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Formation Damage

Taller de Optimización de Producción

Maracaibo, 2006

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Well, Reservoir & Boundaries

A reservoir might have a boundary.

Reservoir boundaries:

•“no flow” – sealing fault, dividing


line between drainage areas

•Constant pressure boundary –


acquifer, injector/producer interface

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Wellbore, Altered Zone & Undamaged Zone

Any alteration on the flowing properties of


the a zone around the well will induce a
correspondent change on the well
production.

A decrease of the conductivity will


correspond to a restriction to produce.

If production is restricted in any zone of


the formation due to whatever
mechanism, the formation is said to be
damaged.

(Dowell Matrix Engineering Manual, 1998) 3


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Permeability changes in Radial Flow

Flow restrictions, light or severe, k/ka

have a higher impact at close ra s=1 s=5 s = 10 s = 100

penetration. 0.36 36.5 178.5 356.0 3,550.8

0.5 3.8 15.0 29.0 281.4

1 2.0 5.8 10.5 96.3

As penetration increases the 2 1.6 3.9 6.7 58.4

restriction “stabilizes”. 3 1.5 3.3 5.7 47.5

5 1.4 2.9 4.8 38.6

10 1.3 2.5 4.0 30.8


Near the wellbore, in the “critical 20 1.2 2.2 3.5 25.7

area”, the restriction is maximal. 50 1.2 2.0 3.0 21.2

100 1.2 1.9 2.8 18.7

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Permeability changes in Radial Flow

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Effect of shifting a 80% damage collar

100
3-in collar
Percent of original productivity

6-in collar
80 12-in collar
rc-rx = collar thickness
Damage collar
60 rc

40 rx

Wellbore
20 re

0
0 1 2 3 4 5 6
Inner radius of damage (ft)

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Critical Area

Area 3 to 5 ft around the wellbore where flow restriction is higher .


Flow linear velocity is higher in the critical area and varies with the
square of the radius.
Critical Area

velocity

rw
re

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Radial Flow & Skin Effect

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Flow Regimes

Transient Pseudo Steady State Steady State


(variable slope) (constant slope) ( slope zero)

time

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Darcy’ Law in Transient Flow

•Infinity acting radial flow period


•No outer boundary
•Pressure vs. time slope changes

Solution in field units (zero skin)

k h (Pe − Pwf )
q=
⎛ k ⎞
162.6 µ Bo ⎜⎜ log t + log − 3.23 ⎟⎟
⎝ φ µ Ct rw
2

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Darcy’s Law in Pseudo Steady State Flow

• No flow across outer boundary


• Reservoir is finite
∂P
• Pressure decline with time is constant ∂t
= const. rw < r < re

Solution in field units (skin zero)


k h (Pe − Pwf )
q=

141.2 µ Bo ⎜ ln
re
− 0.5 ⎞⎟
⎝ rw ⎠
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Darcy’s Law in Steady State Flow

• No flow at the boundary


• Reservoir is finite
∂p
• Pressure is constant with time =0 rw <r < re
∂t

Solution in field units (skin zero)


k h (Pe − Pwf )
q=

141.2 µ Bo ⎜ ln
re ⎞

⎝ rw ⎠
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Skin Effect

Any alteration (restriction or enhancement) to the radial flow in


the formation and at the wellbore is represented by the Skin
Factor (s).

When the alteration is a restriction to the flow, the skin is


positive (s>0).

When the alteration is an enhancement to the flow, the skin is


negative (s<0).

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Darcy’s Law including Skin
(Pseudo Steady State)

k h (Pr − Pwf )
q=

141.2 µ Bo ⎜ ln
re
− 0.75 + s ⎞⎟
⎝ rw ⎠

Pr is the average reservoir pressure

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Darcy’s Law including Skin
(Steady State)

k h (Pr − Pwf )
q=

141.2 µ Bo ⎜ ln
re
− 0.5 + s ⎞⎟
⎝ rw ⎠

Pr is the average reservoir pressure

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Skin & Formation Damage

• A well without restriction to flow has a zero skin (s = 0),


• A positive skin represents a restriction to flow but not
necessarily a formation damage,
• Can be due to a mechanical restriction to flow (e.g. collapse
perforations, gravel pack, etc),
• The purpose of matrix treatment in sandstones is to remove
the damage and reduce the skin to zero (typically, s < 5),
• There is no limit of a positive skin – a cased well before
perforating has an infinite skin (s = ∞).

