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Syllabus
UNIT I ( Page No. 1-10)
Nucleus and Its Basic Features: Nuclear structure, Nuclear forces and their properties,
Nuclear binding energy, Nuclear stability, Nuclear radius and its measurement, Nuclear
spin, Nuclear magnetic and Electrical moments.
UNIT II ( Page No. 11-15)
Nuclear Models: Single particle model, Liquid drop model and Semi-Emperical mass
formula, Nuclear potential and Shell model, Collective model.
UNIT III
Nuclear Reaction: Nuclear reaction and Laws of conservation, Types of nuclear
reaction, Mechanism of nuclear reaction-Q value, Nuclear fission and their explanation
by liquid drop model, Nuclear fusion and its applications.
UNIT IV ( Page No. 16-22)
Radioactivity: Radioactive disintegration, Decay constant, Half life period and Mean
life, Alpha decay, Beta decay, Gamma decay, Interaction of nuclear radiation with
matter.
UNIT V ( Page No. 23-33)
Accelerators: Mass spectrograph: General principle, Aston’s Mass Spectrograph Van de
Graph Generator, Cyclotron, Synchrotron. Detectors: G M Counter, Scintillation counter,
cloud chamber, Bubble Chamber, production and detection of neutrons and Gamma-
photon. Application of Nuclear Techniques: Nuclear magnetic resonance, positron
emission topography, radiotracer techniques and applications in material science and
agriculture.
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Nucleus And Its Basic Features
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SOME BASICS
Isotopes:- The atoms having same atomic number but they have different atomic mass
number are called Isotopes.
Example:- H11 , H12 , H13 O16 17 18
8 , O8 , O8 C612 , C614 35
Cl17 37
, Cl17 ,
Isobar:- The atoms having same atomic mass number but different atomic number
are called as Isobar.
Example:- H13 , He32 Li73 , Be74
Isotones:- The atoms having same number of neutrons are called Isotones .
Example:- He32 , H11
Symbol Of Atom:- XzA
Where X= Element, Z= Atomic Number, A= Atomic Mass Number.
For Example:-
(i) H11 (ii) U92
235
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Mirror Nucleus:- The two nucleus are said to be mirror nucleus if :–
(i) Both have same mass number .&
(ii) Number of Neutrons in first nucleus is equals to number of
Protons in second nucleus.
Example:- (a) H1 ,
3
He32 (b) N715 , O15 8
p=1 p=2 p=7 p=8
n=2 n=1 n=8 n=7
Nucleus:- The smallest centre of atom in which entire positive charge and almost
entire mass is concentrated called Nucleus of atom .
Composition of nucleus:-
Electron proton theory:- Before the discovery of neutron it was believed that nucleus
contains electrons and protons inside it due to following facts:-
(a) The emission of Alpha (α) particle from radioactive nucleus confirm the existence
of proton inside the nucleus.
(b) The emission of Beta (β) particle from the nucleus confirm the existence of
electron inside the nucleus .
But electron - proton theory was failed due to following facts:-
(a) This theory could not explain neutrality of atom
Hence according to this atom is not neutral but we know that total charge on
atom is zero
it means atom is neutral .
(b) According to Heisenberg principle it was proved that electron cannot exist
inside the nucleus,
from Heisenberg principle :-
ђ h
∆x . ∆p ≥ , {ђ = }
2 2π
h
∆x . ∆p ≥
4π
The Maximum uncertainty in position of electron inside the nucleus = diameter of
nucleus
∆xmax = 2 × radius of nucleus
∆xmax = 2 × 10−14 m
h
Hence ∆pmin = = 2.64 × 10−21 kgm/sec
4π∆xmax
(∆pmin )2
Now K. E. = = 23.9 Mev
2m
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Hence the minimum kinetic energy of electron to exist inside the nucleus is 24 MeV.
But was found that maximum kinetic energy of electron which is emitted from the
nucleus is 4 MeV hence electron cannot exist inside the nucleus
Proton neutron theory of nucleus:- This theory was introduced after the discovery of
neutron in 1932 by Chadwick, according to this theory protons and neutrons exist
inside the nucleus and on the basis of this theory all the nucleus normal can be
explained
(i) Electrical neutrality of atom :-
Properties of nucleus:-
(i) Radius of nucleus:- From α-scattering experiment it was found that the nucleus
has finite size and from scattering experiment with electron, proton and neutron
it was observed that volume of nucleus is directly proportional to atomic mass
number a number A of nucleons.
4
i.e. πR3 ∝ A
3
R3 ∝ A
1
R ∝ A3
R = R 0 A1/3 , where R 0 = 1.1 × 10−15 m , A = atomic mass no.
