdk'k dh rjaxnS/;Z ds dkj.k (D) ;g lHkh
3. Phosphine, acetylene and ammonia can be formed by treating water with

QkWLQhu, ,flfVyhu o veksfu;k dks fuEu ds lkFk ty dks mipkfjr dj cuk;k tk ldrk gSA
(A) Mg3P2, Al4C3.Li3N (B) Ca3P2, CaC2.NaN3
(C*) Ca3P2, CaC2, CaCN2 (D) Ca3P2, Mg2C, NH4NO3
4. The incorrect statement/s among the following is/are

I. NCl5 does not while PCl5 does
II. Lead prefers to form tetravalent compounds
III. The three C–O bonds are not equal in the carbonate ion
IV. Both O2+ and NO are paramagnetic
(A) I, III and IV (B) I and IV (C*) II and III (D) I and IIII
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PAGE NO.- 1
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fuEu esa ls vlR; dFku dkSulk@dkSuls gSA
I. NCl5 mifLFkr ugha gksrk gS ysfdu PCl5 gksrk gSA
II. ysM] prq"dla;ksth ;kSfxd cukus dks izkFkfedrk nsrk gSA
III. dkcksZusV vk;u esa rhuksa C–O ca/k leku ugha gksrs gSaA
IV. O2+ rFkk NO nksuksa vuqpqEcdh; gksrs gSaA
(A) I, III rFkk IV (B) I rFkk IV (C*) II rFkk III (D) I rFkk IIII
5. Which one of the following pairs consists of only paramagnetic species ?

fuEu esa ls dkSulk ;qXe dsoy vuqpqEcdh; Lih'kht ls lEcfU/kr gS \
(A*) [O2, NO] (B) [O2+, O22–] (C) [CO, NO] (D) [NO, NO +]
6. Which of the following expected to exhibit optical isomerism ? (en = ethylenediamine)

izdkf'kd leko;ork dks fuEu esa ls dkSu iznf'kZr djrk gSA ? (en = ,fFkyhu Mkb,ehu)
(A) cis-[Pt(NH3)2Cl2] (B*) cis-[Co(en)2Cl2] (C) trans-[Co(en)2Cl2] (D) trans-[Pt(NH3)2Cl2]
(A) lei{k-[Pt(NH3)2Cl2] (B*) lei{k-[Co(en)2Cl2] (C) foi{k-[Co(en)2Cl2] (D) foi{k-[Pt(NH3)2Cl2]
7. Consider the following sets of quantum numbers :

n l m s
(i) 3 0 0 +1/2
(ii) 2 2 1 +1/2
(iii) 4 3 –2 –1/2
(iv) 1 0 –1 –1/2
(v) 3 2 3 +1/2
Which of the following sets of quantum numbers is not possible ?
(A) (i) and (iii) (B) (ii), (iii) and (iv) (C) (i), (ii), (iii) and (iv) (D*) (ii), (iv) and (v)
DokaVe la[;k ds fuEu lsV dk voyksdu dhft, %
n l m s
(i) 3 0 0 +1/2
(ii) 2 2 1 +1/2
(iii) 4 3 –2 –1/2
(iv) 1 0 –1 –1/2
(v) 3 2 3 +1/2
fuEu esa ls DokaVe la[;k dk dkSulk lsV laHko ugha gS ?
(A) (i) rFkk (iii) (B) (ii), (iii) rFkk (iv) (C) (i), (ii), (iii) rFkk (iv) (D*) (ii), (iv) rFkk (v)
8. At 500 K, the half life period of a gaseous reaction at the initial pressure of 80 kPa is 350 sec. W hen the
pressure is 40 kPa, the half life period is 175 sec. The order of the reaction is :
500 K ij, 80 kPa ds izkjfEHkd nkc ij ,d xSlh; vfHkfØ;k dh v)Zvk;q 350 sec gSA tc nkc 40 kPa gS rks v)Z vk;qdky
175 sec gSA vfHkfØ;k dh dksfV fuEu gSA
(A*) Zero 'kwU; (B) One izFke (C) Two f}rh; (D) Three r`rh;
Sol. Reaction follow zero order kinetics because t1/2  P0.
vfHkfØ;k 'kwU; dksfV dh cy xfrdh dk ikyu djrh gS] D;ksafd t1/2  P0.
9. An element (with atom. mass = 250 g) crystallises in a simple cubic.If the density of the unit cell is 7.2 g
cm–3, what is the radius of the element ?
(A) 1.93  10–6 cm (B*) 1.93  10–8 cm (C) 1.93  10–8 Å (D) 1.93  10–8 cm
,d ljy ?ku esa ,d rRo (ijek.kq nzO;eku = 250 g) dks fØLVyhd`r fd;k tkrk gSA ;fn bdkbZ dksf"Bdk dk ?kuRo
7.2 g cm–3, gSA rRo dh f=kT;k D;k gS ?
(A) 1.93  10–6 cm (B*) 1.93  10–8 cm (C) 1.93  10–8 Å (D) 1.93  10–8 cm
ZM
Sol. d=
NA a 3
PAGE NO.- 2
250  1
7.2 =
6  10 23  a3
a3 = 57.65 × 10–24
a = 2R = 3.86 × 10–8
R = 1.93 × 10–8
10. 0.06 mole of KNO3 is added to 100 cm3 of water at 298 K. The enthalpy of solution of KNO 3 is 35.8 KJ
mol–1. After the solute is dissolved, the temperature of the solution will be.
(A*) 293 K (B) 298 K (C) 301 K (D) 310 K
298 K ij 100 cm ty esa 0.06 eksy KNO3 dks feyk;k x;kA KNO3 tyh; foy;u dh ,UFkSYih 35.8 KJ mol–1 gSA foys;
3
?kqyus ds i'pkr~ foy;u dk rkieku fuEu gksxkA

(A*) 293 K (B) 298 K (C) 301 K (D) 310 K
Sol. Dissolution of KNO3 in water is endothermic reaction therefore temperatures of system is decreases.
KNO3 dk ty esa ?kqyuk Å"ek'kks"kh vfHkfØ;k gS] blfy, rU=k dk rki ?kV tk;sxkA
11. Consider the following reaction at 1000°C.

