Solutiorr to Probleni 5.

2
fttgtrcity in
lhe question irere is whether the fugacity of CO: in the compressecl gas is higher than the
and the conclensecl
satur.atecl gas. The actual temperature is lorue. tl.ran the triple-point ternperature,
'phase irr eclr-rilibriunr wiLh the \rapoul-, if it exists, is solicl. 'lo find Lhe strturation pressure. wcr consider holv it
cl.i.irge-i fror' the vapour 1r..r..,r. ol pur.e OO2 (conrponent 1) ti.i
its neu' r'altte by irljection of Il' (cotrtpoltetrt
irr Figure t 'lhe I12 is
2) rrrtrl the rotal pressure is 60 bar'. \ve therefore consider a. process as illusllat,ed
i1itr.r in lltc sense, t.Irat it cloes not clissoll,e in ther solid phase.

(10: (g) 10: (8) + Il.: (g)

P.'. : {1. 13112 i-ral Ap (e) Pq,e, * PH, - tiQ l-rar
-'l'
- L 73 ii ---+ 7'- 173 h
\

C02 (s) Ap (s) C02 (s)

7'= 173 K ----+ I .= 17ll Ii

Figure 1: Available tiata and charrges'

'lhc chilnge in chen-rical potentltll fol CO': in the gas pliase is

C LrntPrr:sstlrl st ai tr

fp,(yr , Ht '1lni 1 H1 [lrr/- i,.]-'; i;' '''' 'l lr {F

t
prlrl (l()"

purt'L02 vapour ctrrt be assumecl to bc'ec1utl to the

u,here /r is the fugacity of co2. The fugt-r,ciry t-rl tlre
\rilpoulr lllessure.0.139i bar, because the vapour
pr.r"ru.. is low The lugacity of C'Oz irl the cottipressed
sLilte nlusr ]re estirl-ri-r,tcd. tttld ri'e seL
I

.l't = iLUtP
r't-slrrctiieL.r' of (''o2, i'illcl P is tlie totiil
*,lrrre rincl gr are the rire fugacitr.coellicie,t a,cl rriole fractir.ru.
/r I
.lhe fugacity c<,rel1lcierrt niust, l-re estinlated. aticl \\'e t]'y t,he Ylrtt deL \'Vat-r'ls equatir-'rr:
pressure) 60 bar.
Pu 'u a
^-: RT r'-b RTr
-:
'I'he coeilicients for the rnixture tlre given by
luia cr lr,r = v) +(rI.)+a(r,r)$fu
er : II!t,u,ttiTt\
ij
h
- = fr,b,
L"'
t
b-= ?\bl" +Y2-b)-
'lhe frigacitv corrflicient ol cotllponetlt I il] tl're rltixtu|e is (trq' (3 5-11) itt Irrausnitz et
al'):

q-
r,r;, : ,.;! * :- t,- l5-r'!'' - 1,, ' (2 3)

in several textboohs. e g' '\tliirls (P'

\u'rerical values fbr the van der waals paralneters may be for.rnd
\\''. Atlrins, Phy s'tcttl C.'hem'istry. 6th edition' O'xl'olcl' I9t)8 )
:

(.. atnl cttto nlol b. cnril ntol

CO: (1) 3.640 x 10b 42.67
H2 (2) 0. 2r176 x 100 26.61