Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Office of Management
1994
Workshop Management
Host Representative
Workshop Coordinator
A Low Cost Ignitor Utilizing an SCB and Titanium Sub-Hydride Potassium Perchlorate
Pyrotechnic 61- _
Robert W.Bickes, Jr. and M. C. Grubelich, Sandia National Laboratories
J. K. Hartman and C. B. McCampbell, SCB Technologies, Inc.
J. K Churchill, Quantic-Holex
Optical Ordnance System for Use in Explosive Ordnance Disposal Activities ......... 65 _
John A. Merson, F. J. Salas and F. M. Helsel, Sandia National Laboratories
Four Channel Laser Firing Unit (LFU) Using Laser Diodes ..................... 101 ' _1
David Rosner and Edwin Spomer
Pacific Scientific, Energy Dynamics Division
iii
SESSION 2 - Electric Initiation
Low Cost, Combined RF and Electrostatic Protection for Electroexplosive Devices . .. 125 t/
Robert L. Dow, Attenuation Technology, Inc.
Cable Discharge System for Fundamental Detonator Studies .................. 149 I-'_
Steven G. Barnhart, Gregg R. Peevy and William P. Brigham,
Sandia National Laboratories
Improved Test Method for Hot Bridgewire All-fire/No-fire Data ................. 165 " !
Gerald L. O'Barr, Retired (formerly with General Dynamics)
Development and Demonstration of an NSI Derived Gas Generating Cartridge (NSGG) 177 -l(_
Laurence J. Bement, NASA, Langley Research Center
Harold Karp, Hi Shear Technology Corp.
Michael C. Magenot, Universal Propulsion Co.
Morry L. Schimmel, Schimmel Company
iv
Finite Element Analysis of the 2.5 Inch Frangible Nut for the Space Shuttle ........ 285 _ 2-
Darin McKinnis, NASA, Johnson Space Center
Portable, Solid State, Fiber Optic Coupled VlSAR for High Speed Motion and Shock
-25
Diagnostics ..................................................... 309
Kevin J. Fleming and O. B. Crump, Jr., Sandia National Laboratories
Development and Qualification of a Laser-Ignited, All-Secondary (DDT) Detonator ... 317 -_-_
Steve Tipton, Air Logistics Center (AFMC)
Thomas J. Blachowski and Darrin Krivitsky, NSWC, Indian Head MD
Panel Members:
Discussion topics:
Note: The panel discussion and open forum commenets were not recorded and are not
included in this conference publication.
V
1994 NASA AEROSPACE
PYROTECHNIC SYSTEMS WORKSHOP
-1-
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sl-_l
Update: NASA
Pyrotechnically Actuated
Systems Program
Norman R. Schulze, NASA Headquarters
Second NASA Aerospace Pyrotechnic Systems Workshop
Sandia National Laboratory, Albuquerque, NM
February 8, 1994
-13-
Agenda
I. Program Origin
I1. Program Description
III. Summary
February 8, 1994
-14-
Introduction- Pyrotechnic Systems
- Jettison
- Control flow
- Escape
- Severance
• Mission Critical
• Are required to have near perfect reliability
• But failures continue, some repeatedly
February 8, 1994
Definition
- Mechanisms
- Firing circuits
February8, 1994
February8, 1994
-16- 7
Program
February 8,1994 i 17 - 9
Future Pyrotechnic Requirements
February 8, 1994 10
12
February 8, 1994
14
February 8, 1994
February 8, 1994 16
February 8, 1994 17
- 21 -
2.1 NSGG (continued)
--@_,4_
February 8, 1994 18
February 8, 1994 20
February 8, 1994 = 23 - 21
3.1 NSGG Performance
February 8, 1994 22
February 8, 1994 - 24 -
3.2.1 NSLSS Performance
February 8, 1994 24
26
February 8, 1994
February 8, 1994 28
III. Summary
February 8, 1994
- 27 - 29
III. Summary (continued)
• Programs eliminated:
Linear Separation System
Improved safe and arm system
Advanced standard hardware
February 8, 1994 3O
- 28 -
Laser Initiated Ordnance (LIO)
Activities in NASA
- 29 -
Second NASA Aerospace Pyrotechnic Workshop
Laser Initiated Ordnance Activities in NASA
• GREATER RELIABILITY
• ENHANCED SAFETY
• LIGHTER WEIGHT
APPLICATIONS
• FLIGHT TERMINATION
• PROGRAM APPLICATIONS
- new launch vehicles
- spacecraft
3 - 30 - January 30.1_4
I Laser
Second Initiated
NASA Ordnance
Aerospace Activities
Pyrotechnic in Workshop
NASA
• LASER DIODES HAVE THE POTENTIAL FOR DESIGN OF ALL SOLID STATE
SYSTEM
• TECHNICAL
- Low voltage to activate laser
- concern over electronics setting off laser accidentally
- BIT not proven
- development of requirements necessary
• MANAGERIAL:
- Hardware not proven with operational experience
- application not mandatory for program success
- new programs wait for others to "break the ice" to reduce risks with cost, performance,
schedule
LIO PROGRAMS
January30. 1994
- Supports Project 2.4, NASA Standard Laser Diode Safe and Arm
• Goals include optimizing optical interface between the fiber and the pyrotechnic charge,
publishing a specification, and the procurement and test of devices to provide a data base
STATUS:
8 January30, 1994
!
Second NASA Aerospace Pyrotechnic Workshop I
Laser Initiated Ordnance Activities in NASA
I
• Quantify performance
STATUS:
9 - _ - Ju_3o. 1994
Laser Initiated Aerospace
Ordnance Activities in Workshop
NASA
Second NASA Pyrotechnic
THEN ......
RE-EVALUATE
IMPLEMENTATION APPROACH
12
January 30. 1994
1
Second NASA Aerospace Pyrotechnic Workshop |
Laser Initiated Ordnance Activities in NASA
1. VALIDATE FEASIBILITY
PHILOSOPHY:
- low hazard level in a controllable application, but safety impact exists and is such that the
LIO hazard must be controlled
- LIO serves an active function in flight - not along just for the ride
2. DEVELOP REQUIREMENTS
14 January30, 1994
B. OPERATIONAL IMPLEMENTATION
REMOVE THE RISK _
1. DEVELOP A "STANDARD"
- discussions held with Aerospace/Air Force:
t5 - 36 -
Second NASA Aerospace Pyrotechnic Workshop
Laser Initiated Ordnance Activities in NASA
STATUS:
COOPERATIVE AGREEMENT
17 - 37 - J_wy30. l_
Second NASA Aerospace Pyrotechnic Workshop
Laser Initiated Ordnance Activities in NASA
• NO HARDWARE IS DELIVERED
• NO FEE
PROJECTS
A. PEGASUS EXPERIMENT
C. SHUTTLE
- Range Safety
19 - 38 - January3o. t994
Second NASA Aerospace Pyrotechnic Workshop I
Laser Initiated Ordnance Activities in NASA
I
A. PEGASUS EXPERIMENT
- safety hazard to operational personnel: accidental motor ignition. Control by design and
procedure
- not mission success dependent. Fin rocket motors not required for mission success
- not a safety hazard. Accidental ignition pressurizes a metal container designed to take the load
- quantitative information. Pressure measurements performed during flight with be compared with
ground test data.
NASA TASKS:
As necessary:
1. Perform technical review, analyses, and test support
2. Involve Range Safety Offices
3. Conduct off-limits/overstress tests & evaluations to support Range Safety objectives
4. Establish requirements for NASA-wide application
5. Provide test equipment support such as OTDR
22 J_-y 30,_4
• 6 MONTH PROGRAM
23 - 40 -
Second NASA Aerospace Pyrotechnic Workshop
Laser Initiated Ordnance Activities in NASA
COMPANY TASKS:
1. Design and manufacture termination ordnance
2. Provide LIO ignition for Nike and Orion motors
3. Provide laser firing unit, the fiber optic cable, connectors, detonators, and initiators
NASA TASKS:
1. Launch vehicle: Nike-Orion
2. Vehicle drawings
3. Provide environmental test requirements and WFF range safety requirements
4. Pyro interface such as mounting platform for LIO electronics
5. Instrumentation defining key events and body accelerations
6. 3-axis accelerometer
7. FTS activation timer
8. FM-FM transmitter
C. SHUTTLE
- 2 different detonators
- no exposure to sun
26 January30, 1994
I
Second NASA Aerospace Pyrotechnic Workshop [
Laser Initiated Ordnance Activities in NASA
I
- work continues
27 - 42 - ,.-, _o.,,,,
i
Second NASA Aerospace Pyrotechnic Workshop |
Laser Initiated Ordnance Activities in NASA
]
PRELIMINARY
1. Single fault tolerant (two independent safeties) before and after installation of SAFE/ARM type connectors
To allow operations during these conditions, LIOS must be at least two-fault tolerant and meet the Man-Rated design
requirements defined in RSM-93 Paragraph 5.3.4.4.5
4. Component (if electrical type) adjacent to the laser system must be single/double fault tolerant
5. Component adjacent to the lasing device (either in the power or return leg of electrical circuit), shall not be activated
until programmed initiation event
6. LIOS must not be susceptible to external energy sources, such as stray light energy, static and RF
7. Design to preclude inadvertent initiation due to singular energy sources, such as unplanned energy in power leg of
circuit or due to short circuits or ground loops.
g. Design to allow for ordnance connection at the latest possible time in the countdown process
9. Design such that voltage required to initiate laser is at least 4 times the VCC of solid state logic circuits
11. Provide circuits to allow for remote control and monitor of all components in the Category "A" system. Application of
.+.35V in the monitor circuit shall not affect the Category "A" circuit
Allow remote testing at energy levels of 10-2 below no fire for both normal and failure modes. Use different
wavelength than main firing laser, separated by at least 100 nm
1 3. Design to allow for "no-stray energy" type of tests prior to performing ordnance connection
14. Employ pulse catcher system to detect inadvertent actuation of laser prior to ordnance connection
Monitor 1/100 no-fn'e and be capable of determining a valid all-fire (power, energy density, frequency, pulse-width)
Ordnance R_uirements:
16. All ordnance used with LIOS must be secondary explosive.
29 - /43 - Jmt_ry30, t_
Second NASA Aerospace Pyrotechnic Workshop
Laser Initiated Ordnance Activities in NASA
17. Install charged ("Hot") batteries into Category "A" circuits only if at least one of the following design approaches is
utilized. Otherwise, charge battery at latest feasible point in countdown process with no personnel in danger area
17.2 Optical barriers utilized which mechanically misalign initiation power from either LID or laser
17.3 Capacitive Discharge Ignition (CDI) system used meeting circuit criteria in RSM-93 Paragraph 5.3.4.4.4
17.4 Designed to be Man-Rated and meets circuit requirements in RSM-93 Paragraph 5.3.4.4.5
PRELIMINARY
2. Wires should be capable of handling 150% of design load. Design shall assure that latched command will remain
latched with a 50 ms dropout pulse
4. Analysis/Testing shall be performed to detemune debris contamination for blind connection sensitivity on optical
conoectors
5. All components in the Category "A" initiation system shall be sealed to 10-6cc/sec
PRELIMINARY
FTS REQUIREMENTS:
1. FTS circuit must meet all requirements defmed under Category "A" requirements
2. Circuit must requirements in RCC STANDARD-319-92, FTS Commonalty Standard, Chapters l, 2, 3, and 4
3. All LIOS components must meet test requirements in RCC STANDARD-31992, FTS Commonalty Standard,
Chapters 5.1 and S.2
4. Meet design requirements specified in WRR- 127. l (June 30, 1993) Chapter 4:
5. System must meet test requirements specified in WRR-127.1 (June 30, 1993) Chapter 4:
6. Incorporate a Built-in-Test (BIT) feature which allow remote testing at energy levels of 10 -2 below no-fire for both
normal and failure modes and must also be at a different wavelength than main firing laser. The wavelengths for the
main firing laser and the test laser must be separated by at least 100 nm
8. All ordnance interfaces shall allow for 4 times (axial, angular max. gap) or 0.15" and 50% minimum design gap
10. Perform analysis/design on: LIOS FTS-FMECA, bent-pin analysis, LID heat dissipation due to SPF's
SAFETY POINTS
• GENERAL REQUIREMENTS:
- avoid introductionof new hazards,
- avoid inadvertent ignition,
33 - 45 -
I
Second NASA Aerospace Pyrotechnic Workshop [
Laser Initiated Ordnance Activities in NASA
I
ISSUES TO WORK
• SAFETY REQUIREMENTS
• BUILT-IN-TEST
• COSTS
• BUILT-IN-TEST
• SPECIFICATION
• MARKET ANALYSIS
35 - /46 - J,,,,_3o.,9_4
Laser Initiated Aerospace
Ordnance Activities in Workshop
NASA
I Second NASA Pyrotechnic
SUMMARY
CONCLUDING THOUGHTS
37 - 47 -
LASER-IGNITED EXPLOSIVE AND
PYROTECHNIC COMPONENTS
_EG_G
- 49
EG&G MOUND APPLIED TECHNOLOGIES HAS PURSUED
(.n_EGL:G
EXPLOSIVES PYROTECHNICS
Cp a Ti/KCIO 4
- 50 -
COMPARISON OF THE IGNITION THRESHOLDS
OBTAINED ON VARIOUS ENERGETIC MATERIALS
I _ _ s°°" eao"
125 mN
I
CP BCTK ri/KC]O_ rs_._ co4_E cw _x/3x FZN_ CP/
tX C4U_aO_ CARBON 3 2X CARBON
/KC] 04 BLACg BLACK BLACK
ENERGETIC MATERIAL
CHARGE CAVITY
IN \\
SHELL \\
\\
\ \
FIBER PIN WINDOW
51
COMPARISON OF THE 50% ALL-FIRE THRESHOLDS
USING SAPPHIRE AND P-GLASS WINDOW DEVICES
4".0-
J
s
.a" SAPPHIRE
s
3.0- s
"--3 s
-GLASS
rY
LO
Z
LO 1.0-
,0 I I I
• 5 "WINDOW"
• 6"FIBER PIN"
_BBmS
- 52 -
MOUND IS ACTIVELY ENGAGED IN LASER DIODE
IGNITION (LDI) COMPONENT DEVELOPMENT
- 53 -
MANUAL
TRIGGER
STC CONNECTER
[_ PHOTODIODE
FILTER
OPTICAL
RBER HIGH SENSITIVI'fY
PHOTODIODE TEST DEVICE
DIGrrlZ]NG OSCILLOSCOPE
IPS92-1O
- SPOT SIZE
- SPOT SHAPE
• LASER BEAM
- PULSE LENGTH
- PULSE SHAPE
- WAVELENGTH
• THERMAL CONDUCTIVITY
- POWDER/FIBER/SHELL/WINDOW
- 54 -
THE DDT DETONATOR HAS BEEN SUCCESSFULLY
LASER-FIRED USING A VARIETY OF TEST PARAMETERS
IX
HMWCARBON BLACK
HERMETIC
- 55 -
The Laser Fired Pyrotechnic device
was derived from the well tested
" Hot-wire"Device
rn
- R N PAD
AEGRG
- 56 -
THRESHOLD PERFORMANCE INDICATES THAT A
RELIABLE DEVICE CAN BE FABRICATED
2_EG;_G
DATA ACQUISITION
DIODE DRIVER :t
I
t
I
TRANSDUCER
OPTICAL
FIBER
-57 -
ZERO VOLUME FIRING TEST RESULT OBTAINED
ON A LASER-IGNITED FIBER PIN DEVICE
174
-
1200
1000 145
0 73
n aJ
t 800 116 m
W v,
v,
W
E 600 87
3
aJ
v,
m
v, 400 58
-
n
W x
E
a 200 -
v)
29
0 0
0 40 80 120 160 200
TIME (microsecond)
I I
I"'
llni
Ill1 I A l l Ill
58
LASER-IGNITED DETONATORS HAVE BEEN
DESIGNED TO BE BON-FIRE SAFE
MOUND TESTING
THRESHOLD DETERMINATION
HOT, COLD, AMBIENT
ENVIRONMENTAL CONDITIONING
THERMAL AND MECHANICAL
SANDIA TESTING
LIGHTNING STRIKE
¢_EB=B
- 59 -
LASER DETONATOR MANUFACTURING REQUIRES
THE APPLICATION OF SEVERAL KEY TECHNOLOGIES
GLASS PROCESSING
- 60 -
y$-2g
.._
f
1004 ASA IPY ©TIEOHIJII LO SYSTemS ©IRIK$1H©IP
J. K. Churchill
Quantic-Holex
Hollister, CA
ABSTRACT
A conventional NSI (NASA Standard Initiator) normally employs a hot-wire ignition element to ignite ZPP
(zirconium potassium perchlorate). With minor modifications to the interior of a header similar to an NSI
device to accommodate an SCB (semiconductor bridge), a low cost initiator was obtained. In addition, the
ZPP was replaced with THKP (titanium subhydride potassium perchlorate) to obtain increased overall gas
production and reduced static-charge sensitivity. This paper reports on the all-fire and no-fire levels
obtained and on a dual mix device that uses THKP as the igniter mix and a thermite as the output mix.
1. INTRODUCTION
The Explosive Components Department at Our solution was to modify an existing Quantic-
Sandia National laboratories was assigned the Holex component (similar to a conventional NSI
task of designing actuators for several different device) with a semiconductor bridge, SCB. Our
functions for a Department of Energy (DOE) prototype device used titanium subhydride
program. The actuators will be exposed to potassium perchlorate (THKP) as the
personnel as well as to a wide variety of pyrotechnic. Our second (dual mix) design used
mechanical, temperature and electromagnetic THKP as the igniter mix and CuO/AI thermite as
environments. In addition, required outputs vary the output charge. The low firing energy
from a high pressure gas pulse for piston requirements of the SCB substantially reduced
actuation to a high temperature thermal output the demands on the firing system; indeed, the
for propellant ignition. In order to minimize present firing system design could not
complexity, the firing sets for all the actuators accommodate conventional hot-wire devices.
must be the same, and the firing signal must be The reduced static sensitivity of THKP _ helped
transmitted via a cable over lengths as long as mitigate the electromagnetic environment
thirty feet. requirements for exposure to radio frequency
*This work performed at Sandia National Laboratories is supported by the U. S. Department of Energy
under contract DE-AC04-76DP00789. Approved for public release; distribution unlimited.
- 61 -
(RF) signals and human-body electrostatic internal charge cavity was reduced to a diameter
discharges (ESD). of 0.156" by utilizing a threaded fiber glass
composite (G10) charge holder. The threads
help prevent separation of the powder from the
2. SCB DESCRIPTION bridge due to mechanical shock. The pins are
hermetically sealed by glass-to-metal seals and
An SCB is a heavily doped polysilicon volume extend approximately 0.020" past the header
approximately 100 pm long by 380 pm wide and base into the charge holder. The SCB chip is
2 _m thick with a nominal resistance of 1 _. It is bonded to the header base between the pins
formed out of the polysilicon layer on a with a thermally conductive epoxy. Aluminum
polysilicon-on-silicon wafer. Aluminum lands are wires, 0.005" in diameter, are thermalsonically
defined over the doped polysilicon; wires are bonded to the header pins and the aluminum
bonded onto the lands connecting the lands to lands on the chip. For the prototype device, a
the electrical feed-throughs of the explosive charge of 85 mg of THKP is pressed at 12,500
header. The firing signal is a short (30 tls) current psi into the charge holder. A G10 disk, 0.156"
pulse that flows from land-to-land through the diameter and 0.010" thick, is placed on top of the
bridge. The current melts and vaporizes the pressed powder, followed by an RTV disk,
bridge producing a bright plasma discharge that 0.150" diameter and 0.016" thick. A G10 plug,
quickly ignites the THKP pressed against the 0.065" thick, is then pressed on top of the RTV
bridge. 2 at a pressure sufficient to compress the RTV pad
to half its thickness, which maintains a pressure
of approximately 5,000 psi on top of the THKP
column. A high temperature epoxy seals the
interference fit G10 plug in place.
t
I
CTION •-A
- 62 -
photomultiplier tube looking at the end of the
device thorough a fiber optic cable).
40,
- • - i - | - • - ! - f " I All Fire: 17.8 + 0.2 V, 4.8 + 0.1 mJ
- 63 -
input for reliable ignition, we developed an SCB using a 50 _F CDU firing set was 17.8 V; the 5
igniter employing two discrete pyrotechnic minute no-fire level is estimated to be greater
compositions. First, 25 mg of THKP is pressed at than 1 A with no device degradation. Future
12.5 kpsi against the SCB and is used as a starter research will examine the tolerance of this device
mix to pyrotechnically amplify the low energy to mechanical shock and electromagnetic
SCB signal. The THKP in turn ignites and ejects environments.
150 mg of a high density thermite composition
composed of CuO and AI pressed onto the
THKP. 8. ACKNOWLEDGMENT
We briefly describe the advantages of this device The testing expertise of Dave Wackerbarth,
over a device composed of only a single load of Sandia National Labs, is acknowledged with
THKP or CuO/AI. THKP has excellent and well grateful thanks.
known interface, ignition and pyrotechnic
propagation properties. It also is an excellent gas
producer providing zero volume pressures 9. REFERENCES
greater than 150 kpsi. Unfortunately, the short,
high pressure output pulse of THKP is not ideally 1E. A. Kjelgaard, "Development of a Spark
suited for the ignition of a composite propellant. Insensitive Actuator/Igniter," Fifth International
CuO/AI on the other hand is an ideal material for
Pyrotechnics Seminar, Vail Colorado (July
the ignition of composite propellants. Hot 1976).
copper vapor condensing and molten copper
impacting on the surface of the propellant 2See for example, D. A. Benson, M. E. Larson,
provides an excellent source of thermal energy A. M. Renlund, W. M. Trott and R. W. Bickes, Jr.,
for ignition. Furthermore, copper and copper "Semiconductor Bridge (SCB): A Plasma
oxides catalytically enhance the ignition and Generator for the Ignition of Explosives," Journ.
combustion of ammonium perchlorate. Appl. Phys. 62, 1622(1987)
Unfortunately, CuO/AI thermites exhibit poor
ignition characteristics at high density and are 3R. W. Bickes, Jr., S. L. Schlobohm and D. W.
sensitive to header and charge holder thermal Ewick, "Semiconductor Bridge (SCB) Igniter
losses. Thus, CuO/AI at high density requires Studies: I. Comparison of SCB and Hot-Wire
large input energies for ignition and the reaction Pyrotechnic Actuators," Thirteenth
once started can be quenched as a result of International Pyrotechnic Seminar, Grand
radial heat losses. The THKP ignition charge Junction Colorado (July 1988).
eliminates both of these problems by providing
an overwhelming thermal input to the CuO/AI. 4Firing set designed by J. H. Weinlein of the
Although the CuO/AI is itself a poor gas producer Firing Set and Mechanical Design Department,
(the copper vapor rapidly condenses), the THKP Sandia National Laboratories.
produces a sufficient gas pulse for this device to
be used to operate small, lightly loaded, piston 5B. T. Neyer, "More Efficient Sensitivity Testing,"
type actuators. In addition, the thermal output of EG&G Mound Applied Technologies, MLM-
the CuO/AI helps to maintain the temperature of 3609, (October 20, 1989)
the gases produced by the THKP. We have
tested both piston actuator and propellant 6H. E. Anderson, "STATLIB," Sandia National
loaded gas generators with this dual mix device Laboratories, SAND82-1976, (September
with good results. 1982).
7. SUMMARY
- 64 -
Optical Ordnance System For Use In Explosive Ordnance Disposal Activities *
Mbuquerque, NM 87185-0329
*This work was sponsored by the Office of Special Technologies under funding documents NO464A92WR07053
and NO464A91WR10380 and supported by the United States Department of Energy under Contracts DE-ACO4-
76DP00789 and DE-ACO4-94AL85000.
- 65 -
by the powder, thus raising its temperature to the standard SMA 906 optical connector. The
auto-ignition temperature. The primary advantage connector positions the optical fiber in contact with a
of optical ignition is that there are no electrically sapphire window as shown in Figure 2. This optical
conductive bridgewires and pins in direct contact interface and the use of optical fibers instead of
with the explosive powder. This removes the electrical wires completely de-couples stray electrical
potential electrostatic discharge pathways and sources from the detonator by removing any
eliminates premature initiations which can be caused electrical path to the explosive.
by stray electrical signals. This is illustrated by the
comparison of the electrically and optically ignited
ordnance systems shown in Figure 1.
BRIDGEWIRE
ELECTRICAL
DEVICE
ELECTRICAL
LEADS
- 66 -
At high powers, such as that provided by the Navy the second generation prototype design from
EOD system, a minimum energy must be delivered Universal Propulsion. Both systems have been
to the explosive in order for it to ignite. As seen in shown to be effective at igniting the optical detonator
Figure 4, this minimum energy for doped CP is on through 1000 meters of optical fiber. Both laser
the order of 0.25 mJ. The Navy EOD system uses a designs are discussed below.
solid state rod laser capable of delivering 100 to 200
mJ of optical energy in a fraction of a millisecond. The first laser firing unit for the Navy EOD laser
Explosive doping is not required in this detonator ordnance system was built by Whittaker Ordnance
when utilizing the high power rod laser but was and was designed to be portable, rugged, water-proof
implemented so that the detonator could be used for during transport, and battery operated. The laser
a wide range of applications. unit contains a 9-volt battery which supplies voltage
to a DC/DC converter to step up the voltage to
3o, oee
approximately 500 volts. This voltage charges the
300 gf capacitor which supplies current to the flash
3 O
E3
lamps. The functioning of the flashlamps excites the
2
laser rod material, Nd doped YAG, and causes the
1.5
laser to function. The system is designed to deliver
between 100 and 200 mJ of optical energy during a
Energy (m J)
t
500 microsecond pulse. This exceeds the energy
required for the ignition of the detonator by at least 2
0.5
orders of magnitude. The laser output is coupled
into a 200 ttm optical fiber which can be connected
0 . • . , . | . • . | . | . , . , . , . to the laser firing unit using the SMA 905 connector
0 o.t o.z o.z o.4 o.s o.s 0.7 o.e 0.9
port on the top of the laser.
Power (watts)
- 67 -
laser uses either six 1.5 V AA batteries or three 3 V eye safe, low power, light source should be used for
AA batteries to power the laser with a 9 V supply. checking fiber continuity. The fiber continuity
The 9 V supply is stepped up to 360 V to charge a cannot be checked by the laser firing unit as it is not
200 iff capacitor. The body of the laser is more eye safe, and the laser light is invisible to the human
rugged and environmentally sealed. The housing is eye.
similar to a flashlight housing and is 10.1 inches
long and 2.75 inches in diameter. The laser weighs Connections to optical fibers can be made with
2.1 pounds. Operation of the laser is similar to that standard optical connectors. This procedure can be
of the Whittaker design. The design utilizes a rotary done in the field if required but is easier if done
arm/fire switch located in the rear of the laser ahead of time. The polish on the optical fiber is
housing. The laser delivers 200 - 300 mJ optical important on the laser end. The polish on the
detonator end is not as critical and a simple cleave of
energy in a 200 gsec pulse. The optical energy is
the fiber is sufficient. During explosive shots, the
coupled into a 200 _m fiber using a press fit SMA
906 connector which attaches to the front of the laser last portion of the optical fiber is destroyed.
Therefore, it is recommended that optical cable
housing.
jumpers be prepared ahead of time and used in the
field to minimize the number of connectors that are
made in the field.
3.3 Optical Fiber and Connections
- 68 -
Pyrotechnic Actuators", to be published in
Proceedings of the Nineteenth International
Pyrotechnics Seminar, Christchurch, New
Zealand, 20-25 February, 1994.
4. M.W. Glass, J. A. Merson, and F. J. Salas,
"Modeling Low Energy Laser Ignition of
Explosive and Pyrotechnic Powders",
Proceedings of the Eighteenth International
Pyrotechnics Seminar, Breckenridge, CO, 12-
17 July 1992, p. 321.
5. R.D. Skocypec, A. R. Mahoney, M. W. Glass,
R. G. Jungst, N. A. Evans and K. L. Erickson,
"Modeling Laser Ignition of Explosives and
Pyrotechnics: Effects and Characterization of
Radiative Transfer", Proceedings of the
Fifteenth International Pyrotechnics Seminar,
Boulder, CO, 9-13 July 1990, p. 877.
6. D.W. Ewick, "Improved 2-D Finite Difference
Model for Laser Diode Ignited Components",
Proceedings of the Eighteenth International
Pyrotechnics Seminar, Breckenridge, CO, 12-
17 July 1992, p. 255.
7. D.W. Ewick, T. M. Beckman, J. A. Holy and
R. Thorpe, "Ignition of HMX Using Low
Energy Laser Diodes", Proceedings of the
Fourteenth Symposium on Explosives and
Pyrotechnics, Philadelphia, PA, 1990, p. 2-1.
8. D. W. Ewick, T. M. Beckman and D. P.
Kramer, "Feasibility of a Laser-Ignited HMX
Deflagration-to-Detonation Device for the U. S.
Navy LITES Program", Rep. No. MLM-3691,
EG&G Mound Applied Technologies,
Miamisburg, OH, June 1991, 21 pp.
9. C.M. Woods, E. M. Spangler, T. M. Beckman
and D. P. Kramer, "Development of a Laser-
Ignited All-Secondary Explosive DDT
Detonator", Proceedings of the Eighteenth
International Pyrotechnics Seminar,
Breckenridge, CO, 12-17 July 1992, p. 973.
10. D. W. Ewick, "F_nite Difference Modeling of
Laser Diode Ignited Components", Proceedings
of the Fifteenth International Pyrotechnics
Seminar, Boulder, CO, 9-13 July 1990, p. 277.
- 69 -
Laser Diode Ignition (LDI)
William J. Kass, Larry A. Andrews, Craig M. Boney, Weng W. Chow,
James W. Clements, John A. Merson, F. Jim Salas, Randy J. Williams
Sandia National Laboratories
Albuquerque, NM
and
Lane g. Hinkle
Martin Marietta Speciality Components
Clearwater, FL
ABSTRACT
This paper reviews the status of the Laser Diode Ignition (LDI) program at Sandia National Labs.
One watt laser diodes have been characterized for use with a single explosive actuator. Extensive
measurements of the effect of electrostatic discharge (ESD) pulses on the laser diode optical
output have been made. Characterization of optical fiber and connectors over temperature has
been done. Multiple laser diodes have been packaged to ignite multiple explosive devices and an
eight element laser diode array has been recently tested by igniting eight explosive devices at
predetermined 100 ms intervals. A video tape of these tests will be shown.
- 71 -
PAGE _SL_ " _':'_.-: ......
actuator. This system along with a power U D U D U W M W p SI U
budget for each loss element is shown I
:*.8
The losses indicated in Figure 1 are 6 *.8
*.a
referenced to the nominal (50%) fire level of *.#
require a measure of the spread in the Figure 3. Optical power vs. drive current
measurement of the fire threshold. Fiber at tempertures between -55C and 75C for
losses (0.1 dB) and connector losses (0.8dB) a typical 1W laser diode.
are estimated from our experience with
commercial connectors and fibers. The obtained and evaluated.
coupling loss (3 .O dB) represents the worst
case coupling between the laser diode chip The single laser diode firing system also
and the integrated optical fiber with which it includes an electronic drive circuit used to
is packaged. Degradation over time, convert 28 V-10 ms input power pulse to the
temperature and thermal and mechanical 1.6-2.0 A-10 ms drive current pulse required
environments is taken as a factor of two (3 .O to deliver 1 W optical power from the fiber
dB) over the expected lifetime (20+ years) of coupled laser diode.
the laser diode ignition system. The result of
this analysis is that the laser diode chip LASER DIODE.
power, before coupling, necessary to ignite The laser diodes used for these tests have an
the explosive is approximately 15 times the optical output of approximately 1 W in the
nominal fire threshold. For HMX/C,the spectral range of 800-850 nm. The laser
nominal threshold for a lOms optical pulse is diode is an AlGaAs single quantum well
70 mW, hence, a 1.0+ watt uncoupled laser device manufactured by Spectra Diode Labs.
diode chip is required. Commercially The laser diode is hermetically packaged
available laser diode chips delivering greater with an integrally coupled 0.22 numerical
than 1.0 W coupled power have been aperture-100 pm diameter optical fiber
which is terminated in a commercial optical
connector ferrule. A photo of this device is
shown in Figure 2.
0 . .
aas no 88s m w
W d m m (nm)
- 72 -
1
0.g
1
0.8
o.I
0.7
0.8
0.6
0.S
0.4
a: 0.3 O_
t O.S
0.2
02
5 10 15 29 25 I
0 I
Temperxtum Sequamce 400 4O
Tmpe_kn (C)
between-55"C and 100*C multiple times. Polyr_ _ Fiber v,qh Pdy_ L,ffer
was 0.22 NA, 100 lam diameter, pure silica -7O 410 4f,0 ...40 .30 -20 -10 0 10 20 30
T_q_ran (C)
- 73 -
characterization done at Sandia National
Labs has been for 2-(5 cyanotetrazolato) SDL RK3,1?
t0
14
il,°
6
0 _ _
Time (no)
- 74 -
8DL RK347 1E+00
31 150
J 1 E-01
2_ -_" 125
[a,
I E-02
1 E-03
11 5O
5 25
1 E-04
/
>,
...................... 0
010 12 14 16 18 20 22 24 26 Q
Chsrgo Voltage (kV) c 1 E-05
uJ
1 E-06
Figure 11 Peak output power (broken line)
and current (solid line) vs. charge voltage on 1 E-07
ESD test circuit.
1 E-08
1E_9 .....................................
decay in about 1000 ns. As the input voltage
1E_9 1E_7 1E_5 1E_3 1E_1 1E+01
to the ESD circuit is increased from 10 kV
to 25 kV, the peak current increases from
Time (s)
60 A to 140 A. The optical output tracks
this current until degradation of the diode Figure 13 Comparison of optical energy
begins. This occurs at about 125 A with a necessary to ignite TKP and CP with the
circuit input voltage of 23 kV. The peak maximum optical energy available from an
optical output power is 25 W while the ESD source.
1E+01 E:5[ _
° \ _KF
others
current
tested
through
indicates
the diode
that even
continues
though
to
the
1E_1
increase with higher circuit drive voltages,
the optical power levels off and begins to
decay as the laser diode is degraded. This
1E-02 .................................. phenomenon becomes a safety advantage
1E- 1E- 1E- 1E- 1E- 1E- 1E- 1E- 1E-
because the diode will not be able to deliver
09 08 07 06 05 04 03 02 01
Figure 12 Optical power necessary for Figure 12 shows the optical power available
explosive ignition and optical power from a laser diode driven by an ESD source
generated by ESD pulses vs time.
- 75 -
vs. time and compared to the power-time been built and tested in various
combination required to ignite titanium configurations. We have estimated a power
potassium perchlorate or CP. The HMX budget for reliable ignition and the individual
threshold falls slightly below that for CP. It loss terms are being characterized. Fiber
can be seen from this plot that even though losses and connector losses can be
there is ample power for ignition, the accommodated with proper choices of
duration is too short to ignite the explosive connectors and fibers. Currently available
material. commerical high power laser diodes provide
ample power to ignite a variety of explosives
The integration of the power vs. time curves under extremes in temperature and
gives a maximum available optical energy of mechanical environments. The behavior of
3-5 llJ from this type of ESD pulse. This these laser diodes is being characterized over
energy also probably represents the temperature, mechanical environments and
maximum energy available under other high time (aging). ESD testing demonstrates that
current conditions. Figure 13 shows the the laser diode is inherently safe from
available optical energy plotted vs. time producing optical power or energy which
compared to the energy required to ignite CP exceeds the explosive ignition threshold.
or TKP. When plotted in this manner it is
apparent that too little ESD generated ACKNOWLEDGMENT
optical energy is available to ignite these The authors would like to express their
explosives. appreciation to John Barnum for making the
ESD measurements.
CONCLUSION
A complete laser diode ignition system has
REFERENCES
1. S. C. Kunz and F. J. Salas, "Diode Laser Ignition of High Explosives and Pyrotechnics, Proc.
of 13th International Pyrotechnics Seminar, Grand Junction, CO, 11-15 July 1988, pp505
- 76 -
6. Powers Garmon, "Analysis of Excess Attenuation in Optical Fibers Subjected to Low
Temperatures", Proc. of the International Wire and Cable Symposium, 1983, pp134-143.
7. R. J. Fisher, "The Electrostatic Discharge Threat Environment Data Base and Recommended
Baseline Stockpile-to-Target Sequence Specifications," SAND88-2658, November 1988.
- 77 -
STANDARDIZED
LASER INITIA TED ORDNANCE
James V. Gageby
Engineering Specialist
Explosive Ordnance Office
The Aerospace Corporation
Abstract
I i_ i o,vic. I/
The LIOS is intended as a state-of-the-art Power/Control I Arm/Rre F" I I I
_m I Switching _
solid state replacement for the present day
electrically initiated ordnance firing circuits for Input I (Moth Relays) _t_oslve transfer line
- 79 -
compliance with safety regulations in flight The LIOS contains no moving parts. The
termination and solid rocket motor ignition systems switching network in the LIOS uses solid state
only. It contains moving parts. It provides a barrier, electronics to accomplish the functions mechanical
or interrupt, in the explosive train so that premature latching relays and S/A's provide in the
ignition of the EED will not cause an unplanned conventional ordnance system.
event. This interrupt is remotely removed during
the mission sequence to allow end item function. Advantages of LIOS are in reduced
The safe and arm device also contains a handling and safety concerns during ground
component called a safing pin which must be operations. During most pre-launch operational
manually removed before remote arming and firing cycles, R-F silence and limited access conditions
can be effected. Removal of the sating pin is done are in effect while ordnance installations are in
late in the pre-launch cycle and usually requires progress. These down times could be eliminated or
the launch site to be cleared of all but essential drastically reduced by use of the proposed LIOS.
personnel. The reduced safety concerns may allow for
installation of ordnance items at the factory instead
The LIOS replaces the EED used in the of the launch site, thus reducing pre-launch
conventional ordnance system with a device that operational costs by streamlining ground
uses laser diode energy to ignite the same operations.
explosives. The primary advantage is the
elimination of electrically conductive paths to the The use of lasers for ignition of explosives
explosive mixes. This drastically reduces concerns is not new. Research in this area began more than
of premature ignition since external environments twenty-five years ago. In fact, the small
like static electricity, electro-magnetic interferences intercontinental ballistic missile _(SICBM) program
as well as radio frequency (R-F) fields are isolated developed and flight demonstrated a crystalline rod
from the explosives. laser system a few years ago. The SICBM laser
ordnance concept is shown below.
The new explosive component is called a
laser initiated device or LID. The LID will be
SICBM Laser Ordnance Concept
designed to use secondary explosive materials as
ignition sources rather than primaries as used in For clarity built-in-test Fiber
features are not shown Motor Ddven Sequencer_ Optics I
EED's. This reduces handling concerns. The LID (moving parts required) _ / aL'D
.....
SIGNAL CONTROL
IN-UNE CONNECTORS
o optical prisms on a rotating wheel that allow for
splitting of the laser beam for multiple output
functions.
• Laser firing unit (LFU) - receives control signals and power
(28VDC.) for sequencing. Laser diodes in LFU produce single Included in the system, but not shown in
or mult,ple laser outputs. Contains no moving parts.
the schematic, is a built-in-test (BIT) feature. The
• Energy transfer system (ETS) - conveys laser light through
fiber optics and Connectors to LID. BIT feature requires additional electro-mechanical
• Laser initiated device (LID) - allows laser energy (heat) to be devices to bypass the rod laser and let a light
absorbed Into chemical mixture causing deflagratlon/ emitting diode (LED) be pulsed into the fiber optic
detonation of explosive.
transmission line. To verify health of the
transmission line, the LED's pulse is reflected at
- 80 -
the LID and it's total travel time measured by
means of an optical time domain reflectometer The first Task is to obtain an agreement
(OTDR). This transmission line check-out is done with the Range Commanders Council allowing use
as late in the pre-launch cycle as practical. The of LIOS at all launch sites. To be specific, the
OTDR is not part of the flight hardware. agreement must allow use of a LIOS, without
moving parts, i.e., remotely controlled shutters,
The use of semiconductor laser diodes as etc., on any ordnance system, at any launch site.
an ignition source is a new, emerging technology. This includes both flight termination and
Their use is, by all indications, a viable alternative operational ordnance firing systems.
not only to the present day electrically initiated
systems but also to the SICBM approach. At the If the Task 1 agreement cannot be attained
onset of the SICBM effort, laser diode technology the SMC LIOS effort will stop. The cost advantages
had not developed sufficiently to provide output of a LIOS using mechanical components compared
energies needed to meet LID ignition margin to the cost of today's conventional ordnance firing
requirements. Today the technology has system are not of sufficient magnitude to warrant
progressed to a point that laser diodes can provide implementation.
high energies with ample margin.
The remaining tasks will provide technical
Using laser diodes in place of crystalline rational to support safety and performance
rod lasers is a quantum leap in miniaturization. requirements of the Task 1 agreement. These must
This miniaturization allows for multiple outputs satisfy any Range Commanders Council or SMC
without having to use a mechanical prism program concerns.
sequencer as in the SICBM system. All mechanical
components are removed. It also allows for the The second task is to analyze the solid
introduction of solid state control logic circuits to state circuits to verify that they can meet safety and
further advance explosive ignition technology in performance requirements. This will be followed by
space applications. an effort to model the entire LIOS and assess
performance margins. The margin analysis must
SMC LIOS show that there is at least 50% more energy
available than necessary to ignite the LID when all
The SMC LIOS standardization plan is system parameters and external environments are
broken down into six major tasks shown at their extremes. If the designs can not show
below. sufficient margins for safety and performance
LIOS Major Tasks needs, the SMC LIOS effort will be stopped.
Task Accomplishment Exit Criteria
1. Acquire Range Cmdrs Eliminate mechanical LIOS not approved or use Circuit concepts will be analyzed and be
Council approval for components In of moving components validated by bench tests of designs that are
use of solid state ordnance firing circuits with LIOS mandated
UOS representative of the optimum configurations.
Validate circuit Solid state logic cannot These tests are considered a key element in the
2. System end circuit
modeling )erformance meat performance/ validation of the LIOS concept. Contributing
safety requirements
Validate system Lack of margin expertise to these tasks are Dave Landis and Don
energy margins Herbert of the Electronics Division.
Assess BIT designs BIT not compatible
with designs
During the course of the modeling BIT
3. Determine system Compatibility validated System not compatible
compatibility with
designs will be evaluated. The BIT feature will be
RF/EMI/ESD used to check continuity of the ETS path between
4. Verify compatibility Interfaces validated LIOS not compatible the laser diode and the LID only. Full power system
with SMC programs
checks will be done prior to final connection of the
5. Determine cost Cost benefits defined No cost savings
LID and be performed as late in the pre-launch
benefit of LIOS use cycle as deemed practical. A key feature of the
Funding not available
LIOS implementation is an ability to perform
6. Quality end flight LIOS technology ready
demo an SMC for SMC use remote check-out of system health without
compatible LIOS
interfering with other pre-launch activities.
Therefore, the LIOS effort will be stopped if an
adequate BIT feature cannot be found.
The following discussion will outline the
The third task is to determine the LIOS
key points of each task. Note that the exit criteria
shown for each task is not task completion. It is compatibility with external environments that may
criteria that will prevent LIOS from becoming a cause premature ignition or prevent ignition of the
standard for SMC programs, i.e., criteria that would LID. These environments include lightning induced
cause cessation of the SMC LIOS standardization electro-static discharges (ESD), R-F and electro-
effort. magnetic interferences (EMI). These are the same
3
- 8] -
environments that are concerns for conventional
ordnance firing circuit designs. As previously Acknowledgments
noted, current designs .are influenced by these
while the LIOS is not. Verification of LID The author wishes to thank Col. J.
compatibility with reasonable limits of these Randmaa, Col W. Riles, Maj. K. Johnson, Capt. R.
environments is obtainable. Much work has been Anderson and W. Evans of the SMC Chief
done in this area and will be evaluated for Engineers office, and Dr. J Meltzer, Dr. R. Hall and
applicability. J. Gower of The Aerospace Corp. Chief Engineers
office for sponsoring the pursuit of the LIOS plan. I
The LFU must also be shown to also need to thank Norm Schulze of NASA Hqtrs
adequately shield these environments from the for the opportunity of being a member of his
sensitive components within it. If the LID or the NASA/DOD/DOE Pyrotechnic Steering Committee
LFU can not be shown to survive reasonable limits where the LIOS concept was initiated.
of these environments, and designs cannot be
altered to do so, the SMC LIOS effort will be
stopped.
- 82 -
..5 I
Tom M. Beckman
The Ensign-Bickford Company
Simsbury, CT
- 83 -
several candidate pyrotechnic materials using full power 840 nm diode with a 10
and stoichiometries were considered. ms pulse width. An interface sensitivity
Size restraints required that the selected test was used to verify reliability. The
pyrotechnic use the space allocated for results of this testing using 200 micron
the charge holder precisely. This fiber are listed in Table 5. These results
analysis was crucial due to space are listed based on the calibrated output
restraints for the charge allocated given from the diode and do not include line
the overall size envelope. losses.
- 84 -
was selected to determine the is then connected to a photo-diode to
approximate output force developed by produce a small voltage. Upon function
each test unit. The bellows must develop of the unit, this optical path is broken
at least 2.64 Ibs to actuate. The goal for resulting in a voltage drop across the
total nominal developed force is 4.02 photo-diode. This voltage is monitored
Ibs. A polyurethane foam was selected using an oscilloscope to determine a time
with a minimum compressive strength to difference between the donor / acceptor
require at least 2.0 Ibs to crush in order pairs. This measurement scheme allows
to assess the total nominal force output. for determination of average bellows
Figure 2 illustrates the test setup and velocity without interrupting the function.
Figure 3 illustrates the results of the four
units tested using this method. The results of three of these test units
are presented in Figure 4. During
Each of the test articles were bonded to function of the bellows motor into air, the
the test block utilizing the existing test bellows for the first unit did not stay
mounting flange and two part epoxy. intact. This indicated that the unit
This bonding method successfully held probably is producing too much gas for
each test unit during function. Three of function without axial load. The resultant
the units extended approximately 0.060 velocity is not for the entire bellows for
inches into the foam block and the fourth this test unit, but for the aluminum end
did not actuate. The failed unit was free from the assembly. The second and
inspected and revealed that the bellows third units functioned correctly and the
had been inadvertently bonded in place velocities measured are for the bellows.
during assembly. This unit burst under
the developed pressure. This lesson Further Development Work
learned resulted in careful inspection of
the bellows area after final assembly. The Ensign-Bickford Company is
The area filled with epoxy cannot be continuing to develop this product under
readily viewed with the unaided eye. contract for Los Alamos National
Future assembly will necessarily require Laboratory. The ideal miniature bellows
magnification. will function under load to produce the
desired force and be able to function in
Velocity_ Testing air without expelling products of reaction.
The final development phase is to
To assess the overall impulse of the concentrate on optimizing the charge
delivered force, a simple velocity size in order to meet these goals.
measurement sensor was devised. This
article is illustrated in Figure 2. Discussion
The velocity fixture is quite simple. Two The analysis and prototype phase
donor fiber optics are aligned across a contributed to development of the
channel with acceptor fiber optics. Each miniature bellows motor. More work
donor / acceptor pair is placed at a needs to be done to refine the design. A
known distance from the unextended pyrotechnic device to deliver a small
bellows. Using white light as a source, amount of force is possible and has been
the acceptor fiber picks up the light and demonstrated.
- 85 -
Table 1. Pressure Requirements for Bellows Actuation and Burst
Minimum
Bellows Actuation Burst
Material Alloy and Temper Pressure Pressure
(psi) (psi)
Actuation Target
Bellows Alloy and Temper Force Force
Material (Ibs) (Ibs)
- 86 -
Table 4. Results of Initial Prototype Testing
B/BaCrO,/KCIO, 6 Nd:YAG 0
Test Results
No. of Tests 10
Standard Deviation 56 mW
- 87 -
i
Figure 1 Minature Laser Ignited Bellows
- 88 -
_ Foam Brock
- 89 -
0
1 , 2 3 4
- go -
0.01
0.011
(O
0.01
E 0.009
E
o
o
>
Q_
"0
m
'-I
0.001
2 3
- 91 -
- 92 -
PERFORMANCE CHARACTERISTICS OF A LASER-INITIATED
NASA STANDARD INITIATOR
John A. Graham
Senior Project Engineer
The Ensign-Bickford Company
Aerospace and Specialty Products
- 93 -
Two versions are available, one using a autoignition temperature of the mix is
stainless steel housing and another using reached quickly, then the function time
Inconel 718. In either design, the charge will be very repeatable because only the
cavity is proof pressure tested at 15,000 propellant is heated and therefore only the
psi prior to loading propellant. variability of the propellant comes into
play (eg mix homogeneity, density
ALL-FIRE POWER gradient within the pressed powder, etc).
As the time to ignition increases, the
Reliability testing has been done to thermal effects of the surrounding
establish the all-fire power requirement at materials become significant. Sources of
room temperature. Testing was done variation include the amount of epoxy and
using 200_tm fiber. The "pass" criteria the concentricity of the optical fiber to the
was that the time from the start of the ferrule. Conditions such as these increase
laser pulse to first pressure had to be less the variability of the thermal time constant
than or equal to 10 milliseconds, although resulting in greater function time jitter.
the actual laser diode pulse width was 50
milliseconds. The long duration pulse was This has system level implications. The
used to get a better characterization of the specification for the laser diode firing unit
relationship between power and time to pulse duration needs to balance the output
ignition (Figure 2). The 0.9999 all-fire power of presently available laser diodes
power at 95 % confidence is 595 versus the inherent increase of non-
milliwatts. This corresponds to an all-fire repeatability of function time as the pulse
power density of 1900 watts/cm 2. duration is lengthened to allow for lower
net laser diode power. Another way to
LASER IGNITION TRANSIENT state this is function time jitter will be
THERMAL FINITE ELEMENT minimized when the laser diode with the
ANALYSIS (FEA) highest output power is used. Also,
thermal isolation of the propellant from
The reliability test data suggests that surrounding materials will result in more
ignition time repeatability is a function of repeatable ignition and, therefore, lower
the laser power. At high laser power, the all-fire power level which in turn means
function time (i.e. time to ignition) is short laser diode output power requirements are
and repeatable, but as power is decreased, reduced.
function time slows and is less predictable.
PRESSURE PERFORMANCE
Transient FEA was done over a range of
input powers to gain a qualitative For many NSI users, the interest is in
understanding of this phenomena. The output pressure characterization since the
computer model included the propellant, NSI is used as a cartridge to actuate
fiber optic core/cladding, epoxy and pressure driven devices (eg bolt cutters,
surrounding metal structure. Upon initial pin pullers, etc). The LNSI has
application of laser energy, the heating demonstrated a nominal output pressure of
rate is high, but slows and asymptotically 654 psi over the last several lots of
approaches a limit that is a measure of the LNSI's; within each lot, the Coefficient of
LNSI's ability to reject heat to the Variation has ranged from 3 to 5 %.
surrounding environment. If the
- 94 -
Also of concern is the response time and Random Vibration will consist of 1
time to peak pressure. At 800 milliwatts min/axis exposures to the level indicated
net power applied at the opto-propellant on Figure 3.
interface, function times (i.e. time from
application of laser diode power to first Thermal cycle exposure will be from
pressure) has been 1.5 milliseconds with a -16°C to +56"C (3°F to 133°F) for a
Coefficient of Variation of 12 %; time to total of 6 cycles with a 2 hours minimum
peak pressure has been 0.13 milliseconds dwell at temperature.
with a Coefficient of Variation of 20 %.
The final two test groups will be used in
This data is difficult to compare with the reliability tests to establish all-fire power
NSI specification since requirements are at hot and cold temperatures.
tied to the applied current level. What can
be said first of all is the energy source, RECOMMENDATIONS FOR FUTURE
whether it be a hot bridge wire or a laser DEVELOPMENT
diode, does not effect the pressure
performance of the NSI propellant. Further development of the LNSI is
Secondly, the pressure rise rate to 525 psi needed to expand the performance
can be inferred to be equal to or better envelope. No problems are anticipated
than the rise rate performance reported from vibration due to the mechanical
above for attaining peak pressure. similarities between the NSI and the LNSI.
Further, all of the NSI pressure-time The thermal environment does however
requirements at 3.5 amps can be met: raise some questions regarding low
temperature performance of optical fibers.
