Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
com
INCONEL® nickel-chromium alloy 625 is used for its The outstanding and versatile corrosion resistance of
high strength, excellent fabricability (including join- INCONEL alloy 625 under a wide range of tempera-
ing), and outstanding corrosion resistance. Service tem- tures and pressures is a primary reason for its wide
peratures range from cryogenic to 1800°F. Composition acceptance in the chemical processing field. Because of
is shown in Table 1. its ease of fabrication, it is made into a variety of com-
Strength of INCONEL alloy 625 is derived from the ponents for plant equipment. Its high strength enables it
stiffening effect of molybdenum and columbium on its to be used, for example, in thinner-walled vessels or
nickel-chromium matrix; thus precipitation-hardening tubing than possible with other materials, thus improv-
treatments are not required. This combination of ele- ing heat transfer and saving weight. Some applications
ments also is responsible for superior resistance to a requiring the combination of strength and corrosion
wide range of corrosive environments of unusual sever- resistance offered by INCONEL alloy 625 are bubble
®
fatigue and thermal-fatigue strength; oxidation resist-
Nickel 58.0 min.
ance; and excellent weldability and brazeability are the Chromium 20.0-23.0
properties of INCONEL alloy 625 that make it interest- Iron 5.0 max.
ing to the aerospace field. It is being used in such appli- Molybdenum 8.0-10.0
cations as aircraft ducting systems, engine exhaust sys- Columbium (plus Tantalum) 3.15-4.15
Carbon 0.10 max.
tems, thrust-reverser systems, resistance-welded honey- Manganese 0.50 max.
comb structures for housing engine controls, fuel and Silicon 0.50 max.
hydraulic line tubing, spray bars, bellows, turbine Phosphorus 0.015 max.
shroud rings, and heat-exchanger tubing in environmen- Sulfur 0.015 max.
Aluminum 0.40 max.
tal control systems. It is also suitable for combustion Titanium 0.40 max.
system transition liners, turbine seals, compressor Cobalt a 1.0 max.
vanes, and thrust-chamber tubing for rocket motors. a
If determined
The data contained in this publication is for informational purposes only and may be revised at any time without prior notice. The data is
believed to be accurate and reliable, but Special Metals makes no representation or warranty of any kind (express or implied) and assumes no
liability with respect to the accuracy or completeness of the information contained herein. Although the data is believed to be representative of
the product, the actual characteristics or performance of the product may vary from what is shown in this publication. Nothing contained in this
publication should be construed as guaranteeing the product for a particular use or application.
INCONEL ® alloy 625
2
INCONEL ® alloy 625
Mechanical Properties
Nominal room-temperature mechanical properties of Tensile Properties and Hardness
INCONEL alloy 625 are shown in Table 5.
For service at 1200°F and below, hot-finished, cold-fin- Typical tensile properties of annealed and solution-treated
ished, and annealed conditions (depending on requirements material from room to elevated temperature are shown in
involved) are recommended. Figures 3, 4, and 5. The approximate relationship between
For service above 1200°F, either annealed or solution- the hardness and tensile and yield strength of strip is shown
treated material will give best service. The solution-treated in Figure 6.
condition is recommended for components that require opti- Increased tensile properties for service at moderate tem-
mum resistance to creep or rupture. Fine-grained (annealed) perature can be achieved by cold work. See the section,
material may be advantageous at temperatures up to 1500°F “Working Instructions” for some specific data.
with respect to fatigue strength, hardness, and tensile and Upon exposure to intermediate temperatures, some hard-
yield strength. ening takes place in alloy 625. To demonstrate this reaction,
MacGregor’s two-load was used for determination of the samples of annealed rod were exposed at 1200°, 1400°, and
true stress-strain curve for alloy 625 at room temperature. 1600°F for 2000 hr. The effect of exposure on properties
The two-load test requires no strain measurement during the both at room temperature and at exposure temperature is
test, and only the maximum and fracture loads are recorded. shown in Table 6. Measurements were made to determine
Data for both annealed and solution-treated material are dimensional stability; the samples exposed at 1200° to
shown in Figure 2. 1400°F for 2000 hr contracted about 0.048%.
COLD-DRAWN
Annealed 120-140 60-75 55-30 - - 40
Elongation
Solution-Treated 100-120 40-60 60-40 - -
a 20
Values shown are composites for various product sizes up to 4 in. They
are not suitable for specification purposes. For properties of larger-sized
products, consult Special Metals Corporation. 0
0 400 800 1200 1600 2000
Temperature, °F
400
Figure 3 - High-temperature tensile properties of annealed bar.