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Skin & Flow Enhancement

• A negative skin represents an improvement over the natural


flow capacity,
• A well with a negative skin is said to be Stimulated,
• After acidizing, carbonate formations might present negative
skins,
• Deviated wells have negative skins,
• Hydraulic fractures provoke negative skins,
• Is there a limit for a negative skin?

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Negative Skin

k h (Pe − Pwf )
q=
141.2 µ Bo ⎛⎜ ln e + s ⎞⎟
r
⎝ rw ⎠

k h (Pe – Pwf) ≥ 0 re ln re/rw

141.2 µBo(ln re/rw + s) > 0 300 6.74


500 7.26
S > - ln re/rw 1000 7.97

rw = 4.25” = 0.35 ft

s>-8

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Reservoir Model of Skin Effect

Bulk
formation
Altered
zone

ka
h

rw

ra
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Reservoir Pressure Profile
2000
Pressure, psi

1500

1000
∆ps

500
1 10 100 1000 10000

Distance from center of wellbore, ft 20


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Skin and Pressure Drop

0.00708 k h
s= ∆p s
qBµ

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Skin and Pressure Drop

141.2qBµ
∆p s = s
kh

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Skin Factor and Properties
of the Altered Zone

⎛k ⎞ ⎛ ra ⎞
s = ⎜⎜ − 1⎟⎟ ln⎜⎜ ⎟⎟
⎝ ka ⎠ ⎝ rw ⎠

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Skin Factor and Properties
of the Altered Zone

k
ka =
s
1+
ln(ra rw )

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Effective Wellbore Radius

⎛ rwa ⎞
s = − ln⎜⎜ ⎟⎟
⎝ rw ⎠
−s
rwa = rw e

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Geometric Skin - Converging Flow to
Perforations

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Geometric Skin - Partial Penetration

hp

27
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Partial Penetration

h1
ht
s= sd + s p
ht hp
hp

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Partial Penetration
Apparent Skin Factor

h1D = h1 ht 1
A=
h1D + h pD 4
h pD = h p ht

1
1 B=
rw ⎛ kv ⎞ 2
h1D + 3h pD 4
rD = ⎜⎜ ⎟⎟
ht ⎝ kh ⎠

⎛ 1 ⎞ π 1 ⎡ h pD ⎛ A − 1 ⎞ 2
1 ⎤

sp = ⎜ − 1⎟ ln + ln ⎢ ⎜ ⎟ ⎥
⎜ h pD ⎟ 2rD h pD ⎢ 2 + h pD ⎝ B − 1 ⎠ ⎥
⎝ ⎠ ⎣ ⎦
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Geometric Skin - Deviated Wellbore

s = sd + sθ

h
θ h secθ

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Deviated Wellbore
Apparent Skin Factor

⎛ kv
−1 ⎜
⎞ h kh
θ w' = tan tanθ w ⎟ hD =
⎜ kh ⎟ rw kv
⎝ ⎠

2.06 1.865

⎛ θ w' ⎛ θ w'⎞ ⎛ hD ⎞
sθ = − ⎜ ⎟ −⎜ ⎟ log⎜ ⎟
⎜ 41 ⎟ ⎜ 56 ⎟ ⎝ 100 ⎠
⎝ ⎠ ⎝ ⎠

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Geometric Skin - Well With Hydraulic Fracture

Lf

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Completion Skin
rw

s = s p + sd + sdp
kdp rdp
rp
kR

Lp
⎛ h ⎞⎛ rdp ⎞⎛ k R k R ⎞
sdp =⎜ ⎟⎜ ln ⎟⎜ − ⎟
kd ⎜ L p n ⎟⎜ rp ⎟⎜ k dp k d ⎟
⎝ ⎠⎝ ⎠⎝ ⎠

rd
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After McLeod, JPT (Jan. 1983) p. 32.
Gravel Pack Skin