(1) Time to first pressure of greater
than 1.0 milliseconds A parallel task is to develop a specification
(2) Time to 525 psig shall not exceed for an LNSI. Specific areas needing
6.0 milliseconds attention are: (1) all-fire power and pulse
(3) Peak pressure shall be 525 to 775 width, (2) no-fire power and pulse width
psig (which also requires credible stray light
(4) Range of time to first pressure shall sources to be identified and quantified)
not exceed 3.5 milliseconds and, (3) pressure versus time performance.
(5) Range of pressure rise from first
pressure to 525 psig shall not
exceed 0.5 milliseconds
PLANNED TESTING
- 95 -
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- 96 -
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- 98 -
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- 97 -
0
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- 99 -
/ 2_( _
Four Channel Laser Firing Unit Using Laser Diodes
David Rosner, Sr. Electrical Development Engineer
Edwin Spomer, Sr. Electrical Development Engineer
Pacific Scientific/Energy Dynamics Division
i01
3.50
J2 Fiber 0
Connector
6.80
J1 Control & Power 4.25
Connector
- 102 -
• Arm Command energizes the Arm Switch The four laser outputs exit the LFU through J2.
Circuit to power the LDSAM arming sole- Each uses 100 lam core 0.37 numerical aperture
noid using power available via the Pro-arm (NA) fiber and provides a 904 nm wavelength
Switch Circuit. 10 ms pulse of approximately 1.0 watt.
• Select 1, Select 2, and Select 3 Commands
act as a three bit code to select between the 2.2 LDSAM Characteristics. The LDSAM is
four LFU outputs before each fire a 24 output electromechanical shutter assembly
command. with only four outputs fully assembled. It pro-
• Fire Command commands the LFU to sup- vides an optomechanical safety feature for ord-
ply the high power laser pulse from the se- nance initiation power. As show in Figure 2, all
lected output provided that the LFU is critical optical elements in the LDSAM are rig-
armed. idly mounted to eliminate misalignment in harsh
environments.
The two output status signals, BIT Pass and BIT
Fail, exit the LFU through J1. Each uses an
opto-isolated pair of connections providing an
electronic switch closure.
Fiber Optic
Collimating Lens
Focusing Lens
- 103 -
For each output, a rigidly mounted laser diode circuit to measure the intensity ofthis refle-
and collimating lens illuminates a rigidly mount- ction.
ed focusing lens and 100 gm core fiber optic ca-
ble. An aluminum shutter, located between the 2.4 Electronic Subsystem. The Electronic
collimating and focusing optics, acts as an ener- Subsystem controls and sequences the BIT fea-
gy barrier. A solenoid rotates the shutter be- tures and the laser initiation system. It also in-
tween Safe and Arm positions with a spring terfaces to other missile systems. The Electron-
loaded return to Safe. ic Subsystem consists of the following elements
shown in the LFU Functional Block Diagram
An electro-optical sensor monitors the Safe po- (Figure 3):
sition of shutter. Visual indication is provided • Input and Output Circuits
by a shutter driven flag and window. The flag is • Power Converters
labeled "S" for safe and "A" for Armed. A re- • Redundant Controllers
movable safing pin locks the shutter into the • Pre-arm Switch Circuit
Safe position when installed. • Arm Switch Circuit
• High Power Laser Drive Circuit
2.3 Built-In-Test (BIT) System.. The LFU also • BIT Laser Drive Circuit
contains a BIT system that perforlns the follow- • BIT Sense Circuits
ing tests on the LFU subsystems:
• Continuity of fiber optic paths between the 2.4.1 Input and Output Circuits. We used
LFU and ordnance devices optocouplers and transient suppressors for all
• Firing of high power laser diodes electronic input and output (I/O) signals. Each
• Operation of Pre-ann circuits input command enters the LFU through J1 and
• Operation of LDSAM. uses an opto-isolated pair of connections that
can be driven by 5 V TTL logic.
To develop an optimal design, PS/EDD investi-
gated two different approaches to performing Each output signal exits the LFU through J1 and
the optical continuity BIT. The LFU is uses an opto-isolated pair of connections provid-
equipped with two channels of each type. They ing electronic switch closure. All electrical in-
are: puts and outputs, including power, are equipped
Single Fiber Reflective BIT. A low power with semiconductor transient suppressors to
laser signal is sent to the ordnance device protect against electrostatic discharge (ESD) and
through the same fiber optic used to initiate electromagnetic pulse (EMP).
that device. This signal reflects off the di-
chroic mirror deposited on the window in 2.4.2 Power Converters. The LFU is equipped
the ordnance device and returns to the BIT with two DC/DC power converters that provide
system through the same fiber optic. A pho- regulated sources of 5 Vdc for logic circuits, and
todiode and electronic circuit measure its of 15 Vdc for the analog circuits and the BIT
intensity. lasers. Unregulated 28 Vdc provides power to
Dual Fiber Reflective BIT. A low power both DC/DC converters and to tile Pre-arm Cir-
laser signal is sent to the ordnance device cuit. Note, the DC/DC Converters operate when
using the same high power diode laser and 28 Vdc is present no matter whether the Pre-ann
fiber optic used to initiate that device. The Switch Circuit is open or closed.
output power of the high power laser diode
is limited to a level safely below the no-fire The power returns for the 28 Vdc, 5 Vdc, and
level by an aperture in the shutter. A small 15 Vdc sources are separately routed. They are
fraction of this signal reflects off the ord- connected to the chassis at a single point
nance device window and returns to the BIT through 47 kfl resistors bypassed by 0.01 gF
system through a second fiber optic. The capacitors. This minimizes cross talk between
BIT system uses a photodiode and electronic tile digital, analog, and laser fire circuits.
- 104 -
[ Laser Firing Unit
p/o J1
Output Circuits L
BIT Fail Status
BIT Pass Status
Tranelent Suppressors[-
Pre-Arm
Ch ....
Command
l Select ]nputB [F-_
[-_JP/°lJl
[
Input Circuits _'
I (I
Controller
Redundant
=
Optocouplers J
¢ I _ 15 Vdc
I
/
/
[ BIT Laser
Circuit
_-_ Drive Channel 1 ] Fiber Optic
J2 Outputs to
Optical Ordnance
Devices
,__j_r Channel 2 ]
Channel 2 Output
(same as Channel I) ] (Single Fiber BIT)
Shutter in
Safe Position
FET Arm
Switch
_
in
Arm Position
2.4.3 Redundant Controllers. PS/EDD chose The BIT logic circuit part of each FPGA is basi-
to use hard logic implemented with application cally a string of latches fed by logic gates. This
specific integrated circuits (ASIC) instead of forms a state machine that sequences through a
using microprocessors or stored program devic- set of predefined steps. Each step sets the
es. This choice eliminates the costs involved in FPGA's outputs to predefined levels and per-
developing, debugging, and eventually qualify- forms a boolean logic test of all inputs. If the
ing software. test passes then the logic proceeds to the next
state, if it fails the logic indicates a BIT failure
Each Redundant Controller consists of a single and stops.
ACTEL brand factory programmable logic array
(FPGA). Both controllers are identical and op- The fire control logic circuit part of each FPGA
erate from a common clock. A common power- consists of logic circuits to decode the channel
up reset circuit resets the logic circuits in each selection and fire commands originating form
FPGA and initiates the automatic BIT testing of outside the LFU. It also consists of timing cir-
the LFU. cuits to control the duration of the High Power
Laser outputs.
- 105 -
Each FPGA monitors the following commands MOSFET switches to control both the +28 Vdc
originating from outside the LFU: Master Reset and 28 Vdc return lines, and to energize the
Command; Test/Launch Mode Command; Pre- LDSAM solenoid. It is also commanded by the
arm Command; Arm Command; Channel Select Redundant Controllers through two series con-
Inputs (Select 1, Select 2, and Select 3 Com- neeted optocouplers and provides a single moni-
mands); and Fire Command. Each FPGA also tor signal to both Redundant Controllers through
monitors the following internal signals: Pre-arm an optocoupler.
Switch Circuit monitor; Arm Switch Circuit
monitor; Safe position status of LDSAM; and 2.4.5 High Power Laser Drive Circuit. This
output of the Bit Sense Circuit. drive circuit consists of four individual
MOSFET switches to control each of the four
Each FPGA generates the Bit Pass and Bit Fail High Power Laser Diodes. These MOSFET
status commands for use by missile systems switches receive switched +28 Vdc power from
outside the LFU. Each also generates com- the Pre-arm Switch Circuit through a common
mands to arm the Arm Switch Circuit and to fire current regulator circuit. The current regulator
High Power Laser Diode Drive Circuits. The compensates for variations in the unregulated
FPGA's command outputs are ANDed together 28 Vdc power source and provides a constant
by the subsystems they control. In other words, current to the High Power Laser Diodes. It is
both FPGAs must issue identical output com- designed to operate the lasers within their rated
mands before a subsystem uses that output power limits.
command. The BIT Fail status outputs are
ORed together so that either controller can issue The MOSFET switches provide the second stat-
a BIT failure signal. ic switch function for ordnance initiation power
and are controlled by the Redundant Controllers
2.4.4 Pre-arm and Arm Switch Circuits. The through two series connected optocouplers. As
LFU uses unregulated 28 Vdc to energize the with the Pre-arm and Arm Switch Circuits, this
LDSAM solenoid and to power the High Power arrangement requires that both Redundant Con-
Laser Diodes. The unregulated power is first trollers issue the fire command to turn on a laser
routed through the Pre-arm Switch Circuit to diode.
provide the first static switch function for arm-
ing and ordnance initiation power. 2.4.6 BIT Laser Drive Circuits. This drive
circuit consists of two individual MOSFET
The Pre-arm Switch Circuit uses MOSFET switches to control each of the two BIT Laser
switches to switch both the +28 Vdc and 28 Vdc Diodes used in the single fiber BIT system.
return lines, and is commanded by the Redun- These MOSFET switches receive regulated
dant Controllers through two series connected 15 Vdc from the Power Converters through a
optocouplers. This arrangement requires that common current regulator circuit. The current
both Redundant Controllers issue the Pre-arm regulator provides a constant current to the BIT
command to turn on the Pre-arm Switch Circuit. Laser Diodes and operates the lasers within their
The Pre-arm Switch Circuit also provides a sin- rated power limits.
gle monitor signal to both Redundant Control-
lers through an optocoupler. The MOSFET switches are controlled by the
Redundant Controllers through two series con-
The switched +28 Vdc and 28 Vdc return out- nected optocouplers. As with the High Power
puts of the Pre-arm Switch Circuit is then routed Laser Drive Circuits, this arrangement requires
to the High Power Laser Drive Circuits and to that both Redundant Controllers issue the fire
the Arm Switch Circuit. command to turn on a laser diode.
The Arm Switch Circuit provides the second 2.4.7 BIT Sense Circuit. This circuit supports
static switch function for arming power. It uses the optical continuity BIT function by sensing
- 106 -
the reflected light and by providing a simple The optical path starts with a 920 nm wave-
digital signal to Redundant Controllers. The length High Power Laser Diode coupled to a
BIT Sense Circuit supports both Single and Dual collimating lens and mounted in the LDSAM,
Fiber BIT systems, and consists of: shown in the Initiation Subsystem Functional
• Photo diodes to sense the reflected BIT sig- Block Diagram Figure 4. The collimated laser
nals light passes through the LDSAM shutter and is
• Analog circuits for amplification and level refocused into a 100 pm fiber using another lens
detection in the LDSAM. For channels one and two, the
• Optocouplers for output to the Redundant coupler is the next item in the optical path. Fi-
Controllers nally the J2 connector on the LFU is the last
item in the optical path. Table 1 lists the typical
The sensitivity of the BIT Sense Circuit is limit- output delivered to an ordnance device through
ed by the photo diode's rated dark current while the external 110 pm cables.
the response time is limited by the photo diode's
total capacitance rating. In other words, the 3.2 Requirements. There are no established
optical BIT signal must be bright enough to be industry-wide all-fire and no-fire standards for
reliably detected above the photo diode's worst laser ordnance. However, PS/EDD has designed
case dark current and must be present long several diode initiated devices. As an example,
enough for the photo diode's capacitance to we designed and manufactured a miniature pis-
charge up. ton actuator that had a 320 mw all-fire and a
130 mw no-fire using 110 lam diameter fiber.
We used these levels as a guide in developing
3. LASER DIODE INITIATION SUBSYS- the LFU.
TEM.
This actuator used titanium potassium
3.1 Introduction. The basic mechanism for perchlorate for the ignition/output charge and
laser ignition is thermal in nature. The laser incorporates a fiber optic pigtail. A Neyer sta-
ignition system must deliver a sufficient intensi- tistical analysis was used to detennine the all-
ty to raise the temperature of the ordnance com- fire and no-fire levels. Table 2 shows the test
pound above its ignition temperature. This de- data from the Neyer test performed on the piston
pends on the properties of the ordnance com- actuator. The power levels listed in the table
pound such as: ignition temperature, thermal were measured prior to each test shot using the
diffusivity, specific heat, surface optical fiber that connects to the pigtail of the device.
properties, and particle size.
3.3 Design Trades. The main goal in designing
The Laser Diode Initiation Subsystem uses con- the LFU is to maximize the efficiency of deliv-
tinuous type lasers that are typically rated in ering power to the ordnance devices. This usu-
watts. For this reason, it is best to specify the ally requires selecting a fiber optic cable with
all-fire and no-fire levels in units of power the smallest diameter practical and usually be-
(milliwatts) instead of units of energy comes a trade between launch efficiency and
(millijoules). Since the all-fire and no-fire lev- spot size. In other words, one must select a
els depend on spot size, the type of fiber used to combination of laser diodes and fibers that sup-
deliver the laser energy to the ordnance device ply the largest power per unit area. Minimizing
must be specified. the quantity of connector interfaces is another
design goal.
For this design we used a 100 pm core step in-
dex fiber optic inside the LFU and 110 pm core In designing ordnance devices, the main goal is
step index fiber for tile external cables. This to minimize the spot size at the ordnance com-
conserves the intensity of the laser diode as it is pound while meeting other requirements like
delivered to the ordnance device. cost, proof pressure, and sealing. Fiber optic
- 107 -
Table 1. Measured LFU Output 3.4 Output Tests. We measured the LFU out-
puts at the ordnance end of external 110 _tm
cables. The results are listed in Table 1. Note,
Output Typical Margin the LFU can delivers sufficient laser intensity to
Channel Output ('based on
320 mw all-
initiate ordnance devices with 141% to 162%
Power
fire) margins above an 320 mw all-fire requirement.
162% This margin means that the LFU operates from
27.1 dBm
4.3 to 6.4 times the 30.7 mw sigma over the
(517 mw)
0.999 reliability all-fire level shown in Table 2.
2 26.6 dBm 141%
(452 mw) Table 2. Neyer Analysis of Laser Initiated Pis-
3 27.0 dBm 156% ton Actuator
Stimulus in Successes
4 26.8 dBm 151%
milliwatts
(482 mw)
133.0 0
172.0 0
190.0 0
cables emit light in a diverging cone that causes
the spot size to grow with distance. To mini- 213.0 1
mize the spot size, the ordnance device must
either put a fiber in contact with the ordnance 241.0 0
compound or use optics to refocus the spot onto
243.5 1
the ordnance compound. Plane parallel win-
dows are not typically used in devices initiated 279.0 1
by laser diodes. However, a gradient index
(GRIN) lens or an integral fiber can efficiently 289.0 1
couple a fiber's output to the ordnance com-
298.0 1
pound.
460.0 1
Note:
The Mu was 222.9 mw with a sigma of
30.7 mw. The calculated 0.999 all-fire
level is 317.8 mw and the 0.001 no-fire
level is 128.1 mw.
- 108 -
Laser Firing Unit 1
Channel 1
J2
Optical Connector at
Coupler Ordnance Device
Connector at
Channel 3 Ordnance Device
Channel 4
(same as Channel 3)
2.
Safe
Laser
I
_
Diode S//A
Shutter
Arm Position
Module
in
l
Figure 4. Initiation Subsystem Functional Block Diagram
4. SINGLE FIBER BIT SUBSYSTEM. During Single Fiber BIT operation, the LDSAM
is in the safe position with the output of the
4.1 Introduction. The Single Fiber BIT Sub- High Power Laser Diodes blocked by the closed
system is meant to detect broken fiber optics or LDSAM shutter. A BIT laser is fired to provide
mismated and contaminated optical connections. a low power laser pulse to illuminate the ord-
Each Single Fiber BIT channel consists of fol- nance device through the single output cable.
lowing elements shown in Figure 5: The dichroic coating on the ordnance device
• A 1.0 mw BIT Laser Diode operating at window reflects 90% of the BIT laser output
780 nm wavelength back to the LFU through the same cable. The
• A fiber coupler that has three inputs and one fiber coupler directs this reflected signal to the
output BIT Sense Circuit.
• A common BIT Sense Circuit to detect the
reflected optical BIT signal. 4.2 Requirements. To keep with the spirit of
• An ordnance device with a dichroic coating the monitor circuit requirements of MIL-STD-
on the window that reflects 780 nm wave- 1516, the power of the BIT signal should be
length light. kept 20 dB below the rated no-fire of the ord-
nance device. Note, MIL-STD-1516 para-
The Optical Coupler provides paths for injecting graph 5.10.7 limits the monitor current for
the BIT laser signal into the output fiber and for electroexplosive devices to one tenth of the no-
extracting the return signal from the output fi- fire level. This corresponds to a one hundredth
ber. The three inputs of the coupler are connect- factor for power or a margin of 20 dB.
ed to tile High Power laser diode, BIT laser di-
ode, and the BIT photodiode.
- 109 -
BIT __ Laser Firing Unit
Sense
Circuit •
BIT Laser
J2
SMA Connector
Connector at
_-- Shutter in Ordnance Device
The BIT Laser Diodes are rated at 1.0 mw 4.4 BIT Tests. We perfornaed some testing to
which is 21 dB below the no-fire level of determine the reflection losses that we can ex-
130 mw. This 1.0 mw output is attenuated by pect at tim ordnance device during Single Fiber
the 11 dB loss in the coupler and the coupling BIT. A mirror and GRIN lens simulated the
loss to the fiber. In other words, the laser inten- ordnance device with dichroic coating. A
sity at the ordnance device is at least 31 dB be- 110 Inn fiber optic with an SMA connector was
low the no-fire level of 130 mw or 12 dB lower routed from the LFU and mated with the GRIN
than the MIL-STD-1516 requirement. Note, this lens/mirror combination. Using an optics bread-
does not include the losses associated with the board we could vary the gap distance between
connectors (typically 0.7 dB fo 1.5 dB loss per the SMA connector and the GRIN lens. Using a
connector) and with the dichroic coating (10 dB HeNe laser in place of the BIT laser diode, we
loss i.e. it passes 10% at 780 nm). measured the reflection loss for a variety of
gaps. Figure 6 is a plot of the relative loss vers-
4.3 Design Trades. Unwanted reflections are es gap distance. The loss values are referenced
the main limiting factor for tim Single Fiber BIT to the BIT output intensity of the LFU.
system. These are caused by the connectors in
the optical path and by the coupler's internal As Figure 6 shows, there is a 1.5 dB dynamic
reflections. These reflections are sensed by the range for discriminating between pass and fail.
BIT Sense Circuit and appear as background However the intensity of the reflection is only
noise that the BIT reflection must over come. about 22 dB to 24 dB below the LFU's BIT out-
For connectors, the fresnel reflection at each put. In the spirit of MIL-STD-1516, the BIT
glass-to-air interface is 4.0% of the incident reflection could be as bright as 44 dB below the
light. The intensity of the coupler's internal rated no-fire of the ordnance device. This could
reflections are approximately 25 dB below (or be as much as 5.2 law for a system using
0.32% of) the BIT Laser intensity. The main 130 mw no-fire ordnance devices. Silicon
design trade is to optimize the coupler design to photodetectors have a typical sensitivity of
minimize reflections while still providing an 0.5 laA/law and would generate a 2.6 laA signal
adequate optical path for initiation energy. that is easily detectable.
- 110 -
-22
-'-' -22.2
r'n o,..
•1o .._
"'" :0 -22.4
_0
0:2:)
.-; u_ -22.6
r.- J
o -22.8
13-. 0
.o o -23
u_
= _ -23.2
(_ d,)
rv" n,,
-23.4
....... f , I
1.00 2.00 3.00 4.00 5.00
Figure 6. Reflection Loss Verses Gap Distance for Single Fiber BIT
5. DUAL FIBER BIT SUBSYSTEM. SMA type fiber optic connector with two fibers
bonded side-by-side and polished. The fiber
5.1 Introduction. The Dual Fiber BIT Sub- core diameter was 110pm with an overall diam-
system is meant to detect mismated and contam- eter of 125 pm, and a numerical aperture (NA)
inated optical connections. It uses two separate of 0.37.
fibers from the LFU that are terminated together
in the connector that mates with the ordnance 5.2 Requirements. To keep with the spirit of
device. One fiber connects to a LDSAM output the monitor circuit requirements of MIL-STD-
while the other connects to a PIN diode 1516, the power of the BIT signal should be
photodetector in the BIT Sense Circuit as shown kept 20 dB below the rated no-fire of the ord-
in Figure 7. nance device. Note, MIL-STD- 1516 para-
graph 5.10.7 limits the monitor current for elect-
During BIT, the LDSAM is in the safe position roexplosive devices to one tenth of the no-fire
and a high power laser diode is fired to provide level. This corresponds to a one hundredth fac-
a low power laser pulse to illuminate the ord- tor for power or a margin of 20 dB.
nance device. Note, the output power of the
high power laser diode is limited by an aperture The High Power Laser Diodes have a 13 dB
in the shutter. A small fraction of this signal dynamic range from 0.1 W at threshold to a
reflects off the ordnance device and returns to maximum of 2.0 W. This dynamic range is not
the BIT Sense Circuit through a second fiber op- large enough to use current limiting alone to
tic. reach the 20 dB safety margin. Therefore a
shutter with either an aperture or other type of
We wanted to minimize costs by making the optical attenuator was required. We found that
ordnance interface simple fabricate. The cable an aperture of about 0.005 in. provides 27 db to
interface at the ordnance device consists of an 30 dB of attenuation.
- 111 -
Laser Firing Unit
0 J2
High
Laser
Circuit
Pwr
Drive
0
t connector
Ordnance Device
Shutter in
Safe Posilion
5.3 Design Trades. The main design trade for re-image the laser spot while providing a seal.
a Dual Fiber BIT systems is cost verses the in- Ideally, the net effect of such optics would be
tensity of reflected signal. For example, we the same as not having any optics. For simplici-
could have used a coupler, a separate BIT laser ty, Figure 8 does not show any re-imaging op-
operating at 780 nm, and a dichroic coating on tics.
the ordnance device. This would have increased
the reflected signal however the system cost and The bottom fiber illuminates the reflector while
configuration are very similar to the Single Fi- the top fiber gathers the reflected light. Both
ber BIT configuration. Alternately, we could fibers emit or accept light in diverging 43.4 de-
have complicated the ordnance interface to im- gree cones that overlap at the reflecting surface.
prove the intensity of the reflected signal. How- The intensity of the reflected BIT laser signal is
ever this would significantly increase the cost of directly effected by this overlap area and by
the ordnance devices. reflectivity of the ordnance compound.
For our low cost approach, the critical design Note that the area of this overlap varies with the
trade is to maximize the reflected BIT signal gap between the reflector and the fiber ends.
while providing adequate initiation power. For a given set of fiber core diameters and fiber
Figure 8 shows the ray diagram associated with spacing, there is a range of usable gaps with
a pair of fibers up against a reflector. The re- specific minimum and maximum gap distances.
fleeting surface represents the ordnance com- One can expect the intensity of tile reflected BIT
pound and fresnel reflections from and imaging to increase with gap distance to a peak value and
optics associated with a practical ordnance de- then decrease with larger gap distances. To
vice. Unlike the single fiber BIT approach, di- avoid the ambiguity of having an intensity value
chroic coatings can not be used since this ap- indicate two different gap distances, a designer
proach uses the same laser for BIT and initia- would select a gap that is ate or beyond the
tion. peak.
- 112 -
/__ Acceptance &
/ radiation angle
_J
determined by NA
__ Reflecting surface
/Acceptance &
0.ii0 mm core dia _ _/ radiation angle
0.125 mm overall dia _p determined by NA
NA=0.37
Usable range for
Half angle = 21.72 deg
Reflecting surface
As mentioned in section 3.1, any gap in the As discussed in section 5.3, the selected fiber
fiber-to-ordnance interface increases spot size geometry has a range of usable gaps with specif-
requiring more all-fire power from the High ic minimum and maximum gaps. The effect of
Power Laser Diodes. With this type of fiber the minimum gap can be seen in the steep rise
geometry, one must select the BIT laser, fiber while the effect of the maximum gap is seen in
size, and ordnance interface geometry to maxi- the curve's fall.
mize the reflected BIT signal while providing
adequate initiation power for the resulting spot However, one would expect a steeper fall than
size. shown. We believe that the gradual drop is
caused by reflections from the test setup. Simi-
5.4 BIT Tests. We performed some testing to lar reflections might be expected from a connec-
determine the reflection losses that we can ex- tor that is partially mated to an ordnance device
pect at the ordnance device during Dual Fiber with its clean reflective connector interface. In
BIT. A flat black surface and GRIN lens simu- any case, the such reflections effect the sensitiv-
lated the ordnance device. A pair of 110 lam ity of this BIT approach.
fibers were terminated in an SMA connector
mated with the GRIN lens/black surface combi- As Figure 9 shows, there is a 15 dB dynmnie
nation. One fiber was routed from a HeNe laser range for discriminating between pass and fail.
to simulate the LFU's BIT output and the other However the intensity of the reflection ranges
fiber was monitored by an optical wattmeter. from 26 dB to 40 dB below the LFU output. In
the spirit of MIL-STD-1516, the BIT reflection
Using an optics breadboard we could vary the could be as bright as 46 dB to 60 dB below the
gap distance between the SMA connector and rated no-fire of the ordnance device. This could
the GRIN lens. Figure 9 is a plot of the relative be as much as 3.3 gw to 130 nw for a system
loss verses gap distance. The loss values are using 130 mw no-fire ordnance devices. Silicon
referenced to the output intensity of the LFU. photodetectors have a typical sensitivity of
The loss curve starts at a low level, peaks at - 0.5 gA/gw and would generate a 1.7 gA to
25 dB, and the gradually drops to -40 dB. Note 65 nA signal that is not easily detectable.
that losses between -25 dB to -40 dB correspond
to two different gap values.
- 113 -
-2O
ro CL
-o
v "-'i
t/) 0 -30
O :D
._1 I..i_
t-- iI
t_ -40
[3.. "o
t--
O
°_ c
o
LI, I
-5o
t-v" n"
-6O 1 i i i i i i i i iii ii i i
Figure 9. Reflection Loss verses Gap Distance for Dual Fiber BIT
- 114 -
LIO Validation on Pegasus
Arthur D. Rhea
- 115-
EBW'S AND EFI'S
THE OTHER ELECTRIC DETONATORS
RON VAROSH
RISI
this "exploding wire concept" could Both EBW's and EFI's require a unique
also be used to initiate secondary high amplitude electrical pulse, and
explosives such as PETN and RDX. The each contains only secondary explo-
concept remained classified for many sives. The differences are that the
- 117 -
simple hot wire devices, that the nize cameras, flash X-Rays, etc. with
question must be addressed as to why detonations makes good use of the
bother with this added complication? inherent repeatability of EBW's and
Three major reasons why people bother EFI's. Much of the explosive welding
with EBW's and EFI's are: is performed on-site to electric
power plant boilers - a location
Safety notorious for stray voltages. Not
Repeatability only is the safety important here,
Reliability. but in addition many of the welds
require the simultaneous detonation
Safety comes primarily from the fact of two charges. Safety is the prim-
that no primary explosives are used ary requirement for the majority of
in either device. Both are electro- the other applications. Mining
statically safe as demonstrated by applications are limited since most
the "standard man test (5). Nominal mining requires "ripple" firing -
values of RF are also not a problem something extremely difficult to
(6). Stray currents do not affect the accomplish with either EBW's or
devices since approximately 3 amps DC EFI's.
are required to melt open a common
type bridgewire and about 5 amps to EBW CONSTRUCTION
open a typical foil. Figure 1 shows a typical EBW detona-
tor and compares it with a typical
The second major reason for using
EBW's and EFI's is their excellent
shot to shot repeatability. Even
with different firing systems, shot
to shot repeatabilities under 5
microseconds are easily obtained.
Military Ordnance
Military R & D hot wire detonator. Heads and output
Explosive Welding pellets are the same for both detona-
Explosive Hardening tors. The major differences are in
Seismic the bridgewires and initial press-
Oil Fields ings. EBW's generally use gold or
Forest Service platinum wires, primarily for their
Mining inertness, while hot wire devices use
Power Plants high resistance materials such as
Nichrome. The explosive against the
Military Ordnance is an obvious bridgewire in an EBW is generally
application, although most conven- PETN although RDX and "thermites"
tional weapons still use hot wire have been used. Hot wire devices
initiators. The reverse is true with generally have Lead Azide or Lead
Ordnance R & D. The need to synchro- Styphnate against the bridge wire.
- 118 -
In addition, the explosive in an EBW The length of the narrow section is
is generally at about 50 percent of approximately equal to the width i.e.
crystal density. In the EBW, the about 0.008 inch long.
"explosion" of the wire starts a
detonation without any intervening
deflagration as is the case with a
hot wire detonator. Tamper
SAFETY DATA
Since EBW's have been around for
Bridge Foil
almost 50 years a great deal of test
data has been accumulated by various
organizations. Everyone has an opin-
ion on which safety tests are most Dielectric
- 119 -
same way except the rapid expansion such as:
of the dielectric "bubble" is the
source of the kinetic energy. batteries
line voltage
Both, EBW bridgewires and EFI foils piezoelectric generators
"explode" because the electric cur- fluidic generators
rent is heating the conductor which etc.
"l 1T '
I
I
1
Time, microseconds
A wide variety of switches have been Both work exactly the same way.
used for both EFI's and EBW's. These Current flows through the device,
have included: when the bridge starts to heat the
resistance increases and the current
- 120 -
19
Also, the current at threshold is
constant regardless of circuit param-
eters whereas the threshold voltage 18
t.7
Burst, preferably should occur at
m
about 1 microsecond for an EBW, and
1.6
0.1 microsecond for an EFI. Longer
times allow the wire or foil to melt
O 1.5
open before exploding. xz
L_
EXPLOSIVES 1.4
- 121 -
burst time is 1 microsecond for an
ELECTRIC DETONATOR COMPARISON EBW and i00 nanoseconds for an EFI.
Of particular interest, is the fact fired over i00 feet of twin lead or
that all the energy values are ap- 300 feet of coax at 3.5kv from a 1
nators. The major difference between obtaining the low inductance required
the three detonators is the power. for a fast rise time.
- 122 -
tures of a Physicist," Basic Books,
Inc., New York, 1987, pp. 132-135.
- 123 -
/ G
LOW COST, COMBINED RADIO FREQUENCY AND ELECTROSTATIC PROTECTION
FOR ELECTROEXPLOSIVE DEVICES
Robert L.Dow
President, Attenuation Technology Incorporated
- 125 -
get the desired combined RF New Technoloqy: The first
and electrostatic (ES) protec- ferrite formulation character-
tion characteristics in the istic that was changed was the
final ferrite protection de- Curie Temperature. This phys-
vice, and then to place that ical property characteristic
ferrite device inside the is important because, when the
electroexplosive devices lossy ferrite device is ex-
(EEDs) in direct contact with posed to RF energy, it con-
and electrically grounded to verts that RF energy to heat.
the conductive case. If that heat cannot be removed
effectively, the ferrite de-
Backqround: Prior to our new vice will increase in tempera-
efforts in this area, prior ture. When the ferrite device
art EED RF protection applica- reaches its Curie Temperature,
tions used ferrite devices it stops converting the RF en-
with Curie Temperatures as low ergy to heat. If the ferrite
as 150°C. The Curie Tempera- device reaches its Curie Tem-
ture of these prior art de- perature, it can not protect
vices was exceeded within a the EED. The RF attenuation
few seconds when the EED was property is reversible in that
exposed to RF energy levels once the ferrite device cools
called out in MIL STD 1385. below its Curie Temperature,
The early prior art ferrite it resumes attenuating RF en-
devices also had cutoff fre- ergy until it repeats the tem-
quencies above 3 megahertz, perature cycle.
which made them unacceptable
when MIL STD 1385 required RF ATI has consistently increased
protection at one megahertz. the Curie Temperatures of its
lossy, soft ferrite formula-
These early failures gave tion with 250 to 280°C modifi-
- 126 -
not DC conductive. Further, eliminated. One lossy ferrite
most of these prior art lossy device could provide both RF
ferrite devices were potted in and ES protection for the EED
place in the EEDs with noncon- for both pin-to-pin and pin-
ductive adhesives. We made to-case RF and ES energy expo-
the conscious effort to go in sure modes.
the opposite direction and
provide lossy, high Curie Tem- It was also determined that
perature ferrite device with a the ferrite device could be
controlled DC resistance inserted into EEDs, such as
within an acceptable range. electric blasting caps (EBC)
thin conductive case, without
The third lossy ferrite formu- excessive breakage. It was
lation physical property that further determined that a good
is included in all our ferrite electrical ground could be
formulations is cut off fre- achieved between the lossy
quenc_q_ below one megahertz. ferrite device and the conduc-
MN 68 "xm Ferrite Devices suc- tive case using just the in-
cessfully attenuate RF energy sertion assembly method. All
at i0 kilohertz. of this work was done with
ferrite devices that were
Our lossy ferrite devices have right circular cylinders. New
a sufficiently low DC resis- manufacturing methods have re-
tance to equalize the electro- cently been developed, so that
static energy that can build a chamfer can be molded into
up between the firing leads of the finished ferrite device to
an EED (pin-to-pin) and/or be- make assembly of other EED de-
tween the firing leads and the signs easier.
conductive case of an EED
(pin-to-case). Our lossy fer- Benefits of Deslqn: The first
rite devices have sufficiently synergistic effect of this as-
high DC resistance so that sembly procedure was that once
they do not act as a DC shunt all of the electrically insu-
for the EED's DC firing pulse. lating potting material was
Each EED application must be removed from the EED design,
tailored to work within those the heat conduction path
DC limits. ATI has developed available to cool the RF at-
the technology to provide this tenuating ferrite device were
acceptable range for each EED greatly improved. Thus, sub-
application. sequent EED designs that con-
tained the higher Curie Tem-
Improved EED Deslqn: Once the perature lossy ferrite de-
three ferrite device require- vices, actually stabilized at
ments were met, the design of lower temperatures when ex-
the RF protective device and posed to comparable amounts of
assembly methods used for se- RF energy than prior art EED
curing it in the EED could be designs.
greatly simplified. Noncon-
ductive potting materials were This observation was at-
no longer required during EED tributed to an improved heat
assembly. The electrical in- removal path directly to the
sulation previously used on EED's conductive case, provid-
the firing leads passing ing better cooling of the at-
through the ferrite device was tenuating, lossy ferrite
- 127-
device. Thus, the safety fac- lossy ferrite choke, has been
tor of these new EED designs reported as passing MIL STD
were improved by two mecha- 1385B RF testing as well as
nisms instead of the original the electrostatic testing.
approach of simply using the
Production Status: ATI is
higher Curie Temperature,
lossy ferrite devices. currently working with three
USA ferrite device manufactur-
The second synergistic effect ers to produce these lossy,
was that tieing the conductive high Curie Temperature, con-
EED case to the firing leads trolled DC resistance, ferrite
through the controlled circuit devices using high volume, low
ferrite allowed large amounts cost production techniques.
of ES energy to be safely dis- So far, the largest production
sipated without firing the lot has only been 25,000 bare
EED. Laboratory tests of the ferrite chokes. This quan-
ATI ferrite devices showed tity, while very small by fer-
that repeated exposures of the rite manufacturer's standards,
wound ferrite devices with up was produced without signifi-
to 12 Joules of ES energy did cant production problems. ATI
not destroy the ferrite device is also working with an over-
or change its RF attenuation seas source for potential ap-
properties. Most other compo- plications in Europe.
nents in the EED when exposed
to that level of ES energy Certification Approach: Some
only once, were completely of the ferrite manufacturers
disintegrated, destroyed, or are offering their versions of
failed to the duded mode. high Curie Temperature, lossy
ferrite devices that are pur-
The final discovery was that ported to be as effective as
the level of RF protection our MN 68 TM Ferrite Devices.
could be changed by selection We have been award_ the USA
of the winding pattern used in Trademark on MN 68 _** to dis-
the ferrite device. One and tinguish our ferrite devices,
one half turns of additive certified by ATI, from those
choke windings on each firing produced with similar formula-
lead was necessary for the EBC tions but not tested as com-
to pass MIL STD 1385B environ- prehensively. ATI has a Cer-
ments, but other winding pat- tification Mark pending at the
terns can be used for commer- US Patent and Trademark Of-
cial applications where the RF fice.
- 128 -
cation, subsequent production protection and ferrite device
lots can be certified to the certification areas.
levels required.
During the EED protection
ATI is maintaining certified technology evolution, ATI de-
ferrite device samples from termined that the technology
each EED successfully quali- can be modified to protect
fied. These samples are main- other devices as well. The
tained to assure that new lots first medical protection de-
of the ferrite devices pro- vice patent US 5,197,468 has
duced in future years can be been issued. Other patent ap-
directly compared to the orig- plications are pending cover-
inal and certified equivalent ing many classes of equipment.
in performance to the baseline
sample. If the project spon- Conclusion: Since this is a
sor wants improved performance completely different approach
(based on how the technology to protecting EEDs from both
has progressed in the mean- RF and ES inadvertent ignition
time) or the projects safety with a single device, ATI is
requirements have increased in prepared to discuss any poten-
the interim, an improved ver- tial applications of this new
sion ferrite device can also technology area with anyone
be manufactured and made interested. Each solution
available. It now appears must be tailored for each ap-
that it may be possible to plication. The technology ap-
produce the improved perfor- pears to have progressed suf-
mance ferrite devices without ficiently so that can be done.
any modifications to the pro- Please contact us if you are
duction tooling. interested in considering this
new approach.
US Patents: Since all of this
work has been funded solely by
ATI, patent protection is the
main form of intellectual
property rights protection.
ATI's issued patents are:
- IZ9 -
%
/ -
William P. Brigham
Explosive Projects and Diagnostics Department
John J. Schwartz
Stockpile Evaluation Department
ABSTRACT
The objective of this study was to find a material and configuration that could
reliably detect the proper functioning of a slapper (non-exploslve) detonator.
Because of the small size of the slapper geometry (on the order of a 15 mils),
most diagnostic techniques are not suitable. This program has the additional
requirement that the device would be used on a centrifuge so that it could not
use any electrical power or output signals. This required that the diagnostic
be completely passive.
The paper describes the three facets of the development effort: complete
characterization of the slapper using VISAR measurements, selection of the
diagnostic material and configuration, and testing of the prototype designs.
The VISAR testing required the use of a special optical probe to allow the laser
light to reach both bridges of the dual-slapper detonator. Results are given in
the form of flyer velocity as a function of the initiating charge voltage level.
The selected diagnostic design functions in a manner similar to a dent block
except that the impact of the Kapton disk from a properly-functioning slapper
causes a fracture pattern. A quick visual inspection is all that is needed to
determine if the flyer velocity exceeded the threshold value. Sub-threshold
velocities produce a substantially different appearance.
Introduction
function time, small jitter, and unique operation and design of the
relatively low energy requirements slapper requires sophisticated
compared to other types of detonators. diagnostics llke VISAR or closure
As part of the Sandia National switches to evaluate performance
Laboratories (SNL) evaluation program, parameters. The complexity of these
detonators are typically tested in the techniques makes their use difficult
.....................................
in the evaluation lab. This paper
This work was supported by the United discusses a device developed to
States Department of Energy under provide a simple evaluation of slapper
Contract DE-ACO4- 94AL85000. function within the constraints
- 131 -- ,. _'-_'"
P/Qi! ....................... "r_ .... '. I \;
......... "......,%
,/_.,
imposed by the laboratory environment. slapper is a dual-bridge functioned
It consists of a small glass target from a common firing set, it was
that provides a unique visual record desired to measure both flyers
when impacted by the flyer from the simultaneously. Most VlSAR's are
slapper. "dual-leg" to provide redundant
measurement of a single device using
two interferometers with different
Slapper Detonator experimental constants. A unique
optical probe was therefore developed
The SNL slapper detonator is shown in to convert the existing equipment into
Figure i. It consists of a central a dual system to make the two separate
"bullseye" connector for attachment to measurements.
the firing set with the flat copper
cables extending in opposite The probe allows the light from a
directions to form a single loop. The single laser to be split into two
upper layer of thin copper narrows at equal beams that are then fiber-
each end to form a "bridge" that coupled to the target locations. A
causes the current density to increase simplified schematic of the probe is
significantly. The current through shown in Figure 2 to demonstrate the
each bridge is strong enough to drive path of the light. The input fiber
the copper into vapor. The pressure connects to optics that allow the
of the gas causes the Kapton to shear light to be focused onto the target
against the sapphire "barrel" forming surface. The target surface causes
a rapidly-accelerating flyer with a the light to be scattered diffusely
diameter of about 0.015" where it is collected by other optics
within the probe. The light is then
Flyer velocity is a function of the collimated and focused onto the return
initial firing set charge voltage and fiber located at the rear of the
the resulting current. Typical probe. In this manner the image from
terminal velocity is on the order of each slapper can be routed to a
3-4 mm/_s, although other designs are different VISAR leg.
capable of nearly 6 mm/_s. It is
assumed that the flyer begins to come A unique feature of the optic probe is
apart soon after it leaves the barrel, the incorporation of a small camera to
but good data have been obtained for give a TV image of the target surface.
distances up to i mm. The most common The selective coating on the angled
practice is to place the explosive of mirror causes a portion of the
the next assembly in contact with the returned light to be transmitted to
barrel. the camera element. The TV image is
then present on a monitor within the
test area. This feature is essential
- 132 -
data were recorded on Tektronix DSA the designation "A" refers to the
602 transient digitizers. Data bridge that first receives the firing
reduction was performed following each pulse, based on the direction of the
test and stored on computer disk. current flow. The "B" suffix then
denotes the opposite bridge.
Figure 3 shows VlSAR data from an
experiment where the initial charge The results given in Figure 5 indicate
voltage was 2.6 kV. The data are in that the behavior of the detonator is
the form of flyer velocity and significantly more erratic at voltage
displacement versus time where the levels below 2 kV. It is thought that
distance is obtained by numerical at the lower voltage, minor tolerance
integration of the velocity-time differences in the construction of the
record. The behavior is typical of bridges have a more pronounced effect
slapper detonators in that the on the behavior. At the higher
acceleration of the flyer is less voltage levels, sufficient energy is
abrupt than a conventional available to overcome these
explosively-driven plate, although the differences and the velocity achieved
final velocity at the exit of the by the two bridges is more consistent.
barrel is over 3 mm/_s. Note that the For both tests at 1.6 kV, the "B" side
record continues for a distance of the unit failed to cause
approaching 0.75 mm. At the higher acceleration of the Kapton to a
initial charge voltage levels, breakup velocity sufficient to be measured by
of the flyer is assumed as manifested the VlSAR, which has a lower detection
by increasingly noisey signal quality. limit of about 0.2 mm/#s. Inspection
of the bridge following the shot
The data of Figure 3 can be cross- indicated that the copper had failed
plotted to give velocity as a function in the region of the bridge.
of displacement as shown in Figure 4.
This is particularly useful in Results in the voltage range above 2.0
assessing the velocity as a given kV show a correspondence between the
distance, such as the exit of the applied voltage and the resulting
barrel or the location of the next velocity. The greatest velocity, on
assembly. the order of 4 mm/#s, was achieved at
the highest voltage level. Some
The firing set for all tests was a Hi- scatter is present above 3.5 mm/_s
Voltage Components, Inc. model CDU2045 that is probably caused by breakup of
with a 0.2 #fd, 5-kV capacitor. the Kapton flyer. There does not
Initial charge voltage was varied from appear to be a discernible trend to
1.6 kV to 3.0 kV. Two tests were done establish that side "A" or "B" is
at each voltage level to provide consistently higher in velocity at a
redundant data. given voltage.
- 133 -
experience had shown that brlttle-like levels, while the 0.025" samples only
fracture could be introduced into some showed cracks at the higher charge
variety of material types, sizes, and a mild compressive load. The other
thicknesses. The presumed 50% side of the slapper continued to use
voltage of about 2.1 kV, although a fixture would have any effect on the
tests were done at higher and lower crack initiation and propagation.
levels to ascertain the sensitivity of
each configuration. Table 2 contains The results with the fixture suggest
the results from the initial screening that it may have induce a slight
tests. Some of the tests used a increase in the crack sensitivity of
slngle-brldge and are shown as one the glass. This is not consistently
configuration only, while the true for all the shots, but in no case
remainder are dual-bridge that may did the unflxtured end show greater
have a different device on each end. damage than the corresponding fixtured
side.
microscope slide also showed excellent unique optical probe was constructed
thicknesses in the range of 0.020" to between applied firing voltage and the
were found that could grind i" were seen between the two sides of the
diameter disks to virtually any value. unit and from one unit to another.
The 0.020" thick BK-7 samples from silica was selected based on
- 134 -
0.020" to 0.025" and a diameter of i"
provides acceptable performance. Table 3
Efforts are continuing using an BK-7 Test Results
intermediate thickness and fixturing
to improve the device's behavior for
the intended application. Charge Sample Number of
Voltage Thickness Cracks
(kV) (in.) (A) (B)
Table I
Slapper Flyer Velocity Results 2.2 0.020 0 0
2.4 " 4 6
Velocity at 0.5 mm
Firing Set Bridge A Bridge B 2.6 " 5 6
Voltage (kv) (ms/ms) (mm/_s)
2.2 O. 020 6 many
1.6 2.37
t!
2.20 2.0 " 4 2
- 135 -
Table 2
Results From Initial Screening Tests
t,
2.8 surface damage
1.8 tt
4 cracks from
contact point
(continued)
- i36 -
Table 2 (Continued)
- 137 -
Q,
L
a
.-w
c
- 138 -
n
W
.-
c
L
- 139 -
Displacemen't (ram)
m m
c: "_ D
\ _V
---I_
(A
w- L.
"5
e_
_==
=
• ._. •
m
(oasn/ww) bl 6_!OOlaN
- 140 -
!
c5
v
-I-'
C IN=
E
CI im
rx
A
m _ m_
.9. ,d "_
(oasn/_) Id _Ll.!OOleh
- 141 -
1
/
\
0
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i_
|: ,.,i,
111
_ i/ ,, ,
i i : • i i
.............................
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i........................ _.:::._ ..........
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(snlwLU)A±IOO7=IA
- 142 -
- .3 .'3
By:
Kenneth E. Willis
Quantic Industries, Inc.
990 Commercial Street
San Carlos, CA 94070
(415) 637-3074
Thomas J. Biachowski
Naval Surface Warfare Center
Indian Head, MD
(301) 743-4876
INTRODUCTION
One of the most efficient methods An integrated circuit performs the
for protecting electro-explosive de- following functions: 1) Chops the
vices (EEDs) from HERO and ESD is DC input to a signal suitable for
to shield the EED in a conducting driving the primary of the trans-
shell (Faraday cage). Electrical en- former, 2) Verifies the input volt-
ergy is transferred to the bridge by age is above a threshold, 3) Verifies
means of a magnetic coupling the input voltage is valid for a pre-
which passes through a portion of set time before enabling the device,
the conducting shell that is made 4) Provides thermal protection of
from a magnetically permeable but the circuit, and 5) Provides an ex-
electrically conducting material. ternal input for independent logic
This technique was perfected by ML level enabling of the power transfer
Aviation, a U.K. company, in the mechanism. This paper describes
early 80's, and was called a Radio the new RFAC product and its ap-
Frequency Attenuation Connector plications.
(RFAC). It is now in wide use in
the U.K. Previously, the disadvan- BACKGROUND
tage of RFAC over more conven- Electro-explosive devices (EEDs)
tional methods was its relatively must, in many applications, be pro-
high cost, largely driven by a thick tected against unintended initia-
film hybrid circuit used to switch tion by Electromagnetic Radiation
the primary of the transformer. (EMR) or Electrostatic Discharge
(ESD).
Recently, through a licensing
agreement, this technology has A variety of methods are in use to
been transferred to the U.S. and mitigate these problems; they in-
significant cost reductions and per- clude:
formance improvements have
been achieved by the introduction 1) Low resistance bridgewires
of analog integrated circuits. which can dissipate some elec-
- 143 -
trical energy before heating to
ignition temperature.
- 144 -
formed flawlessly. These systems modified to accept the inductive
include: coupling initiation hardware. The
MK23 Mod 0 cartridge was previ-
• Chevaline SLBM ously tested by the Navy in nu-
• Airfield Attack Dispenser merous configurations and rated as
(Tornado) "susceptible" when subjected to
• Torpedoes (Spearfish and Hazards of Electromagnetic Radia-
Stingray) tion to Ordnance (HERO) electrical
• Stores Ejection Systems field strengths. There have been
• ASDIC (Cormorant) several documented instances in
which MK23 Mod 0 cartridges have
In 1989, Mr. Tom Blachowski, this inadvertently actuated when sub-
paper's co-author, completed test- jected to a HERO or electromag-
ing of an RFAC equipped impulse netic interference environment.
cartridge for a Naval Surface War- These inadvertent actuations re-
fare Center (Indian Head) applica- suited in mission aborts, loss of es-
tion. sential equipment, and an in-
creased threat to crew members and
EVALUATION TESTING ground personnel during an elec-
The Indian Head Division, Naval trical event. ML Aviation Limited
Surface Warfare Center (NSWC) was contracted by NSWC to install
completed an evaluation of the in- the inductive coupling hardware
ductive coupling technology for into the existing MK23 Mod 0 car-
electrically actuated cartridges and tridge envelope maintaining the
cartridge actuated devices (CADs). same form, fit, and functions as the
This effort was performed as part of Navy standard device. ML Avia-
the Naval Air Systems Command tion packaged the existing RFAC
Foreign Weapons Evaluation secondary transformer into the
(FWE)/ NATO Comparative Test MK23 Mod 0 impulse cartridge and
Program (CTP). The FWE Program designed a primary transformer
is designed to assess the applicabil- into an electrical connector which
ity for foreign-developed, off-the- must be installed in the cartridge
shelf technology for procurement firing circuit.
and implementation in the U.S.
Fleet. The FWE goal is production These primary electrical connectors
procurement offering fleet users and inductively coupled MK23
enhanced performance while low- Mod 0 impulse cartridges were sub-
ering the per item cost to the pro- jected to a specialized design verifi-
gram managers. cation test series at the Indian Head
Division, NSWC. Two phases of
The FWE effort to analyze the in- design verification test were con-
ductive coupling initiation tech- ducted: the first phase was electrical
nology was structured as follows: A requirements and analysis
Navy standard electrically initiated (performed in accordance with
cartridge, the Mark 23 Mod 0 im- MIL-I-23659C, "General Design
pulse cartridge, was selected to be Specification for Electrical Car-
- 145 -
tridges"), and the second phase was
the functional testing of the car-
tridges (performed in accordance
with MIL-D-21625F, "Design and
Evaluation of Cartridges and Car-
tridge Actuated Devices").
- 146 -
9. Designed to be nuclear hard.
Io
o K;
Im,ti
i
! r4 N
P-TI
I._
I_AC PEKFO_NCE , m
Figure 3 klDo L.
- 147 -
Visual inspection diode power supply makes this
Radiographic Inspection problem disappear. A system which
Bridgewire integrity protects the diode and its power
Electrostatic discharge
supply inside a Faraday closure
Stray voltage
Forty foot drop should meet all safety require-
Six foot drop ments for diverse applications such
Temperature, humidity, and altitude as crew escape systems, rocket mo-
cycling tor arm fire devices and automo-
Salt fog
tive air bag initiation.
Cook-off
High temperature exposure
BIOGRAPHIES
High temperature storage
Low temperature (-65°F) testing Mr. Blachowski has held his pre-
Ambient temperature (+70°F) testing sent position as an Aerospace En-
High temperature (+200°F) testing gineer in the Cartridge Actuated
Devices Research and Develop-
APPLICATIONS ment Branch at the Indian Head
The potential applications of RFAC Division, Naval Surface Warfare
include essentially all EEDs which Center for 5 years. In that time, he
must operate in HERO and ESD has been involved in exploratory
environments. We expect the re- R&D, advanced development,
duced cost, made possible by inte- product improvement, and pro-
grated circuit technology, will sub- gram support for cartridges and car-
stantiaUy expand these applications tridge actuated devices throughout
in both the U.S. and U.K. However, the Navy. Mr. Blachowski received
In closing, I would like to discuss his Bachelor of Science degree in
one novel application that may be Aeronautical and Astronautical
of interest to this audience.