200 aled
Anne
n
raw
d-D
True Stress, ksi
100
Col d
80 lled ate
60 t- Ro -Tre
Ho lution
40 So
30
20
10
0.01 0.1 1.0 2.0
3
INCONEL ® alloy 625
140
Elongation, %
120 240
100 Tensile Strength
220
80
Elongation
60 200
Stress, ksi
40 Yield Strength
(0.2% Offset) 180
20
0 160
0 400 800 1200 1600 2000 Tensile Strength
Temperature, °F
Stress, ksi
140
Figure 4 - High-temperature tensile properties of cold-rolled
annealed sheet.
120
100
160
Elongation, %
80
40
60 48 52 56 60 64 68 72
Elongation
Stress, ksi
40 Hardness, Rockwell A
Yield Strength
20 (0.2)% Offset
Temperature, °F
4
INCONEL ® alloy 625
150 80
800°F 85°F
140 1000°F
60
1200°F
130
Stress, ksi
1400°F
Stress, ksi
120 40
As-Rolled Notched 85°F
110 Specimen
(Kt=3.3) 1600°F
20
100
90 Annealed 0
103 104 105 106 107 108
80
104 105 106 107
Cycles to Failure
108
Cycles to Failure
Figure 8 - Rotating-beam fatigue strength of hot-rolled solution-
treated bar (0.625-in. diameter) at elevated temperature. Average
Figure 7 - Fatigue strength at room temperature of hot-rolled round
grain size, 0.004 in.
(5/8-in. diameter).
Fatigue Strength
Room-temperature fatigue strength of hot-rolled round in the as-rolled and annealed conditions is shown in Figure 7. Elevated-
temperature fatigue strengths of solution-treated and annealed bar can be compared in Figures 8 and 9.
The endurance limit (108 cycles) at room temperature of cold-rolled annealed sheet tested in completely reversed bending
was found to be 90,000 psi for smooth bar and 35,000 psi (notched specimen Kt=3.3).
100
80 1000oF
1200oF
60
Stress, ksi
1400oF
40
20
1600oF
0
104 105 106 107 108
Cycles to Failure
Figure 9 - Rotation-beam fatigue strength of hot-rolled annealed bar (0.625-in. diameter) at elevated tempera-
ture. Average grain sized, 0.0006 in.; room-temperature hardness, 24.5 Rc.
5
INCONEL ® alloy 625
100
1200oF
o
1300 F
o
1400 F
Stress, ksi
o
10 1500 F
o
1600 F
0o F
oF 200
1800
1
0.001 0.01 0.1 1.0 10 100 1000 10,000
6
INCONEL ® alloy 625
1200 oF
1300 oF
1400 oF
1500 oF
Stress, ksi
10 1600 oF
1800 o
F
200
0 oF
1
1 10 100 1,000 10,000 100,000
Rupture Life, hr
100
o
1100 F
oF
40 1150
0o F
120
oF
1300
Stress, ksi
10
oF
1400
4
0o F
150
1
0.01 0.1 1.0 10 100 1,000
7
INCONEL ® alloy 625
100
1100 oF
1300oF
1200oF
1150oF
1400oF
Stress, ksi
10
1500oF
1
1 10 100 1,000 10,000 100,000
Rupture Life, hr
Microstructure
INCONEL alloy 625 is a solid-solution matrix-stiffened
face-centered-cubic alloy. Typical microstructure of
annealed rod is shown in Figure 15. The alloy may contain
carbides, which are inherent in this type of alloy. Carbides
that can be found are MC and M6C (rich in nickel, columbi-
um, molybdenum, and carbon). In addition, M23C6, a
chromium-rich carbide, appears in solution-treated material
exposed at lower temperatures.
The hardening effect that takes place in the material on
exposure in the range centered around 1200°F (See
Mechanical Properties section.) is due to sluggish precipita-
tion of a nickel-columbium-rich phase, gamma prime. This
phase gradually transforms to orthorhombic Ni3Cb when the
alloy is heated for long times in the intermediate tempera-
ture range.
Extensive investigation of the stability of alloy 625 fol- Figure 15 - Microstructure of hot-rolled annealed INCONEL alloy
625 round. 1000X. (Reduced about 30%). Etchant: 5% Nital
lowing exposure for extended periods in the 1000° to
electrolytic.
1800°F temperature range has shown complete absence of
embrittling intermetallic phases such as sigma.
