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L"91 128
¶ LD ARTILLERY GUIDED MISSILE SYSTEM
REDSTONE
MT-M44J
TECHNICAL MEMORANDUM
PROPERTIES OF JP-5 FUEL
rotDEC I1I'T1
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REDSTONE
TECHNICAL MEMORANDUM
MT-M44J
by
4 December 1957
CWO 200037
ii
TABLE OF CONTENTS
Page
Object 1
Conclusions 1
Recommendations 1
Discussion 1
Introduction 1
Applicable Specifications 1
Variations of Physical Properties 1
Compatibility of Lubricants with JP-5 Fuel 2
Compatibility of Elastomers with JP-5 Fuel 2
Compatibility of Metallics with JP-5 Fuel 2
Sealants, Threading Compounds, and Packing Compatible
with JP-5 Fuel 2
Flammability Limits of JP-5 Fuel 3
References 3
Appendix 16
ii
LIST OF TABLES
Page
Table I Variations of Physical Properties of JP-5 Fuel Samples 4
Table II Inspection Data JP-5 Fuel 5
Table III Compatibility of Lubricants with JP-5 Fuel 6
Table IV Elastomer Hardness Changes Induced by JP-5 Fuel 7
Table V Elastomer Volume Changes Induced by JP-5 Fuel 8
Table VI Metallic Corrosion Induced by JP-5 Fuel 9
Table VII Calculated Flammability Limits of JP-5 Fuel in Air 9
LIST OF ILLUSTRATIONS
Page
Figure 1 Variation of Specific Gravity with Temperature of
MIL-F-5624C (JP-5) Fuel 10
Figure 2 Variation of Dielectric Constant with Temperature of
MIL-F-5624C (JP-5) Fuel 11
Figure 3 Variation of Latent Heat of Vaporization with
Temperature of MIL-F-5624C (JP-5) Fuel 12
Figure 4 Enthalpy Diagram for Average Quality of MIL-F-5624C
(JP-5) Fuel 13
Figure 5 Viscosity - Temperature Relation of MIL-F-5624C
(JP-5) Fuel 14
Figure 6 Variation of Vapor Pressure with Temperature of
MIL-F-5624C (JP-5) Fuel 15
iv
PROPERTIES OF JP-5 FUEL
OBJECT
CONCLUSIONS
The physical properties of JP-5 fuel can vary considerably yet still lie within the military
specification (MIL- F-5624C).
Parker Fuelube, Carbowax 100, and MIL-L-6032 lubricants are compatible with JP-5 fuel.
No corrosion is promoted by contact of JP-5 fuel with metallics.
Teflon, fluorosilicone rubber, polyethylene, Buna N, and Kel-F elastomers are compatible
with JP-5 fuel.
Definite upper and lower limits of flammability exist for mixtures of air and JP-5 vapor.
RECOMMENDATIONS
The qualification of individual vendor's elastomer compounds for specific missile fuel appli-
cations, through controlled immersion tests, should be made mandatory.
DISCUSSION
Introduction
MIL-F-52.4C (JP-5) fuel, hereafter referred to as JP-5, was established to control the prop-
erties of a spec ial blending component for use in naval aircraft upcrations. This component resembles
a high-flashpoint kerosene. Jp-5 was selected by North American Aviation as the fuel for their S3-D
liquid propellant rocket engine (JUPITER powerplant). It is felt that documentation concerning' military
specification, the envelope of variation obtained from commercial products, and compatibilities of
various engineering materials with the fuel should be consolidatod for easy reference.
Applicable Specifications
The applicable military specification for this fuel, MIL-F-5624C, Fuel, Aircraft and Jet Engine
Grades JP-3, JP-4. and JP-5, is included as an Appendix.
It is impo rtant to understiand that variations of physical properties of a fuel can or do occur
although still remaining within the limits of the specifications set forth. These variations must be
considered when designing, developing, or modifying the particular power plant and related storage
and launching and handling equipment for the fuel. In order to provide an indication of the variation
of these properties, several tables and graphs have been included. Table I illustrates variations
for the physical properties of JP-5 samples as obtained by NACA. Table II shows variations obtained
by the Bureau of Mines. Variations of other physical properties such as viscosity and vapor pres-
sure are presented in Figures 1 through 6.
1. 87x 10 6 143
qn M L+lU-V7,
M = Molecular weight
qn= Net heat of combustion, Btu/lb.
L Lean-limit concentration, volume per cent
R Rich-limit concentration, volume per cent
These equations were derived from pure-hydrocarbon data but are applicable to jet fuels such
as JP-5. The equation requires heats of combusition and molecular weight was estimated from
charts in Reference 5. Calculated values of the flammability limits of JP-5 in airare presented in
Table VII.
REFERENCES
4. "Fuel, Aircraft Turbine and Jet Engine Grades JP-3, JP-4, and JP-6,"
MIL-F-5624C, IS May 1955.
3
TABLE I
Number of Arithmetic
Properties
Fuels Averaged Minimum Maximum Average
Gravity, 60/60 F
Specific 62 0.808 0.842 0.827
degrees API -- 43.6 36.6 39.6
Aniline point, degrees Fahrenheit 44 128 153 139
Viscosity, centistokes at -40 F 52 10.1 19.7 16.1
Flash point, degrees Fahrenheit 52 125 159 147
4
TABLE II
Gum
Existent:
Air-jet, 400 F, ag. /100 ml. 3 2 .. ..