Engineering from Ohio State Uni-
versity in 1985.
The increasing availability of high
power diode lasers has sparked the As division vice president at Quan-
interest of the ordnance commu- tic Industries, Inc., Mr. Willis is re-
nity. A fiber optic cable can conduct sponsible for directing internal re-
the optical energy into an initiator search and development activities,
which is totally immune to RF and developing new products and new
ESD hazards. Offering very business activities. Product areas
lightweight and potentially low include electronic, electromechani-
cost for sating and arming func- cal and ordnance devices used for
tions, the diode laser is nearly ideal safety and control of systems using
for many applications. There is one energetic materials and processes.
catch; the diodes laser generates the
optical energy with a low voltage Mr. Willis received his Master of
(typically 3 volts) source. This cre- Science Degree in Physics from Yale
ates a single point failure safety University in 1959 and a Bachelor
problem unless mechanical means of Arts Degree from Wabash Col-
are used to block the light. How- lege.
ever, using an RFAC to isolate the
- 148 -
/b
William P. Brigham
Explosives Projects and Diagnostics Department
Sandia National Laboratories has recently completed This paper describes the Cable Discharge System
the modification and installation of a cable discharge (CDS) and its use in fundamental detonator studies.
system (CDS) which will be used to study the The CDS is preferred over a conventional capacitor
physics of exploding bridgewire (EBW) detonators discharge unit (CDU) that delivers a decaying
and exploding foil initiators (EFI or slapper). Of sinusoidal current pulse. The fast rising constant,
primary interest are the burst characteristics of these "stiff", current, provided by the CDS charged
devices when subjected to the constant current pulse cable(s) eliminated the uncertainty of a continuously
delivered by this system. The burst process involves changing current density that comes from a CDU.
the heating of the bridge material to a conductive The CDS is actually two systems; the cable discharge
plasma and is essential in describing the electrical system which provides a square wave current pulse
properties of the bridgewire foil for use in to the detonator and the instrumentation system
diagnostics or computer models. The CDS described which measures the detonator parameters of interest.
herein is capable of delivering up to an 8000 A pulse Fundamental detonator studies using the CDS
of 3 _ duration. Experiments conducted with the generates information to be used in diagnostics or
CDS to characterize the EBW and EFI burst computer models. Computer modeling provides
behavior are also described. In addition, the CDS electrical/mechanical performance predictions and
simultaneous VISAR capability permits updating the failure analysis of exploding foil initiator (EFI) and
EFI electrical Gurney analysis parameters used in exploding bridgewire (EBW) detonators. This
our computer simulation codes. Examples of CDS project is being performed in order to improve
generated data for a typical EFI and EBW detonator computer modeling predictive capabilities of EFI and
are provided. EBW detonators. Previous computer simulations
predicted a much higher voltage across the bridge
than was measured experimentally. The data used in
these simulations, for the most part, was collected
two decades ago. Since this data does not adequately
predict performance/failure, and instrumentation and
measurement methods have improved over the years,
the gathering of new data is warranted.
*This work was supported by the United Slates Department of
Energy under Contract DE-ACO4-94AL85000.
- 149 -
2.0 SYSTEM DESCRIPTION The voltage probe is a 1000 F2 resistor placed in
parallel with the bridge and a Tektronix CT-I
The cable discharge system (CDS) resides at Sandia current viewing transformer which measures through
National Laboratories New Mexico in Technical it. This allows for decoupling the measurements
Area II and consists of the following hardware: from ground and minimizes the possibility of ground
• Four 1000 foot long rolls of RG218 coaxial cable loop problems.
• A high-voltage power supply (100 kV, 5 mA)
• A gas pressurized, serf-breaking switch The VISAR is used to measure the free-surface
• A gas system for pressurizing and venting the velocity of the flyers of an EBW or EFI. It also can
switch be used to measure particle velocity at a window
• Custom output couplings with integral current interface which in turn, through the use of Hugoniot
viewing resistor (CVR) curves, can determine the explosive output pressure
• Flat cable coupling for testing of exploding of an EBW. Two separate and independent VISAR
foil initiators (EFI) modules can make these measurements
• Coaxial coupling for testing of exploding simultaneously. They have different sensitivities
bridgewires (EBW) therefore giving a high degree of confidence in these
• Instrumentation for measuring: measurements.
• System current - current viewing resistor
All three of these measurements (current, voltage,
(CVR)
• Voltage across the EBW/EFI bridge elements and velocity) are recorded on Tektronix DSA602A
- voltage probes digitizing signal analyzers. These instruments have
• Free-surface velocity of flying plate and high bandwidth (up to 1 gHz) and high sampling
particle velocities at interfaces for rates (1 gHz for 2 channels of data). They also can
determining device output pressure - velocity produce calculated waveforms from basic current
interferometer system for any reflector and voltage measurements representing:
(VISAR)1 • Resistivity
• Tektronix DSA602A digitizers • Specific action
• 486DX33 PC • Energy
The CDS is operated by pressurizing the output These calculated waveforms are produced from the
switch with nitrogen, charging the cables up to a measured data automatically as soon as they are
pre-determined voltage which will deliver the recorded on the digitizer, see Fig. 5.
required current to the device being tested when the
switch is operated. The switch is operated by The 486DX33 PC can acquire up to 16 waveforms
venting the gas with a fast-acting solenoid valve. on any shot and store it on a 90 megabyte Bernoulli
Current from the CVR is used as a trigger source for disk. Other custom software does VISAR data
the data recording system. A photograph of the CDS reduction/analysis to give profiles of:
is given in Fig. 1 and a schematic of the CDS is • Flyer velocity vs. time
given in Fig. 2. • Flyer displacement vs. time
• Flyer velocity vs. flyer displacement
3.0 CAPABILITIES Other commercial or custom software packages can
then be used to create tables and/or graphs for
The four 1000 foot long RG218 coaxial cables can be presentation and report format.
configured to provide a current pulse ranging in
amplitude from 100 to 8000 A with a width of 3 p.s 4.0 FUNDAMENTAL DETONATOR STUDIES
and a risetime of 25 - 35 ns, Fig. 3 and 4. This wide
range of current is made possible by the parallel This section briefly states the basic electrical/
connection of one to four cables. mechanical theory of EBW and EFI detonators. For
a more detailed explanation see the referenced
The system current is measured with a series 0.005 reports 2 through 6. The CDS can be used to
observe both electrical and mechanical behavior of
f_ CVR that is integral to the output of the CDS. A
detonators. From these observations, models with
voltage probe is used to measure the voltage drop
across the exploding element, either a bridgewire in their parameters can be generated. Tucker and
the case of the EBW or the foil of an EFI (slapper). Toth2 demonstrated that exploding wire (and foil)
- 150 -
resistivity, p, at fixed current density, j, may be EFI detonator. This couples input electrical
uniquely specified as a function of either of two parameters with EFI detonator mechanical output
parameters: energy, e, or specific action, g. These parameters; namely flyer velocity. The Gurney
relationships and equations are summarized below. analysis of an explosive system is based on
conservation of momentum and the assumption that
p = f(e) or /(g) (1) the kinetic energy of the system is proportional to the
total energy released by the exploding foil. The
The resistivity of the bridge is the voltage gradient following is an approximate or simplified analysis
across the bridge divided by the current density (known as a modified Gurney analysis). The ratio of
through the bridge. The resistivity is characteristic the system kinetic energy to the energy released is
of the bridge metallic material. Resistance of the the Gurney efficiency, T1, and the Gurney energy, Eg
metallic bridge can be determined by accounting for is given by
the bridge volume; cross sectional area, A, and
length, £ Eg = vl e (5)
- 151 -
distance to detonation, x, plots or "Pop plots". 6 measured. The "old" resistivity versus specific
These plots can be expressed empirically by the action look-up table data for a gold EBW and a
relationship copper EFI are compared to recently, "new",
generated data in Fig. 14 and 15. Since the peak
log P = A - B log X or (9) resistivity is much lower, predicted voltages now
P = C +D x "1 (10) closely match actual values.
where A, B, C, and D are constants for least squares The mechanical output of both the EBW and EFI
data fit. detonators was also observed over the range of
operating current density by using the VISAR. The
4.1 SAMPLE DATA flyer velocity of the EBW closure disk was measured
at a PMMA window interface. Flyer velocity did not
A typical EBW and EFI detonator were selected and change over the current range. This was expected,
tested in order to present typical data output. The Fig. 16. EFI flyer velocity increased with increasing
EBW is a 1.2 x 20 rail Au bridgewire in contact with current density as expected, Fig. 17. The EFI
a PETN explosive DDT column (18.5 mg 0.88 Gurney energy was calculated from the flyer velocity
g/cm 3 initial pressing, 9.3 mg 1.62 g/cm 3 output and current density, Fig. 18. A least squares data fit
pellet). The EFI is a 15 x 15 x 0.165 rail square Cu yielded a Gurney coefficient of 0.00125 and a
bridge with a 1 mil thick Kapton flyer. An Gurney exponent of 1.28.
investigation was conducted to observe the behavior
of the detonators over a range of operating current 5.0 INTEGRATION OF DETONATOR
density. The response of the EBW and EFI STUDIES DATA INTO PREDICTIVE
detonators to a similar CDU burst current level pulse COMPUTER CODES
was also investigated to verify that CDU and CDS
generated data are comparable. The data is Detonator studies data are used in computer codes to
presented in a summary format at bridge burst predict the electrical and mechanical behavior of
condition. Bridge burst resistivity, specific action, bridges as they burst. An electrical circuit solver
and energy are plotted versus current density, Fig. 8 computes current as a function of time and then
through 13. "looks up" resistivity in a look-up table or calculates
the resistivity with an empirical relationship as a
Based upon these results, several observations could function of computed energy or specific action to get
be made. the instantaneous bridge resistance. Once a burst
• Resistivity at bridge burst decreases with current is known, for an EFI, a flyer velocity can be
increasing current density for the EBW, Fig. 8. calculated. A list of some of the electrical circuit
• Specific action to bridge burst remains fairly solvers available along with a brief description
constant over current density range for both the follows.
EBW and EFI, Fig. 9 and 12. • AITRAC - complex circuit solver with bursting
• Energy to bridge burst increases with increasing wire & foil look-up table 7
current density for both the EBW and EFI, Fig. • CAPRES - simple circuit solver with bursting
10 and 13. foil look-up table and electrical Gurney routine
• Resistivity at bridge burst remains fairly • PSpice© - complex circuit solver with bursting
constant over current density range for the EFI, elements added by Furnberg (empirical
Fig. 11. function) and Peevy (look-up table) with
• CDU and CDS generated data are comparable, electrical Gurney and Pnx initiation criterion 8,9
Fig. 11 through 13. • Fireset - code by Lee with empirical resistivity
From these observations, in order to adequately function 10
model an EBW or EFI detonator, resistivity versus • Slapper - code by R. J. Yactor, Los Alamos
specific action or energy data needs to be taken at National Laboratories, with empirical resistivity
three current levels; slightly above threshold (50% function, electrical Gurney, and Pop plot
fire/no-fire), 1.5 times threshold, and 2 times explosive initiation criteria.
threshold (normal minimum operation). Electrical Gurney and Pnx initiation criterion are
implemented into the PSpice electrical circuit
Previous computer simulations always predicted a
much higher voltage across the bridge than was
- 152 -
simulator as custom circuit elements using the 6. B. M. Dobratz, P. C. Crawford, LLNL
Analog Behavioral Modeling capability. Explosives Handbook Properties of Chemical
Explosives and Explosive Simulants, Lawrence
5.1 COMPUTER PREDICTION VERSUS DATA Livermore National Laboratory, Report No.
UCRL-52997, 1985.
A computer simulation of a typical capacitor 7. Berne Electronics Inc., Sandia National
discharge unit (CDL0 firing system with a single EFI Laboratories, Albuquerque, AITRAC
detonator was performed using the latest CDS Augmented Interactive Transient Radiation
generated resistivity versus specific action data look- Analysis by Computer User's Information
up table. The firing system lumped parameters are: Manual, Sandia National Laboratories, Report
C=0.2 gF No. SAND77-0939.
R = 100 m.Q 8. PSpice (a registered trademark of) Microsim
L= 17 nil. Corporation, 20 Fairbanks, Irvine, California.
Simulation output versus test data is shown 9. G. R. Peevy, S. G. Barnhart, C. M. Furnberg,
graphically in Fig. 19 and 20. As can be seen in Slapper Detonator Modeling Using the PSpice©
Table 1, simulations compare well to experiment. Electrical Circuit Simulator, Sandia National
Laboratories, Report No. SAND92-1944.
6.0 CONCLUSION 10. R. S. Lee, FIRESET, Lawrence Livermore
National Laboratory, Report No. UCID-21322,
The CDS has been fully documented. Newly 1988.
obtained data are more accurate and improves
computer simulation, electrical/mechanical
performance predictions and failure analysis of EBW
and EFI detonators. Future plans are to model other
EBW and EFI detonators of interest.
7.0 REFERENCES
- 153 -
Fig. 1 Photograph of Cable Discharge System
L
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- 154 -
DSA 602A DIGITIZING SIGNAL ANALYZER
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- 155 -
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- 156 -
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- 157-
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Fig. 9 EBW Burst Data Summary of Specific Action vs. Current Density
100
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CURRENT DENSITY (amps/cm" 2)
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- 158 -
2.60E-04
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- 159 -
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- 160 -
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- 161 -
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- 162 -
4.0K T ................................................................................................
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- 163 -
Table 1
EFI Simulation Output vs. Test Data
- 164 -
J /_
INITIATION CURRENT MEASUREMENTS FOR HOT BRIDGEWIRE DEVICES
- 165 -
current to set it off, then it explosive cartridges.
would be unacceptable. Often,
a one-ampere current is 2.0 DIFFICULTIES IN MEASURING
specified as being the minimum THE INITIATION CURRENT
acceptable no-fire current. The phrase "firing current"
If the bridgewire resistance has many different meanings.
could be less than one ohm, a This results in certain
power minimum of one watt is difficulties that we will take
also sometimes specified. care of now. The firing
current is often used to mean
The answer to B provides the the current being applied to
"all-fire" current. This the bridge-wire. It is also
value must obviously be more used for the minimum current
than A, and hopefully low required to ignite a
enough that the power supply cartridge. It is this minimum
being used to set it off can current, along with its
provide the current that is distribution, that allows us
required. Values of 3.5 to 5 to determine the all-fire and
amperes are often specified. the no-fire. Therefore, when
In statistical terminology, we mean this minimum current,
the all-fire and no-fire we shall use the words,
current requirements are often "initiation current."
stated as follows:
To measure the initiation
Ao The cartridges shall have current, it would seem easy to
a 1 ampere/l watt or connect a cartridge up to a
greater no-fire current variable power source and
with a reliability of manually turn up the current
99.9%, at a confidence until it ignites. Another
level of 95%. method would be to use a
series of ever increasing
B.
The cartridges shall have steps or pulses of current.
a 3.5 ampere or less all- The current at which it
fire current with a ignites could then be the
reliability of 99.9%, at desired data.
a confidence level of
95%. When cartridges were
originally made (over 30 years
These statistical ago), such efforts often
requirements can be determined proved to be impossible. The
if the firing currents are "sensitive" ignition mix, when
normally distributed and the exposed to heat, could
mean and the standard degrade. If one raised the
deviation of the lot's firing current too slowly, or exposed
current can be determined. a cartridge to several firing
Basically, this report will currents below that required
discuss a new test method for for ignition, the cartridge
measuring the mean and the could actually become
standard deviation of the impossible to ignite. When
firing current for a lot of the chemicals making up the
- 166 -
ignition mix become that it is the no-fire point.
sufficiently degraded, the The actual no-fire point might
cartridge becomes a dud. be much greater. It could
Thus, the initiation current even be a dud, with an
was often dependent on the infinite firing current value.
rate at which the current was Neither the Bruceton nor the
applied, and could become Probit methods will be
infinite. The industry sensitive to these situations.
- 167 -
device. It can be done at a The firing point of the
rate where no significant cartridges being tested
degrading will occur. appeared to be a clean break
in the circuit, with the
Thus, today, in any modern voltage returning to zero when
laboratory, there is no need the bridgewire initiated the
to work with the out-of-date, cartridge. If the
and very poor data generating programmable power supply has
methods such as the Bruceton too high of a voltage
or Probit one-shot methods. A capability, current can
"dynamic ramp" test method can continue to flow even when the
- 168 -
TABLE 1. DYNAMIC RAMP TEST
CARTRIDGE PEAK
NO. CURRENT (Xi) (Xi-X)^2
1 86845 2.50 0.0045
2 86811 2.14 0.0858
3 86881 2.39 0.0018
4 86850 2.32 0.0128
5 86854 2.71 0.0767
6 86864 1.97 0.2144
7 86991 2.66 0.0515
8 86883 2.55 0.0137
9 86866 2.60 0.0279
10 86816 2.49 0.0032
N = 10
t (for90%,n= 9) = 1.83
STANDARD ERROR
OF THE MEAN (S.D.)/(N^.5) 0.074
STANDARD ERROR
OF THE S.D. = (S.D.)/(2N^.5) 0.052
ALL FIRE =
X + t (S.D./N^.5) + 3.09 ( S.D. + t S.D./(2N)^.5) 3.587
NO FIRE =
X- t (S.D./N^.5) - 3.09 ( S.D. + t S.D./(2N)^.5) = 1.279
- 169 -
TABLE 2. DYNAMIC RAMP TEST
CARTRIDGE PEAK
NO. CURRENT(Xi) (Xi-X)^2
1 86845 2.50 0.0057
2 86811 2.14 0.0809
3 86881 2.39 0.0012
4 86850 2.32 0.0109
5 86854 2.71 0.0815
6 86864 1.97 0.2066
7 86991 2.66 0.0555
8 86883 2.55 0.0158
9 86866 2.60 0.0308
10 86816 2.49 0.0043
11 86826 2.50 0.0057
12 86907 2.50 0.0057
13 86815 2.35 0.0056
14 86863 2.54 0.0133
15 86888 2.02 0.1636
16 86885 2.58 0.0242
17 86814 2.05 0.1403
18 86829 2.47 0.0021
19 86956 2.65 0.0509
2O 86926 2.50 0.0057
N = 20
t (for g0%,n=19) = 1.725
STANDARD ERROR
OF THE MEAN (S.D.)/(N^.5) 0.049
STANDARD ERROR
OF THE S.D. = (S.D.)/(2N^.5) 0.035
ALL FIRE =
X + t (S.D./N'.5) + 3.09 ( S.D. + t S.D./(2N)^.5) 3.370
NO FIRE =
X - t (S.D./N^.5) - 3.09 ( S.D. + t S.D./(2N)^.5) 1.479
- 170 -
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- 171 -
these firings. A deviation occur due to these diffusivity
from a normal distribution effects.
does exist, but a larger set
of data would be desirable The other limit is being too
before too much should be made slow. The slower the ramp
of these details. The rate, the greater could be the
important point is made, the degradation of the ignition
distribution function is mix. With a ramp rate of 3.5
obtainable by this test amperes per second, and all
method. firings being at a value of
less than 3.5 amperes, this
6.0 LIMITATIONS OF THE NEW means that all the units fired
within one second of time.
METHOD There are only two
limitations in using the Very little degradation could
dynamic ramp test method. The be expected in conditioning
times as short as one second.
current ramp can be too slow
or too fast.
7.0 ADVANTAGES OF THE NEW
If one were to use a very fast METHOD Explosive cartridges
current ramp (possibly over 30 are usually very expensive.
amperes per second), a thermal In order to obtain reliability
diffusivity effect might be they must be made in large
observed. This effect is due lots under controlled
to the amount of time it takes conditions, and a large
the heat energy generated in a percentage of the lot tested.
bridgewire to distribute The dynamic ramp test will
itself out to the ignition mix directly reduce the number of
to ignite it. If during this cartridges required for
time, the current in the testing. Even better than
bridgewire changes, the this, however, is a great
initiation current will appear increase in reliability. The
to be slightly greater than dynamic ramp test will catch
that actually required. all cartridges that might be
Because bridgewires are so outside of the normal
small, and are made of metals distribution. Bruceton and
- i72 -
the true current distribution or has some other observed
of a lot. anomaly, the dynamic ramp
test, with very few test
8.0 CONCLUSION units, can quickly tell if
If one has modern test those anomalies are causing
equipment, there are no known any effect in their firing
reasons why one would not want characteristics. For Bruceton
to use the dynamic ramp test or Probit testing, you might
method. It brings the testing need 30 or 40 units before you
of explosive cartridges back could feel good as to whether
to standard statistics. a difference exists between
two different groups.
Books have been written on the
questionable assumptions and Research into thermal
misuse of data from the diffusivity effects and into
Bruceton and Probit methods. degradation effects could also
All those questions disappear be easily accomplished. These
with the use of the dynamic reasons make the dynamic ramp
ramp test. The applications test an exciting approach to a
of the Bruceton and Probit problem that has existed for
methods require special charts over thirty years. It will be
and calculations. The dynamic a powerful and necessary
ramp test uses the same approach if we are to remain
statistics that would be used competitive.
in any other normal approach.
9.0 RECOMMENDATIONS
It is true that the dynamic Government regulations
ramp test is still a requiring Bruceton or Probit
statistical test. The testing of bridgewire type
meaningfulness of the results explosive cartridges should be
will, as always, depend upon modified to include, as a
how well the test units preference, the dynamic ramp
reflect the distribution of testing approach. The dynamic
the lot. If non-random or ramp testing is a major
incomplete selections are made improvement. It provides
from a lot, the dynamic ramp stronger, more direct
test data will be faulty to statistical data for
the extent that this occurs. determining the mean and the
But, this is true for all deviation of the initiation
statistics, and can be guarded current for bridgewire type
against in the same way that explosive cartridges. In
all other statistical tests addition, the true
are handled. distribution of the data is
observable. For all previous
This new method actually testing methods, assumptions
allows additional research. of the distributions were
If at any time a set of required and could never be
cartridges are identified as actually confirmed.
being "out-of-family," having Therefore, all previous
seen some unexpected exposure testing was always with some
- 173 -
uncertainty, especially where
projections of several
standard deviations were
required.
- 174 -
APPENDIX A
2.6 3 1 0 0 0
2.5 2 5 1 2 4
2.4 1 3 4 4 4
2.3 0 1 2 0 0
Mean (XR)
XR = Io + AI (A/N + 1/2)
2.3 + 0.1 (6/7 + 1/2)
2.44 amperes
Therefore,
S = 0.70 (from table)
C_R = S (AI)
= (0.7o) (0.i)
= 0.070
- 175-
APPENDIX A - Continued
1.88 _ 1 ampere
- i76 -
I- J,i
DEVELOPMENT AND DEMONSTRATION
OF AN
by
Laurence J. Bement
NASA Langley Research Center
Hampton, Virginia
Morry L. Schimmel
Schimmel Company
St. Louis, Missouri
Harold Karp
Hi-Shear Technology
Torrance, California
Michael C. Magenot
Universal Propulsion Co.
Phoenix, Arizona
- 177 -
DEVELOPMENT AND DEMONSTRATION OF AN NSI-DERIVED
GAS GENERATING CARTRIDGE (NGGC)
Abstract
- 178 -
WELD IREF)
EPOXh
PROPELLANI_
,.EF,
C CHARGE
SLURRY
GAP REGION
3/8-24 THREAD
_EPOXY
INSULATING
WELD
ELECTRICAL PIN"
CUP, CLOSURE
INSULATING
DISK, INSULATING
DISK, SEAL
BODY ASS_
Zr/KCIO 4
PROPI
114 i 4 MG
(2 INCREMENTS)
_.586 - .596 REF
cient input energy, but also to a lack of under- versus time) are recorded. As described in ref-
standing of pyrotechnic mechanisms and test- erence 5, the closed bomb provides no quanti-
ing methods (ref. 3). The energy output of tative information that can be related to work
pyrotechnic gas generating cartridges is influ- performed in an actual device.
enced by the conditions into which they are fired.
For typical piston/cylinder configurations, these The use of the NSI as a gas generating car-
conditions are volume (shape and size), mass tridge has both advantages and limitations. The
moved, resistance to motion (friction), and ther- advantages are: (1) it is accepted in the com-
mal absorptivity#effectivity of the structure. munity with no additional environmental qualifi-
cation required, (2) it has excellent safety fea-
The only existing standard for measuring car- tures, 1-amp/l-watt no-fire, and electrostatic
tridge output performance in the field of protection, (3) it has a demonstrated structural
pyrotechnics is the closed bomb, reference 4, integrity and (4) it has a demonstrated reliabil-
which is inadequate for measuring energy deliv- ity of electrical initiation and output as an ig-
ered by cartridges. The closed bomb is a fixed niter. The limitations are: (1) it was not de-
volume into which the cartridge is fired. The signed for use as a gas generator, (2) the gas
pressure produced in the volume is monitored output produced is inconsistent in diffcrent man-
with pressure transducers and the data (pressure ufacturing groups (ref. 2), and (3) it does not
- 179 -
provide sufficient work output for many small 4. Maintaining the same environmental surviv-
mechanisms. To overcome these problems, the ability as the NSI.
NSI has been used with booster modules. These
modules are sealed assemblies that contain ad- Approach Used for Development and
Demonstration of the NGGC
ditional pyrotechnic gas generating material and
are installed into the structure of the mechanical The approach for this effort was divided
device. This requires additional volume, mass into designing/developing, demonstrating/
and seals, as well as additional costs for develop- characterizing and environmental survivability.
ment, demonstration, and qualification. Figure 2 shows the design for the NGGC, which
utilizes the NSI body and electrical interface.
Survey of Gas Generating Cartridges The electrical interface is defined as the electri-
A survey of literature and personnel within cal pins, bridgewire, bridgewire slurry mix and
NASA and Air Force space centers was con- the initial load of 40 milligrams of NSI mix. The
ducted, using the following criteria: remaining volume within the NSI was filled with
a thermal/vacuum-stable gas-generating mix, in-
1. Provide the following important features that
cluding the additional second load above the
are the same as those in the NSI:
ceramic cup. A joint development was con-
* safety ducted with the two certified NSI manufactur-
ers, Hi-Shear Technology and Universal Propul-
* reliability of electrical initiation
sion Company (UPCO).
* high-strength construction
The performance of the NGGC was established
* small size by measuring and recording input and output
characteristics for comparison to the same mea-
2. Output performance greater than that of the
surements in other cartridges. That is, for in-
NSI
put electrical ignition performance tests, a direct-
3. Long-term thermal/vacuum stability for current electrical circuit was used to apply input
space applications. electrical currents in discrete steps, measuring
the times from current application to bridgewire
The survey revealed the following information.
break and to first indication of pressure. The
Some cartridges do not have the NSI safety fea-
tures. None have the NSI demonstrated reliabil- output performance of the NGGC was character-
ized with four test methods, the industry stan-
ity. Several use the same pyrotechnic materials
dard and three work-measuring devices: (1) The
as the NSI. Several use gas generating materials
Closed Bomb is the industry standard, which in-
that are not stable under thermal/vacuum condi-
volves firing the cartridge into a closed, fixed vol-
tions. None offer sufficient advantages for further
evaluation. ume, measuring the pressure versus time in the
volume, (2) The Energy Sensor, which involves
Based on this information, a decision was made firing the cartridge against a constant force, mea-
to develop a new, NSI-derived, Gas Generating suring energy as the distance stroked times the
Cartridge (NGGC). resistive force, (3) The Dynamic Test Device,
which involves firing the cartridge to jettison a
Objectives for Development and mass, determining energy by measuring veloc-
Demonstration of the NGGC
ity of the mass to calculate 1/2mv 2 and (4) The
The objectives of this effort were to demonstrate Pin Puller, which involves firing the cartridge to
the feasibility of designing/developing an NSI- withdraw a pin for release of an interface, deter-
derived Gas Generating Cartridge (NGGC) by: mining energy by measuring velocity of the pin
to calculate 1/2mv 2.
1. Maintaining the important electrical initia-
tion and structural reliability of the NSI To demonstrate the environmental survivability
of the NGGC, the input and output performances
2. Providing significantly more energy than is
of as-received (untested) units were used as per-
provided by the NSI formance baselines for comparison to the perfor-
3. Characterizing the work performance of the mances achieved by units that were environmen-
NSI and NGGC to assist in the design of tally tested. Changes in functional performance
pyrotechnically actuated devices, and would indicate a sensitivity to environments.
- 180 -
DISK, INSULATING
GAS-GENERATING LOAD
85-90 MG
Zr/KClO 4
PROPELLANT
40 MG
Figure 2. Cross sectional view of NASA Standard Gas Generator (NSGG), showing changes to NSI configuration.
and two NGGC models, which were produced by Technology and UPCO, are the same as the NSI,
different manufacturers. except for the major changes shown in figure 2.
The electrical interface from the bridgewire re-
mained the same with the slurry mix, but the
NASA Standard Initiator (NSI)
first press was 40 mg of Zr/KC104 at 10,000 psi,
The NSI units evaluated in this program were instead of the 57 mg for the NSI. The gas gen-
manufactured by Hi-Shear Technology. Hi-Shear erating materials were selected by each manufac-
Technology utilized the same Zr/KC104 in both turer, based on a demonstrated stability against
the NSI and their NGGC. elevated temperature and long-term vacuum en-
vironments. This material was pressed into
and completely filled the charge cavity of the
Viking Standard Initiator (VSI)
ceramic cup. An isomica insulating disc was
The VSI is functionally identical to the NSI bonded across the face of the cup to prevent
and was manufactured by Hi-Shear Technology an electrical path from the bridgewirc through
in 1972 for the Viking Program's lander on the the pyrotechnic material to the cartridge case.
surface of Mars', Since very few NSI units were A second increment of gas-generating material
available, the VSI functional performances were was pressed on top of the insulating disc to fill
used to represent that produced by the NSI. as much of the free volume as possible. The
- 181 -
CONSTANT CURRENT I
CURRENT : VOLTAGE I"---I m
SOURCE MAGNETI C
TAPE OSCILLO-
RECORDER GRAPH
I_____!__TO_R
MoN I
PERMA-
I
NENT I
>_<J COR_
10 cc-__
CLOSED PRES.
BOMB
{2)
XDUCER
Figure 3. Cross sectional view of closed bomb and schemtic of firing and monitoring system.
materials selected and the loading procedures was employed to measure the electrical igni-
used were the suppliers' choice and are consid- tion characteristics (function times) of cartridges
ered proprietary. Hi-Shear Technology loaded tested. Long-duration, square-wave electrical
90 mg of gas generating material, while UPCO pulses were applied at levels of 20, 15, 10, 5 and
loaded 85, yielding a total pyrotechnic load of 3 amperes. The input current and the pressure
130 and 125 mg respectively, as compared to the produced by the cartridges in the various out-
ll4-mg load for the NSI. The same electrical mud put test methods were recorded on an FM mag-
thermal insulation discs used at the output end netic tape recorder with a frequency response
of the NSI load were also installed on the NGGC. that was flat to 80 Khz. Electrical initiation
function times were measured from application
of current to bridgewire break and from applica-
Test Apparatus and Methods
tion of current to first indication of pressure from
To characterize the input/output performance of the cartridge.
the test cartridges, an Electrical Firing Circuit
was used for input measurements, and four dif- Closed Bomb
ferent test methods were used for output mea-
surements. These output test methods were: the The closed bomb, shown in figure 3 and de-
Closed Bomb, the Energy Sensor, the Dynamic scribed in references 3 and 4, is the industry
Test Device, and the Pin Puller. All output test standard for measuring the output of cartridges.
hardware was made of steel and was reusable. The cartridge is fired into a fixed, 10-cc cylindri-
cal volume, and the pressure produced is mea-
sured with the pressure transducers, recorded on
Electrical Firing Circuit
the FM tape recorder. The data collected are
A direct current firing circuit, shown schemat- the peak pressure and the time to peak pres-
ically in figure 3 and described in reference 4, sure. This approach has limitations, as described
- 182 -
in reference 5, in trying to relate the pressure the working piston. The cartridge's output gas,
produced to a mechanical or ignition function. generated 90 ° from the working axis of the pis-
For example, the NSI performance requirement ton/pin, must vent through a 0.1-inch diameter
in reference 1 is 650 +/- 125 psi peak pressure, orifice into the working volume. Energy was ob-
achieved within 5 milliseconds at direct-current tained and calculated by measuring the velocity
inputs of five amperes or greater. These data of the piston/pin, as described for the Dynamic
provide no quantitative information that can be Test Device. Pressure in the working volume was
related to work performed in an actual device. measured by a transducer installed in the sec-
ond port, as shown. The data collected were the
Energy Sensor energies delivered in inch-pounds and the peak
pressures achieved.
The Energy Sensor, shown in figure 4 and de-
scribed in references 4 and 5, represents an appli- Test Procedure
cation where the cartridge output works against
a constant resistive force. This resistive force is The testing effort was divided into three major
provided by precalibrated, crushable aluminum areas, as summarized in table I. This table shows
honeycomb. The strength of the honeycomb se- the number of units fired in each test, as well as
lected for this study was 500 pounds force. The
cartridge is fired on the axis of a piston/cylinder
as shown. The amount of work accomplished is Table I. Allocation of Cartridge Test Units
obtained by multiplying the length of honeycomb Performance Baseline Firings
crushed during the firing by the honeycomb's
NGGC
crush strength to yield an energy value in inch-
Test condition VSI NSI Hi-Shear UPCO
pounds.
Closed bomb 13 3 6 5
Energy sensor 5 5 5
Dynamic Test Device
Dynamic test device 8 3 7 5
The Dynamic Test Device, shown in figure 5 Pin puller 5 7 5
and described in references 4 and 5, represents Total 31 6 25 20
the jettisoning of a mass. A one-inch diam-
eter, one-pound, cylindrical mass is jettisoned
Environmental Testing
through a one-inch stroke, when the o-ring clears
the cylinder. The velocity of the mass is mea- NGGC
sured electronically by a grounded needle on Temp. IMech. Mech. rhermal
cycling vibr. shock shock Hi-Shear UPCO
the mass successively contacting spaced, charged
foils to trigger electronic pulses. These pulses Group 1 16 12
were recorded on a magnetic tape recorder to Group 2 2 16 12
measure the time interval between contact of the Group 3 3 3 16 12
needle with the foils. Velocity was calculated by Group 4 4 4 4 16 13
Total 64 49
dividing the spacing distance (0.250 inch) by the
time interval. The energy of the mass was calcu- The units were visually, electrically and x-ray inspected
lated as 1/2 mv 2, where m is the total mass of before and after exposure to each environment.
the 1-pound mass and the needle. The pressure
in the working volume was measured by a pres- Post-Environment Firings
sure transducer installed in the port as shown,
NGGC
and was recorded on the same magnetic tape
Test condition Hi-Shear UPCO
recorder. The data collected were the energies
Closed bomb 16 12
delivered in inch-pounds and the peak pressures
achieved. Energy sensor 16 12
Dynamic test device 16 12
Pin Puller Pin puller 16 13
Total 64 49
The Pin Puller, shown in figure 6 and described Units from the environmentally exposed groups were
in reference 3, represents a pyrotechnic function equally subdivided into each functional test group.
with a low-mass retractor. It also presents a tor-
tuous flow path of gases from the cartridge to I Wotal NGGC test units: I 89 I 69 I
- 183 -
Energy sensor Initiator firing block
1 -_ 1 IIIIIIIIIL
'
_,
_ _," ..... .am
,,
_'-_.,
,,,,_\\\\\\\\\\\
\ ___ IIIIII[IIF 11 I \
_[
I1 t V
_111111
(IH --
L_ Piston seal
Cylinder
O. 250"
Piston
Cartridge port
J Sealing ring
- 184 -
Cartridge Port_ Orifice (2)
O-Rings (5) _ \ ,_ /
"i."ll "lll//llll//lllll ,
the number of units subjected to the various en- their design and performance were essentially the
vironments. The Electrical Firing Circuit was same.
used to collect input electrical ignition charac-
teristics (function time) data for all units (except Environmental Testing
the NSI) that were fired in the Performance Base- Environmental tests, duplicating the qualifica-
line and in the Post-Environment tests. Elec-
tion levels and test order required for the NSI,
trical inspections were accomplished on all units were conducted on the NGGC. The NGGC units
at the start of the program with 50-volt bridge- from each source were divided into four groups
to-case and 10 milliampere bridgewire resistance for testing as shown in table I. Thermal stabi-
measurements.
lization in these tests was established by thermo-
couples attached to several cartridges; once the
Performance Baseline Firings
desired temperature level was indicated by the
The performance baseline firings were conducted thermocouples, the units were soaked for at least
with as-received cartridges to provide a func- 15 minutes before the environmental tests began.
tional reference for comparisons among all The units were visually, electrically and x-ray in-
cartridge types and to compare with post- spected before and after each environment. Elec-
environmental performance of the NGGC. Per- trical inspection was accomplished with 50-volt
formance data included input electrical ignition bridge-to-case and 10 milliampere bridgewire re-
and the four output measurements. The Elec- sistance measm, ements.
trical Firing System was used as the input fir-
The definition of each environmental test follows:
ing source for all cartridges, except the NSI.
(NSI firings were conducted prior to the use of
the Electrical Firing System). The cartridges Temperature cycling. The units were placed in
were subdivided as equally as possible for fir- a wire basket for transfer between chambers that
ings at current levels of 20, 15, 10, 5 and were stabilized at -260 and +300°F. The follow-
3 amperes. As an example of output test fir- ing describes one of twenty cycles conducted:
ings described in table I, the Closed Bomb was
1. Insert units into -260°F chamber, and once
used for 13 VSI, 3 NSI, 6 Hi-Shear Technology
stabilized, maintain that temperature for one
NGGC, and 5 UPCO NGGC units. Due to their
hour
scarcity, no NSI units were functioned in the En-
ergy Sensor or Pin Puller. VSI units were used to 2. Transfer units to +300°F, and once stabilized,
supplement the data collected on the NSI, since maintain that temperature for one-half hour
- 185 -
2. Transfer units to +300°F, and once stabilized, the top portions of tables II through VI and fig-
maintain that temperature for one-half hour ures 7 through 10.
Table II. Electrical Ignition Performance Data
on Cartridges
Mechanical vibration. The units were
mounted into test blocks in a thermal chamber (Average/Standard Deviation)
for vibration tests on all three axes. Two series of Current Time to Time to
tests were conducted at +300 and -260°F. The
applied No. BW break, first press,
units were conditioned at each temperature and Cartridge amperes fired ms ins
the following spectrum, which produced an over- Performance baseline (no environments)
all G rms value of 27.5, was applied for 7.5 min- VSI 20 6 .124/.005 .158/.014
utes in each axis:
15 3 .182/.007 .215/.013
10 2 .354 .389
5 1 1.431 1.480
Frequency (Hz) Level (G/Hz)
3 1 121.020 121.060
10 - 100 0.01 to 0.8 (6 db/oct increase)
Hi-Shear 20 1 .120 .175
100 - 400 0.8 constant
400 - 2000 0.8 to 0.16 (3 db/oct decrease) NGGC 15 1 .190
10 1 .335 .362
5 1 1.350 1.370
Mechanical shock. The units were mounted 3 1 12.400 12.425
in the same test blocks used for the vibration UPCO 20 3 .130/.030
tests. The units were subjected to +/- pulses on NGGC 15 1 .160 .225
each axis to the following trailing edge sawtooth 10 2 .324 .373
pulse: 100 G peak with an 11 ms rise and a 1.298/.020
5 3 1.295/.018
1 ms decay. Tests were conducted at laboratory 3 2 8.355 8.373
ambient conditions. Post environments
Thermal shock. The units were placed in a Hi-Shear 20 16 .135/.012 .187/.025
wire basket and immersed in a container of liq- NGGC 15 12 .184/.020 .224/.029
nid nitrogen and allowed to stabilize (no bub- 10 12 .329/.044 .443/.199
bles). The units were then removed from the 5 12 1.245/.050 1.274/.063
nitrogen and allowed to stabilize at room tem- 3 12 10.653/5.452 11.315/5.78_
perature with no protection from water conden- UPCO 20 12 .121/.013 .792/.663
sate. The units were subjected to this process for NGGC 15 12 .176/.012 .639/.481
five cycles, except during the fifth cycle, follow- 10 10 .348/.045 .739/.441
ing stabilization, the units were held in the liquid 5 8 1.238/.100 1.327/.145
nitrogen for 11 hours. 3 8 7.641/4.015 7.353/3.74(
Post-Environment Firings
- 186 -
Table IV. Energy Sensor Performance Data on
"-I-- ¥81
Test Cartridges
HI*SHEAR, NO ENV
Cartridge I No.
fired I Energy delivered,
inch-pounds
Performance baseline (no environment)
VSI 5 466/21
Hi-Shear NGGC 5 815/99
UPCO NGGC 5 812/90
Post environments 0.1
5 10 18 2O
"]'- V81
HI-SHEAR, NO ENV
UPCO, NO ENV
10
(Average/Standard Deviation)
Energy Peak
No. delivered, pressure,
0.1
Cartridge fired inch-pounds psi 0 6 10 18 20
Post environments
UPCO NGGC I 16 667/45 6953/1866 trical ignition performance baselines (no envi-
12 777/50 8337/1980
ronments) for the VSI and NGGC are shown in
table II and figure 7. As mentioned earlier, no
NSI data were collected. Each of the data points
on the plots is the averaged value of the func-
tion times for each cartridge type at each current
level. Very little difference in performance could
Table VI. Pin Puller Performance Data on be detected among any of the cartridge groups.
Test Cartridges
- 187 -
1600
1200
Hi-Shear _'GGC
UPCO NGGC
800
vsl
Figure 8. Typical pressure traces produced by the NSI, VSI and UPCO, and Hi-Shear NGGC in the closed bomb.
8o00
uPco
Goc
•_ 6o00
4ooo
2000
0
.2 .4 .6 .8 i .0 1.2 I .4 1.6
Time, milliseconds
Figure 9. Typical pressure traces produced by the VSI and Hi-Shear and UPCO NGGC in the dynamic tcst dcvicc.
- 188 -
16000
NGGC
12000
NGGC
m,
J
8000
{o
=w
4000
Figure 10. Typical pressure traces produced by the VSI and Hi-Shear and UPCO NGGC in the pin puller.
- 189 -
the standard deviations of the pre- and post- of pyrotechnic mechanisms now have a cartridge
environments data. These standard deviations that is defined in terms of work, and they can
total 179 and 148 inch-pounds for the respective relate the test configurations and energy deliv-
NGGC models, which could include this range of eries documented in this report to their design
data. requirements. This cartridge performance can
meet the requirements of a substantial portion
Dynamic test device. The Dynamic Test De- of small aerospace pyrotechnic devices (including
vice data are shown in table V. No significant many applications where the NSI with booster
change in performance was observed following en- modules are now employed), such as pin pullers,
vironments, again considering the standard devi- nuts, valves and cutters.
ations.
A word of caution is warranted. The suc-
Pin puller. The Pin Puller data are shown cessful completion of this developmental effort
in table VI. No change was detected following does not "qualify" the NGGC for any appli-
environments. cation. Users must conduct a developmental
effort, including demonstrating functional mar-
Conclusions gins, environmental qualification, and system in-
tegration/operation demonstrations for devices
All objectives of this effort were met, which in which the NGGC is to be used.
should allow for immediate consideration for the
application of the NGGC. The NGGC was man- The acquisition of the NGGC should be based
ufactured using the same body and electrical on performance, as measured by at least one of
interface as the NSI. The electrical initiation the energy measuring devices described in this
characteristics are the same as the NSI. A slight report, the Energy Sensor, the Dynamic Test
delay was observed in the time to first pressure Device or the Pin Puller.
for the UPCO NGGC following environmental
exposures. This delay, caused by a decrease in References
thermal transfer from the bridgewire, is accept-
1. Design and Performance Specification for
able, since it is well within the NSI performance
NSI-1 (NASA Standard Initiator-I),
specification. The cartridge functional evalua-
SKB26100066, January 3, 1990.
tions used in this effort clearly show that out-
put working energy is affected by the configura- 2. Bement, Laurence J. and Schimmel,
tion in which it is used. The Energy Sensor and Morry L.: "Determination of Pyrotechnic
Dynamic Test Device measured the most energy Functional Margin." Presented at the 1991
delivered by the NGGC, about 800 inch-pounds, SAFE Symposium, November 11-14, 1991,
while the Pin Puller was much less efficient, de- Las Vegas, Nevada. Also presented at the
livering only about 500 inch-pounds. Although First NASA Aerospace Pyrotechnic Systems
the two NGGC manufacturers selected different Workshop, June 9-10, 1992, NASA Lyndon B.
thermal/vacuum-stable gas generating materials, Johnson Space Center, Houston, TX.
as evidenced by the different pressure traces ob-
3. Bement, Laurence J.: "Pyrotechnic System
served, the output performance of the two models Failures: Causes and Prevention." NASA
was essentially the same in each of the four test
TM 100633, June 1988.
methods. Under the assumption that the NSI
produces the same output performance as the 4. Bement, Laurence J.: "Monitoring of Explo-
VSI, the NGGC produces approximately twice sive/Pyrotechnic Performance." Presented
the output of the NSI/VSI in the Energy Sensor at the Seventh Symposium on Explosives
and the Dynamic Test Device, and three times and Pyrotechnics, Philadelphia, Pennsylva-
that of the NSI/VSI in the Pin Puller. No signif- nia, September 8-9, 1971.
icant change in output performance was observed
5. Bement, Laurence J. and Schimmel,
following exposure of the NGGC to the rigorous
Morry L.: "Cartridge Output Testing: Meth-
thermal/mechanical environmental requirements ods to Overcome Closed-Bomb Shortcom-
for the NSI.
ings." Presented at the 1990 SAFE Sympo-
A work-producing cartridge has been developed sium, San Antonio, Texas, December 11-13,
with the key attributes of the NSI. Designers 1990.
- 190 -
DEVELOPMENT OF THE TOGGLE DEPLOYMENT MECHANISM
Christopher W. Brown
NASA Lyndon B. Johnson Space Center, Houston, Tx
Abstract
- 191 -
The original SPDS requirements
were translated into the first pin- Friction coefficients of the TDM
puller configured TDM and resulted parts play an important role in
in the United States Patent releasing energy. Figure 3 also
4,836,081.1 . The original concept, shows a difference between the
shown in figure 1, had a problem original piston finish and a Teflon
with the preload forcing the pins impregnated nickel plate finish
back and causing the shear pins to called NEDOX from General
function as primary structure. The Magniplate Corp.. The NEDOX finish
less the angle "a" from the shows a consistent improvement in
horizontal on the toggle, the less releasing energy.
load there is pushing the pins back.
However, the less angle "a", the The second TDM concept had a
harder it is for the toggle to swing different design to avoid
away from the unretracted pins. If transferring the preload into the
angle "a" was zero, there would be axis of the pins. This resulted in
no moment on the toggle, created development of the double swivel
by the 2 unretracted pins, for the toggle and lead to United Stated
toggle to swing away from. Patent 4,864,910. 2 . As seen in Figure
4, this TDM had the axis of the pins
The first NASA-JSC pin-puller running perpendicular the axis of
configured TDM, seen in figure 2, the toggle. When one pin was
has the axis of the pins parallel to retracted, the bottom of the toggle
the conical surface of the toggle. could swivel down and clear itself
The tension of the toggle pushes the from the 2 unretracted pins. This
conical surface perpendicular to TDM was successfully developed and
the pin's axis and does not act on qualified to meet SPDS
the shear pins. requirements.
- 192 -
horizontal. Both toggle stems had less pressure needed to release the
full strain gauge bridges applied 30 degree TDM due to less force
inside holes going through their between the hooks and pistons.
axes. Each piston port had 2 NSI What was unexpected is the
ports. Most parts of the TDM20KS inconsistency of releasing pressure
were plated or coated with low as a function of preload.
friction surfaces.
NSI firing showed similar
TDM2OKS Development Test pressure/preload results after the
TDM's were exposed to vibration,
Three sets of development tests shock, and thermal environments.
were completed. After initial Ambient firings revealed a design
testing, the next 2 development tests problem in the piston stops. The
were performed with design pistons traveled too far and leaving
changes that were needed during the bottom of the piston voids
the initial testing. The initial pushing the hook back up which
development tests were performed prevented toggle releasing. All
with hydraulics and with NSI's, but toggle releases, with the original
the first goal was applying the piston stops, were performed with
one NSI per piston. The second
preload. 4. With 2 NSI ports per
phase of development testing, with
cylinder, pressure monitoring was
2 NSI's per piston, showed some
easily accomplished.
success in an improved design.
TDM2OKS Initial Development
Figures 10 and 11 show pressure
and preload curves in the 30 and 45
degree TDM chambers during 275
Preloading was similar to the
degree F. firings. The TDM's were
original TDM by way of pulling the
successfully fired in -90 degree F.
socket up when unscrewing the environment. Figure 12 shows the
preload collar (otherwise known as data on the 45 degree TDM cold
a preload bolt). Figure 7 shows the
firing.
setup used to get the maximum
preload. A tension machine would Both hydraulic and NSI tests showed
pull the socket up by stretching the a preload increase when
toggle, and the preload bolt was
separating. This is belived to be
unscrewed until it was snug with
caused by the piston bending in
the socket. The bolts connecting
toward the hook while traveling up.
the tension machine to the socket
had a 17,000 pound maximum limit,
A plastic deformation test was
and the TDM2OKS assembly would
performed with the 45 degree TDM
settle down to about 12,000 pounds
while the 30 degree TDM was saved
preload. A future design was able to for testing improved piston stops
obtain a 20,000 pound preload.
and preloading mechanisms.
- 193 -
was unknown due to strain gauge holding the stops, elongated and
damage in the toggle stem. Figure were bent. Figure 15 shows how the
13 shows the average permanent deformed bolts allowed the piston to
change in the deformed parts. The travel too far, pushing the hook
45 degree TDM was preloaded and back up, and wedging the piston
put back into tension. The toggle between the hook and cylinder.
stem finally broke at 34,000 pounds Testing with bolts made of carbon
tension. Besides the toggle, the steel, instead of 300 series SST, also
internal parts were deformed a resulted in stretched bolts but not as
little more and were still able to deformed as the older ones. The
function in the TDM body. bottom surface of the piston void
was lowered 0.15 inchs to give room
TDM20KS Post Development Tests for successful releasing with 2 NSI's
per piston.
The 2 post development tests
evaluated a redesigned piston stop Top Member Redesign v
- 194-
pattern would separate the 4. NASA JSC Thermochemical Test
tensioner from the base plate and Area No. JSC 26486 "Internal
create tension on the toggle. Note For the Toggle Deployment
Mechanism (TDM)" April 1993.
Testing of the new top member and 5. NASA JSC Thermochemical Test
releasing over 20,000 pound preload Area No. JSC 25964 "Internal
with one NSI was successful. 6. Note For Toggle Deployment
Each bolt was torqued at 20 in. lb. Mechanism Piston Stop Test"
increments, in a star pattern, until July 1992.
the toggle's strain gauge failed at 6. NASA JSC Thermochemical Test
18,000 pounds. Preload, as a Area Task History 2P809 " August
function of torque, was continued 1993.
until 20,000 pounds was estimated.
The maximum torque/preload tested
was 200 in.lb, on each bolt and
24,000 pounds preload. At ambient
conditions, one NSI was still able to
release the 24,000 pound preload.
Conclusions
References
- 195-
Preload
Shear Pin
F =- Preload/Tan a
Figure 1
Original Toggle Deployment Mechanism Concept.
- 196-
Preload Collar/Bolt
Top Plate
Socket 7
/
/
_- Separation Plane
Piston/Pin
Collar
Shear Pin
Fi__ure 2
Toggle Deployment Mechanism, Pin-Puller Configuration.
- 197-
o_
w_
0
o
o
_o
0
o
g
>
_3_:I uo:lsTd _q:_ uo _.mss_._d :_3_U_, :_ou s_ocI
(Tsd) _-,nss_._d _TU_uXcI
- 198 -
Preloading Nut
Socket
Separation Plane
Piston/Pin
Bottom Swivel
Figurg 4
Double Swivel Toggle Release.
- 199-
TOP CAP
SOCKET
STOP(3-TYP)
PRELOAD BOLT
LOCK PIN
HOOK (3-TYP)
TOGGLE
PISTON
@ PISTON (3-TYP)
HOOK (3-TYP)
SECTION A-A
Figure 5
Toggle/Hook Deployment Mechanism TDM20KS before separation.