(ii) Mass of nucleus:- The mass of nucleus is expressed in terms of amu atomic
mass unit which is defined as:-
𝟏𝐚𝐦𝐮 = 𝟏. 𝟔𝟕 × 𝟏𝟎−𝟐𝟕 𝐤𝐠
If atomic mass number of nucleus is A then :-
Mass of nucleus = A amu =A× 1. 𝟔𝟕 × 𝟏𝟎−𝟐𝟕 𝐤𝐠
(iii) Density of nucleus:-
Mass of Nucleus
ρ=
Volume of Nucleus
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−𝟐𝟕
A×1.𝟔𝟕×𝟏𝟎 𝐤𝐠
ρ= 4
πR3
3
A × 1. 𝟔𝟕 × 𝟏𝟎−𝟐𝟕
ρ=
4 1/3 3
3 πR 0 (A )
3 × 1. 𝟔𝟕 × 𝟏𝟎−𝟐𝟕
ρ= kg/m3
4π × (1.1 × 10−15 )3
ρ = 3 × 1017 kg/m3
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Magnetic moment of nucleus:- Total magnetic moment of nucleus is the vector sum of
magnetic moment due to orbital and spin motion of protons and its is given by μ =
μN g N I .
μ = Nuclear Mgnaton
J
μN = 5.05 × 10−27
T
I= Nuclear Spin
Mass defect:- It was found that mass of stable nucleus is always less than the total
mass of its nucleons off list of the difference between mass of nucleons and the mass of
nucleus is called mass defect.
Mass Defect = Mass of Nucleons – Mass of Nucleus
p
∆m = Mz + (A − Z)Mn − M
Z= atomic no. (no. of protons)
A=atomic mass no.
(A-Z) = no. of nutrons
𝐌𝐧 = Mass of nucleus
Note 1 :- We know that 𝐌𝐩 ≈ 𝐌𝐧
p
∆m = Mz + (A − Z)Mn − M
∆m = Amp − M
p
Note 2 :- If atomic mass is ∆m = Mz + (A − Z)Mn − M
∆m = Z(Mp + Me ) + (A − Z)Mn − MzA
∆m = Z(MH ) + (A − Z)Mn − MzA
Packing factor:- It represent the difference of atomic mass from atomic mass number
per unit atomic mass number hence it is
MzA − A
f=
A
A
Mz = atomic mass
A=Atomic mass no.
Case 1:- f>0 , for stable nucleus .
Case 2 :- f<0 , for less stable nucleus .
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Note:- Binding energy per nucleon is more important than binding energy and higher
value of binding energy per nucleon indicates that the nucleus is more stable.
Relation between binding energy per nucleon and atomic packing factor:-
∆E = ∆mc 2
∆E = {Z(MH ) + (A − Z)Mn − MzA }c 2
∆E Z Z MzA 2
= { (MH ) + (1 − ) Mn − }c
A A A A
MzA − A MzA
[Note: −if , f= then =1+f]
A A
∆E Z Z
Hence = { (MH ) + (1 − ) Mn − (1 + f)} c 2
A A A
Note 1:- If ∆M is in Kilogram then for binding energy we should have the formula :-
∆E = ∆mc 2
Note 2:- If ∆M is in amu then for binding energy we should have use- ∆E = ∆m ×
931 Mev
Binding energy curve and nucleus stability :-The graph between binding energy per
nucleon and atomic mass number is called binding energy per nucleon with the help of
binding energy curve we get following
results for different nucleus :-
(i) Binding energy per nucleon is very
less par for lighter Nucleus.
(ii) Binding energy per nucleon
increases rapidly up to mass no.20 and
there are peaks for nucleus𝐇𝐞𝟒𝟐 , 𝐁𝐞𝟖𝟒 ,
𝟖 which indicate that these
𝐂𝟔𝟏𝟐 , 𝐎𝟏𝟔
Nucleus are more stable than its
neighbouring and nucleus.
(iii) After mass number 20 the binding
energy per nucleon increases gradually
and for mass number between 40and
120 the curve is Flat and the average value of Binding energy per nucleon is in this
region is about 8.5 Mev and it is maximum for Fe5626 and it is 8.8 Mev .
(iv) After mass number 120 binding energy per nucleon decreases for the heavier
nucleus .
(v)The Binding Energy per nucleon give the measure of
(vi) nucleus stability greater the Binding energy per nucleonnucleus is more stable .
Nuclear force:- The nucleus of an atom is a small sphere of diameter metre and
protons and neutrons are placed inside it. Due to electrostatic introduction it will
protons there is strong repulsion Electricals electron force try to them apart where
gravitational force between nucleon so try to hold together .
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The gravitational force and electrical force between two protons is :-
1 q1 q 2
Fe =
4πε0 r 2
9
( 1.6 × 10−19 )2
Fe = 9 × 10 × … … . (i)
r2
M1 M2
FG = G 2
r
−11
( 1.67 × 10−27 )2
FG = 6.67 × 10 × … … . (ii)
r2
Fe 9 × 109 × ( 1.6 × 10−19 )2
=
FG 6.67 × 10−11 × ( 1.67 × 10−27 )2
Fe
= 1.238 × 1036
FG
Fe = 1036 FG
In Short range strong attractive force acting between nucleons (p-p , n-n, n-p )
which overcome the repulsive force between protons is called Nuclear Force .
The Nuclear forces can be given as :- FN ≈ 100Fe
Hence :- FG : Fe : FN = 1: 1036 ∶ 1038
Properties nuclear force:-
(i) Nuclear forces are strongest forces but effective for very short range (10−14 m).
(ii) Nuclear forces are charge independent i.e (Fp−p = Fn−n = Fp−n
(iii) Nuclear forces are spin dependent . It is observed that the force between two
nucleons having same spin is greater than the two nucleons having been anti
parallel spin . F↿↾ > F↿⇂
(iv) Nuclear forces or non central forces .