1
A. Zn(s) + O (g)  ZnO (s) ; G° = – 360 kJ mol–1
2 2
1
B. C(gr) + O (g)  CO(g) ; G° = – 460 kJ mol–1
2 2
Choose the correct statement at 1000°C
(A) zinc can be oxidised by carbon monooxide.
(B*) zinc oxide can be reduced by graphite.
(C) both statements (a) and (b) are true.
(D) both statements (a) and (b) are false.
1000°C ij fuEu vfHkfØ;k dk voyksdu dhth,A
1
A. Zn(s) + O (g)  ZnO (s) ; G° = – 360 kJ mol–1
2 2
1
B. C(gr) + O (g)  CO(g) ; G° = – 460 kJ mol–1
2 2
1000°C ij lgh dFku pqfu;sA
(A) dkcZuekuks vkWDlkbM }kjk ftad dks vkWDlhd`r fd;k tk ldrk gSA
(B*) xzsQkbV }kjk ftad vkWDlkbM dks vipf;r fd;k tk ldrk gSA
(C) (a) o (b) nksuksa lR; gSA
(D) (a) o (b) nksuksa vlR; gSaA
1
Sol. ZnO (s)  Zn(s) + O2(g) ; G° = 360 kJ mol–1
2
1
C(gr) + O (g)  CO(g) ; G° = – 460 kJ mol–1
2 2
ZnO(s) + C(gr)  Zn (s) + CO(g) ; G° = – 100 kJ mol–1
therefore reaction is spontaneous. blfy, vfHkfØ;k Lor% gksxhA
12. The equilibrium constant for the reaction 2X(g) + Y(g) 2Z(g) is 2.25. What would be the concentration
of Y at equilibrium with 2.0 mole of X and 3.0 mole of Z in one litre vessel at equilibrium.
vfHkfØ;k 2X(g) + Y(g) 2Z(g) ds fy, lkE; fu;rkad 2.25 gSA lkE; ij ,d yhVj ds ik=k esa 2 eksy X o 3 eksy
Z ds lkFk Y dh lkUnzrk D;k gksxh ?
Ans. 1
[ Z] 2 33
Sol. 2.25 = 2 2.25 = [Y] = 1.
[ X] [ Y ] 2  2  [ Y]
PAGE NO.- 3
13. A certain buffer solution contains equal concentration of X – and HX. The Kb for X– is 1 × 10–8. The pH of the
buffer is :
,d fuf'pr cQj foy;u X– o HX dh leku lkUnzrk j[krk gsA X– ds fy, Kb = 1 × 10–8 gS] rks cQj dh pH Kkr dhft,A
Ans. 6
Sol. X– & HX from acidic buffer vEyh; cQj ls X– o HX
[X– ]
pH = pKa + log [X–] = [HX]
[HX]
pH = pKa pKa + pKb = 14
pH = 6 pKa = 14 – 8 = 6.
14. Rate constant of the reaction 2H2O2 (aq.) 2H2O () + O2(g) is 3 × 10–3 minute–1
At what concentration of H2O2, the rate of reaction will be 2 × 10–4 ms–1.
vfHkfØ;k 2H2O2 (aq.) 2H2O () + O2(g) dk nj fu;rkad 3 × 10–3 feuV–1 gS] rks fuEu esa ls H2O2 dh fdl lkUnzrk
ij vfHkfØ;k dh nj 2 × 10–4 ms–1 gksxhA
Ans. 4M
Sol. Rate nj = K[H2O2]
3  10 –3
2 × 10–4 = × [H2O2]
60
[H2O2] = 4m.
15. The mass of glucose in gram that should be dissolve in 100g of water in order to produce same lowering of
vapour pressure as is produce by dissolving 1g of urea (mol mass = 60) in 50g of water is :
Xywdkst dk og Hkkj xzke esa Kkr dhft,] tks fd 50g ty esa 1g ;wfj;k ?kksyus ij fufeZr ok"i nkc ds voueu ds leku]
ok"i nkc voueu mRiUu djus ds fy, 100g ty esa ?kksyk tkuk pkfg,] fuEu gksxk (v.kq Hkkj = 60).
Ans. 6g
P0 – P5 nglu cos e nurea

Sol. P0 = Xsolule n glu cos e  n water = nurea  n water
w 1
180  60
Xglucose = Xurea w 100 1 50
 