- 200 -
TOP CAP
SOCKET
STOP(3-TYP)
BOLT
HOOK
LOCK PIN
B
B
TOC_LE
PISTON (3-TYP)
ISTON (3-TYP)
SECTION B-B
- 201 -
T ENS]ON
ACH]NE
PRELOAD
PLATE
SOCKET
ADAPTOR
SOCKET
BOLTS
TENSION
'_"_ TTOOL
E NSION
MACHINE
Figure 7
Preloading the TDM20KS.
- 202 -
i
i
lbf and psig
12,000
TOGGLE PRELOAD,
10,000
i
8,000
6,000
4,000
2,000
FiRure 8
Hydraulic release tests for the 45 degree TDM. Load cell and toggle gauge lines
were staggered due to pen locations on the strip chart recorder.
- 203 -
o...
" 0
il il
0
B. B.
$.
0
0
- 204 -
©
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•
_._ ,_
_j:::
8
0
I I I I i I
C_
0
0 Tm
Tm
IsdISH P_ I:_°IQXi
"_ql
x
C_
qr--
- 2O5 -
b °
m *
< D
© E _
Q >
r : 0
! .
Z rm_ _ o
r ,°
,-'o
• °_ o_I " _
_c 8
_,I t--
ed _
j-
.°'
o
ol
m .
CI.O
t_
o
c
-e,i
I I I I I I
0
isdISN P_ _oI =Id ";ql
x
0
- 206 -
"tzt
O0 o
r_ N
E
.<_ ,-.,_
t:m
..-,..t
t_
.<_.,
• ,B
t4 _
-d _i._
a
"tzt
Q_
,t
[--,_
? "N
o
l i i i I i I I
CM Q
¢q
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X
Isd I_.'<
P_ P_Ol_Id "._ql
- 207 -
.002 SHORTER --.001 WIDER
1 i
I I
i
I
PISTONS PISTONS
.007 TALLER
.003 OUT OF ROUND
,!
t 1
HOOKS
Figure 13
Dimensional analysis of the deformed 45 degre, e TDM parts after a
29,000 lbf structural load test. Dimensions are averages of all parts and in inches.
- 208 -
i ,l_i,
, l
I f i
I I I
l
I
- 209 -
Figure 15
TDM2OKS Piston/Hook interference after excessive piston travel.
- 210 -
Bolts Socket. Tensioner
Plate
Separation Plane
washers
Toggle
Figure 16
TDM20KS Redesigned Top Assembly
- 211 -
THE ORDNANCE TRANSFER INTERRUPTER° A NEW TYPE OF S&A DEVICE
John T. Greenslade, Senior Staff Engineer
Pacific Scientific Company, Energy Dynamics Division
- z13 -
with the "Inertial" type SAD, when it is conventional SADs. As such, it is one of
subjected to a specific level of vehicle the factors which led to the concept of the
acceleration for a specific minimum Interrupter, which contains no pyrotechnic
duration. The arming mechanisms in the or explosive components, as a replacement
Command type SADs have most commonly for conventional Command SADs in systems
been electro-mechanical, although electronic employing linear ordnance transfer lines
devices have become competitive, and laser such as shielded Mild Detonating Cord
based Command type SADs have started to (SMDC), or Confined Detonating Fuze
make an appearance. The Inertial SADs are (CDF).
armed by inertia forces, resulting from the
missile acceleration, acting on a spring- In the Safe mode, conventional Command
loaded "set-back" weight. With these type SADs must either physically hold their
devices, the movement of the set-back internal detonators out of alignment with
weight is controlled by an escapement their output ports, or, interpose a barrier
mechanism, similar in principle to the between the detonators and ports. They
escapements used in clocks. must also disable the tiring circuits to the
electro-explosive detonators, and impose a
Figure 1 tabulates some of the more safety shunt across those circuits.
common types of SAD which have been Conversely, when in the Armed mode, the
used in missile applications. Command SADs must align their detonators
with the output ports (or remove the
Conventional SADs, Command and Inertial, barrier), and they must complete the tiring
are more than just a system sating and circuits to the detonators. In comparison,
arming mechanism; they are also the the Interrupter, having no internal EEDs, is
ordnance system initiator. For that purpose, not involved in disabling or enabling the
they incorporate electro-explosive devices, tiring circuits to the system initiators. This
usually detonators, and very often explosive considerably simplifies its internal circuitry
transfer components such as "leads," or and switching requirements. The Interrupter
confined detonating cords. This, of course, would, as the name implies, have to
increases the hazard potential associated interrupt the system tiring train, in this case
with pre-flight testing and installation of by a removable barrier. The functional
requirements for a typical conventional
COMBINATIONS OF:
i
Command SAD are compared, in Figure 2
TYPE ENABLE ARM INTERRUPT with those for the Interrupter.
- 2i4 -
CONVENTIONAL
- 2i5 -
drive-train (e.g., solenoids, or springs, or INTERRUPTER DESIGN
..), movable EEDs versus a movable
barrier, and the type of electrical switching As shown in Figure 4, the Interrupter
components to be used (e.g., rotary or snap- housing is a complex rectalinear structure
action, or ...). with overall dimensions of 5 1/4 L x 3 5/8
W x 2 7/8 H inches. The lower LH view in
When generating the design of the Figure 4 shows two of the four input/output
Interrupter, the ground rules had changed detonator ports (the other two oppose the
slightly, and different choices were to be ones shown) in the aft section of the
made. This unit was to contain no EEDs, housing, and two electrical connectors. One
therefore, questions regarding firing trains of these interconnects with the drive train
only related to the external ordnance transfer power circuits, the other connector
lines. The issue of SMDC versus CDF lines interfaces with the remote monitoring
arose, and the propagation characteristics circuits. The two lower views depict the
were found to be somewhat different for the Sating Key, which is located in a cylindrical
two types. Hermeticity was not specified, projection on top of the unit. The two
which simplified the design of the cylindrical projections at one end of the
interlocking Sating Key, since a welded Interrupter house the pneumatic damper
metal bellows "pass-through" was not components.
required. It should be noted that the
Interrupter is environmentally sealed, with Figure 5 shows the drive train components.
and without the Sating Key installed. The prime movers are two identical pull
type solenoids, installed in parallel, one for
Because the unit interrupts fixed transfer driving the mechanism from the Safe to the
lines, the interruption must be done by a Armed state, the other for reversing the
movable barrier. Design choices for the procedure. The plunger in each solenoid is
barrier included a linear displacement type pinned to a rod extension on which a roller
and two rotary displacement types, one a is mounted. A low-inertia rotor is mounted
disc the other a shaft. Workable designs on a shaft aligned on an axis normal to the
could have been generated based on any of solenoid axes and half way between them.
these approaches, but the rotating shaft As shown in Figure 5, the rod-mounted
option was selected because it was believed rollers contact opposite faces on the Rotor.
that it would facilitate the interfacing of the A retraction of the Arm solenoid causes its
barrier with the drive train and the required coupled roller to cam-drive the Rotor in the
manual sating mechanism. clockwise direction (viewed from the rotor
side of the unit). Conversely, the Safe
A linear solenoid/bellcrank solution was solenoid will drive the Rotor in the CCW
chosen for the drive train, rather than a direction. An overcenter spring, pinned, to
more conventional rotary solenoid. The the Rotor and housing, completes the
selection was based on lower cost, and the Rotor's full 90 degree rotation after it is
ability to readily obtain a reversible 90 driven past top-dead-center by either
degree rotation of the barrier without solenoid. The overcenter spring is also
resorting to a gear reduction train. designed to detent the Rotor in either the
Safe or Armed position.
- 216 -
Figure 4: The Interrupter Configuration and Envelope
r-c
.._ / / /
Di,_ __.
,:li r , --...... JO
i
//_//////_,_
..... "_z±_ --._
. . <
S_CT,O.
O-D
- :;17 -
t '1 I = ..........
,.! \
Figure 6: The Pneumatic Damper
as shown
vibration
in Figure
on the rotor,
exposure.
6, consists
during
Each
of a
"it /
spring-loaded piston riding in the bore of a
tubular extension on the housing. The
damper-piston head and rod are sealed by
dynamic "labyrinth" glands designed to
I I I I I I I I l
(,_88)-
coupled
apertures
to the Interrupter.
in the shaft are
Two
aligned
transverse
with the
/ Z)( .250
4X FULL R J_
ports to provide propagation paths when the -- zx ,523
rotor is in the Armed state. When Safe, the
--- 2× ,375
apertures are maintained at 90 degrees to the
propagation paths. The apertures, which are
carefully configured slots rather than Figure 8:
cylindrical bores, are shown in Figure 8. Propagation Apertures in Rotor Shaft
- 2i8 -
The dimensionsand configuration of these
slots evolved during development testing, to
provide reliable detonation propagation
across in airgap of almost I/2 inch. To put
this simple fact in perspective, the airgaps
between donor and receptor tips in ordnance
transfer lines are usually of the order of 40
to 60 thousandths of an inch.
- 219 -
position, only the red side is seen. DEVELOPMENT
- 220 -
EXPLOSIVE GAP PROPAGATION: Tests per DOD-E-83578
VIBRATION:
Frecuencv X and Y A:<is Z Axis
20 Hz .026 G2/Hz .041 Gz/Hz
5HOCK:
Frecuencv Peak Acceleration
I00 45
i00 to 1500 +5 dB per Octave
1500 4100
3000 4100
- 221 -
mounted on the aft face of the housing.
/
Another possible design refinement would
be full integration of the pneumatic dampers
within the main housing, rather than in the
tubular extensions. This would have the
advantage of reducing the overall length of
the unit, although it might make the
assembly of the device slightly more
difficult, therefore, more expensive.
SAFE CONDITION
The Interrupter described in this paper is a
"patent pending" device which offers a
significantly lower cost alternative to
conventional Safe and Arm devices, for
OET#1
some applications. The original design was
limited to applications involving ordnance
transfer lines interconnecting system
initiators with independent output devices.
A recent refinement to the Interrupter, in
which a rotary switch replaces the original
microswitches and an additional connector is
added, permits electrically initiated
detonators to he installed in the unit's input I___--:ET# 2
- 22Z -
A VERY LQW SHQCK ALTERNATIVE TO CQNVENTIONAL, PYROTECHNICALLY
OPERATED RELEASE DEVICES
- 2:)5 -
inefficient and slow compared to existing pyrotechnic
equivalents. This demonstrated that using NiTiNOL as a
mechanical fuse as a means of holding and releasing a
To improve the performance of our release design given preload was feasible. However, any structural
concepts, a review of the basic characteristics of alloy should be capable of accomplishing the same
NiTiNOL was initiated to determine if any properties task. A comparison chart showing the requirements of
were overlooked that would help reduce the size and/or a mechanical fuse compared to the characteristics of
increase speed of operation. This review uncovered the NiTiNOL, nichrome, beryllium-copper, and steel is
fact that "as-wrought" NiTiNOL, prior to annealing, given in Figure 2. As shown, NiTiNOL has the best
is very strong. The ultimate tensile strength can be as combination of properties necessary for a mechanical
high as 270 KSI. When the NiTiNOL is annealed, fuse release concept.
restoring the crystalline phase structure necessary for
shape recovery, the ultimate tensile strength is The most significant factor is the dramatic change in
reduced by a factor of 2 or more. This fact along with strength capability at elevated temperature. This
other characteristics such as high electrical resistance, reduction in the tensile strength of NiTiNOL is
excellent corrosion and fatigue capabilities led us to crucial to the preload breaking the structural tie and
believe that a simple, effective, and fast NiTiNOL releasing the load. None of the other materials show
mechanical "fuse" separation concept is feasible. as large a strength reduction at elevated temperature.
Using NiTiNOL as a mechanical "fuse" appeared to The demonstration of fusing a single NiTiNOL
be a simple structural separation concept with few of element does not automatically demonstrate the idea
the problems associated with pyrotechnic devices. can be scaled up to practical sizes and applications.
Since conventional separation nuts are capable of
INITIAL CONCEPT DEVELOPMENT loads up to 25,000 lbf, the NiTiNOL separation idea
would also have to be capable of achieving these load
The first test to demonstrate the NiTiNOL mechanical levels. In order to accomplish this, a relatively large
fuse concept was relatively simple. This is shown in number of NiTiNOL fuses would have to be
Figure 1. One end of a NiTiNOL wire was mounted incorporated in parallel fashion to increase the load
carrying capability to levels equivalent to explosive
bolts and nuts. Multiple NiTiNOL fuse element
arrangements appear to be the only way to maintain
large load carrying capability and still have the
resistance of the elements high enough for efficient
electrical heating
terminal strip
However, the large number of elements, if they were
NiTiNOL
all heated at the same time, would require a
prohibitive amount of electrical power. This is not
possible with existing power system ratings on
supply today's aerospace systems. A NiTiNOL fusible
_i_rreOL _ power element requires a low voltage, high current electrical
pulse to efficiently heat the element in the shortest
amount of time.
- 224 -
distribute the load and increase the overall load To further increase the load carrying capability,
carrying capability. The clement lengths are all multiple groups of these subsets of NiTiNOL fusible
elements can be arranged to be released in series. As
Material Property Comparison Chart soon as the last element in the first group separates,
power is transfered to the next group of elements,
vrol,mi. fuse .7-4Pt 304 Beryllium Nidmane
_xlm,ts NiTiNOL Steel Steel Coo¢_a" _i "/9.CYLq,_ ; thereby continuing the separation sequence.
clccuical
resistivity High 100 100 72 20 134
(microhm-cml
fatigue R4
reaistanc_ High High High Meal. High
thermal
conductivity Low 10.4 10.4 9.4 120 5,4
(BTU/hr4t-F) I
time -----41-
Comparison of NiTiNOL to other structural alloys
NiTiNOL Fusible Element Release Sequence
Figure 2
Figure 4
stationary structure
NiTiNOL fusible The number of element groups can be increased to
accomodate a wide range of loading conditions. The
time-to-separate requirement must be addressed to
_ element (5 pl) assure there is no impact to the overall separation
operation.
- 225-
NASA/JSC to perform a feasibility experiment element groups. This continues until all fusing pairs
demonstrating that a NiTiNOL sequential structural of element groups have been severed. The circuit
separation system is capable of loads in the range diagram is shown in figure 6. To expedite the circuit
needed for commercial applications. Since this was a design, automobile starter solenoids were utilized in
small experiment, a candidate separation load was the circuit design to transfer battery power between
assumed to be 5000 lbf. This would provide a NiTiNOL fusing element groups.
reasonable loading condition without imposing extra
costs. When switch S 1 is engaged, 28 V is applied to the
first starter solenoid closing the circuit and applying
The basic design concept is shown in figure 5. To 12 V battery power across opposite groups of
expedite the experimental hardware fabrication, we NiTiNOL elements. The 4 ohm resistor prevents the
utilized NiTiNOL strip, 1.4" w x 0.004" t, that was second solenoid from engaging until the last
available in-house, as part of our ongoing IR&D NiTiNOL element, from the first 2 groups, has fused
effort. Although the dimensions of the strip was not open. Battery power is then switched to engage the
optimized for this experiment, we felt valuable second solenoid, which in turn applies battery power
information on laser cutting of NiTiNOL and to the next pair of opposite NiTiNOL element
operation of this patented NiTiNOL non-pyrotechnic groups. This continues until the last NiTiNOL
release concept could be achieved. elements are fractured releasing the structural load.
The structural members were fabricated from 4.0" dia. EXPERIMENTAL TEST RESULTS
molybdenum disulfide impregnated nylon. This
provided an inexpensive, electrically isolating Using 0.004" thick foil for this test generated concern
material capable of handling the 5000 lbf projected that the foil might fail in the attachment holes at the
load. Mounting studs were attached to the center of required load of 5000 lbf. A load test was performed
the nylon parts to provide sufficient grip length for to determine the maximum load capability. As
installation onto an Instron tensile test machine. The predicted, the failure occured in the mounting holes at
NiTiNOL fusible element strip was installed across approximately 3200 lbf. It was obvious that a goal of
the interface between nylon members. The NiTiNOL 5000 lb was not possible with the current material.
fusible element member was attached by two(2) rows However, no alternative was available to support
of 32 each 6-32 fasteners. These were installed into testing. Therefore, it was recommended that the test
tapped holes in the nylon parts. The load across each load be reduced to 2000 lbf. This would still
fastener was 125 lbf max. The one concern was demonstrate the feasibility of this technology with
whether the attachment holes, in the NiTiNOL strip, the current experimental hardware at a realistic load
were strong enough to react the tensile load without value.
tearing out.
One test was performed to demonstrate feasibility.
The cutout pattern and slots, defined the five (5) The test article was mounted on an Instron tensile test
NiTiNOL fusing elements per each of the eight (8) machine with full scale readout of 5000 lbf. The load
groups. The cutouts were produced by a high powered was uniformly increased to 2000 lb indicated. As the
laser cutting system located in the Boeing Materials load reached the test level, switch S1 was closed
Technology Laboratory located in Renton, Wa. applying power to the first solenoid. The fast pair of
Utilizing computer controlled laser cutting provided NiTiNOL element groups fused opened in 156
several benefits. Unique patterns can be cut into the milliseconds, the second pair in 182 msec, the third
strip with great accuracy. This also provides a high pair in 164 msec, and the last pair in 194 msec. The
degree of dimesional repeatability, critical for some total time to release was 0.838 seconds. The trace of
operations. Laser cutting also provides a way to the release operation is shown in figure 7. As the
minimize the area of the heat affected zone which oscilloscope trace shows there was some bounce of
would compromise the large differential strength the solenoid contacts generating some delay of power
characteristic of NiTiNOL from its unnannealed state to the NiTiNOL elements, increasing the apparent
to its annealed state. separation time.
The structural separation operation uses an electrical The circuit performed as designed. Once the switch
circuit that applies battery power to opposite pairs of was engaged, the application of battery power was
fusing elements. This assures a symmetrical release autonomous and continuous. This resulted in a very
of the load minimizing any off-axis unloading simple circuit capable of transferring high current
situations resulting in excessive tip-off rates. As the pulses as many times as needed.
last elements of the first two groups are fused opened,
battery power is switched to the next pair of fusing
- 226 -
NITINOL RELEASE TEST FIXTURE(FULLY ASSEMBLED)
\ I THREAOEB STUO
STRUCTURE[NYLON I
b+IO L
I+++_+e e e
+IO Jeee¢ ++++:° +_.+'
t+
NITINOL FUSIBLE
+
e--e--e-e-
00o-+
-e--e--e--e-
ceee
00o+
÷÷÷¢
U Ooo+/flOoo+ ++++U
0oo+ 00o_ 00o_
-e--e--e-_'-.'.e-.e--e-e- -e--e--e-.¢-
released structure
12 V battery
I
I
I
I wer supply
- 227 -
Although this type of release concept may require a If an existing electrical system, capable of operating
unique electrical system, such as dedicated on-board pyrotechnic devices with 5A DC max. current output
batteries, the changes appear to be minimal and is the only source of power, work was accomplished,
simple to implement. under contract with the Naval Research Laboratory, to
develop such a release device, for spacecraft use, based
on this invention. This work is described in the
following section.
- 228 -
_TOWEO RELEASEO
MINIMUM AREA
(0.020" X 0.030")
_TENSION LINK
• I
TORSION SPRING
(I OF 2}
IRANSFORMER
doubling the strength of the NiTiNOL mechanical NiTiNOL Fusible Link Reaction Force Geometry
fuse without increasing the overall size of the release
device. tension link _ 201_0 lb., NiTiNOL
- 229 -
was 1.3" L x 1.0" W x 0.25" t. Mounting the hold and release a given preload using a typical 28V,
transformer to one of the jaws kept wire lengths to a 5A electrical bus system. Even with the apparent
minimum. This prevented inductance from becoming dependency of release time to preload, this can be
a problem. Too much inductance would reduce the attributed to the limited power available. The effect
amount of power through the NiTiNOL fusible link can be minimized by proper sizing of the NiTiNOL
compromising the heating of the NiTiNOL and the fusible link and optimizing the heating to the power
performance of the device. availability. In addition, the shock of separation was
insignificant. There is no contamination or safety
The preload is applied by threading a bolt into the top issues associated with this device.
of the tension link assembly. As the bolt was
torqued, the tension link would be pulled up and The release device is completely reusable except for
engage the jaws. The moment generated by the the NiTiNOL fusible link. This feature allows the
tension link against the jaw tries to force the jaws same device to be operated many times during ground
apart. The NiTiNOL fusible element reacts this torque testing, and still be available as the flight unit. The
until the NiTiNOL is electrically heated. When this benefits of this device are shown in figure 10.
occurs, the link becomes structurally weak and
fractures, allowing the jaws to spring out and the
Benefits
tension link to be extracted.
- 230 -
assembly of pyrotechnic devices can be practically design flexibility that provides the designer with
eliminated if this technology can be developed to its options not possible with conventional pyrotechnic
fullest capability. systems. This ability to slowly release large preloads
all but eliminates the heavy shock environment
Both of the concepts, described previously, offer both imposed on the surrounding structure. This can be
ends of the design spectrum that is possibile using accomplished without jeopardizing the actual release
this simple technology. Many design alternatives can function.
be created if the drawbacks, associated with
pyrotechnic devices, can beeliminated. We understand The future of non-pyrotechnic structural separation,
this and are continuing to improve the basic concepts based on this patent, will be expanding. The
described here. capabilities offer so many advantages that this
technology will become a major part of structural
One of the most intriguing design possibilities is the separation for the next generation of aerospace
two-step arming/separation function described vehicles.
previously. This idea offers unique advantages and
- 231 -
INVESTIGATION OF FAILURE TO SEPARATE AN INCONEL 718 FRANGIBLE NUT
7oo0
TABLE 2
ORIGINAL MANUFACTURER QUALIFICATION TEST MATRIX FOR
2.5 INCH FRANGIBLE NUT AND BOOSTER CARTRIDGE
* Group G nuts had web thicknesses 120% the nominal maximum allowable
- 236 -
TABLE 3
MATERIAL PROPERTIES, CHEMICAL DATA, AND MICROSTRUC'rURE GRAIN SIZE FOR INCONEL 718 USED
IN FRANGIBLE NUTS BY MANUFACTURERS
Ultimate Tensile
Avg (ksi) 188.5 194.2 192.0 190.7
Std. Dev. (ksi) 4.1 1.2 2.4 0.8
Elongation
Avg. (%) 18.6 18.7 20.2 13.0
Std. Dcv. 1.6 0.5 0.6 0
Reduction of Area
Avg. (%) 28.2 30.3 33.2 38.0
Std. Dev. 2.5 1.2 1.5 0
- 237 -
TABLE 4
NAS 9-17496 FRANGIBLE NUT AND BOOSTER CARTRIDGE
QUALIFICATION TEST MATRIX
- 238 -
TABLE 5
FAILURE INVESTIGATION TEST MATRIX
TABLE 6
NAS 9-17674 FRANGIBLE NUT AND BOOSTER CARTRIDGE QUALIFICATION TEST MATRIX
- 239 -
ORBITER/EXTERNAL TANK j
AFT ATTACH INTERFACE
_. 1920 mg
ISOMICA L_
DISKS _L ISOMICA
DISKS [_
I
0.200" _ HOUSING • _I _ HOUSING
Figure 1. Illustration of orbiter/external tank aft attach Figure 3. Illustration of 2.5-inch booster cartridge
interface and cross section of 2.5 inch frangible -401 configuration and modified design,
nut installation.
-402 configuration.
FRANGIBLE WEBS
A1 BOOSTER
'PORTS
1 I////////A_
...............
_:,-/:,-,,';-,-/l,j
._ 115% (0.149")
I 120% (0.1563
/
AJ
TOP VIEW OF 2.5-INCH SECTION A-A
FRANGIBLE NUT FRANGIBLE NUT
SEPARATION PLANE
-101, -102 MARGIN NUT WEBS
Figure 2. 2.5-inch frangible nut separation plane and Figure 4. 2.5-inch frangible nut nominal web thickness,
frangible webs. (-301 configuration), 120% nominal web thickness,
(-101 configuration) and 115% nominal web thickness
(-102 configuration).
- 240 -
Figure 5. S O 0 X micrograph of original frangible nut Figure 7. lOOX micrograph of Inconel 718 used
supplier’s Inconel 718. inqualification test program under NASA contract
NAS 9-17496.
4 OUTER LEDGE
FRACl
WEBS TOP VIEW OF FRANGIBLE NUT
MATERIAL
REMOVAL
GAP DEVELOPED
FROM SINGLE BOOSTER
CARTRIDGE FIRING
SECTION A
Figure 6. Illustration of clamshell motion experienced by Figure 8. Illustration of material removal from outer
2.5-inch frangible nut during single booster ledge of 2.5-inch frangible nut.
cartridge firing.
- 241 -
Figure 9. lOOX Micrograph of Inconel 718 Used in Figure 10. loOX Micrograph of Inconel 718 Used in
Production Lot under NASA Contract Qualification Lot under NASA Contract
NAS 9-17496. NAS 9-17674.
- 242 -
BOLT CUTTER FUNCTIONAL EVALUATION
ABSTRACT
The Aerospace Corporation has been implementing finite difference and finite
element codes for the analysis of a variety of explosive ordnance devices. Both
MESA-2D and DYNA3D have been used to evaluate the role of several design
parameters on the performance of a satellite separation system bolt cutter.
Due to a lack of high strain rate response data for the materials involved, the
properties for the bolt cutter and the bolt were selected to achieve agreement
between computer simulation and observed characteristics of the recovered
test hardware. The calculations provided insight into design parameters such
as the cutter blade kinetic energy, the preload on the bolt, the relative position
of the anvil, and the anvil shape. Modeling of the cutting process clarifies
metallographic observation of both cut and uncut bolts obtained from several
tests. Understanding the physical processes involved in bolt cutter operation
may suggest certain design modifications that could improve performance
margin without increasing environmental shock response levels.
- 243 -
To obtain the 180-210 ksi UTS, the A286 METALLURGICAL ASSESSMENT OF A286
material requires cold working per AMS 5731. BOLTS
The bolts used in the system separation tests
had not been cold worked. It was found that Metallurgical analyses were performed to infer
the Quantic target bolts, part number F12496, the role of each parameter in the cutting
used in bolt cutter lot acceptance tests are cold process. The analyses were performed on
worked. The F12496 drawing states that the fractured segments of a short bolt obtained
target bolt material comply with AMS 5731 from a Quantic lot acceptance test and on both
and be cold worked to obtain 180-210 ksi UTS fractured and unfractured long bolts from the
following heat treat per MiI-H-6875. Since system separation tests. The analyses included
1972, a large number of bolt cutters from a microscopic examination of the fracture
many production lots have successfully severed surfaces, metallurgical studies of the regions of
the F12496 target bolts. No data base was deformation and fragmentation at the beginning
found to assess cutter performance with A286 of the cutting process, and measurements of
bolts which had not been cold worked. material hardness and microstructure.
The team also found that the mass of the bolts These studies, and an examination of the
used in the system separation tests was at photographs in Figures 3 through 9 lead to the
least six times greater than the Quantic test following observations:
target bolt. The greater mass is due to greater
length and end diameter, which is required for Grain size and hardness differences
installation. The concern then was the lack of exist between the long and short bolts.
information on the effect of bolt inertia on bolt The short bolt had a fine grain size and
cutter performance. high hardness (Rc 42), and was
consistently severed. The long bolt
The team directed efforts toward analyzing the was larger grained and softer (Rc 35),
cut and uncut test bolts and in attempting to and was not consistently severed. See
duplicate the cutter performance analytically. Figures l Oa and lob.
A F12496 target bolt, used in a bolt cutter lot
acceptance test, was obtained from Quantic The long and short bolts which had
and also analyzed. In addition to assessing bolt been successfully severed exhibited
inertia effects, the team attempted to adiabatic shear bands in the deformed
determine the effect of bolt tension on the bolt material regions adjacent to both the
cutter performance. The parameters assumed cutter blade and the anvil. Adiabatic
to affect the ability of the bolt cutter to sever shear bands are regions of highly
the bolts are: localized plastic deformation resulting
from the high material temperatures
• bolt configuration that are caused by high strain rate
• ductility of the bolt material loading.
• preload in the bolt
No evidence of adiabatic shear bands
Other parameters such as gapping between the were seen in the deformed material
bolt and anvil and the anvil configuration were regions adjacent to the anvil on the
also considered. long bolt which had failed to separate.
- 244 -
code that assumes, to a first approximation, The simulations were assumed to start when
that material behavior can be described by fluid the cutter blade begins to move, and neglects
dynamics when strong shocks are present. the functioning of the initiator and the transfer
The equations of motion to be solved are then of energy to the cutter blade.
the time dependent nonlinear equations of
motion for compressible fluids. The initiator consists of 70% by weight
ammonium perchlorate (AP), 27%
Throughout a calculation, MESA-2D computes polybutadiene acrylic acid (PBAA), and 3%
and records all relevant dynamic and combined zirconium barium peroxide (ZBP),
thermodynamic properties for each cell (mass ferrix oxide (FO), and epoxy resin. The ZBP
element) in the model. These variables could and FO as oxidizers will enhance the
include position, velocity, pressure, internal performance of the main constituent, AP. The
energy, temperature, density, intrinsic sound remaining materials are inert binders. The
speed, elastic and plastic work, plastic strain, material properties of all these materials are not
strain rate, and deviator stress. All of these known. An upper and lower bound estimate of
quantities output in graphical form or in tabular kinetic energy output was made from the
form for further analysis. By integrating over available chemical energy of the AP assuming
very small time steps, typically less than 1 instantaneous energy release via detonation.
nanosec, the MESA calculation can handle Since the exact energy partition is unknown,
impulsive loading of materials and allows their trial computer models were run using several
dynamics to be resolved with sufficient candidate velocities within these limits. The
accuracy to elucidate the physical processes cutter velocity was determined by trial and
involved [1 ]. error, matching the resulting penetration into
the bolt to the experimental data. This velocity
The numerical integrations required by the was 332 m/sec.
calculations were performed with coordinate
meshes of between 40,000 and 60,000 cells. Computational Results
This gives better than 0.1 mm resolution,
which is required .to understand small systems The calculations began at time zero with the
such as the bolt cutter. bolt cutter blade poised to impact the surface
of the bolt and with the initial constant velocity
Finite Difference Models of 332 m/sec. The proper penetration of the
cutter blade into the material to agree with the
Figure 11 shows the cutter blade, the anvil, test data from Figures 5, 6 and 7 is achieved in
and the bolt to be cut that were included in the approximately 20 psec. The material interfaces
MESA finite difference model. It also shows show that both light and heavy bolts have
the particle velocity distribution after 20 psec. responded identically to this point. The time
An alternative configuration was also elapsed to this point in the cutting process is
developed in which the massive ends of the one order of magnitude smaller than the time it
flight bolt were eliminated. The models were had previously been assumed by the
analyzed using slab geometry and transmissive community for bolt cutter function.
boundary conditions for the hydrodynamic
equations. Bolt preload was not included. Compression and tension waves propagating
through the bolt show that there is no net
In the computer simulations, the available motion of the bolt ends since the particle
material properties of 304 stainless steel were- velocities of the end cells go to zero. The
used as the basis for the properties of all velocity of the cutter blade also changes
metallic components. The yield strength and direction several times after it penetrates the
shear modulus were adjusted by using 4340 bolt. This is evidence of an oscillation that is
steel for the blade and A286 for the bolt. set up which will cause the blade to bounce
Strain rate effects were accounted for by back.
allowing these constants to vary [2, 3, 4].
- 245 -
The model shows, as does the test hardware, resolution available in the calculation.
that all material deformation occurs within a 1
cm radius of the impact point of the cutter Additional calculations were performed using
blade. No rigid body motion of the bolt is both smaller and larger velocities for the cutter
required for penetration, and indeed the blade. When the velocity is 133 m/sec, the
coordinates of the bolt ends do not change blade does not penetrate far enough to match
throughout the cutting process in the the data. When it is increased to 431 m/sec,
calculation. it is possible to separate the bolt by penetration
alone, independent of the formation of a shear
Shear deformation can be discerned from fracture. These calculations indicated that
inflections in the particle velocity distributions depth of penetration of the blade into the bolt
as early as 10 psec. These patterns are is dependent on this variable alone. This is
apparent in Figure 11. This result agrees with consistent with the results of various empirical
the evidence of the same behavior in the penetration analyses for projectiles [5], which
photomicrographs of the cut surfaces. Ejection show that penetration depth is a function of
of particles from the top surface of the bolt can the velocity of the penetrator and the ratio of
be seen. There is also a small crack that densities of the materials of penetrator and
appears near the tip of the cutter blade. All of target. Since both blade and bolt have the
these features were seen in the hardware, same density, the only other determining factor
especially Figures 5 and 6. The indentation is penetrator velocity.
from the anvil on the underside of the bolt can
also be seen beginning to form although it is
not obvious until some time later. MODELING WITH DYNA3D
The material deformation is due almost entirely Due to analytical considerations of nonlinear
to plastic work. The elastic contribution is dynamics and stress wave propagation effects
between two and three orders of magnitude in bolt cutter structural response, transient
smaller than the plastic, and the penetration dynamic analyses were performed using the
process is completed before the effects of any DYNA3D code. The DYNA3D code is an
elastic waves can be seen. Therefore, the ends explicit, nonlinear, finite element analysis code
of the bolt, and whether or not they are developed by Lawrence Livermore National
massive, may have no effect on cutter Laboratory [8]. It has a sophisticated
performance. simulation capability for handling frictional and
sliding interactions between independent
Blunting of the cutter blade edge occurs as bodies.
well. Figures 12 and 13 show this in the
hardware. The assumption had been that this A built-in feature in the DYNA3D code was
blunting resulted from the impact of the blade selected for modeling the sliding surface failure
against the anvil after the bolt had separated. behavior. A failure criterion based on the total
While there is undoubtedly some effect from cumulative effective plastic strain is defined for
this, the blade edge is also blunted by erosion the elements adjacent to the contact surface.
during the bolt penetration process. When the rate-dependent plastic strain value
within an element satisfies this failure criteria,
As configured, the MESA calculations do not the element is removed from further calculation
show that the cutter completely severs the and a new sliding surface boundary is defined.
bolt. This may be partly attributed to"
insufficient brittleness in the material Parameters compared in this study include the
description. However, the highest shear approaching speed of the cutter blade, the
locations match those in the photomicrographs applied bolt preload, the gap clearance between
of the test bolt that failed to cut. The shear the bolt and the anvil, and the contact surface
deformation regions that originate at the anvil area of the anvil. TABLE I lists the four
side of the bolt are not as clear with the parameters and their variations considered in
- 246 -
the finite element analysis matrix. In this table, from references [9] and [10], respectively.
the 3,270 Ibs bolt preload and a maximum gap
allowable of 0.065 inch between the bolt and In the finite element analysis model,
anvil were based on drawing specifications. nonreflecting boundaries were assumed at the
The loss of preload and a 50% reduction in two ends of the bolt and the anvil to prevent
anvil's contact area were chosen to study their artificial stress wave reflections re-entering the
impact in cutter performance. model and contaminating the results. A fixed
end boundary condition was assumed at the
The speed for the blade was determined using lower end of the anvil. The bolt preload was
system separation test data. In these tests, six first generated by applying pressure loading on
A286 bolts were preloaded to 3,270 Ibs. Two the bolt with a built in dynamic relaxation
of the bolts had a cutting depth of 40% of the option. The cutter blade with the appropriate
bolt diameter and did not fracture. The other approaching speed was then applied. A
four bolts had a slightly deeper blade transient dynamic analysis was performed to
penetration, were totally severed and the cutter estimate the damage in the bolt. The analysis
blades also indented the anvil. The transient results for the eight study cases are listed in
dynamic analysis duplicated these conditions the last column of TABLE II. The O's and l's
by using a 6,000 in/sec (152 m/sec) speed. are corresponding to a partial or a complete
cutting of the bolt, respectively. Figure 14
Finite Element Analysis Matrix shows the simulation results at 0.4 ms for the
baseline model in TABLE II. In Figure 15, with
The Taguchi experimental design technique [6, a finer mesh model, it can be seen that the bolt
7] was then adopted for establishing the is completely severed by the cutter. It can be
analysis matrix. This technique was also used seen that the failure configuration matches
to analyze the finite element calculation results fairly well with the test data in Figure 3.
to identify the optimum bolt cutter
configuration, especially in relation to preload Bolt-Cutter Performance Assessment
or applied tension on the bolt.
From finite element analysis results listed in the
A Taguchi analysis matrix with 8 study cases last column of TABLE II, the bolt cutter
(a Lsorthogonal array [6, 7]), shown in TABLE performance, based on variation levels for each
II, was established to evaluate the criticality of parameter, can be summarized. For example,
the four chosen parameters mentioned above. the cutter performed well with a bolt preload
Interaction effects between these parameters (parameter A) of 3,270 Ibs (level 1). It resulted
were assumed to be negligible. Based on the in three successful cuts and one failure. The
analysis matrix and the chosen parameter listed cutter performed poorly with parameter A at
in TABLE II, 8 different finite element models level 2 (zero preload), with only one success
were constructed. A baseline finite element and three failures. Therefore, the analysis
model of the bolt cutter configuration (case 1 results of level sum A1 and A= are:
in TABLE II) as shown in Figure 2. Due to
symmetry of the bolt cutter geometry, only one AI= 1 + 1 + 1 + 0 = 3 cuts
half of the bolt cutter configuration was A== 1 + 0 + 0 + 0 = 1 failure
modeled. This model consists of 618 solid
elements and 1027 nodes to simulate the 60 Total = 4 cases
degree cutter blade, the 5/16 inch diameter
bolt, and the anvil. Other parameter sums are similarly calculated
and summarized in TABLE IV. These results are
Transient Dynamic Analysis also plotted in Figure 16 in bar chart format in
terms of the percentage of success. It can be
TABLE III lists the mechanical properties used seen that the bolt cutter performance can be
in the analysis. The values chosen for $7 tool improved with the design parameter setting of
steel and A286 stainless steel were obtained A1, B_, C_, D=. That is, it is desirable to
- 247 -
improve the cutter performance by applying a finite element analysis prediction. This result
bolt preload of 3,270 Ib, providing sufficient indicates that the additive model is adequate
energy for the cutter blade to reach a speed of for describing the dependence of the structural
6,000 in/sec, ensuring that no gap exists response on various parameters, and also
between the bolt and the anvil before firing, confirms that the assumption of negligible
and by reducing the anvil and the bolt contact interaction effects between various governing
surface area by half. parameters was valid.
Omega Transformation
CONCLUSIONS
In order to verify the assumption that
interaction effects between these four The evidence obtained from the metallurgical
parameters are negligible and to estimate the examination of test hardware suggests that
response of the optimum condition of the bolt bolt severance from the impact of the bolt
cutter system, the omega transformation cutter blade occurs as a result of a combination
technique [7] can be used. The omega of processes. These include:
transformation is defined as follows:
reduction of the bolt diameter by
(3(P) == -10 log (1/P -1) dB penetration of the blade;
where P is the percentage of success. For the reduction of the bolt diameter by
cases of cutter failure (0%) and cutter success penetration of the anvil;
(100%), they are treated as follows:
wedge opening forces generated by the
0% case - Consider this as 1/(number of cases) cutter blade as it penetrates;
and perform the omega transformation. For the
current study, the number of cases is 8; thus, • applied preload on the bolt; and
(1/8)x100 = 12.5% or o(12.5%) =-8.45 dB.
adiabatic shear band formation under
100% case - Consider this as (number of cases the combined effects of shock heating
- 1)/(number of cases) and perform the omega and the applied stresses on the bolt.
transformation. For the current study,
[(8-1)/8]x100 = 87.5% or Q(87.5%) = 8.45 dB. The two analysis techniques that were
employed proved to be complementary to each
Based on the approach as shown in [7], the other in that they each were able to elucidate
optimum response, m, can be estimated by an different features of the ductile bolt behavior
additive model. and of the governing design parameters of the
system. In addition to the above conclusions,
m(A1B1C1D=) = TAI+ TB1 + Tcl + TD2 -3xT which they confirm, are the following.
= (3(75%) + (3(75%) + Q(75%)
+ (3(75%) - 3 x (3(50%) The MESA-2D analysis indicates:
= 4.77 + 4.77 + 4.77 + 4.77-
3x0 The bolt cutting process is completed
= 19.08dB (> 8.45dB) in less than 60 psec.
= 98.8% ( > 87.5% ).
Neither the length nor mass of the bolt
Here T is the overall mean percentage of has any effect on the ability of the
success for all cases analyzed in Table IV and cutter blade to penetrate the bolt.
Txy is the average for parameter X at level y.
Thus, under the optimum conditions, the bolt The depth of penetration of the cutter
could be totally severed by the design of blade into the bolt is a function of the
AIB1C1D=. This was later confirmed by the cutter blade velocity.
- 248 -
• The bolt fractures due to shear in the REFERENCES
second part of the separation process.
The bolt cutter is more effective if the [3] D. J. Steinberg, S. G. Cochran, and M.
surface area of the anvil in contact W. Guinan, "A Constitutive Model for
with the bolt is decreased. Metals Applicable to High Strain Rate',
J. Appl. Phys. 51 (3), 1498 (1980).
This last conclusion presents a possible design
modification that is an alternative to increasing [4] G. R. Johnson and W. H. Cook,
the kinetic energy of the cutter blade with "Fracture Characteristics of Three
additional explosive. Increasing the amount of Metals Subjected to Various Strains,
explosive could increase the shock from Strain Rates, Temperatures and
functioning the device, whereas a change in Pressures", Eng. Frac. Mech. 21 (1),
anvil configuration would not. 31 (1985).
Further work is still needed on the bolt cutter [5] Joint Technical Coordinating Group for
system to analyze the performance under Munitions Effectiveness (Anti-Air),
conditions where the cutter blade has a Aerial Target Vulnerability Subgroup,
non-parallel impact to the cross section of the Penetration Equations Handbook for
bolt. Kinetic Energy Penetrators (U), 61
JTCG/ME-77-16 Rev. 1, 15 Oct. 1985.
- 249 -
Table I. Parameters for Bolt Cutter Study
1 2
A B C D
1 1 1 1 1 1
2 1 1 2 2 1
3 1 2 1. 2 1
4 1 2 2 1 0
5 2 1 1 2 1
6 2 1 2 1 0
7 2 2 1 1 0
8 2 2 2 2 0
- 250 -
Table III. Mechanical Properties Used for DYNA3D Analysis
A 3 (75) 1 (25)
B 3 (75) 1 (25)
C 3 (75) 1 (25) ;.
D 1 (25) 3 (75)
- 251 -
Figure 1 : Top photo is the configuration of the long bolt used in system separation
tests. One bolt is fully separated, the other is not. Bottom photo shows the
bolt cutter with the internal blade visible through the hole at the anvil end
of the cutter.
- 252 -
t
-
a,
a,
- 253 -
Figure 3:
Top photo shows separation
area on the short bolt. Bottom
photo is an SEM micrograph
providing a face-on view of the
fracture on the top right. Note
secondary cracks on the blade
cut area and complex fracture
surface in lower quadrants.
- 254 -
Fig1Jre 4:
Top photo shows separation
area on the long bolt. Bottom
photo is an oblique view of the
fracture seen on the top left.
Note the limited extent of the
blade cut surface remaining on
this segment.
- 255 -
Figure 5: Top photo shows impact area of the long bolt which failed to separate.
Bottom photo shows impact area after polishing away 1/4 of the bolt
diameter from the side of the bolt. Note the small 45" crack at the tip of the
notch produced by the blade impact.
- 256 -
Figure 6: Top photo shows impact area of the long bolt after polishing away 1/3
of the bolt diameter. Bottom photo shows same area after etching (with
dilute hydrochloric and nitric acid mixture). Note in this section there is
no crack at the tip of the notch. Adiabatic shear bands of localized
deformation are seen on both sides of the notch.
- 257 -
Figure 7: Top photo shows impact area of the long bolt after polishing away 1/2
of the bolt diameter. Bottom photo shows same area after etching.
Adiabatic shear bands emerge from the sides of the notch. There is no
evidence of similar bands adjacent to the anvil.
I - 258 -
Figure 8: Top photo shows separation area of the short bolt. Bottom photo is a view
of the midplane of the bolt segment shown on the top left. Note that a band
of localized deformation (adiabatic shear band) has formed in the deformed
material above the anvil (see arrow).
- 259 -
Figure 9:
Top photo shows polished and
etched section through the
deformed area above the anvil
on the short bolt. Bottom
photo shows polished and
etched section through the
deformed area above the anvil
on the fractured long bolt.
Adiabatic shear bands of
localized deformation are
emerging in the area of the bolt
near the corner of the anvil.
50x
200x
- 260 -
lOOOX
1ooox
- 261 -
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- 262 -
Figure 12: Top photo shows the cutting edge of the blade used in separating the long
bolt. Bottom photo shows damage to the anvil resulting from impact of the
blade after bolt separation.
- 263 -
Figure 13: Comparison of damage to the cutter blades used in separating the long and
short bolts. Blade used for the short bolt is missing more material (bottom
of each photo).
- 264 -
Figure 14: Bolt during impact of cutter blade at 0.4 msec in DYNA3D.
- 265 -
Figure 15: Fractured bolt configuration for finite element analysis.
- 266 -
u
o.
0
.0
r..
m_
0 It) 0 I,_ o (/)
0 I_ 1.0 C_l o I_ I.o C_l
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- 267 -
<,2
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-:/ooz
Abstract
This paper presents an analysis for pyrotechnic combustion and pin motion in the NASA
Standard Initiator (NSI) actuated pin puller. The conservation principles and constitutive
relations for a multi-phase system are posed and reduced to a set of eight ordinary differential
equations which are solved to predict the system performance. The model tracks the inter-
actions of the unreacted, incompressible solid pyrotechnic, incompressible condensed phase
combustion products, and gas phase combustion products. The model accounts for multi-
ple pyrotechnic grains, variable burn surface area, and combustion product mass flow rates
through an orifice located within the device. Pressure-time predictions compare favorably
with experimental data. Results showing model sensitivity to changes in the cross-sectional
area of the orifice are presented.
Introduction
Pyrotechnically actuated devices are widely used for aerospace applications. Examples
of such devices are pin pullers, exploding bolts, and cable cutters. Full-scale modeling efforts
of pyrotechnically driven systems are hindered by many complexities: three dimensional-
ity, time-dependency, complex reaction kinetics, etc. Consequently, simple models have
been the preferred choice of many researchers. 1'2'3'4 These models require that a number
of assumptions be made; typically, a well stirred reactor is simulated; also, the combustion
product composition is typically predicted using principles of equilibrium thermochemistry,
and the combustion rate is modeled by a simple empirical expression.
Recently, Gonthier and Powers s described a methodology for modeling pyrotechnic com-
bustion driven systems which is based upon principles of mixture theory. Though this ap-
proach still requires that simplifying assumptions be made, it offers a rational framework for
1) accounting for systems in which unreacted solids and condensed phase products form a
large fraction of the mass and volume of the total system, and 2) accounting for the transfer
of mass, momentum, and energy both within and between phases. The methodology was
illustrated by applying it to a device which is well characterized by experiments: the NSI
driven pin puller.
*Presented at the Second NASA Aerospace Pyrotechnic Systems Workshop, February 8-9, 1994, Sandia
National Laboratories, Albuquerque, New Mexico. This study is supported by the NASA Lewis Research
Center under Contract Number NAG-1335. Dr. Robert M. Stubbs is the contract monitor.
/Graduate Research Assistant.
tAssistant Professor, corresponding author.
269 -
The focus of this paper is on using the methodology presented in Ref. 5 to formulate a
pin puller model which additionally accounts for the flow of combustion products through
an orifice located within the device; the model is then used to determine the influence of
product mass flow rates on the performance of the device. The present model also accounts
for multiple pyrotechnic grains and variable burn surface area. The model presented in this
paper is an extension of the model presented in Ref. 5 which did not account for product
flow through the orifice, multiple grains, or variable burn surface area.
Figure 1 depicts a cross-section of the NSI driven pin puller in its unretracted state. 6
The primary pin, which will be referred to as the pin for the remainder of the paper, is
driven by gases generated by the combustion of a pyrotechnic which is contained within the
NSI assembly. Two NSI's are tightly threaded into the device's main body. Only one NSI
need operate for the proper functioning of the pin puller; the second is a safety precaution in
the event of failure of the first. The pyrotechnic consists of a 114 mg mixture of zirconium
fuel (54.7 mg Zr) and potassium perchlorate oxidizer (59.3 mg KCI04). Initially a thin
diaphragm tightly encloses the pyrotechnic. Combustion is initiated by the transfer of heat
from an electric bridgewire to the pyrotechnic. Upon ignition, the pyrotechnic undergoes
rapid chemical reaction producing both condensed phase and gas phase products. The
high pressure products accelerate the combustion rate, burst the confining diaphragm, vent
through the NSI port (labeled "port" in Fig. 1), and enter into the gas expansion chamber.
Once in the chamber, the high pressure gas first causes a set of shear pins to fail, then pushes
the pin. After the pin is stopped by crushing an energy absorbing cup, the operation of the
device is complete. Peak pressures within the expansion chamber are typically around 50.0
MPa; completion of the stroke requires approximately 0.5 ms. 6
For sufficiently high NSI assembly/gas expansion chamber pressure ratios (,,_ 2.0), and
for a fixed cross-sectional area of the NSI port, there exists a maximum flow rate of combus-
tion product mass through the port. The occurrence of this maximum flow rate is referred
to as a choked flow condition. Such a condition results in the maximum flux of energy
into the expansion chamber; the energy contained within the chamber can then be used to
perform work in moving the pin and can be lost to the surroundings in the form of heat.
However, if the time scales associated with the flux of energy into the expansion chamber
and the rate of heat lost from the products within the chamber to the surroundings are of
the same magnitude, there may be insufficient energy available to move the pin; functional
f_ilure of the device would result. Therefore, it is possible that variations in the flow rate
of product mass through the port may significantly affect the performance of the device.
Included in this report are 1) a description of the model including both the formula-
tion of the model in terms of the mass, momentum, and energy principles supplemented
by geometrical and constitutive relations and the mathematical reductions used to refine
the model into a form suitable for numerical computations, 2) model predictions and com-
parisons with experimental results, and 3) results showing the sensitivity of the model to
changes in the cross-sectional area of the NSI port.
Model Description
Assumptions for the model are as follows. As depicted in Fig. 2, the total system
is taken to consist of three subsystems: incompressible solid pyrotechnic reactants (s),
incompressible condensed phase products (cp), and gas phase products (g). The solid
pyrotechnic is assumed to consist of N spherical grains having uniform instantaneous radii.
The surroundings are taken to consist of the walls of the NSI assembly, the NSI port, and
- 270 -
.7. v,_1,_ . bridgewire
m,
oxp ion /
i _ charn_r__/ .....
NSI' _n
_N shear pin
NSI Assembly (1)
gas phase products (g)
condensed phase products (cp )
...... system boundary
Figure 2: Schematic of the two component system for modeling choked flow effects.
the gas expansion chamber. Both the NSI assembly and the gas expansion chamber are
modeled as isothermal cylindrical vessels. The gas expansion chamber is bounded at one
end by a movable, frictionless, adiabatic pin while the volume of the NSI assembly remains
constant for all time. The NSI port is assumed to have zero volume and is characterized by
its cross-sectional area.
Mass and heat exchange between subsystems is allowed such that 1) mass can be trans-
ferred from the solid pyrotechnic to both the condensed phase and gas phase products,
and 2) heat can be transferred from the condensed phase to the gas phase products. The
condensed phase - gas phase heat transfer rate is assumed to be sufficiently large such that
thermal equilibrium between the product subsystems exists. There is no mass exchange
between the system and the surroundings. Both product subsystems are allowed to interact
across the system boundary in the form of heat exchanges. The gas phase products are al-
lowed to do expansion work on the surroundings. No work exchange between subsystems is
- 271 -
allowed. Spatial variations within subsystems are neglected; consequently, all variables are
only time-dependent and the total system is modeled as a well-stirred reactor. The kinetic
energy of the subsystems is ignored, while an accounting is made of the kinetic energy of
the bounding pin. Body forces are neglected.
The rate of mass exchange from the reactant subsystem to the product subsystems is
taken to be related to the gas phase pressure within the NSI assembly, namely dr/dr =
-bP_, where r is the instantaneous radii of the pyrotechnic grains, t is time, Pgl is the
gas phase pressure within the NSI assembly, and b and n are experimentally determined
constants. All combustion is restricted to the burn surface of the pyrotechnic grains. In
the absence of burn rate data for Zr/KCI04, we have chosen values for b and n so that
pressure-time predictions of our model agree with experimental data. The equilibrium ther-
mochemistry code CET897 calculated for the constant volume complete combustion of the
Zr/KCI04 mixture is used to predict the product composition; the initial total volume
of the pin puller (0.95 cm 3) was used in this calculation since a significant portion of the
system mass is contained within the gas expansion chamber at the time of complete com-
bustion. The component gases are taken to be ideal with temperature-dependent specific
heats. The specific heats are in the form of fourth-order polynomial curve fits given by the
CET89 code and are not repeated here.