(v) Nuclear forces are saturated forces.
(vi) A nucleon inside the nucleus experiences the force due to its nearest
neighbouring Nucleon
(vii) Nuclear forces are exchange forces . In 1935 Yukawa propose that nuclear forces
between two nucleons is the result of exchange of π − meson.
p → n + π+
n → p + π−
p → p + π0
n → n + π0
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N= Z for Z < 20 .
For heavier Nucleus (N>20 , Z>20) the curve bend
towards N axis. Because coulomb electrostatic repulsion
becomes important for range values of Z therefore to
compensate the repulsive force, the attractive force
between nucleons must increase. for this number of
neutrons must be greater than the number of protons
hence for heavy stable nucleus N/Z ratio will always
be greater than Unity .for maximum stability there
is an optimum ratio of N/Z and it is 1.5 .
4 3 2
1 3 πr ρ × 4πr drρ
dE =
4πε0 r
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1 16 2 2 4
dE = π ρ r dr
4πε0 3
The electrostatic energy of a nucleus having energy are :-
1 16 2 2 R 4
E= π ρ ∫ r dr
4πε0 3 0
1 16 2 2 R5
E= π ρ
4πε0 3 5
1 16 4 2 R5
E= π2 (Ze⁄ πR3 )
4πε0 3 3 5
2
1 16 2 4 3 R5
E= π (Ze⁄ πR )
4πε0 3 3 5
1 3 Z 2 e2
E= … … … . (iii)
4πε0 5 R
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1 e
φ=
4πϵ0 (a2 + r 2 − 2raCosα)1/2
1 e
φ= 1/2
4πϵ0 r 2 2rCosα
a (1 + ( ) −
a a )
1 e r 2 2rCosα −1/2
φ= (1 + ( ) − )
4πϵ0 a a a
2
1 e 1 2r r2 1.3 2r r2
φ= {1 + ( cosα − 2 ) + ( cosα − 2 ) + ⋯ … … … … }
4πϵ0 a 2 a a 2.4 a a
1 e r r 2 3Cos 2 α 1
φ= {1 + cosα + 2 ( − ) + ⋯…………}
4πϵ0 a a a 2 2
2 2
1 e ercosα er 3Cos α 1
φ= { + + 3 ( − ) + ⋯ … … … … } … … (i)
4πϵ0 a a2 a 2 2
1
Form equation (i) :- Coefficient of = monopole strength
a
1
Coefficient of = z component ofdipole moment
a2
1
Coefficient of = z component ofquadrupole moment
a3
er2
Hence Quadrupole Moment :- Q= (3Cos2 α − 1)
2
er 2 z 2
Q= {3 ( ) − 1}
2 r
e
Q = {3z 2 − r 2 }
2
Case 1 :- If x=y=z , then 𝐫 = 𝟑𝐳 ,
𝟐 𝟐
hence Q=0 , In this condition Shape will be Spherical and Most Stable .
Case 2 :- If 𝟑𝐳 𝟐 > 𝐫 𝟐 ,
Hence 𝐐 = +𝐯𝐞 , In This Condition Shape will be Ellipse elongated
along z axis .
Case 2 :- If 𝟑𝐳 𝟐 < 𝐫 𝟐 ,
Hence 𝐐 = −𝐯𝐞 , In This Condition Shape will be Ellipse Contracted
along z axis .
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Nuclear Models
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on the basis of above argument single particle model was proposed and
according to this model:-
Even- even nucleus (even number of neutron and proton ) are assume to made of
α- particles which are closely packed within the nucleus and the major part of binding
energy is shared by α-particles and rest in the form of α- particle bonds.
This model explain emission of Alpha particle and ground state of even - even
nucleus up to few excited state.
Failure of Alpha particle model:- This model was failed due to following reasons:-
a) If we consider a nucleus of mass number A= 4n+ 2. Which may be described as ,
”consisting of an α- particle and two extra nucleons , or (n + 1) α- particle and two
holes then two alternative conjugations are different and actually different from
true conjugation.
b) This model is not capable to explain low energy α- particle scattering.
Hence this model was rejected
In 1936, Niels Bohr suggested that the nucleus might be like a droplet of dense and
incompressible liquid composed of sub droplets of protons and neutrons which are
imagine to interact strongly with each other like the molecules in a drop of liquid .
Hence , nucleus is similar to a small droplets of liquid composed of molecules.
Similarity between nucleus and Liquid Drop:- There are following similarities
between nucleus and small drop of liquid-
a) Radius of nucleus ∝ 𝐴1/3 , (no. of nucleons)1/3
Similarly , Radius of liquid drop ∝ (no. of molecules)1/3
b) Density of nucleus as well as Liquid Drop is size-independent .
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c) Binding energy of nucleus is ∝ number of nucleons.
Similarly, The energy required to vaporize a Liquid Drop is also ∝ number of molecules
present in Liquid Drop.
d) Both , nucleons of a nucleus and molecules of a liquid drop interact with their
closest neighbours.
e) Shape of nucleus is maintained by binding energy. Similarly, shape of Liquid Drop
is maintained by surface tension.
f) Fission :-Nuclear fission , a heavier nucleus decompose into small nucleus point
similar to big liquid drop break into small droplets .