180 18 60 18
wglucose = 6.
16. 1.575g of (COOH)2 . XH2O are dissolved in water and the volume is made up 250 ml. On titration 16.68 ml of
N
this solution are required for the neutralisation of 25ml of NaOH calculate the value of X :
15
ty esa 1.575g (COOH)2 . XH2O dks ?kksyk tkrk gS rFkk vk;ru 250 ml rd cuk;k tkrk gSA ;fn vuqekiu esa bl foy;u
N
ds 16.68 ml, NaOH ds 25ml ds mnklhuhdj.k ds fy, vko';d gS] rks X dk eku ifjdfyr dhft,A
15
Ans. 2
Sol. (COOH)2 + 2NaOH (COO–Na+)2 + 2H2O
5 5
m.mole
6 3
5 5 1.575 1000
= M(acid) × 16.68 = × X=2
6 6  16 .68 90  18X 250
PAGE NO.- 4
17. 3.24g of Hg(NO3)2 (molar mass = 324) dissolve in 1000g of water having freezing point of –0.0558ºC Calculate
degree of ionisation of Hg(NO3)2.(The Kf for water is 1.86 K–Kgmol–1)
3.24 xzke Hg(NO3)2 (eksyj nzO;eku = 324) dks 1000g ty esa ?kksyk x;kA bl tyh; foy;u dk fgekad –0.0558ºC gS]
rks Hg(NO3)2 dh vk;uu dh ek=kk Kkr dhft,A (ty dk Kf 1.86 K–Kgmol–1 gSA)
Ans. 1
0.01
Sol. 0.0558 = 1 × 1.86 ×
1
i=3
i =  +  (n–1)
3 = 1 +  (3–1)
2 = 2
 = 1.
PAGE NO.- 5
ChemINFO-1.22 Special Concentration Units
Daily Self-Study Dosage for mastering Chemistry II. Stength of Oleum
Strength of Oleum :
Oleum is SO3 dissolved in 100% H2SO4. Sometimes, oleum is reported as more than 100% by weight,
say y% (where y > 100). This means that (y  100) grams of water, when added to 100 g of given oleum
sample, will combine with all the free SO 3 in the oleum to give 100% sulphuric acid.
Hence, weight % of free SO 3 in oleum = 80(y 100)/18
Ex. What is the % of free SO 3 in an oleum sample that is labelled as '104.5% H2SO4' ?
(A) 30% (B) 15% (C*) 20% (D) 25%

Sol. SO3 + H2O  H2SO4. ;
18 g water combines with 80 g SO 3
80  4.5
 4.5 g of H2O combines with = 20 g of SO3
18
 100 g of oleum contains 20 g of SO3
or 20% free SO3 in oleum sample.
80
or % of free SO3 = × (104.5 – 100) = 20%
18
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
18. Maximum labelling of oleum is :

(A) 109% (B) 100% (C*) 122.5% (D) 112%
19. Similar to the % labelling of oleum, a mixture of H 3PO 4 and P4O10 is labelled as (100 + x)% where x is
the maximum amount of water which can react with P4O10 present in the mixture. If such a mixture is
labelled as 127%. The mass of P 4O 10 in 100 gm of mixture is :
(A*) 71 g (B) 47 g (C) 83 (D) 35 g
20. What is the % of free SO3 in an oleum sample that is labelled as '109% H2SO4' ?
(A) 30% (B) 15% (C) 20% (D*) 40%
21*. Fuming H 2SO4 (oleum) is a homogenous mixture of H 2SO4 and SO 3. Then which of the following
statement(s) are correct :
(A*) If H 2SO4 and SO3 are equimolar in an oleum sample, then strength of oleum is 110.11%
(B*) If H2SO 4 and SO3 are having equal masses in an oleum sample, then strength of oleum is 111.25%
(C) Strength of an oleum sample may be less than 100%.
(D*) If strength of oleum is (100 + x) %, then x g of water is to be added to 100 g oleum sample to
convert whole of SO 3 to H 2SO4.
PAGE NO.- 6
ChemINFO-1.22 Special Concentration Units
Daily Self-Study Dosage for mastering Chemistry . vkWfy;e dk lkeF;Z
vkWfy;e dk lkeF;Z (Strength of Oleum)

100% H2SO4 esa ?kksyk x;k SO3 vkWfy;e gSA dHkh&dHkh vkWfy;e Hkkj dk 100% ls vf/kd gksrk gSA bls pkgs rks y%
eku ldrs gSa (tgk¡ y > 100)A bldk vFkZ gS fd ty dk (y  100) xzke tc fn;s x;s vkWfy;e uewus ds 100 g esa feyk;k
tkrk gS] rks ty lHkh eqDr SO3 ds lkFk la;ksftr gksxk rFkk 100% lY¶;wfjd vEy nsxkA
vr% vkWfy;e esa eqDr SO3 dk izfr'kr Hkkj = 80/(y 100)/18
Ex. ,d vkWfy;e uewus] ftl ij '104.5% H2SO4' vafdr gS] esa fdrus % eqDr SO3 gksxh ?
(A) 30% (B) 15% (C*) 20% (D) 25%
Sol. SO3 + H2O  H2SO4. ;
18 g ty] 80 g SO3 ds lkFk la;ksftr gksrk gS
 4.5 g H2O, 20 g SO3 ds lkFk la;ksftr gksrk gSA
 100 g vkWfy;e 20 g SO3 j[krk gS
;k vkWfy;e uewus esa 20% eqDr SO3 gSA
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
18. vkWfy;e dh vf/kdre fpUghdj.k gksrh gS %