The rate of gas phase product mass flowing from the NSI assembly, through the NSI port,
and into the gas expansion chamber is modeled using standard principles of gas dynamics.
The flow of condensed phase product mass through the port is assumed to be proportional
to the gas phase mass flow rate. The only energy interaction between the NSI assembly and
the gas expansion chamber is due to the energy flux associated with the exchange of mass
between these two components.
Using principles of mixture theory, a set of mass and energy evolution equations can be
written for each subsystem contained within the NSI assembly and gas expansion chamber.
These equations, coupled with an equation of motion for the pin, form a set of ordinary
differential equations (ODE's) given by the following:
d
d--t(p''Vs, ) = -Ps,Abrb, (1)
d
d-t (Pcpl Vcm ) = 71cpp,_Abrb -- Chop, (2)
d
d-t (Pgl Vg_) = (1 - T/cv)Ps_ Abrb -- rag,
(3)
d
d-t (Psl Vsl esl ) = -Psi esl Abrb, (4)
£ (Pcm Vcp, ecm)= _lc,Ps, es, Abrb -- hop1 ?:crop- (2cp,g, + (2cm, (5)
dt
d
d--_
(pgxYg, egl) --- (1 - _lcp)psleslAbrb -- hg, mg + (2cp,g_ + Qg,, (6)
d
d-'t(Pep2 Vcp2) = fftcv, (7)
d
d-t (Pg2Vg2) = _g' (s)
- 272 -
d
yl = y. + y_ + ygl, (12)
V2 (t4)
% = A--p'
( 3v.
r[V.] = \_] , (15)
Nj
- 273 -
Ncp
N. . d
j=l
N_p . d
j=l ep dT_p i
N9
j=l
gg
ha 1 [Tgl] = _ YChJa [Tg,] , (26)
j=l
Nen . d
cvcva [T_n,] = E Y_ d--_-p_ (h{ptT_px]), (27)
j=l
c.1 =E j d
(28)
j=l
O_p,g,[Top,,
T.,]= hcv,gA_p, (Tcp, - rg,), (29)
¢¢°"'_=P_ dV2
-it ' (32)
Fp { 0Pax Ap if
if Pg_A
Pax Apv <
>__Fc,.it
Fc_it, (33)
\P92] \\P92]
< (34)
mz
"
mcp= ( 1 --
rJ--_P--
ticp )rhg. (35)
Here, and throughout the paper, braces [ ] are used to denote a functional dependence on
the enclosed variable. Equations (12-14) are geometrical constraints; in Eq. (14), Ap is
the cross-sectional area of the pin. Equation (15) is an expression for the radius r of each
- 274 -
st)herical pyrotechnic grain; N is the total number of pyrotechnic grains. The area of the
burn surface is given by Eq. (16); it is assumed here that the area of the burning surface is
the total surface area of the N pyrotechnic grains. Equation (! 7) is a thermal equation of
state for the gas phase products. Occurring in this expression are the gas phase pressure
Pg_, the gas phase temperature Tg_, and the ideal gas constant for the gas phase products R
(the quotient of the universal gas constant and the mean molecular weight of the product
gases). The pyrotechnic burn rate rb is given by Eq. (18).
Equations (19-21) are caloric equations of state for the solid pyrotechnic, condensed
phase products, and gas phase products, respectively. Here, Ts is the temperature of the
solid pyrotechnic, and Tcp_ is the temperature of the condensed phase products. Also, Y_,
YJp,, Y_, gs, Ncp, and Ng are the constant mass fractions and number of component species
of solid pyrotechnic, condensed phase product, and gas phase product species, respectively.
Here, and throughout the paper, the notation superscript "j" is used to label quantities
associated with individual chemical species. Since for both ideal gases and condensed phase
species, the internal energy is only a function of temperature, the specific heat at constant
volume for the solid pyrotechnic, Cvs, the condensed phase products, Cvcp_, and the gas
phase products, c.g_, can be obtained by differentiation of Eqs. (19-21) with respect to their
temperature. Expressions for the specific heats at constant volume are given by Eqs. (22-
24). The specific enthalpies for the condensed phase products and the gas phase products
contained within the NSI assembly are given by Eqs. (25) and (26), respectively. These
expressions can be differentiated with respect to their temperature to obtain the specific
heats at constant pressure cpcpl and cpgl, Eqs. (27) and (28).
Equation (29) gives an expression for the rate of heat transfer from the condensed
phase products to the gas phase products. In this expression, hcp,g is a constant heat
transfer parameter, and Acp_ is the surface area of the condensed phase products. The term
h_p,gA¢p_ is assumed large for this study. The functional dependencies of the heat transfer
rates between the surroundings and the product subsystems are given by Eqs. (30) and
(31). The functional form of these models will be given below.
Equation (32) models pressure-volume work done by the gas contained within the ex-
pansion chamber in moving the pin. Equation (33) models the force on the pin due to the
gas phase pressure and a restraining force due to the shear pins which _re used to initially
hold the pin in place. Here, Fc,.it is the critical force necessary to cause shear pin failure.
The work associated with shearing the pin is not considered.
The flow rate of gas phase product mass through the NSI port is given by Eq. (34). 8
Occurring in this expression are the cross-sectional area of the port, Ae, and the specific
heat ratio for the product gases contained within the NSI assembly, 7 (= cpgl/c_gl). This
expression accounts for mass choking at elevated NSI assembly/gas expansion chamber
pressure ratios. The condensed phase product mass flow rate through the port is given by
Eq. (35).
With the assumption of large heat transfer rates between the condensed phase and gas
phase product subsystems (i.e., hcp,gA_p_ ---*c_), the product subsystems remain in thermal
equilibrium for all time. Therefore, we take Tpl =- T_pl = Tgl and Tp_ =_Tcp2 = Tg_, with Tp_
defined as the temperature of the combined product subsystem contained within the NSI
assembly and Tp2 the temperature of the combined product subsystem contained within the
g.as expansion chamber. With this assumption, one can define the net heat transfer rates
Qp_ and (_p2 governing the transfer of heat from the surroundings to the combined product
- 275 -
subsystems:
(_p2 [Tp2] --- (_cp2 + (_g2 = hA_2 [Vs] (T_. - Tp2 ) + aA 2t-:] (37)
where
Mathematical Reductions
In this section, intermediate operations are described that reduce the governing equa-
tions to a final autonomous system of first order ODE's which can be numerically solved to
predict the pin puller performance. To this end, it is necessary to define a new variable V2
representing the time derivative of the gas expansion chamber volume:
dV2 (39)
V2 =- dt "
The final system consists of eight first order ODE's of the form
du
d-'_ = f (u), (40)
where u = (V2, Vs, Vcp,, pg,, Tp,, Vcp2, Tp2, V2) T is a vector of dependent variables and f is a
non-linear vector function. These eight dependent variables will be referred to as primary
variables. It will now be shown how to express all remaining variables as functions of the
primary variables.
Quantities already expressed in terms of the primary variables are the gas phase pressure
inside the NSI Pgl[Pg_,%_], the heat transfer rates Qp_[%I] and (_p2[V2,Tp2], the specific
internal energies ecp_ [Tp_] and eg_ [%_], the specific heats at constant volume c._ [Tp,] and
evg,[Tp,], the specific enthalpies h_[Tp,] and hg_[Tp_], and the specific heats at constant
pressure cp_p_[T_,,] and cpg,[Tp,]. Also, with a knowledge of Pg_, Eq. (18) can be used to
express rb as functions of pg_ and Tp_:
Addition of Eqs. (1), (2), (3), (7), and (8) results in a homogeneous differential equation
expressing the conservation of the total system's mass:
d
dt (p,Y, + pc_,Vcp, + pg, Vg, + pepVo, 2 + pg2Vg_) = O. (42)
Integrating this expression, applying initial conditions, denoted by the subscript "o", using
Eq. (12) to eliminate Va_ in favor of V1, V,, and Vc_,, using Eq. (13) to eliminate Va_ in
favor of V2 and Vep2, and solving for pa_ results in the following:
Pa_ [V2, V,, Vep,, Pa,, Vc_] = mo - p,V, - pcpVcp, - Pa, (V1 - V, - V_p, ) - pcpVcp: (43)
V2-
- 276 -
where
mo= psVso + pcpVcplo + pgloVglo + P_pVcp2o + Pg2oVg2o.
Here, mo represents the initial mass of the system. Substituting Eq. (43) into Eq. (17)
determines Pg2 as a function of the primary variables:
With a knowledge of Pg2, Eqs. (32), (33), (34), and (35) can be expressed in the following
forms, respectively:
(45)
(46)
(47)
,_ = ,_o_[v,,v,, vow1,
p,, ,T,, ,Vop,,T,,] . (48)
We next simplify the remaining mass evolution equations. Since both Ps and p_ are
constant, Eqs. (1), (2), and (7) can be rewritten as
dYs
------Abrb, (49)
dt
dY_______
= mo___ (51)
dt Pep
To simplify Eq. (3), we use Eq. (12) to replace Vg, in favor of Vs and Vcpl, use Eqs. (49)
and (50) to eliminate the resulting volume derivatives, and solve for the time derivative of
Pro:
/ / \ \
dPgl fitg
-- -- "" "_P " (52)
dt Vl - Vs - Vc,,,
The energy evolution equations will now be simplified. We first multiply Eq. (1) by es
and subtract the result from Eq. (4) to obtain
des
m _ 0o
dt
Thus, in accordance with our assumption of no heat transfer to the solid pyrotechnic, its
specific internal energy remains constant for all time. Integrating this result, we obtain
es=_so. (53)
Addition of Eqs. (5) and (6), and addition of Eqs. (9) and (10) result in expressions governing
the evolution of energy for the combined product subsystems contained within the NSI
assembly and gas expansion chamber, respectively:
d
--[pcpV_,ecn + pgz Vg, eg,] = psesAbrb - hcnfftcp - hg, mg + Qpl, (54)
dt
- 277 -
d [pcpV_p2ecp2
÷ pg2Vg2eg2]
= hcpz rhcp + hg, rhg + (2p2 - lfVo_t2. (55)
dt
The net heat transfer rates given by Eqs. (36) and (37) have been incorporated into these
expressions. Multiplying Eq. (2) by ecpl , multiplying Eq. (3) by egl, subtracting these
results from Eq. (54), using Eqs. (20) and (21) to re-express the derivatives in terms of Tpl ,
and solving for the derivative of %_ yields:
dTp, _ ps (e_ - rlcpecpl - (1 - rlcp) egl ) Ab rb -- ( h_p_ - ecpl ) rhcp -- ( hg_ - egx ) Cng + Q p,
dTp___z
= (hcp_- ecp2)¢n0p
+ (h_, - eg,)rhg + Qp, - ¢¢o_,_ (57)
dt p_V_1,
_ev_c_v_ + pg_ Vg_C_g_
Lastly, Eq. (11) can be split into two first order ODE's. The first of these equations is
given by the definition presented in Eq. (39). The second equation, obtained by using Eq.
(39) and the geometrical relation given by Eq. (14), is expressed by the following:
Equation (39), (49), (50), (52), (56), (51), (57), and (58) for a coupled set of eight
non-linear first order ODE's in eight unknowns. Initial conditions for these equations are
Results
Numerical solutions were obtained for the simulated firing of an NSI into the pin puller
device. The numerical algorithm used to perform the integrations was a stiff ODE solver
given in the standard code LSODE. The combustion process predicted by the CET89 chem-
ical equilibrium code followed the chemical equation given in Table 1. Parameters used in
the simulations are given in Table 2.
Predictions for the pressure history inside the NSI and the gas expansion chamber are
shown in Fig. 3. Also shown in this figure are experimental values obtained by pressure
transducers located inside the gas expansion chamber? A rapid increase in pressure is
predicted within the NSI assembly immediately following combustion initiation (t = 0
ms); the pressure continually rises to a maximum value near 195 MPa occurring near the
time of complete combustion (t = 0.023 ms). The pressure within the expansion chamber
increases more slowly due to mass choking at the NSI port. Following completion of the
combustion process, the pressure within the NSI assembly decreases to 53.9 MPa occurring
near t = 0.06 ms; during this same time, the pressure within the gas expansion chamber
uniformly increases to a maximum value of 53.4 MPa. There is a subsequent decrease in
- 278 -
both pressures- to values near 22.5 MPa at completion of the pin's stroke (tst = 0.466 ms).
These decreases in pressure result from work done by the product gases in moving the pin
and heat transfer from the combined product subsystems to the surroundings.
Figure 4 shows the predicted temperature history for the combustion products contained
within the NSI assembly and the gas expansion chamber. Since the only energy exchange
between subsystems contained withifi these two components is due to the flux of product
mass through the NSI port, the resulting temperatures of the combined product subsystems
do not thermally equilibrate. Figure 5 shows the predicted density history for the gas phase
products inside the NSI and the gas expansion chamber. As a consequence of the product
temperature difference, a significant difference in gas phase density is also predicted.
The predicted velocity history of the combustion products flowing through the NSI port
is given in Fig. 6. Here, a rapid rise in velocity to a maximum value near 928 m/s is predicted
immediately following combustion initiation; during this time, the flow through the port
becomes choked. The flow remains choked as the velocity slowly decreases to 830.3 m/s.
Subsequently, there is a rapid decrease in velocity to a minimum value of approximately
7 m/s ocurring at t = 0.63 ms. This rapid decrease in velocity occurs as the pressures
within the NSI assembly and the gas expansion chamber equilibrate following completion
of the combustion process. As the pin retracts, gases within the expansion chamber expand
creating a slight pressure imbalance across the NSI port; consequently, the velocity of the
flow begins to slowly increase to a value of 23 m/s at completion of the stroke.
Figure 7 shows the time history of the predicted pin kinetic energy. A continual increase
in kinetic energy to a maximum value of approximately 31.4 J at completion of the stroke
is predicted. This value compares to an experimentally measured value of approximately
22.6 J. The larger value for the predicted kinetic energy is consistent with the fact that
frictional effects, which would tend to retard the motion of the pin, have not been accounted
for in the model.
Figure 8 gives results showing the sensitivity of the model to changes in the NSI port
cross-sectional area, A_. For this study, we use the predicted pin puller solution as the
baseline solution (baseline parameters given in Table 2). The sensitivity of the model is
determined by solving the pin puller problem and finding the parametric dependency of
three predicted quantities: the pin kinetic energy at completion of the stroke, the stroke
time, and the maximum pressure attained within the NSI assembly. Quantities presented
in this figure have been scaled by values obtained from the pin puller simulation presented
above. For decreasing values of Ae, pin kinetic energy decreases while both the stroke time
and maximum pressure within the NSI increase. These results are primarily due to smaller
mass flow rates through the port resulting from decreasing port cross-sectional areas. For
slightly larger values of Ae, both the stroke time and the pin kinetic energy approach a
nearly constant value while the peak pressure within the NSI decreases.
Conclusions
The model presented in this paper is successful in predicting the dynamic events asso-
ciated with the operation of an NSI driven pin puller. In addition to tracking the interac-
tions between the reactant and product subsystems, the model also accounts for multiple
pyrotechnic grains, variable burn surface area, and combustion product mass flow rates
through the NSI port. ttesults of a sensitivity analysis reveal that variations in the cross-
sectional area of the port may significantly effect the performance of the device. Specifically,
significant decreases in the pin kinetic energy result from decreases in port cross-sectional
- 279 -
area. In the presence of friction, the smaller kinetic energy of the pin may be insufficient to
overcome frictional effects resulting in functional failure. Decreases in cross-sectional area
may arise from the partial blockage of the NSI port by foreign matter or by the accumula-
tion of condensed phase combustion products. Moreover, it is possible that the very high
predicted pressures within the NSI assembly resulting from decreasing port cross-sectional
areas may be sufficient to cause structural failure of the NSI's webbing, thereby jamming
the pin and preventing it from retracting. Such structural failures have been reported in
the past. 6
References
aRazani, A., Shahinpoor, M., and Hingorani-Norenberg, S. L., "A Semi-Analytical Model
for the Pressure-Time History of Granular Pyrotechnic Materials in a Closed System,"
Proceedings of the Fifteenth International Pyrotechnics Seminar, Chicago, IL, 1990, pp.
799-813.
2Farren, R. E., Shortridge, R. G., and Webster, H. A., III, "Use of Chemical Equilibrium
Calculations to Simulate the Combustion of Various Pyrotechnic Compositions," Proceed-
ings of the Eleventh International Pyrotechnics Seminar, Vail, CO, 1986, pp. 13-40.
3Butler, P. B., Kang, J., and Krier, H., "Modeling of Pyrotechnic Combustion in an Automo-
tive Airbag Inflator," Proceedings - Europyro 93, 5e Congr_s International de Pyrotechnie
du Groupe de Travaile de Pyrotechnie, Strasbourg, France, 1993, pp. 61-70.
4Kuo, J. H., and Goldstein, S., "Dynamic Analysis of NASA Standard Initiator Driven Pin
Puller," AIAA 93-2066, June 1993.
SGonthier, K. A., and Powers, J. M., "Formulation, Predictions, and Sensitivity Analysis of
a Pyrotechnically Actuated Pin Puller Model," Journal of Propulsion and Power, accepted
for publication, 1993.
6Bement, L. J., Multhaup, H. A., and Schimmel, M. L., "HALOE Gimbal Pyrotechnic Pin
Puller Failure Investigation, Redesign, and Qualification," NASA Langley Research Center,
Report, Hampton, VA, 1991.
7Gordon, S., and McBride, B. J., "Computer Program for Calculation of Complex Chem-
ical Equilibrium Compositions, Rocket Performance, Incident and Reflected Shocks, and
Chapman-Jouguet Detonations," NASA Lewis Research Center, SP-273, Cleveland, OH,
1976.
SFox, R. W., and McDonald, A. T., Fundamentals o/Heat and Mass Transfer, 3 rd ed. John
Wiley and Sons, Inc. 1985, pp. 599-617.
9Bement, L. J., private communication, NASA Langley Research Center, Hampton, VA,
1992.
- 280 -
Table 1: Stoichiometric equation used in pin puller simulations.
parameter value
_ep 0.43
N 100
A_ 0.100 em 2
Ap 0.634 cm 2
A1 0.634 cm 2
v1 0.125 ¢m 3
Ps 3.57 g/cm 3
Pep 5.89 g/em 3
Ts 288.0 K
T_ 288.0 K
h 1.25X 106 g/s3/K
E 0.60
Ot 0.60
Fcrit 3.56X 10 r dyne
b 0.003 (dyne/cm2)-°'_°em/ s
n 0.60
V2o 0.824 em 3
V_o 0.038 em 3
Vcpl o 7.425x 10 -8 cm 3
- 281 -
200 ,,,,...,,i,,,,0,,,,i.,,,,,,,,|,.,,,.,,,i,,,,,,,.,|,,,.,,,,,
-- predicted result
--O-- experimental result
150
Pgl
_,_ 100
5O
<> o
o <> ,o
J , , J , , , I J J , , , , , , , I J , , , , , ,, , I , , , , , i m t i J i i , i i i i i J
Figure 3: Predicted and experimental pressure histories for the pin puller simulation.
'''''''''l'''''''''l'''''''''l''''''''']'''''''''['''''''''
6000
4000
2000
t (ms)
- 282 -
0.30 "''''''''1 ..... ''''1'' ....... I .... '''''1'''''''''1''''''''
0.25
0.20
-..,....
P_
,_ 0.15
(D_
0.10
0.05
0.00
/
-0.10 0.00 O. I0 0.20 0.30 0.40 0.50
t (ms)
800 i
6OO
400
200
l (ms)
Figure 6: Predicted velocity of the flow through the NSI port for the pin puller simulation.
- 283 -
3O
10
Figure 7: Predicted kinetic energy of the pin for the pin puller simulation.
P-I
¢o
0 i i i i r i i i J i L i i i i i _ i
Figure 8: Sensitivity of the model to changes in the NSI port cross-sectional area. The
values presented in this figure have been scaled by the gaseline values A_ = 0.10 cm2_
- 284 -
$.%
/4 /I
FINITE ELEMENT ANALYSIS OF THE SPACE SHUTTLE
2.5-INCH FRANGIBLE NUT
Darin N. McKinnis
NASA Lyndon B. Johnson Space Center, Houston, TX
- 285 -
to determine the hardening constant,
The first part of this paper A, and hardening exponent, n. (_ is
discusses the material
the effective stress, (_ys is the
characterization process necessary
yield strength, Ep is the equivalent
for an accurate analysis. The second
part of this paper discusses the plastic strain, and ELis the Luders
structural analysis and design strain. Inconel displays no Luders
changes to the nut which were strain so this term can be
analyzed with comparison to test considered zero. Ep should be
results. The third part of this evaluated according the Heavyside
paper briefly describes other function, designated by the
devices which are being analyzed brackets, i.e. zero if its value is
with this process. negative.
- 286 -
The yield stress and elastic modulus rerun. New post processing commands
from the tensile test, and the are all that is required. PRONTO's
calculated values of tearing designers also anticipated the need
parameter, hardening constant (A) for alternative constitutive models
and hardening exponent(n) are and tearing parameter formulations
necessary to define Inconel 718 for to meet the needs of the specific
the structural analysis to follow. problem. And PRONTO supports post
The only other data required is the processing to permit reformulation
Poisson's ratio and density. These of the tearing parameter if desired.
are all the parameters required by
PRONTO's constitutive model for this However, NASA-JSC sought the ability
analysis. to visualize in real-time the death,
or failure, of material based on the
To confirm the results of the curve tearing parameter. PRONTO supported
fit and JAC2D analysis, the JAC2D adaptive or real-time death for
results can be plotted against the energy, Vonmises stress, pressure,
original tensile test data. If and other variables but not the
necessary, adjustments in A and n tearing parameter. Therefore, the
can then be made and another JAC2D tearing parameter selected to
analysis can be run until the describe failure of the Inconel 718
analysis and tensile test agree. The in the 2.5-inch frangible nut was
tearing parameter can then be added to the elastic/plastic power
reevaluated. When the analysis and law hardening material model of
test agree, the material PRONTO specifically for this
characterization process is complete application. This new constitutive
and the structural analysis can be model, the power law hardening
conducted on the 2.5-inch nut with strength model, was based on the
the PRONTO program. elastic/plastic power law hardening
material model. The elastic/plastic
Selection of the Tearina Parameter power law hardening material model
Failure Definition used by PRONTO was documented by
- 287 -
sensitivity of the nut to various demonstrated in test and repeated by
geometrical factors. The finite the analysis. The outer notch depth
element mesh currently being used is was reduced to 0.075 in the -302
shown in figure 5. The slight configuration of the nut which is
differences between this mesh and the current flight configuration.
the mesh used in phase I of the
analysis are described later in this Although testing preceded analysis,
paper. Figure 6 shows in detail the the analysis showed two
side of the nut with a booster disadvantages to decreasing the
included where detonation will be outer notch depth: reduction in
modeled. The following changes in delivered energy to the nut from the
the nut geometry were analyzed to booster and increased time until
determine the effect on nut separation. Reducing the outer notch
separation: radial gap between the depth the nut causes web i, the
booster cartridge material and the first web to fail, to fail earlier
nut, outer notch depth of the nut, in time, before all the energy of
as shown in figure 7, and the the booster can be imparted to the
booster aspect ratio. The results nut. The analysis showed this loss
were reported by K. E. Metzinger 5. to be small but significant if the
outer notch depth is not properly
Radial gap between the booster and sized. An outer notch depth of 0.153
the nut is limited to 7 mil maximum inches was actually shown to be less
by the tolerances on the nut and likely to separate than either a
booster. The analysis and tests larger notch, 0.303 inches, or a
agree that minimizing the gap as smaller notch, 0.018 inches. The nut
much as possible, including the use has not yet been designed to the
of grease, is beneficial. Analysis optimum notch size. Further analysis
shows the benefit is greatest in will be required to determine the
reducing gap from 7 mil to 4 mil, 5 optimum size of the outer notch
times greater than from 4 mil to 2 depth to ensure separation.
mil. The advantage of reducing gap Furthermore, the increased rotation
from 4 mil to 2 mil is the same as permitted by the smaller notch depth
from 2 mil to 0.5 mil. This suggests causes the nut to fail later in
that tightening tolerances on the time, in general. Although this is
part to reduce gap probably would not a concern in the current design,
not be cost effective beyond 4 mil. this factor may be important in
Reduction of gap from 2 mil to 0.5 applications with smaller tolerances
mil through the addition of grease, in separation time.
epoxy, or other agents would
probably not justify the added Booster aspect ratio is defined as
complexity and cost of such a the diameter of the charge over the
change. length of the charge. It was
proposed that increasing the aspect
The outer notch depth of the nut has ratio would increase the effect
also been shown to be a factor in impulse delivered by the booster to
nut separation. The original flight the nut, with no additional RDX.
configuration of the 2.5-inch Considerable energy was being lost
frangible nut had an outer notch or underutilized because it was
depth of 0.303 inches. Reducing the located at or below the bottom of
the webs of the nut and the
depth from 0.303 to 0.018 allows the
nut halves to rotate further about separation was thought to be
the fourth web, from approximately progressing in zipper fashion, from
25 degrees to over 60 degrees. the top of the web toward the
Without a reduction, the corners of bottom. The advantage of increased
the nut at the outer notch pinch aspect ratio was demonstrated in
together, resulting in energy lost tests and analysis. As a result,
to compressive plastic strain. • NASA-JSC has modified the booster
Rotation of the halves places the from the -401 configuration to the
elements of the fourth web, the last -402 configuration as shown in
web to fail, under increasing figure 3 for all future production
tension. Increased tension means of the booster.
increased tearing values in those
elements and improved likelihood of
failure. This change was first
- 288 -
Structural Analysis - Phase II so that design changes or
A Copper Booster variability between production lots
of Inconel 718 could be compared
A second phase of analysis was
.quantitatively. Qualitative accuracy
conducted in September 1992 to study
had already been demonstrated in the
the effect of changing the booster
earlier analyses. To provide
cartridge material from stainless
steel to copper. This study is quantitative accuracy in the
analysis it would be necessary to
briefly documented by K. E.
perform material characterization,
Metzinger in a memo to D. S.
as previously described, for
Preece 6 . This study showed that a
different lots of Inconel 718 and
copper booster would absorb less
correlate test performance with the
energy in expanding within the
analysis.
booster port of the nut, making more
energy available for nut separation. The selected lots were HSX and HBT.
A nut would thus be more likely to
It had been shown in earlier actual
fracture with a copper booster than tests that these two lots of Inconel
with a stainless steel booster, as
718 had significantly different
shown in figure 8. characteristics based on their
performance. No HBT nut has ever
The analysis also showed that the
separated completely using the -401
NASA Standard Detonator (NSD), the
booster, while no HSX nut has ever
initiating charge of the booster, is
failed to separate with a -401
capable of blowing the top of the
booster. The analysis had to show
booster off and allowing the booster
that HBT would not separate and HSX
pressures to vent. This is confirmed would not.
by tests in which the booster top
consistently separates from the
The first step was to conduct a
assembly. Analysis showed that a material characterization of HSX and
copper booster would vent earlier
HBT, then a structural analysis with
than a stainless steel booster and
the calculated material properties.
the existing design does not permit
The tensile test data for HSX and
strengthening in the area of
HBT is shown on figure i0.
fracture to prevent venting.
However, venting is not considered
The model accurately predicted 'that
to be a major concern as the HSX nuts would be much easier to
analysis showed that the impulse fracture than HBT nuts.
delivered from the booster to the
Significantly different tearing
nut precedes the loss of the booster
parameters, 0.345 for HSX and 0.675
top. for HBT, indicated this trend.
However, structural analysis
Unfortunately, copper has known conducted on HSX nuts failed to
compatibility problems with RDX. So simulate a nut which completely
a copper booster is not feasible.
separated. Clearly the model was not
Testing has confirmed the analysis
yet quantitatively accurate. Since
results by using modified stainless the material characterization
steel boosters, outer diameters
process with JAC analysis appeared
machined down and copper sleeves
sound, geometry and other
inserted over the stainless steel,
characteristics were evaluated to
shown in figure 9. These boosters
increase the accuracy of the model
were successful in every test.
and simulate a separating HSX nut.
Although these modified boosters Three factors were found to increase
have not been accepted for use in
accuracy of the model: the addition
flight at this time, they have an of a simulated bolt, increasing the
advantage over a pure copper booster
granularity of the mesh in the webs,
in that they would not increase the
and increasing the number of points
generation of shrapnel or increase used to initiate detonation of the
venting because the top of the
explosive.
booster is unchanged from the flight
boosters, solid stainless steel. One of the refinements was that the
number of elements in the webs was
Structural Analysis - Phase III
increased slightly. This is done by
Refinina the Model remeshing the nut's geometry. This
In 1993 the goal of the analysis was reduces the size of the average
to improve the accuracy of the model
- 289 -
element in the web area of the nut. the addition of contact surfaces.
In PRONTO, the tearing parameter The number of elements added was
must be exceeded for the entire kept to a minimum by treating the
element for failure of that element bolt as a perfectly elastic pipe.
to occur. A smaller element is thus
more likely to fail due to localized The simulation of an HSX nut with
increases in tearing parameter. these changes resulted in a
Reducing average element size separating nut, failure of all four
increases the number of elements webs. Even with the changes which
which increases output file sizes resulted in more energy to the nut
and run times. Smaller elements also and easier fracture, HBT nuts did
require smaller time steps, further not separate, still in agreement
slowing model processing. Thus this with tests. This study was
step, while increasing accuracy, documented in an SNL report 7 .
increases run times, a common
problem in finite element analysis. Future Studies of the 2.5-inch Nut
A tearing parameter is used to
To increase accuracy of the model, determine when the Inconel 718
the explosive material was provided material would fail. It has been
with more initial detonation points. proposed that the stainless steel of
The original model had a single the booster should also be allowed
detonation point at time = 0. From to fail using a tearing parameter
this point the detonation wave was calculated by a JAC analysis. Even
calculated to spread throughout the if the stainless steel is not
RDX. Ten detonation points were permitted to fail, performing a JAC
added to the model, each simulating analysis, including a tensile test,
detonation at time=0. Thus the
should enhance the model's accuracy.
detonation of all the RDX occurs in
Modeling conducted to date has not
a more even distribution and shorter included material characterization
time period. This produces slightly of stainless steel as was done for
more output from the explosive and the Inconel 718. NASA-JSC is
simulates a mature detonation wave
currently conducting tensile testing
as opposed to an initiating charge. of stainless steel samples from
This change did not require booster lots to perform this
remeshing and was very easy to analysis.
implement.
One geometrical design consideration
A bolt was inserted into the hole of which has not been modeled is the
the nut. The addition of the bolt is
application of a backing plate or
significant to the separation of the
washer to the nut. During testing
nut, critical in some borderline this was shown to have significant
cases, according to the analysis. effect on the separation of the nut,
Figure II shows the nut opening for overshadowing most other variables.
2.5 mil radial gap and 4.5 mil Nuts without the backing plate, were
radial gap HSX nuts. The 4.5 mil nut not as likely to separate. However,
is opening similarly to the 2.5 mil to include the backing plate the
nut until about 2 milliseconds. At model must be converted into three
that point opening has stopped and dimensions. NASA-JSC plans to
the nut is beginning to close down. conduct these analyses in 1994.
However, at 3.5 milliseconds the nut NASA-JSC will probably run this
which is moving to the left impacts analysis on their Cray to handle the
the stationary bolt. The impact significant increase in the number
provided the necessary energy to of elements necessary to conduct
complete the failure of web 4 and this analysis.
separation. At this time there is no
experimental data to confirm this Structural Analysis and Material
effect. However, testing is Characterization Conclusions
typically conducted with a bolt and
The most significant conclusions
no pre-load and should be included
from the analysis performed on the
in the analysis. The effect of
2.5-inch frangible nuts are as
threads is not considered in the
follows:
analysis. This change requires
remeshing, the addition of a new
A. Radial gap between the booster
material elastic Inconel 718, and
and the frangible nut is an
- 290 -
important dimension. This gap should Training in the use of these codes
be minimized if complete separation has been provided. This methodology
is desired. can now be used by NASA-JSC in
several ways.
B. The energy absorbed by the
stainless steel booster is Analysis can be conducted on new
significant. Switching from an all production lots of Inconel 718.
stainless steel cartridge to a Inconel 718 lots which possess
cartridge of reduced diameter and material properties and tearing
the addition of a copper sleeve parameters outside of acceptable
should increase the impulse limits can be rejected before
delivered to a nut. An all copper expensive machining and acceptance
booster housing is not recommended testing is conducted.
due to compatibility issues between
copper and RDX. However, a hybrid Analysis can be conducted on sample
booster made of stainless steel with lots of Inconel 718 to determine the
a copper sleeve has been shown in effect of various heat treatment
test to be effective. procedures on the microstructure.
This approach will suggest measures
C. Reduction in area obtained from a to further control the forging
tensile test of an Inconel 718 process.
sample is significant. Reduction in
area is a significant factor of the Analysis can be conducted to
tearing parameter. Inconel with a quantify the effects of proposed
relatively small reduction in area design changes before manufacturing
will be easier to break. and testing is initiated. Analysis
could also be used to establish the
Other ADDlications design margin of the current
NASA-JSC is currently pursuing configuration or select a more
analysis models of the Space Shuttle meaningful design margin criteria.
3/4-inch frangible nut, the Currently design margin is
Super*Zip linear separation system, determined by increasing the web
and a JSC-designed explosive bolt thickness to 120% of the maximum
utilizing the NASA Standard allowable, as shown in figure 14.
Detonator (NSD) as the actuating This choice for margin demonstration
charge. These models can use the is not ideal. It is unlikely that
same process as was used for the the web thickness will be
2.5-inch frangible nut with slight incorrectly manufactured and that
variations. this error will be overlooked in
acceptance inspections. Furthermore,
The mesh for the explosive bolt no additional information beyond
model is shown in figure 12. Six separation versus failure to
prototype explosive bolts have been separate is obtained. It has been
fired to date. Agreement with the suggested that velocity of the nut
analysis has been excellent. The halves as the nut separates would be
analysis has provided design a better demonstration of margin
modifications which will be used to where failure to separate provides a
slightly change the separation plane velocity of zero. At this point,
and ensure positive retention of the test methods including breakwires
bolt in its confining washer. and high-speed photography are being
used to determine the velocity of
The mesh for the Super*Zip linear nut halves for comparison with the
separation system model is shown in analysis.
figure 13.
The test and analysis methodology is
Conclusions general enough that it can be
The test and finite element analysis successfully applied to other
methodology developed by SNL and mechanical devices and design
NASA-JSC has been successfully problems. NASA-JSC is currently
demonstrated. This methodology pursuing analysis models of the 3/4-
requires the use of SNL developed inch frangible nut, the Super*Zip
software which has been successfully linear separation system, and a
transferred, with substantial NASA-JSC designed explosive bolt
assistance from SNL, to NASA-JSC.
- 291 -
utilizing the NSD as the actuating modeling. The author also wishes to
charge. thank Carl Hohmann, NASA-JSC, who
recommended many of the design
References modifications and variables which
1 . Investigation of Failure to were studied and supported the
Separate an Inconel 718 interpretation of the analysis.
Frangible Nut, William C.
Hoffman, III, and Carl Hohmann,
NASA Lyndon B. Johnson Space
Center, Houston, TX.
3 . A Vectorized Elastic/Plastic
Power Law Hardening Material
Model Including Luders Strain,
Charles M. Stone, Gerald W.
Wellman, Raymond D. Krieg,
Sandia National Laboratories,
Albuquerque, New Mexico, SAND90-
0153, March 1990.
7 ° Structural Analysis of a
Frangible Nut Used on the NASA
Space Shuttle, Kurt E.
Metzinger, Sandia National
Laboratories, SAND93-1720,
November 1993.
Acknowledaments
The author wishes to acknowledge the
work of D.S. Preece and Kurt E.
Metzinger, Sandia National
Laboratories, Albuquerque, New
Mexico, in model generation, initial
modeling and analysis, and in
technical support for NASA-JSC
- 292 -
.70
r----- r------
.60 -.
.so -
.40 -
ORBITEFVMTERNALTANK
/ N .30 -
.20 -
.5-INCH FRANGIBLE NUT
-10 -
.oo -
F R A N G I F WEBS 2.0 -
A 7
1.0 -
AJ
Figure 2. Top view and side view of the Figure 5. 2.5-inch frangible nut mesh.
2.5-inch frangible nut.
c W
- 293 -
c
_--------__
--------___
./ i RDX
SECTION A
cilhr Copper sleeve
Figure 7. Outer notch depth of the nut. Figure 9. Stainless steel booster and
stainless steel booster with copper
sleeve.
250x1 0"
200
1
-
Typical Tensile Test Data for Inconel 718 Lots HBT and HSX
(.005/min strain rate)
Figure 10. Tensile test data f o r Inconel 718 lots HBT and HSX
- 294 -
-301 FRANGIBLENUT WEBS
-0.1 I
0.0
. - .
1.o
,..
2.0
I .. . 1
3.0
__. 4.0
L * I
50
Time (ms) -101, -102 MARGIN NUT WEBS
Figure 11. Nut opening as a function of Figure 14. Web dimensions for
gap 2.5-inch frangible nuts, -301
flight configuration, and -101 and
-102 margin configurations.
Confining washers
.ation plane
explosive charge
- Aluminum doublers
- 295 -
ANALYSIS OF A SIMPLIFIED FRANGIBLE JOINT SYSTEM
Steven L. Renfro
The Ensign-Bickford Company
Simsbury, CT
James E. Fritz
The Ensign-Bickford Company
Simsbury, CT
- 297
model, simple one-dimensional by The Ensign-Bickford Company to
hydrodynamic analysis is used. solve problems involving explosively and
pryotechnically loaded structures. This
For a one-dimensional Lagrangian model, paper represents the first time this
a cylindrical geometry was assumed. technique used input developed by a one
The SIN 1 hydrodynamic code was used dimensional hydrodynamic analysis code.
to solve conservation equations of
momentum, mass, and energy. In Model Development
order to use this information as input for
the finite element model, individual or Using the SIN analysis, the critical areas
groups of cells were monitored to were determined for input into the
develop input equations for the finite ANSYS 5.0 model. The timing and
element calculations. reaction of the shock waves incident and
reflected from the interior steel wall result
Since the hydrodynamic analysis is one in two distinct types of relationships, both
dimensional, it limits the amount of of which are decaying sinusoidal
understanding developed regarding the functions.
specific stress state existing in the
aluminum. Peak stress locations and The area of the stress riser has extremely
probable points of secondary failure high initial amplitude which rapidly
cannot be determined, and assumptions decays. This is consistant with the
must be made for the stiffness and geometry present at this location. A thin
response characteristics. A two layer of elastomeric material and a thin
dimensional hydrodynamic analysis aluminum section bounding the steel do
would assist in understanding these not support reflected pressure waves as
effects, but such analysis is time well as the thicker off axis areas.
consuming, and requires access to Basically, the initial detonation front
sufficient hardware and software experiences a rapid ring down within the
resources. Also, the hydrodynamic wall of the steel tube. The inside surface
model is unable to account for a wide of the steel responds approximately as
range of thermal loads and structural illustrated in Figure 2.
preloads in the parts, and cannot be
used to evaluate stresses in the part due The second input function used is from a
to events other than the explosive cross section at 45 ° from the stress
loading (i.e., flight loads, thermal riser. This relationship was similar in
response, assembly loading). frequency to Figure 2 with a much lower
initial amplitude. Figure 3 shows this
To understand the dynamic response of relationship.
the frangible joint, an ANSYS 5.0 finite
element model was created for use in a A logical choice for a third function is 90 °
non-linear transient analysis. This to the separation plane. Most frangible
analysis was used to determine the joint designs use air gaps combined with
dynamic response of the aluminum when thin silastic sections to control position of
subject to transient loads driving the the MDF and to allow easy installation. If
material above its yield strength. This no air gaps are assumed, the resulting
methodology had been successfully used function resembles the data in Figure 3
- 298 -
with lower amplitude. Introducing the air achieved using the Modified Newton-
gaps increases the difficulty of the Raphson method, based on a Von-Mises
hydrodynamic analysis without any real yield criterion. For the transient portion
benefit. This third function was therefore of the analysis, the Newmark time
not used for this simplified approach. integration scheme is ut_Trz.ed, using
Rayleigh damping with only mass matrix
The source explosive used for this contributions (Beta damping). This
particular design is HNS-IIA. The applied damping is necessary in order to
equation of state for HNS is not currently provide stability of the solution.
available as part of the SIN database. However, a Beta term is chosen which
Alternate explosive materials were used ensures a low level of damping (0.05% or
to bracket the response of HNS. The less) above 10,000 Hz.
density, chemistry, detonation velocity,
and Chapman-Jouget pressure were For the initial time steps, the symmetry
matched as closely as possible with constraints are applied to both the top
candidate materials from the SIN notch and the flange edges of the model.
database. Table 1 lists the explosives When sufficient stress levels are
used and their properties compared to determined in the notch to induce section
HNS. failure, this symmetry constraint on the
notch is removed and the leg of the
To simplify the ANSYS model geometry, section is allowed to bend up and away
symmetric constraints are used along the from its initial position. This is done to
notch edge and one half of the joint simulate proper function of the joint
mounting flange. The length of the during the explosive event.
flange was shortened to reduce the
number of degrees of freedom which Results of Finite Element Model
needed to be incorporated into the
model. This model is shown in Figure 4. As part of the preliminary work
performed using this model, simple static
The transient loads are applied as stress analysis (linear and non-linear) as
pressure pulses along the interior of the well as modal analysis were performed to
aluminum. These loads have the same verify model integrity and to learn about
time profile as that predicted by the one the basic structural characteristics of the
dimensional hydrodynamic analysis, model. Some important data was
however input pressure amplitudes are gleaned from these runs, including the
reduced to achieve numerical stability. presence of a potential plastic hinge near
Unfortunately, this assumption is the flange region of the aluminum
required, although it is expected that the structure. Additionally, the modal runs
results still allow development of an showed that the aluminum had its
understanding of the aluminum response. second, third, and fourth normal modes
The aluminum material (6061-T6) was between 50 and 200 kHz. This was
assumed to act in an elastic-perfectly important information, since it showed
plastic manner. That is, once the yield that the aluminum is capable of dynamic
strength of the material is exceeded, no elastic structural response near the input
additional load can be supported by that frequency of the shock pulse. The 2 °d,
material. Plastic convergence is 3 rd,and 4'", mode shapes are shown in
- 299 -
Figure 5. of the flange wall. It is interesting to note
that a plastic hinge develops in the bend
Once the simpler analysis had been run region of the aluminum leg. This hinge
and verified with hand calculations, the location corresponds well to explosive
more complex non-linear transient over tests where a section of the
analysis was run. The input pulse was aluminum became a flyer.
characterized as a shock pulse with a 1.5
#sec rise and a 1.5 #sec decay at the Finally, at 24 #sec, the leg has plastically
notch location. The magnitude of this deformed over its entire length, a plastic
pressure pulse was chosen to remain hinge occurs near the top of the
slightly below the yield point of the extrusion, and model convergence is no
material (approximately 36 ksi) to avoid longer possible using the elastic-perfectly
model stability problems. As noted plastic static strength allowable. The
above, this assumption needed to be predicted deflection at this time is 0.103
made, however; much information about inches. For the actual hardware, it would
the dynamic response of the structure be expected that energy would be
was still learned. expended by bending at the plastic hinge
until the impulse had been dissipated.
The final results are illustrated in Figure
6. During the rise time of the initial Discussion
pressure pulse, the structure cannot
significantly respond to the high The aluminum is capable of responding
frequency input. The structure simply to the input shock pulse in the 2 to 3
transmits the shock wave through the #sec regime, suggested by the modal
material thickness. By the time the pulse analysis and supported by the transient
is damped, the structure begins to analysis. At approximately 3 /_sec after
significantly respond, and peak stresses the shock pulse has arrived at the interior
in the notch exceed the allowable of the aluminum stress riser, failure at the
material strength. A plastic condition groove is expected to occur. There
through the wall is reached. It is at this remains sufficient energy to severely
time that separation occurs, and the deform the legs once the failure at the
symmetric boundary condition along the stress riser has occurred. A secondary
notch edge is removed. After this time, plastic hinge forms at the bend joint near
the load is no longer applied and the the mounting flange for this particular
inertial loads of the aluminum leg are all design.
that is left driving the deflection.
Obviously, the loading assumption is The aluminum cross section is very
somewhat non-realistic; the shock wave efficiently dissipating the applied impulse
applied to the aluminum will continue once the stress riser failure occurs. In
along the inner wall even after separation other words, plastic stresses do not
has occurred. localize and exist over much of the inner
and outer surfaces of the aluminum.
After this, the frangible joint is behaving
as a cantilever beam with a fixed edge All of these discussion items show good
along the mounting flange. A plastic agreement with test specimen articles.
zone develops along much of the length No failures of this particular joint have
- 300 -
occurred which would disagree with the References:
conclusions of this analysis.
1) Charles L. Mader; Numerical Modelinq of
Detonations; University of California
The hydrodynamic analysis would Press; 1979; pp. 310 - 332.
provide much better resolution if a two
dimensional model were used. Digital 2) B.M. Dobratz; LLNL Explosives
resolution of individual cell results could Handbook; UCRL-52997,
be used as forcing function for the finite
element techniques.
- 30i -
Figure 1 Frangible Joint Before and After Function
- 302 -
0.09
0.08-
0.07-
o.o6-
0.05 -
0.04-
r_
0.03-
0.02-
._ 0.01-
o.
-0.01
0 5 10 15 20 25
Time From Detonation of MDF (usec)
- 303 -
0.02
o ......................
"t-
!
..........
!
........
O.01-
0.005-
o
_0 0-
"6
_ -0.005-
-0.01 t i I , i , ,
0 10 20 30 40
Time From Detonation of MDF (usec)
- 304 -
,_.=.._ , ,,( '¥,
, _ i , 4
',,"', ',. ,l.-.-"
' I
, rT ?
' ,-, I ',
- 305 -
L
MODE 2 MODE3 MODE 4
52.827 HZ 102.348 HZ 154.759 HZ
- 306 -
FEB 7, g4
8:08:03
NODAL SOLUTION
STEP=3
SUB =58
TIME=. 140[-04
SEW (Ave)
DIP( =. 103887
$ml =506.504
SPIX =37ZZ4
A =0
B =3650
C =7300
D =10950
E =14600
F =18250
6 =Z1900
=Z5550
J =32650
K =36500
- 307 -
Table 1. Explosive Properties Used to Bracket HNS Performance 2
- 308 -
UNLIMITED DISTRIBUTION
- 309 -
the target is unique from previous techniques and, in remote target measurements and verification of the
recent tests, has performed flawlessly even after four correct area of target illumination. (figure 1).
months encapsulation in curing concrete. The solid
state VISAR described in this paper was used to
measure ground shock generated by a nuclear
detonation at the Nevada Test Site (NTS).
IMAGING FIBER OPTIC COUPLED
:_ii.!iiiiiiiii:!i!!i
iiiiiii:
The VISAR was developed by Barker and
::_i_i_i_
::::::::::::::::::::::
iii:::
Hollenbach 1 primarily for measuring free surface
velocities of materials in gas gun experiments. An
improved version of VISAR, developed by _/'/X//J//////f///f//////f/_.6c///JJJ/ff/J_J//J_ _/A_
accurately reduced by comparing the results of the small spot onto a target of interest. The reflected
two systems. The conventional VISAR has many light is collected and routed to the interferometer
sensitive components mounted on an optical table. cavity (figure 2). A dichroic mirror is inserted into
The Fixed-Cavity VISAR, developed by Stanton, the light collecting assembly to transmit the laser
Crump and Sweatt 4, simplifies the interferometer light and reflect the other wavelengths (This
cavity by cementing the movable components technique is valuable for viewing the target, allowing
together. The result is a rugged, small, easy to use for precise alignment of the laser beam.).
system with a minimal amount of adjustment.
FOCUSING-COLLECTING LENS
- 310 -
the relationship from equation (1), the delay time x is
given by:
- 311 -
In figure 3, one component of light passes through EXPERIMENT DESCRIPTION
the 1/8 wave retarder twice, which makes it 90 ° out
of phase with the other component. The polarizing- Measurement of ground shock produced by the
beam splitting cubes then separate the S from the P detonation is important because it contains valuable
light and each beam is sent to a photo detector information used for analysis and modeling of the
coupled to a digitizer. Recording two 90 ° out of test. This ground shock measurement method uses a
phase signals produces an interference pattern that is window, with sensors coupled by fiber optics to a
a sinusoidal plot. Phase resolution of the signal is VISAR cavity. The window is oriented towards the
poor when the intensity of the sine wave is at a device and the entire area is filled with concrete.
maxima or mimima. Making the two sinusoidal When the device detonates, a shock wave is
traces 90 ° out of phase insures that at any point in transmitted through the concrete and into the
time one of the signals will be in a region of good window where the shock wave imparts a particle
resolution. Also, target acceleration or deceleration velocity in the window. The Doppler shitt, which
can be discriminated. During target acceleration, corresponds to the particle velocity in the window,
one signal pattern will lead the other by 90 ° and a is transmitted through the fiber optic to the VISAR
deceleration will cause the opposite to occur. cavity. The fringe data are converted to electronic
signals and stored on digitizing oscilloscopes
SOLID STATE VISAR DEVELOPMENT (digitizers). The mechanism for triggering the
digitizers is a time of arrival (TOA) gauge. The
The original intent for the development of the Solid TOA gauge is simply a fiber optic loop protruding in
front of the window with a laser connected to one
State VISAR was for a portable "in house" tool that
could be shared by several experimenters and used in end and a photodetector attached to the other.
the laboratory or in the field. At the same time the When the shock wave breaks the fiber optic, laser
Defense Nuclear Agency (DNA) was interested in light no longer enters the detector, it's output
optical based instrumentation for use at (NTS). One voltage drops, triggering the digitizers in VISAR.
particular experiment required an "up close"
The characteristics of the window and the material
measurement of ground shock generated by the
detonation. Since the nuclear event yields radiation transmitting the shock wave into the window must
and electro-magnetic fields, optical sensors are be known for accurate particle velocity
preferred because of their relative insensitivity to measurements. The simplest way to use a window is
these phenomenon. Also, the sensors require no to choose a material that has already been
electricity which adds a greater margin of safety to characterized. Unfortunately, the unusual laser
personnel. The following are some of the wavelength and the large window thickness required
requirements for the system to function: for adequate recording time (401as) did not allow
• Doppler measurement over kilometer-length previously characterized windows to be used. The
material chosen for the window used in this
fiber optics
• Rugged system, operating on 120VAC experiment is Schott BK-7 glass, which has good
• Must run several days with no adjustments broadband optical transmittance and is available in
• Sensors must withstand mechanical and chemical the 8" thick x 14" diameter required for the test.
abuse Several specimens of BK-7 as well as cored samples
• Window and sensors must survive concrete of the concrete were analyzed for their shock
encapsulation and measure ground shock a few properties by impacting them into other known
meters from the detonation window materials, then into themselves using a gas
• Data acquisition bandwidth limited to 20 MHz gun as the target accelerator. The results from the
analysis, commonly called a Shock Hugoniot,
- 312 -
determine whether the material is suitable for the sensitivity for these detectors happens to be at 1320
shock pressure predicted for the event. The data rim wavelength, which not only affords greater
also correlate the impedance mismatch at the sensitivity, but also increases the signal to noise
grout/glass interface. The anticipated shock ratio. The linear response range for the
pressure for the NTS test, a few meters from the detector/amplifiers is DC to 125MHz with a linear
device, is _ 70 kBar in the grout. Figure 4 is a response better than 3% and an output voltage of
display of the type of plots for the shock pressure 40mV/_tW of light at 1320 rim wavelength (The flat
tests obtained using BK-7 as the impacted material. linear response is critical for accurate data
The BK-7 behaves like fused silica up to 90 kBar. collection).
Although BK-7 does not turn opaque at pressures
above 90 kBar as fused silica does, the non-linear One of the most critical parts of the system design
"shock-up" makes particle velocity correlations was the fiber optic coupled sensors. Laser radiation
more difficult. is injected into a 50 micron graded index, multimode
fiber optic connected to sensors which image the
fiber optic onto the rear surface of the window. The
return light reflected from the window's rear surface
is collected and injected into a 100 Bm step index,
multimode fiber optic connected to the VISAR
f
r"
cavity.
cavity
A redundant
in the event of
sensor
damage
is linked
to one
to the VISAR
of the sensors
(figure 5). Correctly designing the optical train is
paramount to attaining good signal strength that
won't degrade under harsh environmental conditions
(Obviously, aider the sensors are encapsulated in 100
foot thick concrete, re-aligning is impossible.).