235 236
𝑈92 + 𝑛10 𝑈92 𝐵𝑎141 92 1
56 + 𝐾𝑟36 + 3𝑛0 + 𝑒𝑛𝑒𝑟𝑔𝑦
g) Fusion :- Small nucleus are combined together to form a big nucleus . In the same
way , when small droplates of liquid are combined , then a big drop of liquid is
form .
Limitations of liquid drop model:-
a) This model couldn’t explain the number of protons and number of neutrons are
equal for lighter and unequal for heavier nucleus.
b) Failed to explain the isotopes of nucleus.
c) According to this model, the nucleus containing more neutrons in comparison to
protons are more stable. But in case of radioactive elements, rivers result are
observed.
Explanation of nuclear fission by Liquid Drop model :-
The first satisfactory description of nuclear fission is given by Niels Bohr and
wheeler in 1939 .
On the basis of Liquid Drop model of nucleus,
According to this nucleus behave like incompressible drop whose shape is decided by
nuclear force and electrostatic repulsive force and the nuclear force are symmetrical to
surface tension which tense to make drop is spherical in shape while the electrostatic
repulsive force tend to distort comma the spherical shape but nuclear forces are
stronger than electrostatic forces hands, the spherical shape of nucleus is maintained.
When energy is given to the nucleus by slow neutrons, the nucleus is excited and
oscillations are set up in the nucleus and spherical shape is distorted. When the
amplitude of oscillations becomes larger than the nucleus break into smaller nucleus
due to electrostatic repulsive force.
235 236 141 92
𝑈92 + 𝑛10 𝑈92 𝐵𝑎56 + 𝐾𝑟36 + 3𝑛10 + 𝑒𝑛𝑒𝑟𝑔𝑦
The nuclear mass can be expressed in the form of series of binding energy terms.
Then, this expression is known as “semi empirical mass formula ” which is partially
based on the theory and partially on empirical measurements.
We Know that ,
Binding Energy of Nucleons :-
∆𝐸 = {𝑍𝑀𝑝 + (𝐴 − 𝑍)𝑀𝑛 − 𝑀}𝑐 2
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∆𝐸
= {𝑍𝑀𝑝 + (𝐴 − 𝑍)𝑀𝑛 − 𝑀}
𝑐2
∆𝐸
𝑀 = 𝑍𝑀𝑝 + (𝐴 − 𝑍)𝑀𝑛 − 2 … … (𝑖)
𝑐
In liquid Drop Model , the nucleus is treated as Liquid drop . Then the binding energy is
given by :-
∆𝐸 = 𝐸𝑉 + 𝐸𝐶 + 𝐸𝑆 + 𝐸𝑃 + 𝐸𝑄 … … … . (𝑖𝑖)
Where ,
𝐸𝑉 = 𝑎𝑉 𝐴 , Volume energy term is arises due to assembling of neutrons inside the
nucleus .
𝐸𝑆 = −𝑎𝑠 𝐴2/3 , Surface energy term due to surface area of nucleus , this increase the
binding energy .
𝑍(𝑍−1)2
𝐸𝐶 = −𝑎𝐶 1/3 , Coulomb energy term , arises due to mutual repulsion of protons
𝐴
inside the nucleus, this increases the binding energy.
(𝐴−2𝑍)2
𝐸𝑎 = −𝑎𝑎 , Asymmetric energy term , arises due to difference between number
𝐴
of protons and neutrons . this increases the binding energy.
+𝑎𝑝
𝐸𝑝 = 3/4 , For even – even nucleus , pairing energy terms arises due to grouping of
𝐴
protons and neutrons .
And = 0 ,for odd-even , even – odd nucleus .
−𝑎𝑝
= 3/4 , for odd-odd nucleus .
𝐴
Using the value of 𝐸𝑉 , 𝐸𝐶 , 𝐸𝑆 , 𝐸𝑃 𝑎𝑛𝑑 𝐸𝑄
2/3
𝑍(𝑍 − 1)2 𝑎𝑝
∆𝐸 = 𝑎𝑉 𝐴 −𝑎𝑠 𝐴 −𝑎𝐶 ±
𝐴1/3 𝐴3/4
Hence from the equation ,
1 𝑍(𝑍−1)2 𝑎𝑝
Mass of Nucleus , 𝑀 = 𝑍𝑀𝑝 + (𝐴 − 𝑍)𝑀𝑛 − 2 {𝑎𝑉 𝐴 −𝑎𝑠 𝐴2/3 −𝑎𝐶 ± }
𝑐 𝐴 1/3 𝐴 3/4
Here,
𝑎𝑉 = 14.01 𝑀𝑒𝑣
𝑎𝑠 = 13 𝑀𝑒𝑣
𝑎𝑐 = 0.595 𝑀𝑒𝑣
𝑎𝑎 = 19 𝑀𝑒𝑣
𝑎𝑝 = 33.5 𝑀𝑒𝑣
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This model was developed around 1949, which is based on Pauli principal and
magic numbers.
There are certain numbers of phenomena which shows the existence of excited state of
nucleus and Sharply defined nuclear energy levels. This is similar to atomic shell model,
which describe the distribution of electrons in different energy levels of an atom.