(A) 109% (B) 100% (C*) 122.5% (D) 112%
19. vkWfy;e ds izfr'kr fpUghdj.k dh rjg gh H3PO4 o P 4O 10 dk feJ.k (100 + x)% fpUghr fd;k tk ldrk gSA tgka
ij x, feJ.k esa mifLFkr P4O10 ls fØ;k djus okyh ty dh vf/kdre ek=kk gSA ;fn ,sls fdlh feJ.k ij 127 % fpUghr
gks] rks 100 gm feJ.k esa mifLFkr P 4O 10 dk nzO;eku gksxk%
(A*) 71 g (B) 47 g (C) 83 (D) 35 g
20. ,d vkWfy;e uewus] ftl ij '109% H2SO4' vafdr gS] esa fdrus % eqDr SO3 gksxh ?
(A) 30% (B) 15% (C) 20% (D*) 40%
21*. l/kwe H2SO4 (vkWfy;e) H2SO4 o SO 3 dk lekaxh feJ.k gksrk gS rks fuEu esa ls dkSuls dFku lgh gSa %
(A*) ;fn vkWfy;e uewus esa H2SO4 o SO3 leeksyj gks rks vksWfy;e dk lkeF;Z 110.11% gksxkA
(B*) ;fn vkWfy;e uewus esa H2SO4 o SO 3 dk nzO;eku cjkcj gks rks vkWfy;e dk lkeF;Z 111.25% gksxkA
(C) vkWfy;e uewus dk lkeF;Z 100% ls de gks ldrk gSA
(D*) ;fn vkWfy;e dk lkeF;Z (100 + x) % gks rks 100 g vkWfy;e uewus ds fy;s x gm ty dh vko';drk gksxh bldh
lEiw.kZ SO3 dks H2SO4. esa ifjofrZr djus ds fy;sA
PAGE NO.- 7
DPP No. # 47 (JEE-ADVANCED)
Total Marks : 64 Max. Time : 36 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.5 (3 marks, 2 min.) [15, 10]
Multiple choice objective ('–1' negative marking) Q.6 to Q.15 (4 marks, 2 min.) [40, 20]
Comprehension ('–1' negative marking) Q.16 to Q.18 (3 marks, 2 min.) [09, 06]
1. 100 mL of 0.1N I2 oxidizes Na2S2O3 in 50 ml solution to Na2S4O6. The normality of this hypo solution against
KMnO4 (which oxidizes it to Na2SO4) would be
0.1N I2 dk 100 mL, Na2S2O3 dks Na2S4O6 ds 50 ml foy;u esa vkWDlhd`r dj nsrk gSA KMnO4 (tks bls Na2SO4 esa
vkDlhd`r djsa) ds lkis{k bl gkbiks foy;u dh ukeZyrk gksxh
(A) 0.1 (B) 0.2 (C) 1.0 (D*) 1.6.
2. In the synthesis of sodium carbonate by Solvay (or ammonia soda) process the recovery of ammonia is done
by treating NH4Cl with Ca(OH)2. The by-product obtained in this process is
(A*) CaCl2 (B) NaCl (C) NaOH (D) NaHCO3
lkWYos izØe (;k veksfu;k lksMk izØe) }kjk lksfM;e dkcksZusV ds fuekZ.k esa NH4Cl dks Ca(OH)2 ls fØ;k djokdj NH3 dks
iqu% çkIr fd;k tkrk gSA bl çØe esa çkIr lgmRikn gS &
(A*) CaCl2 (B) NaCl (C) NaOH (D) NaHCO3
Sol. NH3 + CO2 + H2O  NH4HCO3
NaCl + NH4HCO3  NaHCO3 + NH4Cl
150 º C
2NaHCO3    Na2CO 3 + CO2 + H2O
2NH4Cl + Ca(OH)2  2NH3 + H2O + CaCl2 (byproduct) (lg mRikn).
3. In a face centred lattice of X and Y, X atoms are present at the corners while Y atoms are at face centres.
Then the formula of the compound would be if two atoms of X are missing from the corners :
X rFkk Y ds Qyd dsfUnzr tkyd esa] X ijek.kq Qyd ds fdukjs ij rFkk Y ijek.kq Qyd ds dsUnz ij mifLFkr gSA ;fn
nks X ijek.kq dks fdukjs (dksauks) ls xk;c dj fn;k tk;s] rks ;kSfxd dk lw=k Kkr djks %
(A) X4Y (B) X3Y4 (C*) XY4 (D) X2Y4
1 3
Sol. for X, 6 × =
8 4
1
for Y, 6 × =3
2
so X3/4 X3 or X3 Y12 or XY4
1 3
Sol. X ds fy,, 6 × =
8 4
1
Y ds fy,, 6 × =3 ; vr% X3/4 X3 ;k X3 Y12 ;k XY4
2
4. An aqueous solution of a solute AB has b.p. of 101.08°C (AB is 100% ionised at boiling point of the solution)
and freezes at – 1.80°C (Kb / Kf = 0.3). Hence, AB
(A) is 100% ionised at the f.p. of the solution
(B*) behaves as non-electrolyte at the f.p. of the solution
(C) forms dimer
(D) none of the above
foys; AB ds tyh; foy;u dk dFkukad 101.08°C gSA (foy;u ds xyukad ij AB 100% vk;fur gksrk gS) rFkk – 1.80°C
ij terk gSA vr% AB (Kb / Kf = 0.3) fn;k x;k gSA
(A) foy;u ds fgekad fcUnq ij 100% vk;fur gksrk gSA
(B*) foy;u ds fgekad fcUnq ij vu~vi?kV~; dh rjg O;ogkj iznf'kZr djrk gSA
(C) f}yd cukrk gSA
(D) mijksDr esa ls dksbZ ugha
PAGE NO.- 8
Sol. Given Tb = 1.080C , i = 2 at boiling pt. of solution.
kb
and Tf = 1.800C , and k = 0.3
f
Tb ibk bm
so Tf = i f k f m
so if = 1
i.e., AB behaves as non–electrolyte at the f.p of the solution.
Sol. fn;k x;k gS Tb = 1.080C , foy;u ds DoFkukad ij i = 2