There was some concern about stress induced
polarization atier observing wildly fluctuating S and
P ratios when the fiber optic was bent. These
figure 4. Data plot of BK-7 particle velocity versus
fluctuations in polarization will change the sine-
time.
cosine relationship critical to accurate data analysis.
In most cases, this polarization problem occurs
The VISAR designed for the underground test
when highly polarized laser beams are injected in
contains a diode pumped Nd:YAG laser operating at
short lengths of fibers. The root cause is the mode
1319 rim wavelength, with a CW output of 160 structure is not fully mixed in the fiber optic and
mW, and a 5 kHz, single frequency linewidth. This stressing the fiber optic redistributes these modes
laser is a good choice for this system because it is
causing a change in the polarization (The laser
stable, has low sensitivity to optical feedback, and
output is single mode-single frequency and should
the wavelength exhibits very low attenuation and not be confused with fiber optic propagation
high bandwidth in silica fiber optics. This high modes.). Since there is no room for error on the
performance is due, in part, to the self cancellation
real test, three solutions are incorporated to remedy
of different wavelength-dependent dispersion effects
the problem: installing a mode scrambler that
that occur in fiber. The photodetectors in the
pinches the fiber optic into a serpentine shape, using
system are comprised of indium-gallium-arsenide a long fiber optic to mix the modes, installing a
(InGaAs) photodiodes coupled to low noise/high
rotatable linear polarizer at the entry into the
gain operational amplifier circuitry. The peak
- 313 -
camera is omitted, since there is no need to see the
rear window surface.
!
E I
OPTIC SENSO_
LU
(3
200(.... _..---_ i '-_T--'--_----I----I
,
I.--
-1
ft.
< ; _ i I I F I ._,
i i i t i t v i i = w i i , SOLID
a_o 82o eso e4o _ 86o em
TIME (microseconds)
figure 5. Diagrammatic layout of the window,
figure 6. Three of several TOA gauges sensors, time of arrival (TOA) gauges, VISAR
cavity, and laser. i
-1 EXPERIMENTAL RESULTS
t
"J 955.06 m
-1.5 _4Ilm The VISAR and TOA gauges performed with
- 314 -
known and was used in calculating the final particle Heidi Anderson- BK-7 characterization & gas gun
velocity. The peak recorded particle velocity was on support, Bill Brigham, Theresa Broyles, Dan
the order of 0.6 mm/Bs, which corresponds to a Sanchez- Electronic design & fabrication, Dan Dow-
pressure at the interface of 85 kBar. mechanical fabrication, Terry Steinfort, Robert
Vasquez- mechanical design & installation, and
William Tarbell- shock analysis. A special thanks to
Lloyd Bonzon for supporting the concept in its
infancy.
REFERENCES
.
L.M. Barker and R. E. Hollenbach, Laser
Interferometer for Measuring High Velocities of
Any Reflecting Surface, Journal of Applied
Physics 43:11 (Nov 1972)
.
W.F. Hemsing, Velocity Sensing Interferometer
(VISAR) Modification, "Review of Scientific
Instruments 50:1 (Jan 1979).
_gure 8. Reduced data showing particle ve
versus time
3. J.E. Kennedy, Org 7130, private communication.
The results indicate that the yield of the device was 4. K.J. Fleming, O.B. Crump Jr., Portable, Solid
greater than expected (60 kBar). The choice of State VISAR,. SAND92-1361. April, 1992
BK-7 was fortunate because if fused silica was
available and used, the data would have been lost. .
O.B. Crump Jr., P.L. Stanton, W.C. Sweatt, The
(Fused silica is known to become opaque at Fixed Cavity VISAK, SAND92-0162 (March
pressures above _ 82 kBar.) The BK-7 is apparently 1992). Sandia National Laboratories,
able to withstand slightly greater shock pressures Albuquerque, NM.
before going opaque and at 1/3 the cost, it is
significantly less expensive. .
K.J. Fleming, Fiber Optic Coupled Probe for
Versatile Interferometry, Department of Energy
Patent Disclosure SD-5034, S-74-181
ACKNOWLEDGMENTS .
L.M. Barker and K.W. Schuler, Velocity
Interferometry System. Journal of Applied
This work was performed at Sandia National Physics. 45,3692 (1974).
Laboratories, Albuquerque, NM for the United
States Department of Energy under Contract DE-
AC04-76DP0089. This project was truly a team
effort and the authors gratefully thank the following
people for their participation:
Leonard Duda- financial and technical design
support, John Matthews and Richard Wickstrom-
sot_ware support, Larry Weirick, Mike Navarro,
- 315 -
,?
Abstract:
The Indian Head Division, Naval Surface Warfare Center (IHDIV, NSWC) is
conducting a qualification program for a laser-ignited, all-secondary (DDT)
explosive detonator. This detonator was developed jointly by IHDIV, NSWC and
the Department of Energy's EG&G Mound Applied Technologies facility in
Miamisburg, Ohio to accept a laser initiation signal and produce a fully
developed shock wave output. The detonator performance requirements were
established by the on-going IHDIV, NSWC Laser Initiated Transfer Energy
Subsystem (LITES) advanced development program. Qualification of the
detonator as a component utilizing existing military specifications is the
selected approach for this program. The detonator is a deflagration-to-
detonator transfer (DDT) device using a secondary explosive, HMX, to generate
the required shock wave output. The prototype development and initial system
integration tests for the LITES and for the detonator were reported at the
1992 International Pyrotechnics Society Symposium and at the 1992 Survival and
Flight Equipment National Symposium. Recent results are presented for the
all-fire sensitivity and qualification tests conducted at two different laser
initiation pulses.
- 317 -
Introduction:
The INDIV, NSWC is the lead service for car=ridges, Cartridge Actuated
Devices (CADs), and Aircrew Escape Propulsion Sys=ems (AEPS) for all services.
The CAD Engineering Division at IHDIV, NSWC manages and implements the
development and engineering functions in the fields of ballistic power
sources, energy transmission sys=ems, and control devices such as cartridges,
CADs, and their associated signal or energy transmission subsystems for the
three services. The CAD Engineering Division also recommends and establishes
policy and conducts service qualification for cartridges, CADs, and related
power signal transmission systems for aircrew escape and survival and
stores/weapons delivery and deployment for the Department of Defense (DoD).
In addition, a_minis=ration of research, design, development, and Product
Improvement Programs (PIP) for ignition devices and-electro-explosive devices
for CADs is performed by the Division. Development of design specifications
for cartridges, CADs, and related ballis_ic systems is maintained under this
authority.
Backqround :
The IHDIV, NSWC has pursued development of LITES for these applications.
LITES utilizes chemical flashlamps to generate light which is amplified by a
laser rod, focused into fiber optic transfer lines, and delivered to optically
initiated pyrotechnic output devices. Proof-of-Principle tests and the
exploratory development program (13th International Pyrotechnics Society
Proceedings - 1988) were completed. An advanced development program was
conducted to miniaturize the laser housing while maintaining the proven
neodymium doped phosphate glass rod and commercially available flashlamp
concept. The miniaturized laser (Figure 1) is a mechanically actuated device
which generates sufficient energy, when delivered through a bundle of fiber
optic lines, to initiate an optical output device. The LITES advanced
development program has designed optical output devices which produce
ballistic pressure or a shock wave output (detonator} as required for a
specific aircrew escape system application (18th International Pyrotechnics
society Symposium - 1992). FI_A $;M%AM95
I -_S-'_ ROD
: PmCSHAT_. G,_ASS
J I F.3CUS,NG
:.,.,f_ _.x_ _
/; .....×\...x.\.<¢<.q ¢_..._..._._x.T..._
--. __\.,__ =
,x.\_ _..
: Y--; f
I l I
I 1.I S _C-£$
- 318 -
A s p a r = cf :IyE3 =- *- ->-,.--=- -..., _ _ _ _ _ A s :=-. s e r i a a cf d i s c * ~ s s i o n w
-e+-,.-.- s i t h EGLG
Mound A p p l i e d Tech?.zlzgiss, :6::’;, ?;Si;C esrz=lis?.e~tb.2 f z l l o w i n g r e q u i r e m e n t s
( T a b l e 1) f o r ti-.e L z ~ s r -l..----
- ; - - ; - = ~c e z z r . a z o r . Ssecifically, t h i s deflagration-
t o - d e t o n a t i o n t r a n s i z r ( 2 3 : j ;-e.;lra (Ti?..-=
3A-- 2 ) WOlild a c c e p t a 1 . 0 6 pm l a s e r
w a v e l e n g t h i n p t s7.e c;cle c7.L:; c = r . r a l r . s e z = r . d x y e x p l o s i v e s t h a t a r e
c o m m e r c i a l l y a v a i l z k l e f r o m s e i . e r a 1 s z - . ~ r c 2 si n t h e Uriited S t a t e s . T h e s e
r e q u i r e m e n t s , a l o n g x L t h t h 2 w i r . , i c w 2r.C s e r . e r a t i o r ; o f a n o u t p u t e q u i v a l e n t t o
a S h i e l d e d M i l d D e t = r , a = i r . q C o r d ( S F J C ) t i p , allows t h e o p t i c a l d e t o n a t o r to be
i n d e p e n d e n t of t h e f13sr cctlr s1;r.a: -- =..=...-ssFr,c sys.ts!z. A l t h o u g h d e v e l o p e d
& - - - - - :
s p e c i f i c a l l y f o r u s e x i t k . L I Y Z S , e f i- -*v- t s % z r s take? t o p e r m i t t h i s o p t i c a l
d e t o n a t o r t o be u s s 5 k>- s . v a .r i e. t y cf ~ ~ . e xculss . - d u r a t i o n and f i b e r o p t i c
l i n e c o n f i g u r a t i o n l a s e r L~F.L:LZ:: s y s z e ~ , s . I:: addition, t r a n s i t i o n of t h e
t e c h n o l o g y r e q u i r e < z 3 r n a n - L f z z r c r e t?.e d e t z r . a t o r t c i n d u s z r y w a s h e l d as a
d e s i g n goal t h r o u g k z t t h i s d z v e l o g m e n ~pr.~:rm ( 1 8 t h I n t e r n a t i o n a l
P y r o t e c h n i c s S o c i e t y S ~ ~ ~ ~ o -s F1992). u z
F l a t wifidow c o n f i g u r atio n
S h i e l s e ” , M i l d C e t o n a t i n g Cor2 (S,HDC) t i p o u t o u t
Hermetically sealed
S t r u c t c r a l l y s x n d , a l l Reacsa5ts contained
~~
N o D r o o r i e t a r v cornoonents
~
T r a n s i t i o n government developed t e c h n o l o g y t o
i n d u s z r y for c o m p e t i t i v e
k
- 319 -
Test Proqram Preparation:
Definitions:
_ _m_mlm
_?aPJLTn_m_ mr_nm
amrlwmlAlr :lmlMm_mR
o_m- _h_Wllmq
Dmmuwmm _ mru_
J _m
_T SlP_A_
- 320 -
Current Specifications:
- 321 -
_-DPROACH ! ._ %__NTAG E S D I SADV._2_TAGES
This leads directly into the disadvantages of this approach. The very
detailed system specific document requires an investment of Program Management
time and resources. The amount of technical detail in these documents will
depend on the individual program office or on the contractor assigned with
their preparation, issues such as competitive procurement of the selected
technology or sole sourcing the procurement to a particular vendor for the
life of the platform must be addressed at this step. If the system specific
document becomes too detailed, sole source procurement or its variations, are
very likely. Upon co_p!etion of these documents, they _ay not be applicable
to other platforms. Some reqairements may transition to a general system very
well; however, most will not.
- 322 -
The third apprcarh is to utilize existing specifications to implement
laser initiation technology into current and planned platforms. There are
several advantages to this approach. Existing specifications are written to a
general format thus allowing all alternative technologies to design
engineering solutions. The previous test requirements for each platform are
well defined and established. Potential vendors for a specific platform have
a defined baseline of past knowledge to build upon. Precedence has been
_stablished by the Program Managers utilizing these specifications. There are
no new technical iLT, ilations for Lmplementing laser initiation technology onto
any platforms.
The disadvantages ofthis approach include the time dated nature of all
the listed specifications (Table 1), and they must be amended somewhat to
address new technical concerns. The listed specifications were written to
address the general design issues of that time and, even including _endments
and re-issuances, do not address some of the attributes of laser initiation
technology. Minor modifications to these specifications to address these
special attributes allow these documents to govern implementation of a new
technology onto current and future DoD platforms.
- 323 -
F.a_.'onm=nu_ Tcs_ /
Qu_firy 4 6 6 9 9 9 9 12 12 6 9 30 10 30
F----
V'm_l ln_Lion t+ 1:1 + 9__3o
X-R.zy& n-Ray Lnspextion I+ 9 [ 12
Non-E1e=u'i=
L--,ki=fi
on
J i
I r-
I I 1____
!
40'Drop Test ! 6
I I I
I
• Shock I 9 9
• TSH&A [ 9
I I
• _=-brtdon
Cook-Off" V-----
y.......--
l_ T=mp. F.xpo=Jn= (70" 19 [
I"--""-"
(3) The "," denotes SEQUENTIAL TESTING which means the nine •
vibration detonators were subjected to all four
environments and functionally tested; three detonators
at -65 ° F, three detonators at 70= F, and three
detonators at 200°F. The Low Temp. Conditioned
detonators were also subjected to TSH&A cycling and
Shock prior to functional tests as described above.
- 324 -
Successful completion of _his QTP demonstrates the laser-ignited
detonator concept. Additiena! testing will be required prior to release of
this device to service use. The application specific locking connectors (both
from the fiber optic transmission system to the detonator and from the
detonator to its work performing device) must be demonstrated through a
similar environmental test series prior to aircrew escape system
implementation.
Defining the specific laser energy pulse, its duration, and the
configuration of the energy delivery system was performed at this time.
Driven by a specific aircrew escape system application, the viability of a
microsecond(s) long pulse duration was considered. Based on the
recommendations from EG&G Mound and by this Activity's research, the laser-
ignited detonator was capable of being successfully initiated with a pulse of
this duration. A 150-microsecond pulse duration delivered through a hard clad
silica (numerical aperture of 0.37) fiber optic line was established as the
initiation condition. A 20 unit Neyer threshold test I was conducted to
determine the all-fire energy of the laser-ignited detonator. Based on these
test results, the 0.99 reliable at a 0.95 confidence interval energy value was
determined to be 131.3 millijoules in this configuration. The diagnostic
equipment was verified for this conficuration (Figure 4). To further insure
initiation of the detonator in this configuration, the following values were
used to begin the qualification testing:
0.10 t
it
0.08 [
._
i
_,u 0.06 i I i
2 i
F I
u
.__ 0.02
J
i
i
I,,Ib l!!n gUIII
_,, o._
I
F
,
i
* t ' t i i i i
-0.C2
Figure 4: 150 Millijoule Laser Energy Pulse from Quantaray DCR-2A Laser
- 325 -
Te_ I Function P_SF.o( Te_:J Func_oe? Pul_ _ "Function "tune Indent
Tcm_ramr¢ (nO3 _) (.tt-_-c) C,_.)
The fiber optic line delivering the required energy pulse was examined.
A standard SMA-905 comnector was used to link the line to the detonator. This
connector centers the fiber optic line in a stainless steel sleeve with epoxy
filling the surrounding gap. One potential failure cause was that if this
epoxy slightly covered the face of the fiber or at the tip of the fiber, the
epoxy was vaporized as the energy pulse exits the fiber. This phenomena would
block the laser energy from the window and result in a greatly decreased
amount reaching the energetic material, inducing non-initiation of the
detonator.
- 326 -
Based on this ¢omp!eted failure investigation and the assets available
to continue this development ani _aalification program, the overall system
initiation cenfigurazien was re-addressed. A _Jesticn was posed to the
aircrew escape system and aircraft system designers, "Could a system be
designed, within existing aircraft parameters, to generate and support a laser
pulse duration of 12 milliseconds?" The response from these designers was
that a 12 millisecond long pulse could be implemented to resolve the
demonstrated failure pattern.
As for the transmission system itself and the diagnostic test equipment,
to further reduce the possibility of inducing a non-initiation, a glass/glass
fiber optic line was selected (with a numerical aperture of 0.22). The SMA-
905 end connector was assembled into this line utilizing a minimum of epoxy
that was held away from the fiber tip itself. A 20 unit Neyer threshold test
was conducted in this configuration to determine the 0.99 reliable at a 0.95
confidence interval all fire energy of the detonator. Based on this test
series, the following values were used for the long pulse qualification
testing:
- 327 -
i: : Env_ntal Fun._n I Rrxi_ / Su_:.ful Funmian Indent Other
:::i!ii:-i:ili:::i:::i.
T.- : ..... Temp. ('F) ..... : .... , .... _:..:: . :. Tune (m_e_.) :: 6a.) Rutd,- .... ..
Table 6 Notes: (i) The Other Results indicated in "( )" are
unacceptable indents. They are below the QTP mandated
0.040 inch indent.
(2) The Other Results indicated in "{ }" are marginal
indents. These very closely achieve the 0.040 inch
indent.
(3) The "1" indicates an initiation failure.
- 328 -
# R-'qu_red I Succ=ssful Fu_:tion
Tu=_ (a_:.) 0=-) R¢su_
i
Table 7 Notes: (i) The Ouher Results indicated in "( )" are
unacceptable indents. They are below the QTP mandated
0.040 inch indent.
(2) The "2" indicates an initiation failure.
- 329 -
Conclusions:
BioqraphT:
- 330 -
- 331 -
.__EXCELLENCE
ENGINEERING DIRECTORATE
DESIGN
lewis _ Center
I
I,Presentation Agenda
• Purpose of Database/Catalog
• Schedule
• DatabaseCatalog availability
ELLENCE
ENGINEERING DIRECTORATE
DESIGN
Lewis Research Center
Purpose of Database/Catalog t
The purpose of the Database is to store all pertinent design, test and certification data for all
existing aerospace pyro devices into a standardized Database accessible to all NASA/DOD/
DOE agencies.
ApDlications Catalog
The purpose of the Applications Catalog is to identify and provide a quick reference for the
pyrotechnic devices available, including basic performance and environmental parameters.
- 332 -
U.£NCE
ENGINEERING DIRECTORATE
Sk3N
Lewis Research Center
Include current and past (non-obsolete) pyro devices used on launch vehicles, spacecraft,
and support systems. Compile information from all NASA/DOD/DOE Centers.
Format
Example : TITLE: Detonator - NASA Standard
PHYSICAL DATA:
.B10 HEK
SPACI[R -_
\ I- :: .39z - .4o8
-- _.277 -.2Bo
DISCS
N ]_a 5
oo:L _- ,793 - .808
CONTRACTOR: n/a
- 333 -
Format (Cont.)
Apollo, Skylab, Apollo-Soyuz, and Space Shuttle.
temperature.
ENERGY SOURCE=
TYPE OF INITIATION: NSI.
CHARGE MATERIAL: Dextrinated Lead Azide (376 mg) and RDX (400 mg).
ELECTRICAL CHARACTERISTICS: n/a.
OPERATING TEMPERATURE/PRESSURE:
TEMPERATURE RANGE: Low -420°F, High +200°F.
PRESSURE: n/a.
DYNAMICS:
SHOCK: 30g, 11 msec sawtooth.
VIBRATION: Random (-65°F to +200°F) at 2000cps.
QUALIFICATION:
DOCUMENTATION: SKD-26100097 Design & Performance Spec, Qualification
Documentation provided by each contractor and on file at JSC.
SERVICE LIFE:
Activity Name
c_atalog
Edit and revise catalog
I
Steering Committee approval /
el Catalog i
I
Publish 1994 issue of I
NAS/VE)OD/DOE Catalog i
Enter information into "
database
iof Database Ii
:Publish 1995 issue of [
P
NASA/OOD[OOE_ Database I __ __
Maintain database and catalog I
i
Ihru 1995
i
L- L
i_l'i __-__
____ 2 .......
I [ , I
! i !
! r
==,,=_ Steering Committee approval milestone If''
rev. 1126194 II!l i ill
- 334 -
ENGINEERING DIRECTORATE
Lewis Research
- 335 -
Page intentionally left blank
FIRE, AS I HAVE SEEN IT
Dick Stresau
Stresau Laboratory, Inc.
Spooner, WE 54801
ABSTRACT
Fire (and much else) is described as I have seen it (in the sense that "to see" is "to understand") from a
succession of perspectives (which seems, like that of most moderns, to parallel the sequence of
perspectives had been assumed by scholars in the past) since childhood. Origin and originators of some
of these perspectives (e.g., that of the "Bohr atom" and the Chapman-Jouguet theory of detonation) are
mentioned in passing. For the most part, I believe my views to be quite similar to those of others who
have concerned themselves with fire in its various forms. However, data, which may not have considered
by others, have led me to see explosion and the shock to detonation transition from apparently new
perspectives, which are discussed.
337
time). We read that this interest had been shared, since understand'). What some refer to as "models" are
their boyhood, be some scientists, including Goddard, referred to as "theories" by others.
in U.S.A., and Ley and von Braun, in Germany,: all of
whom made and tested rockets. Each of us sees things from a constantly changing
perspective. In each encounter, and when we are
During World War II, when most combatants reading, or writing, we try to consider each subject
developed rocket propelled weapons (including the from the perspective of the speaker, writer, listener, or
U.S. "bazooka" ammunition), yon Braun led the group reader. Pursuant to this effort, each of us has assumed
at Peenemunde, where the German ballistic missiles, a succession of perspectives, those of parents,
including the V-2, were developed. After the war, playmates, teachers, professors, lecturers, bosses,
many of the group were recruited by D.O.D. agencies. commentators, the authors of books and articles we
Von Braun came to Redstone Arsenal to participate in have read and those of the people whose views are
the U. S. Army's guided missile program, and, when conveyed. Thus we have viewed our vicinities, the
interest in "outer space" was intensified by the success world, the universe, and much within them from a
of the Russian "Sputnik" he realized part of his variety of perspectives, including those which can be
boyhood dream as the leader of the group that put categorized as "eyewimess', "common sense",
"Explorer I" into orbit (5). "reasonable', "intuitive', "practical', "rational',
"theoretical', references to those credited with
The events mentioned, parts of the sequence which led proposing them, as "Aristotelian', "Newtonian',
to the establishment of NASA, have led me to "Cartesian', etc., and those of several trades, sports,
speculate as to whether von Braun or any of his sciences, etc.
associates or their successors in the space effort
thought of the design and development of space vehicle Consideration of any subject begins with the choice of
propulsion systems as applications of "pyrotechny" or a perspective from which details which we wish to
"pyrotechnics'. They do refer to explosives and consider are visible and. others are obscured. Such
propellants (which Picatinny Arsenal and the American choices are called "simplifying assumptions (or
Defense Preparedness Association include among approximations)', in which numbers which seem too
"energetic materials") as "pyrotechnics'. small to consider are dropped as "infinitesimals of the
second order" and numbers too large to think about
LANGUAGES AND PERSPECTIVES are equated to inf'mity (6). Sometimes such
simplifying assumptions (or approximations) must be
As the years passed, having participated in reassessed on the basis of more recent experience or
conversations, committee meetings, workshops, data, which result in the consideration of a subject
seminars, symposia, etc., I have come to recognize from another perspective. Such changes of perspective
that each art, profession, specialty, and often working have been essential to the advance of science, and to
group or family, communicates in its own language, the education of each individual.
each, in U.K., Canada, U.S., etc, a variant of
English, using many of the same words often with To reiterate, the perspective from which each of us
different meanings. In recognition of the possibility of sees things is and has been constantly changing. The
having been misunderstood, explanations are apt to "steam" from a teakettle and the melting of ice showed
conclude with, "See what I mean?, and include efforts us that water exists in more than one state. (Other
to illustrate the meanings of the words by means of observations and experiences showed us that other
metaphors and models, such as working and scale substances also freeze, melt, boil and condense.).
models, sketches, "layout" and "detail" drawings, Steam emerging from the teakettle spout was invisible
graphs, chemical formulas and equations, mathematical as air, (or, at least transparent), forming a visible
equations and sets of them, and, in recent years, cloud a few inches from the end of the spout.
computer manipulated numerical models, each of Someone may have explained that steam is a gas, like
which shows the subject, from a different perspective. air (and thus, invisible) which, mixing with the cooler
"Model" as used here indicates "a description or air, condensed to liquid water, in droplets too small to
analogy used to help visualize something (as an atom) settle out, which we saw as a cloud. If they thought
which cannot" (literally) "be seen" (2). It can serve we could understand, they may have gone on to say
this purpose if the analogy is to something which can that such suspensions of droplets of liquids or particles
be seen (literally or in the sense that "to see" is "to of solids, which are too small to settle out of fluids
(liquids or gases) in which they are insoluble, are
338
called "colloidal suspensions" and that, when the fluid room wall. He (the father) having painted the wall a
is air, they are called "aerosols" and are the "stuff" of light beige, let it dry, was applying a darker brown
clouds, fog, and mist, and (of other compositions) of paint, a few square feet at a time, and, while each
smoke and smog patch was "fresh', "blotting" it with crumpled news-
paper to expose the lighter paint in a'stippled" pattern.
FIRE, FROM "KID'S" PERSPECTIVES He tossed the paint soaked clumps of paper into a
bushel basket. After about an hour, the pile of paint
The earliest impressions of fire, which I can soaked paper in the basket began to smoke and the
remember, were the sights of the yellow flames of man grabbed the basket and ran out in the yard before
candles on a birthday cake and of trash and wood it burst into flame. He managed to drop it so quickly
fires. Fire had been the source of most artificial light that the only damage to him was some slightly singed
until a bit over a century ago. As we (including the hair. A few years later, when a fireman, visiting our
earliest human observers) saw the flames spread over school to talk about fire and its prevention, warned of
the surface of the fuel, it was apparent that the light, the danger of "spontaneous combustion", I knew, from
which seemed to be the essential property of fire, is on scene, eyewitness observation, what he was talking
"catching", like a cold or the flu. This impression is about, from the "practical" perspective of the fire
perpetuated in the usage of "light" for "ignite" and fighter, but didn't see why "spontaneous combustion"
"catch fire" for what the fuel does when lit. could happen if the "ignition temperature" of the paper
was as high as it seemed to be.
Our perspective changed with the passage of time and
the accumulation of experience, and we came to see At the time of the above episode, our family lived in
fire, from a more "practical" perspective, as a source a suburb of Milwaukee. Sunday drives (in the "Model
of heat, and it became clear that firelight is a mani- T ") often carried us to deserted stretches of Lake
festation of the heat of combustion. Some of us had Michigan beach, on which there were, often
noted that "firelight" is similar, in color to the light "fireplaces", made by arranging rocks in a circle. My
emitted by glowing coals or metal or ceramic which Dad often built fires of driftwood, which was usually
was a bit hotter than "red hot'. With a little thought, available. If suitable vegetation grew nearby, he'd
it became apparent that black smoke, is air borne soot sharpen "green" branches or "shoots" to make "spits"
which, when hot enough, emits black body radiation, for toasting marshmallows or broiling hot dogs. As we
so the yellow flames of candles, oil lamps, and wood sat around the fire I saw it as the focal point of the
and trash fires can be seen as "yellow hot black family's togetherness'.
smoke'. Flames of other colors are effects of atomic
and molecular emission (whereby elements and A few years later, I went with my parents on an
compounds are identified in spectroscopic analysis) automobile trip around Lake Michigan. Most
which occur at elevated temperatures. Although the memories of the trip, particularly that of the ferry boat
usage of "light" for ignite persisted in our crossing of the Straits of Mackinac, are pleasant, but
conversation, we came to recognize that ignition one, less pleasant but more vivid, is that of mile after
occurred when a fuel element was "hot enough'. By mile of "burnt over country" left by the "Peshtigo
this time we had learned to think of heat in the fire', which, fifty years earlier (on the date, Oct. 20,
quantitative terms of temperature and it became 1871, of the more notorious though less disastrous
generally accepted that the temperature at which each Chicago fire.) had devastated 1,280,000 acres,
fuel started and continued to burn was its "kindling including three-quarters of the shores of Green Bay
point" or "ignition temperature'. The propagation of (7). Even after fifty years, the effects of the fire were
fire (combustion) is seen by many as the progressive quite apparent. I suppose that my parents thought that
heating of unburned fuel to its "kindling point" by the I had been sufficiently persuaded of the importance of
heat of combustion of the burning fuel. (The title keeping fire under control to trust me, as they did,
"Fahrenheit 451" (6',4) of the novel by Ray Bradbury, with the responsibility of burning trash (in a woven
and the movie made from it, is derived from the wire trash burner) and leaves (in the gutter, as was the
supposition that 4510F is the "kindling point" of practice in our oak shaded neighborhood).
paper). However, the episode described below has left
me skeptical of this view. My household duties, as subteen, besides trash
burning, raking and burning leaves, and lawn mowing,
When five or six years old, at a friend's invitation, I included tending the coal furnace, which involved
joined him in watching his father paint their dining shaking out ashes, adjusting the damper when neees-
339
sary, and shoveling coal, in the course of which I had stove are blue (if the burner is "properly" adjusted,
plenty of opportunity to observe the fire, which was but yellow if the air intake is restricted to make a
mostly glowing coals, with a few flickering flames. "rich" mixture.
When the fuel was coke, there were no flames nor
smoke. We learned, when quite young, that, although candles
and matches could be "blown out', fire, in general,
After a few years, as a Boy Scout, I became involved was energized by blowing or "fanning" ('red hot"
in a discussion of the concept of "kindling points" or glowing coals brightened and became "yellow hot'),
"ignition points'. In the course of the discussion, I controlled by "damping the draft" and "smothered" by
recalled the "spontaneous combustion" episode I'd depriving it of air. It is apparent that the foregoing
seen. By that time, of course, I'd forgotten, if I ever was known by prehistoric humans. Smelters,
knew, the temperature on the day when I'd witnessed foundries, and forges in archeological sites had flues,
spontaneous combustion but guessed that it must have dampers, and other means of forcing and limiting the
been between 60°F and 90°F and wondered, out loud, supply of air to fires.
whether paint soaked newspaper had a kindling point
in that range. The answer was that it didn't but that Those of us who are old enough to have had spending
"self heating" had raised the temperature of the stuff money in the 1920s (before the passage of "safe and
in the bushel basket to its kindling point. It would be sane Fourth" ordinances) celebrated the Fourth of July
more years before I could sort out the distinctions with firecrackers and other fireworks (some,
between "self heating', "burning', "fire', and apparently, still do), in the course of which, we
"combustion'. (Perhaps I haven't yet, but con- learned that gunpowder and other pyrotechnics burn
sideration from various perspectives has helped me to without air (and, in fact, burn faster when confined -
understand those who use these words.). "smothered'), which had been known by some
alchemists as long ago as the ninth century (4).
Based on our earliest impressions of such matters, the
aphorism that, "Where there's smoke, there's fire.', "Educational toys" included chemistry sets, which
seemed to be a "matter of common sense'. However, provided amusement, seeing the color changes and
when we saw smoke, but no flames, coming from an foaming resulting from chemical reactions, and,
overloaded extension cord or from toasting bread or perhaps, the beginning of a "chemical" perspective.
frying bacon that was getting black and said to be While, since "playing with fire" was discouraged, in-
"burning', with no flame evident, and that, as fire gredients of gunpowder and similar mixtures were not
spread across burning wood, smoke often appeared included in chemistry sets, some of us learned (by
ahead of the flame, we pondered the questions as to reading) what they were and found ways to get some,
what was meant by such words as "smoke" and "fire" and set out to make our own fireworks. I joined a
and, specifically, what is the composition of smoke fourth grade classmate in the "Universal Research
(including.the liquid "hickory smoke" and "mesquite Laboratories" as he called his basement in the
smoke" in bottles on grocery store shelves). We'd fred preparation of some black gunpowder which we loaded
answers in considering these questions from an into a home made skyrocket (which flew straight up to
"intermolecular" perspective of fire and fuels. about six feet from the ground before it lost stability
and tumbled). In the course of these efforts, we
We may have noticed that, if metal ceramic or viewed chemistry from the "practical" perspective
anything else that can stand the heat, is heated from which it seemed that what had worked for others
sufficiently, it gets "red hot" and, if heated more, the should work for us (a perspective shared with the
red brightens to orange, yellow, and, with further Middle Ages alchemists who had practiced pyrotechny
heating, the object becomes "white hot'. Although I since antiquity).
don't remember hearing the phrase, "yellow hot', it
seems an appropriate designation of a condition A "CHEMICAL" PERSPECTIVE
between "red hot" and "white hot'. We may have
heard or read that such glow is called "black body When, in high school, we were shown a "chemical"
radiation', although a red hot poker doesn't look perspective, we saw that (as Lavoisier had shown in
black. 1779 (5)) the fire we had seen (from an "eyewitness"
perspective) was "oxidation" (combining with the
Some of us noticed that, the flames of candles and oxygen of air) and that gunpowder and other pyro-
kerosene or alcohol lamps are yellow, those of a gas technics burn without air because they are mixtures of
340
fuels with nitrates, chlorates, or other compounds The perspective induced by such models can be
which decompose when heated releasing oxygen which referred to as an "intermolecular" perspective. Fire
reacts with the fuels. All of which is expressed in can be seen from this perspective, in the sense that "to
stoichiometric equations, such as: see" is "to understand', only with reference to other
perspectives, views from some of which have been
2H2+O2 -* 2H20 (1) mentioned in the foregoing discussion. Consideration
from "practical', "empirical', "scholarly", and
for the reaction of hydrogen and oxygen, and: "theoretical" (including laws of gravity, magnetism,
fluid mechanics, thermodynamics, heat transfer, and
2KNO3+C+S -+ CO2+SO2+2KO (2) reaction kinetics is necessary to "see" fire clearly.
341
quite loudly and get warm. We were told to "break" powered). By the early 's, the "art" had advanced and
the "short circuit" before it "burned out" the trans- "store bought', "plug in" radios replaced the home
former. made battery sets the parts of which became available
to teenagers for basement experimentation, from which
Some of us learned that batteries could be used instead we gained "practical" perspectives of electronics. One
of transformers to run electric trains, etc. We all misconception, which was corrected, by the view from
became aware of batteries as parts of flashlights and/or the "electronic" perspective was that electrical current
battery operated toys. We found that batteries differed flows from positive to negative. We became aware
from transformers in three ways; that electrical current is the movement of negatively
charged electrons, from negative to positive. We had
1. They have "positive" and "negative" terminals, previously learned, from demonstrations of
marked "+" and "-" electrostatic effects (with combs and bits of paper),
2. They discharge as they are used and in a short that like charges (as like magnetic poles) repel one
time, when "shorted'. another, and opposite charges attract. We were to
learn, later, that these principles apply to chemical
3. They don't hum, even when "shorted" (but do reactions, including fire as well as electrolysis.
warm).
342
of an internal combustion engine has been ascribed to Diesel engines. After a year or so. recognizing that I
"detonation" of the fuel-air mixture. In this respect, was taking the same courses as those in Course II
I don't know don't know which of the several "Mechanical Engineering" whose schedules had been
meanings of "detonation" was intended, but would prearranged, so I switched course to avoid the hassle
guess the definition of Chapman(12) and Jouguet(13), of trying to arrange my own, while others in my
which is reviewed in the later section hereof headed - classes were doing the same, These moves were
EXPLOSION AND DETONATION. motivated by the recognition that practical objectives
are most attained by those who understand the prin-
Also, in the late 1920s (I was in my early 'teens), I ciples involved.
was on a seagull banding expedition (for the National
Bird Survey) in northern Lake Michigan aboard a This transition, of my perspective, from "practical" to
Diesel powered Coast Guard tug (similar to the fishing the "scholarly" is one of many I, and, seemingly many
tugs which were common in the upper lakes at that others, have made since humans became human.
time). The Diesel engine, as I recall, was about six
feet high and ten feet long. Preparatory to starting it, "SCHOLARLY" PERSPECTIVES
the engineer lit a blow torch over each of the four
cylinders. When they were hot enough, he ran the As the word implies, a "scholarly" perspective was
engine as a compressed air motor to "crank it", after gained in school. That acquired in the lower grades is
which he quickly reset hand operated valves and the scholarly" in the sense that, like that of the Medieval
engine ran as a Diesel engine. I was told that, in a "Scholastics", it presented the perspective from which
Diesel engine, the fuel (kerosene - or "coal oil", as the world was seen a few millennia ago, when the
some called it then) was ignited by "compression classics, which, often, explained phenomena with
ignition" rather than a spark'. My dad and the reference to such models as anthropomorphic animals
organizer of the expedition (to whom bird banding was (e.g. the tortoise and the hare) and objects (the
a combination hobby and public service activity) were mountain which talked with the squirrel), supernatural
engineers by profession. One of them explained the entities such as, fairies, brownies, trolls, gods, and the
"Diesel cycle" to me, about (as remembered after six- heroes of Greek, Norse, etc. mythology, were written.
ty-some years) as follows; From a modern perspective, it is, sometimes, hard to
tell where the line was drawn between the
Air, which had been drawn into the cylinder metaphorical and the literal. Even in modern
in the intake stroke,is compressed "adia- discourse, the location of this line is sometimes
batically" (my introduction to this word, and indefinite. As we progressed in school, the,
to the subject of thermodynamics) which "scholarly" perspective melded into "classical',
raises its temperature above the ignition "historical", "mathematical" and "scientific"
temperature of the fuel, which burns as it is perspectives, which were narrowed to those of specific
injected. (the engine can't "knock" because n subjects" or, "academic disciplines', such arithmetic,
the fuel can't burn any faster than it is science, algebra, geometry, chemistry, and physics,
injected into the hot air). The heat of and further, to trigonometry, calculus, organic and
combustion of the fuel raises the temperature physical chemistry, applied mechanics,
and hence the pressure of the air and product thermodynamics, electrostatics, and vector analysis. As
gases, which expand adiabatically, imparting a result we saw fire and other phenomena and things
more mechanical energy to the system than from a succession of perspectives, between which we
was used in the compression stroke. shifted, often after a few seconds.
The above explanation, in combination with the "Classical" perspectives included those mentioned
rationale that Diesel engines, which have higher above based on mythology and those 'of Greek
compression ratios than gasoline engines, should be philosophers, including Plato, Euclid, Pythagoras, and
more powerful and efficient, besides which, they used Aristotle. Euclid's geometry in which the subject is
cheaper fuel. All of which persuaded me that auto- considered from a "logical" perspective, is, in English,
mobiles should have Diesel engines. Based on this still taught. Aristotle viewed physical science from a
conviction, I enrolled, a few years later (in 1934),- at "logical" perspective in which phenomena are
M.I.T. in Course IXB, "General Engineering" (in explained in terms of relationships derived from "first
which each student could choose courses appropriate principles", which, like the axioms of geometry were
for his intended specialty) to specialize in automotive considered (on the basis of what some modern
343
scientists view as "intuition" when they refer to a effect is seen to be determined by Bernoulli's principle
phenomenon as "counter-intuitive') to be "self evident (which is the law of the conservation of energy stated
truths". While the axioms of geometry have stood the in terms of pressure, density, and velocity (5,11).
test of time, some of Aristotle' s "first principles', such
as that "heavy objects fall more rapidly than light Although, for liquids, the assumption of
ones" were discredited by empirical data. incompressibility is a reasonable approximation (in
Consideration of phenomena from the "empirical" fact, when the empirical data, upon which the
perspective, followed by views from "graphical', principles of hydraulics and hydrodynamics were
"analytical", and "theoretical" perspectives has based, were obtained, the available instruments were
advanced science since the renaissance. Empirical sufficiently precise to determine the compressibility of
data are quantitative data, the product of measurements liquids, the compressibility of gases was apparent to
of physical quantities, including time, dimensions, Hero in the first century (5) and must be taken into
position, force, mass, etc, and functions thereof, such account in considering their behavior. The behavior of
as velocity, acceleration, pressure, energy, and power. gases is considered from a "thermodynamic" per-
Some such measurements (for example, those of spective in terms of the "gas laws", which relate
astronomers, microscopists, etc.) are made, using pressure, specific volume, and temperature.
instruments, of natural phenomena which are beyond
the control of the observers. Others are made in the Liquids and gases are seen, from "hydraulic',
course of experiments, including the establishment of "hydrodynamic', and "thermodynamic" perspectives
preconditions and determination of results. By (as they are from "eyewitness", "common sense',
"plotting" such data a "graphical" perspective is "intuitive" "practical" and "empirical" perspectives) as
gained, the view from which may suggest continuous media (thus legitimizing the application of
relationships, which can be expressed in algebraic algebra, calculus, and differential equations in the
equations, manipulation of which can yield an "analyt- generation of theory from empirical data. In contrast,
ical" perspective. Consideration of an object, material, from the "intermolecular" perspective, which is
system, or phenomenon from "empirical", "graphical" mentioned a few pages back, a gas is seen as a
and/or "analytical" perspectives may lead to the "swarm" of atoms and molecules, moving in random
conception of a model or theory, usually, at first directions at random velocities, and bouncing,
"heuristic" but, for purposes of discussion and elastically, from one another ('like tiny billiard balls"
analytical verification, represented by a diagram, as Mach, scornfully, put it) when they collided, as
mathematical or chemical formula, equation or set of envisioned by Maxwell and Boltzmann, who
equations, graph or scale model, which provides considered this motion in terms of statistical
another perspective, which can serve as the basis for mechanics, assuming what has become known as the
verification, or at least support, of the theory by "Boltzmann factor", exp(-E/RT), for the statistical
prediction of observed or experimental data. Such a distribution of kinetic energy, E, among the molecules
sequence has resulted in the advance of each science. and atoms of a volume of gas, at absolute temperature,
However, since the sciences differ with respect to the T, where R is the "gas constant" for the mechanical
phenomena and quantities with which they are equivalent of heat. The result of their consideration (in
concerned, each has evolved an unique perspective 1871) from this "intermolecular perspective has
(each of which is the result of such a sequence). become known as "The Maxwell-Boltzm kinetic
theory of gases', that heat is molecular motion and
From "hydraulic" perspectives, water and other liquids pressure is the aggregate effect of impacts of many (if
are seen as "incompressible fluids" which behave in the order of Avogadro's number (6.026x10:3) times the
accordance with Pascal's law, that "Pressure (force per "Boltzmann factor") molecules on a surface. That the
unit area) exerted at any point on confined liquid is "gas laws', which had been established in the previous
transmitted, undiminished, in all directions" (10). The century, on the basis of experimental data, by Boyle
"hydrostatics" perspective is that from which systems and Charles, can be derived from the kinetic theory of
in which the effect of flow upon pressure is negligible. gases has validated the theory.
so that Pascal's law can be applied without reserva-
tion. As Mach's remark, alluded to in the preceding
paragraph, implies, heat is viewed from more than one
Systems and phenomena in which the effect of perspective. Some, apparently including Mach, view
movement upon pressure is significant are considered it as a fluid (as it seem to be from casual observation
from the "hydrodynamic" perspective, from which this as well as carefully controlled "heat flow" experi-
344
ments). Even today, though heat is generally seen as As pointed out and illustrated herein, perhaps too
"molecular motion", the phrase "heat flow" is often, each of us sees things, substances, systems, and
common. Although the Maxwell-Boltzmann kinetic phenomena from a sequence of constantly changing
theory of gases, when generally accepted, established perspectives, and the sequences are individual. In my
the view that heat is molecular motion, I'm not sure ease, the perspectives alluded to in the foregoing were
that Maxwell or Boltzmann considered the motion to gained by observation, experience, study in school,
include rotation and/or vibration. and recreational reading. I don't remember the exact
sequence, but it seems that before I acquired an
WaR's invention of the steam engine (in 1769) and its "intermolecular" perspective (in fact, before the
widespread application motivated the development of styrofoam used to make the models shown in Figure
the thermodynamics of steam, in the course of which (1) was invented) I had read a book (9) which induced
it became evident that, although the "gas laws" apply an "intra-atomic" perspective, from which I saw an
to "superheated steam', they don't to "wet steam", so atom as a "nucleus" of closely packed protons and
that "steam tables" and "Mollier charts" were needed neutrons, surrounded (as the sun is by planets) by elec-
for quantitative prediction of operating characteristics trons.
of steam engines. Van der Waals considering such
"two phase" systems from the "intermolecular" AN "INTRA-ATOMIC" PERSPECTIVE
perspective of Maxwell and Boitzmann, assuming
finite sizes of (and attractions between) molecules Each electrostaticaily positive proton attracts an
derived the "equation of state" ,which is known by his electrostatically negative electron, so the electrons,
name, in 1873. which don't fall into the nucleus (as the planets don't
fall into the sun) because they are moving too fast.
Chemistry, considered from the "empirical" Thus, the electrons orbit about the nucleus as the
perspective, had suggested and corroborated the "law planets do about the sun. The analogy of an atom to
of defmite proportions" which, in turn, suggested the the solar system is flawed by the difference between
atomic and molecular theories. Faraday, viewing gravity, which attracts all heavenly bodies to one
electrolysis from an "empirical" perspective, another and the electrostatic forces, which attract
established his "laws of electrolysis", which introduced electrons to protons but repel them from one another.
the concepts of "equivalent weight" and valence, in The orbital patterns of electrons are determined by the
1832 (5). (He also favored the proposition that electric interaction of these forces and the laws of motion
current is composed of particles (something that established by Newton's demonstration that they can
Franklin had suggested nearly a century earlier be invoked as the basis of the derivation of Kepler's
(incorrectly assuming the particles to have what he (empirical) laws of planetary motion (as well as the
designated, and is still referred to as a "positive" principles of relativity, and wave and quantum
charge) and would be verified, in the 1890s, by mechanics postulated, formulated and demonstrated in
Arrhenius and Thomson, who corrected Franklin's the early 20th century, by Einstein, Planck, Bohr,
error) (5). Pauli, Heisenberg, and others (8)), of which my
understanding was (and still is) too vague to include in
"Equivalent weights" as measured by Faraday's the model upon which my "intra-atomic" perspective
methods, are ratios of atomic weights or valences. By was based). In this model, the equilibrium positions of
1860, the lack of consensus regarding the means of the electrons, as determined by their attraction to the
separating atomic weight from valence had chemistry nucleus and their repulsion of each other is attained
in a state of controversy and confusion which moti- when they are spaced in an orbit where the attraction
vated the convening of the First International Chemical of the electrons to the nucleus is balanced by their
Congress, ins which these matters were resolved. By repulsion of each other (plus the centrifugal force due
the late 1860s, atomic weights and valences of all to their motion in that spherical surface). Two
elements known at the time had been determined. electrons can occupy such an orbit, from which
When Mendeleev tabulated the elements in order of additional electrons are excluded in accordance with
atomic weights, and entered valences in the table, he the Pauli exclusion principle.(that only two electrons
noted a periodicity of the valences, and in 1871, he (with opposite "spins") can occupy any given
published the, now ubiquitous, Periodic Table of the "quantum state') (8). It seemed that, in the language
Elements. of atomic physics, the term "orbit" meant the spherical
surface (referred to, by some (5)(8) as a "shall')
where these forces are in equilibrium such that the
345
attraction of the electrons to the nucleus balanced their AN "INTERATOMIC" PERSPECTIVE
repulsion of one another plus the centrifugal force due
to their motion in this spherical surface and the effect The electrostatically negative field of a "saturated"
of the Panli exclusion principle etc. Electrons which (filled) electron orbit or "shell", in combination with
are excluded from this inner orbit locate in the Pauli principle, results in a repulsion of electrons
surrounding orbits, which are larger because the net or other electron "shells" which increases with
attracfi,,e force of the nucleus has been diminished by proximity so abruptly that (for atoms of so called
the repulsive force of the electrons in the inner orbit, "monatomic', "noble", or "inert" gases (helium, neon,
so there is room for eight electrons to attain argon, krypton, xenon, and radon) all of whose
equilibrium positions in compliance with the Pauli electron orbits are saturated), Mach's reference to the
exclusion principle. A third orbit has room for eight molecules (which include atoms of monatomic gases)
electrons, while the fourth and fifth orbits contain in accordance with the Maxwell- Boltzmann kinetic
eighteen electrons each and the sixth has room for theory of gases as that of "tiny billiard balls" can be
thirty-two. A seventh orbit, presumably could contain considered an accurate analogy.
thirty-two, if and when elements that heavy are dis-
covered. Of the hundred plus known elements, only the six inert
gases mentioned above have saturated" outer electron
The foregoing is a description of the heuristic model orbits. Atoms with unsaturated outer orbits join in
of an atom, which I remember, after sixty years as the groups in which the electrons of the unsaturated outer
basis of the intra-atomic" perspective got from reading shells (orbits) are shared. The most familiar grouping
"Inside the Atom", by Langdon-Davies (9), as well as (from a "chemicals' perspective) is in molecules,
high school courses I had completed in chemistry, where atoms with relatively few electrons in their
physics, and solid geometry. In my reconstruction of outer shells (metals, such as sodium, which has one)
the model, I was helped by the copy of the book (9), combine with those with nearly saturated outer orbits
which I got for Christmas in 1933 and still have, as (nonmetals, like halogens, including chlorine, whose
well as more recent publications, including periodicals outer orbits lack one electron each of saturation, in
and references (5), (8), and (10), by university courses which all orbits are saturated, such as that of sodium
in chemistry, physics, mechanics, thermodynamics, chloride (NaCI table salt).
physical chemistry, fluid mechanics, etc and from
conversations with and lectures by scientists, including The electrons of the unsaturated outer electron orbits
Gamow, Eyring, and Kistiakowski, all of which may are referred to as "valence electrons" because their
have "edited" my memory of some details. It is numbers correspond with the valences of the elements
apparent, from "browsing" through references (5) and to which they apply.
(8), that the model described above is an
approximation of that which is sometimes referred to As mentioned a few pages back, Faraday had
as "the Bohr Atom', which is the result of the work, introduced the concept of valence in 1832, and
guided by Niels Bohr at the Bohr Institute, by an Mendeleev had published his Periodic Table in 18771.
international group of physicists, including Heisenberg, The "Bohr atomic model N, roughly described above,
Panli, Gamow, Fermi, and Oppenheimer who was conceived, in part, as an explanation of the
considered their work in progress, from perspectives empirical evidence of the periodicity indicated in
of earlier contributors to science, including Mendeleev's table.