Cement

k R hLg
s gp = 2
2nk gp rp

Lg
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Productivity Index

q
J≡
p − p wf

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Flow Efficiency

Jactual p − p wf − ∆p s
Ef ≡ =
Jideal p − p wf

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Damage Characterization

• Damage characterization is complex

• Normally, more than one type of damage

• Production history is fundamental to identify source of


damage and damage mechanisms

Production data Damage Mechanisms Damage types

Expert system
(StimCADETM)
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Types of Damages

Induced Produced

• Solids • Fines migration


• LCM/Kill Pills • Swelling clays
• Incompatibility of waters • Organic deposits
• OBM (cationic emulsifiers) (paraffins, asphaltenes)
• Invasion of fluids (water & • Mixed deposits
emulsion block) • etc
• Bacteria
• etc

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Solids Invasion

Solids invasion can be produced by an external source (during a


work-over, for example) or during production (fines migration).

Solids have to be extremely small to penetrate into the pore


throat.

k Dpore in mm
D pore = 2 × k in Darcies
10 Π φ
6
f in fraction

Normally, external solids plug the formation at sand face.

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Solids Invasion - Mitigation

Mitigation:
Any treatment fluids to be filtered to 2µ.
500

A (2.5 ppm)
(A) Bay Water Filtered
Permeability (md)

Through 2um Cotton Filer


100
(B) Bay Water
Through 5um Cotton Filter

(C) Produced Water Untreated


50
C (94 ppm)
(D) Bay Water Untreated
D (436 ppm)

10
0 0.02 0.04 0.06 0.08 0.10

Volume Injected (gal/perf)

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Fines Migration

• Fine = particle with 44 µ or less. Normally, clays and silts.


• Some clays (kaolinite, for example) may be destabilized and
will produce fines that will plug, partially or completely, the
wellbore.
• Fines can not be controlled, they need to be dissolved.
• Contrarily to sand grains, fines due to their very small
dimension do not cause any harm to the well completion
equipment.

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Identification of Fines Migration

• Turbidity of produced water

• Production declines with increased flow rate (increased


wellhead choke size)

• Fines are not soluble in HCl

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Fines Migration Mitigation

Sandstone Formations:
• Reduce production rate
• Acidize with HCl-HF
• Remove with suspending agents and use N2 fluids

Carbonate Formations:
• Reduce production rate
• Acidize with HCl (don’t use HF)
• Remove with suspending agents and use N2 fluids
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Pore throat

Pore
Throat Pores Provide the
Volume to Contain
Hydrocarbon Fluids

Pore Throats Restrict


Fluid Flow

Scanning Electron Micrograph


Norphlet Formation, Offshore Alabama, USA

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Kaolinite

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Swelling clays: Smectite

• Some clays “swell” when in contact with water with different


salinity.

• The increase in volume restricts the pore throat and


consequently reduces the permeability.

• Smectite is a common swelling clay.

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Smectite

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Scale

•Inorganic mineral deposits.


•Formed due to supersaturation at
wellbore conditions or commingling of
incompatible fluids.
•Form in the plumbing system of the
well, in the perforations/near wellbore
formation

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The Scaling Process

Saturated brines may form precipitates when mineral


equilibrium concentrations are exceeded (supersaturation) due
to:
ƒ Increased mineral concentration
ƒ Change in temperature, pressure or pH
ƒ Mixing incompatible waters

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The Scaling Process

Dissolution
Mineral matter
dissolves in water

Transportation
Produced water carries
minerals through formation
wellbore and tubing

Deposition
Changes in water causes
supersaturation and precipitation.
Scale adheres and grows

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The Nucleation

Supersaturation Ion pairs Clusters / Nuclei

Ba2+ SO42 Ba2+ SO42

Transient Stability
Ba2+ SO42

Imperfect Crystallites
Further growth at sites of
crystal imperfections

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Solubility of various minerals