Magic numbers :- We know that the electrons in an atom are grouped into shells and
subshells and electrons distributed in Shell according to 2 n2 , where
n=1,2,3,4,5……..(2,8,18,32 …) .
These Shells completely filled and search items are stable. A Similar situation also
exist in nucleus. The nucleus having 2, 8, 20,28, 50, 82 and 126 . Nucleons have same
condition and most stable than the nucleus of neighbouring mass numbers. These
numbers are called magic numbers and this observation is based on following facts :-
a) 𝐻𝑒24 and 𝑂816 are most stable because they have Double magic numbers .
b) Calcium (Ca , z=20) and Tin (Sn, z=50) are most stable.
c) 𝑃𝑏82208
is most stable because it contains 82 protons and 126 neutrons.
d) It is found that electric quadrupole moment of the magic number nucleus is almost
zero. Hence, they have a spherical shape and status.
According to this model the nucleons in nucleus present in a square well potential
having rounded corners in which they have separate energy levels and nucleons are
assumed to be arrange in different shells.
Limitations of nuclear shell model :- The nuclear shell model has been very
successful to explaining number of nucleons phenomena but it was not capable to
provide complete description of nucleus it fails to explain –
a) The large quadrupole moment of non magic nucleus which shows departure of
nucleus from spherical shape.
b) The ground state of nucleus is in the range 150 to 190 and A >= 220.
c) The magnetic moment of some others nucleus Where deviations are not sufficient
d) The excited state of even - even nucleus, the probability of radioactive transition
and Nuclear coulomb excitation. Can also be not explain the by this model .
Collective model
Both Liquid Drop model and shell model of nucleus describe the nuclear properties
and many others nuclear phenomena but none of them are entirely correct .
Liquid Drop model and shell model provide collective model of nucleus which is
based on following facts :-
The motion of entire nucleus with the nucleons is in ellipse Idol box that might
rotate deform itself by vibrations.
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The nucleons move in a potential which is not spherically symmetric is
considered in a shell model by considering above 2 facts, most of the nucleus
phenomena can be explained successfully.:-
a) The electric quadrupole moment of all the nucleus can be determined by using this
model.
b) The ground state and excited state of different nucleus can be explained successfully.
c) Magnetic moment of different nucleus can also be calculated with perfect accuracy.
Harmonic potential:-
𝑉 = 𝑉0 [1 − (𝑟/𝑟0 )2 ]
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Radioactivity
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Natural Radioactivity:- In 1986 Henri becquerel discover the transformation of one
element into another by emission of some particle and electromagnetic radiation. This
process is called natural Radioactivity and the substance capable to emit such
radiations is called Radioactive substance .
Example :- Uranium , Thorium, polonium etc .
Law Of Radioactive Decay:- Rutherford and Soddy study the phenomenon of
radioactivity and formulated following law of radioactive decay:-
1. The radioactivity is an spontaneous process and we cannot predict to when an
particular nucleus of atom will disintegrate.
2. When are radioactive atom disintegrates either Alpha particle or beta particle is
emitted both the particle cannot emit simultaneously.
3. The emission of 1 𝛼particle by a radioactive atom results the daughter atom whose
atomic number is it 2 unit less and mass number is 4 unit less of the parent
nucleus.
𝑋𝑍𝐴 𝛼 𝐴−4
𝑋𝑍−2
4. The emission of 𝛽 particle from a radioactive atom results the daughter atom
whose atomic number is one unit more and mass number remains same as that of
parent atom .
𝑋𝑍𝐴 𝛼 𝐴
𝑋𝑍+1
5. Number of atom disintegrate from a radioactive material at any time is directly
proportional to the number of atom present at the time.
𝑑𝑁
− ∝𝑁
𝑑𝑡
𝑑𝑁
= −𝜆𝑁
𝑑𝑡
𝑑𝑁
= −𝜆𝑑𝑡
𝑁
𝑁 𝑡
𝑑𝑁
∫ = − ∫ 𝜆𝑑𝑡
𝑁0 𝑁 0
(𝑙𝑜𝑔𝑒 𝑁)𝑁0 = −𝜆(𝑡)𝑡0
𝑁
𝑁
𝑙𝑜𝑔𝑒 = −𝜆𝑡
𝑁0
𝑁
= 𝑒 −𝜆𝑡
𝑁0
𝑁 = 𝑁0 𝑒 −𝜆𝑡
Where , 𝑁0 = no. of initial atoms
𝜆 = decay constant
𝑁 = no. of atoms present after t time
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Condition 1 :- At t=0 ;
𝑁 = 𝑁0 𝑒 −𝜆 ×0
𝑁 = 𝑁0 𝑒 0
𝑁 = 𝑁0
Condition 2 :- At t= 1/𝜆 ;
𝑁 = 𝑁0 𝑒 −𝜆 ×(1/𝜆)
𝑁 = 𝑁0 𝑒 −1
𝑁
𝑁= 0
𝑒
Condition 3 :- At t= ∞;
𝑁 = 𝑁0 𝑒 −𝜆 ×∞
𝑁 = 𝑁0 𝑒 ∞
𝑁=0
initial value.
Half-Life :- The time interval , in which 50% nucleus of radioactive material
disintegrate, is called Half Life.