Pythagoras, Dalton, Avogadro, Mendeleev, Thomson,
Maxwell, Boltzrnann, Van der Waals, Rutherford, The "valence electrons" of two or more atoms are
Planck, and Einstein, to mention a few (8). As a high drawn into saturated orbits by some of the forces
school senior, I saw the model, as one sees a ship on whose equilibrium determines the numbers of electrons
a foggy night (only by its running lights), befogged as in the saturated orbits (or "shells') while the
it is by relativity (which equates matter to energy) and electrostatic equilibrium between the protons and
wave and quantum mechanics (which consider light electrons of each atom hold it together. Thus
and electrons, seemingly alternately, as waves, molecules are formed in which atoms are so grouped
particles, vibrations, and/or orbits(8)) and my present that they can share electrons to saturate all orbits while
view is still quite misty. The model described above, the electrostatic equilibrium of each atom is
however, has clarified, somewhat, my view of maintained. Such combinations of forces, which hold
chemistry, electronics, and thermodynamics. molecules together, are called molecular bonds. Figure
1 shows models of such molecules, of which the
346
"billiard balls" are a less accurate analogy than they repulsion of one another increases with proximity, as
are of the on atomic molecules of "inert" gases in that sharply as that of elastic solid objects. Thus, the
they are assemblies of spheres rather than separate motion of those components of molecules associated
balls, so that their movement, involving significant with "vibrational heat" is more analogous to that of
fractions of their kinetic energy ('heat') includes that bouncing balls than to that of vibrating piano strings.
of rotation and vibration. While models, such as those
shown in Figure 1, are usually scale models they AN "INTERMOLECULAR" PERSPECTIVE
cannot be viewed as "working" models, because the
"atoms" are rigidly joined, while the real atoms of real The specific heat of a gas is the quantity of energy
molecules assume equilibrium relative positions associated with a one degree increase in the
(determined electrostatic, electromagnetic, and other temperature, of a unit quantity of the gas. Considered
forces involved in the for saturation of atomic electron from the Maxwell-Boltzmann intermolecular
orbits) about which they vibrate or orbit (orbiting is, perspective, heat is the kinetic energy of molecular
essentially, vibration in two or three dimensions.) motion. At constant volume, the energy required to
Consideration of heat as molecular motion, from this heat a given quantity of gas one degree is only the sum
perspective has led to the distinction between of the corresponding "translational', "vibrational', and
"rotational', "vibrational', and "translational" heat, "rotational" motion of the molecules, while, at
which accounts for the differences between gases with constant pressure, the energy involved in the expansion
respect to ratios (k = Cp/Cv) of specific heat at constant is added. Since only translational heat is involved in
pressure (Cp) to that at constant volume (CO. expansion, where vibrational and rotational heat are
significant fractions of specific heat, ratios of specific
Molecules are groups of atoms held together by the heat at constant pressure to specific heat at constant
combination of the quantum mechanical forces which volume are reduced.
establish conditions for saturation of atomic electron
orbits end the electrostatic equilibrium which results in From the perspective of the Maxwell-Boltznmnn
the equality, in each atom, between the number of kinetic theory of gases, only the mutual repulsion of
positive protons in the nucleus and the total number of molecules, atoms, and ions (at very close proximity),
electrons which orbit about it. The repulsion of (which result in effectively elastic rebound from
"saturated" orbits for additional electrons (including collisions, like those of "tiny billiard balls') are dis-
those in other "saturated" orbits) increases so sharply cemible. As mentioned, the empirically established
with proximity that the comparison to "tiny billiard gas laws of Boyle and Charles can be derived from the
balls (or golf, tennis, ping-pong, or basket balls) is an theory. However, from the "interatomic" perspective
accurate analogy of the bounce of colliding molecules, discussed in the previous section hereof, molecules,
atoms, or groups of atoms, including "ions" (atoms or except for those of inert gases, are more complex than
groups of atoms of which all electron orbits are balls. A more accurate analogy would be an
saturated). The forces which hold the electrons in assemblages of balls as represented by the models
orbit, and thus maintain saturation, combine with the shown in Figure 1, except that they are not rigidly
electrostatic force which maintains the equality connected, but vibrate about equilibrium relative posi-
between the nuclear protons and orbiting electrons of tions, since molecules, atoms, and ions are attracted to
each atom to result in attraction which, like gravity, is and repelled from one another by forces (mostly
relatively constant close in and, varies inversely as a electrostatic and magnetic) which vary with their
function of greater separation so that that which is degrees of proximity, relative positions, and
referred to as "vibrational heat" is alternate collision orientations. From this perspective, it is apparent that
and separation of atoms and groups of atoms, the kinetic theory of gases, including the "Boltzmann
including "ions" (atoms with outer orbits saturated by factor', applies to "vibrational" and "rotational" as
the transfer of electrons, which leaves each ion with well as "translational" heat.
an electrical charge). Those with more electrons in
orbit than protons in their nuclei have negative charges NOTES ON THERMODYNAMICS
and those with less have positive charges. The
attraction between the atoms and groups of atoms Carnot "founded" (5) the science of thermodynamics
(including ions) of a molecule (in the gaseous state), with his book, a partial title of which is "On the
like the gravitational field of a planet, varies so little Motive Power of Fire", in which he cited empirical
"close in" that it can be viewed as constant and varies data showing that, in expansion of a gas, heat is
as an inverse function of greater distances, while their transformed into "work" and conversely, in
347
compression, "work" is transformed into heat, a half steam condenses to liquid water and the "gas laws"
century before Maxwell and Boltzmann presented their cease to apply.
kinetic theory of gases (which includes the postulate
that that which is sensed and measured as pressure of Van der Waals accounted for this changed behavior
a gas is the integrated effect of impact of molecules with the change from the gaseous to the liquid state in
upon the surface). If, as implied by the "tiny billiard terms of the Maxwell-Boltzmann "kinetic theory of
ball" analogy, the molecular motion, which the kinetic gases" by assuming an attraction (a) between, and a
theory of gases equates to heat, was only translational, finite volume (b) of molecules, to derive (in 1873 (5))
thermodynamics would be much simpler since the his "equation of state':
interchange between heat and work would be complete
and direct in all adiabatic processes. (P+a/V3)(V-b) = nRT (4)
348
"trials" (reorientations) until adjacent molecules "fit Van der Waals (in 1873) considered the relationship
together" and move closer, with a resulting increase in between temperature, pressure, and specific volume of
their mutual attraction (the "van der Waals force"), substances close to their "boiling points" from the
which, along with their asymmetry, maintains their perspective of the recently (1871) presented
relative positions and orientations. This is the process Maxwell-Boltzmann "kinetic theory of gases",
we observe as "freezing', "solidification', or assuming a finite size of each molecule and an
"crystallization'. attraction between similar atoms and molecules which
became known as the "van der Waals force'. A half
Each of us has been aware since eady childhood that century or more later, from the intra-atomic
water boils and freezes, and as our vocabularies perspective of the "Bohr atom', the "van der Waals
increased we learned that "water", "ice', and "steam" force" was seen to be "caused by a temporary change
are three "phases" or "states" of the same substance. in dipole moment arising from a brief shift of orbital
With the passage of time, we found out that most other electrons from one side to another of adjacent atoms or
substances also can exist in "gaseous", "liquid" and molecules" (16).
"solid" states.
The van der Waals equation of state was derived as a
Our earliest memories (not quite earliest for those in basis for thermodynamic analysis of systems involving
my age group) include the sight of "neon signs" "wet steam" in which water is present in both gaseous
glowing on store fronts, billboards, etc. Later, we and liquid states. The "van der Waals force" is also,
heard or read that the neon lights were tubes filled as discussed a few paragraphs back a factor in
with rarified gases, (neon, in the originals, which glow crystallization, the transition from the liquid to the
red). Other gases glow in other colors, but they are solid state. However although it plays a role, the "van
all called "neon signs" which glowed when "ionized" der Waals force" is not all that holds crystals together.
by the flow through them of electric current. In this Other forces, visible from the "interatomic" and
context, we learned, as we became more sophisticated, similarly close perspectives, contribute. Thus though,
that "ionization" meant the separation of electrons as would be expected (based on the description of
from atoms (or the ions of molecules from one crystallization a page back, in which the "van der
another), after which, in an electrical field, the Waals force" was invoked), most substances "shrink"
electrons (and negative ions) are attracted to the when they solidify, water does not. My impressions,
"anode" (positive electrode), and the positive ions from "intra-atomic", "inter-atomic" and
(atoms or groups of atoms with electrons missing) are "intermolecular" perspectives are too "fuzzy" to
propelled toward the cathode (negative electrode). If include as a logically cohesive part of this paper, but
the electrical field is sufficiently strong, and the free a few seem sufficiently relevant to mention. Some
paths are long enough, the ionization is maintained by molecules, particularly those of a number of "organic"
collisions, which "knock" more electrons free as compounds, are so large and/or complex that they
others enter atomic orbits with resulting luminosity. exist only in the solid state. They "decompose" (break
Gases are also ionized by temperatures high enough into smaller molecules) at rates dependent on
that the "vibrational heat" is sufficient to overcome the temperature and the "reaction kinetic" properties of the
attraction between their ions and collisions between substance. Conversely some compounds which are
molecules "knock them apart". Ionized gas is referred liquid at "room temperature', "polymerize" (their
to as "plasma', and as a "fourth state of matter"(9). molecules join to form larger ones, which exist only in
the solid state) when heated or "catalyzed" and they
Plasma glows. Its light emission be can seen, from solidify.
the "intra-atomic" perspective, to result from the
falling of electrons into orbit. The color, wave length, Crystalline and chemical bonds are similar in that they
or spectral characteristics of the light are unique for are effects of and governed by forces and principles
each element, and are used in spectroscopic analysis, discernible from "intra-atomic', "inter-atomic', and
to identify them The familiar blue flame of a gas stove "inter-molecular" view-points and that, from the
results from such luminosity of plasma of which empirical perspective, they are "exothermal" (evolve
carbon and oxygen are principal constituents, and the heat) (because solidification prevents translational and
red light of a railroad "fuzee" is the spectral emission rotational movement of atoms and molecules so that all
of strontium, thermal energy becomes "vibrational heat", which is
"sensible").
349
Purity is a relative term. The word "pure" is often (in which has been referred to as the "gamma (y) law
some contexts, usually) preceded by a percentage. equation of state", which is considered to be one of the
"100% pure" is not quite credible. So, all substances "ideal gas laws" derived from the empirically
are mixtures. Each solid and liquid has a finite vapor established laws of Boyle and Charles, which can be
pressure (or gaseous decomposition product) and thus derived from the Maxwell-Boltzmann "kinetic theory
an odor, which may not be apparent to most humans, of gases"(17) The "wet steam', to which the van der
but is to many animals and can be detected by means Waals equation of state was first applied, is a
of spectroscopy. Similarly, gases and solids are soluble "colloidal suspension" of liquid water in gaseous
in liquids and gases and liquids are absorbed or steam. As has been mentioned, "colloidal
adsorbed by solids. The distinction between the states suspensions" consist of droplets or particles of liquids
of matter is, thus, based on practical and empirical or solids which are too tiny to settle out from the fluid
considerations. in which they are suspended. Qualitatively, their
failure to settle out can be ascribed to their
Many familiar substances, including wood, whipped bombardment from all directions by molecules close to
cream, mud, smoke, mashed potatoes, glue, wet- their size and (in the case of "wet steam') of a similar
cement, and shaving cream are composed of matter in density. A quantitative explanation is beyond the scope
more than one state and owe their characteristic of this paper. However, the observation, in 1827, by
properties to interactions of their components in two or Brown, of what came to be known as "Brownian
more states. The properties of such mixtures depend, motion" of colloidally suspended cells and particles,
to some extent, upon the "state of aggregation" (the was explained on these bases (in 1871) by the
size, shape (often fibrous), hardness, frictional Maxwell-Boltzmarm "kinetic theory of gases" and
properties, and distribution of solid components, and elucidated by the concept of "Maxwell's demons" (5).
the sizes and distribution of droplets, bubbles, and
pores, and, where such mixtures seem solid, from the It is my impression that the phrase "equation of state"
"empirical" perspective, upon the structure of the was first used to identify the relations between
substance, including the bonds (molecular, crystalline, pressure (P), temperature (T), and specific volume (V)
and other) between the components, as well as their of "wet steam", a colloidal suspension of liquid water
distribution. in gaseous steam. In the "gamma equation of state" in
its original application, to "ideal gases', the effect of
Matter, in its various states, has been viewed from temperature is taken into account by the use of
"practical" and "empirical" perspectives. With a view "gamma" the ratio of specific heat at constant pressure
to prediction of the behavior of systems, empirical data to that at constant volume (= Cp/Cv ).
are plotted, and the indicated relationships are
expressed in algebraic equations, which, when used in For hydrodynamic consideration of the behavior of
analysis with calculus or differential equations, are substances in other states or "states of aggregation',
assumed to apply to inf'mitesimal intervals, an experimentally determined relationships of specific
assumption whose validity, is questionable when volume (V) to pressure (P), referred to as "equations
considered from the "intermolecular" or other of state" (often "gamma law" equations of state" with
theoretical perspectives which have been discussed empirically determined values of gamma) are used.
herein, but have been essential to the advance in the
states of the arts to which they apply, and, where the From the practical perspective of the designer of
principles of logic and mathematics have been applied hydraulic systems, water and other liquids are seen as
to the satisfaction of the scientific community, have incompressible fluids. However, in consideration of
come to be accepted as "rigorous theory". large or sudden changes of pressure (particularly,
those of detonation and the strong shock waves it
Although the van der Waals equation of state (equation induces), their compressibility must be taken into
(4)) relates pressure (P), specific volume (V), and account (11).
absolute temperature (T) for substances under
conditions where both gaseous and liquid states exist, To some, the mention of detonation in the above
the phrase "equation of state" seems to have acquired paragraph may seem to be a change of subject from
the more general meaning of any equation relating that of "fire" indicated in the title hereof. It's not,
specific volume to pressure, such as that for adiabatic because detonation is a form of combustion as will be
compression or expansion of an gas'; pointed out in the section hereof headed
EXPLOSION AND DETONATION. However, it may
PW = a constant (5)
350
be somewhat premature at this point, so further fiber stress of the fuel and the temperature and
discussion is postponed until we get to it there. pressure of the oxidant could interact to affect ignition.
These experimental difficulties seem to have resulted
The subject of detonation came up at this point because in such skepticism on the part of their editors
consideration of detonation from a theoretical regarding "ignition points" that none of the standard
perspective involves relationships between pressure handbooks (10,11,17) at hand as I write this, includes
and specific volume which, as mentioned above, have such data. These difficulties are alleviated for
come to be known as "equations of state', even for substances or mixtures which contain or include
porous solids, where materials in more than one state oxygen or another oxidant or which react
are present. For such materials, a more appropriate "exothermally', (with the evolution of heat). Thus the
term for the pressure/volume relationship might be Smithsonian Physical Tables (18) include tables of
"equation of state of aggregation" (which doesn't "roll ignition temperatures of gaseous and dust mixtures
off the tongue like "equation of state') with atmospheric air of several fuels and several
publications (4, 19, 20, 21) include "ignition points"
Fire, usually, involves changes of state. Yellow flames or "explosion temperatures" of pyrotechnics and
of candles and wood and trash fires are glowing black explosives.
smoke (a colloidal suspension of carbon particles
(soot), the result of evaporation and condensation of Although my doubts regarding the concept of an
the fuel or volatile components or decomposition "ignition point" as a physical property of each fuel
products thereof and the subsequent decomposition of dated from my childhood observation of "spontaneous
this colloidally suspended condensate to carbon and combustion', the general concept by those with whom
gaseous products whose oxidation provides the heat I discussed such matters, (and apparently others (6_h))
which sustains the process. Such fires involve combined with my practical experience with "lighting"
transitions from solid to liquid to gaseous states, fires persuaded me of its general validity. I visualized,
followed by reversals to the liquid state (in a colloidal the propagation of fire as the progressive heating of
state of aggregation), and finally back to the gaseous the fuel, by the heat of combustion, to its "ignition
state before the oxidation takes place.. The familiar point'.
blue flame light of a gas stove flame is spectral
emission of the plasma to which the gaseous products "Fire', the subject of this paper, has been defined (2)
of combustion have changed. Glowing coals glow due as "The visible heat and light emanating from any
to the oxidation of solid carbon to gaseous carbon body during the process of its combustion or burning."
dioxide. As has been pointed out, or at least implied, in the
foregoing, heat and light are forms of energy, of
That changes of state occur at specific temperatures which my changing perspectives are discussed in the
was common knowledge long before quantitative scales following.
of temperature were proposed. Both Fahrenheit and
Celsius established their "degrees" as fractions (1/180th CHANGING PERSPECTIVES OF ENERGY
by Fahrenheit, and 1/100th by Celsius) of the difference
between the freezing and boiling points of water. The As mentioned before, herein, each of us sees things
scales having been established, and instruments for from a constantly changing series of perspectives. The
measuring temperature having become available, following account of the succession of my perspectives
determinations were made of freezing and melting of energy is included in the belief that it roughly
points of other substances. Since it was known that parallels that of most who may read this, as well as
fuels started to burn when heated sufficiently, it those who have considered such matters in the past and
seemed reasonable to determine the "ignition point" or whose views have been alluded to.
"kindling point" (the lowest temperature at which a
substance will continue to burn without addition of My earliest impression of energy was that of a busy
external heat (16)) of each of various substances. For person who could stay busy all day. This perspective,
most fuels, which require air, oxygen, or some Other which seems to be that of the fitness program
oxidant for combustion, such determinations present participant who reported "having more energy" as a
experimental difficulties. Pressure had been found to result of a low calory diet and an exercise program
affect freezing and boiling points and, it was (which seems contradictory from perspectives I have
suspected, might affect kindling points. Where the fuel gained more recently.)
was solid and the oxidant gaseous, the temperature and
351
As seen from this earliest perspective, play required friction, which, he said, transformed the kinetic energy
energy. The experiences which came with play, to heat, which, he said, is another form of energy.
coasting down hill, bouncing balls, etc., lent reality to
views of energy from perspectives to be gained in As its name implies, "General Science" includes many
school and elsewhere. subjects, including those mentioned above and heat,
chemistry, electricity, waves, (gravity (on water
Work, like lawn mowing, also took energy, and after surfaces), elastic (including sound), and
such work, I had less energy left for other activities. electromagnetic - radio, light, etc.), radiation (usually
After school work, on the other hand, I had more electromagnetic waves, but sometimes streams of such
energy for play. particles as electrons, protons, etc.). Each of these
subjects deals with one or another form of energy
In ninth grade "General Science', I began to acquire and/or transformations of one form of energy to
"physical "perspectives of energy. "Work" was another. The conservation of energy was shown (from
delrmed as a form of energy equal to force times perspectives assumed to be familiar to ninth graders)
distance, which was transformed to other forms of to apply to all transformations from one form to
energy as it was accomplished. For example, the another.
work of lifting a pound weight a foot was transformed
to one "foot-pound" of "potential energy'. If the Play, experience, conversation, observation, and
weight is dropped, the potential energy is transformed recreational reading extended the range of my
to "kinetic energy'. perspectives, some of which have been discussed
herein before. Some early impressions, like that (from
My science teach, aware that we were also taking an Aristotelian perspective) that heavy objects fall
algebra, taught us equations for work (W): faster than light ones, were corrected in the above
and kinetic energy (KE): As I advanced through high school, geometry (both
KE = mv 2 plane and solid), trigonometry, and advanced algebra
(7)
provided "graphical" and "analytical" perspectives,
where v is velocity. and chemistry and physics provided "scientific"
perspectives, from which I could reexamine
Since we were familiar with the English system of impressions gained, since early childhood, from such
units, he told us that work (w) was measured in foot- previously mentioned perspectives as "eyewitness',
pounds, force (F) in pounds, distance (x) in feet, mass "common sense', "intuitive', and "practical'.
(m) in "slugs" (a mass of one slug weighs 32 pounds)
and velocity (v) in feet per second. Thus, I began to The combination and interaction of experience,
see things, including energy, from "analytical" and observation, and education persuaded me that work,
"mechanical" perspectives. heat, light, and sound are forms of energy and such
forces as those of gravity, and magnetic and
He told us that, as a weight falls, the sum of its electrostatic "attractions of opposites" are factors of
potential energy and kinetic energy remains constant in energy, as are time and distance, and that, in any
accordance with the "law of the conservation of isolated system, the total energy remains constant
energy'. He demonstrated the conservation of energy (which is "the law of the conservation of energy')
with a pendulum, which continued to swing,
alternately transforming potential energy to kinetic The freshman physics course, which was required for
energy and kinetic energy to potential energy. He all M.I.T. students, in which the notation of calculus
explained the reduction of the swing as the result of (also required) was used to express Newton's laws of
352
motion and gravity, and to derive from them equations (like a coaster brake). I had no idea as to how this
of motion of falling bodies, basic principles of might be accomplished, but thought it would be nice
ballistics, and the equations of orbital motion of the to have one installed in my bike. My freshman year
planets, as Newton had nearly 300 years before, was 1934-'35. A decade later, the conversion of
showing that Kepler's Laws, which were nuclear to other forms of energy (on a much larger
generalizations of Brahe's observations, were empirical scale) was an important factor in the conclusion of
verification of his laws of motion and gravity. World War II. I still have no idea as to how it might
be applied to bicycle (or even automobile) propulsion,
The lecturer of the course Nathaniel H. Frank, who but it is now used to propel submarines and generate
was also the author of the textbook "Introduction to electric power, some of which has been used to charge
Mechanics and Heat" (22), used in the course, which the batteries of electrically propelled cars. However,
included consideration of the language of physics and in the 1930s, nuclear energy was considered to be the
unit systems (metric and English), kinematics (both "stuff of science fiction" (like space travel) and
linear and plane - introducing the concept of vectors), engineering courses were concerned with more
kinetics, and statics of mass points and particles "practical" matters.
(including Newton's laws of motion and gravity -
planetary motion is considered from Copernicus' and Another freshman course was Synthetic Inorganic
Kepler's extra orbital perspective, from which the Chemistry.
planets are seen as mass points), linear and plane
dynamics, work and energy, potential energy, Sophomore courses included physics (optics,
hydrostatics, elasticity, acoustics, heat conduction, electrostatics, electrodynamics, and magnetism)
thermodynamics, the first law of which is the differential equations, machine drawing, physical
conservation of energy, which it shows to be chemistry, graphic analysis, and industrial
applicable in gases to adiabatic systems (from which stoichiometry.
no heat is lost), as well as to reversible mechanical
processes (as distinguished from irreversible processes As a mechanical engineering major, I took courses in
such as frictional heating).The text discusses "entropy" applied mechanics (including stress analysis,
(S), a term coined by Clausius (5) for the ratio kinematics, and kinetics), metallurgy, fluid
(S=Q/T) of the heat content (Q) of a system to its mechanics, materials testing, manufacturing and
absolute temperature (T), which was shown to be a construction processes, as well as such "general"
measure of the unavailability of the heat for subjects as English, history, descriptive astronomy,
transformation to work, and quotes Clausius statement and economics.
of the first and second laws of thermodynamics in
closing, "The energy of the universe remains Each course considered its subject from a unique
constant. The entropy is always increasing." perspective, each of which was somewhat familiar to
Recently, in retrospect, I have wondered how I me from earlier education, experience, and reading,
reconciled this statement with my impression, from the and some of which have been mentioned herein. From
"cosmic" perspective gained in recreational reading, one perspective it is apparent that each form of energy
that the sun and other stars had been radiating energy is either potential or kinetic energy or a combination
for billions of years. Perhaps Frank had cited thereof, and that other forms of energy, such as heat,
Einstein's "Special Theory of Relativity", which holds sound, electromagnetic radiation (including light), etc.
that mass (M) is a form of energy (E) which is are manifestations of these. Each classification is the
expressed in: result of the perspectives from which it has been
considered. From the "intermolecular" perspective of
E = Mc 2 (8)
the Maxwell-Boltzmarm kinetic theory of gasses, for
where c is the speed of light. example, heat is seen as kinetic energy of molecules,
ions, and atoms. From the "interatomic" perspective,
I do remember having read, a few years earlier, that which has been discussed, it becomes apparent that,
the energy radiated by stars was the product of while this view is applicable to "translational" heat,
reactions of atomic nuclei and that there wag enough "rotational" and "vibrational" heat are combinations of
energy in a glass of water to propel an ocean liner kinetic and potential energy as are sound and vibration
across the Atlantic, which had led me to envision a as well as gravity waves on water surfaces. An
device capable of transforming nuclear energy into electrical charge is potential energy while "direct
work, which would fit into the rear hub of a bicycle current" is kinetic energy of electrons and "alternating
353
current" alternates between kinetic and potential A difficulty in the consideration of transformations of
energy. The "heat of combustion" of fuels, in general, energy in quantitative terms is the variety of units in
is the potential energy of the attraction of the atoms which physical quantities (including energy) are
and ions of the carbon, hydrogen, and other elements expressed. The above discussion of transformation of
with positive valences, which they may contain, to energy between mechanical forms is a repetition of the
those of oxygen. explanations, (as I remember after sixty-some years)
by my science teacher, who used the English system,
Consideration from the several perspectives discussed with which we were familiar. It seemed reasonable
herein has left me with the conviction that physical and that it took a foot-pound of work to lift a pound a foot.
chemical phenomena and processes are, in general,
transformations of energy between forms, often I learned, in ninth grade "General Science', that the
involving changes of state of the matter involved. work of lifting an object weighing a pound a foot was
Although views from several perspectives, which have transformed into a foot-pound of potential energy and
led me to this conviction, have been discussed that, if the object was dropped, the potential energy
previously herein, the following account of my would be transformed into kinetic energy. All of which
progress toward it (as recalled decades later) may tend seemed to confirm my previous experience and the
to substantiate the conviction in the minds of readers: aphorism that: "What goes up, must came down.',
which has been applied, with varying degrees of
My earliest quantitative impressions related to energy pertinence, to prices, temperatures, unemployment,
were in terms of power (which, I was to learn, means, voltages, and the popularity of entertainers. I had also
in general, the rate at which energy is transformed noticed that some things, when lifted and dropped on
from one form to another). Light bulbs were (and are) to same surfaces, bounced, and/or made a noise when
graded in watts, a unit of power. Then, as now, they hit. With the passage of time, I learned to explain
illumination of a room or other space was quantified, the bounce as the result of the transformation of
by many, in terms of "watts of light'. I'm still not kinetic energy to elastic potential energy followed by
sure that those who refer to light in these terms are its transformation back to kinetic energy, and the noise
aware that the watt is a unit of power and I doubt that as the result of the transformation of same of the
many recognize (as I have come to with the passage of energy to sound (which is alternately kinetic and
years) that the rating of a light bulb in watts is a potential energy). Nothing seems to bounce forever,
statement of the rate at which it is expected to because, I learned, at each bounce, same of the kinetic
transform electrical energy, by "ohmic heating" into energy is transformed into sound and some is
heat, which is, in turn transformed, as "black body transformed into heat. The foregoing seemed a
radiation" into electromagnetic radiation, mainly in the satisfactory qualitative explanation, but a
visible range of the spectrum. My earliest impressions demonstration in quantitative terms was difficult, not
of the relative power of automobiles and outboard only because of the problems of measuring the
motors came from advertisements of their quantities of sound and heat evolved during a bounce,
"horsepower'. I heard (or read) that James Watt had but also because of the problems of conversion
coined the term "horsepower" for use in between the units in which the results of such
advertisements of the steam engine he had invented in measurements would be expected and those in which
terms which, he hoped, would appeal to his intended kinetic energy is expressed. (Energy has been
customers. In 1783, based on experiments with a expressed, by specialists in various fields, in
strong horse, he established the value of a horsepower foot-pounds, inch-ounces, foot-tons, BTUs, ergs,
as 550 foot pounds per second. By 1800, the metric joules (watt-seconds), watt-hours, kilowatt-hours,
system, which included the watt, so named in honor of calories (cal.,(gm)), and Calories (cal.,(kg) or
Watt, who had defined "power" as a physical quantity kilocalories). Some scientists express the view that
(a horsepower is 746 watts), had been accepted by an confusion can be eliminated by the use of the
international commission and has since been adopted "universal" metric system, Perhaps, but a Ph.D.
internationally by scientists. Although most ratings of chemist once told me of an instance when he and a
devices which are activated by electricity seemed to be colleague allowed the ice cubes in their drinks to melt
in terms of power, it was paid for by the _kilowatt in their mouths, assuming that this would absorb the
hour', a unit of energy. Of course, a kilowatt hour is calories in the alcohol, forgetting that some
more than 21& million foot-pounds (the foot pound was nutritionists refer to Calories as "calories" (so they'd
the first quantitative unit of energy I learned about in have had to melt two kilograms, rather than two grams
school). of ice to absorb the 150 nutritionists "calories" in each
354
drink). In view of these difficulties, I satisfied myself surface temperature of each planet continued to drop
with consideration of this matter in terms of the until equilibrium was reached between the radiant
"coefficient of restitution" the ratio (e=v 2/v I ) of the energy received from the sun and that lost by radiation
(upward) velocity (v2) of an object after it bounced to from the planet. As each planet acquired an
its (downward) velocity (v I ) before it hit. atmosphere by diffusion and volcanic eruption from its
interior and by gravitational attraction of interplanetary
The transformations of energy, mainly mechanical gases and "solar wind', the temperature, in each case,
forms (work, kinetic, and potential energy are was affected by absorption of radiation by atmospheric
considered above, from "eyewitness', "common gases (referred to, in recent years, by
sense', and "empirical" perspectives). As a student of "environmentalists', as the "greenhouse effect'), by
mechanical engineering, I acquired a thermodynamic the point to point variation of the "albedo"
perspective, from which transformations heat and work (reflectivity) of planetary surfaces, in combination with
are considered and that of applied mechanics (which the rotational and orbital movement of each planet
considers relationships of stress and strain, the integral about non-parallel axes, has resulted in variations of
of which is elastic potential energy). Other courses, surface and atmospheric temperatures with time and
which are mentioned a page or two back, presented location, which result in the phenomena referred to as
hydraulic, hydrodynamic, aerodynamic, graphical, "weather" and "climate'. The water vapor which has
analytical, kinematic, dynamic,, and stoichiometric, been a significant fraction of the earth's atmosphere
and other chemical (including organic) perspectives. has contributed to the complexity of these phenomena
since the range of temperatures with include the mean
Recreational reading had, from early childhood, equilibrium temperature of the earth's surface and
provided a succession of perspectives, including those atmosphere is conducive to the existence, of significant
of nursery rhymes, Bible stories, Aesop's fables, fairy fractions of this water in each of all three (gaseous,
tales, Indian legends, Greek and Norse mythology, liquid, and solid) states or phases, transitions between
history, geology (24), astronomy (22), cosmology which are accompanied by mutations between
(23), and atomic and intra-atomic physics (9). translational, vibrational and rotational heat, which are
Considered from those perspectives which seemed seen from the "empirical" and "thermodynamic"
"scientific" to me, in about 1940, I saw (and still see, perspective as "latent heats of fusion and
with a few revisions based on what I've learned since vaporization', and changes of specific volume in
then) energy transformations in the universe and the which heat is transformed into work and consequent
world about as follows: convection which transforms work into the kinetic
energy of wind.
Technical discussions should follow logical or
chronological sequences, preferably both. The The liquid water, which covered most of the earth's
sequence of my perspectives, as remembered after fifty surface, dissolved some of the gases and solids with
years, is neither. If I have failed in the following which it came into contact to become a "primordial
effort to put them in "proper" order, I hope that soup" in which many chemical reactions were bound
readers will be tolerant. to take place, producing a wide variety of chemical
compounds of varying complexity. It has been
In 1940, I was unaware of the "big bang" theory of postulated that, given "enough time', a molecule
the origin of the universe, which had been proposed would form which would be capable of reproduction
(by Le Maitre (5)) in 1927. (I was to learn, from and have the other characteristics of a living cell, and
Gamow, of the theory, a few years later.). However, that such cells would further organize themselves and
I had been aware and accepting of the adapt to their environments to evolve to the many
Chamberlin-Moulton theory that the planets, (including organisms which have existed on the earth. Statistical
the earth) of the solar system were the "drops" formed calculations (in the 1950s), which are cited by
in the "breaking" of a tidal wave raised from the "creationists', indicate that there hasn't been "enough
surface of the sun to a connecting arm by a passing time'. More recently, numerical models of
star, each of which was drawn together by gravity. In "coevolution', have reduced estimates of "enough
the contraction, gravitational potential energy was time" (26).
transformed into kinetic energy, which was, in turn,
transformed into work, and then, to heat, some of I have yet to acquire mathematical or computational
which was radiated as black body radiation, cooling techniques or perspectives from which I can consider
the planets until solid surfaces were formed, the with confidence the relative validity of the views of
355
"evolutionists" and "creationists", but, based on experimental, of the world and everything in it, and of
paleontolologicai evidence, I am persuaded that living all that has happened.
organisms have existed on the earth for billions of
years, which implies the presence of liquid water, and The word "efficient" seems to have originally, meant
that the equilibrium between radiant energy received "effective'. With the development of systems for the
(less than 0.05 % of the sun's radiation) and lost during transformation of energy from one form to another,
this period, would require radiation by the sun of a when preceded by a percentage, it has come to mean
quantity of energy which is credible only on the basis the percentage of available energy which has been
of the consideration that (as stipulated in Einstein's transformed as intended.
"Special Theory of Relativity') that mass (M) is a
form of energy (E) as related by: MY PRE-'41 PERSPECTIVES OF FIRE
E = Mc 2 (8)
As mentioned earlier in the section headed: "A KID'S
where c is the speed of light. PERSPECTIVE OF FIRE', my earliest impression of
fire was that of a yellow flame, which I generalized to
My view of energy transformations, past, present, and the view that fire and light are aspects of the same
anticipated, which seem relevant to the subject of this thing. Grown ups talked about "lighting" fires and
paper, is outlined below: about "firelight', usages which I adopted.
Mass is transformed, in the interior of the sun and Anyone who has tried will recognize the difficulties of
other stars, by thermonuclear reaction, to heat, which recalling how the world looked and what each word
is transformed, at or near the surfaces of the sun and meant in early childhood, without having one's
stars to "black body (electromagnetic) radiation'. A memories distorted by more recent learning and
fraction (referred to as the "albedo" of the plane0 of experience. In view of these difficulties, I'm sure that
the electromagnetic radiation which is intercepted by this account in not completely accurate (for example,
each planet is reflected. Most of the rest is in the final paragraph of the previous section headed
transformed into heat, and, eventually, reradiated as "LANGUAGES AND PERSPECTIVES" I quoted,
"black body radiation" (maintaining its surface adults, explaining that the visible "steam" from a
temperature equilibrium). Some of the radiation teakettle was not steam, but a suspension of droplets of
intercepted by the earth, is transformed, by liquid water, I included the words "colloidal" and
photochemical reactions (including photosynthesis) into "aerosol', neither of which are defined in terms
(chemical) potential energy, which, for the organic applicable to the explanation in a 1939 dictionary (2),
compounds synthesized in photosynthesis which are so they couldn't have been included in an explanation
used as fuels, is referred to as their "heat of to me in the 1920s), but it is the best that I can do.
combustion', and when they are used as foods as their
(nutritionist's) "calory content". In animals (including I could see the light and feel the heat of a fire and of
humans) the potential energy in foods referred to as the sun, and got the idea that light and heat are
"nutritionist's calories" is transformed into work and related, but not the same. If the fire was in a stove, I
heat by movement and metabolic processes. Fire couldn't see its light, but could feel its heat and,
transforms the "heat of combustion" of a fuel into the though I could see sunlight reflected from snowbank,
kinetic energy of molecules referred to by some as I didn't feel much heat.
"sensible heat'.
In time, I began to see that heat is needed to start a
Although neither prehistoric man nor I (as a kid) fire and that fire is a source of heat. The heating
considered such matters from these perspectives. elements of other sources of heat, like electric stoves,
Transformations of energy, by fire from chemical toasters, and space heaters, glowed when they were
potential energy ('heat of combustion") to heat, and hot enough, and I began to recognize that the light of
from heat to light, sound, work, and kinetic energy a flame was an effect of its heat. After seventy some
have been applied to form the basis of most "know years, I can't remember my introduction to the concept
how', trades, technologies, crafts, arts, and sciences, of an "ignition" or "kindling point" as a property of
and provided a series of perspectives, to and by each fuel, but I do remember my observation (which
mankind through prehistory and history, and to (by) is described in that earlier section) of "spontaneous
me in the course of growing up, education, combustion", which was the source of my reservations
recreational reading, and research, both literature and regarding that concept. Practical experience induced
356
me to accept the concept, with the reservations alluded define "convection" essentially as described above,
to. Paper was easy to light with a match, apparently The Random House Dictionary (1) defines it as "The
because its thickness was small compared with the transfer of heat by the circulation of the heated parts
dimensions of a match flame so that some of it could of a liquid or gas", with no mention of cause of the
heated to its 'kindling point'. As a Boy Scout, learning circulation. The term seems to be sometimes used in
to build a fire without paper, as required to pass the this latter sense.
second class firemaking test, I was taught to use twigs
or shavings of dimensions similar to those of a match I had been aware, since early childhood, that fire
stick to pick up the flame from the match. It took a required air. I'd watched while people "smothered"
few seconds, apparently, to heat the twigs to their fire, or blown or fanned fires to make them burn
kindling point. Once the twigs were burning, larger faster or hotter, and had been shown how to regulate
pieces of wood were placed in the flame, The larger a fire by adjusting a "damper". All of which prepared
sticks took longer to "catch fire', as I saw it, because me for the "chemical" perspective which is discussed
there was more wood to heat to its "kindling point'. It in the earlier section under that heading, and the
became apparent that the ignition and spread of fire recognition that the fire with which I was familiar was
depends upon the heating of the fuel to its kindling oxidation.
point by an external source of heat or the established
fire. As my perspectives changed between the several which
have been mentioned in the foregoing, my views of
I was told, when building a fire, to place the new fire and the changes of state and composition of
sticks or logs, above those which were already matter, and transformations and transfers of energy
burning, because "Heat rises.'. As I grew older, I between forms and locations involved, changed as if I
learned that the effective rise of "heat" was, more was "channel surfing" on a television set with a
accurately, stated as "Hot air rises." due to "zapper" (to use a metaphor which would have been
convection, which occurs because fluids, including air, meaningless in the 1930s). On rainy days, I'd seen
expand when heated, and become buoyant with respect water flow down hill, faster down steeper slopes.
to fluids of similar composition (but cooler.) I learned When I acquired a graphical perspective, and saw it
that other heat transfer mechanisms were conduction applied to hydrodynamics, electricity, and heat
and radiation. transfer, pressure, voltage, and temperature seemed,
almost always, to be plotted as vertical displacements
Like, I suppose, most people, both living and dead from the origins of graphical representations of the
(some for long times), I had experienced heat transfer spatial distribution of these quantities. By analogy to
by all three mechanisms since early childhood. My water "seeking its level" I saw fluids, electricity, and
early experiences with light and "radiant heat" (which, heat flowing downward, from points or regions of high
I learned, after a few years, is called "infrared pressure, voltage or temperature at rates proportional
radiation" in the language of physics), are recalled a to (and in the direction of) the gradients (or "slopes")
page back. We have all felt the heat conducted from of these quantities. I have recently learned that this
warm and hot objects. In the kitchen, heat is view of heat transfer (as seen from the "empirical"
conducted by a frying pan, from the burner to the perspective) led Lavoisier and, later Math, to see heat
food, in toasting and broiling, heat is transferred by as a fluid (5).
radiation. Boiling and baking involve convection.
As I remember at the time of this writing, the
Convection is utilized in a hot air heating system, to perspectives I gained from play with a chemistry set
transfer the heat, from the furnace in the basement, was more accurately characterized as an "alchemic"
through a duct system to living quarters on the floors than as a "chemical" perspective. Like the ancient and
above, and, for fireplaces, and coal and wood furnaces medieval alchemists, I followed recipes and observed
and stoves to provide the "draft" of air needed to keep reactions. The operations of the "Universal Research
the fire burning. Laboratories", which are also mentioned in that section
were, like Roger Bacon's thirteenth century
My memories of youthful impressions of heat transfer experiments with gunpowder (4), more alchemy than
and, more specifically, convection are outlined above. chemistry.
In the course of the recall, it occurred to me to check
recent references regarding the current meanings of the Although I may have acquired a (somewhat indistinct)
words. Dictionaries, both 1939 (2) and 1976 (16) chemical perspective from the activities mentioned
357
above and recreational reading, my high school movement is communicated by effectively elastic
chemistry course clarified my chemical perspective and collisions between molecules,
presented a few glimpses from the "intermolecular"
perspective mentioned under that heading. Although the view of heat transfer as seen from the
"intermolecular" perspective, as described above, was
From the "intermolecular" perspective, it became more consistent with the structure of matter in its
apparent that even so simple a reaction as that depicted various states, as seen from this perspective,
in equation (1): quantitative consideration would involve too much
complex computation (since it would have to take into
2H2 + 02 "-* 2H20 (1) account the variation with relative directions of the
is not the single step reaction implied by the intermolecular, interionic, and interatomic attraction
stoicheometic equation (1). Each oxygen molecule and repulsion forces) for practical purposes.
must be dissociated to provide the single oxygen atom
for each water molecule. Based on models of water Like most students, I learned to consider heat transfer
molecules, such as those shown in Figure 1, in which from the empirical perspective (from which Lavoisier
the hydrogen atoms are on opposite sides of the much and Mach had seen heat as a fluid), which is a more
larger oxygen atoms, it seemed that the hydrogen practical approach to heat transfer calculations. Such
molecules also must be dissociated to be oxidized. consideration, for engineering purposes (11), yields:
q = kA(Ti-T2)/x (9)
I don't remember how or when, but at some time
before I graduated from high school I became where: q is the rate of heat transfer through a panel
convinced that heat is molecular motion, the nature of of area A and thickness, x, and T_ and T2 are
which has been discussed herein. In the solid state, temperatures on either side of the panel,
where crystalline bonds hold the molecules in their while k is the thermal conductivity of the
relative positions, only vibration about its equilibrium substance of the panel.
position is possible for each molecule (or atom). With
increasing temperature, the amplitude of the vibration The value of k can be determined experimentally by
is sufficient to move each molecule so far from its measurements of q when values of other variables are
equilibrium position that the crystalline bonding force preestablished.
can no longer restore it, and the solid melts. In the
liquid state, molecules are free to move relative to one For purposes of theoretical consideration of systems in
another, but are drawn together by the "van der Waals which heat transfer is a factor, equation (9) can be
force', further increase in temperature results in generalized as a partial differential equation:
movement beyond the effective range of this force and
q = - k A [0T/ax] (10)
the liquid was said to "boil" or "vaporize'. In the
vapor or gaseous state, molecules are separated and in vector notation as:
sufficiently that they move independently until they q =-kAVT (11)
collide, as can be seen from the perspective of the
Maxwell-Boltzmann kinetic theory of gases.
I gained this perspective of heat transfer, by
conduction, several years after I had learned to build
Considered from the perspectives outlined in the fires as a Boy Scout. From this perspective, in
foregoing paragraphs, I saw heat conduction to be the combination with the concept that each fuel has a
result of essentially mechanical interactions of "kindling point" and heat capacity, I began to see why
molecules and atoms. In a solid, the vibration of each
the techniques I had learned as a Boy Scout were
molecule about its equilibrium position is
effective and necessary.
communicated to its neighbors by the same crystalline
binding forces that establish their equilibrium relative A log or large piece of wood can't be "lit" with a
positions. In a liquid, the molecular motion is match because, although the temperature of the flame
communicated mostly by the van der Waals is well above the "kindling point" of the wood, its
intermolecular attraction force and the intermolecular
thermal conductivity is much lower so that the
repulsion which determines the effective volume of
temperature at the surface attains an equilibrium such
each molecule and hence the specific volume of the that the rate at which heat is conducted into the wood
liquid. In a gas, viewed from the perspective of the is equal to that at which it is conducted from the
Maxwell-Boltznmnn kinetic theory of gases, the
flame. Paper, twigs and shavings can be lit because the
358
heat transferred from the flame is conducted through window and showed me a blackened fmger tip. She
the fuel only a short distance until it reaches another identified the black stuff on her fmger as "soot"
surface from which it is conducted by air, whose which, she explained, had settled out from the black
thermal conductivity is equal to or less than that of the smoke, which came from chimneys of building in
flame, so the heat accumulates in the paper, twigs, or which, she said, "soft coal" was burned. It seemed to
shavings until the "ignition" or "kindling point" is me that grey smoke must be a mixture of black smoke
reached. and white smoke, but, from its odor, I was sure that
all smoke contained something else.
While the view of ignition, from the perspective of
thermal conduction, outlined above, explained some of Consideration of the observations, experiences and
my experiences as a Boy Scout, they left some hearsay mentioned in the foregoing paragraph from my
observations unexplained. From the perspective of developing chemical perspective resulted in views of
"states" of matter, which are discussed earlier herein, fire and smoke which I found satisfying. Although I
it is apparent that, although most of the fuels discussed questioned that "where there's smoke there's fire.',
above are solid, the flames, like the visible "steam" it was apparent that, where there was smoke, fire
from a teakettle, the clouds in the sky and most of the could be expected. If the overload which caused an
white "smoke" which rose from a burning pile of extension cord to overheat wasn't removed, the cord
damp leaves, seemed to be lighter than air. As would soon "burst into flame'. By analogy to the
mentioned in the earlier section headed formation of the aerosol referred to as visible "steam"
"LANGUAGES AND PERSPECTIVES" I was told beyond the spout of a teakettle, I reasoned that
that the visible "steam', white "smoke" and clouds, as something in the insulation of the extension cord (bare
well as fog and mist, were droplets of liquid water too wires, when heated by electric current, don't emit
small to settle out, and referred to as "colloidal smoke) must have evaporated and condensed, after
suspensions" as were similarly suspended droplets and mixing with cooler air, to form the droplets of the
particles of other substances. Grey, brown and black colloid referred to as "smoke'. Reflecting on earlier
smoke are such suspensions of other substances as is experiences and observations, some of which have
evidenced by their odor, while flames are suspensions been mentioned hereinbefore, I recalled that, when
of carbon which is so hot it glows. The droplets and organic substances are heated, smoke often appears
particles are too widely scattered to have as much before flame.
effect on the density of the air as the heat (from the
fire.'?), so the "steam', "smoke" and clouds floated The word "organic', like many others, has a number
upward. This upward movement of flames, often of meanings, the most general of which is "Arising
referred to, by poets, novelists, and journalists, as from an organism.'(2). Organic chemistry is
"leaping', and in technical discussion as "convection', essentially the chemistry of carbon, which owes its
plays a role in the propagation of fire, as mentioned, complexity to four "covalent" bonds whereby carbon
a page or so back, in the account of my recollections atoms bond with one another, and those of other
of Boy Scout firemaking. elements to form a wide variety of molecules (aver
15000 of which are listed in the Handbook of
I don't remember when I first heard the aphorism, Chemistry and Physics (10)). Because carbon atoms
"Where there's smoke there's fire. ", but I'm sure that combine in several ways,it is possible for different
it was before my twelfth birthday that I began to molecules (of compounds with different properties) to
question its (absolute) truth. I'd seen smoke coming have the same composition in terms of the numbers of
from overloaded extension cords, and stop after the atoms of carbon and other elements. For this reason,
appliances which had overloaded them were organic compounds are usually identified by structural
disconnected. I'd seem pictures of smoke (identified as formulas which are, essentially, diagrams or models of
such) coming from volcanoes although I hadn't been their structure. It is quite apparent, from
told of any underground source of the air which would consideration of such structural formulas, that many
have been needed to sustain a fire. I wondered what organic molecules are too large and irregular in shape
smoke was. The white smoke, from burning damp to bounce around like "tiny billiard balls" (as Maeh
leaves was obviously, like visible "steam", fog, mist, characterized the picture presented by the
and clouds, a colloidal suspension of liquid water, but Maxwell-Boltzmann kinetic theory of gases) but are
the grey, brown, and black smoke were something more likely to break into smaller molecules. In other
else. I was a few years younger, when an aunt, who words, some organic compounds tend to decompose
lived in an in-town apartment, reached out of her rather than evaporate when heated. (I became
359
somewhat dimly aware of such matters at an early age If and when the smoke was further heated, the gaseous
because of my father's involvement in the development decomposition products of the wood, such as methane
and construction of "cracking stills" in which large (CH4), ethane (C:Ht), propane (C3Hs), carbon,
molecules of crude oil were "cracked" into the smaller hydrogen, etc. oxidize, raising the temperature still
molecules needed in gasoline.) higher, decomposing and oxidizing the compounds
which had condensed to form the droplets of the
The familiar fuels are organic materials (in the sense colloidal suspension referred to as "smoke'.
of "Arising from an organism. "(2)). As such they are
composites of a number of substances (Mostly organic Most decomposition products of the organic substances
compounds of carbon, hydrogen, and nitrogen, in commonly used as fuels are in gaseous or plasma
solid, liquid, and gaseous states. Wood, for example states at temperatures associated with combustion.
is a mixture of cellulose, which is "made up of The most notable exception is carbon, which is solid
long-chain molecules (fibers) in which the complex at much higher temperature. The charcoal, which is
unit CcLIl005 is repeated as many as 2000 times" (17), the most familiar decomposition product of wood is
lignin (C41H3206) sugars, resin, acetic acid, water, air, mostly carbon. The glowing coals which remain after
and other substances. the flames have subsided are mostly carbon, which
continues to burn while oxygen is available. Enough
When a campfire had subsided to glowing coals and, of the heat of combustion is transferred from the
for one reason or another, a hotter fire was desired, a carbon dioxide, which is the reaction product, to the
few sticks of kindling were laid over the glowing oxygen of ambient air and unburned carbon to
coals, In few minutes (particularly if the glow was maintain the reaction and the glow, which is black
brightened by blowing or fanning the coals, the body radiation. Similarly, the organic substance of the
"kindling" began to emit smoke, which, a minute or droplets of the colloidal suspension referred to as
two later, burst into flame. I had noticed that the smoke decompose to the gaseous products mentioned
smoke appeared before the flame. above, and the small particles of carbon, referred to as
"soot", whose colloidal suspension in air is called
Consideration from perspectives hereinbefore "flame', when it glows, and "black smoke" after it
discussed, particularly the "chemical" perspective and cools enough to stop glowing.
that form which "states" of matter are viewed, led me
to see the sequence of observable phenomena outlined As mentioned a few paragraphs above,the "smoke"
above as resulting from the following sequence of emitted by heated wood is a colloidal suspension of
chemical and physical events: volatile components of the wood. Their composition
varies from one species of wood to another. Many
The "kindling" was heated by radiation and convection have proven useful. Perhaps the best application of
from the glowing coals. When it reached temperatures wood smoke is to the preservation of food, such as
conducive to such processes, volatile components of ham, bacon, and fish.
the "kindling" began to evaporate and nonvolatile
components decomposed to volatile compounds which The flavor of smoked meat has been sufficiently
evaporated. The vapor, mixing with cooler air popular to inspire the invention of the "pit barbecue"
condensed to form the droplets of the colloidal on which meat is smoked while it is broiled and
suspension (or "aerosol') referred to as "smoke'. roasted, although preservation is not a consideration
Further heating brought the smoke to its "ignition because the food is eaten while it is still hot. Hickory
point" so it "burst into flame" . and mesquite smoke seem to be most popular for these
purpose, as well as (in condensate form) as flavoring
The above description satisfied me in 1940, and it still for barbecue sauce, etc.
does except for my continuing reservation regarding
the concept of "ignition points" and the colloquialism Other volatile components of wood, which are
of the phrase "burst into flame" and its implication of undoubtably seen as wood smoke but may not
an "eyewitness" rather than a "chemical" or "physical" condense to "smoke" before they are condensed to
perspective. liquids in stills, are turpentine, which is used as a paint
thinner and brush cleaner, and creosote, which is used
These misgivings were alleviated by replacing the fmal as a wood preservative and harsh disinfectant (17).
sentence (which included the dubious phrases) with the
following continuing description:
360
The last couple of pages contain descriptions of fires the process includes the "piling up" of the matter for
with which I was most familiar before 1941, in which long periods of time.
wood or paper were the fuels, as I saw them from
several perspectives. I was also aware of combustion In the course of the millions of years during which
of other fuels to which some parts of these descriptions coal and petroleum have been forming, various
are not applicable. geological events and processes, including volcanic
eruptions, earthquakes, and continental drift, have
I was aware that although most of the other fuels I had occurred, resulting in deformation of the earth's crust
seen burning were of organic origin, they tended to and the formation of mountain ranges and
have properties more similar to the intermediates of displacement of continents, in the course of which
wood burning than to the wood itself. Most were some of the forming coal and petroleum were covered
gaseous, volatile, or colloidal suspensions, like by layers of rock, which sealed pockets of the gaseous
components of wood smoke, or mostly carbon and products of the decomposition of organic matter
ash (like charcoal), when visibly burning. whereby the coal and petroleum are formed. These
trapped gases are known as "natural gas".
I had heard coal, petroleum, and natural gas referred
to as "fossil fuels', meaning that they were the Some fossil fuels are used as recovered. Coal is
remains of prehistoric organisms which had burned in furnaces to heat buildings, and in boilers of
decomposed and been buried by such geological locomotives, ships, and power plants to generate
processes as volcanic eruption and sedimentation. I steam. Natural gas is distributed through pipes to
had seen the beginning of the formation of coal in the residences and other buildings where it is the fuel for
peat bogs of the upper midwest, many acres of spongy furnaces, space heaters, cook stoves, fireplaces, and
moss, where a misstep could result in a foot coated, refrigerators.
almost to the knee, with dark brown rotted moss,
referred to as "peat', which, in the United States, is Some coal, generally bituminous coal, is heated in
used as fertilizer and (dried) as thermal insulation, kilns, to continue the process of decomposition to
packing, and "potting soil" for plants, but in countries gaseous hydrocarbons (methane, ethane, etc.), which
where other fuels are expensive, dried peat is used, in are referred to as "manufactured gas" and distributed
large quantities, as fuel. The top layers in a peat bog through pipes in communities beyond the range of
are of relatively low density, but, at greater depths the natural gas distribution pipelines, and carbon and ash,
older peat, which has been rotting longer and known as Ncoke', which is sold as household fuel, and
consolidated by the combination of increasing pressure used in blast furnaces in which iron ore is reduced to
and the upward diffusion of water and other low "pig iron', some of which is remelted and cast, to
density (compared with that of carbon [3.51]) liquids make the wide variety of cast iron items with which
and gases (most of which are products of the we are all familiar, but most of which is converted to
continuing decomposition (rotting) of the peat). Gases steel by oxidization of most of its carbon content in
diffuse to the air above as "marsh gas" (which Bessemer converters or open hearth furnaces. Much
sometimes catches fire and is referred to as "will o' of the gas from coke ovens of iron works is used as
the wisp" or "ignis fatuus'). With the passage of the fuel of large (at the Engine and Condenser
time, the growth of the moss continues, piling up more Department of Allis-Chalmers, where I had a summer
peat, so that at the bottom continues to consolidate job in 1937, there was an eight foot bore by twelve
while decomposing, and its density, carbon content, foot stroke engine, for this purpose, on the drawing
and hardness increase with time and depth and the peat boards) internal combustion engines, which drive the
is changed, progressively, to lignite, bituminous and, blowers for the blast furnaces, etc.
finally, anthracite coal.