kb
rFkk Tf = 1.800C , rFkk k = 0.3
f
Tb ibk bm
vr% Tf = if k f m
vr% if = 1 vr% AB foy;u ds fgekad fcUnq ij vuvi?kV~; dh rjg O;ogkj iznf'kZr djrk gSA
5. Aqueous solution of orthoboric acid can be titrated against sodium hydroxide using phenolphthalein indicator
only in presence of :
(A) trans-glycerol (B) catechol (C) cis-glycerol (D*) both (B) and (C)
fuEu esa ls dsoy fdldh mifLFkfr esa] vkWFkksZcksfjd vEy ds tyh; foy;u dks] fQukW¶FkSyhu lwpd (indicator) dk mi;ksx
dj lksfM;e gkbMªksDlkbM ds lkFk vuqekfir fd;k tk ldrk gS %
(A) foi{k&fXyljkWy (B) dSVhdkSy (C) lei{k&fXyljkWy (D*) (B) rFkk (C) nksuksa
Sol. It forms a stable cyclic complex with polyhydroxy compounds like cis-glycerol, cathechol, etc. This helps in
the release of H+ as H3O+ and, therefore, boric acid acts as a strong acid and hence can be titrated with
sodium hydroxide using phenolphthalein.
gy& ;g ikWyhgkbMªksDlh ;kSfxd tSls lei{k fXyljkWy] dSVhdkSy vkfn ds lkFk LFkk;h pfØ; ladqy cukrk gSA ;g H+ dks H3O+
ds :i esa eqDr djus esa enn djrk gSA vr% LFkk;h ladqy cuus ds dkj.k cksfjd vEy] izcy vEy ds leku O;ogkj n'kkZrk
gS rFkk bls fQukW¶FkSyhu lwpd ds mi;ksx }kjk lksfM;e gkbMªksDlkbM ds lkFk vuqekfir fd;k tk ldrk gSA
6.* An arbitrary compound X2Y decomposes acoording to the reaction :
2X2Y(g) 2X2(g) + Y2(g)
If one starts the decomposition reaction with 4 moles of X 2Y and the value of equilibrium constant K p is
numerically equal to the total pressure at equilibrium, then which of the following statement is/are correct :
(A*) Total number of moles at equilibrium will be (16/3)
(B*) The degree of dissociation of X2Y is (2/3)
(C*) Number of moles of X2Y at equilibrium is equal to number of moles of Y2 at equilibrium.
(D) Number of moles of X2 at equilibrium is equal to number of moles of X 2Y at equilibrium.
,d LosfPNd ;kSfxd X2Y dk fo?kVu fuEu lehdj.k ds vuqlkj gksrk gSA
2X2Y(g) 2X2(g) + Y2(g)
;fn 4 eksy X2Y ysdj fo?kVu vfHkfØ;k izkjEHk djs rFkk lkE;koLFkk fu;rkad Kp dk eku xf.krh; :i ls lkE;koLFkk ij dqy
nkc ds cjkcj gks rks fuEu esa ls dkSulk@dkSuls dFku lR; gSA
(A*) lkE;koLFkk ij dqy eksYl (16/3) gksxsaA (B*) X2Y dh fo;kstu dh dksfV (2/3) gSA
(C*) lkE;koLFkk ij X2Y ds eksyksa dh la[;k] lkE;koLFkk ij Y2 ds eksyksa dh la[;k ds cjkcj gSA
(D) lkE;koLFkk ij X2 ds eksyksa dh la[;k] lkE;koLFkk ij X2Y ds eksyksa dh la[;k ds cjkcj gSA
Sol. 2X2Y 2X2 + Y2
t=0 4 0 0
t= eq 4 (1–) 4 2
Kp = = But Kp = (given)
 – 6   = (2/3) Total moles at eq = 4 + 2a = (16/3)
lkE;koLFkk ij dqy eksy eq = 4 + 2a = (16/3)
PAGE NO.- 9
7.* XeF4 + O2F2  [X] + O2 (unbalanced equation)
Select the correct statement(s) for [X].
(A*) Partial hydrolysis of [X] gives XeOF4 as one of the product.
(B*) [X] gives yellow liquid on melting
(C*) [X] reacts with SiO2 to form XeOF4 and SiF4
(D*) [X] reacts with XeO3 to form XeOF4
XeF4 + O2F2  [X] + O2 (vlarqfyr lehdj.k)
[X] ds fy, lgh dFkuksa dks pqfu;sA
(A*) [X] dk vkaf'kd ty vi?kVu ,ds mRikn ds :i esa XeOF4 nsrk gSA
(B*) [X] xykus ij ihyk nzo nsrk gSA
(C*) [X] SiO2 ds lkFk vfHkd`r gksdj XeOF4 rFkk SiF4 cukrk gSA
(D*) [X] XeO3 ds lkFk vfHkd`r gksdj XeOF4 cukrk gSA
Sol. XeF4 + O2F2  XeF6 [X] + O2
(A) XeF6 + H2O  XeOF4 + 2HF

(B) XeF6 turns to yellow liquid on melting where as XeF 2 & XeF4 turn white.
XeF6 xykus ij ihys nzo esa cny tkrk gS tcfd XeF2 rFkk XeF4 lQsn nzo esa cnyrs gSA
(C) 2XeF6 + SiO2  2XeOF4 + SiF4
(D) XeO3 + 2XeF6  3XeOF4
8.* Which of the following species are correctly matched with their geometries according to the VSEPR theory?
(A*) BrF6+  octahedral. (B*) SnCl5–  trigonal bipyramidal.
–
(C*) ClF2  linear. (D*) IF4+  see – saw.
VSEPR fl)kUr ds vuqlkj] fuEu esa ls dkSulh Lih'kht mudh T;kfefr ds lkFk lqesfyr gS \
(A*) BrF6+  v"VQydh; (B*) SnCl5–  f=kdks.kh; f}fijsfefM;
– +
(C*) ClF2  js[kh; (D*) IF4  lh&lkW
Sol. (A) (B) (C) (D)
gy. (A) (B) (C) (D)
9.* Indicate the correct statements :