Scale Solubility mg/liter


Sodium Chloride 318,300.0
Calcium Sulfate 2,080.0
Calcium Carbonate 53.0
Barium Sulfate 2.3

In distilled water

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Calcium Carbonate precipitation

Pressure ↓ pH ↑ Solubility ↓ Precipitation

In presence of CO2 Solubility ↓

Temperature ↑

Without CO2 Slight Solubility ↑

NaCl concentration higher than 10% decreases CaCO3 solubility

Mitigation: CaCO3 and MgCO3 dissolve in HCl


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Calcium Sulfate precipitation

Forms
ƒ Gypsum (CaSO4
2H2O)
Mitigation
ƒ Anhydrite (CaSO4)
Mechanical removal

Precipitation caused by
ƒ Pressure drop
ƒ Temperature change
ƒ Incompatible waters
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Barium Sulfate precipitation

ƒ Mixing incompatible waters


ƒ Common occurrence during water flood breakthrough
ƒ Decreasing temperature (more significant at high salt
concentration)
ƒ Decreasing pressure

Mitigation

Mechanical Removal

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Iron Scales

Types
ƒ Iron Carbonate
ƒ Iron Sulfide Mitigation
ƒ Iron Oxide
Precipitation mechanism Dissolve in HCl
ƒ Aeration (oxidation)
ƒ pH, pressure or
temperature change
ƒ Corrosion products

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Precipitation of Iron Compounds

Fe+3, ppm
•Ferric ion – Fe+3 precipitates 3000
as Fe(OH)3 at pH < 2
•Ferrous ion – Fe+2 2000
precipitates as Fe(OH)2 at pH
≈7
1000
•As the pH of spent acid is
around 5, ferrous ion
0
precipitates on surface 0.5 1 1.5 2 2.5 3 7.2 8

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Precipitation of Iron Compounds - Mitigation

Mitigation:
• Iron concentration in treatment fluid < 100 ppm (clean tanks
and equipment)
• In matrix acidizing, maintain pH very to prevent precipitation
of Fe+3
• Use reducers to reduce Fe+3 to Fe+2

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Paraffins

• Complex molecules (C18H38 to C40H82)


• Precipitates at cloud point (temperature at which first fraction
precipitates).

Mitigation:
Soluble in distillates, aromatics and carbon disulfide.
Keep temperature above cloud point (if possible).

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Asphaltenes

•Precipitation of asphaltic colloidal molecules dispersed by


maltenes.
•Precipitation of hard deposits just below bubble point.
•Precipitation of sludge and solid emulsions due to contact with
acids or addition of surfactants.
Mitigation:
Prevention with addition of special agents, replacing the
maltenes.
Difficult to dissolve. Mechanical removal necessary in many
cases.
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Mixed Deposits

• Mixtures of fines, organic and inorganic deposits.


• Require extensive laboratory studies to design treatment and
define treatment fluids.

Mitigation:
Aromatic solvents normally used to dissolve organic precipitates.
Acids to dissolve fines.
Special solvents to dissolve scales.

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Drilling Damage

• Filter cake should prevent extensive damage to formation during


drilling
• Mud filtrate might cause clay destabilization, emulsions, water blocks
• Low permeability (~ 0.001md) filter cake will be damaging during
production
ƒ formation permeability may be impaired
ƒ potential plugging of screen/ gravel pack
• Openhole completions do not have perforations or fractures to
bypass any damage
• Filter cake removal maybe a necessity!
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Filter Cake

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Drilling Fluids Damage

Drilling Fluids Solids Oil Based Muds


• Plugging formation face • High solids content
• Relative permeability
• Very small solids invasion
• Emulsifiers (cationic)
Drilling Fluid Filtrate
• pH, Salinity
• Capillarity (high penetration)
• Scales
• Clays disturbance
• Cooling
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Cementing Damage

Washes & spacers Mitigation:


Mitigation:
ƒ Destroy mud cake Controlled
Controlledfluid
fluidloss
loss
ƒ Dispersants Perforation
Perforationlength
length
ƒ Filtrate invasion (few inches)
Cement slurries
ƒ High pH
ƒ Precipitation CaCO3
ƒ Free H2O water block (small penetration)
Squeeze
ƒ Formation breakdown 65
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Perforation Damage

Radial Distance (mm)

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Damage in Water Injectors

• Solids plugging (filter to 2µ)


• Disturbance of clays (include clay stabilizer in injection water)
• Scales due to incompatibility of waters (lab tests)
• Plugging by ferric compounds (include iron sequestering
agents)
• Bacteria (include bactericide)

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Damage in Steam Flooding

• Caused by the dissolution of materials due to temperature


and high pH.
• Dissolution of calcareous materials provoke sand
deconsolidation.
• Dissolution of siliceous materials can provoke precipitation
in zones with lower temperatures and pH.
• May for scales of calcium carbonate and amorphous silica.

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Damage in CO2 Flooding

• Precipitation of asphaltenes when in contact with oil


(specially in presence of water).
• Precipitation of scales due to acidic conditions.
• Dissolution of rock cementing materials and deconsolidation
of sand.

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Damage in Polymer Flooding

• Gel residues.
• Fines transportation by gels.

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Damage in Injectors

In Injectors Wells, damage materials can deposit very deep in


the reservoir and their removal might be very difficult.

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Emulsions (Emulsion Block)

• A stable dispersion of two immiscible fluids.


• Formed by invasion of filtrates into all zones or co-mixing of
oil-based filtrates with formation brines.
• Stabilized by fines and surfactants
• Mitigation: Solvents

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Wettability Changes

• Caused by invasion of completion or workover fluids.


• Surfactants may displace the water film around pores
surfaces and replace it by a oil film.
• Changes in relative permeability.
• Mitigation: Solvent & Water-Wet
Surfactant.

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Water Block

A reduction in effective
or relative permeability 1 1
to oil due to increased Water Wet

water saturation in the Oil Wet

near wellbore region.


Kro
Kro Krw
Krw

Favored by pore-lining
clay minerals (Illite)
Mitigation: Reduction of 0

interfacial tension using 0 Swc


Sw
1-Sor 1

surfactants/alcohol's in Wettability change


acid carrier
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Gravel Pack

• Poor or incomplete gravel placement


ƒ (too many perforations, small diameter)

• Polluted pack
ƒ (formation sand, fines, wellbore residues, gel residues)

• Poor screen selection (pseudo-skin)

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Production Damage

Fines Migration/Bridging

Precipitation Scale, Paraffins..


High
Drawdown
Increased Effective Stress

In Situ Distillation/Wettability Changes

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Identification of Formation Damage and
Lithology in Cased Hole

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Identification of Formation Damage

Pressure gauge
ƒ drawdown and buildup tests (skin factor)
ƒ real-time gauges
ƒ memory gauges
Production Logging (PLT)
ƒ identify flowing interval and flowing anomalies (x-flow)
ƒ real-time or memory

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Identifying Lithology across Casing

• Infer formation damage by lithology


• Select right remedy for different lithology

• RST SpectroLith processing


ƒ Quantify formation rock volume behind casing
ƒ Formation evaluation in the absence of openhole logs

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Elements Measured with Wireline Tools

Natural Gamma Ray spectroscopy (NGT)


ƒ Th, U, K
Induced neutron activation (AACT)
ƒ Al
Induced thermal neutron gamma ray spectroscopy
(RST)
ƒ Si, Ca, Fe, S, Ti, Gd

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Reservoir Saturation Tool (RST)

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RST Spectral Analysis

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Spectrolith® Processing

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Spectrolith® Processing

Volume of oil
corresponds to
inputs from
lithology and
porosity.

Client Porosity & Lithology RSTPro Porosity & Lithology


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Damage Sample Testing and Diagnosis

START No No
Yes
Organics Yes Yes Yes
No
Yes

No Yes
Yes

No
No

Yes No
Yes

Yes No
Yes

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