8
INCONEL ® alloy 625
Corrosion Resistance
Aqueous corrosion
The high alloy content of INCONEL alloy 625 enables it to withstand a wide variety of severe corrosive environments. In
mild environments such as the atmosphere, fresh and sea water, neutral salts, and alkaline media there is almost no attack. In
more severe corrosive environments the combination of nickel and chromium provides resistance to oxidizing chemicals,
whereas the high nickel and molybdenum contents supply resistance to nonoxidizing environments. The high molybdenum
content also makes this alloy very resistant to pitting and crevice corrosion, and columbium acts to stabilize the alloy against
sensitization during welding, thereby preventing subsequent intergranular cracking. Also, the high nickel content provides
freedom from chloride ion stress-corrosion cracking.
This combination of characteristics makes INCONEL alloy 625 useful over a broad spectrum of corrosive conditions. For
instance, it has been recommended as a material of construction for a storage tank to handle chemical wastes, including
hydrochloric and nitric acids — chemicals which represent directly opposite types of corrosion problems. Materials which
resist either one of these acids are normally severely attacked by the other.
More general information may be found in the publication ‘High Performance Alloys for Resistance to Aqueous Corrosion’
on our website, www.specialmetals.com.
High-temperature oxidation
6.0
Weight Change per Unit Area, mg/sq cm
-2.0
0 100 200 300 400 500 600 700 800 900 1000
9
INCONEL ® alloy 625
Hardness, Rockwell A
62
60
58
56
54
5% Cold Work Prior To Anneal
10% Cold Work Prior To Anneal
52 20% Cold Work Prior To Anneal
40% Cold Work Prior To Anneal
60% Cold Work Prior To Anneal
50
As Cold- 1700 1800 1900 2000 2100
worked
Annealing Temperature, °F
Figure 17 - Effect of annealing temperature on the hardness of
sheet (30 min at temperature).
Yield Impact
Annealing Tensile Strength Strength
Temperature, Strength, (0.2% Offset), Elongation, Reduction of Hardness, (Charpy V), Grain
F ksi ksi % Area, % Rb ft-lb Size, in.
As-Drawn 163.0 145.5 21.0 50.5 106 64.5 0.003
1100 160.5 134.3 28.0 48.3 106 75.0 0.0035
1200 159.5 133.5 28.5 47.2 106 71.5 0.0045
1300 164.0 135.0 26.0 38.8 106 57.0 0.005
1400 162.5 135.5 27.0 39.0 106 53.0 0.005
1500 152.0 120.0 29.0 41.5 105 55.0 0.0035
1600 146.5 102.5 35.0 45.2 103 62.0 70% 0.005
30% 0.009
1700 133.5 62.3 48.5 44.0 97 82.5 0.0008
1800 127.5 62.3 52.0 55.3 95 84.5 0.0009
1900 130.5 60.8 53.0 55.7 95 91.0 0.0008
2000 126.5 56.5 57.0 61.0 93 115.5 0.0019
2100 118.0 48.3 63.0 60.4 89 138.0 0.0032
2200 113.0 44.6 62.0 58.4 86 141.0 0.006
10
INCONEL ® alloy 625
Pickling
When heated, INCONEL alloy 625, like other nickel-chromium and nickel-chromium-iron alloys, forms a tightly adherent
oxide or scale unless it has been bright-annealed in very dry hydrogen or in a vacuum. To remove the oxide which results from
heating, treatment in a fused-salt bath prior to pickling is usually recommended. Comments on applicable salt baths and pick-
ling solutions may be found in the publication ‘Fabricating’ on the Special Metals website, www.specialmetals.com.
11
INCONEL ® alloy 625
Table 11 - Effect of Cold Work on Mechanical Properties of Strips Cut From Hot-
Rolled Plate (0.372-in.), Solution-Treated 2150°F/1 hr and Cold Worked
Yield Hardness
Cold Strength
Reduc- Tensile (0.2% Elonga- Reduction
tion, Strength, Offset), tion, of Area, Rockwell
% ksi ksi % % C Vickers
0 115.5 49.5 67.0 60.4 88 Rb 179
5 121.0 77.5 58.0 58.1 94 Rb 209
10 130.0 102.5 47.5 54.6 25 257
15 137.0 112.5 39.0 51.9 32 309
20 143.0 125.0 31.5 50.0 34 326
30 165.0 152.0 17.0 49.3 36 344
40 179.5 167.0 12.5 41.9 39 372
50 189.5 177.0 8.5 38.0 40 382
60 205.0 180.5 6.5 32.7 44 427
70 219.0 201.0 5.0 25.4 45 440
500
alloy 625
INCONEL
400
less Steel
Type 304 Stain
718
Vickers Hardness No.
alloy -750
ONEL lloy X
INC NEL a 600
300 INCO EL alloy
INCON
y 400
EL allo
INCON Nickel 200
200
Mild Steel (1020)
Copper
100
Aluminum
0
0 10 20 30 40 50 60 70
Cold Reduction, %
Machining
Guidelines for machining INCONEL alloy 625 are given in the publication ‘Machining’ on the Special Metals website,
www.specialmetals.com.