𝑁0
𝑁= 𝑎𝑡 𝑡 = 𝑡 1/2
2 1
−𝜆 ×(𝑇 2 )
𝑁0 = 𝑁0 𝑒
1
𝑙𝑜𝑔𝑒 2 = 𝜆 × (𝑇 2 )
0.6932
𝑇 1/2 =
𝜆
Condition 1:- After 1 Half Life ,
1 1
𝑁 = 𝑁0 ( )
2
Condition 2:- After 2 Half Life ,
1 2
𝑁 = 𝑁0 ( )
2
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Average life or Mean life:- The mean life of radioactive material is equals to sum of
lifetime of all radioactive items divided by total number of atoms and it is reciprocal of
decay constant.
1
𝑇𝑎𝑣𝑔 =
𝜆
log 𝑒 𝑅
𝜶 −Decay :-The 𝜶 particle is the doubly ionized Helium and properties of 𝜶 particles
are
(i) Charge :- q=+2e
(ii) Mass :- 4𝑚𝑝
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The nucleus which contain more than those 210 nucleons are so large that the
nuclear force holding them together becomes insufficient to balance the electrostatic
repulsive force between protons such nucleons achieve greatest stability by emitting
𝜶 particles and 𝜶 particles have high binding energy 28 MeV . Therefore by emission
of 𝜶 particle nucleus achieve greatest stability.
Energy Relation in 𝜶 particle decay :-
For 𝑋𝑧𝐴 𝐴−4
𝑋𝑧−2 + 𝐻𝑒24 + 𝑄
𝑄 = {(𝑚𝑥 ) − (𝑚𝑦 + 𝑚𝛼 )}𝑐 2
𝑄 = [(𝑚𝑥 ) − (𝑚𝑦 + 𝑚𝛼 )] × 931.5𝑀𝑒𝑉
here negative sign shows that the daughter nuclei will require in the direction opposite
to the direction of 𝜶 particles
so that the net Momentum is still zero after emission.
2. Conservation of relativistic energy:-
For 𝑋𝑧𝐴 𝐴−4
𝑌𝑧−2 + 𝐻𝑒24 + 𝑄
Let 𝑘𝑦 = Relativistic kinetic energy of Product Nuclei
𝑘𝛼 = Relativistic kinetic energy of 𝜶 particle
Relativistic kinetic energy of Initial nuclei =0
Total Relativistic energy before emission of 𝛼 = Total Relativistic energy after emission
of 𝛼
𝐴𝑠, 𝐸 = 𝐸𝐾 + 𝑚𝑜 𝑐 2 (𝑇𝑜𝑡𝑎𝑙 𝑅𝑒𝑙𝑎𝑡𝑖𝑣𝑖𝑠𝑡𝑖𝑐 𝐸𝑛𝑒𝑟𝑔𝑦)
𝐸𝑥= 𝐸𝑦 + 𝐸𝜶
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𝑂 + 𝑚𝑥 𝑐 = (𝑘𝑦 + 𝑚𝑦 𝑐 ) + (𝑘𝜶 + 𝑚𝜶 𝑐 )
𝑚𝑥 𝑐 2 = (𝑘𝑦 + 𝑘𝜶 ) + (𝑚𝜶 + 𝑚𝑦 )𝑐 2
(𝑚𝑥 − 𝑚𝜶 − 𝑚𝑦 )𝑐 2 = (𝑘𝑦 + 𝑘𝜶 )
log 𝜆
log 𝑅
𝜸 − decay:- The emission of 𝛼 , 𝛽 particle from parent nucleus leaves the daughter
nucleus is in the excited state of higher energy . The excited daughter nucleus than
returns to ground state by a emitting one or more, photons.
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226
𝑅𝑎86
𝛼
222
𝑅𝑛86
𝛾
222
𝑅𝑛86
frequency .
following three phenomena are possible when Gamma radiation interact with matter
(i) Photoelectric effect
(ii) Compton scattering
(iii) Electron positron pair production .
1. Photoelectric effect:- In this process the gum of photon interact with an atom of
materials in such a way that all of its energy is absorbed by Bond electron of atom
and then electron is ejected who is kinetic energy is given by
𝐾𝑚𝑎𝑥 = ℎ𝜈 − 𝜑
Where 𝐾𝑚𝑎𝑥 = Maximum Kinetic energy of ejected electron.
ℎ𝜈= Energy of Photon
𝜑 = Work Function
2. Compton scattering:- In this process incoming Photon collide with free electrons of
the atoms and recoil with some scattered Photon having small energy but increased
wavelength the difference in wavelength of scattered a photon and the incident of
photon is called Compton shift which is given by.
ℎ
∆𝜆 = (1 − 𝑐𝑜𝑠∅)
𝑚𝑜 𝑐
Where ∅ = Scattering Angle
C= Speed of Light , 𝑚𝑜 = rest mass of electron
3. Electron positron pair production:- In this process the incoming Gamma Photon is
absorbed by atom then energy is released in the form of electron positron pair this
process occurs only when incoming a photon has energy at least 1.02 MeV.
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Accelerator And Detector
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Mass spectrograph
The spectrograph are used to determine the isotopic masses of all the atoms of
periodic table.
Essentials of mass spectrograph
(i) Ion source:- All the Spectrograph start with an Ion source which are
produced by electron or heating of
suitable coated filaments.