(A*) conductivity cells have cell constant values independent of the solution filled into the cell
(B*) DC (direct current) is not used for measuring the resistance of a solution.
(C*) Kohlrausch law is valid both for strong and weak electrolytes.
(D*) The k decreases but M and E increase on dilution.
PAGE NO.- 10
lgh dFku dks bafxr dhft, &
(A*) pkydrk lSy ds fy, tks lSy fu;rkad eku gksrs gSa og lSy esa Hkjs gq, foy;u ij fuHkZj ugha djrs gSA
(B*) ,d foy;u esa fn"V /kkjk dk mi;ksx izfrjks/k ds ekiu esa ugha fd;k x;k gSA
(C*) dkWyjka'k fu;e izcy rFkk nqcZy fo|qr vi?kV~; ds fy, ekU; gSA
(D*) k ?kVsxk] fdUrq ruqrk ij M rFkk E c<+rk gSA
10.* Assume ideal gas behaviour for all the gases considered and neglect vibrational degrees of freedom. Separate
equimolar samples of Ne, O2, CO2 and SO2 were subjected to a two process as mentionel. Initially all are at
same state of temperature and pressure.
Step I  All undergo reversible adiabatic expansion to attain same final volume, which is double the
original volume thereby causing the decreases in their temperature.
Step II  After step I all are given appropriate amount of heat isochorically to restore the original temperature.
Mark the correct option(s) :
(A*) Due to step I only, the decrease in temperature will be maximum for Ne
(B) During step II, heat given will be minimum for SO2
(C*) There will be no change in internal energy for any of the gas after both the steps of process are competed
(D*) The P–V graph of O 2 and CO2 will be same
lHkh xSlks ds fy;s vkn'kZ O;ogkj ekurs gq;s vkSj dfEir Lora=krk dksfV ux.; gSA Ne, O2, CO2 vkSj SO2 ds leeksyj uewus
i`Fkd dhft;s tSlk fd nks fØ;kvksa esa O;ofLFkr fd;k x;k çkjEHk esa lHkh rki vkSj nkc dh leku voLFkk ij gSA
in I  lHkh mRØe.kh; :)ks"e çlkj.k ds vUrxZr leku vfUre vk;ru xzg.k djrs gS] tks fd okLrfod vk;ru dk
nqxuk gS vFkkZr og muds rkieku esa deh ds dkj.k gksrk gSA
in II  in I ds ckn lHkh nh x;h levk;rfud Å"ek (isochorically Heat) dh vko';d ek=kk,sa okLrfod rkieku
ij yh x;h gSA lgh fodYi pqfu;s %
(A*) dsoy I in ds dkj.k] fu;kWu ds fy;s rkieku esa deh vf/kdre gksxhA
(B) II in ds nkSjku] SO2 ds fy;s fuEure Å"ek nh gksxhA
(C*) ;gk¡ vfHkfØ;k ds nksuksa inksa ds iw.kZ gksus ds ckn dksbZ Hkh xSl ds fy;s vkarfjd ÅtkZ esa ifjorZu ugha gksxkA
(D*) O2 vkSj CO2 ds fy;s P–V xzkQ leku gksxkA
Sol. (A,C,D) First step is adiabatic (q = 0) so U1 = w1 Second step is
isochoric (w = 0)
So, U2 = q2
 initial and final temp. are same
 Utotal = U1 + U2 = 0
or w1 + q2 = 0
Max, work done by the gas, SO 2 is (area) under the curve
So, SO2 absorbed
  SO 2 <  CO2 =  O2 < Ne
So, max, decrease in temp. of Ne due to step 1.
gy- (A,C,D) çFke in :)ks"e gSA (q = 0) blfy;s U1 = w1 f}rh; in
levk;rfud gS (w = 0).
blfy;s] U2 = q2
 çkjEHk vkSj vfUre rki leku gSaA
 Udqy = U1 + U2 = 0
;k w1 + q2 = 0
SO2 xSl }kjk fd;k x;k vf/kdre dk;Z ¼{ks=kQy½ oØ ds uhps gSA
blfy;s SO2 vo'kksf"kr gksrh gSA
  SO 2 <  CO2 =  O2 < Ne
blfy;s 1 in ds dkj.k Ne ds rkieku esa vf/kdre deh gSaA
PAGE NO.- 11
11.* The qualitative order of Debroglie wavelength for electron, proton and  particle is e > P >  if
(A*) If kinetic energy is same for all particles
(B*) If the accelerating potential difference 'V' is same for all the particles (from rest)
(C*) If velocities are same for all particles
(D) None of the above
bySDVªkWu] izksVksu rFkk d.kksa ds fy, MhczksXyh rjaxnS/;Z dk xq.kkRed Øe e > P >  gSa] ;fn&
(A*) lHkh d.kksa ds fy, xfrt ÅtkZ leku gksa
(B*) lHkh d.kksa ds fy, Rofjr foHkokUrj 'V' leku gksa ¼fojkeoLFkk ls½
(C*) lHkh d.kksa ds fy, osx leku gksa
(D) mijksDr esa ls dksbZ ugha
12.* Which of the following sample of reducing agents is/are chemically equivalent to 25ml of 0.2 N KMnO 4 to be
reduced to Mn2+ and H2O?
(A*) 25 mL of 0.2M FeSO4 to be oxidized to Fe3+
(B) 50 mL of 0.1M H3AsO3 to be oxidized to H3AsO4
(C) 25 mL of 0.2M H2O2 to be oxidized to H+ and O2
(D*) 25 mL of 0.1 M SnCl2 to be oxidized to Sn4+
vipk;d vfHkdeZd dk fuEu esa ls dkSulk @ dkSuls uewuk] 0.2 N KMnO4 ds 25 mL dks Mn2+ ,oa H2O esa vipkf;r djus
ds jklk;fud rqY;kdksa ds leku gS \
(A*) 0.2M FeSO4 ds 25 mL dks Fe3+ esa vkWDlhd`r djus ds
(B) 0.1M H3AsO3 ds 50 mL dks H3AsO4 esa vkWDlhd`r djus ds
(C) 0.2M H2O2 ds 25 mL dks H+ vkSj O2 esa vkWDlhd`r djus ds
(D*) 0.1 M SnCl2 ds 25 mL dks Sn4+ esa vkWDlhd`r djus ds
13.* An equilibrium A(g) 2B(g) has been established in a one litre container. At equilibrium, moles of A and moles
of B are found to be equal (2 moles each). Now, if the volume of reaction vessel is halved keeping the
temperature constant and the equilibrium is allowed to restablish, then which of the following statements is/
are true ?
(A*) The concentrations of A and B at new equilibrium are 4.5 M and 3 M respectively.
(B) The equilibrium can be said to be shifted in forward direction upon reducing the volume to half.
(C*) The equilibrium can be said to be shifted in backward direction upon reducing the volume to half.
(D) The equilibrium will not shift in any direction upon reducing the volume to half as moles of A and B at initial
equilibrium are equal (2 each.)
,d yhVj ik=k esa ,d lkE; A(g) 2B(g) LFkkfir gSA lkE;koLFkk ij A ds eksYl rFkk B ds eksYl leku (çR;sd ds 2 eksy)
ik;s x;s gaSA vc fLFkj rki ij ;fn vfHkfØ;k ik=k dk vk;ru vk/kk dj nsa rFkk lkE;koLFkk iqu% LFkkfir gksus nh tk;s rks fuEu
esa ls dkSulk@dkSuls dFku lR; gSa ?
(A*) ubZ lkE;koLFkk esa A rFkk B dh lkUnzrk Øe'k% 4.5 M rFkk 3 M gSaA
(B) vk;ru dks vk/kk djus ij lkE; vxz fn'kk esa foLFkkfir gksxkA
(C*) vk;ru dks vk/kk djus ij lkE; i'p fn'kk esa foLFkkfir gksxkA
(D) vk;ru dks vk/kk djus ij lkE; fdlh Hkh fn'kk esa foLFkkfir ugha gksxk D;ksafd çkjfEHkd lkE; esa A rFkk B ds eksy leku
(çR;sd ds 2 eksy) gaSA
Sol. A(g) 2B(g)
 eq. conc. 2 2  KC = = 2
Conc. after 4 4  QC = = = 4 > KC  Eq. will shift in backward
volume made direction.
half
 eq. conc. 4+x 4 – 2x  KC = = 2 (as T remains constant)
gy djus ij On solving we get x = 0.5
 [A] = 4 + 0.5 = 4.5 M, [B] = 4 – 2 (0.5) = 3 M
PAGE NO.- 12
14.* Select the correct order
(A*) Solubility of alkali metal hydroxides is in order CsOH > RbOH > KOH > NaOH > LiOH
(B*) Solubility of alkali carbonates is in order BeCO3 > MgCO3 > CaCO3 > SrCO3 > BaCO3
(C) Hydrated radii is in order Li+ < Na+ < K+ < Rb+ < Cs+
(D*) Stability of peroxides is in order Na2O2 < K2O2 < Rb2O2 < Cs2O2
lgh Øe dk p;u dhft;s
(A*) {kkjh; /kkrq gkbMªksDlkbMkas dh foys;rk fuEu Øe esa gSA CsOH > RbOH > KOH > NaOH > LiOH
(B*) {kkjh; dkcksZusV dh foys;rk fuEu Øe esa gSA BeCO3 > MgCO3 > CaCO3 > SrCO3 > BaCO3
(C) ty;ksftr f=kT;k fuEu Øe esa gSA Li+ < Na+ < K+ < Rb+ < Cs+
(D*) ijkWDlkbM dk LFkkf;Ro fuEu Øe esa gSA Na2O2 < K2O2 < Rb2O2 < Cs2O2
15.* Which one of the following statements are correct ?

