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b. Concentration of reactants
1. What are the effect of the concentration of HCl to the rate of reaction and
Na2S2O3
Answer:
5 ml of Na2S2O3 0.15 M was mixed with 5 ml of HCL 3 M recorded time
required since addition of 5 ml HCL 3 M solution until sign (X) no longer
seen, the time required was 11 s. The solution becomes turbid and endothermic
reactions occur.
5 ml of Na2S2O3 0.15 M mixed with 5 ml of HCL 1,8 M, the time required
since the addition of 5 ml of HCL 1,8 M solution until the sign (X) is no
longer visible, the time required is 13 s. The solution becomes turbid.
5 ml of Na2S2O3 0.15 M mixed with 5 ml of HCL 0,6 M, the time required
since the addition of 5 ml of HCL 0,6 M solution until the sign (X) is no
longer visible, the time required is 18 s. The solution becomes turbid.
So from the three experiments can be known the effect of concentration on
time: The greater the concentration of HCl, the reaction will be faster too.
2. What are the influences of Na2S2O3 concentration to the rate of reaction?
Answer:
5 ml of HCl 3 M mixed with 25 ml of Na2S2O3 0,12 M, the time required
since the addition of 25 ml of Na2S2O3 0,12 M solution until the sign (X) is no
longer visible, the time required is 14 s. The solution becomes turbid.
5 ml of HCl 3 M mixed with 25 ml of Na2S2O3 0,09 M, the time required
since the addition of 25 ml of Na2S2O3 0,09 M solution until the sign (X) is no
longer visible, the time required is 21 s. The solution becomes turbid.
5 ml of HCl 3 M mixed with 25 ml of Na2S2O3 0,06 M, the time required
since the addition of 25 ml of Na2S2O3 0,06 M solution until the sign (X) is no
longer visible, the time required is 30 s. The solution becomes turbid.
5 ml of HCl 3 M mixed with 25 ml of Na2S2O3 0,03 M, the time required
since the addition of 25 ml of Na2S2O3 0,03 M solution until the sign (X) is no
longer visible, the time required is 60 s. The solution becomes turbid.
So from the five experiments can be known the influence of concentration
on time: The greater the concentration of Na2S2O3, the reaction will be faster
too.
3. Draw a graph showed the relationship of 1/time and sodium thiosulfate
concentration!
Answer:
1
0.9
0.8
0.7
0.6
1/t (10-1)
0.5
0.4
0.3
0.2
0.1
0
1 2 3 4 5 6
Concentration of Na2S2O3 (M)
c. Temperature
1. What are the effect of temperature toward rate reaaction on the reaction
between potassium permanganate with oxalic acid and sulphuric acid?
Answer: when temperature in a reaction that take place is raised (in the
practice is heating), it causes particles to move more actively so the collisions
ar more frequent causing greater the reaction rate.
2. Write down the occured reaction
Answer: 5H2C2O4 + 9H2SO4 + 6KMnO4 → 6MnSO4 + 10CO2 + 14 H2O +
3K2SO4
d. Catalyst
1. FeCl3 are containing two kinds of ions, cations, and anions, which ion works
as a catalyst?
Answer: Fe+3
2. In this reaction, H2O2 decomposes to form H2O and O2. Whether the catalyst is
also changing as aresult of a reaction?
Answer: No, catalyst is just as accelerator of reaction and does not participate
react
e. Autocatalyst
1. Why is the rate of reaction on the first droplets of aa solution of KMnO4 in the
first tube is slower when compared with the second tube?
Answer: Because in the second tube there are two catalysts MnSO4 and
KMnO4. MnO4 act as autocatalyst.
2. What is the effect of Manganese (II) sulfate in the reaction which takes place
on the tube?
Answer: as autocatalyst causes the reaction to take place quickly than thr first
tube.
ELECTROCHEMISTRY
a. Redox titration
1) Write down all of the occured reaction in this experiment.
Answer:
Reaction of metal and metal nitrat solution
2. Cu(s) + Pb(NO3)2(aq) ↛
Cu(s) + Zn(NO3)2 (aq) ↛
Cu(s) + 2AgNO3(aq) → Cu(NO3)2(aq) + 2Ag(s)
Cu(s) + NaNO3(aq) ↛
4. Cu (s) + HCl(aq) ↛
2Fe(s) + 6HCl (aq) → 2FeCl3(aq) + 3H2(g)
Mg(s) + 2HCl (aq) → MgCl2(aq) + H2(g)
Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)
Pb(s) + HCl(aq) → PbCl2(aq) + H2(g)
2) Sort of seven metals (Al, Pb, Zn, Ag, Na, Cu, Fe) by dimishing the power
reduction and give explanation
Answer:
The power reduction of seven metals is Na>Al>Zn>Fe>Pb>Cu>Ag. According to
the position of the left metal in the voltaic cell the characteristics of the reducer are
stronger and the reduction potential is smaller.
3) Where is the position of Hydrogen in the series above
Answer:
Position of Hydrogen between Pb and Cu
b. Electrolysis of KI solution.
1) What is the function of the salt bridge?
Answer:
The function of the salt bridge is to neutralize the anion and cation excess in the
solution and to close the circuit so that the reaction can take place continuously.
2) Explain why the reaction can take place spontaneously in terms of free energy?
Answer:
A reaction can be said to be spontaneous when it qualifies for thermodynamics,
ie, its free energy Gibbs (DGo) is equal to zero. The DGo value can be determined
from the standard cell potential by the formula
DGo = - n F Eocell
Thus, it can be deduced if a cell has a positive Eocell, then DGo will be negative
and its reaction is spontaneous.
c. Electrolysis of CuSO4
1) Write equations for all reactions that occur in electrode!
Answer:
1. Using C electrode occured there is gas bubbles in the anode and in the cathode
there is a golden-brown plating.
Reaction:
CuSO4(aq) → Cu 2+ + SO42-
2. Using Fe electrode occured there is gas bubbles and the color of solution
changes to be brownish black in the anode and in the cathode there is a golden-
brown plating.
CuSO4(aq) → Cu 2+ + SO42-
2) HCl solution containing H+ and Cl- ions. Which ions form complexes with Cu+ ion
? Give an explanation.
Answer :
Cl- , because liganol is an anion or a neutral molecule. Ligan Cl- is weakness than
H2O. The reaction is :
Cu2+ + 4Cl- [Cu(Cl)42-]
2) Write the half reactions for all redox reactions that occur in this experiment.
Answer :
Oxidation : Mn2+ + 2 H2O MnO2 + 2 e- + 4 H+ x3
Reduction : MnO4- + 3 e- + 4 H+ MnO2 + 2 H2O x2