(ii) Energy, Momentum and velocity filters:-
The positive energy ions are given energy by accelerated through a
potential difference so that their energy is much greater than the initial energy
to have been of same Momentum and Mass. The ions are then passed through
electric and magnetic field which acts as Momentum and Velocity filters.
(iii) Vacuum Chambers:- This chamber provides the path to Ion beam to be
detected.
(iv) Detector:- It may use photographic plate or an electro metre.
Aston’s was first to design a mass spectrograph with high accuracy and large
sensitivity . The analysist isotopes can be done if they are converted into ionic beam
normally known as positive rays . This is done by removing outer electron from the
isotopic atoms .
Principle :- The mass spectrograph work on a simple principle and is based on the fact
that charge particle experience a force in both electric and magnetic field.
Construction And Working :-
As the Apparatus shown in the figure : The stream of positive Ion enter through
electric field maintain by Slit P1 and P2 via slit S1 and S2. Due to the electric field this
Ion beam deviated by an angle 𝜃as well as dispersed by an angle 𝑑𝜃 .
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𝑚𝑎1 = 𝑞𝐸
𝑞𝐸
𝑎1 =
𝑚
1
𝑙1 = 𝑎1 𝑡1 2
2
1 𝑞𝐸 𝐿1 2
𝑙1 = ( ) 𝐿 1
2𝑚 𝑉 𝜃
𝑙1 𝑙 1
𝜃=
𝐿1
1 𝑞𝐸 𝐿1 2 1
𝜃= ( )
2 𝑚 𝑉 𝐿1
1 𝑞𝐸 𝐿1
𝜃= … … . (𝑖)
2 𝑚 𝑉2
Now Differentiating equation (i) with respect to V :-
𝑞𝐸 𝐿1
𝑑𝜃 = − 𝑑𝑉 … … . (𝑖𝑖)
𝑚 𝑉3
𝑑𝜃 2𝑑𝑉
=− … … … (𝑎)
𝜃 𝑉
Now This deviated and dispersed Beam of Ion is now passed through magnetic field B
via Slate S3 so that this is again deviated by an angle 𝜑 and converged by an angle 𝑑𝜑
And reaches to the photographic plate S.
𝑚𝑎2 = 𝑞𝑣𝐵
𝑞𝐸
𝑎1 =
𝑚
𝐿2
𝑡2 = 𝑙2
𝑣 𝐿2
1
𝑙2 = 𝑎2 𝑡2 2
2
1 𝑞𝐵 𝐿2 2
𝑙2 =
2𝑚 𝑉
𝑙2 1 𝑞𝐵 𝐿2
𝜑= =
𝐿2 2 𝑚 𝑉
1 𝐿2
𝑑𝜑 = − 𝑞𝐵 2 𝑑𝑉
2 𝑉
𝑑𝜑 𝑑𝑉
=− … … … (𝑎)
𝜑 𝑉
BY Equation (a) and (b) :-
𝑑𝜃 2𝑑𝜑
=
𝜃 𝜑
𝒅𝜽 𝟐𝜽
=
𝒅𝝋 𝝋
𝑺𝒊𝒏𝒄𝒆, (𝒂 + 𝒃)𝒅𝜽 = 𝒃𝒅𝝋
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𝒃 𝟐𝜽
ℎ𝑒𝑛𝑐𝑒 =
𝒂 (𝝋 − 𝟐𝜽)
Advantages :-
(i) All the particles having Q/m ratio are focused at single point adverse to the
other Mass Spectrograph.
(ii) The Intensity of a line obtained on the photo plate is proportional to the total
number of particles of that mass.
Cyclotron
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Construction:- It consists of two D shaped hollow semi circular metal chamber D1 and
D2 these Chambers are called Dees . These Dees placed
horizontally with a small gap between them.
In magnetic poles and connected with high
frequency electric field. The positive ions are
produced in gap between Dees by ionization
of gas.
Working:- Consider a positive ion is produced
at the centre of GAP at that time, when D1 is
positive and D2 is negative then the positive Ion
will move from the one to the two normal to the
magnetic field due to this magnetic field provide
centripetal Force to the positive ions and it is deflected along a circular path after
moving along the semi circular path inside the D2 the positive ions reach in the gap
between the Dees at this stage the polarity of these just reversed due to alternating
voltage or D1 becomes negative and D2 will become positive. Then ions moves from
D2 to D1 and so on .
Radius of Path :-
𝐹 = 𝑞𝑣𝐵𝑆𝑖𝑛𝜃
𝜃 = 900
𝐹 = 𝑞𝑣𝐵
𝑚𝑣 2
= 𝑞𝑣𝐵
𝑟
𝑚𝑣
= 𝑞𝐵
𝑟
𝑚𝑣
𝑟=
𝑞𝐵
2𝜋𝑟
Time Period :- 𝑇 =
𝑣
2𝜋 𝑚𝑣
𝑇=
𝑣 𝑞𝐵
2𝜋𝑚
𝑇=
𝑞𝐵
Frequency :-
𝜂 = 1/𝑇
𝑞𝐵
𝜂=
2𝜋𝑚
Angular Frequency :- 𝜔 = 2𝜋𝑛
𝑞𝐵
𝜔 = 2𝜋
2𝜋𝑚
𝑞𝐵
𝜔=
𝑚
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(ii) Accelerated charge particle produced by cyclotron are used for producing high
energy neutrons .