(A*) Tin is extracted by carbon reduction (smelting)
(B) Aluminium is extracted by Hall’s process which involves carbon reduction.
(C*) Extraction of lead does not involve bessemerisation
(D*) Gold is extracted by cyanide process
fuEu esa ls dkSulk dFku lgh gS \
(A*) fVu dk fu"d"kZ.k dkcZu vip;u ¼izxyu½ }kjk gksrk gSA
(B) ,Y;qfefu;e dk fu"d"kZ.k gkWy fof/k }kjk gksrk gS ftlesa dkcZu vip;u gksrk gSA
(C*) ysM ds fu"d"kZ.k esa cslsejhdj.k izfØ;k fughr ugha gksrh gSA
(D*) xksYM dk fu"d"kZ.k lk;ukbM fof/k }kjk gksrk gSA
Sol. Aluminium is extractecd by Hall-Heroult process (electrolytic reduction).
,Y;qfefu;e gkWy&gsjkWYV fof/k ¼oS|qr vi?kV~; vip;u½ }kjk fu”"df"kZr gksrk gSA
COMPREHENSION # (Q.No. 16 to Q. No. 18)

Following flow chart describes the scheme of classification of anions on the basis of the nature of the
products or nature of reaction with chemical reagents and acids.
PAGE NO.- 13
vuPNsn # (Q.No.16 ls 18)
fuEufyf[kr vkjs[k (chart) esa jklk;fud vfHkdeZd ,oe~ vEyksa ds lkFk] vfHkfØ;k dh izd`fr ;k vRiknks dh izd`fr ds
vk/kkj ij _.kk;uksa ds oxhZdj.k dk o.kZu fd;k x;k gSaA
16. A salt on reaction with dil H2SO4 produces a colourless gas which turns lime water milky and an acidified
orange coloured potassium dichromate solution green. The salt may be -
(A) a carbonate (B*) a sulphite (C) a sulphide (D) acetate.
,d yo.k dh ruq H2SO4 ds lkFk vfHkfØ;k djkus ij ,d jaxghu xSl curh gSa tks pwus ds ty dks nwf/k;k rFkk vEyh; ukjaxh
jax ds ikSVsf'k;e MkbØksesV dks gjk dj nsrh gSaA vr% yo.k lEHkor% gks ldrk gSa %
(A) ,d dkcksZusV (B*) ,d lYQkbZV (C) ,d lYQkbZM (D) ,d ,sflVSV
Sol. SO32– + 2H+  SO2 + H2O
SO2 + Ca(OH)2  CaSO3  (white) + H2O
Cr2O72– + 2H+ + 3SO2  Cr3+ + 3SO42– + H2O
gy- SO32– + 2H+  SO2 + H2O
SO2 + Ca(OH)2  CaSO3  (lQsn) + H2O
Cr2O72– + 2H+ + 3SO2  Cr3+ + 3SO42– + H2O.
17. A solution of a salt in concentrated H2SO4 turns white paste of starch containing potassium iodide blue. The
salt may be a :
(A) chloride (B) carbonate (C*) bromide (D) acetate
lkUnz H2SO4 esa mifLFkr ,d yo.k foy;u ikSVsf'k;e vk;ksMkbZM ;qDr LVkpZ ds lQsn isLV dks uhyk dj nsrk gSaA vr% yo.k
lEHkor% gksxk&
(A) DyksjkbZM (B) dkcksZusV (C*) czksekbZM+ (D) ,sflVSV
Sol. 2KBr + 2 H2SO4  Br2  + SO2 + SO42– + 2K+ + H2O
2I– + Br2  2Br– + I2 .
I2 + starch  blue colour complex.
gy- 2KBr + 2 H2SO4  Br2  + SO2 + SO42– + 2K+ + H2O
2I– + Br2  2Br– + I2 .
I2 + LVkpZ  uhys jax dk ladqyA
18. Which of the following statement is incorrect ?