12
INCONEL ® alloy 625
Welding
INCONEL alloy 625 is readily joined by conventional welding processes and procedures. INCONEL Filler Metal 625 and
INCONEL Welding Electrode 112 are nickel-chromium-molybdenum products designed for welding INCONEL alloy 625 to
itself and to other materials. Compositions of the two products are shown in Table 13. Like alloy 625, deposited weld metals
from both products are highly resistant to corrosion and oxidation and have high strength and toughness from the cryogenic
range to 1800°F. They require no postweld heat treatments to maintain their high strength and ductility. When used to weld
INCONEL alloy 625 to dissimilar metals, both products
Table 13 - Limiting Chemical Composition, %, of Welding Products
tolerate a high degree of dilution yet maintain characteris-
tic properties. INCONEL INCONEL L
a
INCONEL Filler Metal 625 and INCONEL Welding Filler Metal 625 Welding Electrode 112
Electrode 112 are also used as “over-matching composi- Nickel b 58.0 min. 55.0 min.
tion” welding products for iron-nickel-chromium-molyb- Carbon 0.10 max. 0.10 max.
Manganese 0.50 max. 1.0 max.
denum super-austenitic stainless steels, INCOLOY® Iron 5.0 max. 7.0 max.
alloys 825 and 020, and INCONEL alloy G-3. The higher Sulfur 0.015 max. 0.02 max.
alloy content of the alloy 625 welding products offsets the Silicon 0.50 max. 0.75 max.
effects of elemental segregation in weldments which can Chromium 20.0-23.0 20.0-23.0
Columbium (p(plus Tantalum)) 3.15-4.15 3.15-4.15
result in preferential weld corrosion. Molybdenum 8.0-10.0 8.0-10.0
INCONEL Filler Metal 625 is designed for use with the Aluminum 0.40 max. -
gas-tungsten-arc and various gas-metal-arc processes. Titanium c
0.40 max. -
0.12 c
Operating characteristics are similar to those of other Cobalt
Phosphorus
-
0.02 max. 0.03
nickel-chromium filler metals. INCONEL Welding Copper 0.50 max. 0.50 max.
Electrode 112, for shielded metal-arc welding, has excel- Other 0.50 max. 0.50 max.
lent operability. The slag produced is hard, but it detaches Deposited weld metal.
a
Plus cobalt. b
When specified. c
All-Weld-Metal Properties
High-temperature properties of weld metals are shown in
Figures 20, 21, and 22. These welds were made by the gas- 140 160
tungsten-arc process and the shielded-metal-arc process.
Low-temperature toughness of weld metals is shown by the 120
Tensile Strength
140
impact-strength data in Table 14.
6 100 120
Room-temperature fatigue strength (10 cycles; rotating-
beam tests at 10,000 rpm) of polished all-weld-metal speci- 80 Yield Strength 100 Elongation, %
mens was found to be 68,000 psi (Filler Metal 625) and (0.2% Offset)
Stress, ksi
13
INCONEL ® alloy 625
Elongation, %
Stress, ksi
0
Elongation 0 200 400 600 800 1000 1200 1400 1600 1800 2000
20 40
0 20 Temperature, °F
Temperature, °F
100
1200oF
1300 oF
1400 oF
10 1500 oF
1600 oF
Stress, ksi
1700 o
F
1800 o
F
1
0.1
1 10 100 1,000 10,000 100,000
Rupture Life, hr
14
INCONEL ® alloy 625
Transverse Properties
Properties of INCONEL alloy 625 welds made with the dye-penetrant and radiographic inspection and guided-bend tests.
recommended welding products are shown in Figures Barker, Cox, and Margolin report the results of tests on joints
20 and 22. between alloy 625 sheet and other dissimilar metals.
As another example of weld quality, the gas-tungsten-
arc process with 1/8-in. Filler Metal 625 was used to
70
join 1/2-in. annealed plate. Transverse bends with a
radius equal to two thicknesses (2T) had no fissuring or 60
cracking.