Steam-jet, 450 F, mg. /100 ml. 9. 1 1.0 0.9
16-hr Accelerated:
Air-jet, 400 F. 5 2 .. ..
Steam-jet, 4 1 2.0 1.6
Material Remarks
6
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TABLE V
8
TABLE VI
METALLIC CORROSION INDUCED BY JP-5 FUEL
TABLE ViI
9
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Figure 2-Variation of dielectric constant with temperature of NMllF-5624C (JP-5) fuel. (Ref. 1)
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15
MIL-F -5624C
APPENDIX 18 MAY 1955
.up r ((vill
7 Decem or 1) 3
Mi l~iTARY 01PLCIFICATICN
1. SCOPE
1.1 Se-e-Thi:1 ;p(,c~ifiCntiQ'rl covers aircra!ft turi.ine- and jot en,,;Ino fuels.
2.1 The2 fol-owinj; specific -tlons .'ind ntandard, ýt' tnt' M'' in effect eon date
invitat~ion for lbbds, fc cm a par,. of' thiin :np-cifioatiorr to tho'x.2~ spocifivd herein-l:
SPX-'IFICATIONS
Federal
Military
STANDA RDS
(Copies of specifications, standords, drawin,:n, -nd pui lic' ti n.; r.- :,.irerd -y
i corwctin 'it:h specific procurement functions Lshoul-JI..e o~i
contactos
frem the procurin.g activity or as directed Lsy the 'ýontractinC, officer.)
16
APPENDIX- (Continued)
iL-F- 5624c
2.2 Other publications.- The following document forms a part of this specifi-
cation. Unless therwise idicated, the issue in effect on date of invitation for bids
shall apply.
3. REQUIRE1ENTS
3.2 Chemical and physical requirements.- The chemical and physical requirements
of the fuel shall conform to those listed in table I when tested in accordance with the
applicable test methods specified therein.
3.2.1 Corrosion.- There shall be no evidence of corrosion and not more than a
slight tarnish of the copper strip when tested in accordance with the procedure
outlined in 4.3.2.2.
3.2.2 Water reaction.- The fuel shall separate sharply from the water layer,
and there shall be no evidence of an emulsion, precipitate, or suspended matter, within
or upon either layer. Neither layer shall have changed in volume by more than
1 milliliter.
3.2.3 Heat of combustion.- The heat of combustion determination may be waived
at the option o-'he Tspector if the aniline-gravity product of the fuel is not less
than 5,250 for grades JP-3 and JP-4, or not less than 4,500 for grade JP-5. The aniline-
gravity product is defined as the product of the gravity of the fuel in degrees API and
the aniline point of the fuel in degrees Fahrenheit,. as determined by Method 3601 of
Specification VV-L-791, entitled "Aniline point and mixed aniline point."
17
APPENDIX- (Continued)
miL- F- 5624C
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10 "IJ 18
"d
MIL-F-562hC APPENDIX- (Continued)
3.3 Additives.- The additives listed herein may be used singly or in combi-
nation, in amounts not to exceed those specified.
4.l General.- All the tests required herein for the testing of fuels are
classified as Acceptance tests, for which necessary sampling techniques and methods of
testing are specified in this section.
4.3 Tests.-cA
2.3.2 Testin;.- Unless otherwnise specified by the military service for whom
the material is procuired, inspection shall be in accordance with Method 9601 of
Specification VV-L-791, entitled "Inspection requirements." Tests as specified in 3.2
shall be conducted in accordance with Specification VV-L-791, using applicable methods
as listed in table I, except for the following.
19
APPENDIX- (Continued)
MIL-F-5621hC
14.3.2.2 CLorr'o.;io)n.- The Corrunion test shall OCe conducted at nominal 2127
ý10O)C) usin4 Pir-Well ath in accordance with Method 5)1313 entitled "Free and corrosive
Jlulf~ir,"l of Spvcificatior; VV-L-791, except that the fuel sample ohill not be dried as
specified in 6.2 of Method 5313, etntitled "Tests at nominal .2127 (lO00C0."
Li.3.2.3 Smoke tcoint.- The Smoke point test shall be con~ducted in accordance
with met~hod 2107, entitled "Smoke point,," of' Specification VVL',1-t,7, except th:lt
paragraph 80)) _;hall read: "Reproducibility.- Reo;ults obtained in diffearnt laboratories,
2hoald not diffur from each oflir by more thFan 10 percent of. the Mean smoke point."
4.4 Rejection and retest.- Mat-riaJ. not conforming to the requirements of' this
sp-ecification sh .11 be rejecte7. Rejected material shill not hp resubmit~t/:d without
furnishing full particulars concerning; previous rejection and muasures taken to overcome
defects.
5.2 Packaging and packing.- The 55-gallon drums do not require any overpacking
for do',estic aind aver;ea:: ; hipment. (See 3.)4.)
6. NJOTES
20
SIL-F-5624C APPENDIX- (Continued)
6.3 Definitions.-
Custodians:
Army - Ordnance Corps
Navy - Bureau of Aeronautics
Air Force
Other interest:
Army- EQT
Navy- Sh
21
*t
21