(A) Metal iodide with excess chlorine water forms colourless iodic acid.
(B) Nitrates on gentle warming with aluminium powder and sodium hydroxide produces ammonia gas.
(C) Mercury nitrate solution produces yellow precipitate of basic mercury (II) sulphate with sodium sulphate
solution.
(D*) A deep red solution of complex ion [Fe3(OH)2(CH3COO)6]+ on boiling with water produces a greenish-
yellow precipitate.
PAGE NO.- 14
fuEu esa ls dkSulk dFku vlR; gSa \
(A) /kkrq vk;ksMkbZM Dyksjhu ty ds vkf/kD; ds lkFk jaxghu vk;ksfMd vEy cukrk gSaA
(B) ukbVªsV dks ,sY;wfefu;e pw.kZ rFkk lksfZM;e gkbMªksDlkbM ds lkFk /khjsµ/khjs xeZ djus ij veksfu;k xS l curh gS
(C) ejD;wjh ukbVªsV foy;u esa lksfM;e lYQsV foy;u feykus ij {kkjh; ejD;wjh (II) lYQsV dk ihyk vo{ksi izkIr gksrk
gSaA
(D*) [Fe3(OH)2(CH3COO)6]+ ladqy vk;u ds xgjs yky jax ds foy;u dks ty ds lkFk mckyus ij ,d gjk&ihyk vo{ksi
izkIr gksrk gSaA
Sol. (A) 3I– + CI2–  I3– + 2CI– ; I3– + 8CI2 + 9H2O  3IO3– + 16CI– + 18H+
(B) 3 NO3– + 8Al + 5OH– + 18H2O  3NH3 + 8[AI (OH)4]–
(C) SO24– + 3Hg2+ + 2H2O  HgSO4.2HgO  (yellow) + 4H+

(D) 6 CH3 COO– + 3Fe3+ + 2HgO  [Fe3 (OH)2 (CH3COO)6]2 + 2H+
[Fe3(OH)2 (CH3COO)6] + 4 H2O  3 Fe(OH)2 CH3COO  (brownish red) + 3CH3 COOH + H+
gy- (A) 3I– + CI2–  I3– + 2CI– ; I3– + 8CI2 + 9H2O  3IO3– + 16CI– + 18H+
(B) 3 NO3– + 8Al + 5OH– + 18H2O  3NH3 + 8[AI (OH)4]–
(C) SO24– + 3Hg2+ + 2H2O  HgSO4.2HgO  (ihyk) + 4H+

(D) 6 CH3 COO– + 3Fe3+ + 2HgO  [Fe3 (OH)2 (CH3COO)6]2 + 2H+
[Fe3(OH)2 (CH3COO)6] + 4 H2O  3 Fe(OH)2 CH3COO  (Hkwjk yky) + 3CH3 COOH + H+
PAGE NO.- 15

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PHY./INO.

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 46 & 47

This DPP is to be discussed in the week (12.10.2015 to 17.10.2015)

2. The colour of sky is due to :

3. Phosphine, acetylene and ammonia can be formed by treating water with

4. The incorrect statement/s among the following is/are

5. Which one of the following pairs consists of only paramagnetic species ?

6. Which of the following expected to exhibit optical isomerism ? (en = ethylenediamine)

7. Consider the following sets of quantum numbers :

?kqyus ds i'pkr~ foy;u dk rkieku fuEu gksxkA

11. Consider the following reaction at 1000°C.

P0 – P5 nglu cos e nurea

(A) 30% (B) 15% (C*) 20% (D) 25%

18. Maximum labelling of oleum is :

(C) Strength of an oleum sample may be less than 100%.

vkWfy;e dk lkeF;Z (Strength of Oleum)

18. vkWfy;e dh vf/kdre fpUghdj.k gksrh gS %

2NH4Cl + Ca(OH)2  2NH3 + H2O + CaCl2 (byproduct) (lg mRikn).

Sol. fn;k x;k gS Tb = 1.080C , foy;u ds DoFkukad ij i = 2

(A) XeF6 + H2O  XeOF4 + 2HF

(D) XeO3 + 2XeF6  3XeOF4

Sol. (A) (B) (C) (D)

gy. (A) (B) (C) (D)

9.* Indicate the correct statements :

15.* Which one of the following statements are correct ?

COMPREHENSION # (Q.No. 16 to Q. No. 18)

18. Which of the following statement is incorrect ?

(C) SO24– + 3Hg2+ + 2H2O  HgSO4.2HgO  (yellow) + 4H+

(C) SO24– + 3Hg2+ + 2H2O  HgSO4.2HgO  (ihyk) + 4H+

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