Petroleum is a mixture of hydrocarbons, which are
Petroleum, like coal, is a product of decomposition separated, by distillation, into gases, including
(decay) of organic matter, in this case, marine animals methane, butane, propane, and pentane, liquids,
and plants, which, because of their much lower including naphtha, gasoline, kerosene, and fuel and
oxygen/hydrogen ratio than the peat moss, which is lubricating oils, waxes, and asphalt. Asphalt, wax,
mainly cellulose (a carbohydrate (or hydrate of carbon, and the "heavy" (viscous) oils owe their properties to
which can decompose to carbon and water)) tends to the large size and complexity of their molecules,
decay to hydrocarbons. As in the formation of coal, which, since the 1920s have been "cracked', at high
temperature and pressure (which can be reduced by
361
using catalysts) to the smaller molecules of the more Most of the fires which I'd seen consisted of flames,
volatile compounds needed for internal combustion which behaved as gases or colloidal suspensions (like
engines. smoke), and/or glowing coals. Clearly, most solid and
liquid filets volatilize as part of the combustion process
Not long after I'd learned to read, I discovered "car which showed me that more than the single step,
cards', - advertising posters mounted in a row over implied by stoichiometric equations, such as Equations
the windows of a street car. One of these (advertising (1) and (2), are involved in the process. In the
"Carbona', a dry cleaner) included a picture of a burning of gunpowder, expressed in equation (2):
woman, with an article of clothing in one hand, flying
through clouds, with the caption, "You can go twenty 2KN03 + C + S -_, C02+SO2+2KO + N2
miles on a gallon of gasoline" as at least one
automobile maker claimed at that time. My mother the potassium nitrate (KNO3) molecules must
explained the point of the ad - that gasoline vapor dissociate to provide the oxygen atoms to oxidize the
could form an "explosive mixture" with air, but carbon and sulfur. Considered from the "interatomic"
Carbona doesn't. That night, my father explained that perspective, which has been discussed herein before,
Carbona is carbon tetrachloride which, though volatile, it seemed that the oxidation of hydrogen must follow
like gasoline (so it is useful for dry cleaning) but, the dissociation of the oxygen molecules, and probably
unlike gasoline, it was not enflammable (gasoline those of hydrogen. I began to see fire, except where
forms explosive mixtures with air because it is highly elemental carbon, as coal, coke, or charcoal, or in a
enflammable). similar form, is the fuel, is a multistage process. The
decomposition, melting or sublimation, and/or
I accepted these explanations because they came from evaporation, and condensation to the aerosol referred
my parents, but didn't fully understand them at that to as "smoke', precedes its further decomposition,
age (between six and ten). The distinction between dissociation, oxidation, and ionization, the effects of
"enflammable" and "volatile" was unclear (as it still which are seen as the flames of familiar fuels (except
seems to be to some television news reporters). My carbon in its various forms).
father, sensing my perplexity, pointed out that
"enflammable" meant "easily ignited to burst into By 1940, I had acquired enough of the vocabulary of
flame" while "volatile" meant "easily evaporated'. chemistry to understand that chemical processes and
My view of the subject was obfuscated by the frequent changes of state were either "exothermal"
spelling of "enflammable" as "inflammable', and the (characterized by the evolution of heat) or
apparent interchangeability of the prefixes "in-', "endothermal" (characterized by the absorption of
"un-', and "non-'. (It would be fifteen years before heat) and was aware that freezing, condensation, and
I saw less ambiguous word "flammable" on a tank the formation of most molecules by joining atoms,
truck.) The meanings of such words as "explode', ions, or "free radicals" are exothermal, while melting,
"explosion" "explosive', "detonate', and "detonation" sublimation, boiling and other evaporation or
and "detonable" were unclear to me then as they still vaporization, decomposition, ionization, and
seem to be to many. I am often, still, unsure what dissociation are endothermal. I came to recognize that
others mean by them, although I now think I know "ignition" or "kindling', considered from the
what I mean. perspective outlined above, from which fire is seen as
a multistage phenomenon, occurred only after
Consideration of such matters from the various sufficient heat had been transferred to a fuel element
perspectives, acquired in the coarse of education, to result in the necessary succession of endothermal
reading, conversations, and basement and backyard processes (which is unique for each fuel), and maintain
activities, clarified my views of fire, while presenting the exothermal oxidation until the evolution of heat
new perspectives, consideration from which led to from the latter is sufficient to heat the "soot" (the
other pictures, some of which were somewhat "fuzzy', particles of carbon which are products of the
leading to further research (literary, experimental, or decomposition of the colloidaily suspended droplets of
analytical), a sequence which continues to this day. hydrocarbons called "smoke') to the incandescence
visible as "flame'. Fire, in general, stabilizes when
Following is an effort to summarize my picture of fire, heat losses reach equilibrium with evolution of heat.
as I now remember seeing it, in 1940 (which was two When losses exceed evolution of heat, a fire "dies
years after my graduation as a mechanical engineer): out'. When the evolution of heat exceeds losses and
continues to do so, the fire is self accelerating. A few
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years later, the course of "literature research at the and development of systems of which pyrotechnics and
Naval Ordnance Laboratory, I was to read of such a explosives are components.
self accelerating fire referred to as a "thermal
explosion" (which will be discussed in more detail a Although, in 1940, my impressions of explosion and
few pages hence), but, in 1940, "explosion still meant detonation were not very clear, I could see, from a
to me, as it had since I learned the word, a "bang" heuristic perspective of the Maxwell-Boltzmann kinetic
and a flash and an impulse which could throw things theory of gases (as I understood it) that the combustion
around (As a kid, I had seen tin cans, propelled by of an "explosive mixture" of gaseous fuel and air is
firecrackers, fly higher than a house.), and some tines the effect of random intermolecular collisions of
broke them. Dictionaries (1,2) gave "detonation" as sufficient magnitude to break (dissociate) molecules in
a synonym of "explosion', and an encyclopedia (15) into atoms, ions, free radicals. I saw that, in this
stated that "detonation is a distinct phenomenon in state, hydrogen and carbon atoms and/or ions can bond
which the chemical transformation is induced in every to those of oxygen to form carbon dioxide and water,
particle at the same instant'. Even then, I didn't processes which are exothermal (evolving heat) - the
believe that. I already saw fire as the Multistage kinetic energy of molecular motion) thus increasing the
phenomenon described above, of which each stage frequency of collisions of sufficient magnitude to
takes time. I had heard the combustion of an internal initiate the sequence outlined above in the previously
combustion engine referred to as "an explosion" (at the unreacted fuel/air mixture. I saw that this sequence
beginning of each power stroke), and the anti-knock should be expected to propagate at a velocity close to
property of Ethyl and other high octane gasoline the average of those of the molecules (which is about
ascribed to the fact that it was "slower burning" than that of sound).
regular. However, having considered the Otto cycle
(which is employed in most automobiles), I was aware Consideration of the heuristic model, described above
that even high octane gasoline burned fast enough that from a quantitative perspective, would have required
the reaction was complete before the piston moved statistical analysis beyond my abilities. Perhaps I
enough that the volume change had to be considered in could have clarified my view by consideration from
thermodynamic calculations, but "regular" , in a high acoustical, hydrodynamic, and/or fluid mechanical
compression engine, burned so fast that the resulting perspectives, to each of which I had been introduced,
rapid pressure increase is propagated through the but I didn't make such an effort until, at N.O.L., I
cylinder head to the air as a sound or "shock" wave. was engaged in explosive research, the course of
Waves had been familiar to since early childhood, which I learned that others, including Rankine (whose
when I saw them on water. My dad built a radio steam engine cycle I had learned of in thermodynamics
before I was ten and I soon learned to estimate where courses) had done so in the nineteenth century.
to set the dials from the wavelength of each station,
published in the paper. I heard that radio waves were My earliest impressions of fire were effects of
waves in "ether" but, before I found out what "ether" observations of and experience with such familiar fuels
was, I read about the Michelson-Morley experiment, as paper wood, coal, charcoal, candle wax, and
which showed that there was no such thing. As a gasoline. I had became convinced that air is essential
teenager, I had built audio equipment, including to fire. It didn't take long for experience with
amplifiers and recording equipment, in the course of fireworks (which available, in late June and the first
which I acquired practical, empirical, and graphical three days of July, in the 1920s, at grocery and drug
perspectives of sound, which prepared me for stores, to any kid with a dime), to cast doubt on this
acoustical and analytical perspectives of sound I was to conviction. My experience, at the "Universal
learn in physics courses. In 1940, I was aware that Research Laboratory" (as a fourth grade classmate
both "explosion" and "detonation" are derived from referred to his basement) in the preparation of black
Latin words describing sounds (those of clapping and gunpowder, which burned quite vigorously in a rocket
thunder respectively), and that both referred to sudden (which was lacking in aerodynamic stability and
fire (sudden enough that the pressure rise, due to the tumbled a few feet off the ground). I can't say, at this
heat evolved, was propagated as a sound wave, from time (1995) whether, at that time (1926), I understood
which I inferred that the reaction was completed) in a why gunpowder could barn without air, although other
small fraction of a second (the maximum period of a fuels couldn't. However, by 1940, I had learned that
sound wave), but my mental pictures of the processes the burning of familiar fuels is oxidation, requiring the
were rather indistinct until, as a participant, at the oxygen of air, but that gunpowder, as well as other
Naval Ordnance Laboratory (N.O.L.), in the research explosives and pyrotechnics, burned without air
363
because they contained oxygen as a component of concern to all involved in the manufacture and
relatively unstable compounds, such as potassium application of pyrotechnics and explosives.
nitrate. Thus, I saw, the burning of gunpowder is a
multistage reaction (one stage of which is the Although, from instruction, conversation, and "hands
decomposition of the nitrate) which, in fuses, is too on" experience, I had acquired some "eyewitness',
slow to be called "an explosion'. "common sense', "practical', and "empirical"
perspectives of such matters, I felt a lack of applicable
In 1940, World War II had become the "Battle of "chemical", and "scholarly" perspectives. The EAU
Britain', Japan was rearming the invading Asiatic had no official library, but I had noticed a number of
neighbors, and the U.S. armed services were engaged books on ordnance, explosives, and pyrotechnics on
in an effort to regain and surpass the preparedness lost desks and shelves, which I borrowed and read. One,
as the result of the pacifism and disarmament which caught my eye was The Chemistry of Powder
following World War I. Pursuant to this effort, the and Explosives" (4), by Tenney L. Davis (who had
U.S. Naval Ordnance Laboratory (NOL) recruited been the lecturer of my second semester freshman
over 1700 scientists and engineers, of which I was chemistry course). The book was intended to be a
one. textbook for a graduate course on the subject, the
book includes ( in the 1941 edition) chapters on
FIRE, AS I SAW IT AT NOL (EAU) PROPERTIES OF EXPLOSIVES, BLACK POWDER,
PYROTECHNICS, AND AROMATIC NITRO
Arriving at NOL, in early 1941, I was given new COMPOUNDS. It starts by defining an "explosive as:
perspectives, particularly of fire, too frequently to "a material, either a pure of single substance or a
retrace after fifty-odd years. My first assignment, at
mixture of substances which is capable of producing
NOL, was to the Propellant and Pyrotechnics Group of
an explosion by its own energy".
the Experimental Ammunition Unit (EAU), where I
worked with an "ordnance man', directed by the "It seems unnecessary to def'me an explosion, for
pyrotechnics specialist on the adaptation of display everyone knows what it is. -- a loud noise and the
fireworks for use as signals (such as "Submarine sudden going away of things from where they had
Emergency Identification Signals'). My principal been --".
assignment, in that group was design and drafting, but
I spent some time in the laboratory, where we did As I read it, I accepted it, but soon began to recognize
some preparation, fabrication, and testing of that, as with many words, although everyone knows
pyrotechnic mixtures, systems, subsystems, what "explosion" means, it doesn't necessarily mean
components, etc. Our approach, in such adaptation, the same to everyone. Recently, a steam automobile
was generally that of "trial and error" or, to dignify it, enthusiast told me that "Explosion is the most
"Edisonian research'. Based on the view, from the inefficient form of combustion', implying, I support
"practical" or "common sense" perspective, that that a steam automobile should be more efficient than
mixtures and practices which had been used, with one with an internal combustion engine. Do those
success, by others, were most likely to serve our who talk about "the population explosion" mean "a
similar purposes, we usually followed recipes, some loud noise - etc." or "the most inefficient form of
dating back to those of medieval alchemists and combustion'?
ancient Chinese artisans. On occasion, we tried to
improve mixtures by application of stoichiometry, but Davis, in the first chapter on PROPERTIES OF
experience tended to confirm the above mentioned EXPLOSIVES, points out that, although an explosive
view, from the "practical" perspective. It was can produce an explosion by its own energy, it can
apparent that more than stoichiometry was involved. liberate this energy without exploding (as black
We noted that the behavior and properties of powder does in a fuse). Here, he injected an
pyrotechnic mixtures were affected by the granulation explanation of the difference between a "fuse" which
of their ingredients as well as the densities to which is a device for communicating fire" and a "fuze",
they were loaded. Of the properties so affected, which is a device for initiating explosion (usually
sensitivity, which includes their susceptibility to "detonation') of the "bursting charges" of shells,
initiation by the stimuli available for this purpose when bombs, mines, grenades, etc.'. A section of the first
intended, as well as that to initiation by accidentally chapter on PROPERTIES OF EXPLOSIVES headed,
applied stimuli (and resulting hazards), is of primary Classification of explosives includes paragraphs
(condensed below) on:
364
I. Propellants, or "low explosives" which (in their temperature. In a confined space the combustion
usual application) bum but do not explode, and becomes extremely rapid, but it is believed to be
function by producing gas which produces an combustion in the sense that it is a phenomenon
explosion (by busting its container, such as the paper dependent upon the transmission of heat."
tube of a Chinese firecracker or the metal case of a
bomb). Examples: black powder, smokeless powder. "The explosion of a primary explosive or of a high
explosive, on the other hand, is believed to be a
II. Primary Explosives or "initiators", which explode phenomenon which is dependent upon the transmission
or detonate when heated or subjected to shock. of pressure or, perhaps more properly, upon the
Examples: mercury fulminate, lead azide, lead salts of transmission of shock. Fire, friction or shock, acting
picric acid, etc. upon, say, fulminate, in the first instance cause it to
undergo a rapid chemical transformation which
III. High Explosives, which detonate under the produces hot gas and the transformation is so rapid
influence of the shock of the explosion of a suitable that the advancing front of the mass of hot gas
primary. Examples: dynamite, TNT, tetryl, picric amounts to a wave of pressure capable of initiating by
acid, etc. its shock the explosion of the next portion of
fulminate, and so on, the explosion advancing through
It is pointed out that these classes overlap because the the mass with incredible quickness. In a standard No.
behavior of explosives is determined by the nature of 6 blasting cap, the explosion proceeds with a velocity
the stimuli to which they are subjected and by the of about 3500 meters per second."
manner in which they are used. Nitrocellulose,
"colloided" such smokeless powder, is a propellant, as "If a sufficient quantity of fulminate is exploded in
compressed guncotton, is a powerful high explosive, contact with trinitrotoluene, the shock induces the
and, as lower density guncotton, has been used as the trinitrotoluene to explode, producing a shock adequate
"flash charge" of electric detonators, TNT, to initiate the explosion of a further portion. The
nitroglycerine, and other high explosives have been explosive wave traverses the trinitrotoluene with a
ingredients of smokeless powder. Mercury fulminate velocity which is actually greater than the velocity of
can be "dead pressed" so that it loses its power to the initiating wave in the fulminate. Because this sort
detonate from flame. of thing happens, the application of the principle of the
booster is possible. If the quantity of fulminate is not
A review of the foregoing two pages has led me to sufficient, the trinitrotoluene either does not detonate
recognize the need for an explanation. Although the at all or detonates incompletely and only part way into
discussion FIRE AS I SAW IT AT NOL (EAU) is, as its mass. For every high explosive there is a
implied based on my memories after fifty-some years, minimum quantity of each primary explosive which is
the review of Davis's book (4), is a reflection of needed to secure its certain and complete detonation.
current "browsing" through a copy at hand. The The best initiator for one high explosive is not
quotations enclosed in quotation marks, including the necessarily best initiator for another. A high explosive
following, are direct copies. is generally its own best initiator unless it happens to
be used under conditions in which it is exploding with
"Propagation of Explosion" its maximum "velocity of detonation".
"When black powder burns the first portion to receive The section of Davis's book quoted above presents
the fire undergoes a chemical reaction which results in views of explosion and detonation from "common
the production of hot gas. The gas, tending to expand sense" and "empirical" perspectives. I am sure Davis
in all directions from the place where it was produced, was aware of "theoretical", "analytical"
warms the next portion of black powder to the kindling "hydrodynamic', etc. views which had been expressed
temperature. This then takes fire and burns with the in the previous century or more, but confined his
production of more hot gas which raises the description to views from perspectives with which, he
temperature of the next adjacent material. If the black felt confident, his students and other readers of his
powder is confmed, the pressure rises, and the heat, book would be familiar. References to the "kindling
since it cannot escape, is communicated more rapidly temperature" and the "doubling of reaction rate for
through the mass. Further, the gas- and heat- every 10 ° rise of temperature" are evidence of an
producing reaction, like any other chemical reaction, "empirical" perspective based on standardized tests
doubles its rate for every 10 ° (approximate) rise of
365
similar to those described a few pages on in the first The use of high speed photography and cathode ray
chapter of the book (4). oscillographs, in measurement of detonation velocity,
are mentioned as recent developments.
The section of Propagation of Explosion is followed
by a section on Detonating Cord which is also The section on Sensitivity Tests includes descriptions
referred to as "cordeau" (after the French "cordeau of "impact" or "drop" tests in which (typically) the
detonant") and "Primacord" (a trademark of the height is determined which will result in the explosion
Ensign Bickford Company), a narrow tube filled with of a sample of the explosive being investigated
high explosives whose principal use in blasting is the contained in a hole in a block of steel, when a two
simultaneous (or in close sequence) initiation of kilogram weight is dropped on a plunger in contact
detonation of two or more explosive charges. It cam with the explosive sample.
also be used to fell small trees as had been
demonstrated in an ROTC class I had attended a few Also described in a test of "temperature of ignition" or
years before. "explosion temperature" in which a blasting cap cup
containing a sample of an explosive is thrust into
The fn'st chapter of "The Chemistry of Powder and Woods metal which has been heated to a known
Explosives" (4), entitled PROPERTIES OF temperature. The procedure is repeated, with varying
EXPLOSIVES also includes descriptions of temperatures, until the temperature is determined at
experiments, which can be performed in a college which the sample explodes or is ignited within five
chemistry laboratory to demonstrate some of these seconds. In another test which is also described, the
properties, as well as standardized tests for them, and blasting cap cup containing the explosive being tested
cites U.S. War Department Technical Manual TM is dunked in Wood's metal at 100°C and the
2900 "Military Explosives" (25) and a number of temperature is raised at a steady rate until the sample
Bulletins and Technical Papers of the U.S. Bureau of ignites or explodes. The temperature at which this
Mines in which such standardized tests are described occurs is considered to be the "ignition" or "explosion
in more detail. Properties for which tests are temperature". When the temperature is raised more
described in this chapter include Velocity of rapidly, the inflammation occurs at a higher
Detonation Sensitivity (including "explosion', temperature". (As is illustrated in an accompanying
"ignition', or "kindling" temperature and impact table).
sensitivity) and Tests of Power and Brisance.
In the section on Tests of Power and Brisance a
The section on Velocity of Detonation begins with a definition of neither "power" nor "brisance" is
paragraph in which the subject is considered from the included. It seems that, as with "explosion", Davis
"empirical" perspective of the time (ca 1940), which assumed that it was unnecessary to def'me "power"
no longer seems relevant. It mentions detonation because everyone knew what it meant, while, in my
velocity measurements by Berthelot and Vielle, who view, as with "explosion", although everyone knew
used a "Boulenge' chronograph" which is not what "power" meant, it didn't mean the same to
described, except for the mention that its (lack of) everyone. (Dictionaries I've consulted (1,2,16)
precision was such that they were obliged to employ include from eight to seventeen def'mitions).
long columns of explosives'. It goes on to say, "The "Brisance" on the other hand, is not listed in a 1939
Mettegang recorder, now commonly used, is an unabridged dictionary (2). More recent dictionaries
instrument of much greater precision and makes it (1,16) define it as "The sudden release of energy by a
possible to work with much shorter charges'. The explosion', or something similar. Although "brisance"
Mettegang recorder is described as an instrument wasn't defined in Davis (4) or the dictionaries I
whereby time is determined as proportional to the consulted (2), it didn't take long for me to grasp its
distance (measured with a micrometer microscope) meaning, whether from conversation, recognition
between marks made on a rapidly moving smoked (having studied French in high school) that it was
metal surface. derived from "briser'-to break, or from descriptions,
in Davis (4) and references cited therein, of tests of
Also mentioned is the "Dautriche method" in which power and brisance (each of which rated an explosive
the detonation velocity of an explosive being in terms of the measurement of the deformation or
investigated is compared with that of detonating cord, other change of a solid specimen which had been
which can be determined using relatively imprecise exposed to its action.
timers with long lengths of the cord.
366
The opening paragraph of the section on Tests of "tinder" and ignitability, which I had noted when
Power and Brisance mentions a "manometric bomb" passing the Boy Scout second class fir building test in
as a means of measuring the energy liberated in an 1927. As I saw it then (in 1941) ignition required that
explosion, but goes on to point out that the some of the fuel be raised to its "ignition
effectiveness of an explosion depends upon the rate at temperature", a concept in which I believed (with
which the energy is liberated ("Power" as understood some reservations) at that time. This seemed to be
by physicists and engineers). The high pressures more easily accomplished with small elements of fuel
developed by explosions (which reflect this rate) were in not too intimate contact with others.
first measured by the Rodman gauge, in which,
according to Davis (4), the pressure caused a hardened We used black gunpowder for various purposes,
steel knife to penetrate into a disc of soft copper. The including augmentation of primer output to ignite flair
depth of the penetration was taken as a measure of this compositions.
pressure. Davis also mentions "crusher Gauges" in
which copper cylinders are crushed between steel In this connection, I learned that "cannon powder" was
pistons, piezoelectric gauges, the "Trauzl lead block the coarsest of those we used because black powder as
test", in which the enlargement of a hole is taken as a well as other propellants, bums at the surface of the
measure of "power" or "brisance", the "small lead grains so that the coarser grains bum longer to
block test" of the Bureau of Mines, in which the maintain the generation of gas over the longer time
compression of the block is used a such a measure, the that a cannon projectile spends in the barrel. I later
"lead plate test of detonators" in which the diameter of read (in Davis (4)) that the "grains" of smokeless
the hole punched through the plate by a detonator is a powder for large guns are perforated to provide an
measure of its output. Similar tests with aluminum increasing surface area as the burning progresses and
plates are also mentioned. the holes enlarge so that the gas emission rate (which
is proportional to the area of the burning surface)
Explosive research was not, in 1941, among the keeps pace with an accelerating projectile.
missions of the NOL, but tests similar to those of
PROPERTIES OF EXPLOSIVES mentioned and After a year or so with the Propellant and Pyrotechnic
described by Davis (4) in the chapter so titled, which Group, I was transferred to the Research Group of the
is reviewed above, were performed by ordnance men EAU, (supervised by Harry H. Moore) which, as I
assigned to those Fuze Group of the EAU (whose remember, took on all tasks assigned to the EAU,
laboratory, we of the Propellant and Pyrotechnics which were not obviously within the purview of the
Group shared, so I could watch now and then) Propellant and Pyrotechnic Group or the Fuze Group.
pursuant to the development of fuze explosive trains The Research Group also was responsible for the
(an activity in which I was to become engaged in a design and development of some hydrostatic bomb
few months, so that I acquired "hands on" experience fuzes for antisubmarine warfare (probably because, at
with such tests). Meanwhile, however, my job was to some earlier date, the Fuze Group had been too busy
help develop pyrotechnic signals as a member of the with other projects), an area in which I found myself
Propellants and Pyrotechnics Group. shortly after my transfer to the Research Group. My
attempt to design an improved hydrostatic fuze led to
The adaptations of display fireworks, which were the the assignment of an attempt to establish fuze
objects of our efforts, were, for the most part, charges explosive train design criteria. Before asking Mr.
of mixtures of fuels such as charcoal, sulfur, Moore for fuze explosive train design criteria, I asked
magnesium, sugar, aluminum, iron filings, and sodium members of the Fuze Group, who had designing fuzes
oxalate with oxidants, such as potassium, sodium, for several years. Their approach as I understood it,
barium, and strontium nitrates, and potassium chlorate, was that of adapting a successful explosive train to a
and perchlorate, which were usually initiated by the new fuze, showing their proposed design to their boss,
flames from fuses, such as Bickford safety fuse. Mr. Ray Graumann. If he approved, They'd have
Sensitivity to such initiation was characterized in terms some made and test them. Although I was to fmd out,
of the maximum gap between the end of the fuse and some years later, that this was a reasonably sound
the surface of the pyrotechnic charge at which the approach (since Graumarm was a nationally recognized
charge was ignited. It seemed to me that the authority on fuze design), it didn't satisfy me, or Mr.
relationship between particle size, compaction, and Moore, at the time, all of which led to the assignment
sensitivity was similar to the relationship between mentioned above. From the members of the Fuze
analogous features of the twigs, shavings, or other Group, I learned that the word "fuze" was derived
367
from "fuse', (I had read in Davis (4)) the distinction with other EAU employees, that the burning rate of
between the terms, which is quoted hereinbefore and, black powder (and other propellants and explosives) is
they said, "fuze" had been defined "by act of proportional to pressure, I determined by a simple
Congress" (as has been quoted, from Davis (4) integration that the pressure, and hence the burning
herein). rate of a confined charge of black powder (or other
propellant or explosive) must increase exponentially
About the only "fuze explosive train design criterion" with the passage of time until its container, such as a
I learned from them was the requirement for "of-line bomb case or the paper tube of a firecracker, bursts.
safety" to preclude the transmission of detonation from
a detonator to the bursting charge until after a fuze had What Davis meant by "powder and explosives" is what
Narmod". aerospace engineers seem to mean by "pyrotechnics"
and what others mean by "energetic materials."
Application if this criterion requires a definition or
standard of "detonation'. The EAU Fuze Group used Davis' (4) description provided a perspective of fire
the visible damage to the metal parts which had held (or combustion) including explosion and detonation,
the explosive charge for this purpose, which, in turn, which, as Davis pointed out in the paragraph quoted a
requires a practiced eye. Members of the Fuze Group few pages back, are forms of combustion in that they
could, at a glance, recognize evidence of detonation, are dependent upon the transmission of heat. From
and even characterize the detonation as "high order" this explanation, combined with the thermodynamics I
or "low order'. Some even identified certain damage had learned in engineering school, I began to see
as evidence of "high intensity low order. detonation as "The rapid and violent form of
combustion in which energy transfer is by mass flow
I was one of over 1700 engineers and scientists in strong compression waves." Although these words
recruited by NOL in 1939, '40, and '41 to meet the are taken from the opening sentence of "Detonation"
increasing demands of the preparedness effort in by Weldon C. Ficket and William C. Davis (16),
response to the rising hostilities in europe and the (which was published in 1979) they express, more
perceived probability that the US would be involved. adequately than any that come to mind in 1994, the
The new employees, representing a wide range of view I received in 1942 from the book (4) Tenney L.
technical professions and coming from all over the Davis had published the previous year. This view is
country, saw things from many perspectives, to which quite similar to that held today by those who have
we introduced on another. Few of us found ourselves concerned themselves with detonation, but it is not
in a position to apply our previous (specific) sufficiently quantitative to serve as a basis for fuze
experience, but most could apply our general technical explosive train design criteria. The need for further
backgrounds. Lunch time conversations covered a research was quite apparent.
wide range of subjects, mostly more or less technical.
Sometime, in 1941, I remember hearing that My assignments, in the Research Group of the EAU,
"Detonation is a special kind of fire." Somewhere else besides the attempt to establish fuze explosive train
I heard detonation referred to as a "chain reaction". design criteria, were various, including the adaptation
I felt the need for a more meaningful (to me of a motion picture camera (designed for use in the
definition. It seemed to me that such a definition motion picture industry) for "slow motion" recording
should be more "scientific" than "a special kind of (from aircraft) of surface effects of underwater
fire', "a chain reaction', or "explosion", (as it is still explosions, adjusting designs of coil springs, design of
defined in dictionaries (1, 2, 13)). I didn't believe loading presses, fuze test gear, blast gages, and mine
that "detonation is a distinct phenomenon in which the detonators (to replace those which were adaptations of
chemical transformation is induced in every particle of Nobel's original (1864) blasting cap, (and still in use
the mass of explosive at the same instant", as defined in the 1940s) with an adaptation of modern (as of the
in an encyclopedia (14). Davis' (4) description of 1940s) commercial blasting caps. When NOL started
"Propagation of Explosion" which is quoted herein (a using "time sheets" to generate records of the
few pages back) was more meaningful to me. Davis distribution of effort among projects, I found myself
(4) included a heuristic description of what he referred trying to remember how many hours I had spent,
to as the "propagation of explosion" in black powder during each past week on each of 42 projects.
(which, now, seems applicable to other "energetic
materials" which have gaseous reaction products). Research pursuant to the establishment of fuze
Based on impressions I'd gained, from conversations explosive train design criteria, at this stage, literature
368
research, was fit in between other, more urgent sense which had been familiar to me as a kid,
efforts. I started with books on desks and shelves in shopping in late June and early July in preparation for
the EAU, including Davis (4), in which I reviewed the celebration of the Fourth, rather that in the senses, in
parts which have been quoted hereinbefore, and which they are used in connection with biology,
finished reading the 1941 edition, and when it turned ordnance, astronomy, or defined in most dictionaries).
up, the 1943 edition. A couple of books on ordnance Consideration of these formulas led to recognition that
and explosives, the titles and authors of which I have nitrates other than that of potassium, as well as
forgotten, provided a historical perspective, but didn't chlorates perchlorates, etc., have been used as solid
have much which seemed relevant to fuzz design. providers of oxygen, and increased my awareness that
firelight, other than the (black body radiation) of
The chapters of Davis (4) on BLACK POWDER, familiar yellow flames, was spectral emission of some
PYROTECHNICS, and AROMATIC NITRO elements (such as strontium, which emits red light) in
COMPOUNDS broadened and sharpened my historical the plasma state and that colored smoke in a colloidal
and chemical perspectives of fire (particularly in the suspension of dye in air.
forms of explosion and detonation). The use of
"Greek fire", a mixture of saltpeter (potassium nitrate) Davis (4) chapter on AROMATIC NITRO
with combustible substance as an incendiary in naval COMPOUNDS, after an introductory paragraph on
warfare is cited as a progenitor to the discovery that a their usefulness, in which it is stated that they were
mixture of potassium nitrate, charcoal, and sulfur is (when the book was published - in 1941) "the most
capable of doing useful mechanical work, and the important class of military high explosives" warns of
invention of the gun. The chapter traces the evolution their toxicity and the fact that they can be absorbed by
of black powder for blasting as well as use as a the skin. A paragraph on the chemistry of these
propellant and includes tables of the proportions of compounds was probably elementary to the graduate
charcoal, sulfur, and saltpeter as described by Marcus students for which the book was written, but for a
Graecus in the 8th century, Roger Bacon in the 13th mechanical engineer, such as I, it was a bit cryptic.
and others in the 14th, 16th, 17th, and 18th centuries, I'm not sure, in the 1990s, when I learned that
as well as the stoichiometric equation (2): "aromatic compounds" include "benzene rings" "a
structural arrangement -- marked by six carbon atoms
2KNO3+C+S --_ CO2+SO2+2KO lined by alternate single and double bonds" (2a), and
that a "nitro group" (NOz) the oxygen atoms are
for the burning of black powder, and was aware that bonded to the nitrogen atom which in an aromatic nitro
black powder burns without air because the thermal compound is, in turn bonded to one of the carbon
decomposition of the nitrate releases enough oxygen to atoms.
oxidize the charcoal, sulfur, and potassium, while the
nitrogen forms its own (NO molecules. Considering the chemistry of aromatic nitro
compounds as discussed by Davis (4), and quoted
Davis' (4) chapter on PYROTECHNICS, by which he above, from the basic chemical perspective I had
meant display and amusement fireworks (including acquired in chemistry courses, I saw that, like
such noisemakers as firecrackers, flares, signals, etc.), gunpowder and other pyrotechnics, they contained
traces the development of such items from ancient oxygen sufficient to oxidize at least some of the carbon
oriental origin to the fireworks we played with as kids and hydrogen they contained, but that the oxygen
on the Fourth of July, and the signals and illuminating would be available only after decomposition of the
flares used by the military, and warning flares used by nitro groups (or, in the case of black powder, of the
railroads and highway repair crews. This chapter had potassium nitrate). I can't say, now, when I looked up
been of specific interest to me as a member of the the heats of formation of the compounds involved, but,
Propellant and Pyrotechnics Group, providing when I did, I verified that the reactions were
"chemical" and "historical" perspectives of materials exothermal. These relationships were, of course,
with which we were working. Included were tables of obvious to the graduate students in chemistry for
compositions for colored lights, flares, fuzes, smokes, which Davis' book (4) was intended, as was the fact
marine signals, parade torches, whistles, lances, that, at the anticipated temperatures of the reaction
rockets, Roman candles, stars, fountains, pinwheels, products (carbon dioxide and water) they were in a
mines, comets, meteors, torpedoes, flash cracker gaseous state, so that the product of their pressure and
compositions, sparklers, serpents, snakes, etc. (Many volume was many times those of unreaeted solid or
of the foregoing terms were, apparently, used in the liquid unreacted explosives and propellants, as well as
369
those of gases or explosive mixtures of gases or acquired until my literature search in the areas of
gases and sols (colloidal suspensions) This, their explosives and detonation extended beyond the shelves
combustion was considered to be an explosion or and desks of the EAU. Davis' (4), in the section on
detonation if it was fast enough - which, in turn, turns Propagation of Explosion ,, which has been quoted
on definitions of explosion and detonation. herein, made the transition to the discussion of
detonation with the statement that The explosion of a
EXPLOSION AND DETONATION primary explosive or of a high explosive is believed to
be a phenomenon which is dependent upon pressure
Explosion and detonation are among the many or, perhaps more properly, on transmission of shock
words which, like fire and pyrotechnics have a • The propagation of detonation mercury fulminate is
number of meanings. According to some dictionaries described as a reaction which produces hot gas and is
(1,2), they are synonymous, although I doubt that any so rapid that the advancing front of the mass of hot
participant in this workshop considers them to be. gas amounts to a pressure wave capable of initiating
Each of the words has a connotation of sudden by its shock the next portion of fulminate. The high
expansion , and each is derived from a Latin word velocities of propagation of detonation (3500 meters
relating to the sound usually associated with it. per second in the fulminate of a blasting cap and much
Detonation (some meanings of which will be higher in TNT) are mentioned. Although Davis (4)
discussed below) is derived from the Latin for thunder didn't consider shock or detonation waves from
while explosion (like applause ) derives from the physical, thermodynamic, or hydrodynamic
Latin for clap, but it seems to be mostly commonly perspectives, his discussion left me with the impression
used in the sense of bursting of a container such as that consideration from such perspectives would be
a boiler or a bomb, but it often means sudden burning appropriate, an impression which was to be verified
as in a dust explosion or that of another explosive when I started reading OSRD reports.
mixture of gaseous or finely divided fuel with air.
As I recall, the other books on the desks and shelves
As observed by chemists and stated in the rule of of the EAU, which included a couple of books on
thumb which has been mentioned in the quotation of ordnance, one, by a hobbyist, on fireworks, and the
Davis' (4) section on Propagation of Explosion that Dupont Blasters Handbook, considered their subjects
any .... chemical reaction, doubles its rate with each from practical , empirical , and historical
10°C (approximate) rise of temperature, so that perspectives, omitting discussion of chemical or
exothermal reactions (in which heat is evolved) tend physical aspects of their subjects.
to be self accelerating. If, as is usual, their reaction
products include one or more gases, the pressure rises, On the NOL library, I found the War Department
if they are confined, until the container bursts. Since (which, after a decade or so, was to become the
surface or grain burning rates of propellants, Department of the Army) and Bureau of Mines
explosives and explosive mixtures increase with documents which had been cited by Davis (4) and
increasing pressure (17), such burning is self others from these sources and from Picatinny Arsenal,
accelerating and the pressure and rate increase, Frankford Arsenal, the Ballistics Research Laboratory
exponentially with time. Either the bursting of a (BRL) at Aberdeen, MD., the Naval Powder Factory
container or self accelerating process is an explosion at Indian Head, Md., the Franklin Institute, the Bureau
in one or another of the senses mentioned above. of Standards, and the British Ministry of Supply and
(Self accelerating fire is referred to as thermal Ordnance Board. I found these documents
explosion ). This association has led to the use of informative, interesting, and (some of them) quite
explosion to mean any self accelerating process, such pertinent to my objective of establishing fuze explosive
as in population explosion (which seems sudden train design criteria, but none contained much to
only from such perspectives as historical or clarify my views of explosion or detonation except for
geological ). a few OSRD reports.
370
REFERENCES (12) Chapman, D.L., "On the Rate of Explosion of
Gases", Philosophical Magazine (5), V. 47, p. 90,
(1) Stein, Jess, (editor), The Random House 1999.
Dictionary of the English Lan2ua_e, Random House,
Inc. 1966-1967. (13) Jouguet, E., 4echanique des Rxploszifs" Paris, O.
Doin et Fils, Editeurs, 1817.
(2) Webster's Twentieth Century Dictionary of the
English Language (unabridged), Publisher's Guild, (14) The Grolier Society, Grolier Encyclopedia), Vol.
Inc., New York, N.Y., 1939. 4, 1931-1951.
(21h) McCrone, John C., The Ape that Spoke, (15) Brady, George S., and Chuser, Henry R.,
William Morrow and Company, Inc., New York, Materials Handbook, McGraw-Hill Book Co., New
N.Y., 1991. York, etc., etc. 1977.
(3) Calvin, William H., The Ascent of the Mind, Ice (16) Soukhanov, Anne M., (Executive Editor), The
Age Climates and the Evolution of Intelligence, American Heritage Dictionary of the En21ish
Bantam Books, New York, Toronto, London, Sydney, Language, Houghton-Mifflin, Boston, New York,
Auckland, 1990. Londom, 1972.
(4) Davis, Tenney L., The Chemistry of Powder and (17) Ficket, Wildon, and Davis, William C.
Explosives, John Wiley & Sons, Inc., New York, Detonation, University of California Press, Berkeley,
1941, 1943. Los Angeles, London, 1979.
(61,6) Bradbury, Fahrenheit 451, Simon and Shuster, (20) Kabik, I., Rosenthal, L. A., and Solem, A.D.,
New York. "The Response of Electroexplosive Devices to
Transient Electrical Pulses" 3rd Electrical Initiator
(7) Wells, Robert W., Fire and Ice, Two Deadly Symposium, Paper #18, 1960.
Wisconsin Disasters, Fire at Peshtieo, Northword,
Madison, WI, 1968.
(8) Gamow, George, Thirty Years That Shook [Editor's Note: Time and space precludes completion
Physics, Doubleday & Co. (Science Study Series). of Mr. Stresau's paper. He does plan to publish the
New York, N.Y. 1966. entire story as a Stresau Laboratories, Inc. report at
a later date. Interested readers may contact him at:
(9) Langdon-Davies, John, Inside the Atom, Harper & Stresau Company
Brothers, New York and London, 1933. W7882 Stresau Lane
Spooner, WI 54801 ]
(10) Weast, Robert C. (editor), and Astle, Melvin J.
(associate editor), CRC Handbook of Chemistry and
Physics, 63rd Edition, CRC Press, Inc., Boca Raton,
FL. 1982-1983.
371
APPENDIX - List of Participants
Aerojet Propulsion Division .......... Hensen, Jeff Olin Rocket Research Co. ............ Moran, Joe
Aerospace Corporation, The ........ Gageby, James Olin Rocket Research Co. .......... Watson, Bruce
Aerospace Corporation, The ....... Goldstein, Selma
Pacific Scientific Corp. .......... Cunnington, Rick
Aerospace Corporation, The ......... Wong, T. Eric
Pacific Scientific Corp. ............... Day, Bob
American Safety Flight Systems, Inc .... Ziegler, Ron
Pacific Scientific Corp. ........ Greenslade, John T.
Analex Corporation ................ Smith, Floyd
Pacific Scientific Corp. ............ LaFrance, Bob
Analex Corporation ................ Steffes, Paul
Pacific Scientific Corp. ........... Schuman, Alex
Attenuation Technology, Inc ........ Dow, Robert L.
Pacific Scientific Corp. .............. Smith, Bob
Boeing Defense & Space Group . . Robinson, Steven P. Pacific Scientific Corp. .............. Spomer, Ed
Pacific Scientific Corp. .......... Todd, Michael C.
Conax Florida Corporation ....... Nowakowski, Don
Pacific Scientific Corp. .......... VonDerAhe, Ken
Consultant ..................... Folsom, Mark
Pacific Scientific Corp. ............. Welsh, Tom
Consultant ................... Gans, Werner A.
Consultant ................... O'Berr, Gerald L. Quantic Industries, Inc .......... Willis, Kenneth E.
EG&G Mound Applied Tech .... Beckman, Thomas M. Reynolds Industries Systems, Inc ....... Varosh, Ron
EG&G Mound Applied Tech ......... Kramer, Daniel Rockwell International Corp ..... Cascadden, Raymond
EG&G Mound Applied Tech ....... Munger, Alan C. Rockwell International Corp ........... Erazo, Anibal
EG&G Mound Applied Tech .......... Spangler, Ed
Sandia National Laboratories ..... Andrews, Larry A.
Energetic Materials Technology .... Ostrowski, Peter
Sandia National Laboratories • . . Bickes Jr., Robert W.
Ensign Bickford Aerospace Co ...... Graham, John A.
Sandia National Laboratories ...... Bonzon, Lloyd L.
Ensign Bickford Aerospace Co ...... Renfro, Steven L.
Sandia National Laboratories .... Brigham, William P.
Ensign Bickford Aerospace Co ....... Rhea, Arthur D.
Sandia National Laboratories ...... Chow, Wang W.
Franklin Applied Physics ........ Thompson, Ramie Sandia National Laboratories ......... Cooper, Paul
Sandia National Laboratories ........ Curtis, William
Geo-Centers, Inc .............. Landry, Murphy J.
Sendie National Laboratones ...... Fleming, Kevin J.
Halliburton Energy Services Sandia National Laboratories ...... Grubelich, M. C.
Explosive Products Center . . . Barker, James Sandia National Laboratories ....... Harlan, Jere G.
Halliburton Energy Services Sandia National Laboratories .... Holswade, Scott C.
Explosive Products Center . . . Motley, Jerry Sandia National Laboratories ........ Kass, William
Hercules Aerospace .............. Cole, David A. Sandia National Laboratories ...... Merson, John A.
Hercules Inc .................. McAIlister, Pat V. Sandia National Laboratories ....... Metzinger, Kurt
Hi-Shear Technology Corp .......... Novotny, Don Sandia National Laboratories ..... Mitchell, Dennis E.
Hi-Shear Technology Corp ........ Webster, Richard Sandia National Laboratories ......... Sales, F. Jim
Sandia National Laboratories ..... Setchell, Robert E.
Inland Fisher Guide Div. of GM ..... Wirrig, Steven T.
Sandia National Laboratories .... Stichman, Dr. John
John Hopkins University - CPIA ....... Filliben, Jeff Sandia National Laboratories ...... Troh, Wayne M.
Sandia National Laboratories ........ Williams, T. J.
Los Alamos National Laboratory .... Kennedy, James
Santa Barbara Research Center ..... Gonzales, Roman
Martin Marietta Specialty Components . . . Hinkle, Lane Santa Barbara Research Center ........ Jeter, James
Martin Marietta Astronautics ......... Wood, Lance SCB Technologies, Inc .......... McCampbell, C. B.
McDonnell Douglas ............. Tierney, Michael Schimmel Company .......... Schimmel, Morry L.
McDonnell Douglas Aerospace ........ Whalley, lan Special Devices, Inc ............. Sipes, William J.
McDonnell Douglas Space Sys. . . Parenzan, James E. Special Devices, Inc ................ Telle, Dennis
Morton International Inc ............ Hansen, David Stresau Company .............. Stresau, Richard
Morton International Inc ........... Richardson, Bill
Teledyne McCormick Selph ...... Ingnem, Robert W.
NASA Headquarters .......... Schulze, Norman R. Teledyne McCormick Selph ........ Marshall, Clyde
NASA Goddard Space Flight Center . . Bajpayee, Jays Teledyne McCormick Selph .......... Smith, Brian
NASA Johnson Space Center ...... Hoffman, William TPL Inc ....................... Brown, Ralph
NASA Kennedy Space Center ........ Rayburn, Larry
United Technologies/USBI ...... Webster, Charles F.
NASA Langley Research Center ...... Bement, Larry
Universal Propulsion Co., Inc .......... Barlog, Stan
NASA Lewis Research Center ....... Seeholzer, Tom
Universal Propulsion Co., Inc .... Magenot, Michael C.
NASA Stennis Space Center .... St. Cyr, William W.
Universal Propulsion Co., Inc ....... Mayville, Wayne
Naval Surface Warfare Center
Universal Propulsion Co., Inc ......... Wergen, Tom
Indian Head Division ..... Blachowski, Tom
University of Notre Dame ....... Gonthier, Keith A.
Naval Surface Warfare Center
University of Notre Dame ...... Powers, Joseph M.
Indian Head Division ..... Hinds, Jeffery L.
USAF/30 SW/SESX ............. Gotfraind, Mark
Naval Surface Warfare Center
USAF/45SPW/SESE ............ Wadzinski, Mike
Indian Head Division ...... Krivitsky, Darrin
USAF/B-1B Engineering Branch ....... Tipton, Steve
Naval Surface Warfare Center
USAF/Ogden Air Logistics Center .... Kangas, Charles
Indian Head Division ....... Martin, Steve
UTC/Chemical Systems Division ......... Lai, K. S.
Naval Surface Warfare Center
Crane Division .......... Schlsmp, Jan N. ZZYZX ......................... Potter, Jed
A-2
William Curtis Werner A. Gans
SandiaNationalLaboratories Consultant
P.O.Box 5800 1015 Lanark Ct.
Albuquerque,NM 87185 Sunnyvale, CA 94089
(505) 845-9649 (FAX)844-4616 (408) 245-2857
A-3
David Hansen JamesJeter
Morton InternationalInc. SantaBarbaraResearchCenter
M/S X1830 HughesAircraft Company
3350 Airport Road 75 CoromarDrive
Ogden,UT 84405 Goleta,CA 93117
(801) 625-9222 (FAX)625-4949 (805) 562-7539 (FAX) 562-7740
A-4
MurphyJ. Landry Kurt Metzinger
Geo-Centers,Inc. Sandia National Laboratories
2201 BuenaVista Dr., SE Structrual Mechanics Group 1562
Albuquerque,NM 87106 P.O. Box 5800
(505) 243-3483 (FAX)242-9497 Albuquerque, NM 87185-5800
(505) 844-5077
MichaelC. Magenot
UniversalPropulsionCo., Inc. Dennis E. Mitchell
25401 North CentralAve. Sandia National Laboratories
Phoenix,AZ 85027-7837 P.O. Box 5800
Albuquerque, NM 87185-0522
Clyde Marshall (505) 845-8656 (FAX) 844-3894
TeledyneMcCormickSelph
8920 QuartzAve. Joe Moran
Northridge,CA 91324 Olin Rocket Research Co.
(818) 718-6643 (FAX)998-3312 P.O. Box 97009
Redmond, WA 98073-9709
Steve Martin (206) 885-5000 (FAX) 882-5744
NavalSurfaceWarfareCenter
IndianHeadDivision Jerry Motley
101 StraussAve. Halliburton Energy Services
IndianHead,MD 20640-5000 Explosive Products Center
(301) 743-4243 (FAX)743-4881 2001 S. 135
AIvarado, TX 76009
Wayne Mayville (817) 783-5111 (FAX) 783-5812
UniversalPropulsionCo., Inc.
25401 North CentralAve. Alan C. Munger
Phoenix,AZ 85027-7837 EG&G Mound Applied Technologies
(602) 869-8067 (FAX)869-8176 P.O. Box 3000
Miamisburg, OH 45343-0987
PatV. McAIlister (513) 865-3544 (FAX) 865-3491
HerculesInc.
M/S N1EA1 Don Novotny
P.O.Box 98 Hi-Shear Technology Corp.
Magna,UT 84044 24225 Garnier Street
(801) 251-6192 (FAX)251-6676 Torrance, CA 90509-5323
(310) 784-7857 (FAX) 325-5354
C. B. McCampbell
SCB Technologies, Inc. Don Nowakowski
1009 Bradbury Dr. S.E. Conax Florida Corporation
Albuquerque, NM 87106 2801 75th Street North
St. Petersburg, FL 33710
John A. Merson (813) 345-8000 FAX: 345-4217
Sandia National Laboratories
P.O. Box 5800 Gerald L. O'Barr
Albuquerque, NM 87185-0329 6441 Dennison St.
(505) 844-2756 (FAX) 844-4709 San Diego, CA 92122
(619) 453-0071
A-5
PeterOstrowski Steven P. Robinson
EnergeticMaterialsTechnology Boeing Defense & Space Group
P.O.Box 6931 M/S 81-05
Alexandria,VA 22306-0931 P.O. Box 3999
(703) 780-5854 (FAX) 780-4955 Seattle, WA 98124-2499
(206) 773-1894 (FAX) 773-4846
JamesE. Parenzan
McDonnellDouglasSpaceSystemsCo. William W. St. Cyr
MSA3/11-1/L292 NASA Stennis Space Center
5301 BolsaAve. Code KA22 Building 1100
HuntingtonBeach,CA 92647 Stennis Space Center, MS 39529-6000
(714) 896-5778 (FAX)896-1597 (601) 688-1134 (FAX) 688-3312
A-6
RobertE. Setchell Dr. John Stichman
SandiaNationalLaboratories SandiaNationalLaboratories
Department5166 Surety Componentsand
P.O.Box 5800 InstrumentationCenter
Albuquerque,NM 87185-0445 P.O.Box 5800
(505) 844-3847 (FAX)844-7431 Albuquerque,NM 87185-5800
BobSmith DennisTalle
PacificScientificCorp. SpecialDevices,Inc.
102 South Litchfield Road 16830 West PlaceritaCanyonRoad
Goodyear,AZ 85338-1295 Newhall,CA 91321
(602) 932-8450 (FAX)932-8949 (805) 259-0753 (FAX)254-4721
BrianSmith RamieThompson
TeledyneMcCormickSelph FranklinApplied Physics
3601 Union Road 98 Highland Ave.
P.O.Box 6 P.O. Box 313
Hollister,CA 95024-0006 Oaks, PA 19456
(408) 637-3731 (FAX)637-5494 (215) 666-6645 (FAX) 666-0173
A-7
RonVarosh lan Whalley
ReynoldsIndustriesSystems,Inc. McDonnell Douglas Aerospace
3420 FostoriaWay M/S A3-L292/11-1
San Ramon,CA 94583 5301 Bolsa Ave.
(510) 866-0650 (FAX)866-0564 Huntington Beach, CA 92647
(714) 896-6491 (FAX) 896-1106
Ken VonDerAhe
PacificScientific Corp. T. J. Williams
EnergySystemsDivision Sandia National Laboratories
7073 West Willis Road,Box 5002 P.O. Box 5800
Chandler,AZ 85226-5111 Albuquerque, NM 87185-5800
(602) 796-1100 (FAX) 796-0754 (505) 844-3356 (FAX) 844-4616
A-8
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Unlimited
This NASA Conference Publication contains the proceedings of the Second NASA Aerospace Pyrotechnics Systems
Workshop held at Sandia National Laboratories, Albuquerque, New Mexico, February 8-9, 1994. The papers are grouped
by sessions:
Session 1 - Laser Initiation and Laser Systems
Session 2 - Electric Initiation
Session 3 - Mechanisms & Explosively Actuated Devices
Session 4 - Analytical Methods and Studies
Session 5 - Miscellaneous
A sixth session, a panel discussion and open forum, concluded the workshop.