(iii) The accelerated charge particle produce by cyclotron are used in artificial
transmutation of element .
Detectors
Nuclear radiation such as 𝛼, 𝛽 & 𝛾 rays cannot observe directly they are detected
by secondary effect which they produced in the material through which they are
passed. There are following three effects and a number of detecting instruments which
are based upon them.
1. Ionization:- A charged particle like 𝛼, 𝛽 & proton passing through material
produce ions by collision with the molecules of material. This ionisation is basic of
many detecting instruments. The various instruments differ in the material in
which organisation is produced.
Eg 1:- In ionization chamber and diesel Muller counter the ionization is produced
in a gas and the positive ions and electrons are separated by electrostatic field.
Eg 2 :- In cloud chamber the ionization is produced in a gas which is Sulphur
saturated with some vapour and the track of ions is made visible by condensation
of vapour.
2. Effect on photographic plate:- Nuclear particle made track if they travel through
the emulsion of special photographic plate. The track produced on them becomes
clear when the photographic plate is developed.
3. Fluorescence:- Nuclear radiation produce the flash of light when they fall Upon A
screen coated with fluorescent material like ZnS.
GM Counter
Gieger Muller counter is more efficient and accurate useful device to detect
particles like 𝛼, 𝛽 & X-rays.
Construction:- GM Counter consist metallic cylindrical cathode and closed in a glass
envelope. A fine tungsten wire is stretched along the axis of tube which acts as an order
these cylindrical cathode tube have a thin my car Window for entrance of particles .
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Bubble chamber
Scintillation counter
It is very sensitive for detecting high energy nuclear radiations by flow sensor
produced by certain materials called Scintillent.
Construction:- The scientist encounter consists of.
1. The scintillant material which produce flash of light photons. When charged
particle passed through it.
2. The photomultiplier which is used to convert flash of light into electrical Pulsar.
3. Electronic circuits which records and count electrical pulse.
Working:-
When radiation enters into
scientillent material it produce
flash of light for Town. The
photons Travels through
transparent photosensitive layer
( photocathode ) and eject
photoelectrons. The tube have
several electrode called diamonds
on which increasing positive
potentials are applied.
The photoelectrons are attracted
by dinod the one from which secondary
electrons are emitted. These electrons are attracted by
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D2 from where more electrons are produced and this process is further going on and
finally amplifier electrical pulse is generated which is recorded by electronic counter.
Types of scientillant material:-
1. Zinc Sulphate ( used for alpha particle )
2. Anthracene (used for beta particle )
3. Cesium Diodide ( used for gamma rays )
Advantage of scintillation counter:-
1. In this pulse height is directly proportional to the energy of incident ray.
2. Death time of scintillation counter is very small.
3. Pulse duration is very short hands resolution power is high.
4. It is used for detecting gamma rays.
Production of neutrons
1 . From radioactive source:- in this neutron source consists of our target material
with some radioactive material which supply radiation for production if neutron. The
Alpha particle emitted from radioactive material generally have energy 5 M TV since
only those nucleus can be used as target which have Alpha neutron radiation within
this energy range.
Some of radioactive source are :-
(i) Pollonium Baudium ( 𝛼 neutron sources )
(ii) Radium Berrylium (𝛼 , 𝑛 sources)
(iii) Plutonium Barium (𝛼 , 𝑛 sources)
2 . From photo neutron sources:- Photon can cause neutron emission from nucleus
provided at the energy greater than a neutron binding energy. For this purpose
beryllium dutron is used.
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4 . Nuclear reactor:- the most useful source of neutron is nuclear reactor. They are
capable of giving very high number of nucleons of order of 1014 per cm2 sec .
Detection of neutrons
Neutrons are and charged particles and do not produce ionization. Hence they
cannot detect directly from the counters. Hence the detection of neutrons will depend
on secondary effect. Cause buy neutron as a result of collision with target nucleus some
process of neutron detections are
1. Neutron induced nuclear reaction gives charge particle as a product such as
𝛼 & 𝛽 particle .
2. Induced fission in certain heavy element .
3. Elastic collision between neutron and hyduoge nucleus .
4. Capture of nucleus by certain stable isotopes which are converted into
radioactive isotopes with emission of 𝛼 & 𝛽 particle
2. Nuclear reaction
3. Neutron Gama reaction
238 239
(i) 𝑈92 + 𝑛10 𝑈92 𝛾
27 29
(ii) 𝐴𝑙13 + 𝑛10 𝐴𝑙13 𝛾
(iii) Proton - 𝛾 reaction
(i) 𝐿𝑖37 + 𝐻11 𝐵𝑒48 𝛾
(ii) 𝐴𝑙1327
+ 𝐻11 28
𝑆𝑖14 γ
4. Pair annihilation
e− + e− γ+γ
Gamma photons cannot detect directly due to being neutral but they can detect
by ionization produced by them hence they are detected by GM counter.
NUCLEAR SCIENCE BY DR. SANJAY KUMAR SHUKLA , NOTES TYPEWRITTEN BY :- M.A. REHMAN (EE 2016) (33)
(8574312292) (8574312292)