50
Rupture strength of alloy 625 welds made by the gas-
tungsten-arc process and Filler Metal 625 is shown in
Stress, ksi
40
Figure 24. 30
Both INCONEL Filler Metal 625 and INCONEL
Welding Electrode 112 have been used to join alloy 625 20
to a variety of dissimilar metals. The results of tests 10
made on welds of alloy 625 joined to a nickel-iron-
chromium-molybdenum alloy (Hastelloy alloy X), a 0
precipitation-hardenable nickel-chromium alloy 1100 1200 1300 1400 1500 1600
(INCONEL alloy 718), a cast chromium-nickel-iron- Temperature, °F
tungsten alloy (MO-RE 1) and Types 304 and 410 stain- Figure 24 - 100-hr rupture strength of transverse specimens from joints
less steel are shown in Table 15. All the joints passed in alloy 625 made by gas-tungsten-arc process using Filler Metal 625.
15
www.specialmetals.com
U.S.A. France Affiliated Companies
Special Metals Corporation
Special Metals Services SA Special Metals Welding
Billet, rod & bar, flat 17 Rue des Frères Lumière Products
& tubular products 69680 Chassieu (Lyon) 1401 Burris Road
3200 Riverside Drive Phone +33 (0) 4 72 47 46 46 Newton, NC 28658, U.S.A.
Huntington, WV 25705-1771 Fax +33 (0) 4 72 47 46 59 Phone +1 (828) 465-0352
Phone +1 (304) 526-5100 +1 (800) 624-3411
+1 (800) 334-4626 Germany Fax +1 (828) 464-8993
Fax +1 (304) 526-5643
Special Metals Deutschland Ltd. Regal Road
Billet & bar products Postfach 20 04 09 Stratford-upon-Avon
4317 Middle Settlement Road 40102 Düsseldorf Warwickshire CV37 0AZ, U.K.
New Hartford, NY 13413-5392 Phone +49 (0) 211 38 63 40 Phone +44 (0) 1789 268017
Phone +1 (315) 798-2900 Fax +49 (0) 211 37 98 64 Fax +44 (0) 1789 269681
+1 (800) 334-8351
Fax +1 (315)798-2016 Hong Kong Controlled Products Group
590 Seaman Street, Stoney Creek
Atomized powder products Special Metals Pacific Pte. Ltd. Ontario L8E 4H1, Canada
100 Industry Lane Room 1110, 11th Floor Phone +1 (905) 643-6555
Princeton, KY 42445 Tsuen Wan Industrial Centre Fax +1 (905) 643-6614
Phone +1 (270) 365-9551 220-248 Texaco Road, Tsuen Wan
Fax +1 (270) 365-5910 Phone +852 2439 9336 A-1 Wire Tech, Inc.
Fax +852 2530 4511 A Special Metals Company
Shape Memory Alloys 840 39th Avenue
4317 Middle Settlement Road India Rockford, IL 61109, U.S.A.
New Hartford, NY 13413-5392 Phone +1 (815) 226-0477
Phone +1 (315) 798-2939 Special Metals Services Ltd. +1 (800) 426-6380
Fax +1 (315) 798-6860 No. 60, First Main Road, First Fax +1 (815) 226-0537
Block
United Kingdom Vasantha Vallabha Nagar Rescal SA
Subramanyapura Post A Special Metals Company
Special Metals Wiggin Ltd. Bangalore 560 061 200 Rue de la Couronne des Prés
Holmer Road Phone +91 (0) 80 666 9159 78681 Epône Cédex, France
Hereford HR4 9SL Fax +91 (0) 80 666 8918 Phone +33 (0) 1 30 90 04 00
Phone +44 (0) 1432 382200 Fax +33 (0) 1 30 90 02 11
Fax +44 (0) 1432 264030 Italy
DAIDO-SPECIAL METALS
Special Metals Wire Products Special Metals Services SpA Ltd.
Holmer Road Via Assunta 59 A Joint Venture Company
Hereford HR4 9SL 20054 Nova Milanese (MI) Daido Building
Phone +44 (0) 1432 382556 Phone +390 362 4941 7-13, Nishi-shinbashi 1-chome
Fax +44 (0) 1432 352984 Fax +390 362 494224 Minato-ku, Tokyo 105, Japan
Phone +81 (0) 3 3504 0921
China The Netherlands Fax +81 (0) 3 3504 0939